WO2010098691A1

WO2010098691A1 - Apparatus for the purification of liquid, method for washing a hollow-fibre filter and use of the method for washing a hollow-fibre filter

Info

Publication number: WO2010098691A1
Application number: PCT/RU2009/000593
Authority: WO
Inventors: Олег Владимирович ДУБОВ; Олег Евгеньевич САМСОНОВ; Джозеф Львович ШМИДТ
Original assignee: Общество С Ограниченной Ответственностью "Аквафор" (Ооо "Аквафор")
Priority date: 2009-02-26
Filing date: 2009-10-30
Publication date: 2010-09-02
Also published as: CN102099302A; RU2009106887A; CN102099302B; RU2410336C2

Abstract

The present group of inventions relates to devices for the purification of liquids and may, in particular, be utilised for the purification of drinking water and waste waters, including sea, river, lake and well water, by removing polar and non-polar organic substances, ions of heavy metals, microorganisms and a significant amount of salts. The group of inventions may be used both for the collection and purification of liquid from open sources and non-pressurised vessels, and also for the collection and purification of liquid, particularly drinking water, from domestic drinking water lines. An apparatus for the purification of liquid comprises means for supplying liquid to be purified, an electro-coagulation unit, a hollow-fibre filter with liquid backwash, a reverse osmosis unit, a collecting vessel, a non-return valve and means for drawing off the purified liquid. The hollow-fibre filter is backwashed first with liquid and then with a pressurised mixture of liquid and air, fed from the collecting vessel. While liquid is being pumped from the collecting vessel, atmospheric air is fed into the collecting vessel using the non-return valve. The proposed water purification apparatus makes it possible to extend the service life of the membranes used in the apparatus, and furthermore the system for the purification of liquid permits assembly in the form of a compact apparatus with a weight of a few kilograms, so that it can be carried by hand.

Description

INSTALLATION FOR CLEANING A LIQUID, METHOD FOR RINSING A HEMICON-FILTER AND APPLICATION OF A WASHING METHOD

FIBER FILTER

The claimed group of inventions relates to devices for cleaning liquid media and can be used mainly for the treatment of drinking water and wastewater, including sea, river, lake and well water, from polar and non-polar organic substances, heavy metal ions, microorganisms and a significant amount of salts . The group of inventions may be applicable both for the collection and purification of liquids from open sources and non-pressurized containers, and for the collection and purification of liquids, mainly drinking water, from household and drinking water pipelines.

In the prior art, systems for liquid purification based on a combination of membrane filtration and reverse osmosis are known. Often, in such systems, a backwash mode is provided, which allows you to periodically remove a layer of filtered particles from the membrane surface to maintain its constant permeability.

Also, prior art systems using electrocoagulation to remove dissolved organic substances from water are known.

In the patent of the Russian Federation Ns 2171787 (publ. 2001, C 02 F 1/18) a household device for drinking water purification is described, comprising sequentially installed means for supplying purified water, a coarse purification unit, an electrocoagulation unit, a flocculation chamber, a fine purification unit, a water treatment unit UV radiation, a means of removing purified water.

The electrocoagulation unit is a system of parallel plates made of aluminum or its alloys. The flocculation chamber is necessary for the aggregation and precipitation of aluminum hydroxide. As a fine filter, a cartridge filter element is preferably used, which requires periodic replacement. Membrane micro or ultra filtration elements, as a rule, allowing multiple regeneration, are not used in the system.

A serious disadvantage of the described invention is the need for a special chamber for flocculation and sedimentation of the coagulate. From the description of the patent it follows that the flocculation chamber has large dimensions and weight. The need for a large and heavy sedimentation chamber sharply limits the applicability of household electrocoagulation systems that are not equipped with a coagulate forced separation unit (for example, microfiltration).

The closest technical solution to the proposed one is a water purification device, taken as a prototype, containing a means for supplying purified water, a coarse purification unit, a microfiltration unit with periodic backwashing, a reverse osmosis unit, a storage tank for collecting concentrate and a means the withdrawal of purified water (US patent Ns 6,120,688, publ. 2000, C 02 F 1/44).

