WO2009081574A1 - Mobile terminal part - Google Patents
Mobile terminal part Download PDFInfo
- Publication number
- WO2009081574A1 WO2009081574A1 PCT/JP2008/003909 JP2008003909W WO2009081574A1 WO 2009081574 A1 WO2009081574 A1 WO 2009081574A1 JP 2008003909 W JP2008003909 W JP 2008003909W WO 2009081574 A1 WO2009081574 A1 WO 2009081574A1
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- WO
- WIPO (PCT)
- Prior art keywords
- polybutylene terephthalate
- portable terminal
- acid
- resin
- terminal component
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K5/00—Casings, cabinets or drawers for electric apparatus
- H05K5/02—Details
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/0202—Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
Definitions
- the present invention relates to a portable terminal component molded from a specific polybutylene terephthalate resin composition. More specifically, the present invention relates to a portable terminal component using a polybutylene terephthalate resin composition excellent in physical properties such as mechanical strength and impact strength, and moldability such as low sink and low warp deformation.
- Background art a polybutylene terephthalate resin composition excellent in physical properties such as mechanical strength and impact strength, and moldability such as low sink and low warp deformation.
- plastic materials are generally molded by methods such as compression molding, injection molding, injection-compression molding, blow molding, etc. Among them, the injection molding method is excellent in mass production, and therefore, the cost can be reduced. Therefore, it is a molding technique most often used as a casing molding method for electronic devices.
- portable terminals include polycarbonate (PC) resin, acrylonitrile-butadiene-styrene copolymer (ABS) resin, plastic material alone such as blend material of ABS resin and polycarbonate resin or polybutylene terephthalate (PBT) resin, or carbon fiber.
- PC polycarbonate
- ABS acrylonitrile-butadiene-styrene copolymer
- PBT polybutylene terephthalate
- JP-A-6-240132 a reinforced resin material using a blend material of aromatic polyamide resin and modified polyphenylene resin
- Japanese Patent Application Laid-Open No. 62-268612 discloses a polybutylene terephthalate resin composition having excellent mechanical strength by using non-circular cross-section fibers having a longitudinal cross section as glass fibers.
- ordinary polybutylene terephthalate resin has a problem of large shrinkage that occurs during the solidification process during molding such as injection molding, resulting in a large amount of sink of the molded product and large warpage due to shrinkage anisotropy. It was. It has been considered difficult to apply to molded products that require high strength, high rigidity, high impact, sink marks and warp deformation of molded products at the same time as portable terminal components. Disclosure of the invention
- An object of the present invention is to provide a portable terminal component comprising a polybutylene terephthalate resin composition having excellent physical properties such as mechanical strength and impact strength, and having excellent low sink and low warpage deformation.
- the present inventors have achieved the above object by molding a resin composition in which a specific modified polybutylene terephthalate resin and a glass fiber having a flat cross-sectional shape are combined. It has been found that portable terminal parts that can be achieved are obtained, and the present invention has been completed. That is, the present invention (A) For 100 parts by weight of the modified polybutylene terephthalate resin, (B) A mobile terminal component made of a polybutylene terephthalate resin composition containing 40 to 140 parts by weight of glass fibers having a flat cross-sectional shape. This invention is a portable terminal component use of the said composition.
- a mobile terminal part made of the polybutylene terephthalate resin composition of the present invention has a high lightening effect and is resistant to breakage because it is resistant to rigidity and impact. Moreover, since the post-processing process is excellent because of excellent moldability, the manufacturing cost can be reduced.
- the present invention is suitable for a casing (housing), a reinforcing plate (chassis), a frame, a hinge, or a peripheral related component of a portable terminal component.
- the (A) modified polybutylene terephthalate resin used in the present invention is (1) polybutylene terephthalate obtained by polycondensation reaction of terephthalic acid or its ester-forming derivative and 1,4 -butanediol or its ester-forming derivative.
- Terephthalate resin, (1) it may be a combination of combined isophthalic acid modified polybutylene terephthalate, the three isophthalic acid modified polyethylene terephthalate and polybutylene terephthalate (2).
