WO2008110166A1 - Filtre microporeux ayant une source anti-microbienne - Google Patents

Filtre microporeux ayant une source anti-microbienne Download PDF

Info

Publication number
WO2008110166A1
WO2008110166A1 PCT/DK2007/000362 DK2007000362W WO2008110166A1 WO 2008110166 A1 WO2008110166 A1 WO 2008110166A1 DK 2007000362 W DK2007000362 W DK 2007000362W WO 2008110166 A1 WO2008110166 A1 WO 2008110166A1
Authority
WO
WIPO (PCT)
Prior art keywords
fluid
filter
outlet
antimicrobial
microporous
Prior art date
Application number
PCT/DK2007/000362
Other languages
English (en)
Inventor
Mikkel Vestergaard Frandsen
Original Assignee
Vestergaard Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vestergaard Sa filed Critical Vestergaard Sa
Priority to CN2007800529028A priority Critical patent/CN101668580B/zh
Priority to AP2009004999A priority patent/AP3005A/xx
Priority to US12/450,046 priority patent/US20100051527A1/en
Priority to MX2009009608A priority patent/MX2009009608A/es
Priority to EP07785726A priority patent/EP2139590A1/fr
Priority to BRPI0721407A priority patent/BRPI0721407A8/pt
Priority to TW097107917A priority patent/TW200906475A/zh
Priority to AP2009004981A priority patent/AP2454A/xx
Priority to KR1020097021176A priority patent/KR101828603B1/ko
Priority to EP08715574A priority patent/EP2136683A2/fr
Priority to MX2009009609A priority patent/MX2009009609A/es
Priority to BRPI0808473A priority patent/BRPI0808473A8/pt
Priority to PCT/DK2008/000096 priority patent/WO2008110172A2/fr
Priority to CN2008800151998A priority patent/CN101677701B/zh
Priority to KR1020157026464A priority patent/KR20150121188A/ko
Priority to US12/450,042 priority patent/US20100044321A1/en
Publication of WO2008110166A1 publication Critical patent/WO2008110166A1/fr
Priority to IL200805A priority patent/IL200805A0/en
Priority to IL200806A priority patent/IL200806A0/en
Priority to MA32267A priority patent/MA31301B1/fr
Priority to HK10107610.3A priority patent/HK1141215A1/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
    • B01D29/62—Regenerating the filter material in the filter
    • B01D29/66—Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G21/00—Table-ware
    • A47G21/18—Drinking straws or the like
    • A47G21/188—Drinking straws or the like with filters to remove impurities
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G21/00—Table-ware
    • A47G21/18—Drinking straws or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/145—Ultrafiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/18—Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08—Flat membrane modules
    • B01D63/082—Flat membrane modules comprising a stack of flat membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08—Prevention of membrane fouling or of concentration polarisation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • C02F1/002—Processes for the treatment of water whereby the filtration technique is of importance using small portable filters for producing potable water, e.g. personal travel or emergency equipment, survival kits, combat gear
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/40—Adsorbents within the flow path
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/44—Cartridge types
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16—Use of chemical agents
    • B01D2321/168—Use of other chemical agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment

