WO2009103703A1 - Procede de decontamination d'un effluent liquide radioactif en un ou plusieurs elements chimiques radioactifs par extraction solide-liquide mettant en oeuvre une boucle de recyclage - Google Patents
Procede de decontamination d'un effluent liquide radioactif en un ou plusieurs elements chimiques radioactifs par extraction solide-liquide mettant en oeuvre une boucle de recyclage Download PDFInfo
- Publication number
- WO2009103703A1 WO2009103703A1 PCT/EP2009/051862 EP2009051862W WO2009103703A1 WO 2009103703 A1 WO2009103703 A1 WO 2009103703A1 EP 2009051862 W EP2009051862 W EP 2009051862W WO 2009103703 A1 WO2009103703 A1 WO 2009103703A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- radioactive
- reactor
- solid particles
- solid
- particles
- Prior art date
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Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
- G21C19/42—Reprocessing of irradiated fuel
- G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
- G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Definitions
- the present invention relates to a method for decontaminating a radioactive liquid effluent comprising one or more chemical elements to be removed, said elements being radionuclides, said method involving a solid-liquid extraction step (or so-called coprecipitation step) .
- Such a method finds particular application in the reprocessing of radioactive liquid effluents, loaded in particular with strontium, ruthenium, americium, plutonium, uranium or cesium.
- barium sulphate capable of capturing and retaining strontium
- iron and copper hydroxide particles capable of capturing and retaining ruthenium and ⁇ emitters, such as americium, plutonium and uranium;
- nickel and cobalt ferrocyanide particles capable of collecting and selectively retaining cesium.
- the decontamination treatment can be carried out according to two modes: a discontinuous mode, in which only a predetermined volume of liquid effluent to be decontaminated introduced into a reactor, into which the solid particles capable of capturing and retain the chemical element (s) to be removed and / or the precursor reactants of said particles; a continuous mode, in which the effluent to be decontaminated, the solid particles capable of capturing and retaining the chemical element (s) to be removed and / or the reagents, are introduced into a reactor continuously, with a constant or variable flow rate; precursors of said particles, the addition of particles and / or reagents can be carried out in a cascade of reactors.
- a suspension of solid particles having captured the elements to be eliminated initially present in the liquid effluent we obtain at the end of the treatment in the reactor, a suspension of solid particles having captured the elements to be eliminated initially present in the liquid effluent.
- the final outcome of the treatment then consists in carrying out a liquid / solid separation step generally in a decanter. This step can be facilitated by adding to the suspension a coagulating agent and / or a flocculating agent.
- the solid phase collected at the end of this separation step (called at this stage "sludge”) is then considered as an ultimate waste and is packaged, usually in bitumen or in a cement matrix, before being stored.
- the decontaminated liquid is, in turn, released into the environment, if its radiological and chemical composition allows. Otherwise, the liquid may be subjected to, again, a subsequent decontamination treatment.
- the invention relates to a continuous process for decontaminating a radioactive liquid effluent comprising one or more radioactive chemical elements to be eliminated, comprising the following steps:
- a step of separating said solid phase and said liquid phase characterized in that part of said solid phase obtained at the end of the decantation stage is reinjected into the first reactor for the implementation of a contacting step as defined above.
- This newly implemented process has the following advantages: - for a given quantity of radioactive chemical elements to be eliminated, an improvement in the effectiveness of the decontamination without increasing the amount of solid phase generated, because of the reuse of part of the solid phase for decontaminating the liquid effluent; in the end, a reduction in solid waste, due to the reuse of part of the solid phase to eliminate the desired radioactive chemical elements; - As a result, an improvement in the decontamination efficiency and / or concentration of radioactive chemical elements to be eliminated in a smaller volume of solid waste.
- a continuous process is conventionally meant a process in which the steps are carried out without interruption, namely that, at time t, a volume of liquid effluent undergoes the contacting step while another volume undergoes the decantation and separation step.