- isophthalic acid can be used for polycondensation in the form of an ester-forming derivative, for example, a lower alcohol ester such as dimethyl ester, and can be introduced as a copolymer component.
- ester-forming derivative for example, a lower alcohol ester such as dimethyl ester
- the introduction amount of the isophthalic acid comonomer unit is 5 to 30 mol%, preferably 10 to 30 mol%, particularly preferably 10 to 20 mol%. If the amount introduced is less than 5 mol%, the crystallinity is high, so that the anisotropy of molding shrinkage increases and warpage deformation increases. Further, when the introduction amount exceeds 30 mol%, the strength and thermal stability, which are the advantages of the original polybutylene terephthalate, are greatly reduced, and the crystallization is remarkably reduced and delayed, thereby reducing the molding cycle. There is a possibility that the mold releasability is lowered and a problem that is not practically used is caused.
- either an isophthalic acid modified copolymer alone or a combination of an isophthalic acid modified copolymer and polybutylene terephthalate containing no isophthalic acid component can be used.
- the proportion of polybutylene terephthalate is less than 50% by weight.
- isophthalic acid-modified polyethylene terephthalate and polybutylene terephthalate are used in combination.
- the proportion of isophthalic acid-modified polyethylene terephthalate is preferably 10 to 60% by weight.
- the warp deformation suppressing effect is insufficient, and if it exceeds 60% by weight, the moldability as polybutylene terephthalate is impaired, and molding may not be possible at a mold temperature of 100 ° C. or less.
- the modified polybutylene terephthalate resin is used as a copolymer copolymerized with a copolymerizable monomer (hereinafter sometimes referred to simply as a copolymerizable monomer) within a range not impairing the effects of the present invention.
- a copolymerizable monomer hereinafter sometimes referred to simply as a copolymerizable monomer
- Examples of the copolymerizable monomer include dicarboxylic acid components excluding terephthalic acid and isophthalic acid, diols other than alkylene glycol having 2 to 4 carbon atoms, oxycarboxylic acid components, and lactone components.
- a copolymerizable monomer can be used 1 type or in combination of 2 or more types.
- Dicarboxylic acids include aliphatic dicarboxylic acids (for example, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedicarboxylic acid, dodecanedicarboxylic acid, hexadecandioyl carboxylic acid, C 4 ⁇ 40 dicarboxylic acids such as dimer acid, preferably C 4 ⁇ 14 dicarboxylic acids), alicyclic dicarboxylic acid component (e.g., hexahydrophthalic acid, hexahydroisophthalic acid, hexahydroterephthalic acid, hymic C 8 ⁇ 12 dicarboxylic acid), terephthalic acid such as an acid, an aromatic dicarboxylic acid component other than isophthalic acid (e.g., phthalic acid, naphthalene
- aliphatic dicarboxylic acids for example, succ
- polyvalent carboxylic acid such as trimellitic acid and pyromellitic acid, or its ester formation derivative (alcohol ester etc.) etc. as needed.
- a polyfunctional compound such as trimellitic acid and pyromellitic acid, or its ester formation derivative (alcohol ester etc.) etc.
- a branched polybutylene terephthalate resin can also be obtained.
- Diols include, for example, aliphatic alkanediols excluding 1,4-butanediol [eg, alkanediols (eg, ethylene glycol, trimethylene glycol, propylene glycol, neopentyl glycol, hexanediol ( 1,6-hexanediol), octanediol (1,3-octanediol, 1,8-octanediol, etc.), lower alkane diols, such as decanediol, preferably a straight chain or branched chain C 2 ⁇ 12 alkane Diols, more preferably linear or branched C 2-10 alkane diols); (poly) oxyalkylene glycols (eg glycols having a plurality of oxy C 2-4 alkylene units, eg diethylene glycol, diprop
- a polyol such as glycerin, trimethylolpropane, trimethylolethane, pentaerythritol, or an ester-forming derivative thereof may be used in combination.
