WO2010041453A1 - Refrigeration device - Google Patents

Refrigeration device Download PDF

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Publication number
WO2010041453A1
WO2010041453A1 PCT/JP2009/005246 JP2009005246W WO2010041453A1 WO 2010041453 A1 WO2010041453 A1 WO 2010041453A1 JP 2009005246 W JP2009005246 W JP 2009005246W WO 2010041453 A1 WO2010041453 A1 WO 2010041453A1
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WO
WIPO (PCT)
Prior art keywords
refrigerant
heat exchanger
heat
heat storage
low
Prior art date
Application number
PCT/JP2009/005246
Other languages
French (fr)
Japanese (ja)
Inventor
松岡慎也
藤吉竜介
田中修
Original Assignee
ダイキン工業株式会社
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Application filed by ダイキン工業株式会社 filed Critical ダイキン工業株式会社
Publication of WO2010041453A1 publication Critical patent/WO2010041453A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D16/00Devices using a combination of a cooling mode associated with refrigerating machinery with a cooling mode not associated with refrigerating machinery
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B1/00Compression machines, plants or systems with non-reversible cycle
    • F25B1/10Compression machines, plants or systems with non-reversible cycle with multi-stage compression
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00Gas cycle refrigeration machines
    • F25B2309/06Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00Gas cycle refrigeration machines
    • F25B2309/06Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • F25B2309/061Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/04Refrigeration circuit bypassing means
    • F25B2400/0401Refrigeration circuit bypassing means for the compressor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/07Details of compressors or related parts
    • F25B2400/075Details of compressors or related parts with parallel compressors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/13Economisers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/24Storage receiver heat

