WO2009102040A1 - Cream-like emulsion - Google Patents
Cream-like emulsion Download PDFInfo
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- WO2009102040A1 WO2009102040A1 PCT/JP2009/052441 JP2009052441W WO2009102040A1 WO 2009102040 A1 WO2009102040 A1 WO 2009102040A1 JP 2009052441 W JP2009052441 W JP 2009052441W WO 2009102040 A1 WO2009102040 A1 WO 2009102040A1
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- cream
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0053—Compositions other than spreads
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
- A23L9/20—Cream substitutes
- A23L9/24—Cream substitutes containing non-milk fats and non-milk proteins, e.g. eggs or soybeans
Definitions
- the present invention relates to a cream substitute food that can be used in the same manner as conventional cream or whipped cream.
- cream is defined as “raw milk, milk or special milk from which ingredients other than fat have been removed” (December 27, 1951, Ministry of Health and Welfare Ordinance No. 52). 2. “Ingredient standards for milk, etc. and standards for manufacturing, cooking and storage methods” stipulate that milk fat content is 18.0% or more (other conditions include acidity, number of bacteria, etc.) Yes. According to the FAO / WHO (United Nations Food and Agriculture Organization / World Insurance Organization) international dairy product standard, “Cream is a relatively fat separated from milk that forms“ fat emulsion in fat-free milk ”.
- ⁇ Refers to rich dairy products, '' depending on fat content, cream (18% fat content), whipped and whipped cream (28% or more), heavy whipped and whipped heavy cream (35%) Above), double cream (more than 45%) and half cream (10-18%).
- the “fatless milk-in-fat type emulsion” is a so-called Oil in Water (O / W) type emulsion.
- creams are classified in various ways in each country according to their respective laws and regulations.
- a compound in which a part of milk fat is replaced or strengthened with fats other than milk fat (for example, vegetable oils such as palm oil) and an emulsion is stabilized by adding an emulsifier or a stabilizer is “compound cream It is generally excellent in physical properties such as whipping properties as a confectionery raw material and the shape-retaining property of the whipped produced, and is used in various applications such as coffee cream, whipping cream, and cooking cream. (For example, refer nonpatent literature 1).
- cream-like foods made mainly from soy milk instead of milk and vegetable oils such as palm oil, rapeseed oil and coconut oil instead of milk fat are mainly used.
- Cream-like foods used as raw materials are also available on the market, and the type of food is labeled as “vegetable fat food” or “vegetable fat creamed food”, meaning “whipped cream-like food” Products such as “Whipping” and “Fresh” are added to the product name for beverage addition such as coffee.
- the conventional “cream” and its substitutes are collectively referred to as “creams”.
- creams can be used for various decorations such as cakes and other confectionery, emulsification aids for sauces and soups during cooking, and seasonings for beverages such as coffee and tea. Used for applications.
- creams having a relatively high fat content of 30% or more have good whipping properties and good shape-retaining properties of the whipped products, and are therefore used as whipped (whipped cream (also called whipped cream)).
- creams When using creams as described above, there is no problem when the original taste and aroma of milk, which is a raw material for cream (whipped), is required, such as a cream cake.
- creams are often used for emulsification and whipping, but if you want to enhance the taste and fragrance of other ingredients, or you need the emulsified taste and fragrance, milk The taste and aroma of may not be necessary.
- countermeasures have been taken to reduce the taste of the cream itself derived from milk by increasing the water content during cooking. This is not limited to fresh creams made from milk, but the same applies to creams containing vegetable oils as raw materials. Soy protein, pea protein, The same is true when using creams containing plant-derived proteins such as corn protein and wheat gluten.
- the present inventor has found that the taste and aroma of such creams are caused by the taste and aroma of proteins contained in the raw materials such as milk and soybean. That is, although creams are foods rich in fat components, they always contain a certain amount or more of protein, which remains as a part of the taste and aroma of cooking. Therefore, since the protein contained in the cream raw material remains, the measure of increasing the water and diluting the taste of the cream was not sufficient.
- the present invention is intended to provide a cream-like emulsion that can sufficiently ensure physical properties such as emulsifying action and shape retention when whipped even if it is emulsified without containing protein.
- the present invention is a cream-like emulsion comprising a fat component, water, and an emulsifier that does not contain an emulsifying protein or peptide, and emulsified with the fat component, water, and emulsifier. is there.
- the protein component contained in the cream is responsible for the emulsifying action of the fat component and moisture, but the cream-like emulsion of the present invention does not use the action of the protein ingredient but contains an emulsifier.
- the “emulsifier” in the present invention means a substance having an action of emulsifying a fat component and moisture.
- emulsifiers applicable to the present invention include commonly used food emulsifiers such as monoglycerides (glycerin fatty acid esters or derivatives thereof), polyglycerin esters, sucrose fatty acid esters, sorbitan fatty acid esters, propylene glycol fatty acid esters, lecithin, Various types such as saponin and gum arabic can be used singly or in combination.
- the above-mentioned emulsifiers are examples of those that are approved for use as “edible emulsifiers” in Japan.
- the use of emulsifiers varies depending on the national laws and regulations of each country, but any substance that has an emulsifying action may be used. It corresponds to the “emulsifier” in the present invention.
- emulsifiers applicable to the present invention exclude those containing protein components and peptide components, such as gelatin, whey protein, casein and the like.
- the cream-like emulsion of the present invention emulsified without containing the protein component is a cream that does not produce a taste and aroma derived from the protein component, it is compared with the conventional various creams as described above.
- the taste and aroma of milk, soybeans, etc. which are the main raw materials, are hardly felt at all.
- the cream-like emulsion of this invention has the emulsification effect
- the cream-like emulsion of the present invention is emulsified without containing a protein component, it is resistant to heat and acid, and is not easily denatured even when heated or combined with acidic foods. It is possible to expand the variation of cooking usage and usage.
- the fat component contained in the cream-like emulsion of the present invention can be any of animal fat, vegetable fat, a mixture of animal fat and vegetable fat, or processed oil.
- animal fats include milk fats of mammals such as milk, fats and oils derived from dairy products such as butter oil, and edible fats and oils such as lard.
- vegetable fats include various vegetable oils and fats that are generally recognized as edible, such as palm kernel oil, soybean hardened oil, cocoa butter, and the like.
- Processed fats and oils are edible fats and oils which processed animal fat, vegetable fat, or mixtures thereof, such as hydrogenation, fractionation, or transesterification.
- hard fats and oils, liquid fats and oils, or a mixture thereof can be appropriately applied as a fat component in the present invention.
- trans fats are not particularly contained.
- the content of the fat component is in the range of 60% by weight or less. If the fat component exceeds 60% by weight, the O / W emulsion is phase-inverted, making it unsuitable for use as a substitute for conventional creams.
- the lower limit of the content of the fat component is set to a value exceeding 0%, and can be appropriately set as long as an O / W emulsion is formed.
- the cream-like emulsion of the present invention may further contain a stabilizer that stabilizes the emulsified state of the fat component, water, and emulsifier.
- the stabilizer stabilizes the state in which the fat component and water are emulsified with an emulsifier.
- an emulsifier for example, thickening polysaccharides, starch, carrageenan, agar, propylene glycol alginate, gum arabic xanthan gum and the like What is normally used as a stabilizer can be used suitably.
- the stabilizer in the present invention includes those containing protein components derived from milk such as gelatin and casein (or sodium caseinate), and those containing plant-derived protein components such as soybean protein and wheat protein.
- the stabilizer containing these protein components is only used as a “stabilizer” for stabilizing the emulsified state of the cream-like emulsion in the present invention.
- a protein component such as gum arabic, xanthan gum, gelatin, casein (sodium casein), and the like, which have an action as an emulsifier for emulsifying a fat component and moisture, although it can be used as either an emulsifier or a stabilizer, those containing a protein component can be used only as a stabilizer.
- the amount of use such that the cream-like emulsion of the present invention does not exhibit a taste or aroma derived from the stabilizer for example, about several% to 1%, Desirably, it should be kept below 1%.
- the stabilizers mentioned above are examples of those that are approved for use as “edible stabilizers” in Japan. Stabilization of the emulsified state is possible depending on national laws and regulations of each country. Any substance having an action corresponds to the “stabilizer” in the present invention.
- the cream-like emulsion of the present invention is a food product that is emulsified with a fat component, moisture, and an emulsifier without containing any protein component or peptide component, and has the same emulsification performance and whipping performance as conventional creams. Therefore, it can be used for the same use as conventional creams.
- the present invention does not have the taste and scent of raw materials derived from protein components, it has a particular taste and scent for milk, soybeans, etc. It is suitable for use in place of conventional creams in the production and cooking of foods, such as when it is not desired to leave in cooking, or when only an emulsified or whipped taste or flavor is required.
- Examples 7 is a radar graph showing absolute values of taste intensity in Examples 1 to 4 of the present invention and a comparative example.
- 5 is a radar graph showing a relative value of the taste intensity of Examples 1 to 4 with respect to a comparative example.
- the distribution map which shows the balance of the taste of the Examples 1-4 and a comparative example.
- the graph which shows the similarity degree of the smell with respect to the reference gas of the Examples 1-4 and a comparative example.
