KR100881655B1 - Apparatus for treating water have a stepping stones form - Google Patents

Apparatus for treating water have a stepping stones form Download PDF

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Publication number
KR100881655B1
KR100881655B1 KR20080053944A KR20080053944A KR100881655B1 KR 100881655 B1 KR100881655 B1 KR 100881655B1 KR 20080053944 A KR20080053944 A KR 20080053944A KR 20080053944 A KR20080053944 A KR 20080053944A KR 100881655 B1 KR100881655 B1 KR 100881655B1
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South Korea
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box
stepping
stepping stones
water
water purifier
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KR20080053944A
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Korean (ko)
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양기해
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양기해
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Priority to KR20080053944A priority Critical patent/KR100881655B1/en
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Priority to PCT/KR2009/002916 priority patent/WO2009151227A2/en

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C02F3/10—Packings; Fillings; Grids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30207—Sphere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/10—Biological treatment of water, waste water, or sewage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

A stepping stones type water purifier is provided to improve process efficiency of an existing control method because strong oxidizing action by titanium dioxide occurs in a surface of the stepping stones type box and does not remain and causes no influence to microorganisms. A stepping stones type water purifier comprises a space part formed inside the stepping stones type box, an influx part(3) formed in one side of the box and outlet parts(1,1-1) formed in the opposite side and left and right sides of the box. Biofilm carriers(2) of ball shape are filled in an internal space of the box. The biofilm carriers of the stepping stones type water purifier have an outer shape of ball shape.

Description

징검다리형 수질정화기{Apparatus for treating water have a stepping stones form}Stepping Stone Purifier {Apparatus for treating water have a stepping stones form}

본 발명은 이산화티타늄이 징검다리형 박스의 표면에 코팅되고, 상기 박스의 내부 빈 공간에는 구(球, Ball) 형상의 생물막 담체(2)들이 채워져서 구성된 징검다리형 수질정화기에 관한 것으로서, 하천 및 호수정화 또는 폐수 등을 포함한 수질정화에 이용할 수 있으며, 징검다리 형태로 구성하여 친환경적인 시각적 효과도 얻을 수 있다.The present invention relates to a water-refining purifier comprising titanium dioxide coated on a surface of a water-containing box, and filled with a ball-shaped biofilm carrier 2 in an empty space inside the box. And it can be used for water purification, including lake purification or waste water, and can be configured in the form of a stepping bridge to obtain an environmentally friendly visual effect.

본 발명은 징검다리형 수질정화기에 관한 것이다. 티타늄을 특정의 물체에 도포하는 기술로는 한국 공개특허공보 제10-1999-0022798호(정화용 부침체 및 정화장치)(1999.03.25.공개) 등이 있으나, 이는 볼의 외부에 티타늄을 도포하고 내부에는 원통형으로 구멍을 내어 광촉매 반응을 일으키는 방법으로서, 정화용 부침체가 광촉매 반응만을 일으키는 단점이 있다.The present invention relates to a stepping-type water purifier. As a technique of applying titanium to a specific object, there is a Korean Patent Publication No. 10-1999-0022798 (purification and purification device for purification) (published on March 25, 1999), etc., this is applied to the outside of the ball As a method of causing a photocatalytic reaction by drilling a hole in a cylinder, there is a disadvantage in that the purifying submerged body causes only a photocatalytic reaction.

본 발명은 수처리에 있어 이산화티타늄의 산화력과 내부의 생물막 담체를 이용하여 수처리 효율을 높이는 징검다리형 수질정화기에 관한 것이다. 이산화티타늄에 의한 강한 산화작용은 징검다리형 박스의 표면에서만 일어나고 잔류성이 없기 때문에 미생물에 미치는 영향 등은 없어 기존 처리방식의 처리효율을 향상시킨다.The present invention relates to a stepping-type water purifier for improving water treatment efficiency by using the oxidation power of titanium dioxide and the internal biofilm carrier in water treatment. The strong oxidation effect of titanium dioxide occurs only on the surface of the stepping box and there is no residual effect, so there is no effect on microorganisms, thus improving the treatment efficiency of the existing treatment method.