Definitions

  • the present invention relates to a fluid filtration device having a fluid inlet and a fluid outlet and a fluid path between the inlet and the outlet through a microporous filter with a pore size adapted for filtering microbes, for example bacteria and virus by me- chanical particle size separation.
  • halogenated media such as Chlorine or Iodine
  • iodine and iodide is released from a resin to the water in order to deactivate mi- crobes, usually, in relative short contact time and dwell time in the water flowing through the device.
  • the deactivation efficacy is a product of the contact and dwell time and the concentration of halogenated media. The shorter the contact-time and dwell-time, the higher the concentration of halogenated media must be to achieve significant microbe deactivation.
  • halogen-free mechanical filters can be used for microbial purifica- tion by particle size separation.
  • ceramic filters are known in the art, where the filters can be used for water filtration without iodine or chlorine addition.
  • FICL Fairey Industrial Ceramics Limited
  • a halogen-free water filter is disclosed in U.S Patent No. 6,838,005 assigned to Argonide and is commercially available as the product with registered trade name Nanoceram® by the company Argonide®.
  • alumina nanofibres are provided in a porous glass fibre matrix filtering microbes by attachment to the nanofibres.
  • the microbes and anorganic sediments are attracted by the highly electropositive charged alumina and stay permanently, un-releasable in the filter matrix.
  • the shelf life of the filter depends on the level of contaminants in the influent water and the capacity of the filter
  • halogen-free filters are the relatively long lifetime without recharge or exchange of halogen source, and the avoidance of halogen taste and possible health impact of the final, released water.
  • a common disadvantage of these filters has been recognised through experiments, the disadvantage being the formation of a biofilm inside the filters, leading to clogging of the pores and having the risk for release of a substantial amount of microbes from the biofilm in case of membrane rupture.
  • a fluid filtration device having a fluid inlet and a fluid outlet and a fluid path between the inlet and the outlet through a microporous filter with a pore size adapted for filtering bacteria or bacteria and virus by mechanical particle size separation, further comprising an antimicrobial source adding antimicrobial substance to the fluid in the fluid path between the fluid inlet and the inlet surface of the microporous filter.
  • the microporous filter is provided in the form of a membrane or a number of membranes.
  • antimicrobial substances for example halogens
  • the filters are considerably improved, nevertheless, by use of the antimicrobial substance, for example halogens, as the substance prevents the growth of a biofilm in or on the mic- croporous filter, for example on the inlet surface of the a filter membrane, as well as fouling inside the microporous filer, for example inside the filter membrane wall. This is advantageous due to a number of reasons.
  • filtered particles upstream of the microporous filter or on the inlet surface of the microporous filter may be easily flushed out of the device. It has been verified experimentally that a flow pressure of 0.1 - 0.2 bar is suffi- cient to flush particles out of filters according to the invention.
  • a flow pressure of 0.1 - 0.2 bar is suffi- cient to flush particles out of filters according to the invention.
  • the water pressure obtained in a household filter working with gravity is capable to clean the filter by flushing. This is in sharp contrast to prior art filter cartridges, where a rather high flushing pressure through the filter is needed in order to remove sticky biofilms.
  • the flush at a pressure of 0.2 bar is not powerful enough to remove sticky biofilms in front of a microfiltration or ultrafiltration membrane, for example in the bore of a hollow fiber.
  • Biofilm growth in filters may evolve into microbial clusters with the capabilities of releasing vast amounts of microbes to the end user in the case where the porous membranes rupture.
  • the omission of biofilm growth due to halogenic killing or otherwise antimicrobial killing of the microbes or the mere prevention of microbial growth in the filter reduces the risk for infection in case that the filter is damaged.
  • the antimicrobial source preferably halogen source
  • the size of the pores has been defined above to be configured for filtering bac- teria and virus, it is within the scope of the invention that other biological or non- biological material may be filtered with a device according to the invention.
  • the device according to the invention may be used to filter fungi, parasites, colloidal pesticides or chemicals, humic acid, aerosols and other microparticles from liquid or gases, for example air.
  • filtering bacteria and virus is to be understood as holding back bacteria or virus by mechanical particle size separation from entering or generally traversing the microporous filter medium, as the pores have a size smaller than the microbes for preventing microbes to flow into and through the pores.
  • This is in contrast to the com-bitally available NanoCeram®, where particles are attracted to nanoalumina particles inside the filter medium due to an electric charge.
  • the fluid path is confined in such a way that there is a transport of fluid from the inlet through the filter and to the outlet.
  • the above mentioned halogen source may be a halogenated liquid or gas that is provided from a reservoir at a suitable rate to the fluid through the device.
  • the halogen source could be a solid media, for example in the form of a tablet or granules, which is/are dissolved at a suitable rate in the flow path.
  • suitable candidates in connection with the invention are tablets with high trichloro isocyanic acid content (TCCA).
  • TCCA trichloro isocyanic acid content
  • this TCCA tablets have a slow dissolving characteristic, which is leading to a low elution of the halogen.
  • a TCCA tablet with high elution characteristic can be installed into a rigid, porous tablet chamber, where influent water is bypassing most of the TCCA tablet chamber, while only a fraction of the influent water penetrates through the tablet chamber. This will lead to dilution of halogenated influent water, which had contact with the TCCA tablet, by the remaining influent water, which was bypassing the TCCA tablet.
  • the halogen source is provided as a halogenated resin located in the path between the inlet and the microporous filter.
  • the concentration of the halogen for example iodine, may be of a low elution type.
  • Biofilm growth occurs steadily with time, and a filter, which is subject to storage between intermitted use, has growth of biofilm during the storage time due to the remaining fluid in the filter.
  • a filter which is subject to storage between intermitted use, has growth of biofilm during the storage time due to the remaining fluid in the filter.
  • the release of an- timicrobial substance is sufficient even at low rate, because the content of antimicrobial substance in the fluid during storage increases steadily.
  • a filtration of microbes is not filtering all microbes, but only filters the microbes to a certain degree, generally men- tioned as "log reduction” referring to the loglO of the ratio between the level of contaminants in the inlet fluid and the level of contaminants in the outlet fluid of the filter.
  • log reduction referring to the loglO of the ratio between the level of contaminants in the inlet fluid and the level of contaminants in the outlet fluid of the filter.
  • the term "adapted for filtering bacteria or bacteria and virus by mechanical particle size separation” implies a reduction of the microbes in accordance with predetermined reduction levels, for example the above mentioned log 4 or log 5 reduction.
  • the reduction levels for bacteria may be different from the reduction level for viruses, because a fairly efficient virus filter may be highly efficient against bacteria due to their larger size.
  • the antimicrobial source preferably halogen source
  • the antimicrobial source may be configured to release the antimicrobial substance, for example halogens, at a rate, which is substantially less than necessary to reduce the microbes in the fluid by a log 4, or even log 3 or log 2, during the time it takes the fluid to flow through the device at the design flow.
  • a design flow may be based on the suction capacity of a human being in the case of a portable suction straw as a device according to the invention. For a household gravity filter, the design flow is dependent on the pressure that is obtained by the height difference between the fluid inlet and the micropor- ous filter and the resistance that is obtained in the microporous filter and possible other media in the device.
  • the low elution antimicrobial is given by the following, Also in this case, it is assumed that the fluid filtration device is provided with a design flow through the device, the design flow assuring a proper filtration of the fluid flowing through the device with a cleaned fluid at the flow outlet.
  • the antimicrobial source for example a halogen source, is configured to release the antim- icrobial substance at a rate, which implies a content of antimicrobials in the fluid after microfiltration of less that a predetermined limit according to a predetermined health protocol.