A filter with a pore size of about 500 microns is used as a coarse cleaning block. As a microfiltration unit, a module of hollow tubular membranes with a pore size of about 0.2 nm with an integrated air compressor is used to blow air through the membrane module with air bubbles to prevent deposition of contaminants on the working side of the fibers. Rinsing a module with a hollow fiber membrane is carried out periodically under pressure from a concentrate that accumulates in the device described in a special tank. The concentrate is also used to power the reverse osmosis unit during the washing period of the module with a hollow fiber membrane, since at this moment the microfiltration unit does not supply the system with filtered water. The concentrate enters the non-pressurized storage tank and flows freely into the drain when the tank is full. The concentrate is supplied from the backwash tank by a pump, while the concentrate falls on the opposite working side of the hollow fiber membrane, removing contaminants. The backwash takes place automatically by opening the solenoid valves according to the signal from the controller. When backwashing, only water is used, without air, which reduces its effectiveness.

The well-known installation is intended for water purification of any quality, including sea water, surface water, water from areas with adverse environmental conditions and other sources, as well as purification of drinking water from microorganisms, viruses, high molecular weight compounds and salts of heavy metals.

The disadvantage of this installation is the short life of the reverse osmosis membrane. This is due to a sharp decrease in the permeability of the pores of the membrane due to the presence of soluble high molecular weight organic compounds in the purified water, the removal of which is impossible using the sorption methods used in the prototype at the initial stage of purification.

In addition, the disadvantage of the known installation is the presence of a complex and expensive system of compression and distribution of air, and the continuous blowing of the microfiltration module stimulates the development of aerobic bacteria on its surface. In addition, the installation consumes a fairly large amount of water and additionally includes a sufficiently powerful and cumbersome pump for flushing the microfiltration unit. All this together complicates the design of the known installation and increases its cost.

As a rule, the membrane plants used in most modern water treatment systems can significantly concentrate harmful impurities and obtain deeply purified water suitable for subsequent use, for example, in household and drinking needs. The main problem that arises when using membrane technologies (reverse osmosis, micro-, ultrafiltration) is the restriction on the content of soluble high molecular weight organic substances in the purified water. These impurities significantly limit the use of membrane technology, because it significantly reduces the life of the used membranes. The general objective of the group of inventions and the required technical result achieved using the group of inventions is to develop a new installation for cleaning liquid, an effective method of washing a hollow fiber filter and to extend the life of the membranes used in the installation.

An additional objective of the group of inventions is the realization of the possibility of assembling the system in the form of a compact, in comparison with the prototype, installation with a mass of several kilograms, which can be carried manually.

The task and the required technical result when using the group of inventions is achieved by the fact that the installation for cleaning liquid containing means for supplying the liquid to be cleaned, a hollow fiber filter with backwashing liquid, a reverse osmosis unit, a storage tank with upper and lower nozzles and means for draining the purified liquid, according to the invention is equipped with an electrocoagulation unit, the input of which is connected to the output of the means for supplying the liquid to be cleaned, and the output with the inlet of the hollow fiber filter, reverse a valve for supplying air from the atmosphere to the storage tank during pumping of liquid from the storage tank, the storage tank is configured to create a vacuum in it to supply air from the atmosphere and backwash the hollow fiber filter sequentially with a liquid, and then with a mixture of liquid and air coming from it . The non-return valve for supplying air from the atmosphere to the storage tank can be installed in the upper part of the storage tank, or installed on a pipe connected to the upper pipe of the storage tank. The upper branch pipe of the storage tank is made in-depth inside it, and the lower section of the upper pipe is at least 50 mm higher than the lower pipe. The lower nozzle is designed to exit the fluid to the reverse osmosis unit with the possibility of creating a vacuum in the storage tank. The upper nozzle is designed for liquid inlet into the storage tank, liquid outlet, and then a mixture of liquid and air on the hollow fiber filter. The task and the required technical result when using the group of inventions is achieved by the fact that the method of washing a hollow fiber filter, including backwashing with a liquid coming from a storage tank, according to the invention is carried out sequentially with a liquid and then under pressure with a mixture of liquid and air coming from a storage tank. The air supply from the atmosphere to the storage tank during pumping of liquid from the storage tank is carried out using a non-return valve. Moreover, the backwash is carried out at a rate of less than 5 seconds, preferably less than 3 seconds. At the initial stage, backwashing is carried out with liquid under pressure created by an air cushion in the upper part of the storage tank.

Before starting the backwash of a module with a hollow fiber membrane in the storage tank, the pressure inside the atmospheric air increases due to the pressure of the liquid continuously flowing through the upper pipe into the specified storage tank. The flushing process begins when compressed air reaches a certain pressure, when the liquid inside the storage tank is higher than the end of the lower cut of the upper pipe, while the liquid through the specified upper pipe is flushed, and when the liquid level reaches the end of the lower pipe, through the upper pipe air begins to flow into the flushing, dragging along part of the liquid remaining in the storage tank, while a mixture of liquid and air is formed, which is used lzuyut at the final washing stage, thus there is a highly effective cleaning of the at least one module with hollow fiber membrane. Upon reaching the end of the backwashing stage, pumping out of the remaining liquid through the lower pipe of the storage tank to the reverse osmosis unit begins, while a vacuum occurs inside the storage tank, due to which atmospheric air enters the storage tank from the outside through the check valve. The use of a combination of liquid and air significantly increases the washing efficiency of the hollow fiber filter compared to washing only with liquid.

