WO2009010692A3 - Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene - Google Patents

Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene Download PDF

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Publication number
WO2009010692A3
WO2009010692A3 PCT/FR2008/051275 FR2008051275W WO2009010692A3 WO 2009010692 A3 WO2009010692 A3 WO 2009010692A3 FR 2008051275 W FR2008051275 W FR 2008051275W WO 2009010692 A3 WO2009010692 A3 WO 2009010692A3
Authority
WO
WIPO (PCT)
Prior art keywords
oxygen
gas containing
mercury
eliminating mercury
vol
Prior art date
Application number
PCT/FR2008/051275
Other languages
English (en)
Other versions
WO2009010692A2 (fr
Inventor
Philippe Court
Arthur Darde
Vladimir Hasanov
Christian Monereau
Serge Moreau
Jean-Pierre Tranier
Original Assignee
Air Liquide
Philippe Court
Arthur Darde
Vladimir Hasanov
Christian Monereau
Serge Moreau
Jean-Pierre Tranier
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide, Philippe Court, Arthur Darde, Vladimir Hasanov, Christian Monereau, Serge Moreau, Jean-Pierre Tranier filed Critical Air Liquide
Priority to EP08826487A priority Critical patent/EP2178622A2/fr
Priority to JP2010515573A priority patent/JP2010533064A/ja
Priority to US12/668,763 priority patent/US8535416B2/en
Priority to AU2008277537A priority patent/AU2008277537B2/en
Priority to CN200880024609A priority patent/CN101842144A/zh
Priority to CA 2693038 priority patent/CA2693038A1/fr
Publication of WO2009010692A2 publication Critical patent/WO2009010692A2/fr
Publication of WO2009010692A3 publication Critical patent/WO2009010692A3/fr

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/104—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/60—Heavy metals; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/30—Sorption devices using carbon, e.g. coke
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/60—Sorption with dry devices, e.g. beds

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Chimneys And Flues (AREA)

Abstract

Procédé de purification d'un flux de gaz d'alimentation sous une pression > 3 bars, comprenant au moins 1 % en volume d'oxygène (O2) et au moins 75% en volume de CO2 Ct du mercure, caractérisé en ce qu'il comprend une étape de purification par adsorption dans lequel on met en œuvre au moins un lit fixe d'adsorbants contenant un adsorbant soufré et/ou argenté, de manière à éliminer au moins partiellement le mercure.
PCT/FR2008/051275 2007-07-13 2008-07-08 Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene WO2009010692A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP08826487A EP2178622A2 (fr) 2007-07-13 2008-07-08 Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene
JP2010515573A JP2010533064A (ja) 2007-07-13 2008-07-08 Ｃｏ２および酸素を含有するガスから水銀を除去するための方法
US12/668,763 US8535416B2 (en) 2007-07-13 2008-07-08 Method for eliminating mercury from a gas containing CO2 and oxygen
AU2008277537A AU2008277537B2 (en) 2007-07-13 2008-07-08 Method for eliminating mercury from a gas containing CO2 and oxygen
CN200880024609A CN101842144A (zh) 2007-07-13 2008-07-08 从包含co2和氧的气体中除去汞的方法
CA 2693038 CA2693038A1 (fr) 2007-07-13 2008-07-08 Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0756494A FR2918580B1 (fr) 2007-07-13 2007-07-13 Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene
FR0756494 2007-07-13

Publications (2)

Publication Number Publication Date
WO2009010692A2 WO2009010692A2 (fr) 2009-01-22
WO2009010692A3 true WO2009010692A3 (fr) 2009-03-26

Family

ID=39110571

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/051275 WO2009010692A2 (fr) 2007-07-13 2008-07-08 Procede pour eliminer le mercure d'un gaz contenant du co2 et de l'oxygene

Country Status (8)

