WO2010086695A1 - Composition cosmétique sous forme de mousse - Google Patents

Composition cosmétique sous forme de mousse Download PDF

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Publication number
WO2010086695A1
WO2010086695A1 PCT/IB2009/050368 IB2009050368W WO2010086695A1 WO 2010086695 A1 WO2010086695 A1 WO 2010086695A1 IB 2009050368 W IB2009050368 W IB 2009050368W WO 2010086695 A1 WO2010086695 A1 WO 2010086695A1
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WO
WIPO (PCT)
Prior art keywords
weight
composition
anyone
compartment
foam
Prior art date
Application number
PCT/IB2009/050368
Other languages
English (en)
Inventor
Takehiko Kasai
Takahiro Suzuki
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=41202518&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2010086695(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by L'oreal filed Critical L'oreal
Priority to EP09786298.1A priority Critical patent/EP2381915B1/fr
Priority to CN2009801558775A priority patent/CN102300548A/zh
Priority to US13/144,004 priority patent/US10258547B2/en
Priority to ES09786298.1T priority patent/ES2576691T3/es
Priority to BRPI0924203A priority patent/BRPI0924203A2/pt
Priority to JP2011546975A priority patent/JP6009766B2/ja
Priority to PCT/IB2009/050368 priority patent/WO2010086695A1/fr
Publication of WO2010086695A1 publication Critical patent/WO2010086695A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging

