WO2009151227A2 - Water purifier of a stepping-stone type - Google Patents

Water purifier of a stepping-stone type Download PDF

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Publication number
WO2009151227A2
WO2009151227A2 PCT/KR2009/002916 KR2009002916W WO2009151227A2 WO 2009151227 A2 WO2009151227 A2 WO 2009151227A2 KR 2009002916 W KR2009002916 W KR 2009002916W WO 2009151227 A2 WO2009151227 A2 WO 2009151227A2
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Prior art keywords
stepping
titanium dioxide
water
box
water purifier
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PCT/KR2009/002916
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French (fr)
Korean (ko)
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WO2009151227A3 (en
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양기해
Original Assignee
Yang Ki Hae
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C02F3/10—Packings; Fillings; Grids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30207—Sphere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/10—Biological treatment of water, waste water, or sewage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Definitions

  • the present invention relates to a water-purifying device comprising a titanium dioxide coated on the surface of a box-type box and filled with a ball-shaped biofilm carrier (2) in an empty space of the box. It can be used for water purification, including lake purification or wastewater, and it can be configured as a stepping bridge to obtain eco-friendly visual effects.
  • the present invention relates to a stepping-type water purifier.
  • Korean Patent Publication No. 10-1999-0022798 purification and purification device for purification
  • Korean Patent Publication No. 10-1999-0022798 purification and purification device for purification
  • the purifying submerged body causes only a photocatalytic reaction.
  • the present invention relates to a stepping-type water purifier for improving water treatment efficiency by using the oxidation power of titanium dioxide and the internal biofilm carrier in water treatment.
  • the strong oxidation effect of titanium dioxide occurs only on the surface of the stepping box and there is no residual effect, so there is no effect on microorganisms, thus improving the treatment efficiency of the existing treatment method.
  • the present invention uses the oxidation of titanium dioxide in order to increase the water treatment efficiency and the wavelength (TiO 2) has a band gap energy on the surface ( In the case of UV irradiation of 400nm), TiO 2 electrons are transferred from the valence band to the conduction band, thereby creating holes in the valence band. The generated electrons and holes diffuse to the TiO 2 surface.
  • the water adsorbed on the TiO 2 surface or OH - and the hole reaction may generate OH radicals and, in the case of oxygen present in the water has to generate more OH radicals generated by the O 2 2- radical reacts with the e-TiO 2 Organic substances on the surface are decomposed, which is called photocatalytic reaction.
  • OH radicals and O 2 2- radicals are also produced by H 2 O 2 , which is produced as an intermediate of the reaction.
  • H 2 O 2 , HO 2 and O 2 consume the generated electrons to prevent recombination and increase the production of OH radicals.
  • OH radicals and O22- radicals are used as oxidants to oxidize organic materials.
  • the oxidation of titanium dioxide can be efficiently used in water treatment, which can achieve not only a water purification effect but also a visual effect.
  • FIG. 1 is an overall configuration diagram of a stepping water purifier according to the present invention.
  • Figure 2 is an external configuration of the inner biofilm carrier of the stepping water purifier of the present invention.
  • Figure 3 is an internal configuration of the biofilm carrier of the stepping water purifier of the present invention.
  • Figure 4 is a schematic diagram of the outflow and outflow of water of the stepping water purifier of the present invention.
  • Figure 5 is a cross-sectional view illustrating the flow of the biofilm carrier inside the stepping leg type of the present invention.
  • the present invention creates a space in the interior of the stepping box and the inlet portion (3) that can enter the water upstream side and the outlet portion (1) on the downstream side and the side outlet portion on the left and right to form a vortex inside (1-1) is made, and there are various existing biofilm carriers (2) inside to allow flow according to the vortex so that microorganisms can grow excessively to prevent anaerobic and rotting.
  • titanium dioxide on the surface of the stepped box-type box, it reacts with ultraviolet rays of sunlight to generate OH - radicals to oxidize contaminants.
  • a stepping-leg water purifier according to the present invention comprises an inlet part formed on one side of a stepping-type box having an empty space therein, and an outlet part formed on opposite and left and right sides of the inlet part.
  • the surface of the titanium dioxide is made of coating, characterized in that the ball-shaped biofilm carriers (2) filled with the inner space of the stepped box-shaped box.
  • Titanium dioxide can be applied to the surface of rocks, pebbles, sand as well as natural stone stepping bridge, the stepping box may be made of artificial, such as FRP, plastic, cement, or may be made by mixing titanium dioxide powder. Titanium dioxide-coated rocks, pebbles, and sand create a stream in the water to improve water purification along with sunlight.
  • Titanium dioxide is coated between 25 ° C and 250 ° C, which is most effective.
  • the biofilm carrier 2 of the stepping-type water purifier of the present invention has a spherical shape as a whole, and has various holes 5 such as circles and triangles on the outer surface thereof so that water can freely travel inside. It is desirable to make.
  • the biofilm 4 is placed inside the biofilm carrier 2 to purify water quality by microorganisms.
  • the size of the hole 5 can be varied from 5 mm to 300 mm in diameter.
  • the hole 5 may be a spawning place of the fry and can also achieve a natural ecological learning effect.
  • the biofilm 4 uses a film made of fine fiber yarn having a diameter of 0.5 mm or less.
  • the present invention can be used in the field of environmentally friendly water purification, which can be used as a natural water purification technology for the purification of rivers and lakes.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The present invention relates to a water purifier of a type employing stepping-stones coated with titanium dioxide, whereby water-treatment efficiency is improved through the use of the oxidizing power of titanium dioxide and an internal biofilm carrier. The present invention improves on the treatment efficiency of prior-art processing methods in that the powerful oxidising action of titanium dioxide only takes place on the surface and is not persistent and hence there is no effect on microorganisms or the like.

