WO2009133176A2 - Module solaire à couche mince utilisé comme verre de sécurité feuilleté - Google Patents
Module solaire à couche mince utilisé comme verre de sécurité feuilleté Download PDFInfo
- Publication number
- WO2009133176A2 WO2009133176A2 PCT/EP2009/055276 EP2009055276W WO2009133176A2 WO 2009133176 A2 WO2009133176 A2 WO 2009133176A2 EP 2009055276 W EP2009055276 W EP 2009055276W WO 2009133176 A2 WO2009133176 A2 WO 2009133176A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polyvinyl acetal
- glass
- film
- films
- photovoltaic module
- Prior art date
Links
- 239000005336 safety glass Substances 0.000 title description 11
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 43
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000011521 glass Substances 0.000 claims description 40
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 31
- 239000004014 plasticizer Substances 0.000 claims description 27
- 239000004065 semiconductor Substances 0.000 claims description 21
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 9
- 238000007906 compression Methods 0.000 claims description 9
- 230000006835 compression Effects 0.000 claims description 9
- 239000005340 laminated glass Substances 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 13
- 150000001241 acetals Chemical class 0.000 abstract description 31
- 239000010408 film Substances 0.000 description 84
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 43
- 239000010410 layer Substances 0.000 description 19
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 239000003513 alkali Substances 0.000 description 11
- 239000002131 composite material Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000010409 thin film Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 7
- -1 alkaline earth metal salts Chemical class 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229920001515 polyalkylene glycol Polymers 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 4
- 206010041662 Splinter Diseases 0.000 description 4
- 238000006359 acetalization reaction Methods 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- HHECSPXBQJHZAF-UHFFFAOYSA-N dihexyl hexanedioate Chemical compound CCCCCCOC(=O)CCCCC(=O)OCCCCCC HHECSPXBQJHZAF-UHFFFAOYSA-N 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- GCDUWJFWXVRGSM-UHFFFAOYSA-N 2-[2-(2-heptanoyloxyethoxy)ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCC GCDUWJFWXVRGSM-UHFFFAOYSA-N 0.000 description 3
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- OJXOOFXUHZAXLO-UHFFFAOYSA-M magnesium;1-bromo-3-methanidylbenzene;bromide Chemical compound [Mg+2].[Br-].[CH2-]C1=CC=CC(Br)=C1 OJXOOFXUHZAXLO-UHFFFAOYSA-M 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 150000003346 selenoethers Chemical class 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 3
- SSKNCQWPZQCABD-UHFFFAOYSA-N 2-[2-[2-(2-heptanoyloxyethoxy)ethoxy]ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCC SSKNCQWPZQCABD-UHFFFAOYSA-N 0.000 description 2
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 2
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 2
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000003116 impacting effect Effects 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000011654 magnesium acetate Substances 0.000 description 2
- 235000011285 magnesium acetate Nutrition 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- DLZBUNUDESZERL-UHFFFAOYSA-N 1-o-heptyl 6-o-nonyl hexanedioate Chemical compound CCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCC DLZBUNUDESZERL-UHFFFAOYSA-N 0.000 description 1
- GWQRPOCMBMQBTK-UHFFFAOYSA-N 2-[2-(2-ethylhexanoyloxy)ethoxy]ethyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCOCCOC(=O)C(CC)CCCC GWQRPOCMBMQBTK-UHFFFAOYSA-N 0.000 description 1
- WPMUZECMAFLDQO-UHFFFAOYSA-N 2-[2-(2-hexanoyloxyethoxy)ethoxy]ethyl hexanoate Chemical compound CCCCCC(=O)OCCOCCOCCOC(=O)CCCCC WPMUZECMAFLDQO-UHFFFAOYSA-N 0.000 description 1
- FZWOQNIYLGAJOA-UHFFFAOYSA-N 2-[2-[2-(7-methyloctanoyloxy)ethoxy]ethoxy]ethyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OCCOCCOCCOC(=O)CCCCCC(C)C FZWOQNIYLGAJOA-UHFFFAOYSA-N 0.000 description 1
- YWLXLRUDGLRYDR-ZHPRIASZSA-N 5beta,20-epoxy-1,7beta,10beta,13alpha-tetrahydroxy-9-oxotax-11-ene-2alpha,4alpha-diyl 4-acetate 2-benzoate Chemical compound O([C@H]1[C@H]2[C@@](C([C@H](O)C3=C(C)[C@@H](O)C[C@]1(O)C3(C)C)=O)(C)[C@@H](O)C[C@H]1OC[C@]12OC(=O)C)C(=O)C1=CC=CC=C1 YWLXLRUDGLRYDR-ZHPRIASZSA-N 0.000 description 1
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 description 1
- OIUGWVWLEGLAGH-UHFFFAOYSA-N 6-nonoxy-6-oxohexanoic acid Chemical class CCCCCCCCCOC(=O)CCCCC(O)=O OIUGWVWLEGLAGH-UHFFFAOYSA-N 0.000 description 1
- SXKCDRRSQHPBOI-UHFFFAOYSA-N 6-o-cyclohexyl 1-o-hexyl hexanedioate Chemical compound CCCCCCOC(=O)CCCCC(=O)OC1CCCCC1 SXKCDRRSQHPBOI-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102100035474 DNA polymerase kappa Human genes 0.000 description 1