Definitions

  • the present invention relates to a composition in the foam form for caring for and/or making up keratin materials.
  • composition according to the invention may be, for example, a composition for making up or caring for keratinous substances, in particular the skin, lips, eyelashes, eyebrows or nails.
  • the composition may or may not be coloured.
  • the make-up composition may be selected from, e.g., a foundation, a face powder, an eye shadow, a concealer, a blusher, a lipstick, a lip balm, a lip gloss, a mascara, an eyeliner and a product for making up the body or colouring the skin. It may especially be a foundation base.
  • the care composition may be a product for caring for the eyelashes, lips or skin of the body and face, in particular an antisun product.
  • Cosmetic compositions of this type are generally in the form of temporary foam produced just before use. These are either aerosol products distributed from a pressurized container, with the aid of a propellant and thus forming a foam, or compositions distributed from a container using a mechanical pump connected to a distribution head.
  • compositions in the foam form currently available are not always entirely satisfactory, firstly in terms of quality of the foam and secondly in terms of durability of the foam.
  • the foam aspect generally generated at the time of distribution very rapidly degrades. More specifically, the mousse very quickly has a tendency to collapse.
  • compositions in the foam form comprising at least one aqueous phase and talc and exhibiting a satisfying foam stability over time.
  • compositions in the foam form comprising at least one aqueous phase and at least 1% by weight of at least one mineral filler relative to its total weight and exhibiting a satisfying foam stability over time.
  • the present invention is directed towards proposing a composition in the foam form of improved density, especially in terms of stability, satisfying parts or all of these needs.
  • UV filter substances may be used for the foam-boosting of self-foaming, foam-like, after foaming or foamable cosmetic and dermatological preparations which comprise at least one polar oil component.
  • This document does not teach however that such UV sunscreen ingredients may also be useful in compositions in the foam form comprising especially a mineral filler, and in particular talc.
  • the present invention relates to a cosmetic composition in the foam form comprising, in a physiologically acceptable medium, at least one aqueous phase, talc and one UV sunscreen ingredient.
  • the present invention relates to a cosmetic composition in the foam form comprising, in a physiologically acceptable medium, at least one aqueous phase, at least 1% by weight of at least one mineral filler relative to its total weight, and one UV sunscreen ingredient.
  • the compositions in the foam form according to the present invention exhibit good stability over time, in particular in terms of homogeneity, foam stability, and appearance of the product.
  • composition in the foam form according to the invention may be obtained from a base composition packaged in a product.
  • This product may contain, besides the base composition, a propellant.
  • the present invention further relates to a product comprising: a. a container defining at least one compartment ; b. a composition contained in said compartment, said composition comprising, in a physiologically acceptable medium, at least one aqueous phase, talc and one UV sunscreen ingredient ; c. a propellant to pressurize said composition inside said compartment ; and d. a dispensing head having an opening to be selectively put in fluid communication with said compartment in order to deliver said pressurized composition in the form of a foam.
  • the present invention also further relates to a product comprising: a. a container defining at least one compartment ; b. a composition contained in said compartment, said composition comprising, in a physiologically acceptable medium, at least one aqueous phase, at least 1% by weight of at least one mineral filler relative to its total weight and one UV sunscreen ingredient ; c. a propellant to pressurize said composition inside said compartment ; and d. a dispensing head having an opening to be selectively put in fluid communication with said compartment in order to deliver said pressurized composition in the form of a foam.
  • the present invention relates to a kit comprising one of the product defined above and an applicator.
  • composition(s) means the cosmetic composition and/or the base composition.
  • a physiologically acceptable medium is a medium that is compatible with the skin, the eyes and/or the hair and is thus useful for formulating a cosmetic and/or dermatological composition.
  • composition in (the) foam form and the term “composition in the form of a foam” mean the same thing and are understood to mean a composition comprising a gas phase (for example air) in the form of bubbles; another equivalent term is "composition expanded in volume”.
  • the composition in the form of a foam according to the invention is advantageous in several respects. It is easy to handle on the hand. It has a light, fresh feeling, creamy and fondant mousse texture when applied to the skin. It spreads easily and thinly on the skin and gives uniform makeup of the skin without leaving visible traces. Furthermore, after application to the skin, the makeup or the deposit obtained has a powdery, velvety finish and is comfortable to wear, without any effect of drying out or tautness; the made-up or treated skin is pleasantly soft.
  • the composition in the foam form preferably exhibits a light texture and is easy to withdraw and to spread over keratinous substances.
  • composition according to the present invention may comprise talc.
  • composition according to the present invention may comprise at least 1% by weight, for example at least 2% by weight, for example at least 3% by weight, for example at least 5% by weight of at least one mineral filler relative to its total weight.
  • mineral filler does not cover Ti ⁇ 2 and ZnO which are both considered as pigments.