Definitions

  • the present invention relates to a refrigeration apparatus including a refrigerant circuit that performs a supercritical refrigeration cycle.
  • FIG. 26 is a diagram showing a supercritical refrigeration cycle in a conventional refrigeration apparatus on a Ph (pressure-enthalpy) diagram of carbon dioxide.
  • a refrigerant circuit of a conventional refrigeration apparatus is configured by a closed circuit in which a compression mechanism, a heat source side heat exchanger, an expansion valve, and a use side heat exchanger are connected in order.
  • the heat source side heat exchanger serves as a radiator
  • the use side heat exchanger serves as an evaporator.
  • each of the heat source side heat exchanger and the use side heat exchanger is constituted by an air heat exchanger.
  • the high-pressure refrigerant compressed to the critical pressure (point e in FIG. 26) or higher by the compression mechanism is discharged from the compression mechanism.
  • the high-pressure refrigerant discharged from the compression mechanism flows into the heat source side heat exchanger (point b in FIG. 26).
  • the high-pressure refrigerant flowing into the heat source side heat exchanger flows out of the heat source side heat exchanger after radiating heat to the outside air (point c in FIG. 26).
  • the high-pressure refrigerant that has flowed out of the heat-source-side heat exchanger is reduced in pressure by the expansion valve to become low-pressure refrigerant (point d in FIG. 26), and flows into the use-side heat exchanger.
  • the low-pressure refrigerant that has flowed into the use side heat exchanger absorbs heat from the air in the use space and evaporates, and then flows out of the use side heat exchanger.
  • the low-pressure refrigerant that has flowed out of the use-side heat exchanger is sucked into the compression mechanism (point a in FIG. 26), compressed to a critical pressure or higher, and then discharged as high-pressure refrigerant again. By repeating this operation, the cooling operation of the refrigeration apparatus is performed.
  • the refrigerant outlet temperature of the heat source side heat exchanger is about 40 ° C. or so.
  • the HFC refrigerant discharged from the compressor and flowing into the heat source side heat exchanger has a temperature in the heat source side heat exchanger. Phase change occurs until the temperature drops to about 40 ° C., and latent heat is released.
  • the high pressure of the refrigeration cycle is equal to or higher than the critical pressure. Until it falls, carbon dioxide does not change phase. For this reason, carbon dioxide can only release sensible heat in the heat source side heat exchanger. Therefore, when the circulation amount of carbon dioxide and the HFC refrigerant is the same, the amount of heat released in the heat source side heat exchanger is smaller in carbon dioxide.
  • the heat exchanger in order to bring the refrigeration capacity close to the refrigeration capacity of the HFC refrigerant, the heat exchanger is increased in size and the circulation amount of the refrigerant flowing through the refrigerant circuit is increased. Need to be increased. However, even if the circulation amount of the refrigerant is increased to obtain a refrigerating capacity equivalent to that of the HFC refrigerant, the power consumption of the compressor increases due to the increase of the refrigerant circulation amount, which is not preferable. .
  • the present invention has been made in view of such a point, and an object of the present invention is to provide a refrigeration apparatus equipped with a refrigerant circuit that performs a supercritical refrigeration cycle without reducing the refrigeration capacity of the compressor without increasing the power consumption of the compression mechanism.
  • the refrigerating capacity of the refrigerating apparatus using the HFC-based refrigerant is approached.
  • the first invention is a refrigerant circuit (10) in which a compression mechanism (11), a heat source side heat exchanger (12), an expansion mechanism (15), and a use side heat exchanger (16) are connected to perform a supercritical refrigeration cycle. ) Is assumed.
  • the said freezing apparatus while storing water or ice as a thermal storage medium, it is connected to the said refrigerant circuit (10), and the thermal storage heat exchanger (14 which exchanges heat between the thermal storage medium and the refrigerant
  • the compression mechanism (11) includes a low-stage compressor (11a) and a high-stage compressor (11b), while the heat storage heat exchanger (14) includes the low-stage compressor (11a). ) And the higher stage compressor (11b).
  • the ice heat storage tank (2) is provided for the refrigeration apparatus that performs the supercritical refrigeration cycle.
  • the heat storage heat exchanger (14) of the ice heat storage tank (2) serves as a radiator. Therefore, for example, the refrigerant in the refrigerant circuit (10) performing the supercritical refrigeration cycle dissipates heat in both the heat source side heat exchanger (12) and the heat storage heat exchanger (14).
  • the compression mechanism (11) by causing the compression mechanism (11) to perform two-stage compression, it is possible to suppress the amount of power consumption compared to the case of single-stage compression, and the compressor is discharged from the low-stage compressor (11a). By cooling the refrigerant with the heat storage heat exchanger (14), the amount of power consumption can be further reduced.
  • the refrigerating capacity of the refrigeration apparatus having the compression mechanism (11) of the first invention is large. It will be. That is, the refrigerating capacity can be increased without increasing the power consumption.
  • the heat storage heat exchanger (14) is a first heat storage connected between the low-stage compressor (11a) and the high-stage compressor (11b).
  • the compression mechanism (11) by causing the compression mechanism (11) to perform the two-stage compression, the power consumption can be suppressed as compared with the case of the single-stage compression, and the low-stage compressor (11a)
  • the power consumption By cooling the refrigerant discharged from the first heat storage heat exchanger (14), the power consumption can be further suppressed.
  • the refrigerant radiated by the heat source side heat exchanger (12) can be further cooled by the second heat storage heat exchanger (19).
  • the heat source side heat exchanger (12) is composed of an air heat exchanger, as described above, the refrigerant outlet temperature of the heat source side heat exchanger (12) is approximately 40 ° C.
  • the circulation amount of carbon dioxide and the HFC refrigerant is the same, the amount of heat released in the heat source side heat exchanger (12) is smaller in carbon dioxide.
  • the refrigeration effect of the use side heat exchanger (16) in the refrigeration apparatus is smaller when carbon dioxide is used than when the HFC refrigerant is used.
  • the refrigeration effect is the difference between the so-called refrigerant outlet specific enthalpy (point a in FIG. 26) and the refrigerant inlet specific enthalpy (point d in FIG. 26) of the use side heat exchanger (16). .
  • the temperature of the refrigerant flowing out from the heat source side heat exchanger (12) can be further lowered, and the refrigeration effect can be improved.
  • the circulation amount of the refrigerant in the refrigerant circuit (10) can be reduced by the amount that the refrigeration effect is improved, and the power consumption of the compression mechanism (11) is reduced.
  • the refrigerating capacity can be increased without increasing the power consumption.
  • the refrigerant circuit (10) includes a cold heat operation using the cold heat of the ice heat storage tank (2) by using the heat storage heat exchanger (14) as a radiator,
  • the heat storage heat exchanger (14) is used as an evaporator, and an ice storage tank (2) is provided with a switching mechanism (SV) that can be switched to a heat storage operation for storing cold energy.
  • SV switching mechanism
  • the switching mechanism (SV) in the refrigerant circuit (10), it is possible to cause the refrigeration apparatus to perform a cold energy use operation and a heat storage operation.
  • the switching mechanism (SV) is switched so that the heat storage heat exchanger (14) becomes an evaporator. Then, in the heat storage heat exchanger (14), water stored in the ice heat storage tank (2) is cooled by the refrigerant in the refrigerant circuit (10), and ice is generated from the water. In this way, the cold energy of the refrigerant can be stored.
  • the switching mechanism (SV) is switched so that the heat storage heat exchanger (14) becomes a radiator. Then, the refrigerant
  • the refrigerant circuit (10) is configured to start the low-stage compressor (11a) or the high-stage compressor (11b) during the cold heat operation. It is characterized by being.
  • the refrigerant discharged from the activated compressor dissipates heat in the heat storage heat exchanger (14), and after being depressurized to a predetermined pressure by the expansion mechanism (15), evaporates in the use side heat exchanger (16). .
  • the refrigerant evaporated in the use side heat exchanger (16) is sucked into the activated compressor, is compressed, and is discharged from the compressor (11b) again.
  • the fifth invention is characterized in that, in the first invention, the refrigerant flowing through the refrigerant circuit (10) is carbon dioxide.
  • carbon dioxide is used as the refrigerant flowing through the refrigerant circuit (10).
  • this carbon dioxide is compared with the current HFC-based refrigerant, the latent heat increases and the refrigerant density increases as the saturation pressure decreases. Therefore, the capacity
  • the refrigerant in the refrigerant circuit (10) performing the supercritical refrigeration cycle can be radiated to the ice of the heat storage heat exchanger (14).
  • the refrigerant dissipates heat to ice, the temperature of the refrigerant can be greatly reduced.
  • the refrigeration capacity of the conventional refrigeration apparatus can be approached without increasing the power consumption of the compression mechanism (11).
  • the compression mechanism (11) performs two-stage compression, and the refrigerant discharged from the low-stage compressor (11a) is cooled by the heat storage heat exchanger (14). To the high-stage compressor (11b).
  • the first-stage compression mechanism (11) is more than the refrigeration apparatus having the single-stage compression mechanism (11).
  • the refrigerating capacity of the refrigerating apparatus having the compression mechanism (11) of the first invention will be large. That is, the refrigerating capacity can be increased without increasing the power consumption.
  • the refrigeration can be performed without increasing the power consumption of the compression mechanism (11).
  • the refrigeration capacity of the apparatus can be brought close to the refrigeration capacity of a conventional refrigeration apparatus.
  • the compression mechanism (11) performs two-stage compression, and the refrigerant discharged from the low-stage compressor (11a) is transferred to the first heat storage heat exchanger (14 ). If it carries out like this, refrigerating capacity can be increased, without increasing power consumption similarly to 1st invention.
  • the temperature of the refrigerant flowing out from the heat source side heat exchanger (12) can be further lowered, and the refrigeration effect can be improved.
  • the amount of refrigerant circulating in the refrigerant circuit (10) can be reduced by an amount corresponding to the improved refrigeration effect, and the power consumption of the compression mechanism (11) can be reduced.
  • the power consumption of the compression mechanism (11) can be reduced. It is possible to approach the refrigeration capacity of the conventional refrigeration apparatus without increasing it.
  • the heat storage operation is performed by using relatively inexpensive nighttime electric power, and the cold heat of the refrigerant is stored in the ice heat storage tank (2). .
  • the power consumption in the daytime can be suppressed by using the generated ice during the daytime cold energy utilization operation. That is, it is possible to make the peak power shift of the daytime power and to approach the refrigeration capacity of the conventional refrigeration apparatus without increasing the power consumption of the compression mechanism (11).
  • the low-stage compressor (11a) or the high-stage compressor (11b) is activated during the cold utilization operation. If it carries out like this, the power consumption of the said compression mechanism (11) can be reduced compared with the case where both the said low stage side compressor (11a) and the said high stage side compressor (11b) are started.
  • the capacity of the refrigeration apparatus during heat storage operation can be increased compared to the current HFC refrigerant. Can do.
  • FIG. 1 is an overall view of an air conditioning apparatus (refrigeration apparatus) according to the present invention.
  • FIG. 2 is a refrigerant circuit diagram of the air-conditioning apparatus according to Embodiment 1 of the present invention.
  • FIG. 3 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the first embodiment.
  • FIG. 4 is a refrigerant circuit diagram illustrating an operation at the time of cold energy utilization operation according to the first embodiment, FIG. 4 (A) illustrates a first cold energy utilization operation, and FIG. 4 (B) is a second cold energy utilization operation. Is shown.
  • FIG. 5 is a diagram showing a refrigeration cycle performed by the refrigerant circuit according to the first embodiment on a Ph diagram.
  • FIG. 5 is a diagram showing a refrigeration cycle performed by the refrigerant circuit according to the first embodiment on a Ph diagram.
  • FIG. 6 is a refrigerant circuit diagram of an air-conditioning apparatus according to Modification 1 of Embodiment 1.
  • FIG. 7 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the first modification of the first embodiment.
  • FIG. 8 is a refrigerant circuit diagram illustrating an operation at the time of cold utilization operation according to the first modification of the first embodiment.
  • FIG. 9 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the first modification of the first embodiment on a Ph diagram.
  • FIG. 10 is a refrigerant circuit diagram of an air-conditioning apparatus according to Modification 2 of Embodiment 1.
  • FIG. 11 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the second modification of the first embodiment.
  • FIG. 12 is a refrigerant circuit diagram illustrating an operation at the time of the cold energy use operation according to the second modification of the first embodiment.
  • FIG. 13 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the second modification of the first embodiment on a Ph diagram.
  • FIG. 14 is a refrigerant circuit diagram of the air-conditioning apparatus according to Embodiment 2 of the present invention.
  • FIG. 15 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the second embodiment.
  • FIG. 16 is a refrigerant circuit diagram illustrating an operation during a cold energy utilization operation according to the second embodiment.
  • FIG. 17 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the second embodiment on a Ph diagram.
  • FIG. 18 is a refrigerant circuit diagram of the air-conditioning apparatus according to Embodiment 3 of the present invention.
  • FIG. 19 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the third embodiment.
  • FIG. 20 is a refrigerant circuit diagram illustrating an operation at the time of the cold energy utilization operation according to the third embodiment.
  • FIG. 21 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the third embodiment on a Ph diagram.
  • FIG. 22 is a refrigerant circuit diagram of an air-conditioning apparatus according to a modification of the third embodiment.
  • FIG. 23 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to a modification of the third embodiment.
  • FIG. 24 is a refrigerant circuit diagram illustrating an operation at the time of cold utilization operation according to a modification of the third embodiment.
  • FIG. 25 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the modification of the third embodiment on a Ph diagram.
  • FIG. 26 is a diagram showing a refrigeration cycle performed by a conventional refrigerant circuit on a Ph diagram.
  • FIG. 1 is an overall view of an air conditioning apparatus (refrigeration apparatus) (1) according to a first embodiment.
  • 2 is a refrigerant circuit diagram of the air conditioner (1) according to the first embodiment,
  • FIG. 3 shows a refrigerant flow during a heat storage operation, and
  • FIG. 4 shows a refrigerant flow during a cold heat operation.
  • FIG. 5 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
  • the air conditioner (1) of Embodiment 1 includes an ice heat storage tank (2) and an outdoor unit (3) installed outdoors, and an indoor unit (4) installed indoors. And these apparatuses (2, 3, and 4) are mutually connected by connection piping, and the refrigerant circuit (10) shown in FIG. 2 is comprised.
  • the refrigerant circuit (10) is filled with carbon dioxide (hereinafter referred to as refrigerant) as a refrigerant.
  • refrigerant carbon dioxide
  • the high pressure of the refrigerant circuit (10) is set to be higher than the critical pressure of carbon dioxide.
  • the air conditioner (1) is configured such that its operation can be switched between a heat storage operation and a cold energy operation.
  • a heat storage operation For example, in the air conditioner (1), by generating ice from the water in the ice storage tank (2) using the nighttime electricity during the heat storage operation and using the generated ice during the daytime cold energy operation, Power consumption during the daytime can be reduced.
  • the heat storage operation and the cold energy utilization operation will be described later in detail.
  • the refrigerant circuit (10) includes a high stage compressor (11b), a low stage compressor (11a), an outdoor heat exchanger (heat source side heat exchanger) (12), and first and second expansion valves ( Expansion mechanism) (15b, 15c), pressure reducing valve (15a), indoor heat exchanger (use side heat exchanger) (16), supercooling heat exchanger (18), and heat storage heat exchanger (14) ing. Further, the refrigerant circuit (10) is provided with an on-off valve (switching mechanism) (SV) for switching the operation of the air conditioner (1) between the heat storage operation and the cold energy utilization operation.
  • SV switching mechanism
  • the high-stage compressor (11b) and the low-stage compressor (11a) are both configured as a so-called hermetic type and constitute a compression mechanism (11).
  • an inverter (not shown) is connected to each compressor (11a, 11b), and each compressor (11a, 11b) is configured to have a variable capacity by this inverter.
  • Both the outdoor heat exchanger (12) and the indoor heat exchanger (16) are cross fin type fin-and-tube heat exchangers.
  • An outdoor fan (not shown) is provided in the vicinity of the outdoor heat exchanger (12), and an indoor fan (not shown) is provided in the vicinity of the indoor heat exchanger (16).
  • the outdoor heat exchanger (12) is configured to exchange heat between the outdoor air sent from the outdoor fan and the refrigerant flowing through the outdoor heat exchanger (12).
  • the indoor heat exchanger (16) is configured to exchange heat between indoor air sent from the indoor fan and refrigerant flowing through the indoor heat exchanger (16).
  • the first and second expansion valves (15b, 15c) and the pressure reducing valve (15a) are both electronic expansion valves whose opening degrees can be adjusted.
  • the first to fourth on-off valves (SV1, SV2, SV3, SV4) are composed of solenoid valves whose opening degree can be set to either full open or full close.
  • the supercooling heat exchanger (18) includes a high temperature side passage and a low temperature side passage, and is configured to exchange heat between the refrigerant passing through the high temperature side passage and the refrigerant passing through the low temperature side passage.
  • the heat storage heat exchanger (14) is housed in the ice heat storage tank (2), and includes a plurality of heat transfer tubes meandering up and down.
  • the refrigerant flowing through the meandering heat transfer tube and the water or ice as the heat storage medium stored in the ice heat storage tank (2) are configured to exchange heat.
  • the end of the refrigerant pipe extending from the discharge side of the low-stage compressor (11a) is branched and connected to one end of the first and second branch pipes (20, 21).
  • the other ends of the branch pipes (20, 21) merge and are connected to the suction side of the high-stage compressor (11b).
  • the first branch pipe (20) is provided with the first on-off valve (SV1).
  • the second branch pipe (21) includes a third on-off valve (SV3), the heat storage heat exchanger (14), and a second heat exchanger in order from the low stage compressor (11a) to the high stage compressor (11b).
  • a 4 on-off valve (SV4) is provided.
  • the refrigerant pipe extending from the discharge side of the high stage compressor (11b) is connected to one end of the outdoor heat exchanger (12).
  • the refrigerant pipe extending from the other end of the outdoor heat exchanger (12) branches, and one is connected to the inlet side of the low temperature side passage of the supercooling heat exchanger (18) via the pressure reducing valve (15a), The other is connected to the inlet side of the high temperature side passage of the supercooling heat exchanger (18).
  • the refrigerant pipe extending from the outlet side of the low temperature side passage of the supercooling heat exchanger (18) is formed between the high stage compressor (11b) and the first on-off valve (SV1) in the first branch pipe (20). Communicate with each other.
  • the refrigerant pipe extending from the outlet side of the high temperature side passage of the supercooling heat exchanger (18) branches, and one of the refrigerant pipes is connected to one end of the indoor heat exchanger (16) via the first expansion valve (15b).
  • the other is connected to between the heat storage heat exchanger (14) and the fourth on-off valve (SV4) in the second branch pipe (21) via the second expansion valve (15c).
  • the second branch pipe (21) communicates with the third on-off valve (SV3) and the heat storage heat exchanger (14).
  • the air conditioner (1) is configured to be able to switch between a heat storage operation and a cold energy utilization operation.
  • ⁇ Heat storage operation> In the heat storage operation, the low-stage compressor (11a) and the high-stage compressor (11b) are started by nighttime power, while the on-off valve (SV) is switched to store the heat storage heat exchanger (14). To the evaporator. And the cold of a refrigerant
  • the opening degree of the first expansion valve (15b) is fully closed, and the opening degree of the second expansion valve (15c) and the pressure reducing valve (15a) is required. Adjusted accordingly.
  • the first on-off valve (SV1) and the second on-off valve (SV2) are set to open, and the third on-off valve (SV3) and the fourth on-off valve (SV4) are set to close.
  • the supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). To do.
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) is diverted, one of which is depressurized by the pressure reducing valve (15a) to become an intermediate pressure refrigerant, and then the low-temperature side stream of the supercooling heat exchanger (18)
  • the other flows into the channel, and the other flows into the high-temperature channel of the supercooling heat exchanger (18).
  • the high-pressure refrigerant in the high-temperature side channel and the intermediate-pressure refrigerant in the low-temperature side channel exchange heat.
  • the high-pressure refrigerant dissipates heat to the intermediate-pressure refrigerant and is cooled, and flows out of the high-temperature side flow path.
  • the intermediate-pressure refrigerant absorbs heat from the high-pressure refrigerant to become an intermediate-pressure gas refrigerant, and flows out from the low-temperature side flow path.
  • the intermediate-pressure refrigerant that has flowed out of the low-temperature channel of the supercooling heat exchanger (18) flows to the suction side of the high-stage compressor (11b).
  • the high-pressure refrigerant that has flowed out of the high-temperature channel of the supercooling heat exchanger (18) is reduced to a predetermined pressure by the second expansion valve (15c) to become a low-pressure refrigerant in a two-phase state, and then the heat storage It flows into the heat exchanger (14).
  • the low-pressure refrigerant and the water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice.
  • the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
  • the low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the second on-off valve (SV2), is sucked into the low-stage compressor (11a), and is compressed to a predetermined pressure to be intermediate-pressure gas refrigerant. After that, the low-stage compressor (11a) is discharged.
  • the intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) passes through the first on-off valve (SV1) and flows out from the low-temperature side passage of the supercooling heat exchanger (18). After joining the refrigerant, the refrigerant is sucked into the high stage compressor (11b).
  • the intermediate-pressure gas refrigerant sucked into the high-stage compressor (11b) is compressed to a critical pressure or higher to become a high-pressure refrigerant, and then discharged from the high-stage compressor (11b). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  • ⁇ Cryogenic operation> (First cold utilization operation)
  • the low-stage compressor (11a) and the high-stage compressor (11b) are started by daytime power, and the on-off valve (SV) is switched to switch the heat storage heat exchanger.
  • Set (14) as a radiator.
  • coolant which flows through the said refrigerant circuit (10) is radiated using the cold energy stored in the said ice thermal storage tank (2) by the said thermal storage driving
  • the opening degrees of the second expansion valve (15c) and the pressure reducing valve (15a) are fully closed, and the first expansion valve (15b) is opened.
  • the degree is adjusted as necessary.
  • the third on-off valve (SV3) and the fourth on-off valve (SV4) are set to open, and the first on-off valve (SV1) and the second on-off valve (SV2) are set to close.
  • the supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). (FIG. 4 (A), point c in FIG. 5).
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) passes through the supercooling heat exchanger (18) without exchanging heat, and flows into the first expansion valve (15b).
  • the high-pressure refrigerant that has flowed into the first expansion valve (15b) is depressurized to a predetermined pressure to become a two-phase low-pressure refrigerant, and flows out of the first expansion valve (15b) (FIGS. 4A and 5). Point d).
  • the low-pressure refrigerant that has flowed out of the first expansion valve (15b) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then enters the indoor heat exchanger (16). It flows out (point a in FIG. 4 (A) and FIG. 5).
  • the indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
  • the low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed to a predetermined pressure to become an intermediate-pressure gas refrigerant. It is discharged from the machine (11a) (FIG. 4 (A), point a1 in FIG. 5).
  • the intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) flows into the heat storage heat exchanger (14) through the third on-off valve (SV3).
  • the intermediate pressure gas refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water.
  • the intermediate pressure gas refrigerant dissipates heat to the ice in the ice heat storage tank (2), is cooled, and flows out of the heat storage heat exchanger (14) (point a2 in FIGS. 4A and 5). .
  • the intermediate-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) is sucked into the high-stage compressor (11b), compressed to a critical pressure or higher to become a high-pressure refrigerant, and then the high-stage compressor (11b) is discharged (point b in FIGS. 4A and 5). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  • the third on-off valve (SV3) is set to open, and the opening degree of at least one of the first expansion valve (15b) and the second expansion valve (15c) is required. Will be adjusted according to. Further, the first on-off valve (SV1), the second on-off valve (SV2), and the fourth on-off valve (SV4) are set to be closed, and the opening of the pressure reducing valve (15a) is fully closed. At this time, the low stage compressor (11a) is operated, and the high stage compressor (11b) is stopped.
  • the high-pressure refrigerant discharged from the low-stage compressor (11a) flows into the heat storage heat exchanger (14).
  • the high-pressure refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water.
  • the intermediate pressure gas refrigerant dissipates heat to the ice in the ice heat storage tank (2), is cooled, and flows out of the heat storage heat exchanger (14).
  • the refrigerant passes through the first expansion valve (15b) and the second expansion valve (15c), the refrigerant is depressurized to a predetermined pressure to become a two-phase low-pressure refrigerant, and flows out of the first expansion valve (15b).
  • the low-pressure refrigerant that has flowed out of the first expansion valve (15b) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then enters the indoor heat exchanger (16). leak.
  • the indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
  • the low-pressure gas refrigerant flowing out from the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed to a predetermined pressure to become a high-pressure refrigerant, and then the low-stage compressor (11a) Discharged from 11a). As the refrigerant circulates in this way, the second cold energy utilization operation is performed in the air conditioner (1).
  • the low-stage compressor (11a) is started and the high-stage compressor (11b) is stopped.
  • the circuit configuration of the refrigerant circuit (10) may be changed so that the compressor (11a) is stopped and the high-stage compressor (11b) is operated.
  • the refrigerant transport power during the cold energy operation is reduced compared to during the heat storage operation. can do. Therefore, the power consumption of the compression mechanism can be reduced.
  • the ice storage tank (2) is provided in the air conditioner (1), and the first to fourth on-off valves (SV1 to SV4) are provided in the refrigerant circuit (10).
  • the air conditioner (1) can perform the cold energy use operation and the heat storage operation.
  • the low-stage compressor (11a) and the high-stage compressor (11b), which are the compression mechanisms of the refrigerant circuit (30), are allowed to perform two-stage compression in the cold utilization operation, and the low-stage side
  • the refrigerant discharged from the compressor (11a) is cooled by the heat storage heat exchanger (14) and then sucked into the high-stage compressor (11b).
  • the compression mechanism of the refrigerant circuit (10) when configured by single-stage compression and when it is configured as in the first embodiment, if the power consumption is the same, the compression of the single-stage compression is performed.
  • the refrigerating capacity of the refrigerating apparatus having the compression mechanism (11) of the first embodiment is greater than that of the refrigerating apparatus having the mechanism (11). That is, the refrigerating capacity can be increased without increasing the power consumption.
  • the refrigeration can be performed without increasing the power consumption of the compression mechanism (11).
  • the refrigeration capacity of the apparatus can be brought close to the refrigeration capacity of a conventional refrigeration apparatus.
  • the first to fourth on-off valves (SV1 to SV4) are switched as shown in FIG. 3 to perform the heat storage operation and use relatively inexpensive nighttime power.
  • Cold water is stored by cooling the water in the ice heat storage tank (2) to produce ice.
  • the first to fourth on-off valves (SV1 to SV4) are switched as shown in FIG. 4 to perform cold heat operation during the daytime, and the ice generated during the heat storage operation is used to reduce daytime power consumption. be able to.
  • the peak power shift of the daytime power can be performed, and the refrigeration capacity of the conventional refrigeration apparatus can be approached without increasing the power consumption of the compression mechanism (11).
  • carbon dioxide is used as the refrigerant flowing through the refrigerant circuit (10).
  • this carbon dioxide is compared with the current HFC-based refrigerant, the latent heat increases and the refrigerant density increases as the saturation pressure decreases. Therefore, the capacity
  • Modification 1 of Embodiment 1— 6 is a refrigerant circuit diagram of an air conditioner (1) according to Modification 1 of Embodiment 1.
  • FIG. 7 shows the refrigerant flow during the heat storage operation
  • FIG. 8 shows the refrigerant flow during the cold energy use operation.
  • FIG. 9 is a diagram showing a refrigeration cycle during a cold energy operation on a Ph graph of carbon dioxide.
  • the heat storage heat exchanger (14) is connected between the low-stage compressor (11a) and the high-stage compressor (11b).
  • a second heat storage heat exchanger (19) different from the heat storage heat exchanger (14) is connected between the supercooling heat exchanger (18) and the expansion valve.
  • the refrigerant circuit (30) is provided with a flow rate adjustment valve (13) instead of the second expansion valve (15c) of the first embodiment.
  • the refrigerant circuit (30) is provided with fifth and sixth on-off valves (SV5, SV6).
  • the heat storage heat exchanger (14) connected between the low stage compressor (11a) and the high stage compressor (11b) is referred to as a first heat storage heat exchanger (14).
  • Both the first and second heat storage heat exchangers (14, 19) are accommodated in the ice heat storage tank (2).
  • the end of the refrigerant pipe extending from the discharge side of the low-stage compressor (11a) is branched and connected to one end of the first and second branch pipes (20, 21).
  • the other ends of the branch pipes (20, 21) merge and are connected to the suction side of the high-stage compressor (11b).
  • the first branch pipe (20) is provided with the first on-off valve (SV1).
  • the second branch pipe (21) includes a third on-off valve (SV3), the heat storage heat exchanger (14), and a second heat exchanger in order from the low stage compressor (11a) to the high stage compressor (11b).
  • a 4 on-off valve (SV4) is provided.
  • the refrigerant pipe extending from the discharge side of the high stage compressor (11b) is connected to one end of the outdoor heat exchanger (12).
  • the refrigerant pipe extending from the other end of the outdoor heat exchanger (12) branches, and one is connected to the inlet side of the low temperature side passage of the supercooling heat exchanger (18) via the pressure reducing valve (15a), The other is connected to the inlet side of the high temperature side passage of the supercooling heat exchanger (18).
  • the refrigerant pipe extending from the outlet side of the low temperature side passage of the supercooling heat exchanger (18) is between the high stage compressor (11b) and the first on-off valve (SV1) in the first branch pipe (20). Communicated with.
  • the refrigerant pipe extending from the outlet side of the high temperature side passage of the supercooling heat exchanger (18) branches via the flow rate adjusting valve (13), and one of the refrigerant pipes is connected to one end of the second heat storage heat exchanger (19). The other is connected via the fifth on-off valve (SV5) to the first heat storage heat exchanger (14) and the fourth on-off valve (SV4) in the second branch pipe (21).
  • the refrigerant pipe extending from the other end of the second heat storage heat exchanger (19) is connected to one end of the indoor heat exchanger (16) through an expansion valve (15).
  • the refrigerant pipe extending from the other end of the indoor heat exchanger (16) branches, one is connected to the suction side of the low-stage compressor (11a), and the other is connected via the second on-off valve (SV2).
  • the second branch pipe (21) communicates with the third on-off valve (SV3) and the first heat storage heat exchanger (14).
  • the refrigerant circuit (30) is provided with a bypass pipe that bypasses the expansion valve (15) and the indoor heat exchanger (16), and the bypass pipe is provided with a sixth on-off valve (SV6). It has been.
  • the opening degree of the expansion valve (15) is fully closed, and the opening degree of the flow rate adjusting valve (13) and the pressure reducing valve (15a) is adjusted as necessary. Is done.
  • the first on-off valve (SV1), the second on-off valve (SV2), the fifth on-off valve (SV5), and the sixth on-off valve (SV6) are set open, and the third on-off valve (SV3) and The fourth on-off valve (SV4) is set to be closed.
  • the supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). To do.
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) is diverted, one of which is depressurized by the pressure reducing valve (15a) to become an intermediate pressure refrigerant, and then the low-temperature side stream of the supercooling heat exchanger (18) The other flows into the channel, and the other flows into the high temperature side channel of the supercooling heat exchanger (18).
  • the high-pressure refrigerant in the high-temperature side channel and the intermediate-pressure refrigerant in the low-temperature side channel exchange heat.
  • the high-pressure refrigerant dissipates heat to the intermediate-pressure refrigerant and is cooled, and flows out of the high-temperature side flow path.
  • the intermediate-pressure refrigerant absorbs heat from the high-pressure refrigerant to become an intermediate-pressure gas refrigerant, and flows out from the low-temperature side flow path.
  • the intermediate-pressure refrigerant that has flowed out of the low-temperature channel of the supercooling heat exchanger (18) flows to the suction side of the high-stage compressor (11b).
  • the high-pressure refrigerant that has flowed out of the high-temperature side flow path of the supercooling heat exchanger (18) flows into the flow rate adjusting valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant in a two-phase state And flows out of the flow regulating valve (13).
  • the low-pressure refrigerant that has flowed out of the flow rate adjusting valve (13) is divided, one flows into the second heat storage heat exchanger (19), and the other passes through the fifth on-off valve (SV5) and the first heat storage heat exchanger ( 14).
  • the low-pressure refrigerant and the water in each ice heat storage tank (2) exchange heat, and the water in each ice heat storage tank (2). Is cooled to ice.
  • the low-pressure refrigerant that has absorbed heat from the water in each of the ice heat storage tanks (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchangers (14).
  • the refrigerant After becoming a refrigerant, the refrigerant is discharged from the low stage compressor (11a).
  • the intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) passes through the first on-off valve (SV1) and flows out from the low-temperature side passage of the supercooling heat exchanger (18). After joining the refrigerant, the refrigerant is sucked into the high stage compressor (11b).
  • the intermediate-pressure gas refrigerant sucked into the high-stage compressor (11b) is compressed to a critical pressure or higher to become a high-pressure refrigerant, and then discharged from the high-stage compressor (11b). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  • ⁇ Cryogenic operation> In the cold energy utilization operation, as shown in FIG. 8, the opening of the pressure reducing valve (15a) is fully closed, and the openings of the flow rate adjusting valve (13) and the expansion valve (15) are adjusted as necessary. Adjusted.
  • the first on-off valve (SV1), the second on-off valve (SV2), the fifth on-off valve (SV5), and the sixth on-off valve (SV6) are set to be closed, and the third on-off valve (SV3) and The fourth on-off valve (SV4) is set to open.
  • the supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). (Point b1 in FIGS. 8 and 9).
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) passes through the supercooling heat exchanger (18) without exchanging heat, and the flow rate of the high-pressure refrigerant is adjusted by the flow rate adjusting valve (13). 2 flows into the heat storage heat exchanger (19).
  • the high-pressure refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water.
  • the high-pressure refrigerant radiates and cools the ice in the ice heat storage tank (2) and then flows out of the second heat storage heat exchanger (19) (point c in FIGS. 8 and 9).
  • the indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
  • the low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed to a predetermined pressure to become an intermediate-pressure gas refrigerant. It is discharged from the machine (11a) (point a1 in FIGS. 8 and 9).
  • the intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) flows into the first heat storage heat exchanger (14) through the third on-off valve (SV3).
  • the intermediate pressure gas refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water. Become.
  • the intermediate-pressure gas refrigerant dissipates heat to the ice in the ice heat storage tank (2), is cooled, and flows out of the first heat storage heat exchanger (14) (point a2 in FIGS. 8 and 9).
  • the intermediate-pressure gas refrigerant that has flowed out of the first heat storage heat exchanger (14) passes through the fourth on-off valve (SV4) and is sucked into the high-stage compressor (11b) and compressed to a critical pressure or higher. After becoming a refrigerant, the refrigerant is discharged from the high stage compressor (11b) (point b in FIGS. 8 and 9). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  • the low-stage compressor (11a) and the high-stage compressor (11b), which are compression mechanisms of the refrigerant circuit (30), are subjected to two-stage compression,
  • the refrigerant discharged from the low stage compressor (11a) is cooled by the first heat storage heat exchanger (14). If it carries out like this, refrigerating capacity can be increased, without increasing power consumption similarly to Embodiment 1.
  • FIG. 1 the low-stage compressor (11a) and the high-stage compressor (11b), which are compression mechanisms of the refrigerant circuit (30), are subjected to two-stage compression.
  • the refrigerant discharged from the low stage compressor (11a) is cooled by the first heat storage heat exchanger (14). If it carries out like this, refrigerating capacity can be increased, without increasing power consumption similarly to Embodiment 1.
  • the temperature of the refrigerant flowing out from the heat source side heat exchanger (12) can be further lowered, and the refrigeration effect can be improved.
  • the circulation amount of the refrigerant in the refrigerant circuit (30) can be reduced by the amount that the refrigeration effect is improved, and the power consumption of the compression mechanism of the refrigerant circuit (30) can be reduced.
  • the power consumption of the refrigerant circuit (30) It is possible to approach the refrigeration capacity of the conventional refrigeration apparatus without increasing the value.
  • FIG. 10 is a refrigerant circuit diagram of the air conditioner (1) according to the second modification of the first embodiment.
  • FIG. 11 shows the refrigerant flow during the heat storage operation
  • FIG. 12 shows the refrigerant flow during the cold utilization operation.
  • FIG. 13 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
  • the heat storage heat exchanger (14) is connected between the low-stage compressor (11a) and the high-stage compressor (11b). In the refrigerant circuit (40) of Example 2, the heat storage heat exchanger (14) is connected to another position.
  • connection pipe (22) extending from the discharge side of the low stage compressor (11a) is connected to the suction side of the high stage compressor (11b).
  • a refrigerant pipe extending from the discharge side of the high stage compressor (11b) is connected to one end of the outdoor heat exchanger (12).
  • the refrigerant pipe extending from the other end of the outdoor heat exchanger (12) branches, and one is connected to the inlet side of the low temperature side passage of the supercooling heat exchanger (18) via the pressure reducing valve (15a), The other is connected to the inlet side of the high temperature side passage of the supercooling heat exchanger (18).
  • the refrigerant pipe extending from the other end of the heat storage heat exchanger (14) communicates with the connection pipe (22) through a seventh on-off valve (SV7).
  • the refrigerant pipe extending from the other end of the indoor heat exchanger (16) branches, and one end of the refrigerant pipe extends from the other end of the heat storage heat exchanger (14) via an eighth on-off valve (SV8).
  • the heat storage heat exchanger (14) communicates with the seventh on-off valve (SV7), and the other end is connected to the suction side of the low-stage compressor (11a).
  • the supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). To do.
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) is diverted, one of which is depressurized by the pressure reducing valve (15a) to become an intermediate pressure refrigerant, and then the low-temperature side stream of the supercooling heat exchanger (18) The other flows into the channel, and the other flows into the high temperature side channel of the supercooling heat exchanger (18).
  • the high-pressure refrigerant in the high-temperature side channel and the intermediate-pressure refrigerant in the low-temperature side channel exchange heat.
  • the high-pressure refrigerant dissipates heat to the intermediate-pressure refrigerant and is cooled, and flows out of the high-temperature side flow path.
  • the intermediate-pressure refrigerant absorbs heat from the high-pressure refrigerant to become an intermediate-pressure gas refrigerant, and flows out from the low-temperature side flow path.
  • the intermediate-pressure refrigerant that has flowed out of the low-temperature channel of the supercooling heat exchanger (18) flows to the suction side of the high-stage compressor (11b).
  • the high-pressure refrigerant that has flowed out of the high-temperature side flow path of the supercooling heat exchanger (18) flows into the flow rate adjusting valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant in a two-phase state And flows out of the flow regulating valve (13).
  • the low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
  • the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice.
  • the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
  • the low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the eighth on-off valve (SV8), is sucked into the low-stage compressor (11a), is compressed to a predetermined pressure, and is compressed to an intermediate pressure gas. After becoming a refrigerant, the refrigerant is discharged from the low stage compressor (11a).
  • the intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) merges with the intermediate-pressure gas refrigerant flowing out from the low-temperature side flow path of the supercooling heat exchanger (18), and then the high-stage compression Inhaled into the machine (11b).
  • the intermediate-pressure gas refrigerant sucked into the high-stage compressor (11b) is compressed to a critical pressure or higher to become a high-pressure refrigerant, and then discharged from the high-stage compressor (11b). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  • the high-pressure gas refrigerant discharged from the low-stage compressor (11a) flows into the heat storage heat exchanger (14) through the seventh on-off valve (SV7).
  • the high pressure gas refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts to become water.
  • the high-pressure gas refrigerant releases heat to the ice in the ice heat storage tank (2) and condenses, and then flows out of the heat storage heat exchanger (14) (point c in FIGS. 12 and 13).
  • the indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
  • the low-pressure gas refrigerant that has flowed out of the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed within the range below the critical pressure to become a high-pressure gas refrigerant. It is discharged from the side compressor (11a) (point b in FIGS. 12 and 13). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  • the low-stage compressor (11a) and the high-stage compressor (11b) are started during the heat storage operation. Only the low stage compressor (11a) is running. Thereby, compared with the time of the said heat storage driving
  • FIG. 14 is a refrigerant circuit diagram of the air-conditioning apparatus (1) according to Embodiment 2.
  • FIG. 15 shows the refrigerant flow during the heat storage operation
  • FIG. 16 shows the refrigerant flow during the cold utilization operation.
  • FIG. 17 is a diagram showing a refrigeration cycle during a cold heat operation on a Ph graph of carbon dioxide.
  • the major difference between the refrigerant circuit (50) of the second embodiment and the refrigerant circuit (10) shown in the first embodiment is that the compression is performed in place of the low-stage compressor (11a) and the high-stage compressor (11b).
  • the machine (11) and the refrigerant gas pump (refrigerant pump) (17) are provided, and the position of the heat storage heat exchanger (14) is different.
  • the refrigerant gas pump (17) is for conveying refrigerant gas, and has a compression ratio smaller than that of the compressor (11).
  • the refrigerant circuit (50) is provided with a bypass pipe (23) that bypasses the outdoor heat exchanger (12) and the flow rate adjusting valve (13), and is provided from the outdoor heat exchanger (12) side.
  • a ninth on-off valve (SV9) and the heat storage heat exchanger (14) are provided toward the flow rate adjustment valve (13).
  • a branch pipe (24) extending from between the ninth on-off valve (SV9) and the heat storage heat exchanger (14) in the bypass pipe (23) is connected to the indoor heat exchanger (16) and the compressor (11).
  • a tenth on-off valve (SV10) is connected to the branch pipe (24).
  • the refrigerant circuit (10) includes the refrigerant gas pump (17) for conveying the refrigerant.
  • the refrigerant discharged from the compression mechanism (11) dissipates heat in the heat source side heat exchanger (12), evaporates in the heat storage heat exchanger (14), and enters the compression mechanism (11)
  • the return heat storage operation, and the refrigerant discharged from the refrigerant gas pump (17) is condensed in the heat storage heat exchanger (14), evaporated in the use side heat exchanger (16), and returned to the refrigerant pump (17). It is comprised so that it may switch.
  • the supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12).
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant is in a two-phase state.
  • the low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
  • the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice.
  • the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
  • the low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the tenth on-off valve (SV10), is sucked into the compressor (11), and is compressed to a predetermined pressure to be supercritical high-pressure refrigerant. After that, it is discharged from the compressor (11). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  • the refrigerant discharged from the refrigerant gas pump (17) flows into the heat storage heat exchanger (14) through the ninth on-off valve (SV9).
  • the refrigerant and ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts to become water.
  • the refrigerant releases heat to the ice in the ice heat storage tank (2) and condenses, and then flows out of the heat storage heat exchanger (14) (point c in FIGS. 16 and 17).
  • the indoor air is cooled by causing the refrigerant to absorb the heat of the indoor air.
  • the refrigerant flowing out of the indoor heat exchanger (16) is sucked into the refrigerant gas pump (17) and then discharged from the refrigerant gas pump (17) (point b in FIGS. 16 and 17). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  • the refrigerant pump (17) is used without using the compression mechanism (11) during the cold heat operation.
  • coolant conveyance motive power at the time of the said cold utilization operation can be reduced.
  • movement can be reduced. Therefore, as in the second modification of the first embodiment, the refrigeration capacity during the cold-utilizing operation can be increased without increasing the power consumption of the compression mechanism of the refrigerant circuit (50).
  • Embodiment 3 18 is a refrigerant circuit diagram of the air-conditioning apparatus (1) according to Embodiment 3.
  • FIG. 19 shows the refrigerant flow during the heat storage operation
  • FIG. 20 shows the refrigerant flow during the cold energy use operation.
  • FIG. 21 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
  • the major difference between the refrigerant circuit (60) of the second embodiment and the refrigerant circuit (10) shown in the first embodiment is that the low-stage compressor (11a) and the high-stage compressor (11b) are replaced with 1 Only the compressor (11) is provided, and the position of the heat storage heat exchanger (14) is different.
  • the refrigerant pipe extending from the discharge side of the compressor (11) is connected to one end of the heat storage heat exchanger (14) via the outdoor heat exchanger (12) and the flow rate adjusting valve (13).
  • a refrigerant pipe extending from the other end of the heat storage heat exchanger (14) is connected to the suction side of the compressor (11) via the expansion valve (15) and the indoor heat exchanger (16).
  • the refrigerant pipe is provided with a bypass pipe that bypasses the expansion valve (15) and the indoor heat exchanger (16), and the bypass pipe is provided with an eleventh on-off valve (SV11).
  • the supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12).
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant is in a two-phase state.
  • the low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
  • the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice.
  • the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
  • the low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the eleventh on-off valve (SV11), is sucked into the compressor (11), and is compressed to a predetermined pressure so that it is in a supercritical state. After that, it is discharged from the compressor (11). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  • the supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12) (FIG. 20, point b1) in FIG.
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the heat storage heat exchanger (14) after the flow rate is adjusted by the flow rate adjustment valve (13).
  • the high-pressure refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts to become water.
  • the high-pressure refrigerant releases heat to the ice in the ice heat storage tank (2) and is cooled, and then flows out of the heat storage heat exchanger (14) (point c in FIGS. 20 and 21).
  • the indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
  • the low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the compressor (11) and compressed to a predetermined pressure to become a high-pressure refrigerant in a supercritical state, and then the compressor (11) (Point b in FIGS. 20 and 21). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  • the heat storage heat exchanger (14) is connected between the heat source side heat exchanger (12) and the expansion valve (15) of the refrigerant circuit (60). If it carries out like this, the temperature of the refrigerant
  • the refrigeration capacity of the air conditioner (1) can be increased without increasing the power consumption.
  • Embodiment 3- 22 is a refrigerant circuit diagram of an air conditioner (1) according to a modification of the third embodiment.
  • FIG. 23 shows the refrigerant flow during the heat storage operation
  • FIG. 24 shows the refrigerant flow during the cold energy use operation.
  • FIG. 25 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
  • the heat storage heat exchanger (14) is connected between the outdoor heat exchanger (12) and the expansion valve.
  • the heat storage heat exchanger (14) is connected in parallel with the heat source side heat exchanger (12).
  • the refrigerant pipe extending from the discharge side of the compressor (11) is connected to one end of the outdoor heat exchanger (12).
  • the other end of the outdoor heat exchanger (12) is connected to one end of the indoor heat exchanger (16) through the flow rate adjusting valve (13) and the expansion valve (15).
  • the other end of the indoor heat exchanger (16) is connected to the suction side of the compressor (11).
  • the refrigerant circuit (70) is provided with a bypass pipe (23) that bypasses the outdoor heat exchanger (12) and the flow rate adjusting valve (13), and is provided from the outdoor heat exchanger (12) side.
  • a twelfth on-off valve (SV12) and the heat storage heat exchanger (14) are provided toward the flow rate adjustment valve (13).
  • a branch pipe (24) extending from between the twelfth on-off valve (SV12) and the heat storage heat exchanger (14) in the bypass pipe (23) is connected to the indoor heat exchanger (16) and the compressor (11). Is connected to the refrigerant pipe connecting the two.
  • a thirteenth on-off valve (SV13) is connected to the branch pipe (24).
  • the supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12).
  • the high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant is in a two-phase state.
  • the low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
  • the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice.
  • the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
  • the low-pressure gas refrigerant flowing out of the heat storage heat exchanger (14) is sucked into the compressor (11) through the thirteenth on-off valve (SV13) and compressed to a predetermined pressure to be supercritical high-pressure refrigerant. After that, it is discharged from the compressor (11). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  • the supercritical high-pressure refrigerant discharged from the compressor (11) is diverted, one flows into the outdoor heat exchanger (12), and the other passes through the twelfth on-off valve (SV12) and the heat storage. It flows into the heat exchanger (14) (point b1 in FIGS. 24 and 25).
  • the high-pressure refrigerant that has flowed into the outdoor heat exchanger (12) radiates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12) (point c in FIGS. 24 and 25).
  • the refrigerant flowing into the heat storage heat exchanger (14) exchanges heat with the ice in the ice heat storage tank (2), and the ice in the ice heat storage tank (2) melts to become water.
  • the refrigerant dissipates heat to the ice in the ice heat storage tank (2) and is cooled, it flows out of the heat storage heat exchanger (14) (point c2 in FIGS. 24 and 25).
  • the pressure is reduced to become a low-pressure refrigerant in a two-phase state, and flows out from the expansion valve (15) (point d in FIGS. 24 and 25).
  • the low-pressure refrigerant that has flowed out of the expansion valve (15) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then flows out of the indoor heat exchanger (16). (Point a in FIGS. 24 and 25).
  • the indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
  • the low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the compressor (11) and compressed to a predetermined pressure to become a high-pressure refrigerant in a supercritical state, and then the compressor (11) (Point b in FIGS. 24 and 25). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  • the heat storage heat exchanger (14) is connected in parallel with the heat source side heat exchanger (12) of the refrigerant circuit (70). If it carries out like this, the refrigerant
  • the operation state of the air conditioner (1) is switched to the heat storage operation or the cold energy use operation using a plurality of on-off valves (SV).
  • SV on-off valves
  • the operating state of the air conditioner (1) may be switched by a valve or a four-way valve.
  • carbon dioxide is used as a refrigerant
  • the present invention is not limited to this, and other natural refrigerants may be used.
  • the present invention is useful for a refrigeration apparatus including a refrigerant circuit that performs a supercritical refrigeration cycle.
  • Air conditioner refrigeration equipment
  • Ice heat storage tank 3
  • Outdoor unit 4
  • Indoor unit 10
  • Refrigerant circuit 11
  • Compressor compression mechanism
  • Outdoor heat exchanger heat source side heat exchanger
  • Heat storage heat exchanger 15
  • Expansion valve Expansion mechanism 16
  • Indoor heat exchanger (use side heat exchanger)