Description

징검다리형 수질정화기Stepping Bridge Water Purifier
본 발명은 이산화티타늄이 징검다리형 박스의 표면에 코팅되고, 상기 박스의 빈 공간에는 구(球, Ball) 형상의 생물막 담체(2)들이 채워져서 구성된 징검다리형 수질정화기에 관한 것으로, 하천 및 호수정화 또는 폐수 등을 포함한 수질정화에 이용할 수 있으며, 징검다리 형태로 구성하여 친환경적인 시각적 효과도 얻을 수 있다. The present invention relates to a water-purifying device comprising a titanium dioxide coated on the surface of a box-type box and filled with a ball-shaped biofilm carrier (2) in an empty space of the box. It can be used for water purification, including lake purification or wastewater, and it can be configured as a stepping bridge to obtain eco-friendly visual effects.
본 발명은 징검다리형 수질정화기에 관한 것이다. 티타늄을 특정의 물체에 도포하는 기술로는 한국 공개특허공보 제10-1999-0022798호(정화용 부침체 및 정화장치)(1999.03.25.공개) 등이 있으나, 이는 볼의 외부에 티타늄을 도포하고 내부에는 원통형으로 구멍을 내어 광촉매 반응을 일으키는 방법으로서, 정화용 부침체가 광촉매 반응만을 일으키는 단점이 있다.The present invention relates to a stepping-type water purifier. As a technique for applying titanium to a specific object, Korean Patent Publication No. 10-1999-0022798 (purification and purification device for purification) (published on March 25, 1999), etc., which applies titanium to the outside of the ball As a method of causing a photocatalytic reaction by drilling a hole in a cylinder, there is a disadvantage in that the purifying submerged body causes only a photocatalytic reaction.
본 발명은 수처리에 있어 이산화티타늄의 산화력과 내부의 생물막 담체를 이용하여 수처리 효율을 높이는 징검다리형 수질정화기에 관한 것이다. 이산화티타늄에 의한 강한 산화작용은 징검다리형 박스의 표면에서만 일어나고 잔류성이 없기 때문에 미생물에 미치는 영향 등은 없어 기존 처리방식의 처리효율을 향상시킨다.The present invention relates to a stepping-type water purifier for improving water treatment efficiency by using the oxidation power of titanium dioxide and the internal biofilm carrier in water treatment. The strong oxidation effect of titanium dioxide occurs only on the surface of the stepping box and there is no residual effect, so there is no effect on microorganisms, thus improving the treatment efficiency of the existing treatment method.
본 발명은 수처리효율을 높이기 위하여 이산화티타늄의 산화작용을 사용하며 TiO2표면에 Band gap 이상의 에너지를 가지는 파장 (
Figure PCTKR2009002916-appb-I000001
Figure PCTKR2009002916-appb-I000002
400㎚)의 UV를 조사할 경우 TiO2전자는 Valence band에서 Conduction band로 전이가 일어나게 되고 이로 인하여 Valence band에서 hole이 생성된다. 이렇게 생성된 전자와 hole은 TiO2 표면으로 확산 이동하게 된다. TiO2 표면에 흡착된 물이나 OH- 과 hole이 반응하여 OH 라디칼을 생성하기도 하며 수중에 존재하는 산소의 경우에는 전자와 반응하여 O2 2- 라디칼을 생성하여 더 많은 OH 라디칼을 생성시켜 TiO2 표면의 유기물질 등을 분해하게 되는데 이를 광촉매 반응이라고 한다. OH 라디칼과 O2 2- 라디칼은 또한 반응의 중간생성물로 생성되는 H2O2 에 의해서도 생성된다. H2O2, HO2, O2 는 생성된 전자를 소비하여 Recombination을 방지하여 OH 라디칼의 생성을 증가시키며 광촉매반응에서 OH 라디칼과 O22- 라디칼은 유기물질을 산화시키는 산화제로 사용된다. The present invention uses the oxidation of titanium dioxide in order to increase the water treatment efficiency and the wavelength (TiO 2) has a band gap energy on the surface (
Figure PCTKR2009002916-appb-I000001
Figure PCTKR2009002916-appb-I000002
