WO2008132962A1 - オレフィンメタセシス触媒及びそれを用いたメタセシス反応によるオレフィン反応生成物の製造方法 - Google Patents

オレフィンメタセシス触媒及びそれを用いたメタセシス反応によるオレフィン反応生成物の製造方法 Download PDF

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Publication number
WO2008132962A1
WO2008132962A1 PCT/JP2008/056749 JP2008056749W WO2008132962A1 WO 2008132962 A1 WO2008132962 A1 WO 2008132962A1 JP 2008056749 W JP2008056749 W JP 2008056749W WO 2008132962 A1 WO2008132962 A1 WO 2008132962A1
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WIPO (PCT)
Prior art keywords
olefin
reaction
catalyst
reaction product
metathesis
Prior art date
Application number
PCT/JP2008/056749
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English (en)
French (fr)
Inventor
Hisahiro Hagiwara
Original Assignee
Niigata University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Niigata University filed Critical Niigata University
Priority to JP2009511736A priority Critical patent/JP5156010B2/ja
Publication of WO2008132962A1 publication Critical patent/WO2008132962A1/ja

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

安定性が高く、高次のリサイクル使用が可能な、新規のオレフィンメタセシス触媒を提供する。このオレフィンメタセシス触媒を用いたメタセシス反応によるオレフィン反応生成物の製造方法を提供する。イオン液体に溶解したカルベン錯体を多孔質担体に固定化させた。好ましくは、多孔質担体は、表面修飾していない無定形アルミナ、３－アミノプロピル残基で表面修飾した無定形アルミナのいずれかであり、イオン液体は、１－ヘキシル－３－メチルイミダゾリウムヘキサフルオロホスフェート、１－ブチル－３－メチルイミダゾリウムヘキサフルオロホスフェートのいずれかである。このオレフィンメタセシス触媒の存在下において、オレフィン類基質をメタセシス反応させてオレフィン反応生成物を製造する。
PCT/JP2008/056749 2007-04-20 2008-04-04 オレフィンメタセシス触媒及びそれを用いたメタセシス反応によるオレフィン反応生成物の製造方法 WO2008132962A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009511736A JP5156010B2 (ja) 2007-04-20 2008-04-04 オレフィンメタセシス触媒及びそれを用いたメタセシス反応によるオレフィン反応生成物の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007111730 2007-04-20
JP2007-111730 2007-04-20

Publications (1)

Publication Number Publication Date
WO2008132962A1 true WO2008132962A1 (ja) 2008-11-06

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Family Applications (1)

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PCT/JP2008/056749 WO2008132962A1 (ja) 2007-04-20 2008-04-04 オレフィンメタセシス触媒及びそれを用いたメタセシス反応によるオレフィン反応生成物の製造方法

Country Status (2)

Country Link
JP (1) JP5156010B2 (ja)
WO (1) WO2008132962A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009178612A (ja) * 2008-01-29 2009-08-13 Niigata Univ アジド−アルキン付加環化反応触媒及びそれを用いたトリアゾール化合物の製造方法
DE102009017498A1 (de) * 2009-04-16 2010-10-28 Süd-Chemie AG Verwendung einer Katalysatorzusammensetzung zur Olefinmetathese in der Gasphase und Verfahren zur Olefinmetathese in der Gasphase
JP2014517768A (ja) * 2011-05-10 2014-07-24 サウジ アラビアン オイル カンパニー オレフィンメタセシスのためのハイブリッド触媒
CN111378007A (zh) * 2020-05-08 2020-07-07 杭州勇诚睿生物科技有限公司 一种采用第二代Hoveyda-Grubbs催化剂制备帕利普韦的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007501695A (ja) * 2003-08-11 2007-02-01 メルク　パテント　ゲゼルシャフト　ミット　ベシュレンクテル　ハフトング 固定化イミダゾールおよびルテニウム触媒

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE444273T1 (de) * 2005-05-20 2009-10-15 Wacker Chemie Ag Verfahren zur kontinuierlichen carbonylierung durch geträgerte ionische flüssigphasenkatalyse
US8648003B2 (en) * 2006-04-11 2014-02-11 Agency For Science, Technology And Research Catalysts for ring-closing metathesis

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007501695A (ja) * 2003-08-11 2007-02-01 メルク　パテント　ゲゼルシャフト　ミット　ベシュレンクテル　ハフトング 固定化イミダゾールおよびルテニウム触媒

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
HAGIWARA H. ET AL.: "Pd-SILC o Mochiiru Kankyo Taio Gata Suzuki-Miyaura coupling Han'no", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 87, no. 2, 12 March 2007 (2007-03-12), pages 1055 *
HAGIWARA H.: "Ion Ekitai no Kaihatsu no Oyo Ion Ekitai Koteika Shokubai (SILC) no Kaihatsu", FUNCTION & MATERIALS, vol. 27, no. 10, 5 September 2007 (2007-09-05), pages 23 - 32 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009178612A (ja) * 2008-01-29 2009-08-13 Niigata Univ アジド−アルキン付加環化反応触媒及びそれを用いたトリアゾール化合物の製造方法
DE102009017498A1 (de) * 2009-04-16 2010-10-28 Süd-Chemie AG Verwendung einer Katalysatorzusammensetzung zur Olefinmetathese in der Gasphase und Verfahren zur Olefinmetathese in der Gasphase
JP2014517768A (ja) * 2011-05-10 2014-07-24 サウジ アラビアン オイル カンパニー オレフィンメタセシスのためのハイブリッド触媒
JP2018051559A (ja) * 2011-05-10 2018-04-05 サウジ アラビアン オイル カンパニー ハイブリッドオレフィンメタセシス触媒を調製する方法
CN111378007A (zh) * 2020-05-08 2020-07-07 杭州勇诚睿生物科技有限公司 一种采用第二代Hoveyda-Grubbs催化剂制备帕利普韦的方法
CN111378007B (zh) * 2020-05-08 2022-04-12 杭州濡湜生物科技有限公司 一种采用第二代Hoveyda-Grubbs催化剂制备帕利普韦的方法

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Publication number Publication date
JP5156010B2 (ja) 2013-03-06
JPWO2008132962A1 (ja) 2010-07-22

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