WO2009009886A1 - Compositions de bouillie d'agent de soutènement enrobé de résine et leurs procédés de préparation et d'utilisation - Google Patents
Compositions de bouillie d'agent de soutènement enrobé de résine et leurs procédés de préparation et d'utilisation Download PDFInfo
- Publication number
- WO2009009886A1 WO2009009886A1 PCT/CA2008/001293 CA2008001293W WO2009009886A1 WO 2009009886 A1 WO2009009886 A1 WO 2009009886A1 CA 2008001293 W CA2008001293 W CA 2008001293W WO 2009009886 A1 WO2009009886 A1 WO 2009009886A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- resin coated
- proppant
- slurry composition
- proppants
- slurry
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/80—Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
- C09K8/805—Coated proppants
Definitions
- This invention relates to proppant sand slurry compositions and methods of making and using the same.
- Hydraulic fracturing operations are used routinely to increase oil and gas production.
- a fracturing fluid is injected through a wellbore into a subterranean formation at a pressure sufficient to initiate a fracture to increase oil and gas production.
- particulates called proppants
- Proppants include sand, resin coated proppants, ceramic particles, glass spheres, bauxite (aluminum oxide), and the like. Among them, sand is by far the most commonly used proppant.
- Fracturing fluids in common use include various aqueous and hydrocarbon gels.
- Liquid carbon dioxide and nitrogen gas are also used in fracturing treatments.
- the most commonly used fracturing fluids are aqueous fluids containing cross-linked polymers to initiate fractures in the formation and effectively transport proppants into the fractures.
- fracturing fluid is flowed back to surface and proppants are left in the fracture to prevent it from closing back after pressure is released.
- the proppant-filled fracture provides a high conductive channel that allows oil and/ or gas to seep through to the wellbore more efficiently.
- the conductivity of the proppant pack plays a dominant role in increasing oil and gas production.
- polymer residues from polymer fracturing fluids greatly reduce the conductivity of the proppant-pack.
- resin coated proppant is also commonly used in fracturing treatments, especially, to mitigate proppant flowback after a fracturing treatment.
- the outer surfaces of the resin-coated proppants have an adherent resin coating so that the proppant grains can be bonded to each other under suitable conditions forming a permeable barrier.
- the substrate materials for the resin-coated proppants include sand, glass beads and organic materials such as shells or seeds.
- the resins used include epoxy, urea aldehyde, phenol-aldehyde, furfural alcohol and furfural.
- the resin-coated proppants can be either pre-cured or can be cured by an overflush of a chemical binding agent, commonly known as activator, which often contains a surfactant.
- activator which often contains a surfactant.
- Different binding agents have been used.
- United States Patents 3,492,147 and 3,935,339 disclose compositions and methods of coating solid particulates with different resins.
- the particulates which can be coated include sand, nut shells, glass beads, and aluminum pellets.