- the embodiment of the present invention is a cream-like emulsion obtained by mixing and emulsifying a mixture of edible fats and oils, water, and food emulsifiers as fat components.
- a stabilizer can be added to stabilize the emulsification, and other food additives can be appropriately added depending on the application. .
- oils and fats For edible oils and fats, one or more animal oils such as butter oil, lard and het, various vegetable oils such as palm kernel oil, soybean hardened oil, rapeseed oil, corn oil, cocoa butter are mixed. Can be used.
- the fat component can be adjusted to an appropriate amount as long as it is always contained at a value of 60% by weight or less of the cream-like emulsion.
- the emulsifier one or more kinds of commonly used food emulsifiers such as lecithin, sorbitan fatty acid ester, propylene glycol fatty acid ester, glycerin fatty acid ester and sucrose fatty acid ester can be used.
- the proportion of the emulsifier in the cream-like emulsion may be an appropriate amount sufficient to emulsify them according to the proportion of the fat component and water.
- the stabilizer is a mixture of one or more commonly used food stabilizers such as thickening polysaccharides, starch, propylene glycol alginate, gum arabic and the like as described above. Can be used.
- the stabilizer is not an essential component of the cream-like emulsion, but an appropriate amount may be added as necessary in consideration of time from preparation to use and distribution.
- the proportion of the fat component in the cream-like emulsion is relatively low, about several to 20%, it has a light flavor and is suitable for use as a substitute for coffee cream or cooking cream.
- the content is relatively high, such as 30% or more, it has a rich flavor, so it can be used as a substitute for cream for cooking, and is suitable for use as a substitute for whipped cream.
- cream-like emulsions were prepared, and as a comparative example, commercially available creams (“foods mainly made of milk and the like using fresh cream”) were used, An evaluation test, an odor discrimination test, and an overrun test were conducted.
- the cream-like emulsion of each Example needed several days between preparation of a sample, a taste evaluation test, and an odor discrimination test, the stabilizer is used.
- Example 1 Fat component: 235 g of butter oil, water: 238 g, emulsifier: 1.5 g of sorbitan fatty acid ester (trade name “poem60”), 5 g of glycerin fatty acid ester (trade name “poem81”), stable Agent: octenyl succinic esterified starch (trade name “Emulstar”) 20 g, alginate propylene glycol ester (trade name “Duckroid”) 1 g, fat content about 47.0% (weight)
- Example 2 Fat component: 130 g of palm kernel oil, 105 g of soybean hardened oil, water; 234 g, emulsifier; 1.5 g of sorbitan fatty acid ester (same as above), 4 g of lecithin (derived from soybean), glycerin fatty acid ester ( Same as above) 5 g, Stabilizer; Octyl succinate esterified starch (same as above) 20 g, Alginate propylene glycol ester (same as above) 1 g, Fat content of about 47.0% (weight)
- Example 3 Fat component: 130 g of palm kernel oil, 105 g of soybean hardened oil, water; 238 g, emulsifier; 1.5 g of sorbitan fatty acid ester (same as above), 5 g of glycerin fatty acid ester (same as above), stabilizer; Octyl succinate esterified starch (same as above) 20 g, alginate propylene glycol ester (same as above) 1 g, fat content about 47.0% (weight)
- Example 4 Fat component: 130 g of palm kernel oil, 105 g of soybean hardened oil, water; 258 g, emulsifier; 1.5 g of sorbitan fatty acid ester (same as above), 5 g of glycerin fatty acid ester (same as above), stabilizer; 1 g of propylene glycol alginate (same as above), fat content of about 47.0% (weight)
- the taste intensity (absolute value) of a reference solution (a mixture of 30 mM KCl and 0.3 mM tartaric acid solution) that is almost tasteless to human saliva was measured at room temperature (20 ° C.), and the taste of the comparative example was determined from the absolute value. Differences in taste between samples were evaluated using relative values converted so that the intensity was zero.
- the “taste intensity” is a value indicated by the scale of the taste recognition device, and a value (mostly 1.2 times the density difference) that most people feel a difference is set to “1”. Therefore, the taste intensity difference “2” is about 1.44 times the density difference, and “4” is about twice the density difference.
- “Taste” represents the taste immediately after the food is put in the mouth
- “Aftertaste” represents the taste that spreads after the food is swallowed.
- Table 2 below shows the taste intensity of each example and comparative example as an absolute value when the above-described reference solution is 0.
- a radar graph that points to the values in the table is shown in FIG. (1)
- each sample showed a negative value for sourness and saltiness relative to the reference solution. It is a difference at a low concentration that is not felt by the taste, and is considered not effective as a taste comparison between samples.
- the taste intensity effective for the evaluation of each sample is “bitter taste miscellaneous taste”, “stimulated astringency”, “umami”, “bitter taste” of aftertaste, “astringency”, and “umami richness”. .
- the balance state of “umami”, “umami rich”, “bitter taste miscellaneous”, and “astringency stimulation” of each sample is shown as a mapping diagram in FIG.
- FIG. 2 and FIG. 3 the cream-like emulsions of Examples 1, 2, and 3 all showed a similar taste, compared to the comparative examples that are conventional creams, “Bitter taste miscellaneous taste” and “stimulated astringency” were strong, and aftertaste “umami richness” was weak.
- the “umami” taste, the “bitter taste”, and the “astringency” aftertaste were slightly stronger than the comparative example, but were within 1 in that case.
- the cream-like emulsion of Example 4 showed a tendency that all taste strengths were weak unlike all other Examples and Comparative Examples. As a conclusion of the taste evaluation test, it is considered that the cream-like emulsions of each example show different tastes from the creams using the fresh cream of the comparative example.
- the measurement sequence is ASmell condition, gas suction time 60 Measurement is performed in seconds, and the analysis of the measurement result is performed by calculating the similarity to the reference gas, the odor contribution, and the odor index equivalent value using the analysis software (absolute value expression software ASmell2, manufactured by the company) attached to the odor discriminator.
- the odor of each example was compared with that of the comparative example.
- the results of similarity to the reference gas are shown in Table 4 and FIG. 4, and the results of odor index equivalent values are shown in Table 5 and FIG.
- the “similarity” indicates which line the odor quality is close to. If the aldehyde similarity is calculated as 50%, the sample contains 50% aldehydes. This means that the degree of similarity with the aldehyde system is 50%.
- the “odor contribution value” is a value indicating the odor intensity of each system as an odor index equivalent value.
- the “odor index equivalent value” is obtained by quantifying the odor intensity of the sample gas measured by the odor identification device as a value corresponding to the odor index.
- Example 1 and Example 3 showed a difference of 10% or more in hydrogen sulfide, sulfur-based, ammonia, and aldehyde-based
- Example 2 A difference of 10% or more was recognized in hydrogen sulfide, sulfur, ammonia, aldehyde, and hydrocarbon
- Example 4 showed a difference of 10% or more in all systems other than aromatic.
- Ganache chocolate was cooked using 50 g of bitter chocolate and 100 g of the cream-like emulsion of Example 4 or fresh cream.
- A is bitter chocolate and fresh cream
- B is bitter chocolate and the cream-like emulsion of Example 4.
- B has a bitter and sour taste that is characteristic of bitter chocolate. The original chocolate flavor remains.
- Strawberry mousse was cooked with 50 g of strawberry puree and the cream-like emulsion of Example 4 or fresh cream.
- A is strawberry puree and fresh cream
- B is strawberry puree and the cream-like emulsion of Example 4. Impression: A became the taste of strawberry milk, and the richness of sweetness and cream was felt, but the taste of strawberry was weak. B has a strawberry scent and acidity, and it is not milky and light.
- Pasta sauce was cooked with tomato sauce 100 g, olive oil 20 g, the cream-like emulsion of Example 4 or fresh cream or water.
- A is tomato sauce, olive oil and water
- B is tomato sauce, olive oil and the cream-like emulsion of Example 4
- C is tomato sauce, olive oil and fresh cream.
- A has olive oil floating on the surface and completely separated, sour taste of tomato is felt, but also oily.
- B is a little pinkish red and oil is not floating, and is completely emulsified. It has a mild taste and richness.
- C becomes whitish pink and the oil is not floating and is emulsified. It has a mild taste and a rich taste, but has a creamy taste.
- A is a flour and water
- B is a flour and the cream-like emulsion of Example 4. Impression: A is soft, fluffy and watery, and a little oily and damp. B is crisp and has a good texture and is neither oily nor damp.
- A is puree and water and water
- B is puree and water and milk
- C is puree and water and fresh cream
- D is puree and water and the cream-like emulsion of Example 4.
- A is the taste of the pumpkin itself, but it feels blue and watery.
- B loses its pumpkin taste, it is light and watery, and the taste of milk is felt.
- C is mellow and rich, but it feels heavy without the taste of pumpkin.
- D is assassic, but the taste of the pumpkin remains and there is also a richness.
- the cream-like emulsion of the present invention is not limited to the above-mentioned Example 4 but also includes other examples.
- the cream-like emulsion of the present invention can be used as a substitute for fresh creams and other creams. It can be used as a substitute for creams that can enhance the taste of food, and can be used for various foods as a food material with new possibilities.