- 101710108091 DNA polymerase kappa Proteins 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001744 Polyaldehyde Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- TUOSWEIWIXJUAU-UHFFFAOYSA-N bis(7-methyloctyl) cyclohexane-1,1-dicarboxylate Chemical compound CC(C)CCCCCCOC(=O)C1(C(=O)OCCCCCCC(C)C)CCCCC1 TUOSWEIWIXJUAU-UHFFFAOYSA-N 0.000 description 1
- HORIEOQXBKUKGQ-UHFFFAOYSA-N bis(7-methyloctyl) cyclohexane-1,2-dicarboxylate Chemical compound CC(C)CCCCCCOC(=O)C1CCCCC1C(=O)OCCCCCCC(C)C HORIEOQXBKUKGQ-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006059 cover glass Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000004806 diisononylester Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910021424 microcrystalline silicon Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000013615 primer Substances 0.000 description 1
- 239000002987 primer (paints) Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10688—Adjustment of the adherence to the glass layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the invention relates to thin-film solar modules designed as laminated safety glass using a film based on plasticizer-containing polyvinyl acetal and their use.
- Thin-film solar modules consist of a photosensitive
- Semiconductor layer deposited on a substrate e.g. a transparent plate or a flexible carrier sheet e.g. by vapor deposition, vapor deposition, sputtering or wet deposition is applied.
- the thus-supported semiconductor layers are then sandwiched between a glass sheet and a rigid, rear cover plate, e.g. laminated from glass or plastics using a transparent adhesive.
- the transparent adhesive must completely enclose the photosensitive semiconductor layer and its electrical connection lines, be UV-stable and insensitive to moisture and be completely free of bubbles after the lamination process.
- Curing resins or crosslinkable ethylene vinyl acetate (EVA) based systems are often used as transparent adhesives, as disclosed, for example, in DE 41 22 721 C1 or DE 41 28 766 A1. These adhesive systems can be set in the uncured state so low viscosity that they surround the solar cell units bubble-free. After adding a hardener or crosslinking agent, a mechanically resistant adhesive layer is obtained.
- a disadvantage of these adhesive systems is that aggressive substances such as acids are released during the curing process, which can destroy the photosensitive semiconductor layers, in particular thin-film modules.
- some casting resins tend after some years to blistering or delamination by UV radiation.
- PVB polyvinyl butyral
- PVB films Process for the preparation of solar modules using PVB films are z. Example by DE 40 26 165 C2, DE 42 278 60 A1, DE 29 237 70 C2, DE 35 38 986 C2 or US 4,321,418 known.
- the use of PVB films in solar modules as composite safety glazings is e.g. in DE 20 302 045 U 1, EP 1617487 A1, and DE 35 389 86 C2.
- these documents contain no information about the mechanical, chemical and electrical properties of the PVB films used.
- the PVB film is used only for embedding the solar cell units; Safety aspects or the required properties of the PVB film are not described.
- Bonded safety glazings is disclosed in DE 20 302 045 U1 and DE 35 389 86 C2. However, these specifications do not specify the safety properties of the composite glasses or the properties of the PVB film used.
- the safety properties of a composite of glass and PVB film are known to depend on the adhesive force between the film and glass.
- the adhesive force should be so high that the mechanical destruction of the glass gluing the glass fragments to the film is guaranteed and sharp-edged glass fragments can not peel off.
- an impacting object can penetrate the laminated glass, since the PVB film hardly deforms elastically at the point of impact and only slightly contributes to the braking of the object. If the adhesion to the glass is at a lower level, the PVB film at the point of impact can be peeled off from the glass under stretching and deformed, whereby the impacting object is slowed down.
- EP 1617478 A2 describes the production of solar modules which have embedded between two PVB films solar cells.
- the adhesive effect of the PVB film is directly to the glass, so that the safety properties of these solar modules correspond to those of laminated safety glass.
- Thin-film solar modules are not mentioned in this patent.
- the adhesion of the PVB film takes place at least on one surface of the module via the solar cells and not to the glass, so that there is room for improvement here.
- the object of the present invention is therefore to
- the present invention therefore relates to a photovoltaic module, comprising a laminate of a) a transparent front cover b) one or more photosensitive semiconductor layers c) at least one plasticizer-containing, based on polyvinyl acetal Foil and d) a back cover wherein the photosensitive semiconductor layers b) on the transparent
- Front cover a) or the rear cover d) are applied and by at least one plasticized polyvinyl acetal based film c), which have a tensile strength according to EN ISO 527/3 of at least 16 N / mm 2 , are glued together.
