WO2009028371A1 - アクロレインの製造方法およびアクリル酸の製造方法 - Google Patents

アクロレインの製造方法およびアクリル酸の製造方法 Download PDF

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Publication number
WO2009028371A1
WO2009028371A1 PCT/JP2008/064828 JP2008064828W WO2009028371A1 WO 2009028371 A1 WO2009028371 A1 WO 2009028371A1 JP 2008064828 W JP2008064828 W JP 2008064828W WO 2009028371 A1 WO2009028371 A1 WO 2009028371A1
Authority
WO
WIPO (PCT)
Prior art keywords
acrolein
production method
fatty acid
acrylic acid
mixture
Prior art date
Application number
PCT/JP2008/064828
Other languages
English (en)
French (fr)
Inventor
Takanori Aoki
Norihide Arai
Original Assignee
Showa Denko K.K.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2007223069A external-priority patent/JP5401024B2/ja
Priority claimed from JP2007223067A external-priority patent/JP5401022B2/ja
Priority claimed from JP2007223068A external-priority patent/JP5401023B2/ja
Application filed by Showa Denko K.K. filed Critical Showa Denko K.K.
Priority to US12/673,567 priority Critical patent/US20110237828A1/en
Priority to EP08828264.5A priority patent/EP2186790B1/en
Publication of WO2009028371A1 publication Critical patent/WO2009028371A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

本発明は、脂肪酸及び/又は脂肪酸塩、グリセリド、脂肪酸エステル等を含むグリセリン混合物からアクロレインを少ないエネルギー消費量で製造できるアクロレインおよびアクリル酸の製造方法を提供することを目的とする。本発明のアクロレインの製造方法は、グリセリン混合物中のグリセリンを脱水反応させて、アクロレインと脂肪酸及び/又は脂肪酸塩等を含むアクロレイン混合物を得る工程と、該アクロレイン混合物からアクロレインを回収する工程とを有する。本発明のアクリル酸の製造方法は、上述したアクロレインの製造方法により得たアクロレインと、分子状酸素とを反応させる。
PCT/JP2008/064828 2007-08-29 2008-08-20 アクロレインの製造方法およびアクリル酸の製造方法 WO2009028371A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/673,567 US20110237828A1 (en) 2007-08-29 2008-08-20 Acrolein production method and acrylic acid production method
EP08828264.5A EP2186790B1 (en) 2007-08-29 2008-08-20 Acrolein production method and acrylic acid production method

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2007-223067 2007-08-29
JP2007223069A JP5401024B2 (ja) 2007-08-29 2007-08-29 アクロレインの製造方法およびアクリル酸の製造方法
JP2007-223068 2007-08-29
JP2007223067A JP5401022B2 (ja) 2007-08-29 2007-08-29 アクロレインの製造方法およびアクリル酸の製造方法
JP2007-223069 2007-08-29
JP2007223068A JP5401023B2 (ja) 2007-08-29 2007-08-29 アクロレインの製造方法およびアクリル酸の製造方法

Publications (1)

Publication Number Publication Date
WO2009028371A1 true WO2009028371A1 (ja) 2009-03-05

Family

ID=40387094

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/064828 WO2009028371A1 (ja) 2007-08-29 2008-08-20 アクロレインの製造方法およびアクリル酸の製造方法

Country Status (3)

Country Link
US (1) US20110237828A1 (ja)
EP (1) EP2186790B1 (ja)
WO (1) WO2009028371A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012058081A1 (en) 2010-10-27 2012-05-03 The Procter & Gamble Company Preparation of foam materials derived from renewable resources
JP2013075842A (ja) * 2011-09-29 2013-04-25 Nippon Shokubai Co Ltd アクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
CN113080382A (zh) * 2021-03-31 2021-07-09 南京师范大学 小豆蔻明作为丙烯醛抑制剂的应用

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009084417A1 (ja) * 2007-12-28 2009-07-09 Showa Denko K.K. アクリル酸の製造方法
JP5478132B2 (ja) 2009-07-01 2014-04-23 株式会社日立製作所 アクロレインの合成方法及び装置
CN103827070A (zh) 2011-09-29 2014-05-28 株式会社日本触媒 丙烯醛、丙烯酸及其衍生物的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06211724A (ja) 1992-11-14 1994-08-02 Degussa Ag アクロレインまたはアクロレイン水溶液の製造方法および１，３−プロパンジオールの製造方法
JP2005213225A (ja) 2004-01-30 2005-08-11 Nippon Shokubai Co Ltd アクリル酸の製造方法
WO2006087084A2 (en) * 2005-02-15 2006-08-24 Arkema France Process for dehydrating glycerol to acrolein
WO2008066082A1 (fr) * 2006-12-01 2008-06-05 Nippon Shokubai Co., Ltd. Procédé permettant de produire une composition contenant de l'acroléine et de la glycérine

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI522092B (zh) * 2005-02-28 2016-02-21 贏創德固賽有限責任公司 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
PL213939B1 (pl) * 2006-03-24 2013-05-31 Inst Chemii Przemyslowej Im Prof Ignacego Moscickiego Sposób przerobu frakcji glicerynowej z procesu transestryfikacji triglicerydów kwasów tluszczowych
DE102006054519A1 (de) * 2006-11-20 2008-05-21 Evonik Degussa Gmbh Verfahren zur Herstellung von Fettsäurealkylestern und Acrolein aus Triglyceriden
JP2008174544A (ja) * 2007-11-27 2008-07-31 Nippon Shokubai Co Ltd アクロレインの製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06211724A (ja) 1992-11-14 1994-08-02 Degussa Ag アクロレインまたはアクロレイン水溶液の製造方法および１，３−プロパンジオールの製造方法
JP2005213225A (ja) 2004-01-30 2005-08-11 Nippon Shokubai Co Ltd アクリル酸の製造方法
WO2006087084A2 (en) * 2005-02-15 2006-08-24 Arkema France Process for dehydrating glycerol to acrolein
WO2008066082A1 (fr) * 2006-12-01 2008-06-05 Nippon Shokubai Co., Ltd. Procédé permettant de produire une composition contenant de l'acroléine et de la glycérine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2186790A4

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012058081A1 (en) 2010-10-27 2012-05-03 The Procter & Gamble Company Preparation of foam materials derived from renewable resources
JP2013075842A (ja) * 2011-09-29 2013-04-25 Nippon Shokubai Co Ltd アクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
CN113080382A (zh) * 2021-03-31 2021-07-09 南京师范大学 小豆蔻明作为丙烯醛抑制剂的应用
CN113080382B (zh) * 2021-03-31 2023-08-25 南京师范大学 小豆蔻明作为丙烯醛抑制剂的应用

Also Published As

Publication number Publication date
EP2186790B1 (en) 2016-04-13
US20110237828A1 (en) 2011-09-29
EP2186790A1 (en) 2010-05-19
EP2186790A4 (en) 2013-09-04

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