  • Said mineral filler may for example be selected in the group consisting of talc, silica, mica, kaolin, precipitated calcium carbonate, magnesium carbonate, magnesium hydrogen carbonate, hydroxyapatite, and mixtures thereof.
  • talc in particular as described above.
  • Talc may be present in an amount ranging from 1 to 25% by weight, for example from 1 to 10% by weight, preferably from 2 to 8% by weight relative to the total weight of the composition.
  • composition according to the present invention may further comprise at least silica. It may be for example surface-treated silica, such as especially silicone treated silica, such as methicone-treated silica.
  • silica sold under the tradename SI-SB 700 ® by the company MIYOSHI which is sphere-shaped and whose size is around 5.1 ⁇ m.
  • Silica may be present in an amount ranging from 0.1 to 10% by weight, for example from 1 to 8% by weight, preferably from 1 to 3% by weight relative to the total weight of the composition.
  • composition according to the invention may especially comprise a mineral filler, especially talc and/or silica, having a particle size ranging from 0.1 to 100 ⁇ m, for example from 1 to 10 ⁇ m, especially from 2 to 8 ⁇ m.
  • a mineral filler especially talc and/or silica
  • the composition may include talc and silica, especially in a weight ratio [talc/silica] ranging from 0.1 to 10, for example from 0.2 to 8, for example from 0.5 to 1.5, in particular of about 1.
  • UV sunscreen ingredient ranging from 0.1 to 10, for example from 0.2 to 8, for example from 0.5 to 1.5, in particular of about 1.
  • the screening compositions in accordance with the invention comprise organic and/or inorganic UV sunscreen ingredients active in the UV-A and/or UV- B region which are hydrophilic and/or lipophilic.
  • the UV sunscreen ingredients according to the invention might have a solubility parameter ranging from 8.0 to 9.5.
  • Said UV sunscreen ingredients have a good plasticizer function.
  • the UV sunscreen agent according to the invention might have a molecular weight ranging from 150 to 500 g/mol and contain hydrophobic sites and benzene nucleus or electron resonance group binding with polar sites.
  • hydrophilic and/or lipophilic organic UV sunscreen ingredients are selected in particular from dibenzoylmethane derivatives; cinnamic derivatives; salicylic derivatives; benzophenone derivatives; ⁇ , ⁇ -diphenylacrylate derivatives; p- aminobenzoic acid (PABA) derivatives; and their mixtures.
  • the preferred UV sunscreen ingredients are selected in the group consisting of cinnamic derivatives, ⁇ , ⁇ diphenylacrylates derivatives, salicylic derivatives, and their mixtures.
  • the preferred UV sunscreen ingredients are especially selected in the group consisting of ethylhexyl methoxycinnamate, octocrylene and ethylhexyl salicylate, and their mixtures.
  • composition in accordance with the invention may comprise from 0.1% to 30% by weight, for example from 0.5 to 20% by weight, for example from 1 to 15% by weight, and for example at least 1% by weight, of UV sunscreen ingredient relative to the total weight of the composition.
  • the composition may comprise the mineral filler and at least one UV sunscreen ingredient in a weight ratio [mineral f ⁇ ller/UV sunscreen ingredient] ranging from 0.20 to 10, for example from 1 to 9.5, preferably from 3 to 9.
  • the composition may comprise talc and at least one UV sunscreen ingredient in a weight ratio [talc/UV sunscreen ingredient] ranging from 0.1 to 10, for example from 0.5 to 8, preferably from 1 to 5.
  • the composition may comprise silica and at least one UV sunscreen ingredient in a weight ratio [silica/UV sunscreen ingredient] ranging from 0.1 to 10, for example from 0.4 to 8, preferably from 1 to 5.
  • compositions in the foam form according to the invention are formed stably in the form of mousse using a base composition and air or an inert gas.
  • the air or the inert gas may represent especially from 10% to 500% and preferably from 20% to 200%, for example from 30% to 100% of the volume of the composition in the foam form.
  • This volume may be calculated by comparing the density of the base composition and of the in the foam form composition.
  • gases that allow the composition in the foam form to be obtained are in particular inert gases, for example nitrogen, carbon dioxide, nitrogen oxides, noble gases or a mixture of the said gases.
  • gases for example nitrogen, carbon dioxide, nitrogen oxides, noble gases or a mixture of the said gases.
  • an oxygen-free gas such as nitrogen or carbon dioxide.
  • the base composition serving to obtain the composition in the foam form has a composition similar to the composition in the foam form except for its higher density, insofar as it is free of air or of inert gas.
  • the amount of gas introduced into the base composition contributes towards adjusting the density of the composition in the foam form to the desired value, for example less than or equal to 0.12 g/cm 3 .
  • composition in the foam form of the invention may have for example a density of less than or equal to 0.12 g/cm 3 , for example ranging from
  • the test is performed on 50 ml of composition introduced into a 50 ml polished Plexiglas ® goblet (Vi) defining a cylindrical filling space 30 mm high having a base with a diameter of 46 mm.
  • the goblet has a bottom wall 10 mm thick and a side wall 12 mm thick.
  • the composition to be characterized and the goblet are maintained at a temperature of about 20 0 C.
  • the goblet is tared and the weight value (Mi) is recorded.
  • the composition in the foam form is then introduced into the goblet so as to occupy the total volume, while avoiding the formation of air bubbles during the filling of the goblet.
  • the assembly is left to stand for 10 seconds to allow the mousse to expand fully.
  • the top of the goblet is then skimmed before weighing (M 2 ).
  • the composition in the foam form according to the invention shows satisfactory stability, which may be calculated by measuring the volume of mousse (V 2 ) remaining in the goblet after 10 minutes according to the protocol described above for the density measurement.
  • the ratio V 2 AVi corresponds to the ratio between the volume of the composition in the foam form after 10 minutes and the volume of the composition in the foam form after 10 seconds.