- the process comprises a step of contacting a liquid effluent in a first reactor with solid particles able to capture and retain the radioactive chemical element or elements to be eliminated, whereby a suspension of solid particles containing said radioactive chemical element (s) to be removed is obtained.
- the solid particles capable of capturing and retaining the one or more elements of the contacting step are conventionally, in accordance with the method of the invention, of two types: a part is derived from a continuous flow in the first reactor of non-waste particles (namely not having yet undergone a step of contacting with the liquid effluent) and / or reagents capable of generating by chemical reaction said particles; and
- the other part comes from the reinjection step mentioned above.
- the first reactor is conventionally fed, throughout the course of the process, with a stream of liquid effluent to be decontaminated and with a stream of particles and / or reagents such as as mentioned above, a portion of the particle stream from the reinjection step.
- the first reactor may advantageously comprise a stirring device making it possible to ensure the mixing of the incoming flows and the homogenization of the contents of the reactor.
- the assembly consisting of the liquid effluent and the particles form a suspension, without sedimentation of the solid particles in the first reactor.
- an overflow may be formed, in which case the process may comprise, concomitantly with the contacting step, a step of evacuating the overflow, for example, overflow.
- the solid particles capable of capturing and retaining the radioactive chemical element or elements to be extracted from the liquid effluent will be chosen so as to capture and retain the radioactive chemical element (s) in question.
- the radioactive chemical elements may be selected from strontium, ruthenium, cesium, ⁇ emitters, such as americium, plutonium and uranium, and mixtures thereof.
- the decontamination process of the invention may be a process for the decontamination of radioactive liquid effluents, originating, for example, from nuclear installations.
- the solid particles may be particles of barium sulfate, barium carbonate, calcium carbonate, iron hydroxide, calcium phosphate, phosphate iron, manganese dioxide, titanium dioxide, preferably barium sulfate.
- the solid particles may be iron hydroxide and copper particles.
- the solid particles can be particles of ferrocyanides of nickel and cobalt, tetraphenylborate and / or more generally particles having a zeolite structure.
- the solid particles capable of capturing and retaining cesium are ferrocyanide particles of nickel and cobalt.
- the method of the invention comprises a decantation step, this decantation stage conventionally consisting in leaving the suspension obtained in the previous step in a reactor of the decanter type. , so as to obtain sedimentation of the particles having captured and retained the chemical element (s) to be removed.
- a phase is obtained comprising said particles in the lower part of the decanter and a supernatant liquid phase depleted or even devoid of said radioactive chemical element (s) to be removed and consequently of said particle (s). solid.
- the decantation step because of not involving a membrane, has the advantage of not generating radioactive contamination of the membrane and thus the problems arising from such decontamination.
- a membrane in particular an organic membrane as conventionally used in the field of solid-liquid separation, would generate problems of transport and packaging of such contaminated membranes, in particular because of a potential release of hydrogen linked to the radiolysis thereof by the radioactive elements trapped therein.
- the second decanter type reactor is fed with an output stream of the first reactor, this output stream comprising said suspension. Decantation may be facilitated by a step of adding in the second reactor a coagulant and / or flocculant.
- the process of the invention comprises a step of separating said solid phase and said liquid phase, the supernatant liquid phase being conventionally discharged by overflow, whereas the solid phase is conventionally discharged by withdrawal, generally, discontinuously.
- part of this solid phase is reinjected into the first reactor to participate again in the step of contacting with another volume of liquid effluent to be decontaminated.
- the depleted or even depleted liquid phase recovered in radioactive chemical elements retained by the enriched phase solid particles can be either released into the environment, if the radiological examination allows, be subjected to other treatments, if necessary.
- part of the solid phase obtained after decantation is reinjected into the first reactor, generally in the form of a flow conveying the solid phase from the second reactor to the first reactor (this flow may be described as a "recycling loop ").
- this loop has the effect of bringing the solid phase into contact with the liquid effluent charged with chemical element (s) to be removed.
- the solid phase is still able to fix a certain amount of these chemical elements, which consequently has the consequence of increasing the chemical activity of these particles.