- the resins used include urea-aldehyde resms, phenol-aldehyde resms, epoxy resms, furfuryl alcohol resins, and polyester or alkyl resins
- the resms can be in pure form or mixtures containing curing agents, coupling agents or other additives
- the resin coated proppants are pumped mto the near-wellbore formation in the last portion of the sand stage to form a permeable barrier
- Flotation has been used m mmerals engineering for the separation of fmely ground valuable mmerals from other mmerals Crude ore is ground to fine powder and mixed with water, collecting reagents and, optionally, frothing reagents When air is blown through the mixture, hydrophobic mineral particles clmg to the bubbles, which rise to form froth on the surface The waste material (gangue) settles to the bottom The froth is skimmed off, and the water and chemicals are removed, leavmg a clean concentrate The process, also called the froth- flotation process, is used for a number of minerals
- the primary mechanism m such a flotation process is the selective aggregation of micro-bubbles with hydrophobic particles under dynamic conditions to lift the particles to the liquid surface
- the minerals and their associated gangue usually do not have sufficient hydrophobicity to allow bubbles to attach
- Collecting agents known as collectors
- Frothers are chemical agents added to the mixture to promote the generation of semi- stable froth
- the undesired minerals, such as silica sand are floated away from the valuable minerals which remam m the tailings
- the reverse flotation of silica is widely used in processing iron as well as phosphate ores
- a wide variety of chemical agents are useful as collectors and frothers for flotation of silica particles
- Amines such as simple primary and secondary ammes, primary ether amme and ether diammes, tallow ammes and tall oil fatty acid/ amine condensates are known to be useful collectors for silica particles It is well established that these chemical compounds strongly adsorb to sand surface and change the sand surface from hydrophilic to hydrophobic to allow form stable sand/ bubbles aggregations
- the preferred collectors are amine collectors having at least about twelve carbon atoms
- Collectors useful in the present invention are ammes including simple primary and secondary ammes, primary ether amine and ether diammes, tallow ammes and tall oil fatty acid/ amine condensates Examples of such collectors include propanamme, 3-nonyloxy-, 1,3-propanediamine, N-tridecyloxy-3,l-propanediyl-, the condensate of diethylenetetraamine
- Compounds useful as frothers mclude low molecular weight alcohols including methyl isobutyl carbmol (MIBC), amyl, hexyl, hepryl and octyl, and diethyl isohexyl alcohols, pme oil and glycol ethers
- the collectors and frothers can be used alone or in combination
- the collectors and frothers can be used alone or in combination.
- small amount of isooctane or kerosene can be used alone or in combined with pine oil, or small quantity of MIBC or pine oil or hexyl alcohol can acts as both collector and frother in coal flotation.
- a slurry composition including resin coated proppant and an aqueous liquid.
- a slurry composition including resin coated proppant, sand and an aqueous liquid.
- a slurry composition including resin coated proppant, an aqueous liquid and a collector.
- a slurry composition including resin coated proppant, sand, an aqueous liquid and a collector.
- a slurry composition including resin coated proppant, an aqueous liquid and a frother.
- a slurry composition including resin coated proppant, sand, an aqueous liquid and a frother.
- the slurry composition can be used in different applications including hydraulic fracturing, wellbore clean out, sand control operations in unconsolidated formations.
- the present invention relates to a method of making a resin coated proppant slurry composition, the method comprising the steps of: introducing resin coated proppants; mixing the resin coated proppants with an aqueous liquid; and attaching micro- bubbles of sufficient stability to a resin coated proppant surface; wherein the fluidity of the resin coated proppant slurry is increased and transportation of the resin coated proppants is facilitated.
- the present invention relates to a method of making a resin coated proppant slurry composition, the method comprising the steps of: introducing resin coated proppants; mixing the resin coated proppants with an aqueous liquid; and creating a plurality of cavities among neighbouring resin coated proppants; wherein the fluidity of the resin coated proppant slurry is increased and transportation of the resin coated proppants is facilitated.
- the present invention is directed to improving slurry fluidity and stability by "lifting" the proppants instead of suspending them by the liquid medium.
- the lift is achieved by attaching micro-bubbles of sufficient stability to the resin coated proppant surface.
- cavities are created among neighboring resin coated proppant grains. The micro-bubbles or cavities attached to the resin coated proppant surfaces help lift them up, due to the resulting increased buoyancy.
- the basic principle of flotation is applied to the preparation of aqueous resin coated proppant slurries for transporting the resin coated proppant, which has wide applications, especially in oil field. These applications include hydraulic fracturing, proppant flowback control, wellbore cleanout, sand control operation in unconsolidated formations, sand cleanout in pipeline and sand jetting.
- the resin coated proppants used in these applications typically range in size from 10 to about 100 mesh. AU these applications generally are carried out under dynamic conditions, where turbulence normally exists.
- the surfaces of resin coated proppant grains are hydrophobic, while the hydrophobicity can vary from different surface coating.
- the hydrophobic surface of the resin coated proppant promotes aggregation with micro-bubbles in an aqueous liquid, particularly under dynamic conditions.