  • the amount and rate of release of antimicrobials is selected to such a low level, that a predetermined health protocol, for example WHO protocol, is not violated.
  • the rate may be adjusted to yield a relative amount of between 0.01 ppm and 1 ppm, if the halogen is iodine, for example to a concentration of around 0.1 ppm or even less, such as between 1 ppm, 0.5 ppm or 0.1 ppm and 0.01 ppm in the fluid, while the fluid is flowing through the device.
  • a target value in this connection is between 0.01 and 0.05 ppm, preferably in the order of 0.02 ppm, if the device according to the invention is to be operated without iodine scavenger.
  • the concentration ranges and target values are about a factor of 5 to 10 higher than for iodine, for example between 0.1 and 0.5 ppm, preferably in the order of 0.25 ppm.
  • this sharp peak halogen concentration may be removed by a halogen scavenger after the filter.
  • this scavenger may be designed to be used up by the peak value, such that no scavenger is remaining as soon as the peak concentration has been overcome, and the resin or other type of halogen source has entered a quasi steady state halogen release.
  • the halogen release from the resin or other media may be dependent on the temperature, the pH, the flow rate, the viscosity of the fluid and the degree of contamination.
  • the rate of halogen release is not critical for the filtering properties but only has the task to prevent biofilm growth, the influence of these parameters is not crucial.
  • the halogen source may be a low elution iodine resin
  • Typical iodine sources also lead to a certain content of iodide in the fluid.
  • microporous refers to pores in the micrometer and/or sub-micrometer range, for example in the range 0.01-1 micrometer. Thus, the term is not limiting the pore size to the micrometer range for micro-filtration but refers equally well to pores that are used for ultra-filtration to filtrate viruses.
  • Micro-Filtration membranes typically, have a porosity of about 0.1 - 0.3 micron and are able to filter bacteria, parasites and anorganic particles bigger than the pores.
  • Ultra-Filtration membranes typically, have a porosity of about 0.01 - 0.04 micron and are able to filter bacteria, parasites, and anorganic particles bigger than the pores and virus.
  • MF membranes have normally higher flow rates than UF membranes.
  • the porosity according to the above figures is related to the well known test method for this kind of filters termed bubble point measurement, which also relates to the fig- ures as mentioned in connection with the invention.
  • microporous membranes may be it in a tubular form or sheet-like, may be produced with various porosities for particle size seperation.
  • micropores hi order for the micropores to filtrate bacteria, micropores of the size between 0.1 micrometer and 0.3 micrometer are applicable, whereas to filter viruses, smaller pore sizes are required, for example pores in the range between 0.01 and 0.04 micrometer.
  • a preferred microporous filter device has a porosity of around 0.1 micrometer, for example between 0.05 and 0.15 micrometer, if used for filtration of bacteria.
  • filters are tested in order to yield a filtration of log 4 for the bacteriophage MS2 virus having a size of 20nm - 30nm.
  • the viruses dangerous for humans and typically present in tropical countries' water supplies only the polio virus has this similar size.
  • Other viruses that are dangerous for humans are typically larger, such as the Rotavirus with a size of around 70 nm. hi as much as the polio virus is very scarce on Earth, it would suffice in many situations to have a log 4 reduction on viruses with a size larger than 50nm.
  • a filter module of a size of ⁇ 30mm diameter x 250mm length may host between 0.08 and 0.3 m 2 , for example between 0.08 and 0.15 m 2 , active membrane surface area (average 0.20 m 2 ), depending on the outer diameter and number of the fibers in the filter housing.
  • a filter according to the invention as a gravity filter, also sometimes commonly called a siphon filter, implies that at a 1 meter pressure difference of 0.1 bar, a cartridge of 0.1 m 2 membrane area provides a theoretical flow in the order of 10 litres per hour.
  • microporous filter for the invention may be of the ceramic type.
  • such membranes may be used in the form of one or more sheets, the latter being stacked in order to provide a large filtration surface.
  • the filter accord- ing to the invention is possibly provided with a halogen absorbent before the fluid outlet.
  • halogen absorbers for example iodine scavengers
  • One possible candidate is activated carbon, for example in the granular form (GAC) or contained in a fabric, and, potentially, silver enriched.
  • GAC granular form
  • Another pos- sible halogen absorbent in the case of iodine being the halogen is Dow Marathon A® or Iodosorb®.
  • CDC Center for Dis- ease Control, Atlanta, USA
  • CDC recommends for babies with an age of 0-3 months a maximum daily iodine uptake at permanent consumption of 0.01 mg/day.
  • the maximum iodine concentration in the uptaken water should not be higher than 0.02 mg/1.
  • the source does not elute more than 0.02 mg iodine per litre water.
  • the filtration device according to the invention may comprise an additional filtration step with an electroposive attracting ultrafiltration or microfiltration media, for example Nanoceram®, as also disclosed in U.S. Patent No. 6,838,005, though experiments have shown that this is not necessary.
  • an electroposive attracting ultrafiltration or microfiltration media for example Nanoceram®, as also disclosed in U.S. Patent No. 6,838,005, though experiments have shown that this is not necessary.
  • the fluid path may be arranged from inside the fibres to the outside of the fibres.
  • the halogen absorbent may be provided between the hollow fibres, a configuration that saves overall space of the entire filtration device according to the invention.
  • the device comprises a housing or cartridge with the inlet and the outlet and containing the microporous filter and the halogen source.
  • the cartridge may be disposable and contained in a re-usable housing.
  • the de- vice comprises a housing with a rechargeable or exchangeable halogenated resin separate from the microporous filter.
  • the housing with the hollow fibres is advantageously assembled in a so-called forward-flush configuration.
  • filtered bacteria and virus and other particles will be aggregated in the filter and may with time lead to reduced filtration capabilities.
  • the flow rate may be dropping very quickly during use, because the pores are clogging.
  • the membranes would then have to be cleaned or replaced to recover performance, hi order to regenerate the filter, a forward flush mechanism may be included in the device according to the invention.
  • the flush mechanism may, in practice, be established by providing a second flow path from the fluid inlet through the microporous filter along the porous filter wall to a second outlet but not through the porous filter wall, the second outlet being provided with a valve system for flushing purposes during an open valve state.
  • the filter membrane is preferably a hydrophilic porous polymer membrane.
  • the polymers normally being used are Polyether sulphone (PES), Polyvinylidene fluoride (PVDF) or Polyacrylonitrile (PAN).
  • the shape of these membranes is preferably as a hollow fiber tube, but alternatively also as flat membrane.
  • the hollow fiber can have a single bore structure or multi bore structure (for example a 7-bore).
  • Single bore fibers are commercially available from companies like Prime Water International® (BE) or X- Flow® (NL); 7-bore fibers are commercially available from companies like IMT® (NL) or INGE® (DE).
  • BE Prime Water International®
  • NL X- Flow®
  • 7-bore fibers are commercially available from companies like IMT® (NL) or INGE® (DE).
  • an ESf-OUT filter flow is preferred, because it ensures a more concentrated flush to remove the filter debris.
  • the device may have a fluid storage container between the micro- porous filter and the fluid outlet, hi order for the fluid storage container not to imply a risk for microbe breeding, it may be provided with an inner antimicrobial surface.
  • a dirty water storage container can be connected to the inlet.
  • the invention may be used for a portable water filtering device.
  • a portable filtering device may be a drinking straw, for example, with a diameter between 3 centimetre and 6 centimetre, for example in the order of 3 centimeter, and a length between 10 centimetre and 40 centimetre, for example in the order of 25 centimeter, as it is known from the commercially available water filter LifeStraw®.
  • Such drinking straws are especially suitable for camping, hiking and military purposes as well as emergency equipment and water providing aid in rural areas.
  • Another application is in the form of a gravity filter, where water or other liquid is filled into a first container and flows through the filter into a second container arranged at a lower level such that gravity forces the fluid through the filter.
