WO2009136146A3 - Power recovery - Google Patents

Power recovery Download PDF

Info

Publication number
WO2009136146A3
WO2009136146A3 PCT/GB2009/001117 GB2009001117W WO2009136146A3 WO 2009136146 A3 WO2009136146 A3 WO 2009136146A3 GB 2009001117 W GB2009001117 W GB 2009001117W WO 2009136146 A3 WO2009136146 A3 WO 2009136146A3
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
gaseous stream
gas
gas turbine
power recovery
Prior art date
Application number
PCT/GB2009/001117
Other languages
French (fr)
Other versions
WO2009136146A2 (en
Inventor
Harald B. Carrick
Graham Robert Aird
Graeme Humphries
Original Assignee
Invista Technologies S.A.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to RU2010149770/04A priority Critical patent/RU2548026C2/en
Priority to EP09742342A priority patent/EP2384394A2/en
Priority to CA2723701A priority patent/CA2723701C/en
Priority to BRPI0908294-8A priority patent/BRPI0908294A2/en
Priority to JP2011507981A priority patent/JP2011528276A/en
Priority to CN2009801262352A priority patent/CN102770626A/en
Application filed by Invista Technologies S.A.R.L. filed Critical Invista Technologies S.A.R.L.
Priority to MX2010012162A priority patent/MX2010012162A/en
Priority to US12/990,984 priority patent/US20110100007A1/en
Publication of WO2009136146A2 publication Critical patent/WO2009136146A2/en
Publication of WO2009136146A3 publication Critical patent/WO2009136146A3/en
Priority to US13/901,666 priority patent/US20130255259A1/en
Priority to US14/626,199 priority patent/US20150167501A1/en

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F01K25/14—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours using industrial or other waste gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B33/00—Oxidation in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00—General layout or general methods of operation of complete plants
    • F01K13/003—Arrangements for measuring or testing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K21/00—Steam engine plants not otherwise provided for
    • F01K21/04—Steam engine plants not otherwise provided for using mixtures of steam and gas; Plants generating or heating steam by bringing water or steam into direct contact with hot gas
    • F01K21/047—Steam engine plants not otherwise provided for using mixtures of steam and gas; Plants generating or heating steam by bringing water or steam into direct contact with hot gas having at least one combustion gas turbine
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K27/00—Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
    • F01K27/02—Plants modified to use their waste heat, other than that of exhaust, e.g. engine-friction heat
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K7/00—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
    • F01K7/16—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/30—Adding water, steam or other fluids for influencing combustion, e.g. to obtain cleaner exhaust gases
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
    • G01M15/00—Testing of engines
    • G01M15/14—Testing gas-turbine engines or jet-propulsion engines

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a method and apparatus for recovering power from the gaseous stream produced by an oxidation reaction. Specifically, the invention is based on heating the gaseous stream from the oxidation reaction to a temperature of at least 800 °C and recovering energy through a gas turbine. The compressor stage of the gas turbine compresses the oxidant feed to the reactor thereby at least partially offsetting the cost of providing the high temperature and pressure reaction conditions in the reactor. The invention also provides improved control of the power recovery system by optimising the efficiency of the gas turbine by feeding gas to the gaseous stream to modulate the flow of gas to the turbine relative to the compressor discharge flow in order to compensate for the consumption of oxidant in the reactor.
PCT/GB2009/001117 2008-05-06 2009-05-06 Power recovery WO2009136146A2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
EP09742342A EP2384394A2 (en) 2008-05-06 2009-05-06 Power recovery
CA2723701A CA2723701C (en) 2008-05-06 2009-05-06 Power recovery
BRPI0908294-8A BRPI0908294A2 (en) 2008-05-06 2009-05-06 "method for energy recovery from an oxidation reaction, method for monitoring energy recovery from an oxidation reaction, continuous reactor for an oxidation reaction and oxidation process of a precursor to an aromatic carboxylic acid or ester thereof"
JP2011507981A JP2011528276A (en) 2008-05-06 2009-05-06 Power recovery
CN2009801262352A CN102770626A (en) 2008-05-06 2009-05-06 Power recovery
RU2010149770/04A RU2548026C2 (en) 2008-05-06 2009-05-06 Energy recovery
MX2010012162A MX2010012162A (en) 2008-05-06 2009-05-06 Power recovery.
US12/990,984 US20110100007A1 (en) 2008-05-06 2009-05-06 Power recovery
US13/901,666 US20130255259A1 (en) 2008-10-24 2013-05-24 Power recovery for use in start-up or re-start of a pure terephthalic acid production process
US14/626,199 US20150167501A1 (en) 2008-05-06 2015-02-19 Power recovery