- the term of the aqueous liquid includes water, water containing certain amount of organic or inorganic salts, and water containing small amounts of alcohols or other organic solvents.
- the aggregation with bubbles provides the resin coated proppants with increased buoyancy and therefore greatly improves the fluidity and stability of the slurry, without employing the viscosifiers
- resm coated proppant slurries can be mixed with water under high agitation, preferably m the presence of gas such as air, nitrogen or carbon dioxide while pumping into a well
- gas such as air, nitrogen or carbon dioxide
- surfactants which are normally anionic or non-ionic surfactants or mixtures of surfactants, are added mto the fracturing fluid to enhance the flow back of the fracturing fluid after the treatment, by reducing the surface tension of the fluid as low as possible
- surfactants which are normally anionic or non-ionic surfactants or mixtures of surfactants
- the collectors have stronger tendency to adsorb on the particulate surfaces than to disperse or dissolve in the aqueous liquid
- the addition of the collectors or frothers or their mixtures is generally very small, in the order of ppm
- the addition of the collectors or the frothers or their combination enhances the bubble attachment to the particulate surfaces and therefore increases the floatability of the resm coated proppants
- the slurry compositions according to the present invention can fmd many applications, for example, they can be used to effectively transport the resin coated proppants into the fractures durmg the hydraulic fracturing operations
- the resm coated proppant slurries can be prepared at the surface or under a subterranean formation in situ where the proppant, the aqueous fluid, and a frother, such as hexylalcohol are mixed together under dynamic situations
- a collector or a frother or a collector/ frother mixture can be added into water and mixed with the resin coated proppant as slurry under high pumping rate to transport the proppant into formation
- the resm coated proppant and sand are used together
- nitrogen or carbon dioxide gas is mixed into the slurry
- water containing the collector is mixed with resm coated proppant, for example, resm coated sand, in situ at high flow rate and carries the proppant out the wellbore
- nitrogen or carbon dioxide gas can be mixed with the fluid
Landscapes
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Cosmetics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200880024987A CN101755028A (zh) | 2007-07-18 | 2008-07-15 | 树脂涂层支撑剂悬浮液混合物及其制备和使用方法 |
MX2010000682A MX2010000682A (es) | 2007-07-18 | 2008-07-15 | Metodos para elaborar una composicion de la suspension espesa de agente sustentante, y composicion obtenida. |
BRPI0814608-0A2A BRPI0814608A2 (pt) | 2007-07-18 | 2008-07-15 | Composições de lodo propelente revestido com resina e métodos de produção e uso das mesmas |
EA201070155A EA201070155A1 (ru) | 2007-07-18 | 2008-07-15 | Композиции суспензий расклинивающего наполнителя, имеющего нанесенное покрытие из смолы, и способы их получения |
US12/669,178 US20100256024A1 (en) | 2007-07-18 | 2008-07-15 | Resin coated proppant slurry compositions and methods of making and using same |
CA2693427A CA2693427C (fr) | 2007-07-18 | 2008-07-15 | Compositions de bouillie d'agent de soutenement enrobe de resine et leurs procedes de preparation et d'utilisation |