- a polyfunctional compound such as glycerin, trimethylolpropane, trimethylolethane, pentaerythritol, or an ester-forming derivative thereof may be used in combination.
- a branched polybutylene terephthalate resin can also be obtained.
- the proportion of the copolymerizable monomer can be selected from the range of, for example, about 0.01 to 30 mol%, and is usually 1 to 30 mol%, preferably 3 to 25 mol%, more preferably 5 to 5 mol%. It is about 20 mol% (for example, 5 to 15 mol%).
- the proportion of the homopolyester and the copolyester is such that the proportion of the copolymerizable monomer is relative to the total monomers.
- the range is about 0.1 to 30 mol% (preferably 1 to 25 mol%, more preferably 5 to 25 mol%).
- the former / the latter 99/1 to 1/99 (weight ratio), preferably It can be selected from the range of 95/5 to 5/95 (weight ratio), more preferably about 90/10 to 10/90 (weight ratio).
- modified polyethylene terephthalate resin can also be used as a copolymer copolymerized with a copolymerizable monomer other than isophthalic acid within a range not impairing the effects of the present invention.
- the intrinsic viscosity (IV) of the (A) modified polybutylene terephthalate resin is preferably 1.2 dL / g or less, and more preferably 1.0 dL / g or less.
- the intrinsic viscosity (IV) can be measured, for example, in O-chlorophenol at a temperature of 35 ° C.
- the glass fiber having a flat cross-sectional shape used in the present invention is a long diameter (longest linear distance in the cross section) and a short diameter (longest straight distance in the direction perpendicular to the long diameter).
- the glass fiber has a ratio of 1.3 to 10, preferably 1.5 to 8, particularly preferably 2 to 5.
- Specific shapes include a substantially oval shape, a substantially oval shape, a substantially eyebrow shape, and the like.
- (B) Glass fiber having a flat cross-sectional shape is excellent in mechanical strength and impact strength, suppresses warpage deformation, and is excellent in moldability.
- the glass fiber having a flat cross-sectional shape preferably has an average cross-sectional area of 100 to 300 square micrometers. If it is smaller than 100 square micrometers, the mechanical strength and impact strength are not sufficient, and if it exceeds 300 square micrometers, problems such as gate clogging during injection molding and wear of molds and molding machines occur.
- the blending amount of the glass fiber (B) having a flat cross-sectional shape used in the present invention is 40 to 140 parts by weight, preferably 50 to 130 parts by weight with respect to 100 parts by weight of (A) the modified polybutylene terephthalate resin. .
- the blending amount is less than 40 parts by weight, the mechanical strength and impact strength are low, and when it exceeds 140 parts by weight, the fluidity is remarkably deteriorated.
- Such glass fiber (B) can be used regardless of the glass fiber form at the time of blending A glass, E glass, an alkali-resistant glass composition containing a zirconia component, chopped strands, roving glass, or the like.
- the glass fiber having a flat cross-sectional shape used in the present invention uses a nozzle having an appropriate hole shape such as an oval, an ellipse, a rectangle, or a slit as a bushing used for discharging molten glass.
- a nozzle having an appropriate hole shape such as an oval, an ellipse, a rectangle, or a slit as a bushing used for discharging molten glass.
- Prepared by spinning Also prepared by spinning molten glass from a plurality of adjacent nozzles having various cross-sectional shapes (including circular cross-sections), and joining the spun molten glass into a single filament it can.
- resin materials may be colored.
- an inorganic white pigment As the inorganic white pigment optimal for the resin composition of the present invention, (C) inorganic white pigment having a Mohs hardness of 4.5 or less, such as zinc sulfide, zinc oxide, barium sulfate, lithopone, magnesium carbonate, muscovite, calcium sulfate, barite , Calcium carbonate and the like. With these white pigments, good physical properties can be obtained because glass fiber breakage is small.
- rutile-type titanium oxide, anatase-type titanium oxide, brookite-type titanium oxide and the like having a Mohs hardness exceeding 4.5 are not preferable because many glass fiber breaks may occur.