  • compositions in the foam form with a ratio of greater than 0.85 and especially
  • the volume of the composition in the foam form is inversely proportional to the density of the composition in the foam form.
  • the ratio between the density of the composition in the foam form measured after 10 seconds and the density of the composition in the foam form measured after 10 minutes may be greater than 0.85 and especially greater than 0.90, for example greater than 0.95.
  • the air pause may advantageously have a number-average size ranging from 20 ⁇ m to 500 ⁇ m and preferably ranging from 100 ⁇ m to 300 ⁇ m.
  • composition according to the invention generally comprises an aqueous phase comprising water and optionally a hydrophilic organic solvent, for instance monoalcohols and polyols, in particular C2 to C4 polyols, for example ethylene glycol, diethylene glycol, butylene glycol or glycerol.
  • a hydrophilic organic solvent for instance monoalcohols and polyols, in particular C2 to C4 polyols, for example ethylene glycol, diethylene glycol, butylene glycol or glycerol.
  • the solvents are chosen as a function of their compatibility with the desired mousse texture.
  • composition according to the invention may be free of glycerol so as to avoid inducing a tacky feel.
  • the composition advantageously comprises water.
  • the composition may especially comprise from 35% to 95% or even from 40% to 85% water, especially from 55% to 80% water, for example from 45% to 75% water, relative to its total weight.
  • the composition according to the invention may also comprise seawater, especially at least 1% by weight especially from 1 to 20% by weight, for example from 5 to 15% by weight of seawater relative to the total weight.
  • the composition of the invention may comprise at least 30% by weight, for example at least 40% by weight, for example from 40 to 95% by weight, for example from 40 to 85% by weight, for example from 45 to 80% by weight, for example from 45 to 75% by weight of water and/or water-soluble solvent(s) relative to its total weight. Additional Fillers
  • composition according to the invention may also comprise at least one additional filler, different from talc and silica.
  • fillers should be understood as meaning colourless or white, mineral or synthetic particles of any shape, which are insoluble in the medium of the compositions irrespective of the temperature at which the composition is manufactured.
  • the additional fillers may be mineral or organic of any shape, platelet- shaped, spherical or oblong, irrespective of the crystallographic form (for example lamellar, cubic, hexagonal, orthorhombic, etc.). Mention may be made of mica, kaolin, polyamide (Nylon ® ) powders, poly- ⁇ -alanine powders, polyethylene powders, tetrafluoroethylene polymer (Teflon ® ) powders, lauroyllysine, starch, boron nitride, , hollow polymer microspheres such as those of polyvinylidene chloride/acrylonitrile, for instance Expancel ® (Nobel Industrie), or of acrylic acid copolymers, silicone resin powders, especially silsesquioxane powders (silicone resin powders described especially in patent
  • EP 293 795 for example Tospearls ® from Toshiba
  • elastomeric polyorganosiloxane particles precipitated calcium carbonate, magnesium carbonate, magnesium hydrogen carbonate, hydroxyapatite, hollow silica microspheres, glass or ceramic microcapsules, and metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms and preferably from 12 to 18 carbon atoms, for example zinc stearate, magnesium stearate, lithium stearate, zinc laurate or magnesium myristate; and mixtures thereof.
  • the additional fillers are chosen from low-density fillers.
  • low-density means, for example, fillers with a density of less than
  • compositions comprising fillers of excessively high density form mousses of higher porosity.
  • compositions may comprise low-density additional fillers in a content ranging from 0.5% to 30% by weight, preferably ranging from 1% to 15% by weight and preferentially ranging from 1% to 10% by weight relative to the total weight of the composition.
  • compositions may also comprise additional fillers with a low refractive index and/or that substantially do not absorb the water and/or the oils of the composition.
  • a low refractive index is, for example, a refractive index of less than 1.7, for example less than 1.6.
  • a filler that substantially does not absorb the water and/or the oils of the composition may advantageously contribute towards giving the composition a transparent appearance.
  • the additional fillers with a low refractive index and/or that substantially do not absorb the water and/or the oils of the composition may be present in the composition in a content ranging from 0.1% to 30% by weight, preferably ranging from 1% to 15% by weight and preferentially ranging from 1% to 10% by weight relative to the total weight of the composition.
  • the additional fillers may be present in the compositions in a content ranging from 0.1% to 35% by weight, preferably ranging from 0.5% to 30% by weight and preferentially ranging from 1% to 25% by weight relative to the total weight of the composition.
  • the fillers under consideration according to the invention may be surface-treated so as to improve their dispersibility within the composition in the foam form.
  • Such treatments form part of the knowledge of a person skilled in the art and certain fillers thus treated are also commercially available.
  • compositions according to the invention may contain additional fillers with a high density or refractive index or that absorb the water and/or the oil of the composition, but in an amount adjusted so as to obtain a mousse having a satisfactory density, and in particular a low porosity and satisfactory transparency.
  • composition of the invention may also contain at least one anionic surfactant.
  • the salts of sulfates and of ether sulfates the sodium and triethanolamine salts are preferentially chosen.
  • the foaming anionic surfactant that may thus be used is sodium lauryl ether sulfate, and especially the product sold under the name Texapon by the company Henkel.
  • the composition of the invention contains an amount of anionic surfactant ranging from 0.5% to 50% by weight and preferably from 2% to 30% by weight relative to the total weight of the composition.