  • the force on the liquid for the flow through the filter is dependent on the height of the liquid level in the first container relatively to the liquid filter. If the liquid is water and the level is 2 meter over the filter, the pressure is 0.2 bar. As an example, the height may be chosen between 0.2 and 2 meter corresponding to a pressure of 0.02 and 0.2 bar in the case of water.
  • the microporous filter is hosting in the order of 0.1-0.3 m 2 membrane surface area
  • the filter may be capable of providing in the order of 10 liters per hour at a fluid inlet pressure of 0.1 bar.
  • the filter area in a household or portable filter may be of the order of 3 to 10 times larger.
  • the membrane surface area may be much larger than stated above.
  • a filter according to the invention is primarily directed towards production of drinking water, but water - or other liquids - may be cleaned for other purposes as well, for example, for industrial, medical or scientific purposes.
  • a chamber of halogenated media upstream of the filter membrane, a chamber of halogenated media is arranged, for example iodine or chlorine.
  • the media has a low elution charac- teristic, which implies that it is not supposed to kill the microbes instantly during the relatively short contact time while the water flows through the filter. Instead of this, a small dose of halogenated elements is permanently streaming into the "filter cake", possibly but not necessarily killing the microorganisms over time and preventing build-up of biofilm.
  • a low elution dose halogenated resin versus a high dose resin is the following.
  • a low elution halogenated resin lasts longer than a high elution resin with the same halogen content. Due to the low dose, the use of a halogen scavenger may be avoided without any substantial health impact on the consumer by the halogen. Even if a halogen scavenger is used, the requirements for the scavenging properties are lower. Also, the low dose allows the amount of resin and scavenger to be small, which reduces the size, weight and costs of a filtering device according to the invention relative to prior art devices.
  • the membrane material may comprise an antimicrobial substance, for example incorporated in the material itself.
  • antimicrobial substances are AEGIS Microbe Shield ® or colloidal silver.
  • the fluid filtration device comprises a housing, inside which the microporous filer is provided.
  • the housing may have an inner wall releasing antimicrobials.
  • An antimicrobial coating prevents biofilm formation on the surface of the inner wall of the housing.
  • an antimicrobial coating that contains silver, for example in the form of colloidal silver.
  • Colloidal silver comprising silver nanoparticles (lnm to lOOnm) can be suspended in a matrix.
  • the silver colloids can be released from minerals such as zeolites, which have an open porous structure.
  • Silver can also be embedded in a matrix such as a polymer surface film. Alternatively, it may be em- bedded in the matrix of the entire polymer during plastic forming processes, typically known as injection moulding, extrusion or blow moulding.
  • a silver containing ceramic, applicable for the invention, is disclosed in US patent No. 6,924,325 by Qian.
  • Silver for water treatment is disclosed in US patents No. 6,827,874 by Souter et al, No. 6, 551,609 by King, and it is known in general to use silver enhanced granular carbon for water purification.
  • Silver coating for water tanks is disclosed in European patent application EP 1647527.
  • antimicrobial metals that may be employed in connection with the invention are copper and zinc, which, alternatively or in addition, may be incorporated in an antimicrobial coating.
  • An antimicrobial coating containing silver and other metals is disclosed in US patent No 4,906,466 by Edwards and references therein.
  • a coating may, in addition or alternatively, comprise titanium dioxide.
  • Titanium dioxide can be applied as a thin film that is synthesized by sol-gel methods.
  • As anatase TiO 2 is a photo catalyst thin films with titanium dioxide are useful on external surfaces that are exposed to UV and ambient light.
  • nanocrystals of titanium dioxide may be embedded within polymers.
  • silver nanoparticles can be complexed with titanium dioxide for enhanced effectiveness.
  • a thin film coating may have a thickness as little as a few micrometers.
  • a coating may in addition, or alternatively, comprise a reactive silane quaternary ammonium compound, like it is known from the company AEGIS® under the trademark Microbe ShieldTM used for air conditioning.
  • a reactive silane quaternary ammonium compound like it is known from the company AEGIS® under the trademark Microbe ShieldTM used for air conditioning.
  • the active ingredient in the AEGIS® Antimicrobial forms a colourless, odourless, positively charged polymer coating, which chemically bonds & is virtually irremovable from the treated surface.
  • release of antimicrobials may be provided to an extent that only prevents microbes to live on the surface of the wall and prevent biofilm formation, but it may also be provided to an extent, which involves a release of antimicrobials at a rate which suffices to provide the fluid with enough antimicrobials, such that biofilm formation is also prevented in and on the microporous filter.
  • the release of antimicrobials from the inner wall of the housing may be caused by a surface coating of the inner surface, for example a surface coating releasing silver, as described above.
  • An alternative is an inner wall with a surface through which antimicrobials are possible to migrate from inside the wall, for example, due to antimicrobials that are incorporated in the material of the wall or due to antimicrobials that are provided in a reservoir behind the wall and which are capable of migrating through the wall and into the fluid in the housing.
  • the inner wall of the housing may be configured as part of a laminate also containing the reservoir.
  • housing also implies multiple housings and tubings between these multiple housings as well as a device according to the invention with interconnected multiple containers.
  • microbes are accumulated in the fluid upstream of the microporous filter. These microbes can be released and flushed out of the device by a tangential flow along the microporous fil- ter.
  • the first part of the flush fluid released from the device contains a large part of microbes and is hazardous if consumed.
  • the first outlet for the clean fluid has a first marking and the 1 second outlet for the flush fluid has a second marking, for example a different colour, which is distinctly different from the first marking.
  • the flush fluid itself can be marked, for example by colour, taste and/or smell.
  • a chamber is provided upstream of the second outlet. This chamber accumulates a cer- tain volume of the fluid from the inlet and adds a marking substance to this part of the fluid in order to provide a certain colour to the volume of fluid when a user opens a valve for release of fluid from the second outlet, the first fluid released is the fluid from the chamber.
  • This volume of the fluid is coloured, for example green or red, and indicates to the user that this fluid is not for consumption, hi addition to the colour or alternatively, the fluid may be provided with a substance giving the fluid a special taste, for example a bitter taste, and/or a special smell, for example a fouling smell, hi order for the volume of the chamber to be separated from the fluid that traverses the filter, the chamber comprises in a further embodiment a one-way valve separating the chamber from the microporous filter.
  • fluid enters through the fluid inlet, flows along the micro- porous filter surface and exits the device through the second fluid outlet after having traversed the chamber, which is upstream of the second outlet.
  • the chamber is filled with new fluid which takes up the marking sub- stance.
  • the marking substance may be provided in small quantities and, thus, gradually builds up in the fluid of the chamber until the next forward flush.
  • the volume of the chamber can be small, as it is only necessary to warn the user shortly when the second outlet is opened. This implies that the source of colour, smell or taste can be a small source, for example a slowly dissolving tablet provided in the chamber.
  • the first fluid outlet is closed during forward flush, though this is not strictly necessary. It is of advantage, if the microporous filter is treated with some back flush before or during forward flush.
  • the back flush is performed by pressing clean fluid in a backward direction through the microporous filter, for example several times intermitted with forward flush.
  • the device has a back flush container connected to the exit side of the microporous filter for back flush of clean fluid from the back flush container and through the microporous filter.
  • the back flush container advantageously, is a manually activated bellow, for example in the form of a squeeze pump, connected to the exit side of the microporous filter.
  • a manually activated bellow for example in the form of a squeeze pump
  • the bellow By manually pressing the bellow together, clean fluid accumulated in the bellow is pressed back into the microporous filter and back washes the filter.
  • Microbes and other microscopic particles are pressed into the volume upstream of the microporous filter. From this upstream volume, the particles are, then, removed by forward flush.