In contrast to the prototype, a liquid purification unit includes an electrocoagulation unit for deeper liquid purification, mainly drinking water, in which an additional membrane stage of liquid purification takes place. This allows you to translate organic compounds dissolved in water into a colloid, which is easily cut off by subsequent filtration, thereby protecting the reverse osmosis membrane and prolonging its life.

The proposed installation for liquid purification is characterized by a highly efficient method of washing the hollow fiber filter in series with a liquid, and then with a mixture of liquid and air, which does not require, in contrast to the prototype, the installation of an additional bulky pump and air compressor.

Moreover, air does not stimulate the development and formation on the surface of used hollow fiber membranes, bacteria and biological films, since these membranes come into contact with air periodically (only during washing).

The disclosure of the essence of the group of inventions is illustrated below by the following drawings:

FIG. 1 - shows a General view of the installation for cleaning liquid;

FIG. 2 - shows the storage tank connected through a pipeline with a check valve;

FIG. 3 - shows the storage tank connected to the non-return valve through a fitting directly installed in the upper part;

FIG. 4 - shows the storage tank with the liquid level before starting backwashing;

FIG. 5 - shows the storage tank with liquid level at the moment immediately after backwashing;

FIG. 6 - shows the storage tank during pumping fluid to the reverse osmosis unit. A liquid purification device comprises sequentially installed means for supplying a liquid to be cleaned 1, an electrocoagulation unit 2, a hollow fiber filter 3, a reverse osmosis unit 4, a storage tank 5, and a means for withdrawing the purified liquid b (Fig. 1).

The output of the means for supplying the liquid to be cleaned 1 is connected to the input of the electrocoagulation unit 2. The electrocoagulation unit 2 is a system of electrodes that can be made in the form of parallel plates or embedded concentric pipes, with the possibility of supplying a constant / pulsating voltage of 100 V. The anodes are made of aluminum. The cathodes can be made of both aluminum and inert material, for example, stainless steel. When both electrodes are made of aluminum, alternating voltage is applied with uniform polarity reversal for at least 10 ^"4 sec. The current level can be adjusted depending on the degree of water pollution. The output of the electrocoagulation unit 2 is connected to the input of the hollow fiber filter 3 made by from at least one module with a hollow fiber membrane Filtration is carried out through a module with a hollow fiber membrane 8, for example, with a pore size of from 0.01 to 5 microns and preferably from 0.05 to 0.8 microns. the fiber filter 3 is connected to the storage tank 5, and the volume of the storage tank 5 exceeds the volume of the hollow fiber filter 3 by 2-10 times. The storage tank 5 has a top 14 and bottom 15 pipes. 14 is located inside the tank 5 above the lower pipe 15 by more than 50 mm, the lower pipe 15 is designed to exit the fluid to the reverse osmosis unit 4 and to create a vacuum inside the storage tank 5. The upper pipe 14 is intended It is designed to enter liquid into the storage tank 5, exit the liquid, and then the mixture of liquid and air to the hollow fiber filter 3. Air is supplied from the atmosphere through the check valve 21. The specified valve 21 can be installed on the pipe 19 connected to the upper pipe 14 of the storage tank 5 (FIG. 2), or installed in the upper part of the storage tank (for example, in the fitting 22 directly installed in the upper part of the storage tank 5 (Fig. 3). In the storage tank 5, a mixture of liquid and air is formed for countercurrent backwash of the hollow fiber filter 3. The backwash process is controlled by valves in automatic mode. Typically, flushing is carried out for less than 5 seconds, preferably less than 3 seconds. The storage tank 5 is connected to the reverse osmosis unit 4. The reverse osmosis unit 4 consists of a pump 16, at least one sorption purification module 17 and at least one module with a reverse osmosis membrane 18. The contaminants are discharged along line 10, the purified liquid is discharged along line 6 for use (Fig. 1).