- the amount of radioactive chemical elements retained in the solid phase increases with the amount of solid particles in the first reactor. Since the step of reinjection of the solid particles makes it possible to increase the concentration of solid particles in the reactor, the method of the invention thus makes it possible to perform a more thorough decontamination of the effluents to be treated.
- the reinjection step it is also possible to reduce the total amount of reagents and / or solid particles to be introduced during the treatment. Despite the lower introduction of reagents and / or solid particles into the first reactor, the decontamination efficiency can be maintained or even improved by adjusting the rate of reintroduction of particles from the second reactor to the first reactor.
- the process of the invention may advantageously comprise a step of filling the first reactor with a predetermined volume of liquid effluent to be treated and a predetermined quantity of solid particles capable of capturing and retaining the radioactive chemical element (s) to be removed and / or reagents as defined above and, advantageously, a step of filling the second reactor with a suspension comprising solid particles capable of capturing and retaining the radioactive chemical element (s) to be eliminated, so that, at the first start of the implementation stage, contact, the reinjection step can take place from said suspension.
- the solid phase reinjected later will consist of solid particles having already undergone the contacting step.
- the single figure represents, in the form of a block diagram, an example of an installation intended to allow the implementation of the method of the invention.
- This example illustrates the implementation of the method of the invention for the decontamination of a liquid effluent containing strontium.
- FIG. 1 shows, in the form of a schematic diagram, an example of an installation 1 designed for implementing the method of the invention in the context of FIG. an industrial process for decontaminating an aqueous effluent, for example from the reprocessing of an irradiated nuclear fuel, comprising strontium.
- the installation 1 comprises respectively: a first reactor 3 intended to receive the aqueous effluent to be decontaminated and the solid particles (or reagents capable of reacting to form the appropriate particles) capable of capturing and retaining the strontium contained in the liquid effluent, this first reactor being in the form of a glass reactor with a working volume of 2.5 liters; the first reactor 3 being provided with a stirring device 5 and metal baffles and an overflow (not shown, intended to evacuate the overflow if necessary); a second reactor 7 providing the decanter function for receiving the suspension formed in the first reactor, this suspension comprising the solid particles having complexed strontium, this second reactor being a cylindro-conical type reactor having a working volume of 13 liters, the suspension feed being carried out at its center; a first pipe 9 connected to the first reactor 3 which supplies the latter with aqueous effluent comprising the strontium element to be removed, the routing being facilitated via a peristaltic pump (not shown); a second
- a third pipe 13 which connects the first reactor 3 to the second reactor 7 and which conveys, in the form of an overflow flow, the suspension comprising the solid particles having captured and retained the strontium from the first reactor to the second reactor; reactor;
- a fourth pipe 15 which connects the second reactor 7 to the first reactor 3 and which conveys a part of the solid phase decanted in the second reactor to the first reactor (also called recycling loop);
- a fifth pipe 17 which allows the withdrawal of the liquid phase 16 decontaminated; a sixth pipe 19 which allows the withdrawal of the solid phase 18 not being rerouted to the first reactor.
- the treatment efficiency is evaluated by a parameter: the decontamination factor denoted FD.
- the FD corresponds to the ratio of the strontium concentration in the input stream (flow passing through the first pipe 9) and of this same concentration in the flow leaving the first reactor (flow passing through the third conduct 13).
- the FD can also be defined as the ratio of the strontium concentration in the input stream (flow through the first conduit 9) and the same concentration. in the flow leaving the second reactor (flow exiting through line 17).
- the effluent introduced into the reactor 3 via line 9 is composed of 0.5 mol / L of sodium nitrate, 0.1 mol / L of sodium sulphate and 1.14 ⁇ ⁇ 4 mol / L of strontium nitrate.
- the element to be eliminated is strontium.
- the flow rate of effluent in line 9 is adjusted to 14 L / h.
- the reagent introduced via line 11 is a solution of 0.29 mol / L barium nitrate and the flow rate in line 11 is 1 l / h.
