WO2008099847A1 - Reforming catalyst for oxygen-containing hydrocarbon, method for producing hydrogen or synthetic gas using the same, and fuel cell system - Google Patents

Reforming catalyst for oxygen-containing hydrocarbon, method for producing hydrogen or synthetic gas using the same, and fuel cell system Download PDF

Info

Publication number
WO2008099847A1
WO2008099847A1 PCT/JP2008/052347 JP2008052347W WO2008099847A1 WO 2008099847 A1 WO2008099847 A1 WO 2008099847A1 JP 2008052347 W JP2008052347 W JP 2008052347W WO 2008099847 A1 WO2008099847 A1 WO 2008099847A1
Authority
WO
WIPO (PCT)
Prior art keywords
reforming catalyst
fuel cell
cell system
synthetic gas
producing hydrogen
Prior art date
Application number
PCT/JP2008/052347
Other languages
French (fr)
Japanese (ja)
Inventor
Kajornsak Faungnawakij
Koichi Eguchi
Ryuji Kikuchi
Tetsuya Fukunaga
Original Assignee
Japan Science And Technology Agency
Kyoto University
Idemitsu Kosan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Science And Technology Agency, Kyoto University, Idemitsu Kosan Co., Ltd. filed Critical Japan Science And Technology Agency
Publication of WO2008099847A1 publication Critical patent/WO2008099847A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1223—Methanol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Disclosed is a reforming catalyst used in a method for producing hydrogen or a synthetic gas, which essentially contains copper and further contains at least one element selected from nickel, cobalt and platinum group elements. These elements are present in the form of metal oxides, and at least a part of the metal oxides has a spinel structure. This reforming catalyst is excellent in heat resistance, while being greatly improved in the activity per unit surface area. Such an excellent reforming catalyst enables to obtain an excellent fuel cell system.
PCT/JP2008/052347 2007-02-16 2008-02-13 Reforming catalyst for oxygen-containing hydrocarbon, method for producing hydrogen or synthetic gas using the same, and fuel cell system WO2008099847A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007036203 2007-02-16
JP2007237765A JP2008221200A (en) 2007-02-16 2007-09-13 Reforming catalyst of oxygen-containing hydrocarbon, manufacturing method of hydrogen or synthetic gas using it and fuel cell system
JP2007-237765 2007-09-13
JP2007-036203 2007-12-28

Publications (1)

Publication Number Publication Date
WO2008099847A1 true WO2008099847A1 (en) 2008-08-21

Family

ID=39690075

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/052347 WO2008099847A1 (en) 2007-02-16 2008-02-13 Reforming catalyst for oxygen-containing hydrocarbon, method for producing hydrogen or synthetic gas using the same, and fuel cell system

Country Status (5)

Country Link
JP (1) JP2008221200A (en)
KR (1) KR20090115709A (en)
CN (1) CN101541424A (en)
TW (1) TW200846281A (en)
WO (1) WO2008099847A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150148216A1 (en) * 2013-11-26 2015-05-28 Clean Diesel Technologies, Inc. Spinel compositions and applications thereof
CN105854744A (en) * 2016-05-17 2016-08-17 浙江大学 Magnetic nanoparticle/SiO2 aerogel and preparation method thereof and method for treating high level liquid waste
US9511353B2 (en) 2013-03-15 2016-12-06 Clean Diesel Technologies, Inc. (Cdti) Firing (calcination) process and method related to metallic substrates coated with ZPGM catalyst
US9511355B2 (en) 2013-11-26 2016-12-06 Clean Diesel Technologies, Inc. (Cdti) System and methods for using synergized PGM as a three-way catalyst
US9511350B2 (en) 2013-05-10 2016-12-06 Clean Diesel Technologies, Inc. (Cdti) ZPGM Diesel Oxidation Catalysts and methods of making and using same
US9545626B2 (en) 2013-07-12 2017-01-17 Clean Diesel Technologies, Inc. Optimization of Zero-PGM washcoat and overcoat loadings on metallic substrate
US9789471B2 (en) 2013-05-08 2017-10-17 Korea Research Institute Of Chemical Technology Monolith catalyst for carbon dioxide reforming reaction, preparation method for same, and preparation method for synthesis gas using same
WO2023058182A1 (en) * 2021-10-07 2023-04-13 国立大学法人東北大学 Metal oxide having spinel-type crystal structure, method for producing same, carbon dioxide reduction method, and carbon dioxide reduction apparatus