In the case of UV irradiation of 400nm), TiO 2 electrons are transferred from the valence band to the conduction band, thereby creating holes in the valence band. The generated electrons and holes diffuse to the TiO 2 surface. The water adsorbed on the TiO 2 surface or OH - and the hole reaction may generate OH radicals and, in the case of oxygen present in the water has to generate more OH radicals generated by the O 2 2- radical reacts with the e-TiO 2 Organic substances on the surface are decomposed, which is called photocatalytic reaction. OH radicals and O 2 2- radicals are also produced by H 2 O 2 , which is produced as an intermediate of the reaction. H 2 O 2 , HO 2 and O 2 consume the generated electrons to prevent recombination and increase the production of OH radicals. In photocatalytic reactions, OH radicals and O22- radicals are used as oxidants to oxidize organic materials.
또한 상기 수질정화 목적을 달성하기 위하여 생물막을 사용하여 수질정화 효과를 더욱 높인다.In addition, in order to achieve the above water purification objectives, the use of a biofilm further enhances the water purification effect.
본 발명을 이용하여 이산화티타늄의 산화작용을 수처리에 효율적으로 이용할 수 있으며, 이는 수질정화 효과뿐만 아니라 시각적 효과도 이룰 수 있다.By using the present invention, the oxidation of titanium dioxide can be efficiently used in water treatment, which can achieve not only a water purification effect but also a visual effect.
도1은 본 발명에 따른 징검다리형 수질정화기의 전체적 구성도.1 is an overall configuration diagram of a stepping water purifier according to the present invention.
도2은 본 발명의 징검다리형 수질정화기의 내부 생물막 담체의 외부 구성도.Figure 2 is an external configuration of the inner biofilm carrier of the stepping water purifier of the present invention.
도3은 본 발명의 징검다리형 수질정화기의 생물막 담체의 내부 구성도.Figure 3 is an internal configuration of the biofilm carrier of the stepping water purifier of the present invention.
도4는 본 발명의 징검다리형 수질정화기의 물의 유출입 모식도.Figure 4 is a schematic diagram of the outflow and outflow of water of the stepping water purifier of the present invention.
도5은 본 발명의 징검다리형 내부의 생물막 담체물의 유동을 설명하는 평단면도.Figure 5 is a cross-sectional view illustrating the flow of the biofilm carrier inside the stepping leg type of the present invention.
본 발명은 징검다리형 박스의 내부에 공간을 만들고 상류측에 물이 들어올 수 있는 유입부(3)를 만들고 내부에서 와류가 형성될 수 있게 하류측에 유출부(1)와 좌우측에 측면 유출부(1-1)를 만들고, 내부에는 기존의 다양한 생물막 담체(2)를 넣어 와류에 따라 유동할 수 있게 만들어 미생물이 과다 성장하여 혐기화되어 썩는 것을 예방할 수 있는 구조로 한다. 또한, 상기 징검다리형 박스의 표면에는 이산화티타늄을 도포하여 구성함으로써, 태양광의 자외선과 반응하여 OH- 라디칼을 생성하여 오염물질을 산화시키도록 한다.The present invention creates a space in the interior of the stepping box and the inlet portion (3) that can enter the water upstream side and the outlet portion (1) on the downstream side and the side outlet portion on the left and right to form a vortex inside (1-1) is made, and there are various existing biofilm carriers (2) inside to allow flow according to the vortex so that microorganisms can grow excessively to prevent anaerobic and rotting. In addition, by configuring titanium dioxide on the surface of the stepped box-type box, it reacts with ultraviolet rays of sunlight to generate OH - radicals to oxidize contaminants.