AU2008278232A AU2008278232A1 (en) | 2007-07-18 | 2008-07-15 | Resin coated proppant slurry compositions and methods of making and using same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US92993307P | 2007-07-18 | 2007-07-18 | |
US60/929,933 | 2007-07-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009009886A1 true WO2009009886A1 (fr) | 2009-01-22 |
Family
ID=40259252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA2008/001293 WO2009009886A1 (fr) | 2007-07-18 | 2008-07-15 | Compositions de bouillie d'agent de soutènement enrobé de résine et leurs procédés de préparation et d'utilisation |
Country Status (9)
Country | Link |
---|---|
US (1) | US20100256024A1 (fr) |
CN (1) | CN101755028A (fr) |
AR (1) | AR067582A1 (fr) |
AU (1) | AU2008278232A1 (fr) |
BR (1) | BRPI0814608A2 (fr) |
CA (1) | CA2693427C (fr) |
EA (1) | EA201070155A1 (fr) |
MX (1) | MX2010000682A (fr) |
WO (1) | WO2009009886A1 (fr) |
Cited By (7)
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---|---|---|---|---|
WO2012025800A2 (fr) * | 2010-08-25 | 2012-03-01 | Schlumberber Technology B.V. | Mise en place d'une matière particulaire sous terre |
WO2012025799A2 (fr) * | 2010-08-25 | 2012-03-01 | Schlumberger Technology B.V. (Stbv) | Mise en place d'une matière particulaire sous terre |
US8448706B2 (en) | 2010-08-25 | 2013-05-28 | Schlumberger Technology Corporation | Delivery of particulate material below ground |
US8714248B2 (en) | 2010-08-25 | 2014-05-06 | Schlumberger Technology Corporation | Method of gravel packing |
WO2015148836A1 (fr) * | 2014-03-28 | 2015-10-01 | Arr-Maz Products, L.P. | Composite formant agent de soutènement résistant à l'abrasion et ses matières de composition |
US10421897B2 (en) | 2015-11-30 | 2019-09-24 | Schlumberger Technology Corporation | Method of treating a well with the formation of proppant structures (variants) |
US10508231B2 (en) | 2014-03-28 | 2019-12-17 | Arr-Maz Products, L.P. | Attrition resistant proppant composite and its composition matters |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9714371B2 (en) | 2005-05-02 | 2017-07-25 | Trican Well Service Ltd. | Method for making particulate slurries and particulate slurry compositions |
CA2585065A1 (fr) * | 2007-04-13 | 2008-10-13 | Trican Well Service Ltd. | Compositions de boues sablonneuses a particules aqueuses et procedes de preparation |
WO2008131540A1 (fr) | 2007-04-26 | 2008-11-06 | Trican Well Service Ltd | Réduction de l'entraînement particulaire par des fluides |
CA2777748C (fr) * | 2009-10-20 | 2017-09-19 | Soane Energy Llc | Agents de soutenement pour techniques de fracturation hydraulique |
RU2472837C2 (ru) * | 2010-12-02 | 2013-01-20 | Открытое акционерное общество "Боровичский комбинат огнеупоров" | Легкий проппант |
CN103764948B (zh) | 2011-08-31 | 2018-05-18 | 自悬浮支撑有限公司 | 用于水力破碎的自-悬浮支撑剂 |
US20140000891A1 (en) | 2012-06-21 | 2014-01-02 | Self-Suspending Proppant Llc | Self-suspending proppants for hydraulic fracturing |
US9868896B2 (en) | 2011-08-31 | 2018-01-16 | Self-Suspending Proppant Llc | Self-suspending proppants for hydraulic fracturing |
US9297244B2 (en) | 2011-08-31 | 2016-03-29 | Self-Suspending Proppant Llc | Self-suspending proppants for hydraulic fracturing comprising a coating of hydrogel-forming polymer |
US8795766B1 (en) | 2012-02-23 | 2014-08-05 | Fabian Ros | Sand temperature and flow control system for a sand coating process |
DK2722378T3 (en) * | 2012-10-18 | 2015-08-31 | Linde Ag | A method for fracturing or fracking of a well |
