WO2009073903A1 - Procédé de fabrication d'un module photovoltaïque - Google Patents
Procédé de fabrication d'un module photovoltaïque Download PDFInfo
- Publication number
- WO2009073903A1 WO2009073903A1 PCT/AT2008/000437 AT2008000437W WO2009073903A1 WO 2009073903 A1 WO2009073903 A1 WO 2009073903A1 AT 2008000437 W AT2008000437 W AT 2008000437W WO 2009073903 A1 WO2009073903 A1 WO 2009073903A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- primer
- layer
- adhesive
- carrier
- solar cell
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 56
- 239000000853 adhesive Substances 0.000 claims abstract description 23
- 230000001070 adhesive effect Effects 0.000 claims abstract description 23
- 230000004888 barrier function Effects 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 claims description 33
- 239000004814 polyurethane Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 23
- -1 organosilane compounds Chemical class 0.000 claims description 21
- 229920000728 polyester Polymers 0.000 claims description 21
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 20
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 20
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 20
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 19
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 18
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 18
- 239000012876 carrier material Substances 0.000 claims description 17
- 239000002131 composite material Substances 0.000 claims description 17
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 13
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 229920006267 polyester film Polymers 0.000 claims description 12
- 125000005609 naphthenate group Chemical group 0.000 claims description 11
- 229920002620 polyvinyl fluoride Polymers 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 10
- 239000012943 hotmelt Substances 0.000 claims description 10
- 229920000554 ionomer Polymers 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 9
- 238000005538 encapsulation Methods 0.000 claims description 6
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 6
- 239000002318 adhesion promoter Substances 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000002985 plastic film Substances 0.000 claims description 4
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000013464 silicone adhesive Substances 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000010410 layer Substances 0.000 description 79
- 230000007062 hydrolysis Effects 0.000 description 13
- 238000006460 hydrolysis reaction Methods 0.000 description 13
- 239000000654 additive Substances 0.000 description 10
- 239000004593 Epoxy Substances 0.000 description 9
- 239000002033 PVDF binder Substances 0.000 description 9
- 239000012790 adhesive layer Substances 0.000 description 9
- 229920002313 fluoropolymer Polymers 0.000 description 9
- 239000004811 fluoropolymer Substances 0.000 description 9
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 9
- 238000004383 yellowing Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 230000032798 delamination Effects 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 150000001282 organosilanes Chemical class 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- 229910017107 AlOx Inorganic materials 0.000 description 1
- 241000575946 Ione Species 0.000 description 1
- LTXREWYXXSTFRX-QGZVFWFLSA-N Linagliptin Chemical compound N=1C=2N(C)C(=O)N(CC=3N=C4C=CC=CC4=C(C)N=3)C(=O)C=2N(CC#CC)C=1N1CCC[C@@H](N)C1 LTXREWYXXSTFRX-QGZVFWFLSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the invention relates to a method for producing a photovoltaic module, comprising a solar cell system and encapsulation materials attached thereto on both sides, which encapsulate a sealable with respect to the solar cell system
- Embedding material and a barrier material included.
- Photovoltaic modules are used to generate electricity from sunlight.
- the energy is generated by the solar cell system, which consists essentially of semiconductor materials, such as. Silicon is formed in monocrystalline, polycrystalline or amorphous form.
- These solar cell systems have only limited mechanical load, so they must be encased on both sides with encapsulating materials.
- encapsulating materials For example, one or more layers of glass and / or plastic films and / or plastic film composites serve as encapsulation materials.
- EP-A-969 521 it is therefore proposed to apply to the inorganic oxide layer which faces the solar cell system, likewise a primer layer which serves as a bonding agent to the adjacent sealing layer.
- adhesion promoters are also described, inter alia, in EP-A-0 956 657, which relates to the construction of a transparent front-side encapsulation for solar cells or for photovoltaic modules. Due to the multilayer structure, a bonding agent between the rir
- the adhesion promoters known from EP-A-I 956 657 or EP-A-969 521 thus have the function of producing a bond between nonpolar surfaces on the one hand and polar surfaces on the other hand.