- the blending amount of the inorganic white pigment is not particularly limited as long as it is a general coloring requirement amount.
- the resin composition of the present invention may contain other resins as needed within a range not impairing the effects of the present invention.
- Other resins include polyester resins other than polybutylene terephthalate resins (polyethylene terephthalate, polytrimethylene terephthalate, etc.), polyolefin resins, polystyrene resins, polyamide resins, polyacetals, polyarylene oxides, polyarylene sulfides, fluorine resins, etc. Is exemplified.
- copolymers such as acrylonitrile-styrene resin, acrylonitrile-butadiene-styrene resin, and ethylene-ethyl acrylate resin are also exemplified. These other resins may be used alone or in combination of two or more.
- additives may be added to the resin composition of the present invention.
- additives include various stabilizers (antioxidants, ultraviolet absorbers, heat stabilizers, etc.), nucleating agents (crystallization nucleating agents), flame retardants, lubricants, mold release agents, antistatic agents, dyes / pigments, etc. Colorants, dispersions, and the like.
- a phosphorus-based stabilizer to suppress transesterification.
- examples of the phosphorus stabilizer used include organic phosphite compounds, phosphonite compounds, and metal phosphates.
- Specific examples include bis (2,4-di-t-4methylphenyl) pentaerythritol diphosphite, bis (2,4-di-t-butylphenyl) pentaerythritol diphosphite, tetrakis (2,4 Examples of the -di-t-butylphenyl) -4,4'-biphenylene phosphonite and metal phosphate include monobasic calcium phosphate, monobasic sodium phosphate hydrate, and the like.
- reinforcing fillers can be added to the resin composition of the present invention as needed within a range not impairing the effects of the present invention.
- Other reinforcing fillers include glass fibers other than those specified in the present invention, milled glass fibers, glass beads, glass flakes, silica, alumina fibers, zirconia fibers, potassium titanate fibers, carbon fibers, graphite, calcium silicate, Silicates such as aluminum silicate, kaolin, talc and clay, metal oxides such as iron oxide, titanium oxide, zinc oxide, antimony oxide and alumina, carbonates and sulfates of metals such as calcium, magnesium and zinc, and carbonization
- the organic filler include silicon polyester, silicon nitride, boron nitride and the like, and examples of the organic filler include high melting point aromatic polyester fiber, liquid crystalline polyester fiber, aromatic polyamide fiber, fluororesin fiber, and polyimide fiber.
- the composition of the present invention is easily prepared by equipment and methods generally used as conventional resin composition preparation methods. For example, after mixing each component, kneading and extruding with a single-screw or twin-screw extruder to prepare pellets, then forming the pellets, once preparing pellets with different compositions, mixing the pellets in a predetermined amount Any method can be used, such as a method of obtaining a molded product having a desired composition after molding and a method of directly charging one or more of each component into a molding machine. Further, mixing a part of the resin component as a fine powder with other components and adding it is a preferable method for uniformly blending these components. Injection molding, extrusion molding, compression molding, blow molding, vacuum molding, rotational molding, gas injection molding, etc. can be applied as a molding method for filling the resin into the mold, but injection molding is common. .
- FIG. 1 is a diagram showing a cellular phone housing molded in the example and its evaluation status.
- Molding machine Sumitomo Heavy Industries SE100D Cylinder temperature: 270-270-260-230 °C Mold temperature: 100 °C (4-1) Bending strength of hinge portion of mobile phone housing The bending strength was measured by pushing and bending the hinge portion of FIG.
- Measuring instrument Universal testing machine Tensilon UTA50KN (Orientec) Measurement speed: 1000mm / min (4-2) Sink on the boss part of the mobile phone housing Sink condition on the surface of the boss part in FIG. 1 was visually observed. Judgment ⁇ ... Low sink ⁇ ⁇ High sink (4-3) Burning of mobile phone housing (compression heat generated by gas) The burn condition at the flow end of the hinge part in FIG. 1 was visually observed. Judgment ⁇ ... less burnt ⁇ ... more burnt
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Abstract
Description
背景技術 The present invention relates to a portable terminal component molded from a specific polybutylene terephthalate resin composition. More specifically, the present invention relates to a portable terminal component using a polybutylene terephthalate resin composition excellent in physical properties such as mechanical strength and impact strength, and moldability such as low sink and low warp deformation.