  • the composition in accordance with the invention may comprise less than 5% by weight, preferably less than 3% by weight, for example less than 1% by weight of anionic surfactant relative to its total weight.
  • the composition according to the invention may also contain an emulsifier that may be chosen from any emulsif ⁇ er conventionally used for O/W emulsions.
  • emulsif ⁇ ers examples include:
  • nonionic surfactants with an HLB of greater than or equal to 9, such as oxyethylenated fatty acid esters of glycerol; oxyethylenated fatty acid esters of sorbitan; oxyethylenated fatty acid derivatives; fatty acid esters of a sugar and especially fatty esters of sucrose such as sucrose stearate, for instance the product sold under the name Tegosoft PSE 141 G by the company Goldschmidt; alkyl polyglucoside ethers, and mixtures thereof;
  • composition according to the invention may comprise, for example, from 0.5% to 50%, preferably from 2% to 15% and better still from 4% to 10% by weight of emulsif ⁇ er(s) relative to the total weight of the composition.
  • the composition in accordance with the invention may comprise less than 5% by weight, preferably less than 3% by weight, for example less than 1% by weight of emulsifier(s) relative to its total weight.
  • the composition in accordance with the invention may comprise less than 5% by weight, for instance less than 2% by weight, especially less than 1% by weight, of hydrocarbon based emulsifier and/or co-emulsif ⁇ er relative to its total weight.
  • composition according to the invention generally comprises a solid or liquid fatty substance and especially a liquid fatty substance.
  • composition according to the invention may thus comprise an oily phase comprising at least one oil that may be chosen from volatile oils and nonvolatile oils, and mixtures thereof.
  • the composition comprises at least one volatile oil and at least one non-volatile oil.
  • the composition according to the invention may comprise at least one volatile oil.
  • volatile oil means any oil that is capable of evaporating on contact with the skin, at room temperature and atmospheric pressure.
  • the volatile oils of the invention are volatile cosmetic oils that are liquid at room temperature, with a non-zero vapour pressure at room temperature and atmospheric pressure, ranging in particular from 0.13 Pa to 40 000 Pa (0.001 to 300 mmHg) and preferably ranging from 1.3 Pa to 1300 Pa
  • the volatile oil may be chosen from volatile hydrocarbon-based oils, volatile silicone oils and volatile fluoro oils, and mixtures thereof.
  • hydrocarbon-based oil means an oil mainly containing hydrogen and carbon atoms and possibly oxygen, nitrogen, sulfur and/or phosphorus atoms.
  • the volatile hydrocarbon-based oils may be chosen from hydrocarbon- based oils containing from 8 to 16 carbon atoms, and especially branched Cg-Ci ⁇ alkanes, for instance Cg-Ci ⁇ isoalkanes of petroleum origin (also known as isoparaffins), for instance isododecane (also known as 2,2,4,4,6-pentamethyl- heptane), isodecane and isohexadecane, for example the oils sold under the trade names Isopar ® and Permethyl ® .
  • Cg-Ci ⁇ alkanes for instance Cg-Ci ⁇ isoalkanes of petroleum origin (also known as isoparaffins), for instance isododecane (also known as 2,2,4,4,6-pentamethyl- heptane), isodecane and isohexadecane, for example the oils sold under the trade names Isopar ® and Permethyl ® .
  • Volatile oils that may also be used include volatile silicones, for instance volatile linear or cyclic silicone oils, especially those with a viscosity ⁇ 5 centistokes (5 x 10 ⁇ 6 m 2 /s) and especially containing from 2 to 10 silicon atoms and preferably from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms.
  • volatile silicones for instance volatile linear or cyclic silicone oils, especially those with a viscosity ⁇ 5 centistokes (5 x 10 ⁇ 6 m 2 /s) and especially containing from 2 to 10 silicon atoms and preferably from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms.
  • volatile silicone oils that may be used in the invention, mention may be made especially of octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, dodecamethyl cyclo- hexasiloxane, heptamethyl hexyltrisiloxane, heptamethyloctyl trisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, decamethyl tetrasiloxane and dodecamethyl pentasiloxane, and mixtures thereof.
  • Volatile oils that may also be used are volatile fluoro oils: mention may be made of nonafluoroethoxybutane, nonafluoromethoxybutane, decafluoropentane, tetradecafluorohexane and dodecafluoropentane, and mixtures thereof.
  • composition according to the invention may comprise at least one non-volatile oil.
  • non-volatile oil means an oil that remains on the skin at room temperature and atmospheric pressure for at least several hours and that especially has a vapour pressure of less than 0.13 Pa (0.01 mmHg).
  • non-volatile oils may be hydrocarbon-based oils especially of animal or plant origin, or silicone oils, or mixtures thereof.
  • hydrocarbon-based oil means an oil mainly containing hydrogen and carbon atoms and possibly oxygen, nitrogen, sulfur and/or phosphorus atoms.
  • the non- volatile oils may be chosen especially from non- volatile hydrocarbon-based oils, which may be fluorinated, and/or non-volatile silicone oils.
  • Non-volatile hydrocarbon-based oils that may especially be mentioned include:
  • oils of animal origin such as triglycerides consisting of fatty acid esters of glycerol, the fatty acids of which may have varied chain lengths from C 4 to C24, these chains possibly being linear or branched, and saturated or unsaturated; these oils are especially heptanoic or octanoic acid triglycerides, or alternatively wheatgerm oil, sunflower oil, grapeseed oil, sesame seed oil, corn oil, apricot oil, castor oil, shea oil, avocado oil, olive oil, soybean oil, sweet almond oil, palm oil, rapeseed oil, cottonseed oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, poppyseed oil, pumpkin oil, sesame seed oil, marrow oil, rapeseed oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil,
  • triglycerides consisting of fatty acid esters of