  • the back flush container for example a bellow
  • the back flush container is connected to the microporous filter in a dead end configuration in a specific embodiment, which means that the bellow has a separate connection to the downstream side of the microporous filter relative to the first outlet.
  • the device according to the invention has a distinct orientation for proper use.
  • the device according to the invention being a water filter and having a tube-like housing around the microporous filter
  • the proper use of the device may imply a vertical arrangement of the housing. If the first outlet is in the bottom of the housing, and the backflush container is connected to the upper part of the housing, there is a risk that air is trapped in the backflush container instead of clean water such that proper backflush is not possible.
  • the backflush container is located below the first outlet, because the water level for extraction of water through the first outlet will also fill the container.
  • the back flush container can be part of a tube connecting the microporous filter with the first outlet.
  • clean fluid flows through the container, for example bellow, in order to leave the first outlet.
  • the bellow will easily be filled, at least partly, with clean fluid.
  • the housing is a tube with a lateral dimension smaller than 6 cm, and the bellow is provided on an outer side of the housing for manual activation by grabbing around the housing and exerting pressure on the bellow. Each time the housing is grabbed by a person, a backfiush is activated removing microbes from the pores of the filter.
  • the device according to the invention is a portable filter with a housing and a mouthpiece in connection with the first fluid outlet configured for contact with the mouth of a person. If the mouthpiece, or at least part of it, preferably that part that is provided for contact with the mouth of a person drinking from the mouthpiece, has an antimicrobial surface, the bacteria from one person drinking from the mouthpiece are killed on contact, such that a second person using the mouthpiece is not infected, hi this case, the invention is especially suited for compact water purification devices having dimensions as the commercial product with the registered trademark LifeStraw®.
  • the housing, or at least part of the housing of the device according to the invention preferably that part of the housing that is configured for hand contact with the housing, has an antimicrobial surface
  • the bacteria or other microbes from one person holding the housing are killed on contact, such that the second person touching the housing is not infected by microbes on the housing.
  • the filter is stored in an unhygienic place it does not become a bacteria breeding ground.
  • the device according to the invention is applied as a household filter without a mouthpiece configured for contact with the mouth of a person.
  • the fluid filtration device implies the possibility of a great variety of embodiments as it appears from the foregoing.
  • it may be constructed as a modular device with several modules or as a non-modular device, for example made in one piece.
  • the device according to the invention may comprise a water purifying granular resin, for example several types of granular resin or only one type of granular resin.
  • the device does not comprise a first module and a second module containing mutually different water purifying granular resins.
  • the device may be without granular resin at all.
  • the fluid filtration device may have a mouthpiece configured for contact with the mouth of a person or be made without a mouthpiece.
  • the mouthpiece may have an antimicrobial surface, but they may also be provided without an antimicrobial surface.
  • the housing, as well, may be provided with an outer or inner antimicrobial surface or without an inner or an outer antimicrobial surface or even without an antimicrobial surface at all.
  • a number of candidates for microporous filters or electro-active filters usable in connection with the invention including
  • the device according to the invention may be constructed with a variety of antimicrobial sources, as it appears from the foregoing.
  • the device according to the invention may as antimicrobial source use a halogenated resin provided in the path between the fluid inlet and the microporous filter for flow of the fluid through the resin chamber.
  • the halogenated resin may be a granular resin.
  • an antimicrobial source may be used alternatively which is free from granular halogenated resin or free from halogenated resin at all.
  • a number of other antimicrobial substances may be used, as explained in the foregoing, for example halogenated tablets without halogenated resin.
  • the filter media, or even the entire device may be free of antimicrobial resin.
  • the fluid filtration device according to the invention is not in the form of a tubular housing with a length of less than 50 cm and a width of less than 80 mm.
  • the fluid filtration device according to the invention is without a mouthpiece for suction of water through the device, hi some embodiments, it has a mouthpiece but the mouthpiece does not have an antimicrobial surface, hi some embodiments, it has a mouthpiece and a housing, both of which are without an antimicrobial surface, hi some embodiments, the device is without at least a first mod- ule and a second module containing mutually different water purifying granular resins, wherein the first module has a first connector and the second module has a second connector, the first and the second connector both being tubular and being connected for confining water flowing through the first and the second modules.
  • the device is without a first module or a second module or both having at least one water permeable mesh with a mesh size smaller than the grain size of the resins for
  • FIG. 1 illustrates the principle of the invention
  • FIG. 2 illustrates the flush principle
  • FIG. 3 show a stacked membrane configuration
  • FIG. 4 shows a zig-zag stacked membrane configuration
  • FIG. 5 illustrates a hollow fibre arrangement with halogen absorber between the fibres
  • FIG. 6 illustrates a hollow fibre arrangement with storage container
  • FIG. 7 illustrates a gravity filter
  • FIG. 8 illustrates the container of the gravity filter in greater detail
  • FIG. 9 is a capillary filter with a backflush option
  • FIG. 10 is a sheet membrane filter with a backflush option.
  • FIG. 1 illustrates the principle of the invention.
  • the fluid filtration device 1 has a fluid inlet 2 and a fluid outlet 3.
  • the fluid is preferably liquid, but the invention is of general nature and may be used for gases, aerosols or vapours as well.
  • Downstream of the fluid inlet 2 is a chamber 4 where an antimicrobial substance 5, preferably halogen, is provided.
  • the source could be a halogenated liquid or gas that is provided at a suitable rate to the fluid through the device.
  • a halogenated resin through which the fluid flows, which is indicated by arrow 7.
  • the fluid traverses a microporous filter 8, preferably a membrane, be- fore the fluid leaves the device through the fluid outlet 3.
  • the device 1 also has a halogen absorber 9 in a third chamber 10.
  • Material 11, such as bacteria, virus, and other material is held back at the microporous inlet surface of the wall 12 of the membrane 8.
  • the device as illustrated in FIG. 1 may be applied with the gravity principle.
  • the chamber 4 with the antimicrobial substance 5, preferably the halogenated source, for example a resin or tablet may be an integrated part of the housing 1 or a chamber which can be demounted as a module from the remaining part of the housing for exchange of the chamber 4, for example in the case that the source, for example a resin or tablet, is exhausted, hi case that the invention is used as a drinking straw, analogous to the commercial product LifeStraw®, the first outlet 3 may be provided with a mouthpiece.
  • FIG. 2 the basic principle is illustrated for a device according to the invention having a forward flush mechanism included.
  • the device 1 includes a first fluid outlet 3 for outlet of filtered liquid. This first fluid outlet 3 may, optionally, be provided with a valve for regulation of the flow through the outlet 3.
  • the device 1 includes a second fluid outlet 13 with a valve 14, which can be opened for flushing situations, where the flushing fluid flows parallel along the membrane surface 15 to take up the filtered debris 11. If the first fluid outlet 3 is provided with a valve, this valve may be closed during flushing situations.
  • a stacked flat membrane configuration is shown in a cross sectional view.
  • the membranes 8 may be of the ceramic type or the microporous polymer membrane type. Water is flowing into the microporous filter between the inlet walls of adjacent membranes 8 and flows out of the microporous filter into the volume 6 between outlet walls of adjacent membranes 8. As the membranes 8 are fitted tightly to the surround- ing enclosure, water flow from the inlet to the outlet is only possible through the membranes 8.
  • a halogen absorber for example an iodine scavenger resin, may be arranged in the volume 6 between outlet walls of adjacent membranes 8.
  • the stacked membrane configuration may be part of the flushable device principle, an example of which is illustrated in FIG. 2.