- the primer layer is still materially isolated from the other composite layers.
- the adhesion promoter layer can therefore be at least partially dissolved, in particular when working with solvents during the production of the photovoltaic module, so that undesired delamination of the individual composite layers could again occur.
- the invention aims to remedy this situation.
- a method of the aforementioned type is proposed, which is characterized in that the barrier material is provided on the side facing the embedding material on at least one side of the solar cell system with a primer layer, wherein on the carrier layer for the barrier material, the primer is applied from a solution and then the solvents are evaporated to form an adhesive carrier material.
- the finished photovoltaic module can only be destroyed by forcibly separating the layers.
- the finished module shows no losses of mec an sc er he, he nac eau sc agung m uge er
- the photovoltaic module 1 shows an exemplary structure for the photovoltaic module produced according to the invention, comprising the solar cell system 6, which is encased on both sides by the encapsulation materials 1, 1 '.
- the encapsulation material 1, 1 ' consists of the outwardly facing barrier material 7, 7' as well as the embedding material 5, 5 'sealable with respect to the solar cell system 6.
- the adhesive carrier material 13 consists of a carrier layer 3 and a primer layer 4, which faces the embedding material 5.
- FIG. 2 shows an analogous structure of a barrier material 7, as shown in FIG. 1, with the difference that an inorganic oxide layer 8 is additionally arranged between the carrier layer 3 and the weather-resistant layer 2.
- FIG. 3 shows an exemplary method sequence for applying the primer layer 4 to the carrier layer 3.
- the carrier layer 3 is guided by means of deflection rollers 9a, 9b via a corona station 10 into an application system 11. Subsequently, the carrier layer 3 charged with the primer 4 passes through deflection rollers 9c, 9d through a drying channel 12. In this way, the adhesive carrier material 13 is obtained.
- the primer layer 4 represents a characteristic essential to the invention.
- primers based on polyurethane are used.
- Two-component adhesive systems are particularly preferred. These consist of polyurethane prepolymers with isocyanate end groups, we ce mi po y un ione en o en verne z. ie
- Isocyanate end groups may be either of an aromatic nature, such as e.g. Toluene diisocyanate (TDI) or diphenylmethane diisocyanate (MDI), or aliphatic nature, e.g. Hexamethylene diisocyanate (HDI) or isophorone diisoyanate (IPDI).
- aromatic nature such as e.g. Toluene diisocyanate (TDI) or diphenylmethane diisocyanate (MDI)
- aliphatic nature e.g. Hexamethylene diisocyanate (HDI) or isophorone diisoyanate (IPDI).
- the above components are combined with an excess of isocyanate groups together with other components such as stabilizers, pigments, and the like. and organic solvents to obtain the required properties such as tack, dryness of the primer surface, solid content, and color adjustment.
- the primer mixture can cure either at room temperature or at elevated temperature.
- the surface of the carrier layer 3 can be physically pretreated to produce an optimal connection of the primer.
- the method of corona treatment is preferably used, whereby a partial oxidation takes place, which has an increased polarity of the surface of the material in the carrier layer 3 result.
- Weathering-resistant layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Support layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE), as well as co-extrudates in the form of films or film composites, aluminum foils in different thicknesses.
- Primer layer 4 polyurethane, polyacrylate
- Embedding material 5, 5 ' ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Support layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE), as well as o-x ru ae in orm o ien o er o ienverr ⁇ in en,
- Aluminum foils in different thicknesses are Aluminum foils in different thicknesses.
- Primer Layer 4 polyurethane, polyacrylate; Addition of additives such as UV absorbers, antioxidants, hydrolysis additives.
- Embedding material 5, 5 * ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- EVA ethylene vinyl acetate
- PVB polyvinyl butyral
- ionomers polymethylmethacrylate
- TPU polyurethane
- Example c) Weathering-resistant layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Support layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE), as well as co-extrudates in the form of films or film composites, aluminum films in different thicknesses.
- PET polyethylene terephthalate
- PEN polyethylene naphthenate
- ETFE ethylene tetrafluoroethylene copolymer
- Primer Layer 4 polyurethane, polyacrylate; Addition of pigments, such as TiO2, CaCO3 or carbon black.