Background art
発明の開示 On the other hand, Japanese Patent Application Laid-Open No. 62-268612 discloses a polybutylene terephthalate resin composition having excellent mechanical strength by using non-circular cross-section fibers having a longitudinal cross section as glass fibers. However, ordinary polybutylene terephthalate resin has a problem of large shrinkage that occurs during the solidification process during molding such as injection molding, resulting in a large amount of sink of the molded product and large warpage due to shrinkage anisotropy. It was. It has been considered difficult to apply to molded products that require high strength, high rigidity, high impact, sink marks and warp deformation of molded products at the same time as portable terminal components.
Disclosure of the invention
即ち、本発明は
(A)変性ポリブチレンテレフタレート樹脂100重量部に対して、
(B)扁平な断面形状を有するガラス繊維40~140重量部
を配合してなるポリブチレンテレフタレート樹脂組成物からなる携帯端末部品である。
本発明は上記組成物の携帯端末部品用途である。 As a result of intensive studies to solve the above problems, the present inventors have achieved the above object by molding a resin composition in which a specific modified polybutylene terephthalate resin and a glass fiber having a flat cross-sectional shape are combined. It has been found that portable terminal parts that can be achieved are obtained, and the present invention has been completed.
That is, the present invention
(A) For 100 parts by weight of the modified polybutylene terephthalate resin,
(B) A mobile terminal component made of a polybutylene terephthalate resin composition containing 40 to 140 parts by weight of glass fibers having a flat cross-sectional shape.
This invention is a portable terminal component use of the said composition.
発明の詳細な説明 A mobile terminal part made of the polybutylene terephthalate resin composition of the present invention has a high lightening effect and is resistant to breakage because it is resistant to rigidity and impact. Moreover, since the post-processing process is excellent because of excellent moldability, the manufacturing cost can be reduced. The present invention is suitable for a casing (housing), a reinforcing plate (chassis), a frame, a hinge, or a peripheral related component of a portable terminal component.
Detailed Description of the Invention
実施例1~8、比較例1~7
各樹脂組成物を表1に示す混合比率でドライブレンドし、30mmφのスクリューを有する2軸押出機((株)日本製鋼製)を用いて、シリンダー設定温度250℃で溶融混練したのちペレット化し、試験片を作成し、各評価を行った。結果を表1に示す。 Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto.
Examples 1-8, Comparative Examples 1-7
Each resin composition was dry blended at the mixing ratio shown in Table 1, and melt-kneaded at a cylinder set temperature of 250 ° C. using a twin-screw extruder (manufactured by Nippon Steel Co., Ltd.) having a 30 mmφ screw. Test pieces were prepared and evaluated. The results are shown in Table 1.
