WO2010022547A1 - 一种纸基复合材料 - Google Patents

一种纸基复合材料 Download PDF

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Publication number
WO2010022547A1
WO2010022547A1 PCT/CN2008/001771 CN2008001771W WO2010022547A1 WO 2010022547 A1 WO2010022547 A1 WO 2010022547A1 CN 2008001771 W CN2008001771 W CN 2008001771W WO 2010022547 A1 WO2010022547 A1 WO 2010022547A1
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WO
WIPO (PCT)
Prior art keywords
paper
composite material
based composite
layer
rope
Prior art date
Application number
PCT/CN2008/001771
Other languages
English (en)
French (fr)
Inventor
何鹤祥
Original Assignee
纸艺制品有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 纸艺制品有限公司 filed Critical 纸艺制品有限公司
Priority to JP2010543355A priority Critical patent/JP4734478B2/ja
Priority to US13/060,496 priority patent/US20120015137A1/en
Publication of WO2010022547A1 publication Critical patent/WO2010022547A1/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/12—Conjugate fibres, e.g. core/sheath or side-by-side
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/003—Interior finishings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
    • B60R13/0212—Roof or head liners
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23943—Flock surface
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31591—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3854—Woven fabric with a preformed polymeric film or sheet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet

Definitions

  • the present invention relates to a paper-based composite material for use in the manufacture of interior parts such as automotive ceilings. Background technique
  • the interior parts and ceiling of the existing automobile are made of a composite layer material
  • the composite layer material generally consists of two to three layers, wherein the layer is a polyurethane foam layer, and the two sides of the middle layer are non-woven fabric or Suede layer.
  • the polyurethane layer has the advantages of light weight and good thermal insulation, and has the disadvantages of low strength and poor ripening stability.
  • people generally add some fiber materials in the middle layer to strengthen their strength, such as plant fiber, glass fiber, etc., but this method is not easy to form, the production efficiency is low, and because these fibers are thin, the length is short, the layer
  • the overall rigidity of the material is still low; in addition, the problem of poor curing and manufacturing stability is still ubiquitous. Summary of the invention
  • the technical solution adopted by the present invention is: a paper-based composite material comprising a middle layer and a surface layer at least adhered to one side of the middle layer, wherein the middle layer is formed by foaming and aging of polyurethane paper into a paper rope.
  • the paper rope is wound from a paper mixed resin or an adhesive.
  • the paper rope which is wound by the paper mixed resin or the adhesive is light in weight, molded, and the combination of the paper-based composite material and the polyurethane is good, and the overall rigidity of the entire paper-based composite material is good, and It can effectively improve the ripening stability of polyurethane, reduce the expansion of polyurethane, and is not easy to deform.
  • the molding is easy and the production efficiency is high.
  • the invention is simple to manufacture, has strong practicability and popularization value, and can be widely used in automotive interior panels such as ceilings.
  • Figure 1 is a cross-sectional view of a paper-based composite material
  • Figure 2 is a cross-sectional view taken along line A_A of Figure 1;
  • FIG. 3 is a cross-sectional view showing another structure of the paper rope. detailed description
  • a paper-based composite material includes a middle layer 1 and a surface layer 2 adhered to at least one side of the middle layer 1.
  • the surface layer 2 of the one side may be a non-woven fabric for reinforcement and bonding, and this surface layer may be omitted.
  • the surface layer 2 on the other side may be decorative woven fabric, flocking, PU decorative layer, and crust polyurethane for decoration.
  • the middle layer 1 is formed by foaming and aging of a polyurethane paper rope 3, and the paper rope 3 is passed through the entire polyurethane layer.
  • the paper rope 3 is made of a paper-mixed resin or an adhesive, and the paper may be kraft paper or composite paper, and the paper-made resin or the adhesive-rolled paper rope 3 is light in weight and strong in strength.
  • the paper rope 3 in the middle layer 1 is woven into a mesh shape.
  • the paper rope 3 is divided into a horizontal direction and a longitudinal direction, and the horizontal and vertical paper ropes 3 are alternately woven together to form a paper web, so that the middle layer 1 formed by foaming is more strong.
  • the paper rope 3 is provided with a fiber-reinforced core 4 which is added during the process of winding the paper rope 3 and bonded to the paper by a resin or an adhesive.
  • the fiber reinforced core 4 is reinforced to strengthen the rigidity of the paper rope 3 to make the rigidity of the entire paper-based composite material better.
  • the fiber-reinforced core 4 is preferably a plant fiber or a glass fiber.