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB0808200.0 2008-05-06
GBGB0808200.0A GB0808200D0 (en) 2008-05-06 2008-05-06 Power recovery
US10823308P 2008-10-24 2008-10-24
US61/108,233 2008-10-24

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US12/990,984 A-371-Of-International US20110100007A1 (en) 2008-05-06 2009-05-06 Power recovery
US13/901,666 Continuation-In-Part US20130255259A1 (en) 2008-10-24 2013-05-24 Power recovery for use in start-up or re-start of a pure terephthalic acid production process
US14/626,199 Continuation US20150167501A1 (en) 2008-05-06 2015-02-19 Power recovery

Publications (2)

Publication Number Publication Date
WO2009136146A2 WO2009136146A2 (en) 2009-11-12
WO2009136146A3 true WO2009136146A3 (en) 2011-09-22

Family

ID=39537335

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2009/001117 WO2009136146A2 (en) 2008-05-06 2009-05-06 Power recovery

Country Status (13)

Country Link
US (2) US20110100007A1 (en)
EP (2) EP2384394A2 (en)
JP (1) JP2011528276A (en)
KR (1) KR20110005300A (en)
CN (1) CN102770626A (en)
BR (1) BRPI0908294A2 (en)
CA (1) CA2723701C (en)
DE (1) DE202009019033U1 (en)
GB (1) GB0808200D0 (en)
MX (1) MX2010012162A (en)
RU (1) RU2548026C2 (en)
TW (1) TWI368685B (en)
WO (1) WO2009136146A2 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130255259A1 (en) * 2008-10-24 2013-10-03 Invista North America S.A R.L. Power recovery for use in start-up or re-start of a pure terephthalic acid production process
EP2488797B1 (en) * 2009-10-16 2016-04-20 Proto-Technics, Inc. Low emissions direct fired air heater
US8779208B2 (en) 2012-05-18 2014-07-15 Eastman Chemical Company Process for reducing emissions of volatile organic compounds from the ketonization of carboxylic acids
US10138815B2 (en) * 2012-11-02 2018-11-27 General Electric Company System and method for diffusion combustion in a stoichiometric exhaust gas recirculation gas turbine system
WO2014189818A1 (en) * 2013-05-24 2014-11-27 Invista Technologies S.À.R.L. Power recovery for use in start-up or re-start of a pure terephthalic acid production process
JP6342755B2 (en) * 2014-09-05 2018-06-13 株式会社神戸製鋼所 Compression device
DE102016200916A1 (en) 2016-01-22 2017-07-27 Ferdinand Reif Gas turbine use in oxidation processes
US10280844B2 (en) * 2016-11-17 2019-05-07 General Electric Company Control systems for controlling power systems based on fuel consumption and related program products
CN108434982A (en) * 2018-04-28 2018-08-24 杭州谱育科技发展有限公司 Cyclohexanone exhaust gas processing device and method
KR20210083317A (en) * 2018-10-29 2021-07-06 에이알비 파이롤리시스 엘엘씨 Systems and methods for treating carbonaceous feedstock
GB2584712A (en) * 2019-06-13 2020-12-16 Rolls Royce Plc A forced air convection apparatus and method for cooling a turbomachine
US11774427B2 (en) * 2019-11-27 2023-10-03 General Electric Company Methods and apparatus for monitoring health of fuel oxygen conversion unit
EP4121638A4 (en) * 2020-03-19 2024-04-03 Kellogg Brown & Root LLC Power augmentation for a gas turbine
CN111608805A (en) * 2020-04-20 2020-09-01 中国石油化工股份有限公司 Method for recovering energy of oxidized tail gas in cyclohexanone production by oxidation method
CN111608806A (en) * 2020-04-20 2020-09-01 中国石油化工股份有限公司 Method and device for recovering tail gas energy in cyclohexanone oxidation production process

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Also Published As

Publication number Publication date
CA2723701C (en) 2014-03-18
WO2009136146A2 (en) 2009-11-12
US20150167501A1 (en) 2015-06-18
TWI368685B (en) 2012-07-21
GB0808200D0 (en) 2008-06-11
EP2495405A3 (en) 2012-11-21
EP2495405A2 (en) 2012-09-05
MX2010012162A (en) 2010-12-01
CA2723701A1 (en) 2009-11-12
BRPI0908294A2 (en) 2015-07-21
KR20110005300A (en) 2011-01-17
EP2384394A2 (en) 2011-11-09
JP2011528276A (en) 2011-11-17
US20110100007A1 (en) 2011-05-05
RU2010149770A (en) 2012-06-20
DE202009019033U1 (en) 2015-08-20
CN102770626A (en) 2012-11-07
RU2548026C2 (en) 2015-04-10
TW201002933A (en) 2010-01-16

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