- Plasticizer-containing films based on polyvinyl acetal which can be used according to the invention preferably have a tensile strength according to EN ISO 527/3 of 16 to 36 N / mm 2 , in particular 18 to 32 N / mm 2 and preferably of 20 to 30 N / mm 2 .
- Plasticizer-containing polyvinyl acetal-based films used according to the invention therefore preferably have impact strengths of at least 1500 kJ / m 2 , particularly preferably at least 1700 kJ / m 2 , and in particular at least 1800 kJ / m 2 or 2000 kJ / m 2 .
- the upper limit can be a tensile impact strength of 3500 kJ / m 2 .
- Thin-film solar modules contain in particular photosensitive semiconductor layers based on amorphous or microcrystalline silicon, cadmium telluride (CdTe), CIS (copper / indium / (di) selenide) or copper / indium / gallium / sulphide / selenide (CIGS) or thin conductive layers (TCO) are chemically susceptible to corrosion, so the encapsulant must be chemically inert and free of aggressive chemical additives such as crosslinkers, crosslinkers, or primers to avoid acid traces.
- CdTe cadmium telluride
- CIS copper / indium / (di) selenide) or copper / indium / gallium / sulphide / selenide
- TCO thin conductive layers
- the avoidance of acid traces in the production of the material is another way to reduce the tendency of the films used according to the invention to resist photosensitive semiconductor layers.
- Films of this type are produced by extrusion at elevated temperatures, whereby a thermal decomposition of the polymeric material or the plasticizer can occur. Furthermore, by diffused water cleavage of the residual acetate groups of the polyvinyl acetal occur, whereby acetic acid is released. In both cases, acid traces that can attack the photosensitive semiconductor layers result.
- the films used according to the invention therefore preferably have a certain basicity, expressed as alkali titers, which may be above 10, preferably above 15 and in particular above 20, 30 or 40. A maximum alkali titre of 100 should not be exceeded.
- the alkali titer is determined by back-titration of the film, as described below, and may be carried out by addition of basic substances, e.g. Metal salts of organic carboxylic acids having 1 to 15 carbon atoms, in particular alkali or alkaline earth metal salts such as magnesium or potassium acetate can be adjusted.
- the basic compound is usually used in a concentration of 0.005 to 2% by weight, in particular 0.05 to 1% by weight, based on the total mixture.
- the films used in the invention in a
- Ambient humidity of 85% RH at 23 ° C a resistivity of at least 1 E + 11 ohm * cm, preferably at least 5E + 11 ohm * cm, preferably 1 E + 12 ohm * cm, preferably 5E + 12 ohm * cm, preferably 1 E + 13, preferably 5E + 13 ohm * cm, preferably 1 E + 14 ohm * cm on.
- polyvinyl alcohol is dissolved in water and acetalized with an aldehyde such as butyraldehyde with the addition of an acid catalyst.
- the precipitated polyvinyl acetal is separated, washed neutral, optionally suspended in an alkaline aqueous medium, then washed neutral again and dried.
- the acid used for the acetalization must be neutralized again after the reaction. If an excess of base (eg NaOH, KOH or Mg (OH) 2 ) is used here, the alkalititer increases and all or part of the addition of the basic substance can be dispensed with.
- base eg NaOH, KOH or Mg (OH) 2
- the polyvinyl alcohol content of the polyvinyl acetal can be adjusted by the amount of aldehyde used in the acetalization.
- Aldehydes having 2-10 carbon atoms e.g., valeraldehyde.
- the films based on plasticized polyvinyl acetal preferably contain uncrosslinked polyvinyl butyral (PVB), which is obtained by acetalization of polyvinyl alcohol with butyraldehyde.
- PVB polyvinyl butyral
- crosslinked polyvinyl acetals in particular crosslinked polyvinyl butyral (PVB) is also possible.
- Suitable crosslinked polyvinyl acetals are e.g. in EP 1527107 B1 and WO 2004/063231 A1 (thermal self-crosslinking of polyvinyl acetals containing carboxyl groups), EP 1606325 A1 (polyvinyl acetals crosslinked with polyaldehydes) and WO 03/020776 A1 (polyvinyl acetals crosslinked with glyoxylic acid).
- EP 1527107 B1 and WO 2004/063231 A1 thermal self-crosslinking of polyvinyl acetals containing carboxyl groups
- EP 1606325 A1 polyvinyl acetals crosslinked with polyaldehydes
- WO 03/020776 A1 polyvinyl acetals crosslinked with glyoxylic acid
- polyvinyl alcohol terpolymers of hydrolyzed vinyl acetate / ethylene copolymers can be used in the context of the present invention. These compounds are usually hydrolyzed to more than 98 mol% and contain 1 to 10 wt. Based on ethylene units (eg type "Exceval” Kuraray Europe GmbH).
- polyvinyl alcohol hydrolyzed copolymers of vinyl acetate and at least one further ethylenically unsaturated monomer can also be used within the scope of the present invention.