  • hydrocarbons of mineral or synthetic origin such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam ® , squalane and liquid paraffins, and mixtures thereof;
  • oils of formula R4COOR2 in which Ri represents a linear or branched fatty acid residue containing from 1 to 40 carbon atoms and R2 represents a hydrocarbon-based chain, which is especially branched, containing from 1 to 40 carbon atoms, on condition that Ri + R 2 > 10, for instance purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, Ci2to Cu alkyl benzoates, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, isostearyl isostearate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecyl myristate, or alcohol or polyalcohol heptanoates, octanoates, decanoates or ric
  • - fatty alcohols that are liquid at room temperature with a branched and/or unsaturated carbon-based chain containing from 12 to 26 carbon atoms, for instance octyldodecanol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2-butyloctanol or 2-undecylpentadecanol, and
  • - higher fatty acids such as oleic acid, linoleic acid or linolenic acid, and mixtures thereof.
  • the non-volatile silicone oils that may be used in the composition according to the invention may be non- volatile polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising alkyl or alkoxy groups, which are pendent and/or at the end of a silicone chain, these groups each contain from 2 to 24 carbon atoms, phenyl silicones, for instance phenyl trimethicones, phenyl dimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl dimethicones and diphenyl- methyldiphenyltrisiloxanes, and mixtures thereof.
  • PDMS polydimethylsiloxanes
  • polydimethylsiloxanes comprising alkyl or alkoxy groups, which are pendent and/or at the end of a silicone chain, these groups each contain from 2 to 24 carbon atoms
  • phenyl silicones for instance phenyl trimethicones,
  • composition according to the invention advantageously comprises from 1% to 40% by weight, preferably from 2% to 30% by weight and better still from 5% to 20% by weight of oily phase relative to its total weight.
  • the other fatty substances that may be present in the oily phase may be, for example, fatty acids, fatty alcohols such as cetyl alcohol, and waxes.
  • the fatty phase may also comprise compounds that are solid at room temperature (20 0 C) such as waxes, these components possibly improving the stability of the composition in the foam form. These compounds are added either in molten form or in solid form to the oily phase, heated to a temperature above the melting point of the solid.
  • These compounds may be waxes or compounds similar to waxes, for example natural renewable waxes (insect waxes, animal waxes and plant waxes), fossil waxes (petroleum wax, lignite wax, peat wax or ozokerite), synthetic waxes (Fischer-Tropsch waxes, polyethylene waxes or amide waxes), high-melting paraffins, esters, fats, long-chain carboxylic acids or long-chain alcohols of Cio to C22, each of these waxes having a melting or solidification point of above room temperature (20 0 C).
  • natural renewable waxes insect waxes, animal waxes and plant waxes
  • fossil waxes fossil waxes
  • lignite wax lignite wax, peat wax or ozokerite
  • synthetic waxes Fischer-Tropsch waxes, polyethylene waxes or amide waxes
  • high-melting paraffins esters
  • fats long-chain carboxylic acids or long-chain
  • the composition in accordance with the invention may comprise less than 5% by weight of fatty alcohols, preferably less than 3% by weight, for example less than 1% by weight, even less than 0,5% by weight relative to its total weight.
  • composition according to the invention may comprise at least one dyestuff chosen especially from pigments, nacres, liposoluble dyes and water- soluble dyes, and mixtures thereof.
  • pigments should be understood as meaning white or coloured, mineral or organic particles of any shape, which are insoluble in the physiological medium and are intended to colour the composition.
  • nacres should be understood as meaning iridescent particles of any shape, especially produced by certain molluscs in their shell or else synthesized.
  • dyes should be understood as meaning generally organic compounds that are soluble in water or in fatty substances such as oils.
  • the pigments may be white or coloured, and mineral and/or organic.
  • mineral pigments that may be mentioned are titanium dioxides, optionally surface-treated, zirconium oxide and cerium oxide, and also zinc oxide, iron oxide (black, yellow or red) or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue and metal powders such as aluminium powder or copper powder.
  • micronized titanium dioxide powder surface-treated with a silica/aluminium hydroxide/alginic acid mixture sold under the name MT- 100 AQ .
  • organic pigments that may be mentioned are carbon black, pigments of D&C type and lakes based on cochineal carmine or on barium, strontium, calcium or aluminium.
  • the nacreous pigments may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, coloured nacreous pigments such as titanium mica coated with iron oxides, titanium mica coated especially with ferric blue or with chromium oxide, titanium mica coated with an organic pigment of the abovementioned type, and also nacreous pigments based on bismuth oxy chloride.
  • white nacreous pigments such as mica coated with titanium or with bismuth oxychloride
  • coloured nacreous pigments such as titanium mica coated with iron oxides, titanium mica coated especially with ferric blue or with chromium oxide, titanium mica coated with an organic pigment of the abovementioned type, and also nacreous pigments based on bismuth oxy chloride.
  • the liposoluble dyes are, for example, Sudan red, D&C Red No 17,
  • the dyestuffs may be present in a content ranging from 0.1% to 30% by weight, preferably ranging from 0.1% to 20% by weight, preferably ranging from 0.5% to 15% by weight, preferentially ranging from 1% to 15% by weight and more preferentially ranging from 5% to 15% by weight relative to the total weight of the composition.
  • the composition of the invention may also contain adjuvants that are common in cosmetics, such as humectants, preserving agents, antioxidants, complexing agents, solvents, fragrances, bactericides, odour absorbers, vitamins, moisturizers, self-tanning compounds and antiwrinkle active agents.
