WO2010008237A2 - Appareil pour extraire du gaz et générer de l'énergie thermique par dégradation de h2o à température élevée - Google Patents

Appareil pour extraire du gaz et générer de l'énergie thermique par dégradation de h2o à température élevée Download PDF

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Publication number
WO2010008237A2
WO2010008237A2 PCT/KR2009/003949 KR2009003949W WO2010008237A2 WO 2010008237 A2 WO2010008237 A2 WO 2010008237A2 KR 2009003949 W KR2009003949 W KR 2009003949W WO 2010008237 A2 WO2010008237 A2 WO 2010008237A2
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WO
WIPO (PCT)
Prior art keywords
reaction tank
hydrogen
thermal energy
extraction
decomposition
Prior art date
Application number
PCT/KR2009/003949
Other languages
English (en)
Korean (ko)
Other versions
WO2010008237A3 (fr
Inventor
나규성
Original Assignee
Ra Kyu Sung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020090065068A external-priority patent/KR20100009502A/ko
Application filed by Ra Kyu Sung filed Critical Ra Kyu Sung
Publication of WO2010008237A2 publication Critical patent/WO2010008237A2/fr
Publication of WO2010008237A3 publication Critical patent/WO2010008237A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0203—Preparation of oxygen from inorganic compounds
    • C01B13/0207—Water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/042—Decomposition of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00117—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates to a gas extraction and thermal energy generating device according to the high temperature decomposition of H 2 O, and more particularly to a technique for obtaining not only the energy by thermal decomposition of water, but also useful resources hydrogen and oxygen.
  • Nuclear resources are used as other energy sources. Nuclear resources use energy generated by the transformation of nuclear nuclei (nuclear fission and fusion), in particular nuclear power generation using fission. Although such nuclear resources have high energy generation efficiency and high utilization rates, there are problems in handling and waste disposal. In addition, since the miniaturization is difficult, there is a problem that the use is greatly limited.
  • the present invention was derived to solve the problems according to the prior art described above, and an object of the present invention is to provide a technique for obtaining hydrogen and oxygen, which are useful resources using water, which is easy to handle and obtain.
  • Another object of the present invention is to provide a technique capable of generating energy using extracted hydrogen and / or oxygen.
  • the apparatus heats water (H 2 O) to decompose hydrogen and oxygen gas by high temperature, extract the decomposed gas, and extract a part of the extracted gas.
  • the heat of decomposition can be reused for the decomposition of the water and used for the decomposition of the water.
  • the high temperature at which the water is decomposed into hydrogen and oxygen may be 550 degrees Celsius or more as the first temperature range.
  • the hydrogen and oxygen may be further heated to a second temperature range so as to separate and extract the hydrogen and oxygen, so that the hydrogen and oxygen are separated into layers, and the second temperature range is 750 degrees Celsius.
  • the second temperature range may be 850 degrees Celsius or more and 950 degrees or less so that the separation purity of the separated hydrogen and oxygen is high.
  • the apparatus includes a reaction tank including a water supply unit to which water is supplied from the outside, a heating unit for heating the reaction tank, and connected to an upper side of the reaction tank to extract hydrogen generated in the reaction tank. It may include a hydrogen extraction tube.
  • the hydrogen extraction tube may be a hydrogen extraction tube for combustion for use of the generated hydrogen in the combustion of the heat energy generator or a storage hydrogen extraction tube for storing the generated hydrogen in an external reservoir
  • the heating unit is
  • a combustion furnace configured to penetrate the reaction tank body may include a fuel transfer pipe for supplying fuel into the combustion furnace, and an igniter for igniting the fuel.
  • a first valve and a second valve may be installed in the combustion hydrogen extraction pipe and the storage hydrogen extraction pipe, respectively, to control whether the extraction pipes are opened or closed.
  • a controller for controlling the operation of the heating unit, the first valve and the second valve according to the temperature may be further included.
  • the lower side of the reaction tank may further include an oxygen extraction tube for extracting the oxygen generated in the reaction tank, the oxygen extraction tube is for combustion for using the generated oxygen as a combustion of the thermal energy generating device
  • An oxygen extraction tube or a storage oxygen extraction tube for storing the generated oxygen in an external reservoir wherein the combustion oxygen extraction tube and the storage oxygen extraction tube are respectively controlled by a third valve and a third valve to control the opening and closing of the extraction tubes.
  • Four valves can be installed.