- polyvinyl alcohols can be used in the context of the present invention purely or as a mixture of polyvinyl alcohols with different degree of polymerization or degree of hydrolysis.
- Polyvinyl acetals still contain in addition to the acetal units
- the polyvinyl acetals used according to the invention preferably have a polyvinyl alcohol content of less than 22% by weight, 20% by weight or 18% by weight, less than 16% by weight or 15% by weight and in particular less than 14% by weight. A polyvinyl alcohol content of 12% by weight should not be exceeded.
- Polyvinyl acetal is preferably less than 3% by weight or less than 1% by weight, more preferably less than 0.75% by weight, very preferably less than 0.5% by weight and in particular less than 0.25% by weight.
- the degree of acetalization can be determined by calculation.
- the films have a plasticizer content of at most 40% by weight, 35% by weight, 32% by weight, 30% by weight, 28% by weight, 26% by weight, 24% by weight or 22% by weight. on, with a plasticizer content of 15 wt.% Should not be exceeded for reasons of processability of the film (each based on the total film formulation).
- Inventive films or photovoltaic modules may contain one or more plasticizers.
- Suitable plasticizers for the films used according to the invention are one or more compounds selected from the following groups:
- esters of polyhydric aliphatic or aromatic acids for example dialkyl adipates such as dihexyl adipate, dioctyl adipate, hexyl cyclohexyl adipate, mixtures of heptyl and nonyl adipates, diisononyl adipate, heptyl nonyl adipate and esters of adipic acid with cycloaliphatic or Etheritatien containing ester alcohols, dialkyl sebacates such as dibutyl sebacate and esters of sebacic acid with cycloaliphatic or ether bonds containing ester alcohols, esters of phthalic acid such as butyl benzyl phthalate or bis-2-butoxyethylphthalat
- Esters or ethers of polyhydric aliphatic or aromatic alcohols or oligoether glycols having one or more linear or branched aliphatic or aromatic substituents e.g. Esters of di-, tri- or tetraglycols with linear or branched aliphatic or cycloaliphatic carboxylic acids;
- Esters of di-, tri- or tetraglycols with linear or branched aliphatic or cycloaliphatic carboxylic acids may serve diethylene glycol bis (2-ethylhexanoate), triethylene glycol bis (2-ethylhexanoate), tri-ethylene glycol bis (2-ethylbu-ta-no-ate) .
- Phosphates with aliphatic or aromatic ester alcohols e.g. Tris (2-ethylhexyl) phosphate (TOF), triethyl phosphate, diphenyl-2-ethylhexyl phosphate, and / or tricresyl phosphate
- esters of citric acid, succinic acid and / or fumaric acid Particularly suitable as plasticizers for the films used according to the invention are one or more compounds selected from the following group: di-2-ethylhexyl sebacate (DOS), di-2-ethylhexyl adipate (DOA), dihexyl adipate (DHA ), Dibutyl sebacate (DBS), triethylene glycol bis-n-heptanoate (3G7), tetraethylene glycol bis-n-heptanoate (4G7), triethylene glycol bis-2-ethylhexanoate (3GO or 3G8) tetraethylene glycol bis-n-2 ethylhexanoate (4GO or 4G8) di-2-butoxyethyl adipate (DBEA), di-2-butoxyethoxyethyl adipate (DBEEA) di-2-butoxyethyl sebacate (DBES), di-2-ethy
- Plasticizers whose polarity expressed by the formula 100 ⁇ O / (C + H) is less than or equal to 9.4 are particularly suitable as plasticizers for the films used according to the invention, where O, C and H are the number of oxygen atoms. , Carbon and hydrogen atoms in each molecule.
- the following table shows plasticizers which can be used according to the invention and their polarity values according to the formula 100 ⁇ O / (C + H).
- the ion mobility which is possibly dependent on the water content of the film and thus the specific resistance can be influenced by the addition of SiO 2 , in particular fumed silica.
- the plasticizer-containing films based on polyvinyl acetal preferably contain 0.001 to 15% by weight, preferably 2 to 5% by weight, of SiO 2 .
- the solar module has sound insulating properties in that at least one, preferably both, of the films has soundproofing properties.
- Soundproofing films based on PVB are z.
- EP 1 118 258 B1 or EP 387 148 B1 the disclosure of which is hereby incorporated by reference.
- Soundproofing foils according to EP 1 118 258 B1 increase the sound insulation of a laminated safety glass at its coincidence frequency in the range of 1,000 to 3,500 Hz by at least 2 dB, measured according to DIN EN ISO 717.
- Suitable sound-insulating films contain according to EP 1118258 B1:
- PVB partially acetalized polyvinyl alcohol
- plasticizer mixture From 70 to 30% by weight, calculated as a proportion of the plasticizer mixture, of one or more standard plasticizers, such as di-n-hexyl-adipate (DHA), and triethylene glycol-bis-n-heptanoate (3G7) or triethylene glycol bis- 2-ethylhexanoate (3G8).