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Abstract

An air conditioning device provided with a refrigerant circuit for performing a supercritical refrigeration cycle by two-stage compression, wherein the air conditioning device is provided with an ice heat storage tank (2) which provides, without an increase in the amount of electric power consumption by a compressor, the air conditioning device with refrigeration ability close to the refrigeration ability of an air conditioning device using a current HFC-based refrigerant.  The ice heat storage tank (2) stores therein water or ice as a heat storage medium and is provided with a heat storage heat exchanger (14) connected to a refrigerant circuit (10) and exchanging heat between the heat storage medium and the refrigerant in the refrigerant circuit (10).  The ice heat storage tank (2) functioning as a heat dissipater when the heat storage heat exchanger (14) utilizes cold energy of the heat storage medium is provided between a low-stage compressor (11a) and a high-stage compressor (11b) of the air conditioning device (1).

Description

冷凍装置Refrigeration equipment
 本発明は、超臨界冷凍サイクルを行う冷媒回路を備えた冷凍装置に関するものである。 The present invention relates to a refrigeration apparatus including a refrigerant circuit that performs a supercritical refrigeration cycle.
 従来より、冷媒として二酸化炭素を用いて超臨界冷凍サイクルを行う冷媒回路を備えた冷凍装置が知られている(例えば、特許文献1参照)。図26は二酸化炭素のP-h(圧力-エンタルピ)線図上に従来の冷凍装置における超臨界冷凍サイクルを示した図である。 Conventionally, a refrigeration apparatus including a refrigerant circuit that performs a supercritical refrigeration cycle using carbon dioxide as a refrigerant is known (see, for example, Patent Document 1). FIG. 26 is a diagram showing a supercritical refrigeration cycle in a conventional refrigeration apparatus on a Ph (pressure-enthalpy) diagram of carbon dioxide.
 従来の冷凍装置の冷媒回路は、圧縮機構と熱源側熱交換器と膨張弁と利用側熱交換器とが順に接続された閉回路で構成されている。この冷凍装置(空気調和装置)の冷房運転では、上記熱源側熱交換器が放熱器となり、上記利用側熱交換器が蒸発器となる。尚、上記熱源側熱交換器及び上記利用側熱交換器は、いずれも空気熱交換器で構成されている。 A refrigerant circuit of a conventional refrigeration apparatus is configured by a closed circuit in which a compression mechanism, a heat source side heat exchanger, an expansion valve, and a use side heat exchanger are connected in order. In the cooling operation of the refrigeration apparatus (air conditioner), the heat source side heat exchanger serves as a radiator, and the use side heat exchanger serves as an evaporator. Note that each of the heat source side heat exchanger and the use side heat exchanger is constituted by an air heat exchanger.
 上記圧縮機構で臨界圧(図26の点e)以上まで圧縮された高圧冷媒は、該圧縮機構から吐出される。上記圧縮機構から吐出された高圧冷媒は、上記熱源側熱交換器に流入する(図26のb点)。上記熱源側熱交換器に流入した高圧冷媒は、外気に放熱した後で該熱源側熱交換器を流出する(図26のc点)。上記熱源側熱交換器を流出した高圧冷媒は、上記膨張弁で減圧されて低圧冷媒となり(図26の点d)、上記利用側熱交換器に流入する。上記利用側熱交換器に流入した低圧冷媒は、利用空間の空気から吸熱し蒸発した後で該利用側熱交換器を流出する。上記利用側熱交換器を流出した低圧冷媒は、圧縮機構に吸入され(図26の点a)、臨界圧以上まで圧縮された後、再び高圧冷媒となって吐出される。この動作を繰り返すことにより、上記冷凍装置の冷房運転が行われる。 The high-pressure refrigerant compressed to the critical pressure (point e in FIG. 26) or higher by the compression mechanism is discharged from the compression mechanism. The high-pressure refrigerant discharged from the compression mechanism flows into the heat source side heat exchanger (point b in FIG. 26). The high-pressure refrigerant flowing into the heat source side heat exchanger flows out of the heat source side heat exchanger after radiating heat to the outside air (point c in FIG. 26). The high-pressure refrigerant that has flowed out of the heat-source-side heat exchanger is reduced in pressure by the expansion valve to become low-pressure refrigerant (point d in FIG. 26), and flows into the use-side heat exchanger. The low-pressure refrigerant that has flowed into the use side heat exchanger absorbs heat from the air in the use space and evaporates, and then flows out of the use side heat exchanger. The low-pressure refrigerant that has flowed out of the use-side heat exchanger is sucked into the compression mechanism (point a in FIG. 26), compressed to a critical pressure or higher, and then discharged as high-pressure refrigerant again. By repeating this operation, the cooling operation of the refrigeration apparatus is performed.
特開2007-263383号公報JP 2007-263383 A
 ところで、現行のHFC系冷媒を用いた冷凍装置の冷房運転において、例えば外気温度が30℃位の場合、上記熱源側熱交換器の冷媒出口温度は大体40℃位である。 By the way, in the cooling operation of the refrigeration apparatus using the current HFC-based refrigerant, for example, when the outside air temperature is about 30 ° C., the refrigerant outlet temperature of the heat source side heat exchanger is about 40 ° C. or so.
 この冷凍装置の場合、冷凍サイクルの高圧圧力が臨界圧力より低いので、上記圧縮機から吐出されて上記熱源側熱交換器に流入したHFC系冷媒は、該熱源側熱交換器内でその温度が40℃位まで下がるまでの間に相変化して潜熱を放出する。 In the case of this refrigeration apparatus, since the high pressure of the refrigeration cycle is lower than the critical pressure, the HFC refrigerant discharged from the compressor and flowing into the heat source side heat exchanger has a temperature in the heat source side heat exchanger. Phase change occurs until the temperature drops to about 40 ° C., and latent heat is released.
 これに対して、上記冷凍装置の冷媒として、例えば二酸化炭素を用いた場合、冷凍サイクルの高圧圧力が臨界圧力以上となるので、上記熱源側熱交換器内で二酸化炭素の温度が40℃位まで下がるまでの間に二酸化炭素は相変化しない。このため、二酸化炭素は上記熱源側熱交換器内で顕熱しか放出できない。したがって、二酸化炭素及びHFC系冷媒の循環量が同じ場合には、上記熱源側熱交換器内での放熱量は二酸化炭素の方が少なくなる。 On the other hand, for example, when carbon dioxide is used as the refrigerant of the refrigeration apparatus, the high pressure of the refrigeration cycle is equal to or higher than the critical pressure. Until it falls, carbon dioxide does not change phase. For this reason, carbon dioxide can only release sensible heat in the heat source side heat exchanger. Therefore, when the circulation amount of carbon dioxide and the HFC refrigerant is the same, the amount of heat released in the heat source side heat exchanger is smaller in carbon dioxide.
 このことから、二酸化炭素を冷媒として用いた冷凍装置において、その冷凍能力をHFC系冷媒の冷凍能力に近づけるためには、熱交換器のサイズをアップするとともに、上記冷媒回路を流れる冷媒の循環量を増加させる必要がある。しかしながら、上記冷媒の循環量を増加させて、HFC系冷媒と同等の冷凍能力を得たとしても、その冷媒循環量の増加に起因して圧縮機の消費電力量が増加してしまうので好ましくない。 Therefore, in a refrigeration apparatus using carbon dioxide as a refrigerant, in order to bring the refrigeration capacity close to the refrigeration capacity of the HFC refrigerant, the heat exchanger is increased in size and the circulation amount of the refrigerant flowing through the refrigerant circuit is increased. Need to be increased. However, even if the circulation amount of the refrigerant is increased to obtain a refrigerating capacity equivalent to that of the HFC refrigerant, the power consumption of the compressor increases due to the increase of the refrigerant circulation amount, which is not preferable. .
 本発明は、かかる点に鑑みてなされたものであり、その目的は、超臨界冷凍サイクルを行う冷媒回路を備えた冷凍装置において、その冷凍能力を圧縮機構の消費電力量を増加させずに現行のHFC系冷媒を用いた冷凍装置の冷凍能力に近づけることである。 The present invention has been made in view of such a point, and an object of the present invention is to provide a refrigeration apparatus equipped with a refrigerant circuit that performs a supercritical refrigeration cycle without reducing the refrigeration capacity of the compressor without increasing the power consumption of the compression mechanism. The refrigerating capacity of the refrigerating apparatus using the HFC-based refrigerant is approached.
 第1の発明は、圧縮機構(11)と熱源側熱交換器(12)と膨張機構(15)と利用側熱交換器(16)とが接続されて超臨界冷凍サイクルを行う冷媒回路(10)を備えた冷凍装置を前提としている。 The first invention is a refrigerant circuit (10) in which a compression mechanism (11), a heat source side heat exchanger (12), an expansion mechanism (15), and a use side heat exchanger (16) are connected to perform a supercritical refrigeration cycle. ) Is assumed.
 そして、上記冷凍装置において、水又は氷を蓄熱媒体として貯蔵するとともに、上記冷媒回路(10)に接続されて蓄熱媒体と上記冷媒回路(10)の冷媒とを熱交換する蓄熱熱交換器(14)を有し、該蓄熱熱交換器(14)が蓄熱媒体の冷熱利用時に放熱器となる氷蓄熱タンク(2)を備えている。 And in the said freezing apparatus, while storing water or ice as a thermal storage medium, it is connected to the said refrigerant circuit (10), and the thermal storage heat exchanger (14 which exchanges heat between the thermal storage medium and the refrigerant | coolant of the said refrigerant circuit (10) ), And the heat storage heat exchanger (14) includes an ice heat storage tank (2) that serves as a radiator when using the cold energy of the heat storage medium.
 また、上記圧縮機構(11)は、低段側圧縮機(11a)と高段側圧縮機(11b)とを備える一方、上記蓄熱熱交換器(14)は、上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続されている。 The compression mechanism (11) includes a low-stage compressor (11a) and a high-stage compressor (11b), while the heat storage heat exchanger (14) includes the low-stage compressor (11a). ) And the higher stage compressor (11b).
 第1の発明では、超臨界冷凍サイクルを行う上記冷凍装置に対して上記氷蓄熱タンク(2)を設けている。この氷蓄熱タンク(2)で生成された氷の冷熱を利用し、該氷蓄熱タンク(2)の蓄熱熱交換器(14)が放熱器となる。したがって、例えば超臨界冷凍サイクルを行う冷媒回路(10)の冷媒は、上記熱源側熱交換器(12)と上記蓄熱熱交換器(14)との両方で放熱する。 In the first invention, the ice heat storage tank (2) is provided for the refrigeration apparatus that performs the supercritical refrigeration cycle. Using the cold heat of the ice generated in the ice heat storage tank (2), the heat storage heat exchanger (14) of the ice heat storage tank (2) serves as a radiator. Therefore, for example, the refrigerant in the refrigerant circuit (10) performing the supercritical refrigeration cycle dissipates heat in both the heat source side heat exchanger (12) and the heat storage heat exchanger (14).
 また、上記圧縮機構(11)に二段圧縮を行わせることで、単段圧縮の場合に比べて、その消費電力量を抑えることができ、上記低段側圧縮機(11a)から吐出された冷媒を上記蓄熱熱交換器(14)で冷却することで、さらに消費電力量を抑えることができる。 In addition, by causing the compression mechanism (11) to perform two-stage compression, it is possible to suppress the amount of power consumption compared to the case of single-stage compression, and the compressor is discharged from the low-stage compressor (11a). By cooling the refrigerant with the heat storage heat exchanger (14), the amount of power consumption can be further reduced.
 言い換えれば、単段圧縮の圧縮機構(11)と第1の発明の圧縮機構(11)とが同じ消費電力の場合、第1の発明の圧縮機構(11)を有する冷凍装置の冷凍能力が大きいこととなる。つまり、消費電力を増やさずに冷凍能力を増やすことができる。 In other words, when the compression mechanism (11) for single-stage compression and the compression mechanism (11) of the first invention have the same power consumption, the refrigerating capacity of the refrigeration apparatus having the compression mechanism (11) of the first invention is large. It will be. That is, the refrigerating capacity can be increased without increasing the power consumption.
 第2の発明は、第1の発明において、上記蓄熱熱交換器(14)は、上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続された第1蓄熱熱交換器(14)であり、さらに、上記冷媒回路(10)の熱源側熱交換器(12)と膨張機構(15)との間に接続された第2蓄熱熱交換器(19)を備えていることを特徴としている。 In a second aspect based on the first aspect, the heat storage heat exchanger (14) is a first heat storage connected between the low-stage compressor (11a) and the high-stage compressor (11b). A heat exchanger (14), further comprising a second heat storage heat exchanger (19) connected between the heat source side heat exchanger (12) of the refrigerant circuit (10) and the expansion mechanism (15). It is characterized by having.
 第2の発明では、上記圧縮機構(11)に二段圧縮を行わせることで、単段圧縮の場合に比べて、その消費電力量を抑えることができ、上記低段側圧縮機(11a)から吐出された冷媒を上記第1蓄熱熱交換器(14)で冷却することで、さらに消費電力量を抑えることができる。又、上記熱源側熱交換器(12)で放熱した冷媒をさらに上記第2蓄熱熱交換器(19)で冷却することができる。 In the second invention, by causing the compression mechanism (11) to perform the two-stage compression, the power consumption can be suppressed as compared with the case of the single-stage compression, and the low-stage compressor (11a) By cooling the refrigerant discharged from the first heat storage heat exchanger (14), the power consumption can be further suppressed. Moreover, the refrigerant radiated by the heat source side heat exchanger (12) can be further cooled by the second heat storage heat exchanger (19).
 ここで、例えば上記熱源側熱交換器(12)が空気熱交換器で構成されていたとすると、上述したように、上記熱源側熱交換器(12)の冷媒出口温度は大体40℃位となり、二酸化炭素及びHFC系冷媒の循環量が同じ場合には、上記熱源側熱交換器(12)内での放熱量は二酸化炭素の方が少なくなる。 Here, for example, if the heat source side heat exchanger (12) is composed of an air heat exchanger, as described above, the refrigerant outlet temperature of the heat source side heat exchanger (12) is approximately 40 ° C., When the circulation amount of carbon dioxide and the HFC refrigerant is the same, the amount of heat released in the heat source side heat exchanger (12) is smaller in carbon dioxide.
 つまり、冷凍装置における利用側熱交換器(16)の冷凍効果は、HFC系冷媒を用いた場合に比べて、二酸化炭素を用いた場合の方が小さくなる。ここで、上記冷凍効果とは、いわゆる上記利用側熱交換器(16)の冷媒出口比エンタルピ(図26の点a)と冷媒入口比エンタルピ(図26の点d)との差のことである。 That is, the refrigeration effect of the use side heat exchanger (16) in the refrigeration apparatus is smaller when carbon dioxide is used than when the HFC refrigerant is used. Here, the refrigeration effect is the difference between the so-called refrigerant outlet specific enthalpy (point a in FIG. 26) and the refrigerant inlet specific enthalpy (point d in FIG. 26) of the use side heat exchanger (16). .
 上記第2蓄熱熱交換器(19)を用いると、上記熱源側熱交換器(12)から流出した冷媒の温度をさらに下げることができ、上記冷凍効果を向上させることができる。これにより、上記冷凍効果が向上した分だけ、上記冷媒回路(10)における冷媒の循環量を少なくすることができ、上記圧縮機構(11)の消費電力が低減する。 When the second heat storage heat exchanger (19) is used, the temperature of the refrigerant flowing out from the heat source side heat exchanger (12) can be further lowered, and the refrigeration effect can be improved. Thereby, the circulation amount of the refrigerant in the refrigerant circuit (10) can be reduced by the amount that the refrigeration effect is improved, and the power consumption of the compression mechanism (11) is reduced.
 以上より、第1,第2蓄熱熱交換器(14,19)を設けることで、消費電力を増やさずに冷凍能力を増やすことができる。 From the above, by providing the first and second heat storage heat exchangers (14, 19), the refrigerating capacity can be increased without increasing the power consumption.
 第3の発明は、第1の発明において、上記冷媒回路(10)には、上記蓄熱熱交換器(14)を放熱器として氷蓄熱タンク(2)の冷熱を利用する冷熱利用運転と、上記蓄熱熱交換器(14)を蒸発器として氷蓄熱タンク(2)に冷熱を蓄熱する蓄熱運転とに切換可能な切換機構(SV)が設けられていることを特徴としている。 According to a third aspect of the present invention, in the first aspect, the refrigerant circuit (10) includes a cold heat operation using the cold heat of the ice heat storage tank (2) by using the heat storage heat exchanger (14) as a radiator, The heat storage heat exchanger (14) is used as an evaporator, and an ice storage tank (2) is provided with a switching mechanism (SV) that can be switched to a heat storage operation for storing cold energy.
 第3の発明では、上記冷媒回路(10)に上記切換機構(SV)を設けることにより、上記冷凍装置に冷熱利用運転と蓄熱運転とを行わせることができる。 In the third invention, by providing the switching mechanism (SV) in the refrigerant circuit (10), it is possible to cause the refrigeration apparatus to perform a cold energy use operation and a heat storage operation.
 上記蓄熱運転の場合には、上記蓄熱熱交換器(14)が蒸発器となるように上記切換機構(SV)を切り換える。すると、上記蓄熱熱交換器(14)において、上記氷蓄熱タンク(2)内に貯留された水が上記冷媒回路(10)の冷媒で冷却されて、該水から氷が生成される。このようにして、冷媒の冷熱を蓄えることができる。 In the case of the heat storage operation, the switching mechanism (SV) is switched so that the heat storage heat exchanger (14) becomes an evaporator. Then, in the heat storage heat exchanger (14), water stored in the ice heat storage tank (2) is cooled by the refrigerant in the refrigerant circuit (10), and ice is generated from the water. In this way, the cold energy of the refrigerant can be stored.
 一方、上記冷熱利用運転の場合には、上記蓄熱熱交換器(14)が放熱器となるように上記切換機構(SV)を切り換える。すると、上述した蓄熱運転で生成された氷を利用して上記冷媒回路(10)を流れる冷媒を放熱させることができる。 On the other hand, in the case of the operation using cold energy, the switching mechanism (SV) is switched so that the heat storage heat exchanger (14) becomes a radiator. Then, the refrigerant | coolant which flows through the said refrigerant circuit (10) can be radiated using the ice produced | generated by the heat storage operation mentioned above.
 第4の発明は、第3の発明において、上記冷媒回路(10)は、上記冷熱利用運転時には上記低段側圧縮機(11a)又は上記高段側圧縮機(11b)を起動するように構成されていることを特徴としている。 According to a fourth aspect, in the third aspect, the refrigerant circuit (10) is configured to start the low-stage compressor (11a) or the high-stage compressor (11b) during the cold heat operation. It is characterized by being.
 第4の発明では、上記冷熱利用運転時には、上記低段側圧縮機(11a)又は上記高段側圧縮機(11b)のみが起動する。そして、その起動した圧縮機から吐出した冷媒が上記蓄熱熱交換器(14)で放熱し、上記膨張機構(15)で所定圧力まで減圧された後で利用側熱交換器(16)で蒸発する。上記利用側熱交換器(16)で蒸発した冷媒は、起動した圧縮機に吸入された後、圧縮されて再びその圧縮機(11b)から吐出される。 In the fourth aspect of the invention, only the low-stage side compressor (11a) or the high-stage side compressor (11b) is activated during the cold utilization operation. Then, the refrigerant discharged from the activated compressor dissipates heat in the heat storage heat exchanger (14), and after being depressurized to a predetermined pressure by the expansion mechanism (15), evaporates in the use side heat exchanger (16). . The refrigerant evaporated in the use side heat exchanger (16) is sucked into the activated compressor, is compressed, and is discharged from the compressor (11b) again.
 第5の発明は、第1の発明において、上記冷媒回路(10)を流れる冷媒が二酸化炭素であることを特徴としている。 The fifth invention is characterized in that, in the first invention, the refrigerant flowing through the refrigerant circuit (10) is carbon dioxide.
 第5の発明では、上記冷媒回路(10)を流れる冷媒を二酸化炭素を用いている。この二酸化炭素と現行のHFC系冷媒とを比較すると、二酸化炭素の方が、飽和圧力が下がるほど潜熱が大きくなり、冷媒密度も大きくなる。従って、上記二酸化炭素を用いることで上記冷凍装置の蓄熱運転時の能力をアップすることができる。 In the fifth invention, carbon dioxide is used as the refrigerant flowing through the refrigerant circuit (10). When this carbon dioxide is compared with the current HFC-based refrigerant, the latent heat increases and the refrigerant density increases as the saturation pressure decreases. Therefore, the capacity | capacitance at the time of the thermal storage driving | operation of the said freezing apparatus can be improved by using the said carbon dioxide.
 本発明によれば、超臨界冷凍サイクルを行う冷媒回路(10)の冷媒を上記蓄熱熱交換器(14)の氷に放熱させることができる。上記冷媒が氷に放熱することで、その冷媒の温度を大きく下げることができる。圧縮機構(11)の消費電力量を増加させずに従来の冷凍装置の冷凍能力に近づけることができる。 According to the present invention, the refrigerant in the refrigerant circuit (10) performing the supercritical refrigeration cycle can be radiated to the ice of the heat storage heat exchanger (14). When the refrigerant dissipates heat to ice, the temperature of the refrigerant can be greatly reduced. The refrigeration capacity of the conventional refrigeration apparatus can be approached without increasing the power consumption of the compression mechanism (11).
 また、本発明によれば、上記圧縮機構(11)に二段圧縮を行わせるとともに、上記低段側圧縮機(11a)から吐出された冷媒を上記蓄熱熱交換器(14)で冷却してから上記高段側圧縮機(11b)に吸入させることができる。こうすると、単段圧縮の圧縮機構(11)と第2の発明の圧縮機構(11)とが同じ消費電力とした場合、上記単段圧縮の圧縮機構(11)を有する冷凍装置よりも、第1の発明の圧縮機構(11)を有する冷凍装置の冷凍能力が大きいこととなる。つまり、消費電力を増やさずに冷凍能力を増やすことができる。 Further, according to the present invention, the compression mechanism (11) performs two-stage compression, and the refrigerant discharged from the low-stage compressor (11a) is cooled by the heat storage heat exchanger (14). To the high-stage compressor (11b). Thus, when the compression mechanism (11) of the single-stage compression and the compression mechanism (11) of the second invention have the same power consumption, the first-stage compression mechanism (11) is more than the refrigeration apparatus having the single-stage compression mechanism (11). The refrigerating capacity of the refrigerating apparatus having the compression mechanism (11) of the first invention will be large. That is, the refrigerating capacity can be increased without increasing the power consumption.
 以上より、上記熱源側熱交換器(12)とは別の放熱手段である上記蓄熱熱交換器(14)を設けることにより、圧縮機構(11)の消費電力量を増加させずに、上記冷凍装置の冷凍能力を従来の冷凍装置の冷凍能力に近づけることができる。 As described above, by providing the heat storage heat exchanger (14), which is a heat dissipating means different from the heat source side heat exchanger (12), the refrigeration can be performed without increasing the power consumption of the compression mechanism (11). The refrigeration capacity of the apparatus can be brought close to the refrigeration capacity of a conventional refrigeration apparatus.
 また、上記第2の発明によれば、上記圧縮機構(11)に二段圧縮を行わせるとともに、上記低段側圧縮機(11a)から吐出された冷媒を上記第1蓄熱熱交換器(14)で冷却している。こうすると、第1の発明と同様に消費電力を増やさずに冷凍能力を増やすことができる。 According to the second aspect of the invention, the compression mechanism (11) performs two-stage compression, and the refrigerant discharged from the low-stage compressor (11a) is transferred to the first heat storage heat exchanger (14 ). If it carries out like this, refrigerating capacity can be increased, without increasing power consumption similarly to 1st invention.
 又、上記第2蓄熱熱交換器(19)を設けることで、上記熱源側熱交換器(12)から流出した冷媒の温度をさらに下げることができ、上記冷凍効果を向上させることができる。これにより、上記冷凍効果が向上した分だけ、上記冷媒回路(10)における冷媒の循環量を少なくすることができ、上記圧縮機構(11)の消費電力を低減することができる。 Also, by providing the second heat storage heat exchanger (19), the temperature of the refrigerant flowing out from the heat source side heat exchanger (12) can be further lowered, and the refrigeration effect can be improved. As a result, the amount of refrigerant circulating in the refrigerant circuit (10) can be reduced by an amount corresponding to the improved refrigeration effect, and the power consumption of the compression mechanism (11) can be reduced.
 以上より、上記熱源側熱交換器(12)とは別の放熱手段である上記第1,第2蓄熱熱交換器(14,19)を設けることにより、圧縮機構(11)の消費電力量を増加させずに従来の冷凍装置の冷凍能力に近づけることができる。 As described above, by providing the first and second heat storage heat exchangers (14, 19), which are heat dissipating means different from the heat source side heat exchanger (12), the power consumption of the compression mechanism (11) can be reduced. It is possible to approach the refrigeration capacity of the conventional refrigeration apparatus without increasing it.