- the sulphate ions introduced via line 9 will react with the barium ions introduced via line 11 to form solid particles of barium sulphate which will capture and retain strontium.
- the recycling loop is not activated (no flow in line 15), after 40 minutes of operation, the FD measured at the outlet of reactor 3 through line 13 is equal to 60 ⁇ 5 and the FD measured at the outlet of the reactor 7 through line 17 is equal to 100 ⁇ 10.
- the FD in the liquid phase in line 13 is increased by a factor of about 8 or about 500 ⁇ 150.
- the FD in the liquid phase of the pipe 17 is about 500 ⁇ 50. Improvement of the decontamination is linked to the existence of the recycling loop and, chemical point of view, inter alia, the decrease in the crystal growth rate of BaSO 4 resulting from the existence of this loop, the decrease in speed being related to a quantity and a surface of BaSO 4 crystals greater than those existing in the case where there is no recycling loop. It has been found that the decrease in crystal growth rate of BaSO 4 promotes strontium decontamination.
- the effluent introduced into the reactor 3 via line 9 is composed of 0.5 mol / L of sodium nitrate, of 0.1 mol / L. sodium sulphate and l, 14.10 ⁇ 4 mol / L of strontium nitrate.
- the element to be eliminated is strontium.
- the flow rate of effluent in line 9 is adjusted to 14 L / h.
- the reagent introduced via line 11 is a solution of barium nitrate at 0.29 mol / L and the flow rate in line 11 is 0.5 L / h, divided by 2 relative to Example 1. This As a result, the production rate of barium sulphate in reactor 3 is divided by 2. As a result, hourly production of sludge is divided by 2.
- the measured DF at the outlet of reactor 3 through line 13 is equal to 20 ⁇ 3 and the FD measured at the outlet of reactor 7 through line 17 is equal to 30 ⁇ 3.
- the FD in the liquid phase in line 13 is increased by a factor of 5 or about 100 ⁇ 10.
- the FD in the liquid phase of line 17 is about 150 ⁇ 10.
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Plasma & Fusion (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20090711778 EP2253000B1 (fr) | 2008-02-18 | 2009-02-17 | Procede de decontamination d'un effluent liquide radioactif en un ou plusieurs elements chimiques radioactifs par extraction solide-liquide mettant en oeuvre une boucle de recyclage |
JP2010546362A JP5586479B2 (ja) | 2008-02-18 | 2009-02-17 | リサイクルループを用いる固液抽出により放射性液体排出物を1つ以上の放射性化学元素に除染するプロセス |
AT09711778T ATE515040T1 (de) | 2008-02-18 | 2009-02-17 | Verfahren zur dekontaminierung einer radioaktiven flüssigeffluenz mit einem oder mehreren chemischen elementen durch feststoff-flüssigkeit- extraktion mithilfe eines recycling-kreislaufs |
US12/918,032 US8696911B2 (en) | 2008-02-18 | 2009-02-17 | Decontamination of radioactive liquid effluent by solid-liquid extraction using a recycle loop |
CN200980106162.0A CN101952898B (zh) | 2008-02-18 | 2009-02-17 | 使用再循环回路通过固-液萃取法对放射性液态流出物净化的方法 |
