WO2009114953A1 - Email - Google Patents

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Publication number
WO2009114953A1
WO2009114953A1 PCT/CH2009/000089 CH2009000089W WO2009114953A1 WO 2009114953 A1 WO2009114953 A1 WO 2009114953A1 CH 2009000089 W CH2009000089 W CH 2009000089W WO 2009114953 A1 WO2009114953 A1 WO 2009114953A1
Authority
WO
WIPO (PCT)
Prior art keywords
nanoparticles
aggregate
lost
enamel
ability
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CH2009/000089
Other languages
English (en)
French (fr)
Inventor
Michèle Reigner
Olivier Pujol
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rolex SA
Original Assignee
Rolex SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rolex SA filed Critical Rolex SA
Priority to CN2009801095699A priority Critical patent/CN101977859A/zh
Priority to JP2011500022A priority patent/JP5793072B2/ja
Priority to EP09722884A priority patent/EP2271592A1/fr
Publication of WO2009114953A1 publication Critical patent/WO2009114953A1/fr
Anticipated expiration legal-status Critical
Priority to US12/885,823 priority patent/US8329779B2/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • B44F1/04—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back
    • B44F1/045—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back having mirrors or metallic or reflective layers at the back side
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62—Metallic pigments or fillers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62—Metallic pigments or fillers
    • C09C1/627—Copper
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62—Metallic pigments or fillers
    • C09C1/64—Aluminium
    • C09C1/644—Aluminium treated with organic compounds, e.g. polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B19/00—Indicating the time by visual means
    • G04B19/06—Dials
    • G04B19/12—Selection of materials for dials or graduations markings
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B37/00—Cases
    • G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent

Definitions

  • the present invention relates to a transparent or translucent colored enamel.
  • This enamel may be in the form of a layer supported on a light reflecting substrate, the "color" effect then being essentially provided by surface reflection, multiple internal reflections and dispersion.
  • a first way to remove the metallic nanoparticles their ability to aggregate during the preparation of the enamel or during the thermal treatment of cooking thereof, is to coat them with a substance inert with respect to others constituents present in the slip, for example crystalline silica such as that described in particular in the disclosure WO 2008/014623, which relates to ceramics and not enamels.
  • a second way of eliminating the ability of metal nanoparticles to aggregate or join together is to functionalize their surface.
  • the invention also relates to layer enamels which can be deposited on a base, a metal surface or other light reflective surface, for example on white enamel.
  • the intense and deep "color” effect is then amplified by the scattering of light reflected on the background.
  • moiré effects or "butterfly wings” or “holograms” effects (i.e., iridescence, color variation, or ghosting effects when the incidence of light varies) one can create a finished decoration consisting of several layers of enamel, especially if the enamel layers are very thin, typically less than 1 micron.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Glass Compositions (AREA)
  • Paints Or Removers (AREA)
  • Powder Metallurgy (AREA)
  • Surface Treatment Of Glass (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
PCT/CH2009/000089 2008-03-19 2009-03-10 Email Ceased WO2009114953A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2009801095699A CN101977859A (zh) 2008-03-19 2009-03-10 搪瓷
JP2011500022A JP5793072B2 (ja) 2008-03-19 2009-03-10 エナメル
EP09722884A EP2271592A1 (fr) 2008-03-19 2009-03-10 Email
US12/885,823 US8329779B2 (en) 2008-03-19 2010-09-20 Enamel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08405083.0 2008-03-19
EP08405083A EP2103572A1 (fr) 2008-03-19 2008-03-19 Email

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/885,823 Continuation-In-Part US8329779B2 (en) 2008-03-19 2010-09-20 Enamel

Publications (1)

Publication Number Publication Date
WO2009114953A1 true WO2009114953A1 (fr) 2009-09-24

Family

ID=39494695

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CH2009/000089 Ceased WO2009114953A1 (fr) 2008-03-19 2009-03-10 Email

Country Status (5)