  • it may further include a temperature sensor for measuring the temperature inside the reaction tank and delivers to the controller, the thermal energy generating device is connected to the side of the reaction tank for supplying water and the control of the controller And a fifth valve for controlling whether the water supply pipe is opened or closed, and further comprising a pressure sensor for measuring the pressure inside the reaction tank and transmitting the pressure to the controller. The opening and closing amount of the fifth valve can be adjusted.
  • the fifth valve of the present invention may be a check valve for preventing the back flow so that the gas inside the reaction tank does not flow back by the pressure of the reaction tank.
  • the controller may block the supply of fuel supplied through the fuel delivery pipe when the first valve is opened.
  • the controller may open the first valve when the temperature inside the reaction tank measured by the temperature sensor is 750 degrees Celsius or more, the second range temperature.
  • the controller of the present invention may open the second valve when the temperature inside the reaction tank is 850 degrees Celsius or more by the temperature sensor.
  • a cooler for cooling the hot hydrogen to be transported may be connected to one side of the storage hydrogen extraction pipe.
  • one end of the water supply pipe may be connected to the water reservoir for storing the water to be forcibly supplied by the pump at a certain level.
  • the heat energy generating device casing may be installed standing in the vertical direction.
  • the upper portion of the heat energy generating device may further include a cover for discharging the heat of combustion to the outside, the cover is a heat insulating cap covering the upper portion of the reaction tank, the upper portion of the heat in the combustion heat is insulated for thermal insulation of the reaction tank
  • the lid is mounted, and the top of the heat insulating lid may be equipped with a control lid which is adjusted in height to adjust the discharge of the heat of combustion.
  • the thermal energy generating device may further include a control valve that operates to discharge the gas in the reaction tank to the outside by a pressure sensor when the pressure in the reaction tank is more than a predetermined pressure.
  • the safety valve to operate so that the gas inside the reaction tank is discharged to the outside by a pressure sensor when the pressure inside the reaction tank is more than a predetermined pressure even when the control valve is operated. valve may be further included.
  • the hydrogen extraction tube, the oxygen extraction tube, the water light pipe, the igniter may be installed to each temperature sensor to operate only at a predetermined temperature or more.
  • hydrogen and oxygen which are useful resources can be obtained by pyrolyzing water which is easy to handle and obtain.
  • FIG. 1 is a side cross-sectional view of a thermal energy generating device according to a first embodiment of the present invention.
  • FIG. 2 illustrates a state in which fuel and water are supplied to FIG. 1.
  • FIG. 3 illustrates a state in which water vapor is formed inside the reaction tank in FIG. 1.
  • FIG. 4 illustrates a state in which hydrogen for combustion is supplied in FIG. 1.
  • FIG. 5 illustrates a state in which hydrogen and oxygen for storage are extracted in FIG. 1.
  • FIG. 6 is a side sectional view of a heat energy generating device according to a second embodiment of the present invention.
  • FIG. 7 is an external view of a horizontal casing of an embodiment of the present invention.
  • FIG. 8 is an exploded view of the vertical casing according to the application of the present invention.
  • FIG. 9 is a vertical casing coupling of FIG.
  • FIG. 10 is a vertical casing installation state of FIG.
  • thermal energy generator 110,210,310 casing
  • reaction tanks 130,230,330 combustion furnace
  • 140,240,340 hydrogen extraction pipe for combustion 142,242,342: hydrogen extraction pipe for storage
  • igniter 160,260,360 water supply pipe
  • FIG. 1 is a side cross-sectional view of a thermal energy generating device according to a first embodiment of the present invention.
  • the gas extraction and thermal energy generating apparatus 100 according to the high temperature decomposition of water according to the first embodiment (100: for convenience of description, hereinafter, unless otherwise stated, 'gas extraction according to high temperature decomposition of water)
  • the 'heat energy generator' is briefly referred to as a 'heat energy generator', and the casing 110 constitutes an appearance of the heat energy generator 100.
  • the reaction tank 120 is installed in the inner space of the casing 110, and a combustion furnace 130 penetrating the body is formed.
  • the heating unit is coupled to one side of the reaction tank 120 to heat the reaction tank 120.
  • the heating unit includes a fuel transfer pipe 150 for supplying fuel into the combustion furnace 130 and an igniter 152 for igniting the fuel.
  • the fuel used is preferably diesel or LPG, but it is not limited thereto. Of course, general fossil fuel may be used.