  • the stacked mem- branes may be curved.
  • a further alternative may be provided as pairs of spiralling membranes.
  • FIG. 4 a different stacked membrane configuration is shown, where the membranes 8 form a zig-zag pattern. This may be convenient, if the membrane is a foldable mi- croporous membrane 8, which is folded into the harmonica-like form before mounting in a housing.
  • the zig-zag stacked membrane configuration may be part of the flush- able device principle, an example of which is illustrated in FIG. 2.
  • FIG. 5a a configuration is illustrated incorporating hollow fibres 16.
  • a plurality of hollow fibres 16 are arranged in a housing 40, and fluid 7 may flow through a chamber 5 with an antimicrobial, for example a halogenated resin 5, and into the fibres 16 before flowing through the fibre walls and out of the filter through the interspaces between the fibres 16, which is illustrated by arrows, hi the interspaces between the fi- bres 16, a halogen absorber 9 may, optionally, be provided in order to take up residual halogen from the fluid before release from the filtering device 1.
  • the antimicrobial substance 5, for example a halogenated resin, as illustrated may be contained in a rechargeable chamber 4.
  • the hollow fibres 16 are through-going, that means they are not closed at their ends. If the valve 14 is opened, as illustrated in FIG. 5b, the fluid will seek the easiest possible way out through the valve 14. Biomaterial and other material that is retained in the fibres will be flushed out of the fibres 16 by the flow of the fluid.
  • FIG. 6a and 6b illustrate a similar principle as FIG. 5.
  • a storage container 17 surrounds the membranes in order to take up water or other, filtered fluid before release for consumption.
  • the storage container is especially useful in the case of gravity filters, where water may flow through the filter a substantial time prior to consumption. For example, water may flow through the filter during night time and be accumulated in the storage container for consumption the following day.
  • the storage container 17 is arranged to surround the tubular housing 40 and is made of a flexible material. By grabbing around the housing and the container 40, pressure is exerted on the container. If at the same time, the first outlet 3 is closed, the clean fluid in the container 17 will be pressed back into the inter- spaces between the fibres 16 and perform a backflush through the fibre walls. The backflush will remove particles and microbes from the inner side of the fibres 16, after which the microbes and particles can be flushed out in the forward flush configuration though opened valve 14 as illustrated in FIG. 6b.
  • FIG. 7 illustrates a gravity filter 20 with a feeding container 21 for feeding water into the filter device 22 arranged at a lower level.
  • the container 21 is provided with a handle 23 for easy transport of the container 21.
  • the lower part of the container 21 comprises a chamber 24 with antimicrobial substance, preferably a low elusion halogenated source chamber 24, for example containing a chlorinated tablet.
  • the container 21 may contain a replacement or cleanable pre filter for filtering larger particles from the water.
  • the halogenated source chamber 24 of the container 21 is connected to a filter device 22 by a flexible pipe 25.
  • the filter device 22 contains a forward flush configured porous hollow fibre unit, for example with a maximum pore size of 0.04 micrometer or 0.02 micrometer.
  • the filter device also comprises a flush water outlet 28 with a flush valve 29 to be opened for flushing purposes.
  • FIG. 8 shows the feeding container 21 in greater detail.
  • a pre-filter insert 30 having a fluid inlet in the upper end is releasably inserted into the container 21.
  • a cylindrical replacement filter to be placed in the pre-filter insert 30.
  • the container 21 is provided with holes 31 for hanging the container 21 on a hook or nail in a wall.
  • the handle 23 of the container 21 has a cross sectional U-form for press fit insertion of the filter device 22 into the handle for easy transport and storage.
  • FIG. 9 illustrates a further embodiment of the invention.
  • the microporous filter 1 comprises a number of microporous capillaries 16 into which water or other fluid enters through a fluid inlet 2.
  • the water flows through the capillaries 16 into an outlet chamber 45 in the lower end, from which it can be released through a valve 14 at the second fluid outlet 13 in the case of forward flush. If the valve 14 at the second outlet 13 is closed, the pressure on the water drives the water through the capillary walls 43 and into the interspace 44 between the capillaries. From the interspaces 44, the water can be released for consumption through first outlet 3 having a valve 46 as well, hi addition, the filtration device 1 has a container 42 in which clean water is accumulated.
  • the container 42 As the container 42 is located lower than the first outlet 3, it is filled with clean water before water is released through the first outlet 3.
  • the container 42 is made of a compressable material, for example a polymer bellow that can be manually compressed.
  • first outlet When the first outlet is closed by the valve 46, and pressure is exerted on the container 42, pressure drives the water from the container through the capillary walls 43 and back into the capillaries 16. This back flush presses microbes and other particles out of the capillary pores and away from the inner surface of the capillaries 16.
  • a subsequent or simultaneous forward flush through second outlet 13 removes the microbes and particles from the filtration device 1.
  • the outlet chamber 45 between the open outlet ends 48 of the capillaries 16 and the second outlet 13 is formed with bending walls 49, for example walls with a semispherical shape.
  • the advantage of such shape is a proper flow without substantial turbulence also for those capillaries that are located close to the housing 40.
  • This is in contrast to a prior art flat end cap, which restricts the flow through the outermost capillaries such that an uneven flow is provided, which is disadvantageous, especially, in forward flush situations.
  • an inlet chamber 47 is provided with a bending chamber wall 49', in order to provide a proper flow into the outermost capillaries.
  • the outlet chamber 45 may be delimited by a one way valve 50, allowing water, preferably water, to enter the outlet chamber 45 from the capillaries 16, but which prevents flow back into the capillaries 16.
  • the outlet chamber 45 is filled with unfiltered water from the capillaries.
  • the outlet valve 14 When the outlet valve 14 is closed, water is retained in the outlet chamber 45. This water slowly dissolved a tablet 51 which gradually colours the water in the outlet chamber 45 until the next forward flush. At the next forward flush, the first part of the released water has a certain colour and warns the user that this water is not for consumption.
  • a granular agent, a coating on the inner surface of the out- let chamber, or a colouring agent incorporated in the material of the walls of the outlet chamber for migration to the inner surface of the walls of the outlet chamber may be used instead.
  • the colouring agent may be substituted or complimented by a taste giving agent and/or a smell giving agent.
  • the one-way valve 50 prevents the added colour, smell or taste giving agent to reach the liquid in the capillaries 16 and the first end.
  • FIG. 10 Liquid enters the upper fluid inlet 2 into a first chamber 5', from which antimicrobial substance is released to the liquid before it enters the inlet chamber 47 through a filter or membrane 57.
  • This antimicro- bial substance can be a halogen, preferably iodine or chlorine, from a source in the first chamber 5'.
  • the liquid From the inlet chamber 47, the liquid enters the outlet chamber 45 through a one way valve 50 in analogy with the aforementioned embodiment in FIG. 9. If the second outlet valve 14 is closed, liquid traverses microporous membrane 8, for example a ceramic membrane, into an outlet reservoir 53 before it is released through outlet 3 for consumption. Also, in this case, a container 42 is used for back- flush through the microporous membrane 8.
  • the outlet chamber is separated from the outlet reservoir 53 by a fluid tight wall partition 56. hi addition, the outlet reservoir 53 may contain a halogen scavenger.
  • antimicrobial substance to the liquid in the inlet chamber 47 by release from the wall 55 of the inlet chamber, for example by a coating on the inner wall of the housing 40 or by having migratably incorporated antimicrobials in the wall material of the housing 40.
  • antimicrobial substance to the liquid in the inlet chamber 47 by migration of the substance from a reservoir 54 and through the wall 55' of the inlet chamber.
  • release of antimicrobials may be provided to an extent that only prevents microbes to live on the surface of the wall 55, 55' and prevent biofilm formation on it, but it may also be provided to an extent, which involves a release of antimicrobials at a rate which suffices to provide the fluid with enough antimicrobials, such that biofilm formation is also prevented in and on the microporous filter 52.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Filtering Materials (AREA)
  • Water Treatment By Sorption (AREA)
  • External Artificial Organs (AREA)