- EVA ethylene vinyl acetate
- PVB polyvinyl butyral
- ionomers polymethylmethacrylate
- TPU polyurethane
- Weathering-resistant layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Support layer 3 Polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE), as well as co-extrudates in the form of films or film composites, applying a vapor deposited inorganic oxide layer 8 to increase the barrier effect.
- Primer layer 4 polyurethane, polyacrylate
- Embedding material 5, 5 ' ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- EVA ethylene vinyl acetate
- PVB polyvinyl butyral
- PMMA polymethylmethacrylate
- TPU polyurethane
- Weathering-resistant layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- gersc c o ye y en erep aa, o ye y en naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE) and co-extrudates in the form of films or film composites.
- Primer layer 4 Polyurethane which is coextruded in the form of a thermoplastic (TPU, thermoplastic polyurethane) with the polyester film in the form of a pressure and temperature-sensitive film.
- TPU thermoplastic polyurethane
- Embedding material 5, 5 ' ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- EVA ethylene vinyl acetate
- PVB polyvinyl butyral
- PMMA polymethylmethacrylate
- TPU polyurethane
- Weathering-resistant layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Support layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE) and; Co-extrudates in the form of films or film composites.
- Primer Layer 4 Polyurethane mixed with organosilanes to improve adhesion promoting properties.
- Embedding material 5, 5 ⁇ ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- EVA ethylene vinyl acetate
- PVB polyvinyl butyral
- ionomers polymethylmethacrylate
- PMMA polymethylmethacrylate
- TPU polyurethane
- polyester or hotmelt hotmelt.
- Weathering layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Carrier layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE) and coextrudates in the form of films or film composites.
- Primer layer 4 polyurethane, based on a two-component adhesive consisting of the components A and B.
- the component A consists of a polyester mixture, which due to its composition to no yellowing in weathering long-term tests (Damp Heat Test, 85 0 C, 85% humidity) under UV irradiation tends.
- Component B consists of an isocyanate polymer which, owing to its aliphatic structure, hardly leaves any possibilities for yellowing. , in en ementma,: y enviny ace a,
- PVB Polyvinyl butyral
- PMMA polymethylmethacrylate
- TPU polyurethane
- polyester or hotmelt Polyvinyl butyral
- Example h Weathering-resistant layer 2: PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Carrier layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE) and coextrudates in the form of films or film composites.
- Primer layer 4 polyurethane, additionally protected by an acrylate layer.
- Embedding material 5, 5 " ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- Weathering-resistant layer 2 PVF film, soluble fluoropolymers (PVDF) or fluorine copolymers for direct coating, hydrolysis-resistant polyester films.
- Adhesive layer (not shown): polyurethane, polyester, epoxy.
- Carrier layer 3 polyethylene terephthalate (PET), polyethylene naphthenate (PEN), ethylene tetrafluoroethylene copolymer (ETFE) and coextrudates in the form of films or film composites.
- Primer Layer 4 Silicone-based polyurethane, one or two component adhesive.
- Embedding material 5, 5 ' ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), ionomers, polymethylmethacrylate (PMMA), polyurethane (TPU), polyester or hotmelt.
- EVA ethylene vinyl acetate
- PVB polyvinyl butyral
- PMMA polymethylmethacrylate
- TPU polyurethane
- a 35% solution of a primer based on the solids content of the primer components is prepared.
- the polyester-polyol component is mixed with a ketone-based organic solvent.
- the isocyanate hardener is added and mixed again well.
- the primer solution is applied via the application system 11 -see FIG. 3 -to the carrier layer 3, for example a polyester film pretreated with corona radiation.
- Primer layer 4 which is in the range of 13 ⁇ 3 g / m2.
- the coated material is passed over deflection rollers 9 c and 9 d through a dryer 12, in which the solvent used at temperatures between 70 ° C and 120 0 C evaporated.
- the exhaust air and temperature settings are selected so that a bubble-free and as dry as possible coating.