- DHA di-n-hexyl-adipate
- G7 triethylene glycol-bis-n-heptanoate
- G8 triethylene glycol bis- 2-ethylhexanoate
- the inventively usable PVB films have the following properties:
- the adhesion of the PVB films on glass and on the solar cell units of importance In addition to the tear strength and / or impact resistance, the adhesion of the PVB films on glass and on the solar cell units of importance.
- the degree of splinter bonding of PVB film in laminated safety glass is determined by the so-called Pummeltest. The performance of this test is known to the person skilled in the art or described in WO 03/033583 A1.
- the solar modules according to the invention should have pummel values of 3 to 5 (high penetration protection) or 7 to 10 (good splinter bonding, eg in the case of overhead glazing).
- Pummel Pummel
- adhesion of PVB films to glass can by the addition of adhesion regulators such.
- adhesion regulators such as alkali and / or alkaline earth metal salts of organic acids can be adjusted. Be particularly suitable potassium acetate and / or magnesium acetate have been found.
- adhesion regulators such as alkali and / or alkaline earth salts.
- the safety properties of the solar modules according to the invention are determined by the adhesion properties of the PVB films to glass. These can be described by measuring compression shear adhesion.
- suitable PVB films preferably have a compression shear adhesion to air / air glass surfaces of 8 - 30 N / mm 2 , preferably 10 - 25 N / mm 2 and in particular 12 - 20 N / mm 2 .
- the compression shear adhesion of these films to glass surfaces with respect to the tin / tin sides of the glass is preferably 8-25 N / mm 2 , preferably 10-20 N / mm 2 .
- Foils are usually 0.38, 0.51, 0.76, 1.14, 1.52 or 2.28 mm.
- the photosensitive material In general, in thin-film modules, the photosensitive material
- this edge region can be very narrow, preferably below 3 cm, especially below 2 cm and in particular below 1 cm.
- the transparent front cover is usually made of glass or PMMA.
- the rear cover of the photovoltaic module according to the invention may consist of glass, plastic or metal or their composites, wherein at least one of the carrier may be transparent. It is also possible to use one or both covers as Laminated glazing (ie as a laminate of at least two glass panes and at least one PVB film) or as insulating glazing with a gas gap perform. Of course, the combination of these measures is possible.
- the photosensitive semiconductor layers used in the modules need not have any special properties. Mono-, polycrystalline or amorphous systems can be used.
- Photovoltaic modules used vacuum laminators. These consist of a heatable and evacuable chamber, in which composite glazing can be laminated within 30 - 60 minutes. Reduced pressures of 0.01 to 300 mbar and temperatures of 100 to 200 0 C, in particular 130 - 160 0 C have proven in practice.
- a laminated as described above composite body between at least one pair of rollers at a temperature of 60 to 150 ° C are pressed into a module according to the invention.
- Systems of this type are known for the production of laminated glazing and usually have at least one heating tunnel before or after the first press shop in systems with two pressing plants.
- the invention relates to the use of plasticizer-containing, based on polyvinyl acetal films having a tensile strength according to EN ISO 527/3 of at least 16 N / mm 2 for the production of photovoltaic modules constructed from a) a transparent front cover b) one or more photosensitive semiconductor layers c) of at least one plasticizer-containing polyvinyl acetal-based film and d) a back cover wherein the photosensitive semiconductor layers b) are applied to the transparent front cover a) or the rear cover d) and by at least one plasticizer-containing on Polyvinyl acetal based film c) are glued together.
- the polyvinyl acetal-based films c) used for this purpose may have the preferred properties described.
- Photovoltaic modules according to the invention can be used as a facade component
- the measurement of the volume resistivity of the film is carried out according to DIN IEC 60093 at a defined temperature and ambient humidity (23 ° C and 85% rl_F) after the film has been conditioned for at least 24 hours under these conditions.
- a plate electrode type 302 132 from Fetronic GmbH and an ohmmeter ISO-Digi 5 kV from Amprobe were used.
- the test voltage was 2.5kV, the waiting time after application of the test voltage up to the data acquisition 60 sec.
- Polyvinyl acetals were determined according to ASTM D 1396-92. The analysis of the metal ion content was carried out by atomic absorption spectroscopy (AAS).
- the water or moisture content of the films is with the Karl Fischer method determined. This method can be carried out both on the unlaminated film and on a laminated photovoltaic module as a function of the distance to the edge of the film.
- the measurement of the toughness of the interlayer material under a rapid, dynamic load is carried out in the impact tensile test according to DIN EN ISO 8256 and is given in kJ / m 2 . Concerning. the testing machine is referred to the ISO 13802.
- the pendulum impact test is carried out in accordance with EN12600; the result is given in the classification of this standard.
- the adhesion of the film to the glass is given in "punch values" in each case based on the fire or tin side of the glass.