Abstract

La présente invention porte sur un dispositif de filtration de liquides ayant une entrée de liquide et une sortie de liquide et un trajet de liquide confiné entre l'entrée et la sortie à travers un filtre microporeux ayant une dimension de pore adaptée pour la filtration de microbes, par exemple, de bactéries et de virus. Le dispositif comprend une source anti-microbienne, de préférence une source d'halogène, ajoutant une substance anti-microbienne au liquide dans le trajet de liquide confiné entre l'entrée de liquide et le filtre microporeux pour empêcher la formation d'un biofilm dans le filtre microporeux.
PCT/DK2007/000362 2007-03-09 2007-07-18 Filtre microporeux ayant une source anti-microbienne WO2008110166A1 (fr)

Priority Applications (20)

Application Number Priority Date Filing Date Title
CN2007800529028A CN101668580B (zh) 2007-03-09 2007-07-18 带有抗菌源的微孔过滤器
AP2009004999A AP3005A (en) 2007-03-09 2007-07-18 Microporous filter with an antimicrobial source
US12/450,046 US20100051527A1 (en) 2007-03-09 2007-07-18 Microporous filter with an antimicrobial source
MX2009009608A MX2009009608A (es) 2007-03-09 2007-07-18 Filtro microporoso con una fuente antimicrobiana.
EP07785726A EP2139590A1 (fr) 2007-03-09 2007-07-18 Filtre microporeux ayant une source anti-microbienne
BRPI0721407A BRPI0721407A8 (pt) 2007-03-09 2007-07-18 Dispositivo de filtragem de fluido
TW097107917A TW200906475A (en) 2007-03-09 2008-03-06 Microporous filter with a low elution antimicrobial source
EP08715574A EP2136683A2 (fr) 2007-03-09 2008-03-08 Filtre microporeux avec une source antimicrobienne à faible élution
KR1020157026464A KR20150121188A (ko) 2007-03-09 2008-03-08 저 용출 항균물질 공급원을 갖는 미세다공성 여과기를 사용하는 여과 방법
AP2009004981A AP2454A (en) 2007-03-09 2008-03-08 Filtration process using microporous filter with alow elution antimicrobial source
MX2009009609A MX2009009609A (es) 2007-03-09 2008-03-08 Proceso de filtracion usando filtros microporosos teniendo una fuente antimicrobiana de baja elucion.
BRPI0808473A BRPI0808473A8 (pt) 2007-03-09 2008-03-08 Método para filtragem de fluido
PCT/DK2008/000096 WO2008110172A2 (fr) 2007-03-09 2008-03-08 Filtre microporeux avec une source antimicrobienne à faible élution
CN2008800151998A CN101677701B (zh) 2007-03-09 2008-03-08 使用带有低洗脱抗菌源的微孔过滤器的过滤方法
KR1020097021176A KR101828603B1 (ko) 2007-03-09 2008-03-08 저 용출 항균물질 공급원을 갖는 미세다공성 여과기를 사용하는 여과 방법
US12/450,042 US20100044321A1 (en) 2007-03-09 2008-03-08 Microporous filter with a low elution antimicrobal source
IL200805A IL200805A0 (en) 2007-03-09 2009-09-08 Filtration process using microporous filter with a low elution antimicrobial source
IL200806A IL200806A0 (en) 2007-03-09 2009-09-08 Microporous filter with an antimicrobial source
MA32267A MA31301B1 (fr) 2007-03-09 2009-10-07 Filtre microporeux avec une source antimicrobienne a faible elution
HK10107610.3A HK1141215A1 (en) 2007-03-09 2010-08-10 Filtration process using microporous filter with a low elution antimicrobial source

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPCT/DK2007/000120 2007-03-09
PCT/DK2007/000120 WO2008110165A1 (fr) 2007-03-09 2007-03-09 Filtre microporeux ayant une source d'halogène

Publications (1)

Publication Number Publication Date
WO2008110166A1 true WO2008110166A1 (fr) 2008-09-18

Family

ID=38668856

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/DK2007/000120 WO2008110165A1 (fr) 2007-03-09 2007-03-09 Filtre microporeux ayant une source d'halogène
PCT/DK2007/000362 WO2008110166A1 (fr) 2007-03-09 2007-07-18 Filtre microporeux ayant une source anti-microbienne
PCT/DK2007/000363 WO2008110167A1 (fr) 2007-03-09 2007-07-18 Dispositif de filtration de liquides
PCT/DK2008/000096 WO2008110172A2 (fr) 2007-03-09 2008-03-08 Filtre microporeux avec une source antimicrobienne à faible élution

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/DK2007/000120 WO2008110165A1 (fr) 2007-03-09 2007-03-09 Filtre microporeux ayant une source d'halogène

Family Applications After (2)

Application Number Title Priority Date Filing Date
PCT/DK2007/000363 WO2008110167A1 (fr) 2007-03-09 2007-07-18 Dispositif de filtration de liquides
PCT/DK2008/000096 WO2008110172A2 (fr) 2007-03-09 2008-03-08 Filtre microporeux avec une source antimicrobienne à faible élution

Country Status (12)

Country Link
US (2) US20100051527A1 (fr)
EP (2) EP2139590A1 (fr)
KR (3) KR101547362B1 (fr)
CN (2) CN101668580B (fr)
AP (2) AP3005A (fr)
BR (2) BRPI0721407A8 (fr)
HK (1) HK1141215A1 (fr)
IL (2) IL200805A0 (fr)
MA (2) MA31302B1 (fr)
MX (2) MX2009009608A (fr)
TW (2) TW200906475A (fr)
WO (4) WO2008110165A1 (fr)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011110173A1 (fr) 2010-03-08 2011-09-15 Vestergaard Sa Dispositif de purification de l'eau possédant un élément soupape surmoulé
US8173018B2 (en) 2010-08-25 2012-05-08 Dow Global Technologies Llc Fluid filter module including sealed boss
US8261919B2 (en) 2010-08-25 2012-09-11 Dow Global Technologies Llc Fluid filter module including handle
US20120298583A1 (en) * 2009-12-18 2012-11-29 Vestergaard Frandsen Sa Drinking straw with Hollow Fibre Liquid Filter
WO2014055700A1 (fr) * 2012-10-04 2014-04-10 Applied Nanostructured Solutions, Llc Membranes de séparation à nanostructures de carbone et procédés de séparation
US9107292B2 (en) 2012-12-04 2015-08-11 Applied Nanostructured Solutions, Llc Carbon nanostructure-coated fibers of low areal weight and methods for producing the same
US9133031B2 (en) 2012-10-04 2015-09-15 Applied Nanostructured Solutions, Llc Carbon nanostructure layers and methods for making the same
US9327969B2 (en) 2012-10-04 2016-05-03 Applied Nanostructured Solutions, Llc Microwave transmission assemblies fabricated from carbon nanostructure polymer composites
US9352252B2 (en) 2011-04-27 2016-05-31 Lifestraw Sa Water purification device
US9447259B2 (en) 2012-09-28 2016-09-20 Applied Nanostructured Solutions, Llc Composite materials formed by shear mixing of carbon nanostructures and related methods
USD782610S1 (en) 2015-11-09 2017-03-28 Lifestraw Sa Water purifier
USD782609S1 (en) 2015-07-14 2017-03-28 Lifestraw Sa Water purifier
USD783773S1 (en) 2015-07-14 2017-04-11 Lifestraw Sa Water purifier
US9802373B2 (en) 2014-06-11 2017-10-31 Applied Nanostructured Solutions, Llc Methods for processing three-dimensional printed objects using microwave radiation
WO2019130356A1 (fr) * 2017-12-30 2019-07-04 INDIAN INSTITUTE OF TECHNOLOGY MADRAS (IIT Madras) Dispositif de filtration d'eau portable pour éliminer les impuretés de l'eau à l'aide de cartouches de purification spécifiques aux contaminants
US10399322B2 (en) 2014-06-11 2019-09-03 Applied Nanostructured Solutions, Llc Three-dimensional printing using carbon nanostructures
WO2020023993A1 (fr) * 2018-08-01 2020-02-06 Membrane Systems Australia Pty Ltd Système et procédé d'élimination de polluants polyfluorés de l'eau
US11053141B2 (en) 2013-10-28 2021-07-06 Vestergaard Sa Water purification device
EP3935946A1 (fr) 2020-07-06 2022-01-12 AgXX Dispositif de réduction des microorganismes actifs dans des fluides