본 발명은 수처리효율을 높이기 위하여 이산화티타늄의 산화작용을 사용하며 TiO2 표면에 Band gap 이상의 에너지를 가지는 파장(λ< 400nm)의 UV를 조사할 경우 TiO2 전자는 Valence band에서 Conduction band로 전이가 일어나게 되고 이로 인하여 Valence band에서 hole이 생성된다. 이렇게 생성된 전자와 hole은 TiO2 표면으로 확산 이동하게된다. TiO2 표면에 흡착된 물이나 OH- 과 hole이 반응하여 OH 라디칼을 생성하기도 하며 수중에 존재하는 산소의 경우에는 전자와 반응하여 O2 2 - 라디칼을 생성하여 더 많은 OH 라디칼을 생성시켜 TiO2 표면의 유기물질 등을 분해하게 되는데 이를 광촉매 반응이라고 한다. OH 라디칼과 O2 2 - 라디칼은 또한 반응의 중간생성물로 생성되는 H2O2 에 의해서도 생성된다. H2O2, HO2, O2 는 생성된 전자를 소비하 여 Recombination을 방지하여 OH라디칼의 생성을 증가시키며 광촉매반응에서 OH 라디칼과 O2 2 - 라디칼은 유기물질을 산화시키는 산화제로 사용된다.The present invention uses the oxidation of titanium dioxide to increase the water treatment efficiency and when TiO 2 surface is irradiated with UV of wavelength (λ <400nm) with energy above the band gap, TiO 2 electrons are transferred from the conductance band to the conduction band. This causes holes in the valence band. The generated electrons and holes are TiO 2 Will diffuse and move to the surface. TiO 2 Water adsorbed on the surface or OH - and the hole reacts to produce OH radicals, and in the case of oxygen present in water, it reacts with electrons to generate O 2 2 - radicals to generate more OH radicals to form TiO 2 Organic substances on the surface are decomposed, which is called photocatalytic reaction. OH radicals and O 2 2 - radicals are also H 2 O 2 generated as intermediates of the reaction It is also generated by H 2 O 2 , HO 2 , O 2 Consume the generated electrons to prevent recombination and increase the production of OH radicals. In photocatalytic reactions, OH radicals and O 2 2 - radicals are used as oxidants to oxidize organic materials.

또한 상기 수질정화 목적을 달성하기 위하여 생물막을 사용하여 수질정화 효과를 더욱 높인다.In addition, in order to achieve the above-mentioned water purification purpose, using a biofilm further enhances the water purification effect.

본 발명을 이용하여 이산화티타늄의 산화작용을 수처리에 효율적으로 이용할 수 있으며, 이는 수질정화 효과 뿐만 아니라 시각적 효과도 이룰 수 있다.By using the present invention, the oxidation of titanium dioxide can be efficiently used in water treatment, which can achieve not only a water purification effect but also a visual effect.

본 발명은 징검다리형 박스의 내부에 공간을 만들고 상류측에 물이 들어올 수 있는 유입부(3)를 만들고 내부에서 와류가 형성될 수 있게 하류측에 유출부(1)와 좌우측에 측면 유출부(1-1)를 만들고 내부에는 기존의 다양한 생물막 담체(2)를 넣어 와류에 따라 유동할 수 있게 만들어 미생물이 과다 성장하여 혐기화되어 썩는 것을 예방할 수 있는 구조로 한다. 또한, 상기 징검다리형 박스의 표면에는 이산화티타늄을 도포하여 구성함으로써, 태양광의 자외선과 반응하여 OH- 라디칼을 생성하여 오염물질을 산화시키도록 한다.
본 발명의 바람직한 실시예에 따른 징검다리형 수질정화기의 기술 구성을 보다 정확히 설명하면 다음과 같다.
본 발명에 의한 징검다리형 수질정화기는, 내부에 빈 공간부를 갖는 징검다리형 박스의 일측에 형성되는 유입부와, 상기 유입부의 반대측과 좌우 측면에 형성되는 유출부로 구성되며, 상기 징검다리형 박스의 표면에는 이산화티타늄이 코팅되어 이루어지며, 상기 징검다리형 박스의 내부 공간부에 구(球, Ball) 형상의 생물막 담체(2)들이 채워진 것을 특징으로 한다.
이산화티타늄은 자연석 징검다리 뿐만 아니라 바위, 조약돌, 모래의 표면에도 도포할 수 있으며, 상기 징검다리형 박스는 FRP, 플라스틱, 시멘트 등 인조로 만들 수도 있으며, 이산화티타늄 분말을 혼합해서 만들 수도 있다. 이산화티타늄이 코팅된 바위, 조약돌, 모래는 물속에서 여울을 만들어 태양광과 함께 수질정화기능을 향상시킨다.
이산화티타늄은 가장 효과가 좋은 25℃에서 250℃ 사이에서 코팅한다.The present invention creates a space in the inside of the stepping box and the inlet portion (3) that can enter the water upstream side and the outlet portion (1) downstream and the side outlet portion on the left and right so that the vortex can be formed inside (1-1) and the inside of the various biofilm carriers (2) to put the flow to the vortex so that the microorganisms are overgrown and anaerobic to prevent rotting. In addition, by configuring titanium dioxide on the surface of the stepped box-type box, it reacts with ultraviolet rays of sunlight to generate OH - radicals to oxidize contaminants.
Referring to the technical configuration of the water-purifying water purifier according to a preferred embodiment of the present invention more precisely as follows.
A stepping-leg water purifier according to the present invention comprises an inlet part formed on one side of a stepping-type box having an empty space therein, and an outlet part formed on opposite and left and right sides of the inlet part. The surface of the titanium dioxide is made of coating, it characterized in that the biofilm carriers (2) of the ball shape (ball, ball) filled in the inner space of the stepped box-shaped box.
Titanium dioxide can be applied to the surface of rocks, pebbles, sand as well as natural stone stepping bridge, the stepping box may be made of artificial, such as FRP, plastic, cement, or may be made by mixing titanium dioxide powder. Titanium dioxide-coated rocks, pebbles, and sand create a stream in the water to improve water purification along with sunlight.
Titanium dioxide is coated between 25 ° C and 250 ° C, which is most effective.