- the PVB film to be tested is placed between two flat silicate glass panes of the format 300 mm x 300 mm with a thickness of 2 mm, deaerated in a pre-composite oven with calender rolls to a glass pre-composite and then in an autoclave at a pressure of 12 bar and at a temperature of 140 ° C within a total of 90 min. pressed into a flat laminated safety glass. From the laminated safety glass thus produced, 10 samples measuring 25.4 mm ⁇ 25.4 mm are cut.
- test parameters are as follows:
- Substrate glasses having thereon deposited, functionally contacted thin-layer cells were laminated in the laminator method with a cover glass by PVB films of the composition given in Tables 3 and 4 and subjected to various mechanical tests.
- Float glass of thickness 3 mm VSG 33.2 was used as the substrate glass and plasticized PVB with a total thickness of 0.76 was used as the film mm inserted.
- the quantities in Tables 3 and 4 are in wt.% Based on the sum of PVB and plasticizer. 3G8 stands for
- Interlayer materials i. those with a high tensile strength and / or high tensile impact strength particularly penetration resistant
- Photovoltaic modules are obtained. These are as
Landscapes
- Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
L'invention concerne l'utilisation de feuilles à base de polyvinalacétale, contenant des plastifiants, qui présentent une résistance à la rupture d'au moins 16 n/mm2, pour produire des modules photovoltaïques à couche mince.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008001512.1 | 2008-04-30 | ||
DE102008001512A DE102008001512A1 (de) | 2008-04-30 | 2008-04-30 | Dünnschicht-Solarmodul als Verbundsicherheitsglas |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009133176A2 true WO2009133176A2 (fr) | 2009-11-05 |
WO2009133176A3 WO2009133176A3 (fr) | 2010-08-19 |
Family
ID=41130703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2009/055276 WO2009133176A2 (fr) | 2008-04-30 | 2009-04-30 | Module solaire à couche mince utilisé comme verre de sécurité feuilleté |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE102008001512A1 (fr) |
WO (1) | WO2009133176A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009135930A2 (fr) * | 2008-05-08 | 2009-11-12 | Kuraray Europe Gmbh | Modules photovoltaïques contenant des feuilles plastifiées intermédiaires à haute résistivité transversale et bonne résistance à la pénétration |
DE102018209979A1 (de) * | 2018-06-20 | 2019-12-24 | Solibro Hi-Tech Gmbh | Solarmodul und Verfahren zur Herstellung eines Solarmoduls |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102822250B (zh) | 2010-03-31 | 2015-11-25 | 可乐丽股份有限公司 | 聚乙烯醇缩醛膜及其用途 |
US9254625B2 (en) | 2013-06-10 | 2016-02-09 | Solutia Inc. | Polymer interlayers having improved optical properties |
US10252500B2 (en) | 2014-10-02 | 2019-04-09 | Solutia Inc. | Multiple layer interlayer resisting defect formation |
US9355631B2 (en) | 2014-10-15 | 2016-05-31 | Solutia Inc. | Multilayer interlayer having sound damping properties over a broad temperature range |
US9809010B2 (en) | 2014-10-15 | 2017-11-07 | Solutia Inc. | Multilayer interlayer having sound damping properties over a broad temperature range |
US9809006B2 (en) | 2014-12-08 | 2017-11-07 | Solutia Inc. | Polymer interlayers having improved sound insulation properties |
US9884957B2 (en) | 2014-12-08 | 2018-02-06 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9809695B2 (en) | 2014-12-08 | 2017-11-07 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9815976B2 (en) | 2014-12-08 | 2017-11-14 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US10354636B2 (en) | 2014-12-08 | 2019-07-16 | Solutia Inc. | Polymer interlayers having improved sound insulation properties |
US10553193B2 (en) | 2014-12-08 | 2020-02-04 | Solutia Inc. | Polymer interlayers having improved sound insulation properties |
US9809009B2 (en) | 2014-12-08 | 2017-11-07 | Solutia Inc. | Multiple layer interlayer having improved optical and sound insulation properties |
US9573329B2 (en) | 2014-12-08 | 2017-02-21 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9586386B2 (en) | 2014-12-08 | 2017-03-07 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9925746B2 (en) | 2014-12-08 | 2018-03-27 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9522517B2 (en) | 2014-12-08 | 2016-12-20 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9586387B2 (en) | 2014-12-08 | 2017-03-07 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