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8828903B2 (en) * 2008-11-10 2014-09-09 Basf Corporation Copper catalyst for dehydrogenation application
JP5659067B2 (en) * 2011-04-04 2015-01-28 住友精化株式会社 Method for producing hydrogen gas
US9314775B2 (en) * 2012-01-19 2016-04-19 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying catalyst and method for producing same
CN104801333B (en) * 2015-03-03 2017-12-19 新奥科技发展有限公司 A kind of preparation method of loading type nickel-based catalyst
KR102186058B1 (en) 2018-05-29 2020-12-03 한국화학연구원 Catalyst Comprising MgO-Al2O3 Hybrid Support and The Method of Preparing Synthesis Gas from Carbon Dioxide Reforming of Alcohol Using the Same
KR102186052B1 (en) 2018-05-29 2020-12-03 한국화학연구원 Catalyst Comprising MgO-Al2O3 Hybrid Support and The Method of Preparing Synthesis Gas from Carbon Dioxide Reforming of Acetone Using the Same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5227085A (en) * 1975-08-27 1977-03-01 Nippon Soken Inc Catalyst for reforming of hydrocarbon fuel
JP2003320254A (en) * 2002-05-01 2003-11-11 National Institute Of Advanced Industrial & Technology Catalyst for water gas shift reaction and steam reforming reaction of methanol
JP2005342543A (en) * 2003-05-20 2005-12-15 Idemitsu Kosan Co Ltd Oxygen-containing hydrocarbon reforming catalyst, process for producing hydrogen or synthesis gas by using the same and fuel cell system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5227085A (en) * 1975-08-27 1977-03-01 Nippon Soken Inc Catalyst for reforming of hydrocarbon fuel
JP2003320254A (en) * 2002-05-01 2003-11-11 National Institute Of Advanced Industrial & Technology Catalyst for water gas shift reaction and steam reforming reaction of methanol
JP2005342543A (en) * 2003-05-20 2005-12-15 Idemitsu Kosan Co Ltd Oxygen-containing hydrocarbon reforming catalyst, process for producing hydrogen or synthesis gas by using the same and fuel cell system

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SHIMODA N. ET AL.: "DME Suijoki Kaishitsu Hanno ni Okeru Cu-Fe Spinel Shokubai no Kassei Oyobi Taikyusei eno Tenkabutsu Koka", DAI 100 KAI CATSJ MEETING TORONKAI A YOKOSHU, September 2007 (2007-09-01), pages 162 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9511353B2 (en) 2013-03-15 2016-12-06 Clean Diesel Technologies, Inc. (Cdti) Firing (calcination) process and method related to metallic substrates coated with ZPGM catalyst
US9789471B2 (en) 2013-05-08 2017-10-17 Korea Research Institute Of Chemical Technology Monolith catalyst for carbon dioxide reforming reaction, preparation method for same, and preparation method for synthesis gas using same
US9511350B2 (en) 2013-05-10 2016-12-06 Clean Diesel Technologies, Inc. (Cdti) ZPGM Diesel Oxidation Catalysts and methods of making and using same
US9545626B2 (en) 2013-07-12 2017-01-17 Clean Diesel Technologies, Inc. Optimization of Zero-PGM washcoat and overcoat loadings on metallic substrate
US20150148216A1 (en) * 2013-11-26 2015-05-28 Clean Diesel Technologies, Inc. Spinel compositions and applications thereof
US9511355B2 (en) 2013-11-26 2016-12-06 Clean Diesel Technologies, Inc. (Cdti) System and methods for using synergized PGM as a three-way catalyst
US9511358B2 (en) * 2013-11-26 2016-12-06 Clean Diesel Technologies, Inc. Spinel compositions and applications thereof
US9555400B2 (en) 2013-11-26 2017-01-31 Clean Diesel Technologies, Inc. Synergized PGM catalyst systems including platinum for TWC application
CN105854744A (en) * 2016-05-17 2016-08-17 浙江大学 Magnetic nanoparticle/SiO2 aerogel and preparation method thereof and method for treating high level liquid waste
CN105854744B (en) * 2016-05-17 2018-09-11 浙江大学 A kind of magnetic nanoparticle/SiO2Aeroge and preparation method thereof and the method for handling high activity liquid waste
WO2023058182A1 (en) * 2021-10-07 2023-04-13 国立大学法人東北大学 Metal oxide having spinel-type crystal structure, method for producing same, carbon dioxide reduction method, and carbon dioxide reduction apparatus