 また、上記第3の発明によれば、例えば、上記冷凍装置において、比較的に安価な夜間電力を利用して上記蓄熱運転を行い、上記氷蓄熱タンク(2)に冷媒の冷熱を蓄えておく。そして、昼間の冷熱利用運転時にその生成した氷を利用することで昼間の消費電力を抑えることができる。つまり、昼間電力のピークシフトを行うことを可能にしつつ、圧縮機構(11)の消費電力量を増加させずに従来の冷凍装置の冷凍能力に近づけることができる。 According to the third aspect of the invention, for example, in the refrigeration apparatus, the heat storage operation is performed by using relatively inexpensive nighttime electric power, and the cold heat of the refrigerant is stored in the ice heat storage tank (2). . And the power consumption in the daytime can be suppressed by using the generated ice during the daytime cold energy utilization operation. That is, it is possible to make the peak power shift of the daytime power and to approach the refrigeration capacity of the conventional refrigeration apparatus without increasing the power consumption of the compression mechanism (11).
 また、上記第4の発明によれば、上記冷熱利用運転時に、上記低段側圧縮機(11a)又は上記高段側圧縮機(11b)のみを起動させている。こうすると、上記低段側圧縮機(11a)及び上記高段側圧縮機(11b)の両方を起動する場合に比べて、上記圧縮機構(11)の消費電力量を低減することができる。 In addition, according to the fourth aspect of the invention, only the low-stage compressor (11a) or the high-stage compressor (11b) is activated during the cold utilization operation. If it carries out like this, the power consumption of the said compression mechanism (11) can be reduced compared with the case where both the said low stage side compressor (11a) and the said high stage side compressor (11b) are started.
 また、上記第5の発明によれば、上記冷媒回路(10)を流れる冷媒に二酸化炭素を用いることにより、現行のHFC系冷媒に比べて、上記冷凍装置の蓄熱運転時の能力をアップすることができる。 According to the fifth aspect of the invention, by using carbon dioxide as the refrigerant flowing through the refrigerant circuit (10), the capacity of the refrigeration apparatus during heat storage operation can be increased compared to the current HFC refrigerant. Can do.
図1は、本発明の空気調和装置(冷凍装置)の全体図である。FIG. 1 is an overall view of an air conditioning apparatus (refrigeration apparatus) according to the present invention. 図2は、本発明の実施形態1に係る空気調和装置の冷媒回路図である。FIG. 2 is a refrigerant circuit diagram of the air-conditioning apparatus according to Embodiment 1 of the present invention. 図3は、実施形態1に係る蓄熱運転時の動作を示す冷媒回路図である。FIG. 3 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the first embodiment. 図4は、実施形態1に係る冷熱利用運転時の動作を示す冷媒回路図であり、図4(A)は第1の冷熱利用運転を示し、図4(B)は第2の冷熱利用運転を示している。FIG. 4 is a refrigerant circuit diagram illustrating an operation at the time of cold energy utilization operation according to the first embodiment, FIG. 4 (A) illustrates a first cold energy utilization operation, and FIG. 4 (B) is a second cold energy utilization operation. Is shown. 図5は、実施形態1に係る冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 5 is a diagram showing a refrigeration cycle performed by the refrigerant circuit according to the first embodiment on a Ph diagram. 図6は、実施形態1の変形例1に係る空気調和装置の冷媒回路図である。FIG. 6 is a refrigerant circuit diagram of an air-conditioning apparatus according to Modification 1 of Embodiment 1. 図7は、実施形態1の変形例1に係る蓄熱運転時の動作を示す冷媒回路図である。FIG. 7 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the first modification of the first embodiment. 図8は、実施形態1の変形例1に係る冷熱利用運転時の動作を示す冷媒回路図である。FIG. 8 is a refrigerant circuit diagram illustrating an operation at the time of cold utilization operation according to the first modification of the first embodiment. 図9は、実施形態1の変形例1に係る冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 9 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the first modification of the first embodiment on a Ph diagram. 図10は、実施形態1の変形例2に係る空気調和装置の冷媒回路図である。FIG. 10 is a refrigerant circuit diagram of an air-conditioning apparatus according to Modification 2 of Embodiment 1. 図11は、実施形態1の変形例2に係る蓄熱運転時の動作を示す冷媒回路図である。FIG. 11 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the second modification of the first embodiment. 図12は、実施形態1の変形例2に係る冷熱利用運転時の動作を示す冷媒回路図である。FIG. 12 is a refrigerant circuit diagram illustrating an operation at the time of the cold energy use operation according to the second modification of the first embodiment. 図13は、実施形態1の変形例2に係る冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 13 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the second modification of the first embodiment on a Ph diagram. 図14は、本発明の実施形態2に係る空気調和装置の冷媒回路図である。FIG. 14 is a refrigerant circuit diagram of the air-conditioning apparatus according to Embodiment 2 of the present invention. 図15は、実施形態2に係る蓄熱運転時の動作を示す冷媒回路図である。FIG. 15 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the second embodiment. 図16は、実施形態2に係る冷熱利用運転時の動作を示す冷媒回路図である。FIG. 16 is a refrigerant circuit diagram illustrating an operation during a cold energy utilization operation according to the second embodiment. 図17は、実施形態2に係る冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 17 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the second embodiment on a Ph diagram. 図18は、本発明の実施形態3に係る空気調和装置の冷媒回路図である。FIG. 18 is a refrigerant circuit diagram of the air-conditioning apparatus according to Embodiment 3 of the present invention. 図19は、実施形態3に係る蓄熱運転時の動作を示す冷媒回路図である。FIG. 19 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to the third embodiment. 図20は、実施形態3に係る冷熱利用運転時の動作を示す冷媒回路図である。FIG. 20 is a refrigerant circuit diagram illustrating an operation at the time of the cold energy utilization operation according to the third embodiment. 図21は、実施形態3に係る冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 21 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the third embodiment on a Ph diagram. 図22は、実施形態3の変形例に係る空気調和装置の冷媒回路図である。FIG. 22 is a refrigerant circuit diagram of an air-conditioning apparatus according to a modification of the third embodiment. 図23は、実施形態3の変形例に係る蓄熱運転時の動作を示す冷媒回路図である。FIG. 23 is a refrigerant circuit diagram illustrating an operation during a heat storage operation according to a modification of the third embodiment. 図24は、実施形態3の変形例に係る冷熱利用運転時の動作を示す冷媒回路図である。FIG. 24 is a refrigerant circuit diagram illustrating an operation at the time of cold utilization operation according to a modification of the third embodiment. 図25は、実施形態3の変形例に係る冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 25 is a diagram illustrating a refrigeration cycle performed by the refrigerant circuit according to the modification of the third embodiment on a Ph diagram. 図26は、従来の冷媒回路が行う冷凍サイクルをP-h線図上に示した図である。FIG. 26 is a diagram showing a refrigeration cycle performed by a conventional refrigerant circuit on a Ph diagram.
 以下、本発明の実施形態を図面に基づいて詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
 《発明の実施形態1》
 《実施形態1》
 図1は実施形態1の空気調和装置(冷凍装置)(1)の全体図である。図2は実施形態1に係る上記空気調和装置(1)の冷媒回路図であり、図3は蓄熱運転時の冷媒の流れを示し、図4は冷熱利用運転時の冷媒の流れを示している。図5は二酸化炭素のP-h線図上に冷熱利用運転時の冷凍サイクルを示した図である。
Embodiment 1 of the Invention
Embodiment 1
FIG. 1 is an overall view of an air conditioning apparatus (refrigeration apparatus) (1) according to a first embodiment. 2 is a refrigerant circuit diagram of the air conditioner (1) according to the first embodiment, FIG. 3 shows a refrigerant flow during a heat storage operation, and FIG. 4 shows a refrigerant flow during a cold heat operation. . FIG. 5 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
 実施形態1の空気調和装置(1)は、屋外に設置された氷蓄熱タンク(2)及び室外機(3)と、室内に設置された室内機(4)とを備えている。そして、これらの機器(2,3,4)が互いに連絡配管で接続されることにより、図2に示す冷媒回路(10)が構成される。尚、この冷媒回路(10)には、冷媒として二酸化炭素(以下、冷媒という。)が充填されている。又、上記冷媒回路(10)の高圧圧力が二酸化炭素の臨界圧力以上に設定されている。 The air conditioner (1) of Embodiment 1 includes an ice heat storage tank (2) and an outdoor unit (3) installed outdoors, and an indoor unit (4) installed indoors. And these apparatuses (2, 3, and 4) are mutually connected by connection piping, and the refrigerant circuit (10) shown in FIG. 2 is comprised. The refrigerant circuit (10) is filled with carbon dioxide (hereinafter referred to as refrigerant) as a refrigerant. The high pressure of the refrigerant circuit (10) is set to be higher than the critical pressure of carbon dioxide.
 又、上記空気調和装置(1)は、その運転動作が蓄熱運転及び冷熱利用運転に切換可能に構成されている。例えば、蓄熱運転時に夜間電力を利用して氷蓄熱タンク(2)内の水から氷を生成し、昼間の冷熱利用運転時にその生成した氷を利用することにより、上記空気調和装置(1)における昼間の消費電力を抑えることができる。この蓄熱運転と冷熱利用運転については、詳しく後述する。 In addition, the air conditioner (1) is configured such that its operation can be switched between a heat storage operation and a cold energy operation. For example, in the air conditioner (1), by generating ice from the water in the ice storage tank (2) using the nighttime electricity during the heat storage operation and using the generated ice during the daytime cold energy operation, Power consumption during the daytime can be reduced. The heat storage operation and the cold energy utilization operation will be described later in detail.
 上記冷媒回路(10)には、高段側圧縮機(11b)と低段側圧縮機(11a)と室外熱交換器(熱源側熱交換器)(12)と第1及び第2膨張弁(膨張機構)(15b,15c)と減圧弁(15a)と室内熱交換器(利用側熱交換器)(16)と過冷却熱交換器(18)と蓄熱熱交換器(14)とが設けられている。又、上記冷媒回路(10)には、上記空気調和装置(1)の運転を蓄熱運転及び冷熱利用運転に切り換えるための開閉弁(切換機構)(SV)が設けられている。 The refrigerant circuit (10) includes a high stage compressor (11b), a low stage compressor (11a), an outdoor heat exchanger (heat source side heat exchanger) (12), and first and second expansion valves ( Expansion mechanism) (15b, 15c), pressure reducing valve (15a), indoor heat exchanger (use side heat exchanger) (16), supercooling heat exchanger (18), and heat storage heat exchanger (14) ing. Further, the refrigerant circuit (10) is provided with an on-off valve (switching mechanism) (SV) for switching the operation of the air conditioner (1) between the heat storage operation and the cold energy utilization operation.
 上記高段側圧縮機(11b)及び上記低段側圧縮機(11a)は、いずれもいわゆる全密閉型に構成され、圧縮機構(11)を構成している。又、各圧縮機(11a,11b)にはそれぞれ図示しないインバータが接続されており、このインバータにより、各圧縮機(11a,11b)は容量可変に構成されている。 The high-stage compressor (11b) and the low-stage compressor (11a) are both configured as a so-called hermetic type and constitute a compression mechanism (11). In addition, an inverter (not shown) is connected to each compressor (11a, 11b), and each compressor (11a, 11b) is configured to have a variable capacity by this inverter.
 上記室外熱交換器(12)及び上記室内熱交換器(16)は、いずれもクロスフィン式のフィン・アンド・チューブ型熱交換器で構成されている。又、上記室外熱交換器(12)の近傍には室外ファン(図示なし)が設けられ、上記室内熱交換器(16)の近傍には室内ファン(図示なし)が設けられている。そして、上記室外熱交換器(12)は、上記室外ファンから送られる室外空気と上記室外熱交換器(12)を流れる冷媒とが熱交換するように構成されている。又、上記室内熱交換器(16)は、上記室内ファンから送られる室内空気と上記室内熱交換器(16)を流れる冷媒とが熱交換するように構成されている。 Both the outdoor heat exchanger (12) and the indoor heat exchanger (16) are cross fin type fin-and-tube heat exchangers. An outdoor fan (not shown) is provided in the vicinity of the outdoor heat exchanger (12), and an indoor fan (not shown) is provided in the vicinity of the indoor heat exchanger (16). The outdoor heat exchanger (12) is configured to exchange heat between the outdoor air sent from the outdoor fan and the refrigerant flowing through the outdoor heat exchanger (12). The indoor heat exchanger (16) is configured to exchange heat between indoor air sent from the indoor fan and refrigerant flowing through the indoor heat exchanger (16).
 上記第1、第2膨張弁(15b,15c)及び減圧弁(15a)は、いずれも開度が調節可能な電子膨張弁で構成されている。上記第1から第4開閉弁(SV1,SV2,SV3,SV4)は、開度が全開及び全閉の何れか一方に設定可能な電磁弁で構成されている。 The first and second expansion valves (15b, 15c) and the pressure reducing valve (15a) are both electronic expansion valves whose opening degrees can be adjusted. The first to fourth on-off valves (SV1, SV2, SV3, SV4) are composed of solenoid valves whose opening degree can be set to either full open or full close.
 上記過冷却熱交換器(18)は、高温側通路と低温側通路とを備え、高温側通路を通過する冷媒と低温側通路を通過する冷媒とが熱交換するように構成されている。 The supercooling heat exchanger (18) includes a high temperature side passage and a low temperature side passage, and is configured to exchange heat between the refrigerant passing through the high temperature side passage and the refrigerant passing through the low temperature side passage.
 上記蓄熱熱交換器(14)は、上記氷蓄熱タンク(2)に収容されており、上下に蛇行する複数の伝熱管によって構成されている。そして、この蛇行する伝熱管を流れる冷媒と上記氷蓄熱タンク(2)内に貯蔵された蓄熱媒体としての水又は氷とが熱交換するように構成されている。 The heat storage heat exchanger (14) is housed in the ice heat storage tank (2), and includes a plurality of heat transfer tubes meandering up and down. The refrigerant flowing through the meandering heat transfer tube and the water or ice as the heat storage medium stored in the ice heat storage tank (2) are configured to exchange heat.
 上記低段側圧縮機(11a)の吐出側から延びる冷媒配管の端部は分岐して第1及び第2分岐配管(20,21)の一端に接続されている。各分岐配管(20,21)の他端は合流して上記高段側圧縮機(11b)の吸入側に接続されている。上記第1分岐配管(20)には上記第1開閉弁(SV1)が設けられている。上記第2分岐配管(21)には、低段側圧縮機(11a)から高段側圧縮機(11b)に向かって順に第3開閉弁(SV3)と上記蓄熱熱交換器(14)と第4開閉弁(SV4)が設けられている。 The end of the refrigerant pipe extending from the discharge side of the low-stage compressor (11a) is branched and connected to one end of the first and second branch pipes (20, 21). The other ends of the branch pipes (20, 21) merge and are connected to the suction side of the high-stage compressor (11b). The first branch pipe (20) is provided with the first on-off valve (SV1). The second branch pipe (21) includes a third on-off valve (SV3), the heat storage heat exchanger (14), and a second heat exchanger in order from the low stage compressor (11a) to the high stage compressor (11b). A 4 on-off valve (SV4) is provided.
 上記高段側圧縮機(11b)の吐出側から延びる冷媒配管は上記室外熱交換器(12)の一端に接続されている。上記室外熱交換器(12)の他端から延びる冷媒配管は分岐して、一方が減圧弁(15a)を介して上記過冷却熱交換器(18)の低温側通路の入口側に接続され、他方が上記過冷却熱交換器(18)の高温側通路の入口側に接続されている。 The refrigerant pipe extending from the discharge side of the high stage compressor (11b) is connected to one end of the outdoor heat exchanger (12). The refrigerant pipe extending from the other end of the outdoor heat exchanger (12) branches, and one is connected to the inlet side of the low temperature side passage of the supercooling heat exchanger (18) via the pressure reducing valve (15a), The other is connected to the inlet side of the high temperature side passage of the supercooling heat exchanger (18).
 上記過冷却熱交換器(18)の低温側通路の出口側から延びる冷媒配管は上記第1分岐配管(20)における上記高段側圧縮機(11b)と上記第1開閉弁(SV1)との間と連通している。一方、上記過冷却熱交換器(18)の高温側通路の出口側から延びる冷媒配管は分岐して、一方が第1膨張弁(15b)を介して上記室内熱交換器(16)の一端に接続され、他方は第2膨張弁(15c)を介して上記第2分岐配管(21)における蓄熱熱交換器(14)と上記第4開閉弁(SV4)との間と連通している。 The refrigerant pipe extending from the outlet side of the low temperature side passage of the supercooling heat exchanger (18) is formed between the high stage compressor (11b) and the first on-off valve (SV1) in the first branch pipe (20). Communicate with each other. On the other hand, the refrigerant pipe extending from the outlet side of the high temperature side passage of the supercooling heat exchanger (18) branches, and one of the refrigerant pipes is connected to one end of the indoor heat exchanger (16) via the first expansion valve (15b). The other is connected to between the heat storage heat exchanger (14) and the fourth on-off valve (SV4) in the second branch pipe (21) via the second expansion valve (15c).
 上記室内熱交換器(16)の他端から延びる冷媒配管は分岐して、一方が上記低段側圧縮機(11a)の吸入側に接続され、他方が第2開閉弁(SV2)を介して上記第2分岐配管(21)における第3開閉弁(SV3)及び上記蓄熱熱交換器(14)の間と連通している。 The refrigerant pipe extending from the other end of the indoor heat exchanger (16) branches, one is connected to the suction side of the low-stage compressor (11a), and the other is connected via the second on-off valve (SV2). The second branch pipe (21) communicates with the third on-off valve (SV3) and the heat storage heat exchanger (14).
  -運転動作-
 次に、上記空気調和装置(1)の運転動作について説明する。上記空気調和装置(1)は、上述したように蓄熱運転と冷熱利用運転とが切換可能に構成されている。
-Driving operation-
Next, the operation of the air conditioner (1) will be described. As described above, the air conditioner (1) is configured to be able to switch between a heat storage operation and a cold energy utilization operation.
  〈蓄熱運転〉
 上記蓄熱運転では、夜間の電力で上記低段側圧縮機(11a)と高段側圧縮機(11b)とを起動する一方、上記開閉弁(SV)を切り換えて上記蓄熱熱交換器(14)を蒸発器に設定する。そして、上記冷媒回路(10)を循環する冷媒で上記氷蓄熱タンク(2)の水を冷却して氷にすることにより、冷媒の冷熱を蓄える。
<Heat storage operation>
In the heat storage operation, the low-stage compressor (11a) and the high-stage compressor (11b) are started by nighttime power, while the on-off valve (SV) is switched to store the heat storage heat exchanger (14). To the evaporator. And the cold of a refrigerant | coolant is stored by cooling the water of the said ice thermal storage tank (2) with the refrigerant | coolant which circulates through the said refrigerant | coolant circuit (10), and making it ice.
 上記蓄熱運転では、図3に示すように、上記第1膨張弁(15b)の開度が全閉になり、上記第2膨張弁(15c)及び上記減圧弁(15a)の開度が必要に応じて調整される。又、上記第1開閉弁(SV1)及び上記第2開閉弁(SV2)が開設定となり、上記第3開閉弁(SV3)及び上記第4開閉弁(SV4)が閉設定となる。 In the heat storage operation, as shown in FIG. 3, the opening degree of the first expansion valve (15b) is fully closed, and the opening degree of the second expansion valve (15c) and the pressure reducing valve (15a) is required. Adjusted accordingly. The first on-off valve (SV1) and the second on-off valve (SV2) are set to open, and the third on-off valve (SV3) and the fourth on-off valve (SV4) are set to close.
 上記高段側圧縮機(11b)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する。上記室外熱交換器(12)を流出した高圧冷媒は分流し、一方が上記減圧弁(15a)で減圧されて中間圧冷媒となった後、上記過冷却熱交換器(18)の低温側流路に流入し、他方が上記過冷却熱交換器(18)の高温側流路に流入する。 The supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). To do. The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) is diverted, one of which is depressurized by the pressure reducing valve (15a) to become an intermediate pressure refrigerant, and then the low-temperature side stream of the supercooling heat exchanger (18) The other flows into the channel, and the other flows into the high-temperature channel of the supercooling heat exchanger (18).
 上記過冷却熱交換器(18)では、上記高温側流路の高圧冷媒と上記低温側流路の中間圧冷媒とが熱交換する。上記高圧冷媒は上記中間圧冷媒に放熱して冷却されて、上記高温側流路を流出する。一方、上記中間圧冷媒は上記高圧冷媒から吸熱して中間圧のガス冷媒となり、上記低温側流路を流出する。 In the supercooling heat exchanger (18), the high-pressure refrigerant in the high-temperature side channel and the intermediate-pressure refrigerant in the low-temperature side channel exchange heat. The high-pressure refrigerant dissipates heat to the intermediate-pressure refrigerant and is cooled, and flows out of the high-temperature side flow path. On the other hand, the intermediate-pressure refrigerant absorbs heat from the high-pressure refrigerant to become an intermediate-pressure gas refrigerant, and flows out from the low-temperature side flow path.
 上記過冷却熱交換器(18)の低温側流路を流出した中間圧冷媒は、上記高段側圧縮機(11b)の吸入側へ流れる。 The intermediate-pressure refrigerant that has flowed out of the low-temperature channel of the supercooling heat exchanger (18) flows to the suction side of the high-stage compressor (11b).
 上記過冷却熱交換器(18)の高温側流路を流出した高圧冷媒は、上記第2膨張弁(15c)で所定の圧力まで減圧されて二相状態の低圧冷媒となった後、上記蓄熱熱交換器(14)に流入する。上記蓄熱熱交換器(14)では、低圧冷媒と上記氷蓄熱タンク(2)内の水とが熱交換して、該氷蓄熱タンク(2)内の水が冷却されて氷になる。一方、上記氷蓄熱タンク(2)内の水から吸熱した低圧冷媒は低圧ガス冷媒となり、該蓄熱熱交換器(14)を流出する。 The high-pressure refrigerant that has flowed out of the high-temperature channel of the supercooling heat exchanger (18) is reduced to a predetermined pressure by the second expansion valve (15c) to become a low-pressure refrigerant in a two-phase state, and then the heat storage It flows into the heat exchanger (14). In the heat storage heat exchanger (14), the low-pressure refrigerant and the water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice. On the other hand, the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)を流出した低圧ガス冷媒は、第2開閉弁(SV2)を経て、上記低段側圧縮機(11a)に吸入されて所定の圧力まで圧縮されて中間圧ガス冷媒となった後、該低段側圧縮機(11a)から吐出される。上記低段側圧縮機(11a)から吐出された中間圧ガス冷媒は、上記第1開閉弁(SV1)を経て、上記過冷却熱交換器(18)の低温側流路から流出した中間圧ガス冷媒と合流した後、上記高段側圧縮機(11b)に吸入される。 The low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the second on-off valve (SV2), is sucked into the low-stage compressor (11a), and is compressed to a predetermined pressure to be intermediate-pressure gas refrigerant. After that, the low-stage compressor (11a) is discharged. The intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) passes through the first on-off valve (SV1) and flows out from the low-temperature side passage of the supercooling heat exchanger (18). After joining the refrigerant, the refrigerant is sucked into the high stage compressor (11b).
 上記高段側圧縮機(11b)に吸入された中間圧ガス冷媒は、臨界圧力以上まで圧縮されて高圧冷媒となった後、上記高段側圧縮機(11b)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において蓄熱運転が行われる。 The intermediate-pressure gas refrigerant sucked into the high-stage compressor (11b) is compressed to a critical pressure or higher to become a high-pressure refrigerant, and then discharged from the high-stage compressor (11b). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  〈冷熱利用運転〉
 (第1冷熱利用運転)
 第1の冷熱利用運転では、昼間の電力で上記低段側圧縮機(11a)と高段側圧縮機(11b)とを起動する一方、上記開閉弁(SV)を切り換えて上記蓄熱熱交換器(14)を放熱器に設定する。そして、上記蓄熱運転で上記氷蓄熱タンク(2)内に蓄えた冷熱を利用して、上記冷媒回路(10)を流れる冷媒を放熱させる。
<Cryogenic operation>
(First cold utilization operation)
In the first cold energy utilization operation, the low-stage compressor (11a) and the high-stage compressor (11b) are started by daytime power, and the on-off valve (SV) is switched to switch the heat storage heat exchanger. Set (14) as a radiator. And the refrigerant | coolant which flows through the said refrigerant circuit (10) is radiated using the cold energy stored in the said ice thermal storage tank (2) by the said thermal storage driving | operation.
 上記冷熱利用運転では、図4(A)に示すように、上記第2膨張弁(15c)及び上記減圧弁(15a)の開度が全閉になり、上記第1膨張弁(15b)の開度が必要に応じて調整される。又、上記第3開閉弁(SV3)及び上記第4開閉弁(SV4)が開設定となり、上記第1開閉弁(SV1)及び上記第2開閉弁(SV2)が閉設定となる。 In the cold energy utilization operation, as shown in FIG. 4A, the opening degrees of the second expansion valve (15c) and the pressure reducing valve (15a) are fully closed, and the first expansion valve (15b) is opened. The degree is adjusted as necessary. The third on-off valve (SV3) and the fourth on-off valve (SV4) are set to open, and the first on-off valve (SV1) and the second on-off valve (SV2) are set to close.
 上記高段側圧縮機(11b)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する(図4(A),図5の点c)。上記室外熱交換器(12)を流出した高圧冷媒は、上記過冷却熱交換器(18)を熱交換することなく通過し、上記第1膨張弁(15b)に流入する。 The supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). (FIG. 4 (A), point c in FIG. 5). The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) passes through the supercooling heat exchanger (18) without exchanging heat, and flows into the first expansion valve (15b).