(1)使用成分
(A)成分
(A-1)イソフタル酸変性ポリブチレンテレフタレート(固有粘度IV=0.65dL/g)
テレフタル酸と1,4 -ブタンジオールとの反応において、テレフタル酸の一部(12.5モル%)に代えて、共重合成分としてのジメチルイソフタル酸12.5モル%を用いた変性ポリブチレンテレフタレート
(A-2)ポリブチレンテレフタレート(固有粘度IV=0.69dL/g、ウィンテックポリマー(株)製)
(A-3)イソフタル酸変性ポリエチレンテレフタレート(イソフタル酸12.0モル%変性、固有粘度IV=0.80dL/g、(株)ベルポリエステルプロダクツ製)
(B)ガラス繊維
(B-1) ;扁平な断面形状を有するガラス繊維(長径・短径比:4、平均断面積196μm2、日東紡(株)製)
(B'-1) ;一般的な円形断面形状を有するガラス繊維(長径・短径比:1、平均断面積133μm2、日本電気ガラス(株)製)
(C)白色顔料
(C-1)硫化亜鉛 モース硬度4
(C'-1)ルチル型酸化チタン モース硬度7
尚、実施例6、7、8および比較例5については、表中の組成に更に第一リン酸カルシウムを0.15重量部添加している。
(2)物性評価
<引張強さ>
得られたペレットを140℃で3時間乾燥後、成形機シリンダー温度260℃、金型温度80℃で、射出成形により引張試験片を作製し、ISO-527(試験片厚み4mm)に準じて測定した。
<シャルピー衝撃強さ>
得られたペレットを140℃で3時間乾燥後、成形機シリンダー温度260℃、金型温度80℃で、射出成形によりシャルピー衝撃試験片を作製し、ISO-179(試験片厚み4mm)に準じて測定した。
(3)そり変形の評価
下記基準で平板の平面度を測定した。
評価成形品;50mm×50mm×厚さ1mmの平板
成形機;FANUC ROBOSHOTα-100Ia
シリンダー温度;260-260-240-220℃
金型温度;80℃
射出圧力;69MPa
平面度測定機;CNC画像測定機クイックビジョンQVH404(ミツトヨ社製)
平面度測定法は平板上の9点(縦横3×3点)にて測定した。
(4)携帯電話ハウジングでの評価
図1に示す携帯電話ハウジングを成形し、(4-1)~(4-3)の評価を行った。
成形機;住友重機工業SE100D
シリンダー温度;270-270-260-230℃
金型温度;100℃
(4-1)携帯電話ハウジングのヒンジ部の曲げ強度
図1のヒンジ部を押し曲げて、破壊強度を測定した。 Moreover, the detail of the used component and the measuring method of physical property evaluation are as follows.
(1) Components used
(A) Component (A-1) Isophthalic acid modified polybutylene terephthalate (Intrinsic viscosity IV = 0.65dL / g)
In the reaction of terephthalic acid with 1,4-butanediol, modified polybutylene terephthalate using 12.5 mol% of dimethylisophthalic acid as a copolymerization component instead of part of terephthalic acid (12.5 mol%) (A-2 ) Polybutylene terephthalate (Intrinsic viscosity IV = 0.69 dL / g, manufactured by Wintech Polymer Co., Ltd.)
(A-3) Isophthalic acid-modified polyethylene terephthalate (modified with 12.0 mol% isophthalic acid, intrinsic viscosity IV = 0.80 dL / g, manufactured by Bell Polyester Products)
(B) Glass fiber (B-1): Glass fiber having a flat cross section (major axis / minor axis ratio: 4, average cross-sectional area 196 μm 2 , manufactured by Nittobo Co., Ltd.)
(B'-1): Glass fiber having a general circular cross-sectional shape (major axis / minor axis ratio: 1, average cross-sectional area of 133 μm 2 , manufactured by NEC Glass, Inc.)
(C) White pigment (C-1) Zinc sulfide Mohs hardness 4
(C'-1) Rutile type titanium oxide Mohs hardness 7
In Examples 6, 7, 8 and Comparative Example 5, 0.15 parts by weight of primary calcium phosphate was further added to the composition in the table.
(2) Physical property evaluation <Tensile strength>
The obtained pellets were dried at 140 ° C. for 3 hours, and then a tensile test piece was prepared by injection molding at a molding machine cylinder temperature of 260 ° C. and a mold temperature of 80 ° C., and measured according to ISO-527 (test piece thickness 4 mm). did.
<Charpy impact strength>
The obtained pellets were dried at 140 ° C. for 3 hours, and then Charpy impact test pieces were prepared by injection molding at a molding machine cylinder temperature of 260 ° C. and a mold temperature of 80 ° C., according to ISO-179 (test piece thickness 4 mm). It was measured.
(3) Evaluation of warpage deformation The flatness of the flat plate was measured according to the following criteria.
Evaluation molded product; 50mm x 50mm x 1mm thickness flat plate molding machine; FANUC ROBOSHOTα-100Ia
Cylinder temperature: 260-260-240-220 ℃
Mold temperature: 80 ℃
Injection pressure: 69MPa
Flatness measuring machine; CNC image measuring machine Quick Vision QVH404 (Mitutoyo)
The flatness measurement method was performed at 9 points (3 × 3 points in length and width) on a flat plate.