Also Published As

Publication number Publication date
JP2008221200A (en) 2008-09-25
CN101541424A (en) 2009-09-23
KR20090115709A (en) 2009-11-05
TW200846281A (en) 2008-12-01

Similar Documents

Publication Publication Date Title
WO2008099847A1 (en) Reforming catalyst for oxygen-containing hydrocarbon, method for producing hydrogen or synthetic gas using the same, and fuel cell system
Wei et al. CO2 dry reforming of CH4 with Sr and Ni co-doped LaCrO3 perovskite catalysts
Papurello et al. Performance of a solid oxide fuel cell short-stack with biogas feeding
WO2008111570A1 (en) Membrane-electrode assembly and fuel cell using the membrane-electrode assembly
Saidi Performance assessment and evaluation of catalytic membrane reactor for pure hydrogen production via steam reforming of methanol
WO2006091651A3 (en) Proton conducting solid oxide fuel cell systems having temperature swing reforming
Nahar et al. Hydrogen via steam reforming of liquid biofeedstock
EA200901458A1 (en) CATALYTIC HYDROGENIZATION OF CARBON DIOXIDE IN A SYNTHESIS-GAS MIXTURE
Itoh et al. Efficient hydrogen production via methanol steam reforming by preventing back-permeation of hydrogen in a palladium membrane reactor
US20150284651A1 (en) Method and Apparatus for Generating a Methane-Containing Substitute Natural Gas and Related Energy Supply System
WO2007005255A3 (en) System and method for hydrogen production
WO2011009124A3 (en) Catalytic electrode with gradient porosity and catalyst density for fuel cells
EP2335824A4 (en) Method for producing catalyst for reforming tar-containing gas, method for reforming tar and method for regenerating catalyst for reforming tar-containing gas
TW200500138A (en) Oxyhydrocarbon reforming catalyst, process for producing hydrogen or synthetic gas using the same and fuel cell system
WO2008109129A3 (en) Solid fuel volatilization to produce synthesis
ATE526081T1 (en) CATALYST FOR SELECTIVE HYDROGENATION AND METHOD FOR THE PRODUCTION THEREOF
Ioannidou et al. Experimental clarification of the RWGS reaction effect in H2O/CO2 SOEC co-electrolysis conditions
WO2008132313A3 (en) Compact exchanger reactor using a plurality of porous burners
MX283314B (en) Improved preferential oxidation catalyst containing platinum, copper and iron to remove carbon monoxide from a hydrogen-rich gas.
EP1900682A3 (en) Carbon monoxide reducing unit of a reformer for fuel cell
WO2008136480A1 (en) Reforming system, fuel cell system, and its operation method
Lee et al. Cost‐competitive methane steam reforming in a membrane reactor for H 2 production: Technical and economic evaluation with a window of a H 2 selectivity
WO2009048083A1 (en) Catalyst for hydrocarbon reforming and process for producing synthesis gas with the same
Heo et al. Integrative technical, economic, and environmental feasibility analysis for ethane steam reforming in a membrane reactor for H2 production
WO2008050350A3 (en) Methods and systems for producing energy from carbon dioxide

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880000551.0

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08711205

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 1020097002907

Country of ref document: KR

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 08711205

Country of ref document: EP

Kind code of ref document: A1