US9932521B2 (en) | 2014-03-05 | 2018-04-03 | Self-Suspending Proppant, Llc | Calcium ion tolerant self-suspending proppants |
CA2889374A1 (fr) | 2014-04-25 | 2015-10-25 | Trican Well Service Ltd. | Composes et methodes de fabrication de boues aqueuses |
CA2856942A1 (fr) | 2014-07-16 | 2016-01-16 | Trican Well Service Ltd. | Boue aqueuse servant au transport de particules |
CA2880646A1 (fr) * | 2015-01-30 | 2016-07-30 | Trican Well Service Ltd. | Composition et methode d'utilisation d'huiles naturelles polymerisables en vue du traitement d'agents de soutenement |
CN105754580B (zh) * | 2016-03-25 | 2018-09-11 | 山东诺尔生物科技有限公司 | 压裂用低摩阻自悬浮支撑剂的制备方法 |
CN106248537B (zh) * | 2016-08-30 | 2018-08-24 | 重庆长江造型材料(集团)股份有限公司 | 自悬浮支撑剂悬浮性能检测仪器 |
CN106967410A (zh) * | 2017-01-20 | 2017-07-21 | 北京清水兰德油田技术服务有限公司 | 一种树脂悬浮剂组合物及其应用 |
US11713415B2 (en) | 2018-11-21 | 2023-08-01 | Covia Solutions Inc. | Salt-tolerant self-suspending proppants made without extrusion |
CN111286318A (zh) * | 2020-04-07 | 2020-06-16 | 赣江新区澳博颗粒科技研究院有限公司 | 一种压裂用自生气泡悬浮支撑剂及其施工方法 |
CN114479823B (zh) * | 2021-12-31 | 2023-06-20 | 宁波锋成先进能源材料研究院有限公司 | 一种压裂支撑剂及其制备方法与应用 |
CN115324541B (zh) * | 2022-08-22 | 2023-04-18 | 大庆信辰油田技术服务有限公司 | 一种微纳二氧化碳气水混液驱油方法 |
CN116640566A (zh) * | 2023-05-19 | 2023-08-25 | 四川省威沃敦化工有限公司 | 一种压裂用支撑剂改性剂的制备方法 |
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US4725351A (en) * | 1986-09-29 | 1988-02-16 | International Minerals & Chemical Corp. | Collecting agents for use in the froth flotation of silica-containing ores |
CA2509115A1 (fr) * | 2004-06-15 | 2005-12-15 | Halliburton Energy Services, Inc. | Methodes de revetement de resine et de melange d'agent de soutenement enduit de resine |
CA2545563A1 (fr) * | 2005-05-02 | 2006-11-02 | Trican Well Service Ltd. | Methode pour produire des boues de particules et compositions de boues de particules |
US20070144736A1 (en) * | 2005-12-28 | 2007-06-28 | Shinbach Madeline P | Low density proppant particles and use thereof |
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US4964465A (en) * | 1989-11-06 | 1990-10-23 | Texaco Inc. | Method employing liquidized sand for controlling lost circulation of drilling fluids |
FR2695558B1 (fr) * | 1992-09-11 | 1994-10-21 | Oreal | Composition cosmétique contenant des particules solides revêtues avec un polymère amphotère. |
US6772838B2 (en) * | 1996-11-27 | 2004-08-10 | Bj Services Company | Lightweight particulate materials and uses therefor |
US7135231B1 (en) * | 2003-07-01 | 2006-11-14 | Fairmont Minerals, Ltd. | Process for incremental coating of proppants for hydraulic fracturing and proppants produced therefrom |
US20050194142A1 (en) * | 2004-03-05 | 2005-09-08 | Nguyen Philip D. | Compositions and methods for controlling unconsolidated particulates |
-
2008
- 2008-07-15 CN CN200880024987A patent/CN101755028A/zh active Pending
- 2008-07-15 BR BRPI0814608-0A2A patent/BRPI0814608A2/pt not_active IP Right Cessation
- 2008-07-15 CA CA2693427A patent/CA2693427C/fr not_active Expired - Fee Related
- 2008-07-15 MX MX2010000682A patent/MX2010000682A/es unknown
- 2008-07-15 US US12/669,178 patent/US20100256024A1/en not_active Abandoned
- 2008-07-15 WO PCT/CA2008/001293 patent/WO2009009886A1/fr active Application Filing
- 2008-07-15 AU AU2008278232A patent/AU2008278232A1/en not_active Abandoned
- 2008-07-15 EA EA201070155A patent/EA201070155A1/ru unknown
- 2008-07-17 AR ARP080103076A patent/AR067582A1/es unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US4725351A (en) * | 1986-09-29 | 1988-02-16 | International Minerals & Chemical Corp. | Collecting agents for use in the froth flotation of silica-containing ores |