 上記第1膨張弁(15b)に流入した高圧冷媒は、所定の圧力まで減圧されて二相状態の低圧冷媒となり、該第1膨張弁(15b)を流出する(図4(A),図5の点d)。上記第1膨張弁(15b)を流出した低圧冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱して低圧ガス冷媒となった後、該室内熱交換器(16)から流出する(図4(A),図5の点a)。上記室内空気は、該室内空気の熱を上記低圧ガス冷媒に吸収させることにより冷却される。 The high-pressure refrigerant that has flowed into the first expansion valve (15b) is depressurized to a predetermined pressure to become a two-phase low-pressure refrigerant, and flows out of the first expansion valve (15b) (FIGS. 4A and 5). Point d). The low-pressure refrigerant that has flowed out of the first expansion valve (15b) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then enters the indoor heat exchanger (16). It flows out (point a in FIG. 4 (A) and FIG. 5). The indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した低圧ガス冷媒は、上記低段側圧縮機(11a)に吸入され、所定の圧力まで圧縮されて中間圧ガス冷媒となった後、該低段側圧縮機(11a)から吐出される(図4(A),図5の点a1)。上記低段側圧縮機(11a)から吐出された中間圧ガス冷媒は、第3開閉弁(SV3)を経て、上記蓄熱熱交換器(14)に流入する。 The low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed to a predetermined pressure to become an intermediate-pressure gas refrigerant. It is discharged from the machine (11a) (FIG. 4 (A), point a1 in FIG. 5). The intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) flows into the heat storage heat exchanger (14) through the third on-off valve (SV3).
 上記蓄熱熱交換器(14)では、中間圧ガス冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記中間圧ガス冷媒は上記氷蓄熱タンク(2)内の氷に放熱して冷却されて、該蓄熱熱交換器(14)を流出する(図4(A),図5の点a2)。 In the heat storage heat exchanger (14), the intermediate pressure gas refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water. On the other hand, the intermediate pressure gas refrigerant dissipates heat to the ice in the ice heat storage tank (2), is cooled, and flows out of the heat storage heat exchanger (14) (point a2 in FIGS. 4A and 5). .
 上記蓄熱熱交換器(14)を流出した中間圧ガス冷媒は、上記高段側圧縮機(11b)に吸入され、臨界圧力以上まで圧縮されて高圧冷媒となった後、上記高段側圧縮機(11b)から吐出される(図4(A),図5の点b)。このように冷媒が循環することにより、空気調和装置(1)において冷熱利用運転が行われる。 The intermediate-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) is sucked into the high-stage compressor (11b), compressed to a critical pressure or higher to become a high-pressure refrigerant, and then the high-stage compressor (11b) is discharged (point b in FIGS. 4A and 5). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
 (第2冷熱利用運転)
 第2の冷熱利用運転では、図4(B)において、第3開閉弁(SV3)が開設定となり、第1膨張弁(15b)及び第2膨張弁(15c)の少なくとも一方の開度が必要に応じて調整される。又、第1開閉弁(SV1),第2開閉弁(SV2)及び第4開閉弁(SV4)が閉設定となり、減圧弁(15a)の開度が全閉になる。このとき、低段側圧縮機(11a)は運転され、高段側圧縮機(11b)は停止状態となる。
(Second cold energy operation)
In the second cold energy utilization operation, in FIG. 4B, the third on-off valve (SV3) is set to open, and the opening degree of at least one of the first expansion valve (15b) and the second expansion valve (15c) is required. Will be adjusted according to. Further, the first on-off valve (SV1), the second on-off valve (SV2), and the fourth on-off valve (SV4) are set to be closed, and the opening of the pressure reducing valve (15a) is fully closed. At this time, the low stage compressor (11a) is operated, and the high stage compressor (11b) is stopped.
 この状態で、低段側圧縮機(11a)から吐出された高圧冷媒は、上記蓄熱熱交換器(14)に流入する。上記蓄熱熱交換器(14)では、高圧冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記中間圧ガス冷媒は上記氷蓄熱タンク(2)内の氷に放熱して冷却されて、該蓄熱熱交換器(14)を流出する。 In this state, the high-pressure refrigerant discharged from the low-stage compressor (11a) flows into the heat storage heat exchanger (14). In the heat storage heat exchanger (14), the high-pressure refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water. On the other hand, the intermediate pressure gas refrigerant dissipates heat to the ice in the ice heat storage tank (2), is cooled, and flows out of the heat storage heat exchanger (14).
 冷媒は、次に、第1膨張弁(15b)及び第2膨張弁(15c)を通過するときに所定の圧力まで減圧されて二相状態の低圧冷媒となり、第1膨張弁(15b)を流出する。上記第1膨張弁(15b)を流出した低圧冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱して低圧ガス冷媒となった後、該室内熱交換器(16)から流出する。上記室内空気は、該室内空気の熱を上記低圧ガス冷媒に吸収させることにより冷却される。 Next, when the refrigerant passes through the first expansion valve (15b) and the second expansion valve (15c), the refrigerant is depressurized to a predetermined pressure to become a two-phase low-pressure refrigerant, and flows out of the first expansion valve (15b). To do. The low-pressure refrigerant that has flowed out of the first expansion valve (15b) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then enters the indoor heat exchanger (16). leak. The indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した低圧ガス冷媒は、上記低段側圧縮機(11a)に吸入され、所定の圧力まで圧縮されて高圧冷媒となった後、該低段側圧縮機(11a)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において第2の冷熱利用運転が行われる。 The low-pressure gas refrigerant flowing out from the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed to a predetermined pressure to become a high-pressure refrigerant, and then the low-stage compressor (11a) Discharged from 11a). As the refrigerant circulates in this way, the second cold energy utilization operation is performed in the air conditioner (1).
 なお、図4(B)の例では、低段側圧縮機(11a)を起動し、高段側圧縮機(11b)を停止するようにしているが、第2の冷熱利用運転時に低段側圧縮機(11a)を停止し、高段側圧縮機(11b)を運転するように冷媒回路(10)の回路構成を変更してもよい。このように冷熱利用運転時に低段側圧縮機(11a)と高段側圧縮機(11b)の一方のみを起動するようにすると、蓄熱運転時に比べて、冷熱利用運転時の冷媒搬送動力を低減することができる。従って、圧縮機構の消費電力を低減できる。 In the example of FIG. 4B, the low-stage compressor (11a) is started and the high-stage compressor (11b) is stopped. The circuit configuration of the refrigerant circuit (10) may be changed so that the compressor (11a) is stopped and the high-stage compressor (11b) is operated. When only one of the low-stage compressor (11a) and the high-stage compressor (11b) is activated during the cold energy operation, the refrigerant transport power during the cold energy operation is reduced compared to during the heat storage operation. can do. Therefore, the power consumption of the compression mechanism can be reduced.
  -実施形態1の効果-
 本実施形態1によれば、上記空気調和装置(1)に上記氷蓄熱タンク(2)を設けるとともに、上記冷媒回路(10)に上記第1から第4開閉弁(SV1~SV4)を設けることにより、上記空気調和装置(1)に冷熱利用運転と蓄熱運転とを行わせることができる。
-Effect of Embodiment 1-
According to the first embodiment, the ice storage tank (2) is provided in the air conditioner (1), and the first to fourth on-off valves (SV1 to SV4) are provided in the refrigerant circuit (10). Thus, the air conditioner (1) can perform the cold energy use operation and the heat storage operation.
 又、上記冷熱利用運転に、上記冷媒回路(30)の圧縮機構である上記低段側圧縮機(11a)と高段側圧縮機(11b)に二段圧縮を行わせるとともに、上記低段側圧縮機(11a)から吐出された冷媒を上記蓄熱熱交換器(14)で冷却してから上記高段側圧縮機(11b)に吸入させている。 Also, the low-stage compressor (11a) and the high-stage compressor (11b), which are the compression mechanisms of the refrigerant circuit (30), are allowed to perform two-stage compression in the cold utilization operation, and the low-stage side The refrigerant discharged from the compressor (11a) is cooled by the heat storage heat exchanger (14) and then sucked into the high-stage compressor (11b).
 こうすると、上記冷媒回路(10)の圧縮機構を単段圧縮で構成した場合と実施形態1のように構成した場合とで比較すると、両者が同じ消費電力であれば、上記単段圧縮の圧縮機構(11)を有する冷凍装置よりも、実施形態1の圧縮機構(11)を有する冷凍装置の冷凍能力が大きいこととなる。つまり、消費電力を増やさずに冷凍能力を増やすことができる。 In this way, when the compression mechanism of the refrigerant circuit (10) is configured by single-stage compression and when it is configured as in the first embodiment, if the power consumption is the same, the compression of the single-stage compression is performed. The refrigerating capacity of the refrigerating apparatus having the compression mechanism (11) of the first embodiment is greater than that of the refrigerating apparatus having the mechanism (11). That is, the refrigerating capacity can be increased without increasing the power consumption.
 以上より、上記熱源側熱交換器(12)とは別の放熱手段である上記蓄熱熱交換器(14)を設けることにより、圧縮機構(11)の消費電力量を増加させずに、上記冷凍装置の冷凍能力を従来の冷凍装置の冷凍能力に近づけることができる。 As described above, by providing the heat storage heat exchanger (14), which is a heat dissipating means different from the heat source side heat exchanger (12), the refrigeration can be performed without increasing the power consumption of the compression mechanism (11). The refrigeration capacity of the apparatus can be brought close to the refrigeration capacity of a conventional refrigeration apparatus.
 又、上記空気調和装置(1)において、上記第1から第4開閉弁(SV1~SV4)を図3のように切り換えて、上記蓄熱運転を行い、比較的に安価な夜間電力を利用して上記氷蓄熱タンク(2)の水を冷却して氷を生成することで冷熱を蓄えておく。そして、上記第1から第4開閉弁(SV1~SV4)を図4のように切り換えて、昼間に冷熱利用運転を行い、上記蓄熱運転で生成した氷を利用することで昼間の消費電力を抑えることができる。 Further, in the air conditioner (1), the first to fourth on-off valves (SV1 to SV4) are switched as shown in FIG. 3 to perform the heat storage operation and use relatively inexpensive nighttime power. Cold water is stored by cooling the water in the ice heat storage tank (2) to produce ice. Then, the first to fourth on-off valves (SV1 to SV4) are switched as shown in FIG. 4 to perform cold heat operation during the daytime, and the ice generated during the heat storage operation is used to reduce daytime power consumption. be able to.
 つまり、昼間電力のピークシフトを行うことを可能にしつつ、圧縮機構(11)の消費電力量を増加させずに従来の冷凍装置の冷凍能力に近づけることができる。 That is, the peak power shift of the daytime power can be performed, and the refrigeration capacity of the conventional refrigeration apparatus can be approached without increasing the power consumption of the compression mechanism (11).
 又、本実施形態1によれば、上記冷媒回路(10)を流れる冷媒に二酸化炭素を用いている。この二酸化炭素と現行のHFC系冷媒とを比較すると、二酸化炭素の方が、飽和圧力が下がるほど潜熱が大きくなり、冷媒密度も大きくなる。従って、上記二酸化炭素を用いることで上記空気調和装置(1)の蓄熱運転時の能力をアップすることができる。 Moreover, according to the first embodiment, carbon dioxide is used as the refrigerant flowing through the refrigerant circuit (10). When this carbon dioxide is compared with the current HFC-based refrigerant, the latent heat increases and the refrigerant density increases as the saturation pressure decreases. Therefore, the capacity | capacitance at the time of the heat storage driving | operation of the said air conditioning apparatus (1) can be improved by using the said carbon dioxide.
  -実施形態1の変形例1-
 図6は実施形態1の変形例1に係る空気調和装置(1)の冷媒回路図であり、図7は蓄熱運転時の冷媒の流れを示し、図8は冷熱利用運転時の冷媒の流れを示している。図9は二酸化炭素のP-h線図上に冷熱利用運転時の冷凍サイクルを示した図である。
—Modification 1 of Embodiment 1—
6 is a refrigerant circuit diagram of an air conditioner (1) according to Modification 1 of Embodiment 1. FIG. 7 shows the refrigerant flow during the heat storage operation, and FIG. 8 shows the refrigerant flow during the cold energy use operation. Show. FIG. 9 is a diagram showing a refrigeration cycle during a cold energy operation on a Ph graph of carbon dioxide.
 上記実施形態1の冷媒回路(10)では、上記蓄熱熱交換器(14)が上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続されていたが、変形例1の冷媒回路(30)では、上記蓄熱熱交換器(14)とは別の第2蓄熱熱交換器(19)が上記過冷却熱交換器(18)と上記膨張弁との間に接続されている。又、上記冷媒回路(30)には、実施形態1の第2膨張弁(15c)の代わりに流量調整弁(13)が設けられている。又、上記冷媒回路(30)には、第5、第6開閉弁(SV5,SV6)が設けられている。 In the refrigerant circuit (10) of the first embodiment, the heat storage heat exchanger (14) is connected between the low-stage compressor (11a) and the high-stage compressor (11b). In the refrigerant circuit (30) of Example 1, a second heat storage heat exchanger (19) different from the heat storage heat exchanger (14) is connected between the supercooling heat exchanger (18) and the expansion valve. Has been. The refrigerant circuit (30) is provided with a flow rate adjustment valve (13) instead of the second expansion valve (15c) of the first embodiment. The refrigerant circuit (30) is provided with fifth and sixth on-off valves (SV5, SV6).
 尚、ここでは、上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続されていた蓄熱熱交換器(14)を第1蓄熱熱交換器(14)という。又、第1、第2蓄熱熱交換器(14,19)はともに上記氷蓄熱タンク(2)に収容されている。 Here, the heat storage heat exchanger (14) connected between the low stage compressor (11a) and the high stage compressor (11b) is referred to as a first heat storage heat exchanger (14). Both the first and second heat storage heat exchangers (14, 19) are accommodated in the ice heat storage tank (2).
 具体的に、上記低段側圧縮機(11a)の吐出側から延びる冷媒配管の端部は分岐して第1及び第2分岐配管(20,21)の一端に接続されている。各分岐配管(20,21)の他端は合流して上記高段側圧縮機(11b)の吸入側に接続されている。上記第1分岐配管(20)には上記第1開閉弁(SV1)が設けられている。上記第2分岐配管(21)には、低段側圧縮機(11a)から高段側圧縮機(11b)に向かって順に第3開閉弁(SV3)と上記蓄熱熱交換器(14)と第4開閉弁(SV4)が設けられている。 Specifically, the end of the refrigerant pipe extending from the discharge side of the low-stage compressor (11a) is branched and connected to one end of the first and second branch pipes (20, 21). The other ends of the branch pipes (20, 21) merge and are connected to the suction side of the high-stage compressor (11b). The first branch pipe (20) is provided with the first on-off valve (SV1). The second branch pipe (21) includes a third on-off valve (SV3), the heat storage heat exchanger (14), and a second heat exchanger in order from the low stage compressor (11a) to the high stage compressor (11b). A 4 on-off valve (SV4) is provided.
 上記高段側圧縮機(11b)の吐出側から延びる冷媒配管は上記室外熱交換器(12)の一端に接続されている。上記室外熱交換器(12)の他端から延びる冷媒配管は分岐して、一方が減圧弁(15a)を介して上記過冷却熱交換器(18)の低温側通路の入口側に接続され、他方が上記過冷却熱交換器(18)の高温側通路の入口側に接続されている。 The refrigerant pipe extending from the discharge side of the high stage compressor (11b) is connected to one end of the outdoor heat exchanger (12). The refrigerant pipe extending from the other end of the outdoor heat exchanger (12) branches, and one is connected to the inlet side of the low temperature side passage of the supercooling heat exchanger (18) via the pressure reducing valve (15a), The other is connected to the inlet side of the high temperature side passage of the supercooling heat exchanger (18).
 上記過冷却熱交換器(18)の低温側通路の出口側から延びる冷媒配管は上記第1分岐配管(20)における上記高段側圧縮機(11b)及び上記第1開閉弁(SV1)の間と連通している。一方、上記過冷却熱交換器(18)の高温側通路の出口側から延びる冷媒配管は上記流量調整弁(13)を介して分岐し、一方が第2蓄熱熱交換器(19)の一端に接続され、他方は第5開閉弁(SV5)を経て上記第2分岐配管(21)における第1蓄熱熱交換器(14)及び上記第4開閉弁(SV4)の間と連通している。 The refrigerant pipe extending from the outlet side of the low temperature side passage of the supercooling heat exchanger (18) is between the high stage compressor (11b) and the first on-off valve (SV1) in the first branch pipe (20). Communicated with. On the other hand, the refrigerant pipe extending from the outlet side of the high temperature side passage of the supercooling heat exchanger (18) branches via the flow rate adjusting valve (13), and one of the refrigerant pipes is connected to one end of the second heat storage heat exchanger (19). The other is connected via the fifth on-off valve (SV5) to the first heat storage heat exchanger (14) and the fourth on-off valve (SV4) in the second branch pipe (21).
 上記第2蓄熱熱交換器(19)の他端から延びる冷媒配管は、膨張弁(15)を介して上記室内熱交換器(16)の一端に接続されている。上記室内熱交換器(16)の他端から延びる冷媒配管は分岐して、一方が上記低段側圧縮機(11a)の吸入側に接続され、他方が第2開閉弁(SV2)を介して上記第2分岐配管(21)における第3開閉弁(SV3)及び上記第1蓄熱熱交換器(14)の間と連通している。 The refrigerant pipe extending from the other end of the second heat storage heat exchanger (19) is connected to one end of the indoor heat exchanger (16) through an expansion valve (15). The refrigerant pipe extending from the other end of the indoor heat exchanger (16) branches, one is connected to the suction side of the low-stage compressor (11a), and the other is connected via the second on-off valve (SV2). The second branch pipe (21) communicates with the third on-off valve (SV3) and the first heat storage heat exchanger (14).
 又、上記冷媒回路(30)には、上記膨張弁(15)と上記室内熱交換器(16)とをバイパスするバイパス配管が設けられ、そのバイパス配管には第6開閉弁(SV6)が設けられている。 The refrigerant circuit (30) is provided with a bypass pipe that bypasses the expansion valve (15) and the indoor heat exchanger (16), and the bypass pipe is provided with a sixth on-off valve (SV6). It has been.
  -運転動作-
  〈蓄熱運転〉
 上記蓄熱運転では、図7に示すように、上記膨張弁(15)の開度が全閉になり、上記流量調整弁(13)及び上記減圧弁(15a)の開度が必要に応じて調整される。又、上記第1開閉弁(SV1)と上記第2開閉弁(SV2)と第5開閉弁(SV5)と第6開閉弁(SV6)とが開設定となり、上記第3開閉弁(SV3)及び上記第4開閉弁(SV4)が閉設定となる。
-Driving operation-
<Heat storage operation>
In the heat storage operation, as shown in FIG. 7, the opening degree of the expansion valve (15) is fully closed, and the opening degree of the flow rate adjusting valve (13) and the pressure reducing valve (15a) is adjusted as necessary. Is done. In addition, the first on-off valve (SV1), the second on-off valve (SV2), the fifth on-off valve (SV5), and the sixth on-off valve (SV6) are set open, and the third on-off valve (SV3) and The fourth on-off valve (SV4) is set to be closed.
 上記高段側圧縮機(11b)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する。上記室外熱交換器(12)を流出した高圧冷媒は分流し、一方が上記減圧弁(15a)で減圧されて中間圧冷媒となった後、上記過冷却熱交換器(18)の低温側流路に流入し、他方が上記過冷却熱交換器(18)の高温側流路に流入する。 The supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). To do. The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) is diverted, one of which is depressurized by the pressure reducing valve (15a) to become an intermediate pressure refrigerant, and then the low-temperature side stream of the supercooling heat exchanger (18) The other flows into the channel, and the other flows into the high temperature side channel of the supercooling heat exchanger (18).
 上記過冷却熱交換器(18)では、上記高温側流路の高圧冷媒と上記低温側流路の中間圧冷媒とが熱交換する。上記高圧冷媒は上記中間圧冷媒に放熱して冷却されて、上記高温側流路を流出する。一方、上記中間圧冷媒は上記高圧冷媒から吸熱して中間圧のガス冷媒となり、上記低温側流路を流出する。 In the supercooling heat exchanger (18), the high-pressure refrigerant in the high-temperature side channel and the intermediate-pressure refrigerant in the low-temperature side channel exchange heat. The high-pressure refrigerant dissipates heat to the intermediate-pressure refrigerant and is cooled, and flows out of the high-temperature side flow path. On the other hand, the intermediate-pressure refrigerant absorbs heat from the high-pressure refrigerant to become an intermediate-pressure gas refrigerant, and flows out from the low-temperature side flow path.
 上記過冷却熱交換器(18)の低温側流路を流出した中間圧冷媒は、上記高段側圧縮機(11b)の吸入側へ流れる。 The intermediate-pressure refrigerant that has flowed out of the low-temperature channel of the supercooling heat exchanger (18) flows to the suction side of the high-stage compressor (11b).
 上記過冷却熱交換器(18)の高温側流路を流出した高圧冷媒は、上記流量調整弁(13)に流入し、その流量が調整されるとともに減圧された後、二相状態の低圧冷媒となって該流量調整弁(13)を流出する。上記流量調整弁(13)を流出した低圧冷媒は分流し、一方は第2蓄熱熱交換器(19)に流入し、他方は上記第5開閉弁(SV5)を経て第1蓄熱熱交換器(14)に流入する。 The high-pressure refrigerant that has flowed out of the high-temperature side flow path of the supercooling heat exchanger (18) flows into the flow rate adjusting valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant in a two-phase state And flows out of the flow regulating valve (13). The low-pressure refrigerant that has flowed out of the flow rate adjusting valve (13) is divided, one flows into the second heat storage heat exchanger (19), and the other passes through the fifth on-off valve (SV5) and the first heat storage heat exchanger ( 14).
 上記第1、第2蓄熱熱交換器(14,19)では、それぞれ低圧冷媒と上記各氷蓄熱タンク(2)内の水とが熱交換して、該各氷蓄熱タンク(2)内の水が冷却されて氷になる。一方、上記各氷蓄熱タンク(2)内の水から吸熱した低圧冷媒は低圧ガス冷媒となり、該各蓄熱熱交換器(14)を流出する。 In the first and second heat storage heat exchangers (14, 19), the low-pressure refrigerant and the water in each ice heat storage tank (2) exchange heat, and the water in each ice heat storage tank (2). Is cooled to ice. On the other hand, the low-pressure refrigerant that has absorbed heat from the water in each of the ice heat storage tanks (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchangers (14).
 上記第1、第2蓄熱熱交換器(14,19)を流出した各低圧ガス冷媒は合流した後、上記低段側圧縮機(11a)に吸入されて所定の圧力まで圧縮されて中間圧ガス冷媒となった後、該低段側圧縮機(11a)から吐出される。上記低段側圧縮機(11a)から吐出された中間圧ガス冷媒は、上記第1開閉弁(SV1)を経て、上記過冷却熱交換器(18)の低温側流路から流出した中間圧ガス冷媒と合流した後、上記高段側圧縮機(11b)に吸入される。 The low-pressure gas refrigerants that have flowed out of the first and second heat storage heat exchangers (14, 19) join together, and are then sucked into the low-stage compressor (11a) and compressed to a predetermined pressure, so that an intermediate-pressure gas is obtained. After becoming a refrigerant, the refrigerant is discharged from the low stage compressor (11a). The intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) passes through the first on-off valve (SV1) and flows out from the low-temperature side passage of the supercooling heat exchanger (18). After joining the refrigerant, the refrigerant is sucked into the high stage compressor (11b).
 上記高段側圧縮機(11b)に吸入された中間圧ガス冷媒は、臨界圧力以上まで圧縮されて高圧冷媒となった後、上記高段側圧縮機(11b)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において蓄熱運転が行われる。 The intermediate-pressure gas refrigerant sucked into the high-stage compressor (11b) is compressed to a critical pressure or higher to become a high-pressure refrigerant, and then discharged from the high-stage compressor (11b). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  〈冷熱利用運転〉
 上記冷熱利用運転では、図8に示すように、上記減圧弁(15a)の開度が全閉になり、上記流量調整弁(13)及び上記膨張弁(15)の開度が必要に応じて調整される。又、上記第1開閉弁(SV1)と上記第2開閉弁(SV2)と第5開閉弁(SV5)と第6開閉弁(SV6)とが閉設定となり、上記第3開閉弁(SV3)及び上記第4開閉弁(SV4)が開設定となる。
<Cryogenic operation>
In the cold energy utilization operation, as shown in FIG. 8, the opening of the pressure reducing valve (15a) is fully closed, and the openings of the flow rate adjusting valve (13) and the expansion valve (15) are adjusted as necessary. Adjusted. The first on-off valve (SV1), the second on-off valve (SV2), the fifth on-off valve (SV5), and the sixth on-off valve (SV6) are set to be closed, and the third on-off valve (SV3) and The fourth on-off valve (SV4) is set to open.
 上記高段側圧縮機(11b)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する(図8,図9の点b1)。上記室外熱交換器(12)を流出した高圧冷媒は、上記過冷却熱交換器(18)を熱交換することなく通過し、上記流量調整弁(13)でその流量が調整されて、上記第2蓄熱熱交換器(19)に流入する。 The supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). (Point b1 in FIGS. 8 and 9). The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) passes through the supercooling heat exchanger (18) without exchanging heat, and the flow rate of the high-pressure refrigerant is adjusted by the flow rate adjusting valve (13). 2 flows into the heat storage heat exchanger (19).
 上記第2蓄熱熱交換器(19)では、高圧冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記高圧冷媒は上記氷蓄熱タンク(2)内の氷に放熱して冷却された後、該第2蓄熱熱交換器(19)を流出する(図8,図9の点c)。 In the second heat storage heat exchanger (19), the high-pressure refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water. On the other hand, the high-pressure refrigerant radiates and cools the ice in the ice heat storage tank (2) and then flows out of the second heat storage heat exchanger (19) (point c in FIGS. 8 and 9).