RU2010138608/07A RU2498431C2 (ru) | 2008-02-18 | 2009-02-17 | Способ дезактивации жидких радиоактивных отходов от одного или нескольких радиоактивных химических элементов путем отделения твердой фазы от жидкой с использованием контура рециркуляции |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0851023A FR2927725B1 (fr) | 2008-02-18 | 2008-02-18 | Procede de decontamination d'un effluent liquide en un ou plusieurs elements chimiques par extraction solide-liquide mettant en oeuvre une boucle de recyclage |
FR0851023 | 2008-02-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009103703A1 true WO2009103703A1 (fr) | 2009-08-27 |
Family
ID=39577495
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2009/051862 WO2009103703A1 (fr) | 2008-02-18 | 2009-02-17 | Procede de decontamination d'un effluent liquide radioactif en un ou plusieurs elements chimiques radioactifs par extraction solide-liquide mettant en oeuvre une boucle de recyclage |
Country Status (10)
Country | Link |
---|---|
US (1) | US8696911B2 (fr) |
EP (1) | EP2253000B1 (fr) |
JP (1) | JP5586479B2 (fr) |
KR (1) | KR101575916B1 (fr) |
CN (1) | CN101952898B (fr) |
AT (1) | ATE515040T1 (fr) |
ES (1) | ES2369066T3 (fr) |
FR (1) | FR2927725B1 (fr) |
RU (1) | RU2498431C2 (fr) |
WO (1) | WO2009103703A1 (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011082285A1 (de) * | 2011-09-07 | 2013-03-07 | Itn Nanovation Ag | Verfahren zur Abtrennung von radioaktiven Nukliden mittels keramischer Filtermembranen |
JP6343760B2 (ja) * | 2012-01-10 | 2018-06-20 | 国立研究開発法人日本原子力研究開発機構 | 液中からの放射性元素の分離・除去方法 |
JP5722242B2 (ja) * | 2012-01-16 | 2015-05-20 | 株式会社日立パワーソリューションズ | 放射性物質の除染方法及び除染装置 |
JP2013231695A (ja) * | 2012-05-01 | 2013-11-14 | Sanai Fujita | 除染剤及び除染方法 |
JP2013231696A (ja) * | 2012-05-01 | 2013-11-14 | Sanai Fujita | 放射性物質の固定化剤及び固定化方法 |
JP6078987B2 (ja) * | 2012-05-29 | 2017-02-15 | 栗田工業株式会社 | 放射性ストロンチウム含有排水の処理方法及び処理装置 |
WO2014038713A1 (fr) * | 2012-09-10 | 2014-03-13 | 学校法人慈恵大学 | Agent de décontamination du césium radioactif et procédé pour sa production et procédé d'élimination du césium radioactif |
JP6180748B2 (ja) * | 2013-02-06 | 2017-08-16 | 株式会社東芝 | 放射性廃液の沈降分離装置及び沈降分離方法 |
JP2015114315A (ja) * | 2013-12-06 | 2015-06-22 | 株式会社 環境浄化研究所 | 晶析を利用したストロンチウム除去方法 |
KR102557638B1 (ko) * | 2021-07-12 | 2023-07-21 | 한국원자력연구원 | 순환식 염폐기물 처리방법 및 장치 |
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BE535584A (fr) * | ||||
FR1399711A (fr) * | 1964-04-09 | 1965-05-21 | Kuhlmann Ets | Procédé de décontamination d'une solution radioactive |
FR2478364A1 (fr) * | 1980-02-29 | 1981-09-18 | Rhein Westfael Elect Werk Ag | Procede de traitement d'effluents liquides provenant de centrales nucleaires ou analogues et contenant des radionucleides |
EP0180308A1 (fr) * | 1984-10-25 | 1986-05-07 | Mobil Oil Corporation | Zéolite an borosilicate pour l'élimination des déchets nucléaires |
DE3744699A1 (de) * | 1987-02-10 | 1988-12-08 | Allgaeuer Alpenmilch | Verfahren zum entfernen von radioaktiven metallisotopen aus fluessigen lebens- oder futtermitteln |
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GB1242733A (en) * | 1967-10-24 | 1971-08-11 | Rudolf Paul Fritsch | A slit-shaped extrusion nozzle for extrusion of synthetic thermoplastics materials |
GB1312852A (en) * | 1970-09-01 | 1973-04-11 | Belgonucleaire Sa | Decontamination processes for radio-active liquids |