  • the igniter 152 ignites the fuel supplied as fuel during the initial operation, and then ignites the hydrogen when hydrogen is supplied through the combustion hydrogen extraction pipe 140.
  • the hydrogen extraction pipe 140 for combustion is connected to the other upper side of the reaction tank 120 to transfer the hydrogen generated in the reaction tank 120 to the combustion furnace 130.
  • the first valve 141 controls whether the combustion hydrogen extraction pipe 140 is opened or closed under the control of the controller.
  • the storage hydrogen extraction pipe 142 is connected to an upper side of the reaction tank 120 to transfer the hydrogen generated in the reaction tank 120 to a hydrogen storage tank (not shown).
  • the second valve 143 controls whether the storage hydrogen extraction pipe 142 is opened or closed under the control of the controller.
  • the storage oxygen extraction pipe 144 is connected to one lower side of the reaction tank 120 to transfer oxygen generated in the reaction tank 120 to an oxygen storage tank (not shown).
  • the fourth valve 145 controls whether the storage oxygen extraction pipe 144 is opened or closed under the control of the controller.
  • the water supply pipe 160 is connected to the side of the reaction tank 120 to supply water.
  • the fifth valve 161 controls whether the water supply pipe 160 is opened or closed under the control of the controller.
  • the fifth valve 151 uses a check valve for preventing a back flow so that the gas inside the reaction tank does not flow back due to the pressure of the reaction tank.
  • the temperature sensor 122 measures the temperature inside the reaction tank 120 and transmits the temperature to the controller.
  • the pressure sensor 124 measures the pressure inside the reaction tank 120 and transmits the pressure to the controller.
  • a controller (not shown) controls the operation of the heater and valves in accordance with the temperature or pressure inside the reaction tank 120.
  • FIG. 2 illustrates a state in which fuel and water are supplied from FIG. 1
  • FIG. 3 illustrates a state in which water vapor is formed inside the reaction tank in FIG. 1
  • FIG. 4 is a state in which hydrogen for combustion is supplied in FIG. 1.
  • 5 shows a state in which hydrogen and oxygen for storage are extracted in FIG. 1.
  • the fuel 155 transferred through the fuel transfer pipe 150 is supplied to the combustion furnace 130 and ignited by the igniter 152.
  • the fifth valve 161 is opened so that the water 165 transferred through the water supply pipe 160 is supplied into the reaction tank 120. The state at this time is shown in FIG.
  • the reaction tank 120 is heated by the combustion heat of the fuel complexed in the combustion furnace 130, whereby the water 165 supplied into the reaction tank 120 becomes the steam 166.
  • the fifth valve 161 When the set temperature and pressure conditions are reached, the fifth valve 161 is closed. At this time, the temperature inside the reaction tank 120 is more than 100 degrees Celsius, and as the water 165 becomes water vapor 166, the internal pressure increases. The state at this time is shown in FIG.
  • the steam 166 is pyrolyzed, and the upper portion of the reaction tank 120 is relatively Hydrogen 167 having a low specific gravity is produced and oxygen 168 having a large specific gravity is produced at the lower portion.
  • the reaction tank 120 When the reaction tank 120 is further heated at the time when hydrogen and oxygen are decomposed, and the temperature inside the tank is 750 degrees Celsius or more, since most of the decomposed hydrogen and oxygen are separated from the upper and lower layers, the decomposed hydrogen can be discharged. Done.
  • the generated hydrogen 167 is transferred to the combustion furnace 130 through the hydrogen extraction pipe 140 for combustion as the first valve 141 is opened, and is ignited by the igniter 152 to react with the reaction tank 120. ) Is used to heat.
  • the fuel delivery pipe 150 cuts off the fuel supply under the control of the controller.
  • water is supplied through the water supply pipe 160 such that the pressure inside the reaction tank 120 is constant by the pressure sensor 124, and the supplied water is immediately pyrolyzed. The state at this time is shown in FIG.
  • the second valve 143 is opened to store the hydrogen extraction pipe 142. Through the pure water of high purity is transferred to the hydrogen storage tank. The state at this time is shown in FIG. On the other hand, since such combustion is performed using hydrogen and oxygen, no separate exhaust gas or pollutants are emitted, and only water is generated, so that it does not cause environmental pollution.
  • FIG. 6 is a side sectional view of a heat energy generating device according to a second embodiment of the present invention.