 上記第2蓄熱熱交換器(19)を流出した高圧冷媒は、上記膨張弁(15)に流入し、所定の圧力まで減圧されて二相状態の低圧冷媒となり、該膨張弁(15)を流出する(図8,図9の点d)。上記膨張弁(15)を流出した低圧冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱して低圧ガス冷媒となった後、該室内熱交換器(16)から流出する(図8,図9の点a)。上記室内空気は、該室内空気の熱を上記低圧ガス冷媒に吸収させることにより冷却される。 The high-pressure refrigerant that has flowed out of the second heat storage heat exchanger (19) flows into the expansion valve (15), is reduced to a predetermined pressure, becomes a low-pressure refrigerant in a two-phase state, and flows out of the expansion valve (15). (Point d in FIGS. 8 and 9). The low-pressure refrigerant that has flowed out of the expansion valve (15) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then flows out of the indoor heat exchanger (16). (Point a in FIGS. 8 and 9). The indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した低圧ガス冷媒は、上記低段側圧縮機(11a)に吸入され、所定の圧力まで圧縮されて中間圧ガス冷媒となった後、該低段側圧縮機(11a)から吐出される(図8,図9の点a1)。上記低段側圧縮機(11a)から吐出された中間圧ガス冷媒は、上記第3開閉弁(SV3)を経て、上記第1蓄熱熱交換器(14)に流入する。 The low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed to a predetermined pressure to become an intermediate-pressure gas refrigerant. It is discharged from the machine (11a) (point a1 in FIGS. 8 and 9). The intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) flows into the first heat storage heat exchanger (14) through the third on-off valve (SV3).
 上記第1蓄熱熱交換器(14)では、中間圧ガス冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記中間圧ガス冷媒は上記氷蓄熱タンク(2)内の氷に放熱して冷却されて、該第1蓄熱熱交換器(14)を流出する(図8,図9の点a2)。 In the first heat storage heat exchanger (14), the intermediate pressure gas refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts into water. Become. On the other hand, the intermediate-pressure gas refrigerant dissipates heat to the ice in the ice heat storage tank (2), is cooled, and flows out of the first heat storage heat exchanger (14) (point a2 in FIGS. 8 and 9).
 上記第1蓄熱熱交換器(14)を流出した中間圧ガス冷媒は、第4開閉弁(SV4)を経て、上記高段側圧縮機(11b)に吸入され、臨界圧力以上まで圧縮されて高圧冷媒となった後、上記高段側圧縮機(11b)から吐出される(図8,図9の点b)。このように冷媒が循環することにより、空気調和装置(1)において冷熱利用運転が行われる。 The intermediate-pressure gas refrigerant that has flowed out of the first heat storage heat exchanger (14) passes through the fourth on-off valve (SV4) and is sucked into the high-stage compressor (11b) and compressed to a critical pressure or higher. After becoming a refrigerant, the refrigerant is discharged from the high stage compressor (11b) (point b in FIGS. 8 and 9). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  -実施形態1の変形例1の効果-
 上記実施形態1の変形例1によれば、上記冷媒回路(30)の圧縮機構である上記低段側圧縮機(11a)と高段側圧縮機(11b)に二段圧縮を行わせるとともに、上記低段側圧縮機(11a)から吐出された冷媒を上記第1蓄熱熱交換器(14)で冷却している。こうすると、実施形態1と同様に消費電力を増やさずに冷凍能力を増やすことができる。
-Effect of Modification 1 of Embodiment 1-
According to the first modification of the first embodiment, the low-stage compressor (11a) and the high-stage compressor (11b), which are compression mechanisms of the refrigerant circuit (30), are subjected to two-stage compression, The refrigerant discharged from the low stage compressor (11a) is cooled by the first heat storage heat exchanger (14). If it carries out like this, refrigerating capacity can be increased, without increasing power consumption similarly to Embodiment 1. FIG.
 又、上記第2蓄熱熱交換器(19)を設けることで、上記熱源側熱交換器(12)から流出した冷媒の温度をさらに下げることができ、上記冷凍効果を向上させることができる。これにより、上記冷凍効果が向上した分だけ、上記冷媒回路(30)における冷媒の循環量を少なくすることができ、上記冷媒回路(30)の圧縮機構の消費電力を低減することができる。 Also, by providing the second heat storage heat exchanger (19), the temperature of the refrigerant flowing out from the heat source side heat exchanger (12) can be further lowered, and the refrigeration effect can be improved. Thereby, the circulation amount of the refrigerant in the refrigerant circuit (30) can be reduced by the amount that the refrigeration effect is improved, and the power consumption of the compression mechanism of the refrigerant circuit (30) can be reduced.
 以上より、上記熱源側熱交換器(12)とは別の放熱手段である上記第1,第2蓄熱熱交換器(14,19)を設けることにより、上記冷媒回路(30)の消費電力量を増加させずに従来の冷凍装置の冷凍能力に近づけることができる。 As described above, by providing the first and second heat storage heat exchangers (14, 19) which are heat dissipating means different from the heat source side heat exchanger (12), the power consumption of the refrigerant circuit (30). It is possible to approach the refrigeration capacity of the conventional refrigeration apparatus without increasing the value.
  -実施形態1の変形例2-
 図10は実施形態1の変形例2に係る空気調和装置(1)の冷媒回路図であり、図11は蓄熱運転時の冷媒の流れを示し、図12は冷熱利用運転時の冷媒の流れを示している。図13は二酸化炭素のP-h線図上に冷熱利用運転時の冷凍サイクルを示した図である。
Modification 2 of Embodiment 1
FIG. 10 is a refrigerant circuit diagram of the air conditioner (1) according to the second modification of the first embodiment. FIG. 11 shows the refrigerant flow during the heat storage operation, and FIG. 12 shows the refrigerant flow during the cold utilization operation. Show. FIG. 13 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
 上記実施形態1の冷媒回路(10)では、上記蓄熱熱交換器(14)が上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続されていたが、変形例2の冷媒回路(40)では、上記蓄熱熱交換器(14)が別の位置に接続されている。 In the refrigerant circuit (10) of the first embodiment, the heat storage heat exchanger (14) is connected between the low-stage compressor (11a) and the high-stage compressor (11b). In the refrigerant circuit (40) of Example 2, the heat storage heat exchanger (14) is connected to another position.
 上記低段側圧縮機(11a)の吐出側から延びる接続配管(22)は、上記高段側圧縮機(11b)の吸入側に接続されている。上記高段側圧縮機(11b)の吐出側から延びる冷媒配管は上記室外熱交換器(12)の一端に接続されている。上記室外熱交換器(12)の他端から延びる冷媒配管は分岐して、一方が減圧弁(15a)を介して上記過冷却熱交換器(18)の低温側通路の入口側に接続され、他方が上記過冷却熱交換器(18)の高温側通路の入口側に接続されている。 The connection pipe (22) extending from the discharge side of the low stage compressor (11a) is connected to the suction side of the high stage compressor (11b). A refrigerant pipe extending from the discharge side of the high stage compressor (11b) is connected to one end of the outdoor heat exchanger (12). The refrigerant pipe extending from the other end of the outdoor heat exchanger (12) branches, and one is connected to the inlet side of the low temperature side passage of the supercooling heat exchanger (18) via the pressure reducing valve (15a), The other is connected to the inlet side of the high temperature side passage of the supercooling heat exchanger (18).
 上記過冷却熱交換器(18)の低温側通路の出口側から延びる冷媒配管は上記接続配管(22)と連通している。一方、上記過冷却熱交換器(18)の高温側通路の出口側から延びる冷媒配管は上記流量調整弁(13)を介して分岐し、一方が上記蓄熱熱交換器(14)の一端に接続され、他方が膨張弁(15)を介して上記室内熱交換器(16)の一端に接続されている。 The refrigerant pipe extending from the outlet side of the low temperature side passage of the supercooling heat exchanger (18) communicates with the connection pipe (22). On the other hand, the refrigerant pipe extending from the outlet side of the high-temperature side passage of the supercooling heat exchanger (18) branches via the flow rate adjusting valve (13), and one is connected to one end of the heat storage heat exchanger (14). The other is connected to one end of the indoor heat exchanger (16) through the expansion valve (15).
 上記蓄熱熱交換器(14)の他端から延びる冷媒配管は第7開閉弁(SV7)を介して上記接続配管(22)に連通している。一方、上記室内熱交換器(16)の他端から延びる冷媒配管は分岐して、一端が第8開閉弁(SV8)を介して上記蓄熱熱交換器(14)の他端から延びる冷媒配管における該蓄熱熱交換器(14)及び第7開閉弁(SV7)の間と連通し、他端が上記低段側圧縮機(11a)の吸入側に接続されている。 The refrigerant pipe extending from the other end of the heat storage heat exchanger (14) communicates with the connection pipe (22) through a seventh on-off valve (SV7). On the other hand, the refrigerant pipe extending from the other end of the indoor heat exchanger (16) branches, and one end of the refrigerant pipe extends from the other end of the heat storage heat exchanger (14) via an eighth on-off valve (SV8). The heat storage heat exchanger (14) communicates with the seventh on-off valve (SV7), and the other end is connected to the suction side of the low-stage compressor (11a).
  -運転動作-
  〈蓄熱運転〉
 上記蓄熱運転では、図11に示すように、上記膨張弁(15)の開度が全閉になり、上記流量調整弁(13)及び上記減圧弁(15a)の開度が必要に応じて調整される。又、上記第8開閉弁(SV8)が開設定となり、上記第7開閉弁(SV7)が閉設定となる。
-Driving operation-
<Heat storage operation>
In the heat storage operation, as shown in FIG. 11, the opening degree of the expansion valve (15) is fully closed, and the opening degree of the flow rate adjusting valve (13) and the pressure reducing valve (15a) is adjusted as necessary. Is done. The eighth on-off valve (SV8) is set to open, and the seventh on-off valve (SV7) is set to close.
 上記高段側圧縮機(11b)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する。上記室外熱交換器(12)を流出した高圧冷媒は分流し、一方が上記減圧弁(15a)で減圧されて中間圧冷媒となった後、上記過冷却熱交換器(18)の低温側流路に流入し、他方が上記過冷却熱交換器(18)の高温側流路に流入する。 The supercritical high-pressure refrigerant discharged from the high-stage compressor (11b) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). To do. The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) is diverted, one of which is depressurized by the pressure reducing valve (15a) to become an intermediate pressure refrigerant, and then the low-temperature side stream of the supercooling heat exchanger (18) The other flows into the channel, and the other flows into the high temperature side channel of the supercooling heat exchanger (18).
 上記過冷却熱交換器(18)では、上記高温側流路の高圧冷媒と上記低温側流路の中間圧冷媒とが熱交換する。上記高圧冷媒は上記中間圧冷媒に放熱して冷却されて、上記高温側流路を流出する。一方、上記中間圧冷媒は上記高圧冷媒から吸熱して中間圧のガス冷媒となり、上記低温側流路を流出する。 In the supercooling heat exchanger (18), the high-pressure refrigerant in the high-temperature side channel and the intermediate-pressure refrigerant in the low-temperature side channel exchange heat. The high-pressure refrigerant dissipates heat to the intermediate-pressure refrigerant and is cooled, and flows out of the high-temperature side flow path. On the other hand, the intermediate-pressure refrigerant absorbs heat from the high-pressure refrigerant to become an intermediate-pressure gas refrigerant, and flows out from the low-temperature side flow path.
 上記過冷却熱交換器(18)の低温側流路を流出した中間圧冷媒は、上記高段側圧縮機(11b)の吸入側へ流れる。 The intermediate-pressure refrigerant that has flowed out of the low-temperature channel of the supercooling heat exchanger (18) flows to the suction side of the high-stage compressor (11b).
 上記過冷却熱交換器(18)の高温側流路を流出した高圧冷媒は、上記流量調整弁(13)に流入し、その流量が調整されるとともに減圧された後、二相状態の低圧冷媒となって該流量調整弁(13)を流出する。上記流量調整弁(13)を流出した低圧冷媒は蓄熱熱交換器(14)に流入する。 The high-pressure refrigerant that has flowed out of the high-temperature side flow path of the supercooling heat exchanger (18) flows into the flow rate adjusting valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant in a two-phase state And flows out of the flow regulating valve (13). The low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)では、上記低圧冷媒と上記氷蓄熱タンク(2)内の水とが熱交換して、該氷蓄熱タンク(2)内の水が冷却されて氷になる。一方、上記氷蓄熱タンク(2)内の水から吸熱した低圧冷媒は低圧ガス冷媒となり、該蓄熱熱交換器(14)を流出する。 In the heat storage heat exchanger (14), the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice. On the other hand, the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)を流出した低圧ガス冷媒は、上記第8開閉弁(SV8)を経て、上記低段側圧縮機(11a)に吸入されて所定の圧力まで圧縮されて中間圧ガス冷媒となった後、該低段側圧縮機(11a)から吐出される。 The low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the eighth on-off valve (SV8), is sucked into the low-stage compressor (11a), is compressed to a predetermined pressure, and is compressed to an intermediate pressure gas. After becoming a refrigerant, the refrigerant is discharged from the low stage compressor (11a).
 上記低段側圧縮機(11a)から吐出された中間圧ガス冷媒は、上記過冷却熱交換器(18)の低温側流路から流出した中間圧ガス冷媒と合流した後、上記高段側圧縮機(11b)に吸入される。 The intermediate-pressure gas refrigerant discharged from the low-stage compressor (11a) merges with the intermediate-pressure gas refrigerant flowing out from the low-temperature side flow path of the supercooling heat exchanger (18), and then the high-stage compression Inhaled into the machine (11b).
 上記高段側圧縮機(11b)に吸入された中間圧ガス冷媒は、臨界圧力以上まで圧縮されて高圧冷媒となった後、上記高段側圧縮機(11b)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において蓄熱運転が行われる。 The intermediate-pressure gas refrigerant sucked into the high-stage compressor (11b) is compressed to a critical pressure or higher to become a high-pressure refrigerant, and then discharged from the high-stage compressor (11b). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  〈冷熱利用運転〉
 上記冷熱利用運転では、図12に示すように、上記膨張弁(15)の開度が必要に応じて調整され、上記流量調整弁(13)及び上記減圧弁(15a)の開度が全閉となる。又、上記第8開閉弁(SV8)が閉設定となり、上記第7開閉弁(SV7)が開設定となる。又、上記高段側圧縮機(11b)は停止している。
<Cryogenic operation>
In the cold energy utilization operation, as shown in FIG. 12, the opening degree of the expansion valve (15) is adjusted as necessary, and the opening degree of the flow rate adjusting valve (13) and the pressure reducing valve (15a) are fully closed. It becomes. Further, the eighth on-off valve (SV8) is set to close, and the seventh on-off valve (SV7) is set to open. The high stage compressor (11b) is stopped.
 上記低段側圧縮機(11a)から吐出された高圧ガス冷媒は、上記第7開閉弁(SV7)を経て、上記蓄熱熱交換器(14)に流入する。 The high-pressure gas refrigerant discharged from the low-stage compressor (11a) flows into the heat storage heat exchanger (14) through the seventh on-off valve (SV7).
 上記蓄熱熱交換器(14)では、高圧ガス冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記高圧ガス冷媒は上記氷蓄熱タンク(2)内の氷に放熱して凝縮した後、該蓄熱熱交換器(14)を流出する(図12,図13の点c)。 In the heat storage heat exchanger (14), the high pressure gas refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts to become water. On the other hand, the high-pressure gas refrigerant releases heat to the ice in the ice heat storage tank (2) and condenses, and then flows out of the heat storage heat exchanger (14) (point c in FIGS. 12 and 13).
 上記蓄熱熱交換器(14)を流出した高圧冷媒は、上記膨張弁(15)に流入し、所定の圧力まで減圧されて二相状態の低圧冷媒となり、該膨張弁(15)を流出する(図12,図13の点d)。上記膨張弁(15)を流出した低圧冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱して低圧ガス冷媒となった後、該室内熱交換器(16)から流出する(図12,図13の点a)。上記室内空気は、該室内空気の熱を上記低圧ガス冷媒に吸収させることにより冷却される。 The high-pressure refrigerant that has flowed out of the heat storage heat exchanger (14) flows into the expansion valve (15), is depressurized to a predetermined pressure, becomes a low-pressure refrigerant in a two-phase state, and flows out of the expansion valve (15) ( Point d) in FIGS. The low-pressure refrigerant that has flowed out of the expansion valve (15) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then flows out of the indoor heat exchanger (16). (Point a in FIGS. 12 and 13). The indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した低圧ガス冷媒は、上記低段側圧縮機(11a)に吸入され、臨界圧以下の範囲内で圧縮されて高圧ガス冷媒となった後、該低段側圧縮機(11a)から吐出される(図12,図13の点b)。このように冷媒が循環することにより、空気調和装置(1)において冷熱利用運転が行われる。 The low-pressure gas refrigerant that has flowed out of the indoor heat exchanger (16) is sucked into the low-stage compressor (11a) and compressed within the range below the critical pressure to become a high-pressure gas refrigerant. It is discharged from the side compressor (11a) (point b in FIGS. 12 and 13). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  -実施形態1の変形例2の効果-
 上記実施形態1の変形例2によれば、上記蓄熱運転時は、上記低段側圧縮機(11a)と上記高段側圧縮機(11b)を起動するが、上記冷熱利用運転時は、上記低段側圧縮機(11a)のみを起動している。これにより、上記蓄熱運転時に比べて、上記冷熱利用運転時の冷媒搬送動力を低減することができる。従って、上記冷媒回路(40)の圧縮機構の消費電力を増やさずに上記冷熱利用運転時の冷凍能力を増やすことができる。
-Effects of Modification 2 of Embodiment 1-
According to the second modification of the first embodiment, the low-stage compressor (11a) and the high-stage compressor (11b) are started during the heat storage operation. Only the low stage compressor (11a) is running. Thereby, compared with the time of the said heat storage driving | operation, the refrigerant | coolant conveyance motive power at the time of the said cold utilization operation | movement can be reduced. Therefore, it is possible to increase the refrigeration capacity during the cold heat operation without increasing the power consumption of the compression mechanism of the refrigerant circuit (40).
 《実施形態2》
 図14は実施形態2に係る空気調和装置(1)の冷媒回路図であり、図15は蓄熱運転時の冷媒の流れを示し、図16は冷熱利用運転時の冷媒の流れを示している。図17は二酸化炭素のP-h線図上に冷熱利用運転時の冷凍サイクルを示した図である。
<< Embodiment 2 >>
FIG. 14 is a refrigerant circuit diagram of the air-conditioning apparatus (1) according to Embodiment 2. FIG. 15 shows the refrigerant flow during the heat storage operation, and FIG. 16 shows the refrigerant flow during the cold utilization operation. FIG. 17 is a diagram showing a refrigeration cycle during a cold heat operation on a Ph graph of carbon dioxide.
 実施形態2の冷媒回路(50)と上記実施形態1で示した冷媒回路(10)との大きな違いは、上記低段側圧縮機(11a)及び高段側圧縮機(11b)に代えて圧縮機(11)及び冷媒ガスポンプ(冷媒ポンプ)(17)が設けられている点、及び蓄熱熱交換器(14)の位置が異なる点である。ここで、上記冷媒ガスポンプ(17)は、冷媒ガスを搬送するためのものであり、上記圧縮機(11)よりも圧縮比が小さく設定されている。 The major difference between the refrigerant circuit (50) of the second embodiment and the refrigerant circuit (10) shown in the first embodiment is that the compression is performed in place of the low-stage compressor (11a) and the high-stage compressor (11b). The machine (11) and the refrigerant gas pump (refrigerant pump) (17) are provided, and the position of the heat storage heat exchanger (14) is different. Here, the refrigerant gas pump (17) is for conveying refrigerant gas, and has a compression ratio smaller than that of the compressor (11).
 上記圧縮機(11)及び上記冷媒ガスポンプ(17)の吐出側から延びる各冷媒配管は合流して上記室外熱交換器(12)の一端に接続されている。上記室外熱交換器(12)の他端から延びる冷媒配管は上記流量調整弁(13)と上記膨張弁(15)とを介して上記室内熱交換器(16)の一端に接続されている。上記室内熱交換器(16)の他端から延びる冷媒配管は分岐して、一端が上記圧縮機(11)の吸入側に接続され、他端が上記冷媒ガスポンプ(17)の吸入側に接続されている。 The refrigerant pipes extending from the discharge side of the compressor (11) and the refrigerant gas pump (17) merge and are connected to one end of the outdoor heat exchanger (12). A refrigerant pipe extending from the other end of the outdoor heat exchanger (12) is connected to one end of the indoor heat exchanger (16) through the flow rate adjusting valve (13) and the expansion valve (15). The refrigerant pipe extending from the other end of the indoor heat exchanger (16) branches, one end is connected to the suction side of the compressor (11), and the other end is connected to the suction side of the refrigerant gas pump (17). ing.
 又、上記冷媒回路(50)には、上記室外熱交換器(12)と上記流量調整弁(13)とをバイパスするバイパス配管(23)が設けられ、上記室外熱交換器(12)側から上記流量調整弁(13)側へ向かって第9開閉弁(SV9)と上記蓄熱熱交換器(14)とが設けられている。そして、上記バイパス配管(23)における第9開閉弁(SV9)及び上記蓄熱熱交換器(14)の間から延びる分岐配管(24)が上記室内熱交換器(16)と上記圧縮機(11)及び上記冷媒ガスポンプ(17)とを接続する冷媒配管に接続されている。この分岐配管(24)には、第10開閉弁(SV10)が接続されている。 The refrigerant circuit (50) is provided with a bypass pipe (23) that bypasses the outdoor heat exchanger (12) and the flow rate adjusting valve (13), and is provided from the outdoor heat exchanger (12) side. A ninth on-off valve (SV9) and the heat storage heat exchanger (14) are provided toward the flow rate adjustment valve (13). A branch pipe (24) extending from between the ninth on-off valve (SV9) and the heat storage heat exchanger (14) in the bypass pipe (23) is connected to the indoor heat exchanger (16) and the compressor (11). And a refrigerant pipe connecting the refrigerant gas pump (17). A tenth on-off valve (SV10) is connected to the branch pipe (24).
 このように、上記冷媒回路(10)は、冷媒を搬送する冷媒ガスポンプ(17)を備えている。そして、上記冷媒回路(10)は、上記圧縮機構(11)から吐出した冷媒が熱源側熱交換器(12)で放熱し、蓄熱熱交換器(14)で蒸発して圧縮機構(11)に戻る蓄熱運転と、上記冷媒ガスポンプ(17)から吐出した冷媒が蓄熱熱交換器(14)で凝縮し、利用側熱交換器(16)で蒸発して冷媒ポンプ(17)に戻る冷熱利用運転とに切り換わるように構成されている。 Thus, the refrigerant circuit (10) includes the refrigerant gas pump (17) for conveying the refrigerant. In the refrigerant circuit (10), the refrigerant discharged from the compression mechanism (11) dissipates heat in the heat source side heat exchanger (12), evaporates in the heat storage heat exchanger (14), and enters the compression mechanism (11) The return heat storage operation, and the refrigerant discharged from the refrigerant gas pump (17) is condensed in the heat storage heat exchanger (14), evaporated in the use side heat exchanger (16), and returned to the refrigerant pump (17). It is comprised so that it may switch.
  -運転動作-
  〈蓄熱運転〉
 上記蓄熱運転では、図15に示すように、上記膨張弁(15)の開度が全閉になり、上記流量調整弁(13)の開度が必要に応じて調整される。又、上記第10開閉弁(SV10)が開設定となり、上記第9開閉弁(SV9)が閉設定となる。
-Driving operation-
<Heat storage operation>
In the heat storage operation, as shown in FIG. 15, the opening degree of the expansion valve (15) is fully closed, and the opening degree of the flow rate adjusting valve (13) is adjusted as necessary. The tenth on-off valve (SV10) is set to open, and the ninth on-off valve (SV9) is set to close.
 上記圧縮機(11)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する。上記室外熱交換器(12)を流出した高圧冷媒は、上記流量調整弁(13)に流入し、その流量が調整されるとともに減圧された後、二相状態の低圧冷媒となって該流量調整弁(13)を流出する。上記流量調整弁(13)を流出した低圧冷媒は蓄熱熱交換器(14)に流入する。 The supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant is in a two-phase state. Outflow valve (13). The low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)では、上記低圧冷媒と上記氷蓄熱タンク(2)内の水とが熱交換して、該氷蓄熱タンク(2)内の水が冷却されて氷になる。一方、上記氷蓄熱タンク(2)内の水から吸熱した低圧冷媒は低圧ガス冷媒となり、該蓄熱熱交換器(14)を流出する。 In the heat storage heat exchanger (14), the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice. On the other hand, the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)を流出した低圧ガス冷媒は、上記第10開閉弁(SV10)を経て、上記圧縮機(11)に吸入されて所定の圧力まで圧縮されて超臨界状態の高圧冷媒となった後、上記圧縮機(11)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において蓄熱運転が行われる。 The low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the tenth on-off valve (SV10), is sucked into the compressor (11), and is compressed to a predetermined pressure to be supercritical high-pressure refrigerant. After that, it is discharged from the compressor (11). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  〈冷熱利用運転〉
 上記冷熱利用運転では、図16に示すように、上記流量調整弁(13)の開度が全閉になり、上記膨張弁(15)の開度が必要に応じて調整される。又、上記第10開閉弁(SV10)が閉設定となり、上記第9開閉弁(SV9)が開設定となる。
<Cryogenic operation>
In the cold energy utilization operation, as shown in FIG. 16, the opening degree of the flow rate adjustment valve (13) is fully closed, and the opening degree of the expansion valve (15) is adjusted as necessary. Further, the tenth on-off valve (SV10) is set to be closed, and the ninth on-off valve (SV9) is set to be open.