- the cream-like emulsion of the present invention can be used as a substitute for conventional creams, and can be applied to the production of food, the production of seasonings and food additives, cooking, and the like.
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Abstract
Provided is a novel cream-like emulsion which contains a fat component, moisture and an emulsifier, wherein an emulsifier containing no emulsifying protein or peptide is used as the emulsifier and emulsification is conducted by using these fat component, moisture and emulsifier. Owing to the above-described constitution, this cream-like emulsion is free from the taste or smell originating in protein components contained in the starting material and ensures sufficient emulsifying effect and physical properties such as shape retention in whipping, which makes it equally usable with the existing creams such as fresh cream and cream substitutes.
Description
本発明は、従来の生クリームやホイップクリーム等と同様に使用することができるクリーム代用食品に関するものである。
The present invention relates to a cream substitute food that can be used in the same manner as conventional cream or whipped cream.
クリームとは、日本国においては「生乳、牛乳または特別牛乳から脂肪以外の成分を除去したものを言う」と定義され(昭和26年12月27日厚生省令第52号)、同省令の別表の二「乳等の成分規格並びに製造、調理及び保存の方法の基準」では、乳脂肪分が18.0%以上(他の条件として酸度、際菌数等が定められている)と定められている。また、FAO/WHO(国連食糧農業機関/世界保険機構)の乳製品国際規格では、「クリームとは、“無脂肪牛乳中脂肪型のエマルジョン”を形成している牛乳から分離した比較的脂肪に富む乳製品を言う」と定義されており、脂肪含量に応じて、クリーム(脂肪分18%以上)、ホイッピングおよびホイップドクリーム(同28%以上)、ヘビーホイッピングおよびホイップドヘビークリーム(同35%以上)、ダブルクリーム(同45%以上)、ハーフクリーム(同10~18%)の5種類に分類されている。ここで、“無脂肪牛乳中脂肪型のエマルジョン”とは、いわゆるOil in Water(O/W)型エマルジョンのことである。さらに、各国においてはそれぞれの法令等により、クリームは種々に分類されている。
In Japan, cream is defined as “raw milk, milk or special milk from which ingredients other than fat have been removed” (December 27, 1951, Ministry of Health and Welfare Ordinance No. 52). 2. “Ingredient standards for milk, etc. and standards for manufacturing, cooking and storage methods” stipulate that milk fat content is 18.0% or more (other conditions include acidity, number of bacteria, etc.) Yes. According to the FAO / WHO (United Nations Food and Agriculture Organization / World Insurance Organization) international dairy product standard, “Cream is a relatively fat separated from milk that forms“ fat emulsion in fat-free milk ”. `` Refers to rich dairy products, '' depending on fat content, cream (18% fat content), whipped and whipped cream (28% or more), heavy whipped and whipped heavy cream (35%) Above), double cream (more than 45%) and half cream (10-18%). Here, the “fatless milk-in-fat type emulsion” is a so-called Oil in Water (O / W) type emulsion. Furthermore, creams are classified in various ways in each country according to their respective laws and regulations.
日本国内では、製品の種類別表示として「クリーム」と表示するためには、前述の乳等省令に記載されているクリームの成分規格の規定を満たさなければならず、食品添加物を一切添加しない場合は「クリーム」または「生クリーム」と称することができるが、同規格に規定されている以外のものとして、例えば安定剤やメタリン酸ナトリウム等を原材料成分に含む場合には、「乳等を主要原料とする食品」と表示されている。また、乳脂肪の一部を乳脂肪以外の脂肪(例えば、パーム油等の植物性油脂)で置換または強化し、乳化剤や安定剤を加えてエマルジョンを安定化させたものは、「コンパウンド・クリーム」と呼ばれ、一般に製菓原料等としてのホイッピング性や生成されたホイップの保型性といった物性に優れており、コーヒー用クリーム、ホイップ用クリーム、料理用クリーム等の多様な用途に用いられている(例えば、非特許文献1参照)。
In Japan, in order to display “Cream” as a product type label, it must meet the requirements for cream ingredient standards described in the Ordinance of the Ministry of Milk, etc., and no food additives are added. In some cases, it may be referred to as “cream” or “fresh cream”. However, as other than those prescribed in the same standard, for example, when a stabilizer, sodium metaphosphate, etc. It is labeled “Food as a main ingredient”. In addition, a compound in which a part of milk fat is replaced or strengthened with fats other than milk fat (for example, vegetable oils such as palm oil) and an emulsion is stabilized by adding an emulsifier or a stabilizer is “compound cream It is generally excellent in physical properties such as whipping properties as a confectionery raw material and the shape-retaining property of the whipped produced, and is used in various applications such as coffee cream, whipping cream, and cooking cream. (For example, refer nonpatent literature 1).
また、以上の他にも、クリームの代用品としては、牛乳に代えて豆乳を主原料としたクリーム様食品や、乳脂肪に代えてパーム油やナタネ油やヤシ油等の植物性油脂を主原料として用いたクリーム様の食品も市販されており、食品の種類別表示としては「植物性脂肪食品」や「植物油脂クリーミング食品」と表示され、「泡立てたクリーム状のもの」を意味する「ホイップ」や、コーヒー等の飲料添加用として「フレッシュ」等の名称を商品名に付して販売されている。以下、本明細書においては、従来の「クリーム」やその代用品を総称する場合は、「クリーム類」と呼ぶものとする。
In addition to the above, as substitutes for cream, cream-like foods made mainly from soy milk instead of milk and vegetable oils such as palm oil, rapeseed oil and coconut oil instead of milk fat are mainly used. Cream-like foods used as raw materials are also available on the market, and the type of food is labeled as “vegetable fat food” or “vegetable fat creamed food”, meaning “whipped cream-like food” Products such as “Whipping” and “Fresh” are added to the product name for beverage addition such as coffee. Hereinafter, in the present specification, the conventional “cream” and its substitutes are collectively referred to as “creams”.
このようなクリーム類は、脂肪分の含有量に応じて、ケーキ等の菓子類のデコレーション、調理の際のソースやスープの乳化補助剤、コーヒーや紅茶等の飲料への調味剤など、様々な用途に用いられている。特に脂肪分が30%以上と比較的多いクリーム類はホイッピング性や生成されたホイップの保型性が良好であるため、泡立ててホイップ(ホイップドクリーム(ホイップクリームともいう))として使用される。
Depending on the fat content, such creams can be used for various decorations such as cakes and other confectionery, emulsification aids for sauces and soups during cooking, and seasonings for beverages such as coffee and tea. Used for applications. In particular, creams having a relatively high fat content of 30% or more have good whipping properties and good shape-retaining properties of the whipped products, and are therefore used as whipped (whipped cream (also called whipped cream)).
上述のようにクリーム類を使用する場合、例えば生クリームのケーキのように、クリーム(ホイップ)の原材料である牛乳本来の味や香りが必要とされる場合は何ら問題が生じることはない。一方、調理においては、乳化や泡立て(ホイップ)のためにクリーム類を使用することが多々あるが、他の材料の味や香りを引き立てたい場合や、乳化した味や香りは必要であるが牛乳の味や香りは必要でない場合がある。さらにいえば、単に乳化等が調理で必要であるにもかかわらず、クリームの味や香りが料理に残るのは不都合な場合さえある。このような場合においては、従来は、調理の際に水の含有量を増加して牛乳に由来するクリーム自体の味を薄めるという対応がなされていた。このことは、牛乳を原料とする生クリームの場合に限られたことではなく、植物油脂を原料に含むクリーム類においても同様であり、そのようなクリーム類に含まれる大豆タンパク、エンドウ豆タンパク、トウモロコシタンパク、小麦グルテン等の植物由来のタンパクを含有しているクリーム類を使用する場合でも同様のことがいえる。
When using creams as described above, there is no problem when the original taste and aroma of milk, which is a raw material for cream (whipped), is required, such as a cream cake. On the other hand, in cooking, creams are often used for emulsification and whipping, but if you want to enhance the taste and fragrance of other ingredients, or you need the emulsified taste and fragrance, milk The taste and aroma of may not be necessary. Furthermore, it may even be inconvenient that the taste and aroma of the cream remain in the dish even though emulsification or the like is simply required for cooking. In such a case, conventionally, countermeasures have been taken to reduce the taste of the cream itself derived from milk by increasing the water content during cooking. This is not limited to fresh creams made from milk, but the same applies to creams containing vegetable oils as raw materials. Soy protein, pea protein, The same is true when using creams containing plant-derived proteins such as corn protein and wheat gluten.
鋭意研究の結果、本発明者は、このようなクリーム類の味や香りが、原料である牛乳や大豆等に含まれているタンパク質の味や香りに起因していることを見出した。すなわち、クリーム類は、脂肪成分が豊富な食品ではあるが、一定量以上のタンパク質が必ず含まれており、これが料理の味や香りの一部として残ってしまうのである。したがって、クリーム類の原料に含まれるタンパク質は残存しているので、水を増やしてクリーム類の味を薄めて調理するという対策では到底十分とはいえなかった。
As a result of diligent research, the present inventor has found that the taste and aroma of such creams are caused by the taste and aroma of proteins contained in the raw materials such as milk and soybean. That is, although creams are foods rich in fat components, they always contain a certain amount or more of protein, which remains as a part of the taste and aroma of cooking. Therefore, since the protein contained in the cream raw material remains, the measure of increasing the water and diluting the taste of the cream was not sufficient.