  • the heat energy generator 200 according to the second embodiment of the present invention is compared with the heat energy generator 100 according to the first embodiment of the combustion oxygen extraction pipe 246 and the fourth valve 247. ) Are substantially the same except that they are further combined.
  • the combustion oxygen extraction tube 246 is connected to the other lower side of the reaction tank 220 to transfer the oxygen generated in the reaction tank 220 to the combustion furnace 230.
  • the fourth valve 247 controls whether the combustion oxygen extraction tube is opened or closed under the control of the controller.
  • the heat energy generator 200 can supply oxygen required for combustion of hydrogen without external air.
  • the daily output is 432,000 rubes (18,000 ⁇ 24 hours)
  • the 30-day output is 12,960,000 rubes (432,000 ⁇ 30 days)
  • the annual output is 155,520,000 rubes (12,960,000 ⁇ 12 months).
  • FIG. 8 is an exploded view of the vertical casing according to the third embodiment of the present invention
  • FIG. 9 is a vertical casing coupling diagram of FIG. 8
  • FIG. 10 is a vertical casing installation state of FIG. 8.
  • the vertical thermal energy generator 300 is installed by standing the casing 310 in a vertical direction as shown in FIGS. 8 to 10, and a combustion tank penetrating the body in the reaction tank 320 installed in the inner space. 330 is formed, the heat insulating cap 370 is mounted on the upper portion and the heat insulating lid 380 is flowed by the heat of combustion discharged through the combustion furnace 330 on the upper portion of the heat of the combustion can be controlled
  • the adjusting lid 380 is configured to be seated.
  • a heating unit including a fuel transfer pipe 350 and an igniter 352 is configured at a lower portion thereof, and a combustion hydrogen extraction pipe 340 for supplying hydrogen generated in the reaction tank 320 is provided at one side. .
  • one side of the casing 310 is provided with a water tank 362 for storing the water to be transmitted through the water supply pipe 360 to the reaction tank 320, the water tank 363 is composed of a glass tube with a scale of water It is desirable to allow consumption to be checked.
  • the storage hydrogen extraction pipe 342 for transferring the hydrogen generated in the reaction tank 320 to the hydrogen storage tank (not shown) is configured to be connected, one end of the storage hydrogen extraction pipe 342 As in 10, the three coolers 390 are configured to be sequentially connected to cool the high temperature hydrogen.
  • the lower one side of the reaction tank 320 can be confirmed that the storage oxygen extraction pipe 344 for connecting the oxygen generated therein to the oxygen storage tank (not shown) is configured.
  • one or more coolers capable of cooling high temperature oxygen may be included.
  • reference numeral 301 is a control valve (control valve), when the pressure inside the reaction tank 320 is more than a predetermined pressure by a pressure sensor (not shown) the control valve 301 is opened while the reaction tank Oxygen in 320 is discharged to the outside.
  • 302 is a safety valve (safty valve), when the pressure control in the reaction tank 320 is not possible to control even when the control valve is open, the safety valve to prevent accidents such as tank explosion due to high pressure Is opened to allow the gas inside the reaction tank 320 to be discharged to the outside.
  • the temperature sensor (303, 304, 305, 306) is mounted to the combustion hydrogen extraction pipe 340, the storage oxygen extraction pipe 344, the water supply pipe 360, the igniter 352, respectively, the hydrogen extraction pipe,
  • the valve mounted on the water supply pipe and the oxygen extraction pipe is configured to open.
  • the storage hydrogen extraction tube 342, the combustion oxygen extract tube 346 may be equipped with a temperature sensor.
  • the igniter when the predetermined temperature is above, the igniter is turned off so that the temperature sensor is mounted on the igniter so that the reactor itself stops operating.
  • the water stored in the water tank 362 is pumped by the water supply pipe. It is supplied into the reaction tank 320 through 360.
  • the reaction tank 320 is heated by the combustion heat of the fuel ignited in the combustion furnace 330, and the internal pressure increases as the supplied water changes to a vapor state, thereby increasing hydrogen and oxygen due to a difference in pyrolysis specific gravity of water vapor. Will be created.
  • the hydrogen completely separated by continuous heating is moved downward through the hydrogen extraction pipe 340 for combustion and then ignited by the igniter 352 to continuously heat the reaction tank 320. .
  • pure hydrogen having high purity is continuously transferred through the storage hydrogen extraction pipe 342 to be cooled in the cooler 390 and then stored in the hydrogen storage tank by the continuous heating action.
