WO2009011075A1 - 銅砒素化合物の処理方法 - Google Patents

銅砒素化合物の処理方法 Download PDF

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Publication number
WO2009011075A1
WO2009011075A1 PCT/JP2007/071132 JP2007071132W WO2009011075A1 WO 2009011075 A1 WO2009011075 A1 WO 2009011075A1 JP 2007071132 W JP2007071132 W JP 2007071132W WO 2009011075 A1 WO2009011075 A1 WO 2009011075A1
Authority
WO
WIPO (PCT)
Prior art keywords
arsenic
scorodite
copper
oxidizing agent
leaching
Prior art date
Application number
PCT/JP2007/071132
Other languages
English (en)
French (fr)
Inventor
Mitsuo Abumiya
Yusuke Sato
Hironobu Mikami
Masami Oouchi
Tetsuo Fujita
Masayoshi Matsumoto
Original Assignee
Dowa Metals & Mining Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dowa Metals & Mining Co., Ltd. filed Critical Dowa Metals & Mining Co., Ltd.
Publication of WO2009011075A1 publication Critical patent/WO2009011075A1/ja

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B30/00—Obtaining antimony, arsenic or bismuth
    • C22B30/04—Obtaining arsenic
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G28/00—Compounds of arsenic
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G28/00—Compounds of arsenic
    • C01G28/02—Arsenates; Arsenites
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0065—Leaching or slurrying
    • C22B15/008—Leaching or slurrying with non-acid solutions containing salts of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0084—Treating solutions
    • C22B15/0086—Treating solutions by physical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0084—Treating solutions
    • C22B15/0089—Treating solutions by chemical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0095—Process control or regulation methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/008—Wet processes by an alkaline or ammoniacal leaching
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

　非鉄製錬中間産物に含まれる砒素の処理、特に金属間化合物形態の銅砒素化合物の処理において、濾過性に優れ且つ安定なスコロダイトを、再現性良く、煩雑な操作なしに簡便に生成する方法を提供する。金属間化合物形態の銅砒素化合物を含む非鉄製錬中間産物から、硫化剤と酸化剤の共存下で砒素を浸出する浸出工程と、当該浸出液に酸化剤を添加して、３価砒素を５価砒素へ酸化する液調整工程と、当該調整液中の砒素をスコロダイト結晶へ転換する結晶化工程とによりスコロダイトを製造する。
PCT/JP2007/071132 2007-07-13 2007-10-30 銅砒素化合物の処理方法 WO2009011075A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007185052 2007-07-13
JP2007-185052 2007-07-13

Publications (1)

Publication Number Publication Date
WO2009011075A1 true WO2009011075A1 (ja) 2009-01-22

Family

ID=40259423

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/071132 WO2009011075A1 (ja) 2007-07-13 2007-10-30 銅砒素化合物の処理方法

Country Status (1)

Country Link
WO (1) WO2009011075A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010084877A1 (ja) * 2009-01-21 2010-07-29 Ｄｏｗａメタルマイン株式会社 砒素の処理方法
CN108164030A (zh) * 2017-12-27 2018-06-15 中国科学院过程工程研究所 一种含砷溶液中砷的固定化方法
CN111778520A (zh) * 2020-05-22 2020-10-16 西北矿冶研究院 一种并流沉淀法降低铜电解过程漂浮阳极泥的方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6124329B2 (ja) * 1978-06-09 1986-06-10 Sumitomo Metal Mining Co
JPS6277431A (ja) * 1985-09-30 1987-04-09 Sumitomo Metal Mining Co Ltd 脱銅スライムから銅及び砒素を夫々選択的に抽出する方法
JPH0625763A (ja) * 1992-02-25 1994-02-01 Mitsubishi Materials Corp 製錬中間産物の処理方法
JP2000219920A (ja) * 1999-01-29 2000-08-08 Dowa Mining Co Ltd 砒素含有溶液からの砒素の除去および固定方法
JP2006328498A (ja) * 2005-05-27 2006-12-07 Univ Of Tokyo 酸性鉱山廃水の水処理工程で発生する中和殿物の資源化方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6124329B2 (ja) * 1978-06-09 1986-06-10 Sumitomo Metal Mining Co
JPS6277431A (ja) * 1985-09-30 1987-04-09 Sumitomo Metal Mining Co Ltd 脱銅スライムから銅及び砒素を夫々選択的に抽出する方法
JPH0625763A (ja) * 1992-02-25 1994-02-01 Mitsubishi Materials Corp 製錬中間産物の処理方法
JP2000219920A (ja) * 1999-01-29 2000-08-08 Dowa Mining Co Ltd 砒素含有溶液からの砒素の除去および固定方法
JP2006328498A (ja) * 2005-05-27 2006-12-07 Univ Of Tokyo 酸性鉱山廃水の水処理工程で発生する中和殿物の資源化方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010084877A1 (ja) * 2009-01-21 2010-07-29 Ｄｏｗａメタルマイン株式会社 砒素の処理方法
CN108164030A (zh) * 2017-12-27 2018-06-15 中国科学院过程工程研究所 一种含砷溶液中砷的固定化方法
CN111778520A (zh) * 2020-05-22 2020-10-16 西北矿冶研究院 一种并流沉淀法降低铜电解过程漂浮阳极泥的方法

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