Country Link
US (1) US8329779B2 (enExample)
EP (2) EP2103572A1 (enExample)
JP (1) JP5793072B2 (enExample)
CN (1) CN101977859A (enExample)
WO (1) WO2009114953A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011035446A1 (fr) 2009-09-22 2011-03-31 Rolex S.A. Matériau composite coloré par des nanoparticules

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515782B (zh) * 2011-12-22 2014-09-03 许昌学院 一种通过外加纳米材料在氧化气氛下烧制钧瓷的方法
US20140013800A1 (en) * 2012-07-12 2014-01-16 Richline Group, Inc. Jewelry article with formed illusion plate
TWI534819B (zh) * 2014-07-31 2016-05-21 常憶科技股份有限公司 於靜態電流測試下檢測全域字元線缺陷
ITUA20163229A1 (it) * 2016-05-06 2017-11-06 Angelo Po Grandi Cucine Spa Prodotto per il rivestimento di superfici metalliche
CN106365452B (zh) * 2016-08-31 2019-03-12 醴陵市恒辉瓷厂 亮光砂金釉及其制备方法
EP4528390A1 (fr) * 2023-09-25 2025-03-26 The Swatch Group Research and Development Ltd Procédé de fabrication d'un composant horloger émaillé

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0094801B1 (en) * 1982-05-14 1987-10-07 Johnson Matthey Public Limited Company Compositions comprising inorganic particles
EP0651030A1 (en) * 1993-10-29 1995-05-03 COOKSON MATTHEY CERAMICS & MATERIALS LIMITED Pigmentary material
US20060240254A1 (en) * 2005-04-25 2006-10-26 Hitachi Magnet Wire Corporation Partial-discharge-resistant insulating varnish, insulated wire and method of making the same
DE102006005089A1 (de) * 2006-02-04 2007-08-09 Preh Gmbh Bedienelement

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11228175A (ja) * 1998-02-19 1999-08-24 Mitsuboshi Belting Ltd ガラス着色剤組成物及びガラス着色膜の製造方法
JP4865994B2 (ja) * 2004-05-06 2012-02-01 株式会社ノリタケカンパニーリミテド 厚盛加飾が施された陶磁器およびその製造方法
DE602006009921D1 (de) * 2006-07-31 2009-12-03 Rolex Sa Pigmentierter keramischer Körper
WO2008014623A1 (fr) 2006-07-31 2008-02-07 Ecole Polytechnique Federale De Lausanne (Epfl) Nanoparticules a noyau metallique recouvert de silice
CN101058284A (zh) * 2007-04-18 2007-10-24 赵建明 陶瓷、搪瓷、玻璃装饰图纹绘制方法及肌理专用颗粒色料

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0094801B1 (en) * 1982-05-14 1987-10-07 Johnson Matthey Public Limited Company Compositions comprising inorganic particles
EP0651030A1 (en) * 1993-10-29 1995-05-03 COOKSON MATTHEY CERAMICS & MATERIALS LIMITED Pigmentary material
US20060240254A1 (en) * 2005-04-25 2006-10-26 Hitachi Magnet Wire Corporation Partial-discharge-resistant insulating varnish, insulated wire and method of making the same
DE102006005089A1 (de) * 2006-02-04 2007-08-09 Preh Gmbh Bedienelement

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; TERAOKA, FUMIO ET AL: "Characteristics of hard resin teeth with nanocomposite enamel layer", XP002484615, retrieved from STN Database accession no. 2003:136534 *
SHIKA ZAIRYO, KIKAI , 21(6), 351-356 CODEN: SZKIDA; ISSN: 0286-5858, 2002 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011035446A1 (fr) 2009-09-22 2011-03-31 Rolex S.A. Matériau composite coloré par des nanoparticules

Also Published As

Publication number Publication date
EP2103572A1 (fr) 2009-09-23
JP2011519379A (ja) 2011-07-07
US8329779B2 (en) 2012-12-11
EP2271592A1 (fr) 2011-01-12
CN101977859A (zh) 2011-02-16
JP5793072B2 (ja) 2015-10-14
US20110009525A1 (en) 2011-01-13

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