そこで本発明は、タンパク質を含まずに乳化させても、乳化作用やホイップした際の保形性等の物性を十分確保することができる、クリーム様乳化物を提供しようとするものである。
Therefore, the present invention is intended to provide a cream-like emulsion that can sufficiently ensure physical properties such as emulsifying action and shape retention when whipped even if it is emulsified without containing protein.
すなわち本発明は、脂肪成分と、水分と、乳化作用のあるタンパク質又はペプチドを含有しない乳化剤とを含有し、これら脂肪成分と水分と乳化剤とにより乳化させたことを特徴とするクリーム様乳化物である。
That is, the present invention is a cream-like emulsion comprising a fat component, water, and an emulsifier that does not contain an emulsifying protein or peptide, and emulsified with the fat component, water, and emulsifier. is there.
従来のクリーム類であれば、それに含有されるタンパク質成分が脂肪成分と水分との乳化作用を担っているが、本発明のクリーム様乳化物ではタンパク質成分の作用を利用せず乳化剤を含有させることにより脂肪成分と水分とを乳化させるようにしている。ここで、本発明において「乳化剤」とは、脂肪成分と水分とを乳化させる作用を有する物質を意味する。本発明に適用可能な乳化剤としては、通常使用される食品用乳化剤、例えばモノグリセリド(グリセリン脂肪酸エステル、又はその誘導体)、ポリグリセリンエステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン、サポニン、アラビアガム等の種々のものを単一種類又は複数種類組み合わせて用いることができる。なお、上述した乳化剤は、日本国において「食用乳化剤」として使用が認められているものを例示したものであり、各国の国内法令等により使用の可否は異なるが、乳化作用のある物質であれば本発明における「乳化剤」に該当する。但し、本発明に適用可能な乳化剤からは、タンパク質成分やペプチド成分を含有するもの、例えばゼラチン、ホエイプロテイン、カゼイン等は除外される。
In the case of conventional creams, the protein component contained in the cream is responsible for the emulsifying action of the fat component and moisture, but the cream-like emulsion of the present invention does not use the action of the protein ingredient but contains an emulsifier. Thus, fat components and water are emulsified. Here, the “emulsifier” in the present invention means a substance having an action of emulsifying a fat component and moisture. Examples of emulsifiers applicable to the present invention include commonly used food emulsifiers such as monoglycerides (glycerin fatty acid esters or derivatives thereof), polyglycerin esters, sucrose fatty acid esters, sorbitan fatty acid esters, propylene glycol fatty acid esters, lecithin, Various types such as saponin and gum arabic can be used singly or in combination. The above-mentioned emulsifiers are examples of those that are approved for use as “edible emulsifiers” in Japan. The use of emulsifiers varies depending on the national laws and regulations of each country, but any substance that has an emulsifying action may be used. It corresponds to the “emulsifier” in the present invention. However, emulsifiers applicable to the present invention exclude those containing protein components and peptide components, such as gelatin, whey protein, casein and the like.
そして、タンパク質成分を含有させることなく乳化させた本発明のクリーム様乳化物は、タンパク質成分に由来する味や香りを生じ得ないクリーム類であるため、上述したような従来の各種クリーム類と比較して、主要原材料となる牛乳や大豆等の味や香りがほぼ全く感じられない。しかも本発明のクリーム様乳化物は、従来のクリーム類と同様の乳化作用やホイッピング作用を有していることから、従来のクリーム類と同様に使用することができる。したがって、本発明のクリーム様乳化物を用いれば、このクリーム様乳化物自体から牛乳や大豆等の味や香りが生じないため、乳化やホイップした味や風味のみを必要とする料理を調理する際に極めて有用となる。さらに、本発明のクリーム様乳化物は、タンパク質成分を含まずに乳化したものであることから熱や酸に強く、加熱したり酸性の食材と組み合わせても変性が起こりにくいため、従来のクリーム類よりも調理の用途や使用方法のバリエーションを広げることができる。
And since the cream-like emulsion of the present invention emulsified without containing the protein component is a cream that does not produce a taste and aroma derived from the protein component, it is compared with the conventional various creams as described above. In addition, the taste and aroma of milk, soybeans, etc., which are the main raw materials, are hardly felt at all. And since the cream-like emulsion of this invention has the emulsification effect | action and whipping effect | action similar to the conventional cream, it can be used similarly to the conventional cream. Therefore, if the cream-like emulsion of the present invention is used, the cream-like emulsion itself does not produce a taste or aroma such as milk or soybean. Therefore, when cooking a dish that only needs an emulsified or whipped taste or flavor, Very useful. Furthermore, since the cream-like emulsion of the present invention is emulsified without containing a protein component, it is resistant to heat and acid, and is not easily denatured even when heated or combined with acidic foods. It is possible to expand the variation of cooking usage and usage.
ここで、本発明のクリーム様乳化物に含まれる脂肪成分は、動物性脂肪、又は植物性脂肪、又は動物性脂肪と植物性脂肪の混合物、又は加工油脂の何れかとすることができる。動物性脂肪としては、牛乳等の哺乳動物の乳脂肪やバターオイル等の乳製品由来の油脂、ラード等の食用油脂を例示することができる。また、植物性脂肪としては、パーム核油、大豆硬化油、カカオバター等、通常食用として認められている種々の植物油脂を例示することができる。加工油脂は、動物性脂肪、植物性脂肪、又はそれらの混合物に水素添加や分別又はエステル交換等の加工を施した食用油脂である。別の分類に従えば、本発明には脂肪成分として、硬化油脂、液状油脂、又はそれらの混合物を適宜適用することができるが、摂取に伴う健康面に配慮すれば、特にトランス脂肪酸を含有しないか、低トランス脂肪酸の脂肪成分を用いることが望ましい。
Here, the fat component contained in the cream-like emulsion of the present invention can be any of animal fat, vegetable fat, a mixture of animal fat and vegetable fat, or processed oil. Examples of animal fats include milk fats of mammals such as milk, fats and oils derived from dairy products such as butter oil, and edible fats and oils such as lard. Examples of vegetable fats include various vegetable oils and fats that are generally recognized as edible, such as palm kernel oil, soybean hardened oil, cocoa butter, and the like. Processed fats and oils are edible fats and oils which processed animal fat, vegetable fat, or mixtures thereof, such as hydrogenation, fractionation, or transesterification. According to another classification, hard fats and oils, liquid fats and oils, or a mixture thereof can be appropriately applied as a fat component in the present invention. However, in consideration of health associated with ingestion, trans fats are not particularly contained. Alternatively, it is desirable to use a fat component of a low trans fatty acid.
特に本発明においては、脂肪成分の含有率を60重量%以下の範囲内とすることが望ましい。脂肪成分が60重量%を超えると、O/W型エマルジョンが転相するため、従来のクリーム類の代用として用いるには不適切となる。脂肪成分の含有率の下限値は0%を超える値とし、O/W型エマルジョンを形成する限り、適宜に設定することができる。
Particularly in the present invention, it is desirable that the content of the fat component is in the range of 60% by weight or less. If the fat component exceeds 60% by weight, the O / W emulsion is phase-inverted, making it unsuitable for use as a substitute for conventional creams. The lower limit of the content of the fat component is set to a value exceeding 0%, and can be appropriately set as long as an O / W emulsion is formed.
また、本発明のクリーム様乳化物には、前記脂肪成分と水と乳化剤とによる乳化状態を安定させる安定剤を更に含有させることができる。本発明において安定剤は、脂肪成分と水分とを乳化剤により乳化させた状態を安定させるものであり、例えば増粘多糖類、デンプン、カラギーナン、寒天、アルギン酸プロピレングリコールエステル、アラビアガムキサンタンガム等の乳化用安定剤として通常使用されるものを適宜に用いることができる。これらの他にも、本発明において安定剤には、ゼラチンやカゼイン(又はカゼインナトリウム)等の乳由来のタンパク質成分を含むものや、大豆タンパク質や小麦タンパク質等の植物由来のタンパク質成分を含むものも適用することができる。ただし、これらのタンパク質成分を含む安定剤は、本発明においてはあくまでもクリーム様乳化物の乳化状態を安定させる「安定剤」として使用するものである。また、安定剤としてのアラビアガムやキサンタンガム、ゼラチンやカゼイン(カゼインナトリウム)等、脂肪成分と水分とを乳化させる乳化剤としての作用を有するものについては、本発明においては、タンパク質成分を含まないものは乳化剤又は安定剤の何れとしても使用することができるが、タンパク質成分を含むものは安定剤としてのみ使用することができる。さらに、タンパク質成分を含む安定剤を使用する場合であっても、本発明のクリーム様乳化物がその安定剤に由来する味や香りを呈さない程度の使用量、例えば数%乃至1%程度、望ましくは1%未満に留めておくものとする。なお、上述した安定剤は、日本国において「食用安定剤」として使用が認められているものを例示したものであり、各国の国内法令等により使用の可否は異なるが、乳化状態を安定化する作用のある物質であれば本発明における「安定剤」に該当する。
In addition, the cream-like emulsion of the present invention may further contain a stabilizer that stabilizes the emulsified state of the fat component, water, and emulsifier. In the present invention, the stabilizer stabilizes the state in which the fat component and water are emulsified with an emulsifier. For example, thickening polysaccharides, starch, carrageenan, agar, propylene glycol alginate, gum arabic xanthan gum and the like What is normally used as a stabilizer can be used suitably. In addition to these, the stabilizer in the present invention includes those containing protein components derived from milk such as gelatin and casein (or sodium caseinate), and those containing plant-derived protein components such as soybean protein and wheat protein. Can be applied. However, the stabilizer containing these protein components is only used as a “stabilizer” for stabilizing the emulsified state of the cream-like emulsion in the present invention. In addition, in the present invention, those that do not contain a protein component, such as gum arabic, xanthan gum, gelatin, casein (sodium casein), and the like, which have an action as an emulsifier for emulsifying a fat component and moisture, Although it can be used as either an emulsifier or a stabilizer, those containing a protein component can be used only as a stabilizer. Further, even when a stabilizer containing a protein component is used, the amount of use such that the cream-like emulsion of the present invention does not exhibit a taste or aroma derived from the stabilizer, for example, about several% to 1%, Desirably, it should be kept below 1%. The stabilizers mentioned above are examples of those that are approved for use as “edible stabilizers” in Japan. Stabilization of the emulsified state is possible depending on national laws and regulations of each country. Any substance having an action corresponds to the “stabilizer” in the present invention.