- the adhesive carrier material 13 obtained is fed to the storage roll after the dryer section via a deflection roller 9 e and wound up. Depending on the curing time and thus dependent on the chemical structure of the isocyanate, the storage time for the carrier material 13 results.
- Examples a) -i) show the different possibilities as to which components and additives can be used.
- Example a shows the basic structure of a two-layer laminate with primer.
- the primer layer can be made.
- Polyurethane and / or acrylate adhesives exist.
- additives - such as UV absorbers; Antioxidants or hydrolysis additives
- the primer for the formation of the primer layer 4 is protected against weathering and UV radiation.
- Aromatic components which may be contained in the primer are temporarily protected from yellowing by additives. Yellowing is prevented until the entire proportion of additives is consumed.
- UV additives compounds are listed on HALS (hindered amine) and triazine based.
- hydrolysis additives compounds based on phosphonites can be used. In order to completely prevent the yellowing of the primer, primer systems with aliphatic isocyanate content are preferred.
- Example c describes the addition of color pigments such as TiO 2, CaCO 3 or carbon black.
- the primer for the formation of the primer layer 4 can be colored white or black, • to enhance the optical color impression of the overall system.
- the photocatalytic effect of TiO2 requires the addition of UV additives.
- an additional oxide layer for example SiOx or AlOx, is applied to the carrier layer 3.
- the inorganic oxide layer is penetrated to a thickness of 100 nm amp a s on the outside and on
- Polyester surface provides additional protection against water vapor entry into the photovoltaic module.
- the primer layer does not have a solvent-containing system but a thermoplastic one
- This primer film can with the
- Carrier layer 3 coextruded or applied by means of pressure and temperature during the lamination process on the carrier film 3.
- Example g proposes the use of an aliphatic two-component primer mixture which shows no yellowing and which is distinguished by hydrolysis stability.
- the connection to the carrier layer 3 and the embedding material 5 shows no impairment.
- the polyurethane primer layer 4 is additionally protected with an acrylate layer.
- Example i) describes the use of a silicone adhesive based on polyurethane. The silicone shows excellent properties in the event of temperature fluctuations.
- the application of the primer layer 4 to the carrier layer 3 brings about a significant improvement in the binding of the embedding material 5 for the solar cell system 6.
- 2 cm wide strips of the roll-mounted carrier material 13 were produced, wherein in each case according to the exemplary embodiments according to a) to i) was proceeded.
- the test strips were subjected to a peeling rate of 50 N / mm, it being possible to demonstrate that the carrier material 13 shows no delamination even after accelerated aging, namely 500 h and 1000 h at 85 ° C. and 85% atmospheric humidity.
- the roll-mounted adhesive carrier material 13 can now be further processed in combination with other weather-resistant films, such as, for example, polyvinyl fluoride films or polyethylene naphthenate films.
- the embedding material layer 5 can also be attached to the adhesive carrier material 13 by coextrusion.
- This material structure can now be present on one or both sides of the solar cell system 6.
- known material constructions such as, for example, the combination of a transparent glass layer 7 'in combination with an embedding material 5'.