Description

一种纸基复合材料
技术领域
本发明涉及一种用于制造汽车顶棚等内饰件的纸基复合材料。 背景技术
现有的汽车的内饰件及顶棚由复合层状材料制成， 复合层状材料一般由两层至三层 所组成， 其中层是聚氨脂发泡层， 中层的两面是无纺布或绒面层。 聚氨脂层的优点是质 轻、 具有良好的隔热保温作用， 缺点是强度低， 熟化稳定性差。 为解决强度问题， 人们 在中层中一般会加一些纤维材料以加强其强度、 如植物纤维、 玻璃纤维等， 但这种方式 成型不易， 生产效率低， 且由于这些纤维较细， 长度短， 层状材料的整体刚性仍然较低； 此外， 熟化及制造的稳定性差的问题仍然普遍存在。 发明内容
本发明的目的在于提供一种强度高、 熟化稳定性及成型好的纸基复合材料。
为解决上述技术问题， 本发明采用的技术方案为： 一种纸基复合材料， 包括中层和 至少粘在中层一面的表层， 所述的中层是由聚氨脂加入纸绳发泡熟化而成， 所述的纸 绳是由纸张混合树脂或胶粘剂卷成的。
由于采用了上述的结构， 本发明由纸张混合树脂或胶粘剂卷成的纸绳质量轻， 模塑 好， 纸基复合材料与聚氨脂的结合好， 整个纸基复合材料的整体刚性好， 并可有效地提 高聚氨脂的熟化稳定性， 减少聚氨脂膨胀， 不易变形。 此外成型容易， 生产效率高。 本 发明制作简单， 具有很强的实用性和推广价值， 可广泛用于汽车的内饰板如顶棚等处。 附图说明
下面结合附图对本发明的具体实施方式作进一步详细的描述，但并不构成对本发明 的任何限制。
图 1是一种纸基复合材料的剖视图；
图 2是沿图 1中 A_A线的剖视图；
图 3是纸绳的另一结构的截面图。 具体实施方式
如图 1和图 2所示， 一种纸基复合材料， 包括中层 1和至少粘在中层 1一面的表层 2。 所述的一面的表层 2可以是无纺布， 作加固和粘合用， 这一表层可省略。 另一面的 表层 2 可以是装饰纺织布、 植绒、 PU装饰层、 结皮聚氨脂， 作装饰用。 所述的中层 1 是由聚氨脂加入纸绳 3发泡熟化而成， 纸绳 3贯穿整个聚氨脂层。 所述的纸绳 3是由纸 张混合树脂或胶粘剂卷成的， 所述的纸张可以是牛皮纸或复合纸， 纸张混合树脂或胶粘 剂卷成的纸绳 3质轻且强度好。
所述的中层 1中的纸绳 3编织为网状。 纸绳 3分为横向和纵向， 横向和纵向的纸绳 3交替编织在一起形成纸网， 这样发泡形成的中层 1强度更好。
如图 3所示， 所述的纸绳 3中设有纤维加强芯 4， 纤维加强芯 4在卷纸绳 3的过程 中加入， 通过树脂或胶粘剂与纸张粘合。 纤维加强芯 4加加强纸绳 3的刚性， 使整个纸 基复合材料的刚性更良好。 所述的纤维加强芯 4优选为植物纤维或玻璃纤维。
总之， 本发明虽然例举了上述优选实施方式， 但是应该说明， 显然本领域的技术人 员可以进行各种变化和改型。 因此， 除非这样的变化和改型偏离了本发明的范围， 否则 都应该包括在本发明的保护范围之内。

Claims

权 利 要 求
1. 一种纸基复合材料， 包括中层（1)和至少粘在中层（1)一面的表层（2)， 其特征在于： 所述的中层 （1) 是由聚氨脂加入纸绳 （3)发泡熟化而成， 所述的 纸绳 （3) 是由纸张混合树脂或胶粘剂卷成的。
2.按照权利要求 1所述的一种纸基复合材料，其特征在于：所述的中层（1) 中的纸绳 （3) 编织为网状。
3.按照权利要求 1所述的一种纸基复合材料，其特征在于：所述的纸绳（3) 中设有通过树脂或胶粘剂与纸张粘合的纤维加强芯 （4)。
4. 按照权利要求 1至 3中任一项所述的一种纸基复合材料， 其特征在于： 所述的纸张是牛皮纸或复合纸。
5. 按照权利要求 3所述的一种纸基复合材料， 其特征在于： 所述的纤维加 强芯 （4) 是植物纤维或玻璃纤维。
6. 按照权利要求 1所述的一种纸基复合材料，其特征在于：所述的表层（2) 是无纺布。
7. 按照权利要求 1所述的一种纸基复合材料， 其特征在于： 所述的表层 （2)是 装饰纺织布、 植绒、 PU装饰层、 结皮聚氨脂。
PCT/CN2008/001771 2008-08-29 2008-10-21 一种纸基复合材料 WO2010022547A1 (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2010543355A JP4734478B2 (ja) 2008-08-29 2008-10-21 紙基材複合材料
US13/060,496 US20120015137A1 (en) 2008-08-29 2008-10-21 Paper-based composite material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2008201894196U CN201427420Y (zh) 2008-08-29 2008-08-29 一种纸基复合材料
CN200820189419.6 2008-08-29

Publications (1)

Publication Number Publication Date
WO2010022547A1 true WO2010022547A1 (zh) 2010-03-04

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JP (1) JP4734478B2 (zh)
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WO (1) WO2010022547A1 (zh)

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CN103294439B (zh) * 2013-06-28 2016-03-02 华为技术有限公司 一种图像更新方法、系统及装置
WO2016143647A1 (ja) 2015-03-10 2016-09-15 国立大学法人 東京大学 ゲル前駆体クラスターを用いた低濃度ゲルの製造方法、及び当該製造方法により得られるゲル
SG10201502009XA (en) * 2015-03-16 2016-01-28 Ha Fee Ho Pre-Impregnated Composite Material

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CN1034446A (zh) * 1988-11-03 1989-08-02 钱幼沧 复合绝缘材料
CN1367733A (zh) * 1999-08-04 2002-09-04 拜尔公司 生产具有夹心结构的汽车内饰材料的方法
JP2001062950A (ja) * 1999-08-30 2001-03-13 Sekisui Chem Co Ltd 複合材およびその製造法
WO2003022566A1 (en) * 2001-09-12 2003-03-20 Apache Products Company Composite foam products and method

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US20120015137A1 (en) 2012-01-19
JP4734478B2 (ja) 2011-07-27
JP2011510837A (ja) 2011-04-07
CN201427420Y (zh) 2010-03-24

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