本発明のクリーム様乳化物は、タンパク質成分やペプチド成分を全く含有させない状態で脂肪成分と水分と乳化剤により乳化させてクリーム状とした食品であり、従来のクリーム類と同様の乳化性能やホイッピング性能を有していることから、従来のクリーム類と同様の用途に供することができるものである。しかも、本発明は、タンパク質成分に由来する原材料の味や香りを有していないことから、特に他の食品素材の味や香りを引き立てたい場合や、牛乳や大豆等に特有の味や香りを料理に残したくない場合や、乳化した或いはホイップした味や風味だけが必要な場合など、食品の製造や調理の際に従来のクリーム類の代わりに使用するのに適している。
The cream-like emulsion of the present invention is a food product that is emulsified with a fat component, moisture, and an emulsifier without containing any protein component or peptide component, and has the same emulsification performance and whipping performance as conventional creams. Therefore, it can be used for the same use as conventional creams. In addition, since the present invention does not have the taste and scent of raw materials derived from protein components, it has a particular taste and scent for milk, soybeans, etc. It is suitable for use in place of conventional creams in the production and cooking of foods, such as when it is not desired to leave in cooking, or when only an emulsified or whipped taste or flavor is required.
本発明の実施形態は、脂肪成分として食用油脂、水、食品用乳化剤を混合したものを主要原料とし、これらを混合して乳化して得られるクリーム様乳化物である。このクリーム様乳化物には、乳化を安定させるために安定剤を加えることができ、またその他の食品添加物を用途に応じて適宜加えることができる。。
The embodiment of the present invention is a cream-like emulsion obtained by mixing and emulsifying a mixture of edible fats and oils, water, and food emulsifiers as fat components. To this cream-like emulsion, a stabilizer can be added to stabilize the emulsification, and other food additives can be appropriately added depending on the application. .
食用油脂には、バターオイルやラードやヘット等の動物性油脂、パーム核油、大豆硬化油、菜種油、コーン油、カカオバター等の各種の植物性油脂を、1種又は2種以上を混合して用いることができる。脂肪成分は、クリーム様乳化物の60重量%以下の値で必ず含まれていれば、適宜の量に調整することができる。
For edible oils and fats, one or more animal oils such as butter oil, lard and het, various vegetable oils such as palm kernel oil, soybean hardened oil, rapeseed oil, corn oil, cocoa butter are mixed. Can be used. The fat component can be adjusted to an appropriate amount as long as it is always contained at a value of 60% by weight or less of the cream-like emulsion.
乳化剤には、レシチン、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の通常使用される食品用乳化剤を1種又は2種以上混合して用いることができる。クリーム様乳化物中に占める乳化剤の割合は、脂肪成分と水との割合に応じてそれらを十分に乳化させるだけの適量とすればよい。
As the emulsifier, one or more kinds of commonly used food emulsifiers such as lecithin, sorbitan fatty acid ester, propylene glycol fatty acid ester, glycerin fatty acid ester and sucrose fatty acid ester can be used. The proportion of the emulsifier in the cream-like emulsion may be an appropriate amount sufficient to emulsify them according to the proportion of the fat component and water.
安定剤には、乳化を安定させることを目的として、増粘多糖類、デンプン、アルギン酸プロピレングリコールエステル、アラビアガム等の上述したような通常使用される食品用安定剤を1種又は2種以上混合して用いることができる。安定剤は、クリーム様乳化物の必須の成分ではないが、調整から使用までの時間や流通を考慮して、必要に応じて適量を添加すればよい。
For the purpose of stabilizing the emulsification, the stabilizer is a mixture of one or more commonly used food stabilizers such as thickening polysaccharides, starch, propylene glycol alginate, gum arabic and the like as described above. Can be used. The stabilizer is not an essential component of the cream-like emulsion, but an appropriate amount may be added as necessary in consideration of time from preparation to use and distribution.
そして、クリーム様乳化物に占める脂肪成分の割合が数%から20%程度と比較的低い場合は、あっさりとした風味となるので、コーヒークリームや調理用クリームの代用品として用いるのに適しており、30%以上と比較的高い場合は、コクのある風味となるので、調理用クリームの代用品として使用できるほか、泡立ててホイップドクリームの代用品として用いるのに適している。
And when the proportion of the fat component in the cream-like emulsion is relatively low, about several to 20%, it has a light flavor and is suitable for use as a substitute for coffee cream or cooking cream. When the content is relatively high, such as 30% or more, it has a rich flavor, so it can be used as a substitute for cream for cooking, and is suitable for use as a substitute for whipped cream.
なお、本発明は上述した実施形態に限定されるものではない。各成分の具体的な種類や割合についても上記実施形態に限られるものではなく、本発明の趣旨を逸脱しない範囲で種々変形が可能である。
Note that the present invention is not limited to the embodiment described above. The specific types and ratios of the respective components are not limited to the above embodiment, and various modifications can be made without departing from the spirit of the present invention.
本発明の実施例として、以下の通り、クリーム様乳化物を4種類調整し、また比較例として市販のクリーム類(生クリームを使用した「乳等を主要原料とする食品」)を用い、味評価試験、におい識別試験、オーバーラン試験を行った。なお、各実施例のクリーム様乳化物には、試料の調整から味評価試験とにおい識別試験までの間に数日の時間が必要であったため、安定剤を用いている。
As examples of the present invention, as follows, four types of cream-like emulsions were prepared, and as a comparative example, commercially available creams (“foods mainly made of milk and the like using fresh cream”) were used, An evaluation test, an odor discrimination test, and an overrun test were conducted. In addition, since the cream-like emulsion of each Example needed several days between preparation of a sample, a taste evaluation test, and an odor discrimination test, the stabilizer is used.