US9975315B2 (en) | 2014-12-08 | 2018-05-22 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001079305A2 (fr) * | 2000-04-13 | 2001-10-25 | Kuraray Specialities Europe Gmbh | Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation |
WO2003033583A1 (fr) * | 2001-10-11 | 2003-04-24 | Ht Troplast Ag | Feuille de pvb pour verre de securite et verre de securite feuillete |
WO2005005525A2 (fr) * | 2003-07-12 | 2005-01-20 | Kuraray Specialities Europe Gmbh | Film destine a un vitrage composite de securite et ayant une faible auto-adherence et une bonne adherence sur le verre |
EP1617487A2 (fr) * | 2004-06-23 | 2006-01-18 | Kuraray Specialities Europe GmbH | Module de cellules solaires composé comme un verre de sécurité |
WO2009047223A2 (fr) * | 2007-10-05 | 2009-04-16 | Kuraray Europe Gmbh | Modules photovoltaïques comprenant des films plastifiés présentant une absorption d'humidité réduite |
WO2009047222A2 (fr) * | 2007-10-05 | 2009-04-16 | Kuraray Europe Gmbh | Films plastifiés à base d'acétal de polyvinyle présentant une température de transition vitreuse accrue et un comportement au fluage amélioré |
WO2009071703A2 (fr) * | 2007-12-07 | 2009-06-11 | Kuraray Europe Gmbh | Modules photovoltaïques dotés de films adhésifs réfléchissants |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE876681A (fr) | 1978-06-14 | 1979-11-30 | Bfg Glassgroup | Procede de fabrication d'un panneau comprenant au moins une cellule photovoltaique et panneau comprenant au moins une telle cellule |
EP0018924B2 (fr) | 1979-05-08 | 1989-01-04 | Saint Gobain Vitrage International | Procédé de fabrication de panneaux de photopiles solaires et panneaux obtenus par ce procédé |
US4452935A (en) | 1981-06-01 | 1984-06-05 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Interlayer film for laminated glass |
EP0185863B1 (fr) | 1984-12-24 | 1989-05-03 | Hüls Troisdorf Aktiengesellschaft | Procédé pour fabriquer des feuilles, notamment à base de polyvinyl-butyral à adhésivité superficielle minimale |
DE3538986C3 (de) | 1985-11-02 | 1994-11-24 | Deutsche Aerospace | Verfahren zur Herstellung eines Solargenerators |
FR2644112B1 (fr) | 1989-03-10 | 1991-05-10 | Saint Gobain Vitrage | |
DE4026165A1 (de) | 1990-08-15 | 1992-03-05 | Flachglas Solartechnik Gmbh | Bauplatte fuer laermschutzwand |
DE4122721C1 (fr) | 1991-07-06 | 1992-11-05 | Flachglas Solartechnik Gmbh | |
DE4128766C2 (de) | 1991-08-29 | 1995-07-20 | Flachglas Ag | Solarmodul sowie Verfahren zu dessen Herstellung |
DE4227860A1 (de) | 1991-09-19 | 1993-04-01 | Aug Guttendoerfer Gmbh & Co | Photovoltaische platte, insbesondere zum einsatz als fassadenplatte |
DE19756274A1 (de) | 1997-12-18 | 1999-06-24 | Huels Troisdorf | Weichmacherhaltige Folie aus teilacetalisierten Polyvinylalkoholen |
US6801652B1 (en) | 1998-09-29 | 2004-10-05 | Siemens Aktiengesellschaft | Method for checking the presentation of components to an automatic onserting unit |
DE19951444A1 (de) | 1999-10-25 | 2001-04-26 | Huels Troisdorf | Verfahren und Folie zur Herstellung von Verbundsicherheitsscheiben |
DE10129422A1 (de) | 2001-06-19 | 2003-01-02 | Huels Troisdorf | Weichmacherhaltige PVB-Folie |
DE10143190A1 (de) | 2001-09-04 | 2003-03-20 | Kuraray Specialities Europe | Hochmolekulare, vernetzte Polyvinylbutyrale, Verfahren zu deren Herstellung sowie deren Verwendung |
DE10319198A1 (de) | 2002-07-04 | 2004-01-15 | Kuraray Specialities Europe Gmbh | Vernetzte Polyvinylacetale |
ATE388170T1 (de) | 2003-01-09 | 2008-03-15 | Kuraray Europe Gmbh | Vernetzte polyvinylacetale |
MXPA05007218A (es) | 2003-01-09 | 2005-11-23 | Kuraray Specialities Europe | Poliacetales degradados. |
DE20302045U1 (de) | 2003-02-10 | 2003-07-10 | Wulfmeier Solar Gmbh | Photovoltaik-Module mit PVB (Polyvinyl-Butyral)-Folie |
-
2008
- 2008-04-30 DE DE102008001512A patent/DE102008001512A1/de not_active Withdrawn
-
2009
- 2009-04-30 WO PCT/EP2009/055276 patent/WO2009133176A2/fr active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001079305A2 (fr) * | 2000-04-13 | 2001-10-25 | Kuraray Specialities Europe Gmbh | Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation |
WO2003033583A1 (fr) * | 2001-10-11 | 2003-04-24 | Ht Troplast Ag | Feuille de pvb pour verre de securite et verre de securite feuillete |
WO2005005525A2 (fr) * | 2003-07-12 | 2005-01-20 | Kuraray Specialities Europe Gmbh | Film destine a un vitrage composite de securite et ayant une faible auto-adherence et une bonne adherence sur le verre |