본 발명의 징검다리형 수질정화기의 생물막 담체(2)는 전체적으로 구(球) 형태의 외형을 가지고 있으며, 외부 표면에는 원형, 삼각형 등 다양한 구멍(5)을 내어 물이 자유로이 내부로 왕래할 수 있도록 만드는 것이 바람직하다.
그리고, 생물막 담체(2)의 내부에는 생물막(4)을 두어 미생물에 의해 수질을 정화한다. 상기 구멍(5)의 크기는 직경 5mm에서 300mm까지 다양하게 만들 수 있다. 상기 구멍(5)은 치어의 산란장소가 될 수도 있으며 자연생태적인 학습효과도 이룰 수 있다.
상기 생물막(4)은 직경 0.5mm이하의 미세한 섬유사로 만든 막을 이용한다.The biofilm carrier 2 of the stepping water purifier of the present invention has a spherical shape as a whole, and has various holes 5 such as a circle and a triangle on its outer surface so that water can freely travel inside. It is desirable to make.
The biofilm 4 is placed inside the biofilm carrier 2 to purify water quality by microorganisms. The size of the hole 5 can be made variously from 5mm to 300mm in diameter. The hole 5 may be a spawning place of the fry and can also achieve a natural ecological learning effect.
The biofilm 4 uses a film made of fine fiber yarn having a diameter of 0.5 mm or less.

도1은 본 발명에 따른 징검다리형 수질정화기의 전체적 구성도.1 is an overall configuration diagram of a stepping water purifier according to the present invention.

도2은 본 발명의 징검다리형 수질정화기의 징검다리 구조물을 표현한 구성도.Figure 2 is a block diagram representing the stepping structure of the stepping water purifier of the present invention.

도3은 본 발명의 징검다리형 수질정화기의 내부 생물막 담체의 외부 구성도.Figure 3 is an external configuration of the inner biofilm carrier of the stepping water purifier of the present invention.

도4은 본 발명의 징검다리형 수질정화기의 생물막 담체의 내부 구성도.Figure 4 is an internal configuration of the biofilm carrier of the stepping water purifier of the present invention.

도5a는 본 발명의 징검다리형 수질정화기의 물의 유출입 모식도.
도5b는 본 발명의 징검다리형 내부의 생물막 담체물의 유동을 설명하는 평단면도.Figure 5a is a schematic diagram of the outflow and outflow of water of the stepping water purifier of the present invention.
Figure 5b is a cross-sectional view illustrating the flow of the biofilm carrier inside the stepping leg of the present invention.

Claims (3)

삭제delete 징검다리형 박스의 내부에 형성되는 공간부와,A space portion formed inside the stepping box; 상기 박스의 일측에 형성되는 유입부와, An inlet formed on one side of the box, 상기 박스의 반대측과 좌우측에 각각 형성되는 유출부로 구성되며,Consists of the outlet portion formed on the opposite side and left and right sides of the box, 상기 박스의 표면에는 이산화티타늄이 도포되어 이루어지며,The surface of the box is made of titanium dioxide is applied, 상기 박스의 내부 공간부에 구(球, Ball) 형상의 생물막 담체(2)들이 채워진 것을 특징으로 하는 징검다리형 수질정화기.A stepping-type water purifier, characterized in that the inner space of the box is filled with a bio-film carrier (2) in the shape of a ball. 삭제delete
KR20080053944A 2008-06-10 2008-06-10 Apparatus for treating water have a stepping stones form KR100881655B1 (en)

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KR20080053944A KR100881655B1 (en) 2008-06-10 2008-06-10 Apparatus for treating water have a stepping stones form
PCT/KR2009/002916 WO2009151227A2 (en) 2008-06-10 2009-06-02 Water purifier of a stepping-stone type

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JPH04247297A (en) * 1991-01-31 1992-09-03 Three M:Kk Water permeable pseudo rock containing biospecies bacterium
KR20010000340A (en) * 2000-09-18 2001-01-05 김현용 Water treatment device using horizontal sand filtration and photocatalytic reaction
KR20020050428A (en) * 2000-12-21 2002-06-27 이구택 A removal method of algae by using photocatalyst coated plates in river and lake
KR200361785Y1 (en) * 2004-04-21 2004-09-14 이우원 The device for water purification of river using rock wool
KR20070006299A (en) * 2005-07-08 2007-01-11 주식회사 우일 이알에스 Stepping stone structure for water quality purification
KR100576063B1 (en) 2006-02-02 2006-05-03 한국기술개발 주식회사 Sluice gates under a bridge of clean water

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