<実施例1(乳化物1)> 脂肪成分;バターオイル235g、水;238g、乳化剤;ソルビタン脂肪酸エステル(商品名「poem60」)1.5g,グリセリン脂肪酸エステル(商品名「poem81」)5g、安定剤;,オクテニルコハク酸エステル化澱粉(商品名「エマルスター」)20g,アルギン酸プロピレングリコールエステル(商品名「ダックロイド」)1g、脂肪分約47.0%(重量)
<Example 1 (Emulsion 1)> Fat component: 235 g of butter oil, water: 238 g, emulsifier: 1.5 g of sorbitan fatty acid ester (trade name “poem60”), 5 g of glycerin fatty acid ester (trade name “poem81”), stable Agent: octenyl succinic esterified starch (trade name “Emulstar”) 20 g, alginate propylene glycol ester (trade name “Duckroid”) 1 g, fat content about 47.0% (weight)
<実施例2(乳化物2)> 脂肪成分;パーム核油130g,大豆硬化油105g、水;234g、乳化剤;ソルビタン脂肪酸エステル(同上)1.5g,レシチン(大豆由来)4g,グリセリン脂肪酸エステル(同上)5g、安定剤;オクテニルコハク酸エステル化澱粉(同上)20g,アルギン酸プロピレングリコールエステル(同上)1g、脂肪分約47.0%(重量)
<Example 2 (Emulsion 2)> Fat component: 130 g of palm kernel oil, 105 g of soybean hardened oil, water; 234 g, emulsifier; 1.5 g of sorbitan fatty acid ester (same as above), 4 g of lecithin (derived from soybean), glycerin fatty acid ester ( Same as above) 5 g, Stabilizer; Octyl succinate esterified starch (same as above) 20 g, Alginate propylene glycol ester (same as above) 1 g, Fat content of about 47.0% (weight)
<実施例3(乳化物3)> 脂肪成分;パーム核油130g,大豆硬化油105g、水;238g、乳化剤;ソルビタン脂肪酸エステル(同上)1.5g,グリセリン脂肪酸エステル(同上)5g、安定剤;オクテニルコハク酸エステル化澱粉(同上)20g,アルギン酸プロピレングリコールエステル(同上)1g、脂肪分約47.0%(重量)
<Example 3 (Emulsion 3)> Fat component: 130 g of palm kernel oil, 105 g of soybean hardened oil, water; 238 g, emulsifier; 1.5 g of sorbitan fatty acid ester (same as above), 5 g of glycerin fatty acid ester (same as above), stabilizer; Octyl succinate esterified starch (same as above) 20 g, alginate propylene glycol ester (same as above) 1 g, fat content about 47.0% (weight)
<実施例4(乳化物4)> 脂肪成分;パーム核油130g,大豆硬化油105g、水;258g、乳化剤;ソルビタン脂肪酸エステル(同上)1.5g,グリセリン脂肪酸エステル(同上)5g、安定剤;アルギン酸プロピレングリコールエステル(同上)1g、脂肪分約47.0%(重量)
<Example 4 (Emulsion 4)> Fat component: 130 g of palm kernel oil, 105 g of soybean hardened oil, water; 258 g, emulsifier; 1.5 g of sorbitan fatty acid ester (same as above), 5 g of glycerin fatty acid ester (same as above), stabilizer; 1 g of propylene glycol alginate (same as above), fat content of about 47.0% (weight)
<比較例> 市販「乳等を主要原料とする食品」 原材料名;クリーム(乳製品、生クリーム使用)、乳化剤、安定剤(増粘多糖類)、その他の情報;乳脂肪分47.0%,無脂乳固形分4.0%
<Comparative example> Commercially available “food mainly made of milk” Raw material name: cream (dairy product, using fresh cream), emulsifier, stabilizer (thickening polysaccharide), other information; milk fat 47.0% , Non-fat milk solid content 4.0%
[味評価試験] 上記4種類の実施例と比較例を試料として、財団法人おいしさの科学研究所に依頼して、味認識装置を用いて評価を行った。試料の調整方法としては、各試料40gに対して(1)純水または(2)1%NaCl溶液160gを加え、重量比5倍に希釈した後、40℃の恒温槽で5分間攪拌しながら加温したものを遠心分離(3000rpm、10分間、20℃)と油相除去を2回繰り返して得られた水相部分を測定試料とした。測定方法としては、味認識装置SA402B(Insent社製)を用い、下記表1に示した項目について測定した。人間の唾液に近いほぼ無味の基準溶液(30mMのKClと0.3mMの酒石酸溶液の混合溶液)に対する味強度(絶対値)を室温(20℃)で測定し、その絶対値から比較例の味強度が0になるように換算した相対値を用いて、試料間の味の違いを評価した。なお、「味強度」とは、味認識装置の目盛りで示される値であり、ほとんどの人が違いを感じる値(濃度差で約1.2倍)を目安として「1」としている。そのため、味強度差「2」は濃度差約1.44倍、「4」は濃度差約2倍となる。表1中、「先味」は、食品を口に入れた直後の味覚を表し、「後味」は食品を飲み込んだ後に広がる味を表す。
[Taste Evaluation Test] Using the above four types of Examples and Comparative Examples as samples, we asked the Scientific Research Institute of Tastes to evaluate using a taste recognition device. Samples were prepared by adding (1) pure water or (2) 160% 1% NaCl solution to 40 g of each sample, diluting it to a weight ratio of 5 times, and stirring for 5 minutes in a constant temperature bath at 40 ° C. An aqueous phase portion obtained by repeating centrifugation (3000 rpm, 10 minutes, 20 ° C.) and oil phase removal twice for the heated one was used as a measurement sample. As a measurement method, the taste recognition device SA402B (manufactured by Insent) was used, and the items shown in Table 1 below were measured. The taste intensity (absolute value) of a reference solution (a mixture of 30 mM KCl and 0.3 mM tartaric acid solution) that is almost tasteless to human saliva was measured at room temperature (20 ° C.), and the taste of the comparative example was determined from the absolute value. Differences in taste between samples were evaluated using relative values converted so that the intensity was zero. The “taste intensity” is a value indicated by the scale of the taste recognition device, and a value (mostly 1.2 times the density difference) that most people feel a difference is set to “1”. Therefore, the taste intensity difference “2” is about 1.44 times the density difference, and “4” is about twice the density difference. In Table 1, “Taste” represents the taste immediately after the food is put in the mouth, and “Aftertaste” represents the taste that spreads after the food is swallowed.
下記表2に、各実施例及び比較例の味強度を、上述した基準溶液を0としたときの絶対値で示す。また同表の値をポイントしたレーダーグラフを図1に示す。(1)純水で希釈して測定した結果では、各試料とも、酸味と塩味が基準溶液に対しマイナスの値を示したが、これは試料間の味強度の差は大きいが、実際は人の味覚では感じない程度の低い濃度での差であり、試料間の味の比較として有効ではないと考えられる。このため、各試料の評価に有効な味強度は、先味の「苦味雑味」、「刺激渋味」、「旨味」、後味の「苦味」、「渋味」、「旨味コク」である。このうち、先味の「苦味雑味」、「刺激渋味」、「旨味」において試料間に大きな味強度差が認められたが、これらの値は塩味を用いて補正しているため、塩味の大きな味強度差を反映したと考えられる。そこで、(2)1%NaCl溶液で希釈し、試料間の塩濃度をほぼ同じにして測定を行い、塩味の差の影響を除いて味強度を測定した。その結果、塩味の味強度差は全試料間で1以内となり、「苦味雑味」、「刺激渋味」、「旨味」の味強度差は、(1)の場合と比較して小さくなった。
Table 2 below shows the taste intensity of each example and comparative example as an absolute value when the above-described reference solution is 0. A radar graph that points to the values in the table is shown in FIG. (1) As a result of measurement after dilution with pure water, each sample showed a negative value for sourness and saltiness relative to the reference solution. It is a difference at a low concentration that is not felt by the taste, and is considered not effective as a taste comparison between samples. For this reason, the taste intensity effective for the evaluation of each sample is “bitter taste miscellaneous taste”, “stimulated astringency”, “umami”, “bitter taste” of aftertaste, “astringency”, and “umami richness”. . Among these, there was a large difference in taste intensity between samples in the previous bitter taste, irritating astringency, and umami, but these values were corrected using saltiness, so the salty taste This is thought to reflect a large difference in taste intensity. Therefore, (2) the sample was diluted with a 1% NaCl solution and the salt concentration between the samples was approximately the same, and the taste intensity was measured by removing the influence of the difference in salty taste. As a result, the difference in salty taste intensity was within 1 among all samples, and the difference in taste intensity between “bitter taste miscellaneous taste”, “stimulated astringency”, and “umami taste” was smaller than in the case of (1). .
上記(2)の結果から、味強度の絶対値がマイナスの値を示した「酸味」と、味強度を揃えた「塩味」を除き、比較例に対する実施例の味の相対評価には、「苦味雑味」、「刺激渋味」、「旨味」、「苦味」、「渋味」、「旨味コク」を用いることとした。下記表3に、比較例の味強度を0とした場合における各実施例の味強度(相対値)を示す。また同表の値をポイントしたレーダーグラフを図2に示す。
From the results of (2) above, except for “acidity” in which the absolute value of the taste intensity showed a negative value and “salt taste” in which the taste intensity was uniformed, It was decided to use “bitter miscellaneous taste”, “stimulated astringency”, “umami”, “bitter taste”, “astringency”, and “umami richness”. Table 3 below shows the taste intensity (relative value) of each example when the taste intensity of the comparative example is 0. A radar graph that points to the values in the table is shown in FIG.
以上の結果から、各試料の「旨味」と「旨味コク」、「苦味雑味」と「渋味刺激」のバランスの状態を図3のマッピング図として示す。表3、図2及び図3に示されるように、実施例1、2、3のクリーム様乳化物は何れもよく似た味を示し、従来のクリーム類である比較例と比べて、先味の「苦味雑味」、「刺激渋味」が強く、後味の「旨味コク」が弱かった。また、各実施例は比較例よりも、先味の「旨味」、後味の「苦味」、「渋味」はわずかに強かったが、その際は1以内であった。また、実施例4のクリーム様乳化物は、他の全ての実施例及び比較例とは異なり、全ての味強度が弱い傾向を示した。味評価試験の結論としては、各実施例のクリーム様乳化物は、何れも比較例の生クリームを使用したクリーム類とは異なる味を示すと考えられる。
From the above results, the balance state of “umami”, “umami rich”, “bitter taste miscellaneous”, and “astringency stimulation” of each sample is shown as a mapping diagram in FIG. As shown in Table 3, FIG. 2 and FIG. 3, the cream-like emulsions of Examples 1, 2, and 3 all showed a similar taste, compared to the comparative examples that are conventional creams, “Bitter taste miscellaneous taste” and “stimulated astringency” were strong, and aftertaste “umami richness” was weak. In each example, the “umami” taste, the “bitter taste”, and the “astringency” aftertaste were slightly stronger than the comparative example, but were within 1 in that case. Moreover, the cream-like emulsion of Example 4 showed a tendency that all taste strengths were weak unlike all other Examples and Comparative Examples. As a conclusion of the taste evaluation test, it is considered that the cream-like emulsions of each example show different tastes from the creams using the fresh cream of the comparative example.