EP1617487A2 (fr) * | 2004-06-23 | 2006-01-18 | Kuraray Specialities Europe GmbH | Module de cellules solaires composé comme un verre de sécurité |
WO2009047223A2 (fr) * | 2007-10-05 | 2009-04-16 | Kuraray Europe Gmbh | Modules photovoltaïques comprenant des films plastifiés présentant une absorption d'humidité réduite |
WO2009047222A2 (fr) * | 2007-10-05 | 2009-04-16 | Kuraray Europe Gmbh | Films plastifiés à base d'acétal de polyvinyle présentant une température de transition vitreuse accrue et un comportement au fluage amélioré |
WO2009071703A2 (fr) * | 2007-12-07 | 2009-06-11 | Kuraray Europe Gmbh | Modules photovoltaïques dotés de films adhésifs réfléchissants |
Non-Patent Citations (1)
Title |
---|
KARL HEINZ DIEFENBACH: "The return of laminated glass modules with PVB" INTERNET CITATION April 2005 (2005-04), Seiten 1-4, XP002563934 Gefunden im Internet: URL:http://www.photon-magazine.com/News/ne ws_2005-04%20ww%20feat%20PVB%20 foils.htm [gefunden am 2010-01-18] * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009135930A2 (fr) * | 2008-05-08 | 2009-11-12 | Kuraray Europe Gmbh | Modules photovoltaïques contenant des feuilles plastifiées intermédiaires à haute résistivité transversale et bonne résistance à la pénétration |
WO2009135930A3 (fr) * | 2008-05-08 | 2010-09-23 | Kuraray Europe Gmbh | Modules photovoltaïques contenant des feuilles plastifiées intermédiaires à haute résistivité transversale et bonne résistance à la pénétration |
DE102018209979A1 (de) * | 2018-06-20 | 2019-12-24 | Solibro Hi-Tech Gmbh | Solarmodul und Verfahren zur Herstellung eines Solarmoduls |
Also Published As
Publication number | Publication date |
---|---|
WO2009133176A3 (fr) | 2010-08-19 |
DE102008001512A1 (de) | 2009-11-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2009133176A2 (fr) | Module solaire à couche mince utilisé comme verre de sécurité feuilleté | |
EP1617487B1 (fr) | Module de cellules solaires composé comme un verre de sécurité | |
EP2145353B1 (fr) | Modules photovoltaïques dotés de films adhésifs réfléchissants | |
EP2408619B1 (fr) | Modules photovoltaïques contenant des couches intermédiaires en feuilles plastifiées à haute transmission du rayonnement | |
WO2009047222A2 (fr) | Films plastifiés à base d'acétal de polyvinyle présentant une température de transition vitreuse accrue et un comportement au fluage amélioré | |
WO2009047223A2 (fr) | Modules photovoltaïques comprenant des films plastifiés présentant une absorption d'humidité réduite | |
EP2274366B1 (fr) | Films plastifiés à base d acétal de polyvinyle avec des esters d acide cyclohexane-1,2-dicarboxylique comme plastifiant | |
EP2195854A2 (fr) | Modules photovoltaïques comprenant des films plastifiés à base d'acétal de polyvinyle présentant une résistivité élevée | |
EP2286463A2 (fr) | Modules photovoltaïques contenant des feuilles plastifiées intermédiaires à haute résistivité transversale et bonne résistance à la pénétration | |
WO2009132987A2 (fr) | Modules photovoltaïques contenant des feuilles de couche intermédiaire plastifiées présentant une faible teneur en polyacétate de vinyle | |
EP2259334A1 (fr) | Module photovoltaïque doté de feuilles contenant du plastifiant et ayant un fluage faible | |
WO2009133163A2 (fr) | Modules photovoltaïques contenant des feuilles plastifiées ayant fonction de couche intermédiaire, à base d'acide silicique | |
EP2286461B1 (fr) | Modules photovoltaïques contenant des feuilles plastifiées ayant fonction de couche intermédiaire, à titre alcalin élevé | |
EP2395561B1 (fr) | Modules photovoltaïques dotés de feuilles adhésives réfléchissantes ayant une tendance à la décoloration réduite | |
EP2288498A2 (fr) | Procédé de fabrication de modules photovoltaïques dans une machine à stratifier sous vide à vide de traitement réduit | |
EP2283522B1 (fr) | Modules photovoltaïques contenant des feuilles plastifiées faisant office de couche intermédiaire, à faible température de transition vitreuse | |
EP2425969A1 (fr) | Modules photovoltaïques dotés de films adhésifs à base de polyvinylacétal contenant un produit de remplissage minéral | |
WO2010043641A1 (fr) | Module photovoltaïque contenant des films plastifiés de couche intermédiaire en polyacétate de vinyle, ayant une teneur élevée en polyacétate de vinyle |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09738220 Country of ref document: EP Kind code of ref document: A2 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 09738220 Country of ref document: EP Kind code of ref document: A2 |