ZA923591B (en) * | 1991-05-16 | 1993-11-18 | Johannesburg Cons Invest | A method of treating water containing radioactive constituents |
JP2738478B2 (ja) * | 1992-02-10 | 1998-04-08 | 株式会社日立製作所 | 放射性廃液中の放射性核種の分離方法および産業廃液中の有用または有害元素の分離方法 |
JPH08327789A (ja) * | 1995-06-01 | 1996-12-13 | Toshiba Eng Co Ltd | 放射性廃棄物処理系設備 |
JP2000246262A (ja) * | 1999-03-03 | 2000-09-12 | Nuclear Fuel Ind Ltd | 廃液からの重金属除去時、発生するスラッジの低減方法 |
CN1281525C (zh) * | 2004-05-25 | 2006-10-25 | 侯立安 | 放射性废水处理方法及其所使用的处理系统 |
RU2273066C1 (ru) * | 2004-09-13 | 2006-03-27 | Государственное унитарное предприятие города Москвы - объединенный эколого-технологический и научно-исследовательский центр по обезвреживанию РАО и охране окружающей среды (ГУП МосНПО "Радон") | Способ переработки жидких радиоактивных отходов |
FR2904888B1 (fr) * | 2006-08-11 | 2008-12-19 | Cezus Cie Europ Du Zirconium S | Methode de stabilisation du radium dans les effluents radiferes. |
CN101051534A (zh) * | 2007-04-27 | 2007-10-10 | 清华大学 | 一种处理含低放射性水的方法 |
-
2008
- 2008-02-18 FR FR0851023A patent/FR2927725B1/fr not_active Expired - Fee Related
-
2009
- 2009-02-17 JP JP2010546362A patent/JP5586479B2/ja not_active Expired - Fee Related
- 2009-02-17 US US12/918,032 patent/US8696911B2/en not_active Expired - Fee Related
- 2009-02-17 ES ES09711778T patent/ES2369066T3/es active Active
- 2009-02-17 WO PCT/EP2009/051862 patent/WO2009103703A1/fr active Application Filing
- 2009-02-17 EP EP20090711778 patent/EP2253000B1/fr active Active
- 2009-02-17 AT AT09711778T patent/ATE515040T1/de not_active IP Right Cessation
- 2009-02-17 CN CN200980106162.0A patent/CN101952898B/zh not_active Expired - Fee Related
- 2009-02-17 KR KR1020107018377A patent/KR101575916B1/ko not_active IP Right Cessation
- 2009-02-17 RU RU2010138608/07A patent/RU2498431C2/ru not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE535584A (fr) * | ||||
FR1399711A (fr) * | 1964-04-09 | 1965-05-21 | Kuhlmann Ets | Procédé de décontamination d'une solution radioactive |
FR2478364A1 (fr) * | 1980-02-29 | 1981-09-18 | Rhein Westfael Elect Werk Ag | Procede de traitement d'effluents liquides provenant de centrales nucleaires ou analogues et contenant des radionucleides |
EP0180308A1 (fr) * | 1984-10-25 | 1986-05-07 | Mobil Oil Corporation | Zéolite an borosilicate pour l'élimination des déchets nucléaires |
DE3744699A1 (de) * | 1987-02-10 | 1988-12-08 | Allgaeuer Alpenmilch | Verfahren zum entfernen von radioaktiven metallisotopen aus fluessigen lebens- oder futtermitteln |
Also Published As
Publication number | Publication date |
---|---|
EP2253000A1 (fr) | 2010-11-24 |
FR2927725B1 (fr) | 2014-09-05 |
ES2369066T3 (es) | 2011-11-25 |
KR101575916B1 (ko) | 2015-12-08 |
FR2927725A1 (fr) | 2009-08-21 |
JP5586479B2 (ja) | 2014-09-10 |
CN101952898B (zh) | 2014-03-26 |
US8696911B2 (en) | 2014-04-15 |
KR20100114898A (ko) | 2010-10-26 |
JP2011512531A (ja) | 2011-04-21 |
CN101952898A (zh) | 2011-01-19 |
RU2498431C2 (ru) | 2013-11-10 |
EP2253000B1 (fr) | 2011-06-29 |
US20110036777A1 (en) | 2011-02-17 |
ATE515040T1 (de) | 2011-07-15 |
RU2010138608A (ru) | 2012-03-27 |
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