 上記冷媒ガスポンプ(17)から吐出された冷媒は、上記第9開閉弁(SV9)を経て、上記蓄熱熱交換器(14)に流入する。 The refrigerant discharged from the refrigerant gas pump (17) flows into the heat storage heat exchanger (14) through the ninth on-off valve (SV9).
 上記蓄熱熱交換器(14)では、上記冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記冷媒は上記氷蓄熱タンク(2)内の氷に放熱して凝縮した後、該蓄熱熱交換器(14)を流出する(図16,図17の点c)。 In the heat storage heat exchanger (14), the refrigerant and ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts to become water. On the other hand, the refrigerant releases heat to the ice in the ice heat storage tank (2) and condenses, and then flows out of the heat storage heat exchanger (14) (point c in FIGS. 16 and 17).
 上記蓄熱熱交換器(14)を流出した冷媒は、上記膨張弁(15)に流入し、所定の圧力まで減圧された後、該膨張弁(15)を流出する(図16,図17の点d)。上記膨張弁(15)を流出した冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱した後、該室内熱交換器(16)から流出する(図16,図17の点a)。上記室内空気は、該室内空気の熱を上記冷媒に吸収させることにより冷却される。 The refrigerant that has flowed out of the heat storage heat exchanger (14) flows into the expansion valve (15), is depressurized to a predetermined pressure, and then flows out of the expansion valve (15) (points in FIGS. 16 and 17). d). The refrigerant that has flowed out of the expansion valve (15) flows into the indoor heat exchanger (16), absorbs heat from indoor air, and then flows out of the indoor heat exchanger (16) (points in FIGS. 16 and 17). a). The indoor air is cooled by causing the refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した冷媒は、上記冷媒ガスポンプ(17)に吸入された後、該冷媒ガスポンプ(17)から吐出される(図16,図17の点b)。このように冷媒が循環することにより、空気調和装置(1)において冷熱利用運転が行われる。 The refrigerant flowing out of the indoor heat exchanger (16) is sucked into the refrigerant gas pump (17) and then discharged from the refrigerant gas pump (17) (point b in FIGS. 16 and 17). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  -実施形態2の効果-
 上記実施形態2によれば、上記冷熱利用運転時に、上記圧縮機構(11)を用いずに、上記冷媒ポンプ(17)を用いている。こうすることで、上記冷熱利用運転時の冷媒搬送動力を低減することができる。これにより、上記蓄熱運転時に比べて、上記冷熱利用運転時の冷媒搬送動力を低減することができる。従って、上記実施形態1の変形例2と同様に、上記冷媒回路(50)の圧縮機構の消費電力を増やさずに上記冷熱利用運転時の冷凍能力を増やすことができる。
-Effect of Embodiment 2-
According to the second embodiment, the refrigerant pump (17) is used without using the compression mechanism (11) during the cold heat operation. By carrying out like this, the refrigerant | coolant conveyance motive power at the time of the said cold utilization operation can be reduced. Thereby, compared with the time of the said heat storage driving | operation, the refrigerant | coolant conveyance motive power at the time of the said cold utilization operation | movement can be reduced. Therefore, as in the second modification of the first embodiment, the refrigeration capacity during the cold-utilizing operation can be increased without increasing the power consumption of the compression mechanism of the refrigerant circuit (50).
 《実施形態3》
 図18は実施形態3に係る空気調和装置(1)の冷媒回路図であり、図19は蓄熱運転時の冷媒の流れを示し、図20は冷熱利用運転時の冷媒の流れを示している。図21は二酸化炭素のP-h線図上に冷熱利用運転時の冷凍サイクルを示した図である。
<< Embodiment 3 >>
18 is a refrigerant circuit diagram of the air-conditioning apparatus (1) according to Embodiment 3. FIG. 19 shows the refrigerant flow during the heat storage operation, and FIG. 20 shows the refrigerant flow during the cold energy use operation. FIG. 21 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
 実施形態2の冷媒回路(60)と上記実施形態1で示した冷媒回路(10)との大きな違いは、上記低段側圧縮機(11a)及び高段側圧縮機(11b)に代えて1台の圧縮機(11)のみが設けられている点、及び蓄熱熱交換器(14)の位置が異なる点である。 The major difference between the refrigerant circuit (60) of the second embodiment and the refrigerant circuit (10) shown in the first embodiment is that the low-stage compressor (11a) and the high-stage compressor (11b) are replaced with 1 Only the compressor (11) is provided, and the position of the heat storage heat exchanger (14) is different.
 上記圧縮機(11)の吐出側から延びる冷媒配管は、上記室外熱交換器(12)及び上記流量調整弁(13)を介して上記蓄熱熱交換器(14)の一端に接続されている。上記蓄熱熱交換器(14)の他端から延びる冷媒配管は、上記膨張弁(15)及び上記室内熱交換器(16)を介して上記圧縮機(11)の吸入側に接続されている。又、上記冷媒配管には、上記膨張弁(15)及び上記室内熱交換器(16)をバイパスするバイパス配管が設けられ、そのバイパス配管には第11開閉弁(SV11)が設けられている。 The refrigerant pipe extending from the discharge side of the compressor (11) is connected to one end of the heat storage heat exchanger (14) via the outdoor heat exchanger (12) and the flow rate adjusting valve (13). A refrigerant pipe extending from the other end of the heat storage heat exchanger (14) is connected to the suction side of the compressor (11) via the expansion valve (15) and the indoor heat exchanger (16). The refrigerant pipe is provided with a bypass pipe that bypasses the expansion valve (15) and the indoor heat exchanger (16), and the bypass pipe is provided with an eleventh on-off valve (SV11).
  -運転動作-
  〈蓄熱運転〉
 上記蓄熱運転では、図19に示すように、上記膨張弁(15)の開度が全閉になり、上記流量調整弁(13)の開度が必要に応じて調整される。又、上記第11開閉弁(SV11)が開設定となる。
-Driving operation-
<Heat storage operation>
In the heat storage operation, as shown in FIG. 19, the opening degree of the expansion valve (15) is fully closed, and the opening degree of the flow rate adjusting valve (13) is adjusted as necessary. The eleventh on-off valve (SV11) is set to open.
 上記圧縮機(11)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する。上記室外熱交換器(12)を流出した高圧冷媒は、上記流量調整弁(13)に流入し、その流量が調整されるとともに減圧された後、二相状態の低圧冷媒となって該流量調整弁(13)を流出する。上記流量調整弁(13)を流出した低圧冷媒は蓄熱熱交換器(14)に流入する。 The supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant is in a two-phase state. Outflow valve (13). The low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)では、上記低圧冷媒と上記氷蓄熱タンク(2)内の水とが熱交換して、該氷蓄熱タンク(2)内の水が冷却されて氷になる。一方、上記氷蓄熱タンク(2)内の水から吸熱した低圧冷媒は低圧ガス冷媒となり、該蓄熱熱交換器(14)を流出する。 In the heat storage heat exchanger (14), the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice. On the other hand, the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)を流出した低圧ガス冷媒は、上記第11開閉弁(SV11)を経て、上記圧縮機(11)に吸入されて所定の圧力まで圧縮されて超臨界状態の高圧冷媒となった後、上記圧縮機(11)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において蓄熱運転が行われる。 The low-pressure gas refrigerant that has flowed out of the heat storage heat exchanger (14) passes through the eleventh on-off valve (SV11), is sucked into the compressor (11), and is compressed to a predetermined pressure so that it is in a supercritical state. After that, it is discharged from the compressor (11). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  〈冷熱利用運転〉
 上記冷熱利用運転では、図20に示すように、上記膨張弁(15)及び上記流量調整弁(13)の開度が必要に応じて調整される。又、上記第11開閉弁(SV11)が閉設定となる。
<Cryogenic operation>
In the cold energy utilization operation, as shown in FIG. 20, the opening degrees of the expansion valve (15) and the flow rate adjustment valve (13) are adjusted as necessary. The eleventh on-off valve (SV11) is set to be closed.
 上記圧縮機(11)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する(図20,図21の点b1)。上記室外熱交換器(12)を流出した高圧冷媒は、上記流量調整弁(13)でその流量が調整された後で、上記蓄熱熱交換器(14)に流入する。 The supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12) (FIG. 20, point b1) in FIG. The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the heat storage heat exchanger (14) after the flow rate is adjusted by the flow rate adjustment valve (13).
 上記蓄熱熱交換器(14)では、高圧冷媒と上記氷蓄熱タンク(2)内の氷とが熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記高圧冷媒は上記氷蓄熱タンク(2)内の氷に放熱して冷却された後、該蓄熱熱交換器(14)を流出する(図20,図21の点c)。 In the heat storage heat exchanger (14), the high-pressure refrigerant and the ice in the ice heat storage tank (2) exchange heat, and the ice in the ice heat storage tank (2) melts to become water. On the other hand, the high-pressure refrigerant releases heat to the ice in the ice heat storage tank (2) and is cooled, and then flows out of the heat storage heat exchanger (14) (point c in FIGS. 20 and 21).
 上記蓄熱熱交換器(14)を流出した高圧冷媒は、上記膨張弁(15)に流入し、所定の圧力まで減圧されて二相状態の低圧冷媒となり、該膨張弁(15)を流出する(図20,図21の点d)。上記膨張弁(15)を流出した低圧冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱して低圧ガス冷媒となった後、該室内熱交換器(16)から流出する(図20,図21の点a)。上記室内空気は、該室内空気の熱を上記低圧ガス冷媒に吸収させることにより冷却される。 The high-pressure refrigerant that has flowed out of the heat storage heat exchanger (14) flows into the expansion valve (15), is depressurized to a predetermined pressure, becomes a low-pressure refrigerant in a two-phase state, and flows out of the expansion valve (15) ( The point d) of FIG. 20, FIG. The low-pressure refrigerant that has flowed out of the expansion valve (15) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then flows out of the indoor heat exchanger (16). (Point a in FIGS. 20 and 21). The indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した低圧ガス冷媒は、上記圧縮機(11)に吸入され、所定の圧力まで圧縮されて超臨界状態の高圧冷媒となった後、該圧縮機(11)から吐出される(図20,図21の点b)。このように冷媒が循環することにより、空気調和装置(1)において冷熱利用運転が行われる。 The low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the compressor (11) and compressed to a predetermined pressure to become a high-pressure refrigerant in a supercritical state, and then the compressor (11) (Point b in FIGS. 20 and 21). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  -実施形態3の効果-
 本実施形態3によれば、上記蓄熱熱交換器(14)を、上記冷媒回路(60)の熱源側熱交換器(12)と膨張弁(15)との間に接続している。こうすると、上記蓄熱熱交換器(14)により、上記熱源側熱交換器(12)から流出した冷媒の温度をさらに下げることができ、上記冷凍効果を向上させることができる。これにより、上記冷凍効果が向上した分だけ、上記冷媒回路(10)における冷媒の循環量を少なくすることができ、上記圧縮機(11)の消費電力を低減することができる。
-Effect of Embodiment 3-
According to the third embodiment, the heat storage heat exchanger (14) is connected between the heat source side heat exchanger (12) and the expansion valve (15) of the refrigerant circuit (60). If it carries out like this, the temperature of the refrigerant | coolant which flowed out from the said heat-source side heat exchanger (12) can further be lowered | hung by the said heat storage heat exchanger (14), and the said freezing effect can be improved. Thereby, the circulation amount of the refrigerant in the refrigerant circuit (10) can be reduced by the amount that the refrigeration effect is improved, and the power consumption of the compressor (11) can be reduced.
 以上より、上記蓄熱熱交換器(14)を設けることで、消費電力を増やさずに空気調和装置(1)の冷凍能力を増やすことができる。 From the above, by providing the heat storage heat exchanger (14), the refrigeration capacity of the air conditioner (1) can be increased without increasing the power consumption.
  -実施形態3の変形例-
 図22は実施形態3の変形例に係る空気調和装置(1)の冷媒回路図であり、図23は蓄熱運転時の冷媒の流れを示し、図24は冷熱利用運転時の冷媒の流れを示している。図25は二酸化炭素のP-h線図上に冷熱利用運転時の冷凍サイクルを示した図である。
-Modification of Embodiment 3-
22 is a refrigerant circuit diagram of an air conditioner (1) according to a modification of the third embodiment. FIG. 23 shows the refrigerant flow during the heat storage operation, and FIG. 24 shows the refrigerant flow during the cold energy use operation. ing. FIG. 25 is a diagram showing a refrigeration cycle at the time of operation using cold energy on a Ph diagram of carbon dioxide.
 上記実施形態1の空気調和装置(1)では、上記蓄熱熱交換器(14)を上記室外熱交換器(12)と上記膨張弁との間に接続していたが、実施形態3の変形例の冷媒回路(70)では、上記蓄熱熱交換器(14)が上記熱源側熱交換器(12)と並列に接続されている。 In the air conditioner (1) of the first embodiment, the heat storage heat exchanger (14) is connected between the outdoor heat exchanger (12) and the expansion valve. In the refrigerant circuit (70), the heat storage heat exchanger (14) is connected in parallel with the heat source side heat exchanger (12).
 上記圧縮機(11)の吐出側から延びる冷媒配管は上記室外熱交換器(12)の一端に接続されている。上記室外熱交換器(12)の他端は上記流量調整弁(13)及び上記膨張弁(15)を介して上記室内熱交換器(16)の一端に接続されている。上記室内熱交換器(16)の他端は上記圧縮機(11)の吸入側に接続されている。 The refrigerant pipe extending from the discharge side of the compressor (11) is connected to one end of the outdoor heat exchanger (12). The other end of the outdoor heat exchanger (12) is connected to one end of the indoor heat exchanger (16) through the flow rate adjusting valve (13) and the expansion valve (15). The other end of the indoor heat exchanger (16) is connected to the suction side of the compressor (11).
 又、上記冷媒回路(70)には、上記室外熱交換器(12)と上記流量調整弁(13)とをバイパスするバイパス配管(23)が設けられ、上記室外熱交換器(12)側から上記流量調整弁(13)側へ向かって第12開閉弁(SV12)と上記蓄熱熱交換器(14)とが設けられている。そして、上記バイパス配管(23)における第12開閉弁(SV12)及び上記蓄熱熱交換器(14)の間から延びる分岐配管(24)が上記室内熱交換器(16)と上記圧縮機(11)とを接続する冷媒配管に連通している。この分岐配管(24)には、第13開閉弁(SV13)が接続されている。 The refrigerant circuit (70) is provided with a bypass pipe (23) that bypasses the outdoor heat exchanger (12) and the flow rate adjusting valve (13), and is provided from the outdoor heat exchanger (12) side. A twelfth on-off valve (SV12) and the heat storage heat exchanger (14) are provided toward the flow rate adjustment valve (13). A branch pipe (24) extending from between the twelfth on-off valve (SV12) and the heat storage heat exchanger (14) in the bypass pipe (23) is connected to the indoor heat exchanger (16) and the compressor (11). Is connected to the refrigerant pipe connecting the two. A thirteenth on-off valve (SV13) is connected to the branch pipe (24).
  -運転動作-
  〈蓄熱運転〉
 上記蓄熱運転では、図23に示すように、上記膨張弁(15)の開度が全閉になり、上記流量調整弁(13)の開度が必要に応じて調整される。又、上記第12開閉弁(SV12)が閉設定となり、上記第13開閉弁(SV13)が開設定となる。
-Driving operation-
<Heat storage operation>
In the heat storage operation, as shown in FIG. 23, the opening degree of the expansion valve (15) is fully closed, and the opening degree of the flow rate adjusting valve (13) is adjusted as necessary. The twelfth on-off valve (SV12) is set to be closed, and the thirteenth on-off valve (SV13) is set to be open.
 上記圧縮機(11)から吐出された超臨界状態の高圧冷媒は、上記室外熱交換器(12)に流入し、室外空気へ放熱した後、該室外熱交換器(12)を流出する。上記室外熱交換器(12)を流出した高圧冷媒は、上記流量調整弁(13)に流入し、その流量が調整されるとともに減圧された後、二相状態の低圧冷媒となって該流量調整弁(13)を流出する。上記流量調整弁(13)を流出した低圧冷媒は蓄熱熱交換器(14)に流入する。 The supercritical high-pressure refrigerant discharged from the compressor (11) flows into the outdoor heat exchanger (12), dissipates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12). The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), the flow rate is adjusted and the pressure is reduced, and then the low-pressure refrigerant is in a two-phase state. Outflow valve (13). The low-pressure refrigerant that has flowed out of the flow control valve (13) flows into the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)では、上記低圧冷媒と上記氷蓄熱タンク(2)内の水とが熱交換して、該氷蓄熱タンク(2)内の水が冷却されて氷になる。一方、上記氷蓄熱タンク(2)内の水から吸熱した低圧冷媒は低圧ガス冷媒となり、該蓄熱熱交換器(14)を流出する。 In the heat storage heat exchanger (14), the low-pressure refrigerant and water in the ice heat storage tank (2) exchange heat, and the water in the ice heat storage tank (2) is cooled to become ice. On the other hand, the low-pressure refrigerant that has absorbed heat from the water in the ice heat storage tank (2) becomes a low-pressure gas refrigerant and flows out of the heat storage heat exchanger (14).
 上記蓄熱熱交換器(14)を流出した低圧ガス冷媒は、上記第13開閉弁(SV13)を経て、上記圧縮機(11)に吸入されて所定の圧力まで圧縮されて超臨界状態の高圧冷媒となった後、上記圧縮機(11)から吐出される。このように冷媒が循環することにより、空気調和装置(1)において蓄熱運転が行われる。 The low-pressure gas refrigerant flowing out of the heat storage heat exchanger (14) is sucked into the compressor (11) through the thirteenth on-off valve (SV13) and compressed to a predetermined pressure to be supercritical high-pressure refrigerant. After that, it is discharged from the compressor (11). As the refrigerant circulates in this way, a heat storage operation is performed in the air conditioner (1).
  〈冷熱利用運転〉
 上記冷熱利用運転では、図24に示すように、上記膨張弁(15)と上記流量調整弁(13)の開度が必要に応じて調整される。又、上記第12開閉弁(SV12)が開設定となり、上記第13開閉弁(SV13)が閉設定となる。
<Cryogenic operation>
In the cold utilization operation, as shown in FIG. 24, the opening degrees of the expansion valve (15) and the flow rate adjustment valve (13) are adjusted as necessary. The twelfth on-off valve (SV12) is set to open, and the thirteenth on-off valve (SV13) is set to closed.
 上記圧縮機(11)から吐出された超臨界状態の高圧冷媒は分流して、一方が上記室外熱交換器(12)に流入し、他方が上記第12開閉弁(SV12)を経て、上記蓄熱熱交換器(14)に流入する(図24,図25の点b1)。 The supercritical high-pressure refrigerant discharged from the compressor (11) is diverted, one flows into the outdoor heat exchanger (12), and the other passes through the twelfth on-off valve (SV12) and the heat storage. It flows into the heat exchanger (14) (point b1 in FIGS. 24 and 25).
 上記室外熱交換器(12)に流入した高圧冷媒は、室外空気へ放熱した後、該室外熱交換器(12)を流出する(図24,図25の点c)。一方、上記蓄熱熱交換器(14)に流入した冷媒は、上記氷蓄熱タンク(2)内の氷と熱交換して、該氷蓄熱タンク(2)内の氷が融解して水になる。一方、上記冷媒は上記氷蓄熱タンク(2)内の氷に放熱して冷却された後、該蓄熱熱交換器(14)を流出する(図24,図25の点c2)。 The high-pressure refrigerant that has flowed into the outdoor heat exchanger (12) radiates heat to the outdoor air, and then flows out of the outdoor heat exchanger (12) (point c in FIGS. 24 and 25). On the other hand, the refrigerant flowing into the heat storage heat exchanger (14) exchanges heat with the ice in the ice heat storage tank (2), and the ice in the ice heat storage tank (2) melts to become water. On the other hand, after the refrigerant dissipates heat to the ice in the ice heat storage tank (2) and is cooled, it flows out of the heat storage heat exchanger (14) (point c2 in FIGS. 24 and 25).
 上記室外熱交換器(12)を流出した高圧冷媒は、上記流量調整弁(13)に流入し、その流量が調整されるとともに減圧された後、該流量調整弁(13)を流出する。上記流量調整弁(13)及び上記蓄熱熱交換器(14)を流出した各冷媒は合流した後(図24,図25の点c1)、上記膨張弁(15)に流入し、所定の圧力まで減圧されて二相状態の低圧冷媒となり、該膨張弁(15)を流出する(図24,図25の点d)。上記膨張弁(15)を流出した低圧冷媒は、上記室内熱交換器(16)に流入し、室内空気から吸熱して低圧ガス冷媒となった後、該室内熱交換器(16)から流出する(図24,図25の点a)。上記室内空気は、該室内空気の熱を上記低圧ガス冷媒に吸収させることにより冷却される。 The high-pressure refrigerant that has flowed out of the outdoor heat exchanger (12) flows into the flow rate adjustment valve (13), and after the flow rate is adjusted and reduced, the flow rate adjustment valve (13) flows out. The refrigerants flowing out of the flow rate adjusting valve (13) and the heat storage heat exchanger (14) merge (point c1 in FIGS. 24 and 25), flow into the expansion valve (15), and reach a predetermined pressure. The pressure is reduced to become a low-pressure refrigerant in a two-phase state, and flows out from the expansion valve (15) (point d in FIGS. 24 and 25). The low-pressure refrigerant that has flowed out of the expansion valve (15) flows into the indoor heat exchanger (16), absorbs heat from the indoor air, becomes low-pressure gas refrigerant, and then flows out of the indoor heat exchanger (16). (Point a in FIGS. 24 and 25). The indoor air is cooled by causing the low-pressure gas refrigerant to absorb the heat of the indoor air.
 上記室内熱交換器(16)から流出した低圧ガス冷媒は、上記圧縮機(11)に吸入され、所定の圧力まで圧縮されて超臨界状態の高圧冷媒となった後、該圧縮機(11)から吐出される(図24,図25の点b)。このように冷媒が循環することにより、空気調和装置(1)において冷熱利用運転が行われる。 The low-pressure gas refrigerant flowing out of the indoor heat exchanger (16) is sucked into the compressor (11) and compressed to a predetermined pressure to become a high-pressure refrigerant in a supercritical state, and then the compressor (11) (Point b in FIGS. 24 and 25). As the refrigerant circulates in this way, the cold air operation is performed in the air conditioner (1).
  -実施形態3の変形例の効果-
 上記実施形態3の変形例によれば、上記蓄熱熱交換器(14)を上記冷媒回路(70)の熱源側熱交換器(12)と並列に接続している。こうすると、上記圧縮機(11)から吐出された冷媒を分流させることができ、一方を上記熱源側熱交換器(12)で、他方を蓄熱熱交換器(14)で放熱させることができる。仮に、実施形態3と同様に、上記蓄熱熱交換器(14)を上記熱源側熱交換器(12)に直列に接続したとすると、蓄熱利用量(ピークシフト量)が小さく、蓄熱利用時の電力量が大きくなる。
-Effect of Modification of Embodiment 3-
According to the modification of Embodiment 3, the heat storage heat exchanger (14) is connected in parallel with the heat source side heat exchanger (12) of the refrigerant circuit (70). If it carries out like this, the refrigerant | coolant discharged from the said compressor (11) can be shunted, one side can be radiated with the said heat source side heat exchanger (12), and the other with the thermal storage heat exchanger (14). As in the third embodiment, if the heat storage heat exchanger (14) is connected in series to the heat source side heat exchanger (12), the heat storage use amount (peak shift amount) is small, and heat storage use The amount of power increases.
 上記実施形態3の変形例のように、上記蓄熱熱交換器(14)を熱源側熱交換器(12)と並列に接続して上記圧縮機構(11)から吐出された冷媒を分流させると、蓄熱利用量を大きくとれるので、利用運転時の電力量が小さくなる。 As in the modification of the third embodiment, when the heat storage heat exchanger (14) is connected in parallel with the heat source side heat exchanger (12) and the refrigerant discharged from the compression mechanism (11) is divided, Since the amount of heat storage use can be increased, the amount of power during use operation is reduced.
 《その他の実施形態》
 上記実施形態については、以下のような構成としてもよい。
<< Other Embodiments >>
About the said embodiment, it is good also as the following structures.
 本実施形態では、複数の開閉弁(SV)を用いて、上記空気調和装置(1)の運転状態を上記蓄熱運転又は上記冷熱利用運転に切り換えていたが、これに限定されず、例えば、三方弁や四方弁で上記空気調和装置(1)の運転状態を切り換えてもよい。 In the present embodiment, the operation state of the air conditioner (1) is switched to the heat storage operation or the cold energy use operation using a plurality of on-off valves (SV). However, the present invention is not limited to this. The operating state of the air conditioner (1) may be switched by a valve or a four-way valve.
 本実施形態では、上記空気調和装置(1)では、冷媒として二酸化炭素を用いていたが、これに限定されず、その他の自然冷媒であってもよい。この場合、その自然冷媒を封入した冷媒回路が超臨界冷凍サイクルを行うように構成する必要がある。 In the present embodiment, in the air conditioner (1), carbon dioxide is used as a refrigerant, but the present invention is not limited to this, and other natural refrigerants may be used. In this case, it is necessary to configure the refrigerant circuit in which the natural refrigerant is sealed to perform the supercritical refrigeration cycle.
 なお、以上の実施形態は、本質的に好ましい例示であって、本発明、その適用物、あるいはその用途の範囲を制限することを意図するものではない。 In addition, the above embodiment is an essentially preferable example, and is not intended to limit the scope of the present invention, its application, or its use.
 以上説明したように、本発明は、超臨界冷凍サイクルを行う冷媒回路を備えた冷凍装置について有用である。 As described above, the present invention is useful for a refrigeration apparatus including a refrigerant circuit that performs a supercritical refrigeration cycle.
  1 空気調和装置(冷凍装置)
  2 氷蓄熱タンク
  3 室外機
  4 室内機
 10 冷媒回路
 11 圧縮機(圧縮機構)
 12 室外熱交換器(熱源側熱交換器)
 14 蓄熱熱交換器
 15 膨張弁(膨張機構)
 16 室内熱交換器(利用側熱交換器)
1 Air conditioner (refrigeration equipment)
2 Ice heat storage tank 3 Outdoor unit 4 Indoor unit 10 Refrigerant circuit 11 Compressor (compression mechanism)
12 Outdoor heat exchanger (heat source side heat exchanger)
14 Heat storage heat exchanger 15 Expansion valve (expansion mechanism)
16 Indoor heat exchanger (use side heat exchanger)