Country Link
US (1) US8535416B2 (fr)
EP (1) EP2178622A2 (fr)
JP (1) JP2010533064A (fr)
CN (1) CN101842144A (fr)
AU (1) AU2008277537B2 (fr)
CA (1) CA2693038A1 (fr)
FR (1) FR2918580B1 (fr)
WO (1) WO2009010692A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2949978B1 (fr) * 2009-09-17 2012-08-31 Air Liquide Procede de purification d'un flux gazeux comprenant du mercure
US8690991B2 (en) 2010-09-24 2014-04-08 Phillips 66 Company Supported silver sulfide sorbent
FR2992233B1 (fr) * 2012-06-26 2018-03-16 IFP Energies Nouvelles Masse de captation composee de soufre elementaire depose sur un support poreux pour la captation des metaux lourds
AU2013270629B2 (en) * 2012-12-21 2017-10-19 IFP Energies Nouvelles Polymetallic capture mass for capturing heavy metals
CN110559793A (zh) * 2019-09-29 2019-12-13 河北石兴科技有限公司 一种可再生天然气脱汞新方法
CN112191227B (zh) * 2020-10-12 2021-04-02 西南石油大学 一种用于天然气的脱汞剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4094777A (en) * 1975-12-18 1978-06-13 Institut Francais Du Petrole Process for removing mercury from a gas or a liquid by absorption on a copper sulfide containing solid mass
US20030104937A1 (en) * 2001-11-27 2003-06-05 Sinha Rabindra K. In-situ generation of special sorbents in combustion gases for the removal of mercury and other pollutants present in them
US7048781B1 (en) * 2002-10-07 2006-05-23 Ada Technologies, Inc. Chemically-impregnated silicate agents for mercury control
US20070122327A1 (en) * 2005-11-30 2007-05-31 Yang Xiaolin D Pollutant emission control sorbents and methods of manufacture

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4708853A (en) * 1983-11-03 1987-11-24 Calgon Carbon Corporation Mercury adsorbent carbon molecular sieves and process for removing mercury vapor from gas streams
US4909926A (en) 1989-02-01 1990-03-20 Mobil Oil Corporation Method for removing mercury from hydrocarbon oil by high temperature reactive adsorption
US5281258A (en) * 1992-12-21 1994-01-25 Uop Removal of mercury impurity from natural gas
JP3985291B2 (ja) * 1996-12-11 2007-10-03 東ソー株式会社 燃焼排ガス中の水銀除去方法
US6439138B1 (en) * 1998-05-29 2002-08-27 Hamon Research-Cottrell, Inc. Char for contaminant removal in resource recovery unit
FR2832141B1 (fr) * 2001-11-14 2004-10-01 Ceca Sa Procede de purification de gaz de synthese
US7416716B2 (en) * 2005-11-28 2008-08-26 Air Products And Chemicals, Inc. Purification of carbon dioxide
US20070234902A1 (en) * 2006-03-29 2007-10-11 Fair David L Method for mercury removal from flue gas streams
US7585476B2 (en) * 2006-04-13 2009-09-08 Babcock & Wilcox Power Generation Group Inc. Process for controlling the moisture concentration of a combustion flue gas
US7708804B2 (en) * 2007-07-11 2010-05-04 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and apparatus for the separation of a gaseous mixture

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4094777A (en) * 1975-12-18 1978-06-13 Institut Francais Du Petrole Process for removing mercury from a gas or a liquid by absorption on a copper sulfide containing solid mass
US20030104937A1 (en) * 2001-11-27 2003-06-05 Sinha Rabindra K. In-situ generation of special sorbents in combustion gases for the removal of mercury and other pollutants present in them
US7048781B1 (en) * 2002-10-07 2006-05-23 Ada Technologies, Inc. Chemically-impregnated silicate agents for mercury control
US20070122327A1 (en) * 2005-11-30 2007-05-31 Yang Xiaolin D Pollutant emission control sorbents and methods of manufacture

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SANGRAS, R., CHATEL-PELAGE, F., PRANDA, P. ET AL.: "Oxycombustion process in pulverized coal-fired boilers: a promising technology for CO2 capture", THE 29TH INTERNATIONAL CONFERENCE ON COAL UTILIZATION AND FUEL SYSTEMS, 2004, Clearwater, FL, pages 1 - 12, XP002471956 *

Also Published As

Publication number Publication date
JP2010533064A (ja) 2010-10-21
FR2918580A1 (fr) 2009-01-16
US8535416B2 (en) 2013-09-17
CA2693038A1 (fr) 2009-01-22
AU2008277537A1 (en) 2009-01-22
US20100212494A1 (en) 2010-08-26
CN101842144A (zh) 2010-09-22
FR2918580B1 (fr) 2010-01-01
EP2178622A2 (fr) 2010-04-28
AU2008277537B2 (en) 2012-09-06
WO2009010692A2 (fr) 2009-01-22

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