If the device for cleaning the liquid is intended for the intake of liquid from open sources and containers not pressurized, then the means for supplying the liquid to be cleaned 1 can be performed, for example, in the form of a supply unit consisting of a coarse filter and a pump. As a coarse filter, it is preferable to use a set of grids and / or a volumetric filter (flat in the form of a layer of non-woven material or a cartridge) capable of retaining mechanical impurities from 20 to 1000 microns in size.

If the fluid purification device is designed to draw fluid from highways under pressure, for example, from household drinking water, the means for supplying the fluid to be cleaned 1 can be made in the form of a fitting with a valve.

Installation for cleaning liquid works as follows.

The liquid from open sources or tanks that are not under pressure, which passed through the means for supplying the liquid to be cleaned 1, enters the input of the electrocoagulation unit 2.

In the electrocoagulation unit 2, the liquid passes through a system of electrodes, which, when dissolved, emit aluminum hydroxide, causing coagulation of high molecular weight organic compounds, the presence of which in the liquid being cleaned, even in small quantities, sharply reduces the resource of reverse osmosis and, in part, filtration membranes. After the block of electrocoagulation 2 can be a check valve 7 is installed, which serves to prevent the reverse flow of water towards the water intake at times when the hollow fiber filter 3 is under high pressure.

The liquid exiting the electrocoagulator 2 enters the inlet of the hollow fiber filter 3. During the passage of the liquid through the hollow fiber filter 3, colloidal aluminum hydroxide with high molecular weight organic substances adsorbed on it is removed, only low molecular weight organic compounds and inorganic ions remain. After filtration treatment, the liquid through the valve 12 enters the pump 16, the reverse osmosis unit 4. The pump 16 directs the liquid to at least one sorption treatment module 17, where the removal of residual organic substances occurs, and then to at least one module with a reverse osmosis membrane 18 with a pore size of the order of 0.0001 microns. Reverse osmosis membranes contain the narrowest pores and therefore are the most selective. They are used in the final stages of liquid purification, as they are able to retain bacteria, viruses, as well as most of the dissolved salts and organic substances.

As a result of the passage of liquid through the module with reverse osmosis membrane 18, permeate is formed - purified liquid and concentrate. Permeate is supplied for use on line 6, and the concentrate (hereinafter simply liquid) is supplied through line 19 through a water flow control device 20 to storage tank 5. At this moment, valves 9, 11, 12 are closed.

Before the start of the backwash stage, the pressure inside the storage tank 5 gradually increases, due to the compression of the continuously flowing liquid inside the atmospheric air. Upon reaching a pressure of preferably not less than 1, 5 and not more than 10 atmospheres and at a liquid level above the cutoff of the upper pipe 14, valves 9, 11 are forcibly opened at the same time and valve 12 is closed. Forced opening / closing of valves 9, 11, 12 and 13 during operation of the installation and the implementation of the backwash method is provided, for example, using a special controller system. At the beginning of washing, the liquid in the storage tank 5 (Fig. 4) is supplied under pressure from the air cushion from above through the upper pipe 14 to the inlet of the hollow fiber filter 3, washing at least one module with a hollow fiber membrane 8. When the liquid level is in the storage capacity 5 reaches the lower cut of the upper pipe 14 (Fig. 5), the air located in the upper part of the storage tank 5 and squeezing the liquid inside it begins to flow through the specified upper pipe 14 to the exit of the storage containers 5, carrying the part remaining inside said liquid container 5. At this time, a mixture of liquid and air is formed inside the storage tank 5. Air bubbles present in large quantities in the aforementioned mixture of liquid and air pass through the pores of the hollow fiber membrane, providing a much more complete cleaning, unlike the prototype, where the air bubbles generated by a separate air compressor inside the microfiltration unit remove pollution only from the outside ( working) surface of the membrane fibers, without penetrating deep into its pores. The backwash rate can be from 3 to 20 ml per 1 second per 1 m ^{2 of} hollow fiber membrane. The total washing time of the hollow fiber filter 3 is not more than 2% of the total continuous operation time of the installation.

Contaminants are discharged through line 10. After the cleaning process is over, valves 9, 11 are forcibly closed and valve 13 opens. Through the lower pipe 15, the pump 16 starts pumping water to at least one sorption treatment module 17 and then to at least one a module with a reverse osmosis membrane 18. During pumping out, inside the mentioned container 5, a vacuum occurs, which is necessary for atmospheric air to enter through the check valve 21 (Fig. 6). Moreover, due to the use of the washing liquid remaining in the storage tank 5, the system operates autonomously in a closed loop, which allows the reverse osmosis unit to continuously operate 4. The advantage of the closed loop of the system is the effective saving of the fluid. For example, for fresh water, the total volume of liquid used for backwashing and leaving in discharge, does not exceed 20%, preferably 5%, of the total volume of fluid consumed.