Claims (5)

  1.  圧縮機構(11)と熱源側熱交換器(12)と膨張機構(15)と利用側熱交換器(16)とが接続されて超臨界冷凍サイクルを行う冷媒回路(10)を備えた冷凍装置であって、
     水又は氷を蓄熱媒体として貯蔵するとともに、上記冷媒回路(10)に接続されて蓄熱媒体と上記冷媒回路(10)の冷媒とを熱交換する蓄熱熱交換器(14)を有し、該蓄熱熱交換器(14)が蓄熱媒体の冷熱利用時に放熱器となる氷蓄熱タンク(2)を備え、
     上記圧縮機構(11)は、低段側圧縮機(11a)と高段側圧縮機(11b)とを備える一方、
     上記蓄熱熱交換器(14)は、上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続されていることを特徴とする冷凍装置。
    A refrigeration apparatus comprising a refrigerant circuit (10) that performs a supercritical refrigeration cycle by connecting a compression mechanism (11), a heat source side heat exchanger (12), an expansion mechanism (15), and a use side heat exchanger (16) Because
    A heat storage heat exchanger (14) for storing water or ice as a heat storage medium and exchanging heat between the heat storage medium and the refrigerant in the refrigerant circuit (10) connected to the refrigerant circuit (10); The heat exchanger (14) is equipped with an ice heat storage tank (2) that becomes a radiator when using the cold energy of the heat storage medium,
    The compression mechanism (11) includes a low-stage compressor (11a) and a high-stage compressor (11b),
    The refrigeration apparatus, wherein the heat storage heat exchanger (14) is connected between the low-stage compressor (11a) and the high-stage compressor (11b).
  2.  請求項1において、
     上記蓄熱熱交換器(14)は、上記低段側圧縮機(11a)と高段側圧縮機(11b)との間に接続された第1蓄熱熱交換器(14)であり、
     さらに、上記冷媒回路(10)の熱源側熱交換器(12)と膨張機構(15)との間に接続された第2蓄熱熱交換器(19)を備えていることを特徴とする冷凍装置。
    In claim 1,
    The heat storage heat exchanger (14) is a first heat storage heat exchanger (14) connected between the low stage compressor (11a) and the high stage compressor (11b),
    The refrigerating apparatus further comprises a second heat storage heat exchanger (19) connected between the heat source side heat exchanger (12) and the expansion mechanism (15) of the refrigerant circuit (10). .
  3.  請求項1において、
     上記冷媒回路(10)には、上記蓄熱熱交換器(14)を放熱器として氷蓄熱タンク(2)の冷熱を利用する冷熱利用運転と、上記蓄熱熱交換器(14)を蒸発器として氷蓄熱タンク(2)に冷熱を蓄熱する蓄熱運転とに切換可能な切換機構(SV)が設けられていることを特徴とする冷凍装置。
    In claim 1,
    In the refrigerant circuit (10), the heat storage heat exchanger (14) is used as a radiator and the cold storage operation using the cold heat of the ice storage tank (2) and the heat storage heat exchanger (14) is used as an ice A refrigeration apparatus comprising a switching mechanism (SV) capable of switching to a heat storage operation for storing cold energy in a heat storage tank (2).
  4.  請求項3において、
     上記冷媒回路(10)は、上記冷熱利用運転時には上記低段側圧縮機(11a)又は上記高段側圧縮機(11b)を起動するように構成されていることを特徴とする冷凍装置。
    In claim 3,
    The refrigerant circuit (10) is configured to start the low-stage compressor (11a) or the high-stage compressor (11b) at the time of the cold utilization operation.
  5.  請求項1において、
     上記冷媒回路(10)を流れる冷媒は二酸化炭素であることを特徴とする冷凍装置。
    In claim 1,
    The refrigeration apparatus characterized in that the refrigerant flowing through the refrigerant circuit (10) is carbon dioxide.
PCT/JP2009/005246 2008-10-08 2009-10-08 Refrigeration device WO2010041453A1 (en)

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EP2587189A3 (en) * 2011-10-27 2014-05-14 LG Electronics Inc. Air conditioner
EP3045843A4 (en) * 2013-09-10 2017-05-31 Mitsubishi Electric Corporation Refrigerating device

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JP7099201B2 (en) * 2018-09-05 2022-07-12 富士電機株式会社 Heat pump device

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JP2006308251A (en) * 2005-04-28 2006-11-09 Daikin Ind Ltd Regenerative heat recovery device
JP2008025904A (en) * 2006-07-20 2008-02-07 Daikin Ind Ltd Heat pump device

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JP2006308251A (en) * 2005-04-28 2006-11-09 Daikin Ind Ltd Regenerative heat recovery device
JP2008025904A (en) * 2006-07-20 2008-02-07 Daikin Ind Ltd Heat pump device

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Publication number Priority date Publication date Assignee Title
EP2587189A3 (en) * 2011-10-27 2014-05-14 LG Electronics Inc. Air conditioner
US9267720B2 (en) 2011-10-27 2016-02-23 Lg Electronics Inc. Air conditioner and method of controlling the same
EP3045843A4 (en) * 2013-09-10 2017-05-31 Mitsubishi Electric Corporation Refrigerating device
US10082325B2 (en) 2013-09-10 2018-09-25 Mitsubishi Electric Corporation Refrigerating apparatus

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