  • the oxygen generated in the reaction tank 320 is transferred to the lower through the combustion oxygen extraction pipe 346 is used for the ignition action by the igniter 352, the high purity oxygen is a separate storage oxygen extraction pipe Transferred through 344 may be stored in an oxygen storage tank (not shown).
  • the daily output is 720,000 rubes (30,000 ⁇ 24 hours)
  • the 30-day output is 21,600,000 rubes (720,000 ⁇ 30 days)
  • the annual output is 259,200,000 rubes (22,600,000 ⁇ 12 months).

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

L'invention concerne un appareil pour extraire du gaz et générer de l'énergie thermique par dégradation de H2O à température élevée. Ledit appareil de l'invention est supposé obtenir des ressources utiles en hydrogène et en oxygène par dégradation thermique de l'eau. L'appareil comprend une enveloppe, un réservoir de réacteur qui est installé à l'intérieur de l'enveloppe et qui comprend un four de combustion traversant son corps, une partie dispositif de chauffage combinée au four de combustion sur un côté pour chauffer le réservoir du réacteur, un tube d'extraction d'hydrogène qui est relié à un côté de la partie supérieure du réservoir du réacteur afin d'alimenter de réservoir de stockage en hydrogène générée dans le réservoir du réacteur; un tube d'alimentation en eau relié au côté du réservoir du réacteur pour fournir de l'eau; un capteur de température qui mesure la température à l'intérieur du réservoir du réacteur et la transmet à un contrôleur; et un contrôleur qui commande le fonctionnement de la partie dispositif de chauffage et de soupapes en fonction de la température à l'intérieur du réservoir du réacteur.
PCT/KR2009/003949 2008-07-17 2009-07-17 Appareil pour extraire du gaz et générer de l'énergie thermique par dégradation de h2o à température élevée WO2010008237A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2008-0069482 2008-07-17
KR20080069482 2008-07-17
KR10-2009-0065068 2009-07-16
KR1020090065068A KR20100009502A (ko) 2008-07-17 2009-07-16 Ｈ₂ｏ의 고온 분해에 따른 기체 추출 및 열에너지 발생장치

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WO2010008237A2 true WO2010008237A2 (fr) 2010-01-21
WO2010008237A3 WO2010008237A3 (fr) 2010-04-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014008753A1 (fr) * 2012-07-09 2014-01-16 Guo Zhinan Four industriel alimenté par plasma d'eau
GB2541033A (en) * 2015-08-07 2017-02-08 Ultimate Engines Ltd Reactor
CN110127606A (zh) * 2019-06-26 2019-08-16 张朝林 一种水高温分解为氢气和氧气的方法及分离器

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3901669A (en) * 1973-11-05 1975-08-26 Sun Ventures Inc Manufacture of hydrogen from high temperature steam
US4278650A (en) * 1980-03-24 1981-07-14 Organization Control Services, Inc. Method for producing oxygen and hydrogen from water
US6521205B1 (en) * 1998-05-05 2003-02-18 SHEC Labs—Solar Hydrogen Energy Corporation Process for the production of hydrogen by thermal decomposition of water, and apparatus therefor
KR20040004799A (ko) * 2002-07-05 2004-01-16 한국과학기술연구원 메탄을 열분해하여 수소와 카본블랙을 동시에 제조하는방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3901669A (en) * 1973-11-05 1975-08-26 Sun Ventures Inc Manufacture of hydrogen from high temperature steam
US4278650A (en) * 1980-03-24 1981-07-14 Organization Control Services, Inc. Method for producing oxygen and hydrogen from water
US6521205B1 (en) * 1998-05-05 2003-02-18 SHEC Labs—Solar Hydrogen Energy Corporation Process for the production of hydrogen by thermal decomposition of water, and apparatus therefor
KR20040004799A (ko) * 2002-07-05 2004-01-16 한국과학기술연구원 메탄을 열분해하여 수소와 카본블랙을 동시에 제조하는방법

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014008753A1 (fr) * 2012-07-09 2014-01-16 Guo Zhinan Four industriel alimenté par plasma d'eau
GB2541033A (en) * 2015-08-07 2017-02-08 Ultimate Engines Ltd Reactor
CN110127606A (zh) * 2019-06-26 2019-08-16 张朝林 一种水高温分解为氢气和氧气的方法及分离器

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