WO2010005190A3 - 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법 - Google Patents

올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법 Download PDF

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Publication number
WO2010005190A3
WO2010005190A3 PCT/KR2009/003342 KR2009003342W WO2010005190A3 WO 2010005190 A3 WO2010005190 A3 WO 2010005190A3 KR 2009003342 W KR2009003342 W KR 2009003342W WO 2010005190 A3 WO2010005190 A3 WO 2010005190A3
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WO
WIPO (PCT)
Prior art keywords
olefin polymerization
same
polymerization catalyst
polymerization method
compound represented
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PCT/KR2009/003342
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English (en)
French (fr)
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WO2010005190A2 (ko
Inventor
홍사문
강성우
전용재
손병길
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대림산업
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Publication of WO2010005190A2 publication Critical patent/WO2010005190A2/ko
Publication of WO2010005190A3 publication Critical patent/WO2010005190A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

본 발명은 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법에 관한 것으로서, 본 발명의 올레핀 중합 촉매는 M1R1 lR2 mR3 n　또는 R2 mR3 nM1R1 l-Q-R1 lM1R2 mR3 n 로 표시되는 유기 금속 화합물; M2R4 pXq 로 표시되는 유기 전이금속 화합물 및 M2X4 로 표시되는 유기 전이금속 화합물; 및 알루미녹산을 포함한다. 또한, 본 발명의 올레핀 중합 방법은 상기 올레핀 중합 촉매의 존재하에 하나 이상의 올레핀을 중합하는 단계를 포함한다.
PCT/KR2009/003342 2008-07-09 2009-06-22 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법 WO2010005190A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080066492A KR20100006307A (ko) 2008-07-09 2008-07-09 올레핀 중합 촉매 및 이를 이용한 폴리올레핀 중합체의중합방법
KR10-2008-0066492 2008-07-09

Publications (2)

Publication Number Publication Date
WO2010005190A2 WO2010005190A2 (ko) 2010-01-14
WO2010005190A3 true WO2010005190A3 (ko) 2010-03-25

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PCT/KR2009/003342 WO2010005190A2 (ko) 2008-07-09 2009-06-22 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법

Country Status (2)

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KR (1) KR20100006307A (ko)
WO (1) WO2010005190A2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509138A (zh) * 2012-06-27 2014-01-15 大林产业株式会社 烯烃聚合催化剂组合物以及使用所述烯烃聚合催化剂组合物的烯烃聚合方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05170819A (ja) * 1991-12-20 1993-07-09 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
JPH07316219A (ja) * 1994-05-24 1995-12-05 Mitsui Petrochem Ind Ltd オレフィン重合用固体触媒成分、該触媒成分を含むオレフィン重合用触媒および該触媒を用いるオレフィンの重合方法
WO1999061489A1 (en) * 1998-05-25 1999-12-02 Borealis Technology Oy Supported olefin polymerization catalyst composition
US20070142221A1 (en) * 2005-12-16 2007-06-21 Daelim Industrial Co., Ltd. Olefin polymerization catalyst and olefin polymerization process using the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05170819A (ja) * 1991-12-20 1993-07-09 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
JPH07316219A (ja) * 1994-05-24 1995-12-05 Mitsui Petrochem Ind Ltd オレフィン重合用固体触媒成分、該触媒成分を含むオレフィン重合用触媒および該触媒を用いるオレフィンの重合方法
WO1999061489A1 (en) * 1998-05-25 1999-12-02 Borealis Technology Oy Supported olefin polymerization catalyst composition
US20070142221A1 (en) * 2005-12-16 2007-06-21 Daelim Industrial Co., Ltd. Olefin polymerization catalyst and olefin polymerization process using the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509138A (zh) * 2012-06-27 2014-01-15 大林产业株式会社 烯烃聚合催化剂组合物以及使用所述烯烃聚合催化剂组合物的烯烃聚合方法

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Publication number Publication date
KR20100006307A (ko) 2010-01-19
WO2010005190A2 (ko) 2010-01-14

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