[におい識別試験] 上記4種類の実施例と比較例を試料として、財団法人日本食品分析センターに依頼して、におい識別装置を用いて評価を行った。試料の調整方法としては、各試料10gをポリエステル製サンプルバッグ(容量3L)に入れ、窒素ガスで袋内を置換し、それを室温に約3時間放置して試料ガスとした。測定機材として、におい識別装置FF-2A(株式会社島津製作所製)、サンプルバッグ用オートサンプラーFAS-1(同社製)、通常用の捕集管を用い、測定シーケンスをASmell条件、ガス吸引時間60秒として計測を行い、測定結果の解析は、におい識別装置に付属の解析ソフト(絶対値表現ソフトASmell2、同社製)を用いて、基準ガスに対する類似度、臭気寄与度及び臭気指数相当値を算出し、各実施例のにおいを比較例のにおいと比較した。
[Odor identification test] Using the above four types of examples and comparative examples as samples, we asked the Japan Food Analysis Center to make an evaluation using an odor identification apparatus. As a sample adjustment method, 10 g of each sample was placed in a polyester sample bag (capacity 3 L), the inside of the bag was replaced with nitrogen gas, and the sample was left at room temperature for about 3 hours to obtain a sample gas. As measurement equipment, an odor identification device FF-2A (manufactured by Shimadzu Corporation), a sample bag autosampler FAS-1 (manufactured by the same company), and a normal collection tube are used. The measurement sequence is ASmell condition, gas suction time 60 Measurement is performed in seconds, and the analysis of the measurement result is performed by calculating the similarity to the reference gas, the odor contribution, and the odor index equivalent value using the analysis software (absolute value expression software ASmell2, manufactured by the company) attached to the odor discriminator. The odor of each example was compared with that of the comparative example.
基準ガスに対する類似度の結果を表4及び図4に、臭気指数相当値の結果を表5及び図5に示す。なお、「類似度」とは、においの質がどの系統に近いかを示すものであり、仮にアルデヒド系の類似度が50%と算出された場合、試料中にアルデヒド類が50%含まれているという意味ではなく、アルデヒド系との類似度が50%であるという意味である。「臭気寄与値」とは、各系統のにおいの強さを臭気指数相当値で示した値である。「臭気指数」とは、悪臭防止法で規定された臭気強度の表示方法で、測定したにおいを段階的に希釈して、においが無くなったときの希釈倍率(臭気濃度)から、次式『臭気指数=10Xlog10(臭気濃度)』により算出した値である。「臭気指数相当値」とは、におい識別装置で測定した試料ガスのにおいの強さを、臭気指数に相当する値として数値化したものである。
The results of similarity to the reference gas are shown in Table 4 and FIG. 4, and the results of odor index equivalent values are shown in Table 5 and FIG. The “similarity” indicates which line the odor quality is close to. If the aldehyde similarity is calculated as 50%, the sample contains 50% aldehydes. This means that the degree of similarity with the aldehyde system is 50%. The “odor contribution value” is a value indicating the odor intensity of each system as an odor index equivalent value. “Odor index” is a display method of odor intensity stipulated by the Odor Prevention Law, and the following formula is used to calculate the odor from the dilution factor (odor concentration) when the measured odor is diluted stepwise and the odor disappears. Index = 10Xlog 10 (odor concentration) ". The “odor index equivalent value” is obtained by quantifying the odor intensity of the sample gas measured by the odor identification device as a value corresponding to the odor index.
本試験で使用した解析ソフトによれば、においの強さは臭気指数相当値の差が3あれば、また、においの質は基準ガスに対する類似度で10%の差がある系統があれば、人間の嗅覚で認識できる程度の差がある、とされている。本試験では、臭気指数相当値は4つの実施例でほぼ同じ値を示し、比較例と比べた場合、嗅覚で認識できる程度の差は認められなかった。しかしながら、基準ガスとの類似度について比較例と比べた場合は、実施例1と実施例3は、硫化水素、硫黄系、アンモニア、及びアルデヒド系で10%以上の差が認められ、実施例2は、硫化水素、硫黄系、アンモニア、アルデヒド系、及び炭化水素系で10%以上の差が認められ、実施例4は、芳香族系以外の全ての系統で10%以上の差が認められた。以上の結果から、各実施例のクリーム様乳化物は、比較例である従来のクリーム類とは、においの強さについては差がないが、においの質が異なると判断できる。
According to the analysis software used in this test, if there is a difference in the odor intensity corresponding to the odor index value of 3, and if there is a system where the odor quality is similar to the reference gas and there is a difference of 10%, It is said that there is a difference that can be recognized by human sense of smell. In this test, the odor index equivalent values showed almost the same values in the four examples, and when compared with the comparative examples, there was no difference that was recognized by the sense of smell. However, when compared with the comparative example with respect to the similarity to the reference gas, Example 1 and Example 3 showed a difference of 10% or more in hydrogen sulfide, sulfur-based, ammonia, and aldehyde-based, and Example 2 A difference of 10% or more was recognized in hydrogen sulfide, sulfur, ammonia, aldehyde, and hydrocarbon, and Example 4 showed a difference of 10% or more in all systems other than aromatic. . From the above results, it can be judged that the cream-like emulsions of the respective examples are different from the conventional creams as comparative examples in the odor strength, but the odor quality is different.
[オーバーラン試験] クリーム類を泡立てると、適度な堅さを持ったホイップができるが、その際に抱き込まれる空気の量を指標としてオーバーラン値が用いられ、ホイップ時のクリーム類の保形性が表される。オーバーランは、次式{(ホイップ後の重量-ホイップ前の重量)/ホイップ前の重量}X100(%)で求められる。各実施形態のクリーム様乳化物と比較例のクリーム類とを同一条件にて泡立てたところ、全て100%から120%程度のオーバーラン値が得られたことから、各実施例のクリーム様乳化物はホイップしても従来のクリーム類と同様に使用することができることが判明した。
[Overrun test] Whilst cream can be whipped with moderate firmness, but the overrun value is used as an index of the amount of air entrapped at that time, and the shape of the cream during whipping Sex is expressed. The overrun is obtained by the following formula {(weight after whipping−weight before whipping) / weight before whipping} X100 (%). When the cream-like emulsion of each embodiment and the cream of the comparative example were foamed under the same conditions, an overrun value of about 100% to 120% was obtained, and thus the cream-like emulsion of each example It was found that can be used in the same way as conventional creams even if whipped.
[官能試験] 上記実施例のうち、実施例4(乳化物4)のクリーム様乳化物を用いて下記の各種の料理を調理し、それらを実食しての官能試験を行った。本試験にあたっては、各料理につき実施例4のクリーム様乳化物を用いたものと比較対象を合計2種類以上作り、どれが実施例を用いたものか分からない状態として8人の成人による試食を行い、各人がそれぞれについて感想を記載する形式で行った。以下、各料理の簡単なレシピと感想の総括について記載する。
[Sensory test] Among the above examples, the following various dishes were cooked using the cream-like emulsion of Example 4 (emulsion 4), and the sensory test was performed after eating them. In this test, for each dish, make a total of two or more comparison objects using the cream-like emulsion of Example 4, and sample it by eight adults in a state where they do not know which one used the example. We performed in the form that each person described impression about each. The following is a summary of simple recipes and impressions for each dish.
<1.ガナッシュチョコ> ビターチョコレート50gと実施例4のクリーム様乳化物又は生クリーム100gを用い、ガナッシュチョコを調理した。Aはビターチョコレートと生クリーム、Bはビターチョコレートと実施例4のクリーム様乳化物である。感想;Aはミルクチョコレートの味になり、生クリームのコクが感じられた。Bはビターチョコレートの特徴の苦味と酸味が強く感じられあっさりとしている。元のチョコレートの味の特徴が残されている。
<1. Ganache Chocolate> Ganache chocolate was cooked using 50 g of bitter chocolate and 100 g of the cream-like emulsion of Example 4 or fresh cream. A is bitter chocolate and fresh cream, B is bitter chocolate and the cream-like emulsion of Example 4. Impressions: A became the taste of milk chocolate and the richness of fresh cream was felt. B has a bitter and sour taste that is characteristic of bitter chocolate. The original chocolate flavor remains.
<2.イチゴムース> イチゴピューレ50gと実施例4のクリーム様乳化物又は生クリームでイチゴムースを調理した。Aはイチゴピューレと生クリーム、Bはイチゴピューレと実施例4のクリーム様乳化物である。感想;Aはイチゴミルクの味になり、甘さと生クリームのコクが感じられたが、イチゴの味が薄かった。Bはイチゴの香りと酸味が感じられ、ミルクらしさがなくあっさりとしている。
<2. Strawberry mousse> Strawberry mousse was cooked with 50 g of strawberry puree and the cream-like emulsion of Example 4 or fresh cream. A is strawberry puree and fresh cream, B is strawberry puree and the cream-like emulsion of Example 4. Impression: A became the taste of strawberry milk, and the richness of sweetness and cream was felt, but the taste of strawberry was weak. B has a strawberry scent and acidity, and it is not milky and light.