  • adjuvants that are common in cosmetics, such as humectants, preserving agents, antioxidants, complexing agents, solvents, fragrances, bactericides, odour absorbers, vitamins, moisturizers, self-tanning compounds and antiwrinkle active agents.
  • the amounts of these various adjuvants are those conventionally used in the field under consideration, for example from 0.01% to 20% of the total weight of the composition.
  • these adjuvants may be introduced into the fatty phase, into the aqueous phase and/or into lipid vesicles.
  • the composition may comprise more than 1% by weight, for example from 1 to 35% by weight, for example at least 5% by weight for example at least 10% by weight, for example at least 15% by weight, for example at least 20% by weight of particulate material relative to its total weight.
  • composition in the foam form according to the invention finds its application in a wide variety of treatments, especially cosmetic treatments, of the skin, the lips and the hair, including the scalp, especially for treating, protecting or caring for the skin, the lips and/or the hair, and/or for making up the skin and/or the lips. It may also be intended for treating dry skin and/or dry lips.
  • a subject of the invention is also the cosmetic use of the composition in the foam form as defined above for treating, protecting or caring for the skin, the lips and/or the hair, and/or for making up the skin and/or the lips, in particular for preparing a foundation or a foundation base.
  • a subject of the invention is also the use of a product as defined above to form a composition in the foam form serving as a base for the preparation of a makeup of foundation type.
  • compositions in accordance with the invention mention may be made more particularly of those combining at least talc, silica, and a UV sunscreen ingredient chosen among ethylhexyl methoxycinnamate, octocrylene and ethyl hexyl salicylate.
  • Said composition may further comprise calcium carbonate and micronized titanium dioxide powder surface-treated with a silica/aluminium hydroxide/alginic acid mixture.
  • composition before expansion in volume can be provided in the suspension, dispersion, solution or gel form.
  • the composition in the foam form may be obtained from a base composition in a distributor.
  • This distributor may be an aerosol containing, besides the base composition, a propellant.
  • This propellant may represent less than 20% by weight of the base composition and in particular may represent from 1% to 10% by weight, for example from 2 to 8% by weight, for example at least 5% by weight of the total weight of the base composition.
  • the propellant that may be used may be chosen from carbon dioxide, nitrogen, nitrous oxide and volatile hydrocarbons such as butane, isobutane, propane, ethane, pentane, isododecane or isohexadecane, and mixtures thereof.
  • It may especially be a propane/butane mixture (Liquified Petroleum Gas or LPG) in a weight ratio [propane/butane] ranging from 0.1 to 1, especially of 0.31.
  • propane/butane mixture Liquified Petroleum Gas or LPG
  • LPG Liquified Petroleum Gas
  • the pressure of the propellant, and for example of said propane/butane mixture, in the aerosol may range from 0.20 to 0.50 MPa, for example from 0.20 to 0.40, and especially from 0.25 to 0.35 MPa.
  • compositions employed in the invention can be prepared by processes for mixing, stirring or dispersing compressed gases, such as air, chlorofluorocarbon-based compounds, nitrogen, carbon dioxide, oxygen or helium, a process for mixing and stirring in the presence of a foaming agent, such as a surfactant.
  • compressed gases such as air, chlorofluorocarbon-based compounds, nitrogen, carbon dioxide, oxygen or helium
  • a foaming agent such as a surfactant
  • the composition is prepared by mixing the ingredients with stirring, generally under hot conditions, and by then expanding in volume under the action of a gas, it being possible for the gas to be introduced during the stage of cooling the composition or after preparation of the composition, for example using a device for expanding in volume of Mondomix type, a beater of Kenwood type, a scraped-surface exchanger or a dynamic mixer (of IMT type, for example).
  • the gas is preferably air or nitrogen.
  • the composition according to the invention can be packaged in a container delimiting at least one compartment which comprises the composition, the container being closed by a closure part.
  • the container can be equipped with a means for the dispensing of the product.
  • the container can be equipped with a pump.
  • the container can be a pot.
  • the container can be at least partly made of thermoplastic. Mention may be made, as examples of thermoplastics, of polypropylene or polyethylene. Alternatively, the container is made of nonthermoplastic material, in particular of glass or metal (or alloy).
  • the composition can be applied, e.g., by finger or using an applicator.
  • the container is preferably used in combination with an applicator comprising at least one application component configured in order to apply the composition to keratinous substances.
  • the applicator comprises an application nozzle.
  • Powder phase is mixed by powder mixer
  • compositions in the foam form have a density of less than 0.12 g/cm 3 (even of less than 0.10 g/cm 3 ), this density being measured at a temperature of about 20 0 C and at atmospheric pressure.
  • volume ratio corresponding to the ratio between the volume of the composition in the foam form after 10 minutes and the volume of the composition in the foam form after 10 seconds.
  • compositions in the foam form further comprising a UV sunscreen ingredient in accordance with the invention exhibit a satisfactory stability over time.
  • compositions in the foam form in accordance with the instant invention exhibit, at the same time, an improved density and foam stability over time.
  • EXAMPLE 2 The following base compositions were prepared (the ingredients are named by their INCI name and their content is expressed in weight %).
  • compositions in accordance with the invention exhibit a satisfactory stability over time.