- the primer layer 4 is applied to the respectively particularly stressed side of the solar cell system 6, preferably in the form of a backside laminate, then extremely satisfactory long-term results can be achieved when using the photovoltaic module in the outdoor area.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Photovoltaic Devices (AREA)
Abstract
L'invention concerne un procédé de fabrication d'un module photovoltaïque, comprenant un système de cellules solaires (6), ainsi que des matières d'encapsulation (1, 1') disposées de chaque côté de ce système, ces matières comprenant une matière d'enrobage (5, 5') scellable vis-à-vis du système de cellules solaires (6) et une matière barrière (7, 7'). Selon l'invention, sur au moins un côté du système de cellules solaires (6), la matière barrière (7, 7') est pourvue d'une couche primaire (4) sur le côté faisant face à la matière d'enrobage (5). Cette couche primaire est appliquée à partir d'une solution sur la couche support (3) pour la matière barrière (7), puis les solvants sont évaporés de façon à former la matière support adhésive (13).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA2026/2007 | 2007-12-13 | ||
AT0202607A AT506100A1 (de) | 2007-12-13 | 2007-12-13 | Photovoltaisches modul mit primerschicht |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009073903A1 true WO2009073903A1 (fr) | 2009-06-18 |
Family
ID=40481880
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2008/000437 WO2009073903A1 (fr) | 2007-12-13 | 2008-12-09 | Procédé de fabrication d'un module photovoltaïque |
Country Status (2)
Country | Link |
---|---|
AT (2) | AT506100A1 (fr) |
WO (1) | WO2009073903A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115230263A (zh) * | 2022-07-04 | 2022-10-25 | 苏州中来光伏新材股份有限公司 | 一种一体化玻纤增强型光伏板及其制备方法和应用 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016095952A1 (fr) * | 2014-12-15 | 2016-06-23 | Ven Van De Marcus Leonardus Gerardus Maria | Film de recouvrement pour production d'énergie électrique photovoltaïque |
DE102016222129A1 (de) * | 2016-11-10 | 2018-05-17 | Sig Technology Ag | Verfahren zum Bedrucken eines Laminats zum Herstellen formstabiler Nahrungsmittelbehälter mit Aufbringen einer Grundierung mit Überdosierung von Isocyanatgruppen |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1054456A2 (fr) * | 1999-05-17 | 2000-11-22 | Dai Nippon Printing Co., Ltd. | Couche de protection pour un module de cellules solaires, sa méthode de fabrication et module de cellules solaires |
WO2003064529A1 (fr) * | 2002-02-01 | 2003-08-07 | Shell Solar Gmbh | Couche barriere constituee par une resine durcissante contenant un polyol polymere |
WO2004069949A1 (fr) * | 2003-02-06 | 2004-08-19 | Canon Kabushiki Kaisha | Procede de liaison de produit forme contenant un copolymere d'ethylene-acetate de vinyle |
US20060166023A1 (en) * | 2002-09-06 | 2006-07-27 | Dai Nippon Printing Co., Ltd. | Backside protective sheet for solar battery module and solar battery module using the same |
WO2007009140A1 (fr) * | 2005-07-21 | 2007-01-25 | Isovolta Ag | Procede de fabrication de lamines resistants aux intemperies destines a l'encapsulage de systemes de cellules solaires |
-
2007
- 2007-12-13 AT AT0202607A patent/AT506100A1/de active IP Right Grant
-
2008
- 2008-12-09 WO PCT/AT2008/000437 patent/WO2009073903A1/fr active Application Filing
-
2009
- 2009-09-02 AT AT0806009U patent/AT11128U1/de not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1054456A2 (fr) * | 1999-05-17 | 2000-11-22 | Dai Nippon Printing Co., Ltd. | Couche de protection pour un module de cellules solaires, sa méthode de fabrication et module de cellules solaires |
WO2003064529A1 (fr) * | 2002-02-01 | 2003-08-07 | Shell Solar Gmbh | Couche barriere constituee par une resine durcissante contenant un polyol polymere |
US20060166023A1 (en) * | 2002-09-06 | 2006-07-27 | Dai Nippon Printing Co., Ltd. | Backside protective sheet for solar battery module and solar battery module using the same |
WO2004069949A1 (fr) * | 2003-02-06 | 2004-08-19 | Canon Kabushiki Kaisha | Procede de liaison de produit forme contenant un copolymere d'ethylene-acetate de vinyle |
WO2007009140A1 (fr) * | 2005-07-21 | 2007-01-25 | Isovolta Ag | Procede de fabrication de lamines resistants aux intemperies destines a l'encapsulage de systemes de cellules solaires |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115230263A (zh) * | 2022-07-04 | 2022-10-25 | 苏州中来光伏新材股份有限公司 | 一种一体化玻纤增强型光伏板及其制备方法和应用 |
CN115230263B (zh) * | 2022-07-04 | 2023-09-26 | 苏州中来光伏新材股份有限公司 | 一种一体化玻纤增强型光伏板及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
AT11128U1 (de) | 2010-05-15 |
AT506100A1 (de) | 2009-06-15 |
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