After emptying the capacity 5, the device switches to the intake mode of the liquid intended for cleaning from an external source.

The specific performance of the installation is determined by the quality of the source fluid and the requirements for the purity and quality of the resulting fluid.

Depending on the quality of the initial liquid, it is possible to control the repetition rate of the backwash of the hollow fiber filter 3 and the permeate / concentrate ratio in the reverse osmosis unit 4. The adjustment can be carried out either manually or using feedback algorithms using conductometric, photometric, turbodimetric, and other sensors.

The use of a liquid purification unit allows extending the life of membrane components due to the presence of an electrocoagulation unit, in which the removal of dissolved high molecular weight organic substances takes place, and the developed method for efficient backwashing of a hollow fiber filter in series with a liquid and then with a mixture of liquid and air.

An additional result is the possibility of realizing the assembly of the system in the form of an installation with small dimensions and mass, up to several kilograms, and high specific productivity (up to 1 l / min per 1, 4 kg of installation weight), due to the small size and high speed of the electrocoagulation unit 2.

The liquid purification installation can be made of various modifications, including the inclusion of additional blocks (both after the hollow fiber filter and after the reverse osmosis block), such as photocatalytic, sorption, ion exchange, as well as modules and cartridges filled with special resins (for example, antibacterial), ultraviolet sources, and electrooxidation units.

Depending on the modification of the installation, it is possible to use both a filtration filter and a hollow fiber filter microfiltration membranes, and instead of reverse osmosis - ultrafiltration membranes. Therefore, the method of washing a hollow fiber filter can be applicable not only in the inventive installation for cleaning liquids, but also in installations including various filtration units, necessarily containing a hollow fiber filter.

Claims

CLAIM

1. Installation for cleaning liquid, containing means for supplying the liquid to be cleaned, a hollow fiber filter with backwashing liquid, a reverse osmosis unit, a storage tank with upper and lower nozzles and a means for removing purified liquid, characterized in that it is equipped with an electrocoagulation unit, the input of which is connected to the output of the means for supplying the liquid being cleaned, and the outlet with the inlet of the hollow fiber filter, a check valve for supplying air from the atmosphere to the storage tank during pumping of the liquid from the storage containers, and the storage tank is configured to create a vacuum in it to supply air from the atmosphere and to reverse wash the hollow fiber filter in series with a liquid, and then with a mixture of liquid and air coming from it.

2. Installation for cleaning liquid according to claim 1, characterized in that the non-return valve for supplying air from the atmosphere to the storage tank is mounted on a pipeline connected to the upper pipe of the storage tank.

3. Installation for cleaning liquid according to claim 1, characterized in that the check valve for supplying air from the atmosphere to the storage tank is installed in the upper part of the storage tank.

4. Installation for cleaning liquid according to claim 1, characterized in that the upper pipe of the storage tank is made in-depth inside it, with the lower section of the upper pipe being at least 50 mm higher than the lower pipe.

5. Installation for cleaning liquid according to claim 1, characterized in that the lower pipe is designed to exit the fluid to the reverse osmosis unit with the possibility of creating a vacuum in the storage tank.

6. Installation for cleaning liquid according to claim 1, characterized in that the upper nozzle is designed to enter the liquid into the storage capacity, liquid outlet, and then a mixture of liquid and air on a hollow fiber filter.

7. A method of washing a hollow fiber filter, including backwashing with a liquid coming from a storage tank, characterized in that the backwashing is carried out sequentially with a liquid and then under pressure with a mixture of liquid and air coming from a storage tank.

8. The method of washing the hollow fiber filter according to claim 7, characterized in that the air is supplied from the atmosphere to the storage tank while pumping liquid from the storage tank using a non-return valve.

9. The method of washing the hollow fiber filter according to claim 7, characterized in that the backwashing is carried out at a speed of less than 5 seconds.

10. The method of washing the hollow fiber filter according to claim 9, characterized in that the backwashing is carried out, preferably at a rate of less than 3 seconds.

11. The method of washing the hollow fiber filter according to claim 7, characterized in that the backwashing at the initial stage is carried out with liquid under pressure created by an air cushion in the upper part of the storage tank.

12. The use of the method of washing a hollow fiber filter according to any one of paragraphs. 7-11 in installations for cleaning liquid.

13. The use of the method of washing a hollow fiber filter according to any one of paragraphs. 7-11 in combination with a method of purifying a liquid.