Abstract

La présente invention porte sur une composition cosmétique sous forme de mousse comprenant, dans un milieu physiologiquement acceptable, au moins une phase aqueuse, du talc et un ingrédient d'écran solaire anti-UV. Elle porte également sur une composition cosmétique sous forme de mousse comprenant, dans un milieu physiologiquement acceptable, au moins une phase aqueuse, au moins 1 % en poids d'au moins une charge minérale par rapport à son poids total, et un ingrédient d'écran solaire anti-UV.
PCT/IB2009/050368 2009-01-29 2009-01-29 Composition cosmétique sous forme de mousse WO2010086695A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP09786298.1A EP2381915B1 (fr) 2009-01-29 2009-01-29 Composition cosmétique sous forme de mousse
CN2009801558775A CN102300548A (zh) 2009-01-29 2009-01-29 处于泡沫形式的化妆品组合物
US13/144,004 US10258547B2 (en) 2009-01-29 2009-01-29 Cosmetic foam compositions comprising UV sunscreens and mineral fillers
ES09786298.1T ES2576691T3 (es) 2009-01-29 2009-01-29 Composición cosmética en forma de espuma
BRPI0924203A BRPI0924203A2 (pt) 2009-01-29 2009-01-29 composição cosmética em forma de espuma, produto, kit, e, processo para cuidar e/ou maquiar o corpo.
JP2011546975A JP6009766B2 (ja) 2009-01-29 2009-01-29 泡状の化粧品組成物
PCT/IB2009/050368 WO2010086695A1 (fr) 2009-01-29 2009-01-29 Composition cosmétique sous forme de mousse

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2009/050368 WO2010086695A1 (fr) 2009-01-29 2009-01-29 Composition cosmétique sous forme de mousse

Publications (1)

Publication Number Publication Date
WO2010086695A1 true WO2010086695A1 (fr) 2010-08-05

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PCT/IB2009/050368 WO2010086695A1 (fr) 2009-01-29 2009-01-29 Composition cosmétique sous forme de mousse

Country Status (7)

Country Link
US (1) US10258547B2 (fr)
EP (1) EP2381915B1 (fr)
JP (1) JP6009766B2 (fr)
CN (1) CN102300548A (fr)
BR (1) BRPI0924203A2 (fr)
ES (1) ES2576691T3 (fr)
WO (1) WO2010086695A1 (fr)

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WO2012160169A1 (fr) 2011-05-25 2012-11-29 L'oreal Composition cosmétique colorée expansée par aérosol
WO2013119989A1 (fr) * 2012-02-09 2013-08-15 The Dial Corporation Crème hydratante et lubrifiante pour la peau, et procédé de fabrication et d'utilisation de celle-ci
CN112294699A (zh) * 2020-11-04 2021-02-02 钟达金 一种低刺激性及泡沫丰富的沐浴露及其制备方法

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FR3028753B1 (fr) * 2014-11-24 2018-01-05 L'oreal Gel aqueux ou hydroalcoolique de phyllosilicates synthetiques a titre d'agent viscosant, matifiant et/ou homogeneisant d'application
WO2016157995A1 (fr) * 2015-03-30 2016-10-06 株式会社マンダム Substance cosmétique moussante
JP2015166358A (ja) * 2015-04-22 2015-09-24 ロレアルＬ′Ｏｒｅａｌ 泡状の化粧品組成物
BR112018073097B1 (pt) 2016-05-11 2022-05-17 Bayer Healthcare Llc Formulação espumante, métodos para fabricar e usar a mesma, e, formulação
WO2017197196A1 (fr) 2016-05-11 2017-11-16 Bayer Healthcare Llc Formulations de gel fouetté
MX2019013454A (es) 2017-05-11 2020-08-03 Beiersdorf Ag Formulaciones de gel.
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WO2012160169A1 (fr) 2011-05-25 2012-11-29 L'oreal Composition cosmétique colorée expansée par aérosol
WO2013119989A1 (fr) * 2012-02-09 2013-08-15 The Dial Corporation Crème hydratante et lubrifiante pour la peau, et procédé de fabrication et d'utilisation de celle-ci
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EP2381915B1 (fr) 2016-03-23
JP2012516318A (ja) 2012-07-19
JP6009766B2 (ja) 2016-10-19
EP2381915A1 (fr) 2011-11-02
ES2576691T3 (es) 2016-07-08
CN102300548A (zh) 2011-12-28
US10258547B2 (en) 2019-04-16
US20120213712A1 (en) 2012-08-23
BRPI0924203A2 (pt) 2016-01-19

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