(4) Evaluation in mobile phone housing The mobile phone housing shown in FIG. 1 was molded and evaluated in (4-1) to (4-3).
Molding machine: Sumitomo Heavy Industries SE100D
Cylinder temperature: 270-270-260-230 ℃
Mold temperature: 100 ℃
(4-1) Bending strength of hinge portion of mobile phone housing The bending strength was measured by pushing and bending the hinge portion of FIG.
測定速度;1000mm/分
(4-2)携帯電話ハウジングのボス部のひけ
図1のボス部の表面のひけ状況を目視観察した。
判断
○…ひけ少ない
×…ひけ多い
(4-3)携帯電話ハウジングのやけ(ガスによる圧縮発熱)
図1のヒンジ部流動末端のやけ状況を目視観察した。
判断
○…やけ少ない
×…やけ多い Measuring instrument: Universal testing machine Tensilon UTA50KN (Orientec)
Measurement speed: 1000mm / min
(4-2) Sink on the boss part of the mobile phone housing Sink condition on the surface of the boss part in FIG. 1 was visually observed.
Judgment ○… Low sink × × High sink
(4-3) Burning of mobile phone housing (compression heat generated by gas)
The burn condition at the flow end of the hinge part in FIG. 1 was visually observed.
Judgment ○… less burnt ×… more burnt
Claims (8)
- (A)変性ポリブチレンテレフタレート樹脂100重量部に対して、
(B)扁平な断面形状を有するガラス繊維40~140重量部
を配合してなるポリブチレンテレフタレート樹脂組成物からなる携帯端末部品。 (A) For 100 parts by weight of the modified polybutylene terephthalate resin,
(B) A mobile terminal part made of a polybutylene terephthalate resin composition containing 40 to 140 parts by weight of glass fibers having a flat cross-sectional shape. - (A)変性ポリブチレンテレフタレート樹脂が、全ジカルボン酸成分に対して5~30モル%のイソフタル酸を含むイソフタル酸変性ポリブチレンテレフタレートである請求項1記載のポリブチレンテレフタレート携帯端末部品。 2. The polybutylene terephthalate portable terminal component according to claim 1, wherein the (A) modified polybutylene terephthalate resin is isophthalic acid-modified polybutylene terephthalate containing 5 to 30 mol% of isophthalic acid with respect to the total dicarboxylic acid component.
- (A)変性ポリブチレンテレフタレート樹脂が、ポリブチレンテレフタレートとイソフタル酸変性ポリエチレンテレフタレートの混合物である請求項1記載の携帯端末部品。 The portable terminal component according to claim 1, wherein (A) the modified polybutylene terephthalate resin is a mixture of polybutylene terephthalate and isophthalic acid-modified polyethylene terephthalate.
- (B)扁平な断面形状を有するガラス繊維が、長さ方向に直角の断面の長径(断面の最長の直線距離)と短径(長径と直角方向の最長の直線距離)の比が1.3~10の間にあるものである請求項1~3の何れか1項記載の携帯端末部品。 (B) The ratio of the long diameter (longest straight line distance in the cross section) to the short diameter (long straight line and longest straight distance in the right direction) of the glass fiber having a flat cross section is 1.3 to 10 The mobile terminal component according to any one of claims 1 to 3, wherein the mobile terminal component is between the two.
- (B)扁平な断面形状を有するガラス繊維が、平均断面積100~300平方マイクロメートルのものである請求項1~4の何れか1項記載の携帯端末部品。 (B) The portable terminal component according to any one of claims 1 to 4, wherein the glass fiber having a flat cross-sectional shape has an average cross-sectional area of 100 to 300 square micrometers.
- 更に(C)モース硬度4.5以下の無機白色顔料を用いて着色された請求項1~5の何れか1項記載の携帯端末部品。 6. The portable terminal component according to claim 1, further comprising (C) an inorganic white pigment having a Mohs hardness of 4.5 or less.