본 발명에 의한 징검다리형 수질정화기는, 내부에 빈 공간부를 갖는 징검다리형 박스의 일측에 형성되는 유입부와, 상기 유입부의 반대측과 좌우 측면에 형성되는 유출부로 구성되며, 상기 징검다리형 박스의 표면에는 이산화티타늄이 코팅되어 이루어지며, 상기 징검다리형 박스의 내부 공간부에 구(球, Ball)형상의 생물막 담체(2)들이 채워진 것을 특징으로 한다. A stepping-leg water purifier according to the present invention comprises an inlet part formed on one side of a stepping-type box having an empty space therein, and an outlet part formed on opposite and left and right sides of the inlet part. The surface of the titanium dioxide is made of coating, characterized in that the ball-shaped biofilm carriers (2) filled with the inner space of the stepped box-shaped box.
이산화티타늄은 자연석 징검다리 뿐만 아니라 바위, 조약돌, 모래의 표면에도 도포할 수 있으며, 상기 징검다리형 박스는 FRP, 플라스틱, 시멘트 등 인조로 만들 수도 있으며, 이산화티타늄 분말을 혼합해서 만들 수도 있다. 이산화티타늄이 코팅된 바위, 조약돌, 모래는 물속에서 여울을 만들어 태양광과 함께 수질정화기능을 향상시킨다. Titanium dioxide can be applied to the surface of rocks, pebbles, sand as well as natural stone stepping bridge, the stepping box may be made of artificial, such as FRP, plastic, cement, or may be made by mixing titanium dioxide powder. Titanium dioxide-coated rocks, pebbles, and sand create a stream in the water to improve water purification along with sunlight.
이산화티타늄은 가장 효과가 좋은 25℃ 에서 250℃ 사이에서 코팅한다. Titanium dioxide is coated between 25 ° C and 250 ° C, which is most effective.
본 발명의 징검다리형 수질정화기의 생물막 담체(2)는 전체적으로 구(球) 형태의 외형을 가지고 있으며, 외부표면에는 원형, 삼각형 등 다양한 구멍(5)을 내어 물이 자유로이 내부로 왕래할 수 있도록 만드는 것이 바람직하다. 그리고, 생물막 담체(2)의 내부에는 생물막(4)을 두어 미생물에 의해 수질을 정화한다. 상기 구멍(5)의 크기는 직경 5㎜에서 300㎜까지 다양하게 만들 수 있다. 상기 구멍(5)은 치어의 산란장소가 될 수도 있으며 자연생태적인 학습효과도 이룰 수 있다. The biofilm carrier 2 of the stepping-type water purifier of the present invention has a spherical shape as a whole, and has various holes 5 such as circles and triangles on the outer surface thereof so that water can freely travel inside. It is desirable to make. The biofilm 4 is placed inside the biofilm carrier 2 to purify water quality by microorganisms. The size of the hole 5 can be varied from 5 mm to 300 mm in diameter. The hole 5 may be a spawning place of the fry and can also achieve a natural ecological learning effect.
상기 생물막(4)은 직경 0.5㎜이하의 미세한 섬유사로 만든 막을 이용한다.The biofilm 4 uses a film made of fine fiber yarn having a diameter of 0.5 mm or less.
본 발명은 친환경적인 수질정화분야에 사용할 수 있으며, 이는 하천, 호수 정화에도 자연친화적인 수질정화기술로 사용할 수 있다.The present invention can be used in the field of environmentally friendly water purification, which can be used as a natural water purification technology for the purification of rivers and lakes.