<3.パスタソース> トマトソース100g、オリーブオイル20g、実施例4のクリーム様乳化物又は生クリーム又は水でパスタソースを調理した。Aはトマトソースとオリーブオイルと水、Bはトマトソースとオリーブオイルと実施例4のクリーム様乳化物、Cはトマトソースとオリーブオイルと生クリームである。感想;Aはオリーブオイルが表面に浮き完全に分離しており、トマトの酸味が感じられるが油っぽさも感じられる。Bは少しピンクがかった赤色になり油は浮いておらず、完全に乳化している。マイルドな味でコクがある。Cは白っぽいピンクになり油は浮いておらず乳化している。マイルドな味になりコクがあるがクリームの味がする。
<3. Pasta sauce> Pasta sauce was cooked with tomato sauce 100 g, olive oil 20 g, the cream-like emulsion of Example 4 or fresh cream or water. A is tomato sauce, olive oil and water, B is tomato sauce, olive oil and the cream-like emulsion of Example 4, and C is tomato sauce, olive oil and fresh cream. Impression: A has olive oil floating on the surface and completely separated, sour taste of tomato is felt, but also oily. B is a little pinkish red and oil is not floating, and is completely emulsified. It has a mild taste and richness. C becomes whitish pink and the oil is not floating and is emulsified. It has a mild taste and a rich taste, but has a creamy taste.
<4.天ぷらの衣> 薄力粉100ccと実施例4のクリーム様乳化物又は水100ccで天ぷらの衣を作り、180℃の油で海老に衣を付け揚げて10分間常温で放置したものを試食した。Aは薄力粉と水、Bは薄力粉と実施例4のクリーム様乳化物である。感想;Aは衣が柔らかくふわふわと水っぽく、また少し油っぽく、湿気っている。Bは衣がさくさくとして食感が良く、油っぽさもなく湿気ってもいない。
<4. Tempura Cloth> Tempura garments were made with 100 cc of weak flour and the cream-like emulsion of Example 4 or 100 cc of water, and the lobster was fried with 180 ° C. oil and allowed to stand at room temperature for 10 minutes. A is a flour and water, B is a flour and the cream-like emulsion of Example 4. Impression: A is soft, fluffy and watery, and a little oily and damp. B is crisp and has a good texture and is neither oily nor damp.
<5.ポタージュ>カボチャのピュレ100g及び水50gを実施例4のクリーム様乳化物又は生クリーム又はミルク又は水50gと混ぜ合わせ、ポタージュスープを調理した。Aはピュレ及び水と水、Bはピュレ及び水とミルク、Cはピュレ及び水と生クリーム、Dはピュレと水と実施例4のクリーム様乳化物である。感想;Aはカボチャそのものの味であるが、青臭さと水っぽさが感じられる。Bはカボチャの味が薄まり、さらりとしていて水っぽく、ミルクの味が感じられる。Cはまろやかでコクもあるが、カボチャの味がせず重く感じられる。Dはアッサリとしているがカボチャの味が残りコクもある。
<5. Potage> 100 g of pumpkin puree and 50 g of water were mixed with the cream-like emulsion of Example 4 or fresh cream or milk or 50 g of water to prepare a potage soup. A is puree and water and water, B is puree and water and milk, C is puree and water and fresh cream, D is puree and water and the cream-like emulsion of Example 4. Impression: A is the taste of the pumpkin itself, but it feels blue and watery. B loses its pumpkin taste, it is light and watery, and the taste of milk is felt. C is mellow and rich, but it feels heavy without the taste of pumpkin. D is assassic, but the taste of the pumpkin remains and there is also a richness.
以上の結果から、本発明の一実施例(実施例4)のクリーム様乳化物を材料として料理をした場合、他のメインとなる材料の味が引き立てたれることが分かった。特に<1><2>からは、本実施例のクリーム様乳化物を生クリームの代用品として使用した場合、物性はそのままで他の素材の風味の特徴を生かせることができる、といえる。<3>からは、本実施例のクリーム様乳化物の乳化特性を活かし、ソースと油脂を容易に乳化させることができ、料理にコクを与えることができた。また、クリーム様乳化物は生クリームのようにトマトソースの個性をこわすこともなかった。<4>からは、クリーム様乳化物を天ぷらやフリッターの衣に使用すると、サクサクとしたクリスピーな仕上がりとなり、湿気にくくカラリとした揚げ物ができる、といえる。<5>からは、クリーム様乳化物は、水、ミルクよりもスープにコクを与え、生クリームよりも他の素材の個性を際立てることができる、といえる。よって、上記実施例4に限らず、他の実施例も含めて本発明のクリーム様乳化物は、生クリームやその他のクリーム類の代用品としても、従来のクリーム類よりも他の素材の味をより引き立てることができるクリーム類の代用品として使用することができ、また新しい可能性を持った食品素材として様々な食品に使用することができるものである。
From the above results, it was found that when cooking using the cream-like emulsion of one example (Example 4) of the present invention as a material, the taste of other main ingredients was enhanced. In particular, from <1> and <2>, when the cream-like emulsion of this example is used as a substitute for fresh cream, it can be said that the flavor characteristics of other materials can be utilized without changing the physical properties. From <3>, the emulsification characteristics of the cream-like emulsion of this example were utilized, the sauce and fats and oils could be easily emulsified, and the food could be rich. Moreover, the cream-like emulsion did not break the individuality of tomato sauce like fresh cream. From <4>, it can be said that when a cream-like emulsion is used for tempura and fritter clothes, it becomes a crispy and crispy finish, and a fried food that is moisture-proof and crisp can be made. From <5>, it can be said that the cream-like emulsion gives more richness to the soup than water and milk, and can stand out the individuality of other materials than fresh cream. Therefore, the cream-like emulsion of the present invention is not limited to the above-mentioned Example 4 but also includes other examples. The cream-like emulsion of the present invention can be used as a substitute for fresh creams and other creams. It can be used as a substitute for creams that can enhance the taste of food, and can be used for various foods as a food material with new possibilities.
本発明のクリーム様乳化物は、従来のクリーム類の代用品として用いることができ、食品の製造、調味剤や食品用添加物の製造、調理等に適用することが可能である。
The cream-like emulsion of the present invention can be used as a substitute for conventional creams, and can be applied to the production of food, the production of seasonings and food additives, cooking, and the like.
Claims (4)
- 脂肪成分と、水分と、乳化作用のあるタンパク質又はペプチドを含有しない乳化剤とを含有し、これら脂肪成分と水分と乳化剤とにより乳化させたことを特徴とするクリーム様乳化物。 A cream-like emulsion comprising a fat component, moisture, and an emulsifier not containing an emulsifying protein or peptide, and emulsified with the fat component, moisture and an emulsifier.
- 前記脂肪成分は、動物性脂肪、又は植物性脂肪、又は動物性脂肪と植物性脂肪の混合物、又は加工油脂の何れかである請求項1に記載のクリーム様乳化物。 The cream-like emulsion according to claim 1, wherein the fat component is any of animal fat, vegetable fat, a mixture of animal fat and vegetable fat, or processed oil.
- 前記脂肪成分を、60重量%以下の範囲内で含有する請求項1又は2の何れかに記載のクリーム様乳化物。 The cream-like emulsion in any one of Claim 1 or 2 which contains the said fat component within the range of 60 weight% or less.
- 前記脂肪成分と水と乳化剤とによる乳化状態を安定させる安定剤を更に含有する請求項1乃至3の何れかに記載のクリーム様乳化物。 The cream-like emulsion according to any one of claims 1 to 3, further comprising a stabilizer that stabilizes an emulsified state of the fat component, water, and an emulsifier.
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CN103384476A (en) * | 2011-02-11 | 2013-11-06 | 焙乐道有限责任公司 | An emulsion whippable at room-temperature |
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WO2003026441A1 (en) * | 2001-09-26 | 2003-04-03 | Fuji Oil Company, Limited | Foaming oil-in-water type emulsions and process for producing the same |
JP2003253291A (en) * | 2002-02-28 | 2003-09-10 | Snow Brand Milk Prod Co Ltd | Method for stabilizing oil-in-water emulsion |
JP2004016187A (en) * | 2002-06-20 | 2004-01-22 | Miyoshi Oil & Fat Co Ltd | Food-foaming agent composition and method for producing the same |
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CN103384476A (en) * | 2011-02-11 | 2013-11-06 | 焙乐道有限责任公司 | An emulsion whippable at room-temperature |
JP2014504885A (en) * | 2011-02-11 | 2014-02-27 | プラトス・エン・フェー | Emulsions that can be whipped at room temperature |
JP2015130877A (en) * | 2011-02-11 | 2015-07-23 | プラトス・エン・フェー | Emulsion capable of being whipped at room temperature |
CN103384476B (en) * | 2011-02-11 | 2016-03-23 | 焙乐道有限责任公司 | The emulsion at room temperature can beaten |
US9648895B2 (en) | 2011-02-11 | 2017-05-16 | Puratos N.V. | Emulsion whippable at room-temperature |
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