- 携帯端末部品の筐体(ハウジング)、補強板(シャーシ)、フレーム、ヒンジ又はこれらの周辺関連部品である請求項1~6の何れか1項記載の携帯端末部品。 The portable terminal component according to any one of claims 1 to 6, which is a casing (housing), a reinforcing plate (chassis), a frame, a hinge, or a peripheral related component thereof.
- 請求項1に記載した組成物の携帯端末部品用途。 Use of the composition according to claim 1 for portable terminal parts.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020107014025A KR101503100B1 (en) | 2007-12-26 | 2008-12-24 | Mobile terminal part |
CN200880122938.3A CN101910305B (en) | 2007-12-26 | 2008-12-24 | Mobile terminal part |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007-334706 | 2007-12-26 | ||
JP2007334706A JP5329804B2 (en) | 2007-12-26 | 2007-12-26 | Mobile terminal parts |
Publications (1)
Publication Number | Publication Date |
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WO2009081574A1 true WO2009081574A1 (en) | 2009-07-02 |
Family
ID=40800891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/003909 WO2009081574A1 (en) | 2007-12-26 | 2008-12-24 | Mobile terminal part |
Country Status (4)
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JP (1) | JP5329804B2 (en) |
KR (1) | KR101503100B1 (en) |
CN (1) | CN101910305B (en) |
WO (1) | WO2009081574A1 (en) |
Cited By (1)
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JP2010111816A (en) * | 2008-11-07 | 2010-05-20 | Mitsubishi Engineering Plastics Corp | Molded article of polybutylene terephthalate resin having weld part |
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WO2011155366A1 (en) * | 2010-06-10 | 2011-12-15 | ウィンテックポリマー株式会社 | Modified polyalkylene terephthalate resin for improving adhesive strength, modified polyalkylene terephthalate resin composition for improving adhesive strength, resin molded article, and bonded article |
JP5773999B2 (en) * | 2010-06-10 | 2015-09-02 | ウィンテックポリマー株式会社 | Adhesive strength improving resin composition, resin molded body, joined body and adhesive strength improving agent |
CN104272885B (en) * | 2012-05-01 | 2017-05-17 | 胜技高分子株式会社 | Case for electronic devices |
JP5973282B2 (en) * | 2012-08-24 | 2016-08-23 | 三菱エンジニアリングプラスチックス株式会社 | Polycarbonate resin composition and molded body |
JP5968722B2 (en) * | 2012-08-24 | 2016-08-10 | 三菱エンジニアリングプラスチックス株式会社 | Polycarbonate resin composition and molded body |
KR101823736B1 (en) | 2015-09-24 | 2018-01-30 | 롯데첨단소재(주) | Polyester resin composition and article using the same |
CN106009542A (en) * | 2016-06-28 | 2016-10-12 | 长沙争明新材料有限公司 | Glass fiber reinforced terephthalic acid butanediol composite material and preparation method thereof |
WO2019070025A1 (en) * | 2017-10-06 | 2019-04-11 | 東洋紡株式会社 | Inorganic reinforced thermoplastic polyester resin composition |
JP7471065B2 (en) | 2019-09-13 | 2024-04-19 | アルテミラ製缶株式会社 | Sleeve printing plate and its manufacturing method |
KR102463004B1 (en) * | 2020-10-15 | 2022-11-03 | 니토 보세키 가부시기가이샤 | Glass Fiber Reinforced Resin Board |
CN115505245B (en) * | 2022-09-29 | 2023-12-19 | 江苏金发科技新材料有限公司 | PBT composite material and preparation method and application thereof |
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Also Published As
Publication number | Publication date |
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JP2009155449A (en) | 2009-07-16 |
JP5329804B2 (en) | 2013-10-30 |
CN101910305A (en) | 2010-12-08 |
CN101910305B (en) | 2013-02-13 |
KR20100105840A (en) | 2010-09-30 |
KR101503100B1 (en) | 2015-03-16 |
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