WO2008126844A1 - Catalyst for reforming oxygen-containing hydrocarbon, and hydrogen or synthetic gas production method and fuel cell system using the catalyst - Google Patents

Catalyst for reforming oxygen-containing hydrocarbon, and hydrogen or synthetic gas production method and fuel cell system using the catalyst Download PDF

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Publication number
WO2008126844A1
WO2008126844A1 PCT/JP2008/056952 JP2008056952W WO2008126844A1 WO 2008126844 A1 WO2008126844 A1 WO 2008126844A1 JP 2008056952 W JP2008056952 W JP 2008056952W WO 2008126844 A1 WO2008126844 A1 WO 2008126844A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
reforming
fuel cell
oxygen
hydrogen
Prior art date
Application number
PCT/JP2008/056952
Other languages
French (fr)
Japanese (ja)
Inventor
Kajornsak Faungnawakij
Koichi Eguchi
Ryuji Kikuchi
Tetsuya Fukunaga
Original Assignee
Japan Science And Technology Agency
Kyoto University
Idemitsu Kosan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2007275772A external-priority patent/JP5178143B2/en
Application filed by Japan Science And Technology Agency, Kyoto University, Idemitsu Kosan Co., Ltd. filed Critical Japan Science And Technology Agency
Priority to CN200880011292A priority Critical patent/CN101715367A/en
Priority to KR1020097020833A priority patent/KR101486095B1/en
Publication of WO2008126844A1 publication Critical patent/WO2008126844A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/17—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

The object is to improve the catalytic activity of reforming an oxygen-containing hydrocarbon of a cupper-containing metal oxide having a spinel structure, and thus to provide a reforming catalyst having an improved reforming activity and improved durability and a hydrogen or synthetic gas production method and a fuel cell system both using the catalyst. Specifically disclosed are: a catalyst for reforming an oxygen-containing hydrocarbon, which is prepared by the step of firing a mixture of (A) a copper-containing metal oxide having a spinel structure with (B) a solid acid at 300 to 850˚C in an atmosphere containing at least oxygen; a method for producing hydrogen or a synthetic gas, which comprises subjecting an oxygen-containing hydrocarbon to any one of various reforming treatments using the catalyst; and a fuel cell system which comprises a reformer having the catalyst and a fuel cell utilizing hydrogen produced by the reformer as a fuel.
PCT/JP2008/056952 2007-04-11 2008-04-08 Catalyst for reforming oxygen-containing hydrocarbon, and hydrogen or synthetic gas production method and fuel cell system using the catalyst WO2008126844A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN200880011292A CN101715367A (en) 2007-04-11 2008-04-08 Catalyst for reforming oxygen-containing hydrocarbon, method for producing hydrogen or synthesis gas using same, and fuel cell system
KR1020097020833A KR101486095B1 (en) 2007-04-11 2008-04-08 Catalyst for reforming oxygen-containing hydrocarbon, and hydrogen or synthetic gas production method and fuel cell system using the catalyst

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-104227 2007-04-11
JP2007104227 2007-04-11
JP2007275772A JP5178143B2 (en) 2007-04-11 2007-10-23 Oxygen-containing hydrocarbon reforming catalyst, method for producing hydrogen or synthesis gas using the same, and fuel cell system
JP2007-275772 2007-10-23

Publications (1)

Publication Number Publication Date
WO2008126844A1 true WO2008126844A1 (en) 2008-10-23

Family

ID=39863941

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/056952 WO2008126844A1 (en) 2007-04-11 2008-04-08 Catalyst for reforming oxygen-containing hydrocarbon, and hydrogen or synthetic gas production method and fuel cell system using the catalyst

Country Status (1)

Country Link
WO (1) WO2008126844A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013085861A1 (en) * 2011-12-08 2013-06-13 Saudi Basic Industries Corporation Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use
CN112479703A (en) * 2020-11-20 2021-03-12 辽宁石油化工大学 Spinel solid solution material and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003010685A (en) * 2001-06-27 2003-01-14 Nkk Corp Hydrogen manufacturing catalyst, method for manufacturing the same and hydrogen manufacturing method
JP2003010684A (en) * 2001-06-27 2003-01-14 Nkk Corp Catalyst for manufacturing hydrogen and hydrogen manufacturing method
JP2003033656A (en) * 2001-07-25 2003-02-04 Nkk Corp Synthesis gas manufacturing catalyst and method of manufacturing synthesis gas
JP2003320254A (en) * 2002-05-01 2003-11-11 National Institute Of Advanced Industrial & Technology Catalyst for water gas shift reaction and steam reforming reaction of methanol
JP2005342543A (en) * 2003-05-20 2005-12-15 Idemitsu Kosan Co Ltd Oxygen-containing hydrocarbon reforming catalyst, process for producing hydrogen or synthesis gas by using the same and fuel cell system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003010685A (en) * 2001-06-27 2003-01-14 Nkk Corp Hydrogen manufacturing catalyst, method for manufacturing the same and hydrogen manufacturing method
JP2003010684A (en) * 2001-06-27 2003-01-14 Nkk Corp Catalyst for manufacturing hydrogen and hydrogen manufacturing method
JP2003033656A (en) * 2001-07-25 2003-02-04 Nkk Corp Synthesis gas manufacturing catalyst and method of manufacturing synthesis gas
JP2003320254A (en) * 2002-05-01 2003-11-11 National Institute Of Advanced Industrial & Technology Catalyst for water gas shift reaction and steam reforming reaction of methanol
JP2005342543A (en) * 2003-05-20 2005-12-15 Idemitsu Kosan Co Ltd Oxygen-containing hydrocarbon reforming catalyst, process for producing hydrogen or synthesis gas by using the same and fuel cell system

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KIKUCHI T. ET AL.: "Cu-kei Spinel Shokubai ni yoru Dimethyl Ether no Suijoki Kaishitsu Hanno", SHOKUBAI, vol. 48, no. 6, 2006, pages 458 - 460 *
TANAKA Y. ET AL.: "Cu-Mn-Fe-kei Sankabutsu to Al2O3 no Kongo Shokubai ni yoru Dimethyl Ether no Suijoki Kaishitsu Hanno", 94TH SHOKUBAI TORONKAI TORONAKI A YOKOSHU, 2004, pages 390 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013085861A1 (en) * 2011-12-08 2013-06-13 Saudi Basic Industries Corporation Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use
US8962702B2 (en) 2011-12-08 2015-02-24 Saudi Basic Industries Corporation Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use
CN112479703A (en) * 2020-11-20 2021-03-12 辽宁石油化工大学 Spinel solid solution material and preparation method and application thereof

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