CA2509115A1 (fr) * | 2004-06-15 | 2005-12-15 | Halliburton Energy Services, Inc. | Methodes de revetement de resine et de melange d'agent de soutenement enduit de resine |
CA2545563A1 (fr) * | 2005-05-02 | 2006-11-02 | Trican Well Service Ltd. | Methode pour produire des boues de particules et compositions de boues de particules |
US20070144736A1 (en) * | 2005-12-28 | 2007-06-28 | Shinbach Madeline P | Low density proppant particles and use thereof |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9234415B2 (en) | 2010-08-25 | 2016-01-12 | Schlumberger Technology Corporation | Delivery of particulate material below ground |
WO2012025800A3 (fr) * | 2010-08-25 | 2012-04-26 | Schlumberber Technology B.V. | Mise en place d'une matière particulaire sous terre |
US9388334B2 (en) | 2010-08-25 | 2016-07-12 | Schlumberger Technology Corporation | Delivery of particulate material below ground |
WO2012025800A2 (fr) * | 2010-08-25 | 2012-03-01 | Schlumberber Technology B.V. | Mise en place d'une matière particulaire sous terre |
US8448706B2 (en) | 2010-08-25 | 2013-05-28 | Schlumberger Technology Corporation | Delivery of particulate material below ground |
US8459353B2 (en) | 2010-08-25 | 2013-06-11 | Schlumberger Technology Corporation | Delivery of particulate material below ground |
US8714248B2 (en) | 2010-08-25 | 2014-05-06 | Schlumberger Technology Corporation | Method of gravel packing |
WO2012025799A3 (fr) * | 2010-08-25 | 2012-04-26 | Schlumberger Technology B.V. (Stbv) | Mise en place d'une matière particulaire sous terre |
WO2012025799A2 (fr) * | 2010-08-25 | 2012-03-01 | Schlumberger Technology B.V. (Stbv) | Mise en place d'une matière particulaire sous terre |
GB2538907B (en) * | 2014-03-28 | 2022-03-23 | Arr Maz Products Lp | Attrition resistant proppant composite and its composition matters |
WO2015148836A1 (fr) * | 2014-03-28 | 2015-10-01 | Arr-Maz Products, L.P. | Composite formant agent de soutènement résistant à l'abrasion et ses matières de composition |
US9969929B2 (en) | 2014-03-28 | 2018-05-15 | Arr-Maz Products, L.P. | Attrition resistant proppant composite and its composition matters |
RU2702039C2 (ru) * | 2014-03-28 | 2019-10-03 | АРР-МАЗ ПРОДАКТС, Эл.Пи. | Стойкий к истиранию композиционный пропант и его компоненты |
US10435624B2 (en) | 2014-03-28 | 2019-10-08 | Arr-Maz Products, L.P. | Attrition resistant proppant composite and its composition matters |
US10508231B2 (en) | 2014-03-28 | 2019-12-17 | Arr-Maz Products, L.P. | Attrition resistant proppant composite and its composition matters |
US10731074B2 (en) | 2014-03-28 | 2020-08-04 | Arr-Maz Products, L.P. | Attrition resistant proppant composite and its composition matters |
GB2538907A (en) * | 2014-03-28 | 2016-11-30 | Arr-Maz Products L P | Attrition resistant proppant composite and its composition matters |
US10421897B2 (en) | 2015-11-30 | 2019-09-24 | Schlumberger Technology Corporation | Method of treating a well with the formation of proppant structures (variants) |
Also Published As
Publication number | Publication date |
---|---|
AR067582A1 (es) | 2009-10-14 |
CA2693427C (fr) | 2016-03-08 |
MX2010000682A (es) | 2010-03-30 |
BRPI0814608A2 (pt) | 2015-01-27 |
CA2693427A1 (fr) | 2009-01-22 |
AU2008278232A1 (en) | 2009-01-22 |
CN101755028A (zh) | 2010-06-23 |
EA201070155A1 (ru) | 2010-06-30 |
US20100256024A1 (en) | 2010-10-07 |
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