Claims (1)

  1. 징검다리형 박스의 내부에 형성되는 공간부와, A space portion formed inside the stepping box;
    상기 박스의 일측에 형성되는 유입부와,An inlet formed on one side of the box,
    상기 박스의 반대측과 좌우측에 각각 형성되는 유출부로 구성되며,Consists of the outlet portion formed on the opposite side and left and right sides of the box,
    상기 박스의 표면에는 이산화티타늄이 도포되어 이루어지며, The surface of the box is made of titanium dioxide is applied,
    상기 박스의 내부 공간부에 구(球, Ball) 형상의 생물막 담체(2)들이 채워진 것을 특징으로 하는 징검다리형 수질정화기.A stepping-type water purifier, characterized in that the inner space of the box is filled with a bio-film carrier (2) in the shape of a ball.
PCT/KR2009/002916 2008-06-10 2009-06-02 Water purifier of a stepping-stone type WO2009151227A2 (en)

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KR20080053944A KR100881655B1 (en) 2008-06-10 2008-06-10 Apparatus for treating water have a stepping stones form
KR10-2008-0053944 2008-06-10

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01315391A (en) * 1988-06-13 1989-12-20 Nikken Kogaku Kk Apparatus and block for purifying river filthy water
KR200361785Y1 (en) * 2004-04-21 2004-09-14 이우원 The device for water purification of river using rock wool
KR100576063B1 (en) * 2006-02-02 2006-05-03 한국기술개발 주식회사 Sluice gates under a bridge of clean water
KR20070006299A (en) * 2005-07-08 2007-01-11 주식회사 우일 이알에스 Stepping stone structure for water quality purification

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04247297A (en) * 1991-01-31 1992-09-03 Three M:Kk Water permeable pseudo rock containing biospecies bacterium
KR20010000340A (en) * 2000-09-18 2001-01-05 김현용 Water treatment device using horizontal sand filtration and photocatalytic reaction
KR20020050428A (en) * 2000-12-21 2002-06-27 이구택 A removal method of algae by using photocatalyst coated plates in river and lake

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01315391A (en) * 1988-06-13 1989-12-20 Nikken Kogaku Kk Apparatus and block for purifying river filthy water
KR200361785Y1 (en) * 2004-04-21 2004-09-14 이우원 The device for water purification of river using rock wool
KR20070006299A (en) * 2005-07-08 2007-01-11 주식회사 우일 이알에스 Stepping stone structure for water quality purification
KR100576063B1 (en) * 2006-02-02 2006-05-03 한국기술개발 주식회사 Sluice gates under a bridge of clean water

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