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2000799C2 (nl) * 2007-08-08 2009-02-10 Prime Water Internat N V Inrichting voor het filtreren van verontreinigd water.
GB0719983D0 (en) * 2007-10-12 2007-11-21 Isis Innovation A portable water purification device
WO2011088376A2 (fr) * 2010-01-15 2011-07-21 Perry Equipment Corporation Eléments filtres discoïdes pour production de gaz
US8920743B2 (en) 2011-04-06 2014-12-30 The Clorox Company Faucet mountable water conditioning devices
TW201248091A (en) * 2011-05-31 2012-12-01 Jg Environmental Tech Co Ltd Air purification device
US8445864B2 (en) * 2011-08-26 2013-05-21 Raytheon Company Method and apparatus for anti-biofouling of a protected surface in liquid environments
JP2014525343A (ja) * 2011-09-04 2014-09-29 アジレント・テクノロジーズ・インク 流体測定用デブリフィルタ
EP2791061B1 (fr) 2011-12-16 2022-06-15 Helen of Troy Limited Filtre par gravité
US20150034544A1 (en) * 2012-01-24 2015-02-05 William F. Aftoora Filter straw
TW201434763A (zh) * 2012-12-10 2014-09-16 Nitto Denko Corp 消毒水裝置
US9776219B2 (en) 2013-01-17 2017-10-03 Raytheon Company Method and apparatus for removing biofouling from a protected surface in a liquid environment
CA2898784C (fr) 2013-02-05 2018-10-23 Pocared Diagnostics Ltd. Agencement de filtre et procede d'utilisation associe
WO2015066347A1 (fr) * 2013-10-30 2015-05-07 Lembcke Felipe Séparation de composés organiques d'un liquide
CN113634124B (zh) 2013-12-04 2022-11-18 普凯尔德诊断技术有限公司 用于处理和分析通过切向过滤提取的颗粒的方法和装置
US9623229B2 (en) * 2014-01-29 2017-04-18 Wilmarc Holdings, Llc Antimicrobial straw
CN104276698A (zh) * 2014-10-27 2015-01-14 安徽省科普产品工程研究中心有限责任公司 可拆装直饮纳米净水器
CA2913766C (fr) * 2015-04-08 2018-01-16 Lifestraw Sa Systeme de purification d'eau par gravite et procede de fabrication d'un contenant d'eau pliable, souple
FR3044933B1 (fr) * 2015-12-15 2017-12-22 Commissariat Energie Atomique Dispositif de filtration d'une suspension
CN105544650A (zh) * 2016-03-17 2016-05-04 邓泳安 一种具有树脂颗粒抑菌涂层的海上风机的淡水获取系统
US10307005B1 (en) 2017-03-28 2019-06-04 LaMonte′ D. Pierce Filtered drinking straw
CN111065904A (zh) 2017-08-02 2020-04-24 普凯尔德诊断技术有限公司 包括通过过滤器去除废液的方法和装置的处理器过滤器布置
GB201713111D0 (en) 2017-08-16 2017-09-27 Griffith John Water filter
DE102017216030A1 (de) * 2017-09-12 2019-03-14 Fresenius Medical Care Deutschland Gmbh Verfahren zum verarbeiten einer proteinhaltigen suspension oder proteinhaltigen lösung
GB2573983A (en) * 2018-03-02 2019-11-27 Icon Lifesaver Ltd A portable water filtration device
CN110577258B (zh) * 2019-08-26 2024-05-14 江西博鑫环保科技股份有限公司 用自然力作动力的恒压错流过滤水处理工艺方法及处理装置
EP4051404A4 (fr) * 2019-11-01 2024-02-21 Biofouling Tech Inc Protection contre l'encrassement biologique de flux de volume/vitesse élevés
US20220032221A1 (en) * 2020-07-31 2022-02-03 Hamilton Sundstrand Corporation Multifunctional composite microwave air purifier
DE102020129849A1 (de) * 2020-11-12 2022-05-12 Bwt Holding Gmbh Vorrichtung und Verfahren zum Schutz von Trinkwasser vor Mikroorganismen
KR20230121819A (ko) * 2020-12-15 2023-08-21 제이티 인터내셔널 소시에떼 아노님 에어로졸 발생 시스템을 위한 항균 구성 요소
WO2023036929A1 (fr) * 2021-09-13 2023-03-16 Topas Gmbh Technologie-Orientierte Partikel-, Analysen- Und Sensortechnik Dispositif et procédé de séparation de particules à partir d'aérosols pour le conditionnement d'aérosols test destinés à la mesure de pénétration sur des filtres
CN113929257B (zh) * 2021-11-25 2023-08-22 广东先导微电子科技有限公司 一种碘甲烷生产废水的处理方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3327859A (en) * 1963-12-30 1967-06-27 Pall Corp Portable unit for potable water
US4769143A (en) * 1987-02-17 1988-09-06 Or-Tsurim Device for purifying water
EP0364111A1 (fr) * 1988-09-20 1990-04-18 Kabushiki Kaisha Aiaishi Purificateur d'eau
EP0617951A2 (fr) * 1993-03-31 1994-10-05 Tomey Technology Corporation Dispositif portable pour purifier des liquides
WO1994027914A1 (fr) * 1993-06-01 1994-12-08 Alpine Water Purification, Inc. Dispositif de purification d'eau en flux continu
US5518613A (en) * 1994-12-14 1996-05-21 Harrison First International, Inc. Portable water purifying and drinking device

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1064630A (fr) * 1975-04-29 1979-10-16 John J. Doumas Procede et appareil de traitement de l'eau potable
US4769134A (en) * 1985-11-20 1988-09-06 C D Medical Open patient fluid management method and system
JPS62136293U (fr) * 1986-02-20 1987-08-27
US5273649A (en) * 1991-10-07 1993-12-28 Magnusson Jan H Personal water purification systems
US5540972A (en) * 1993-05-28 1996-07-30 Hexacomb Corporation Prestressed honeycomb, method and apparatus therefor
WO1993018837A1 (fr) * 1992-03-20 1993-09-30 Spangrud Bruce D Systeme de purification d'eau
US5490938A (en) * 1993-12-20 1996-02-13 Biopolymerix, Inc. Liquid dispenser for sterile solutions
AUPM800694A0 (en) * 1994-09-09 1994-10-06 Memtec Limited Cleaning of hollow fibre membranes
US5855788A (en) * 1996-02-07 1999-01-05 Kimberly-Clark Worldwide, Inc. Chemically charged-modified filter for removing particles from a liquid and method thereof
US6454941B1 (en) * 1998-12-17 2002-09-24 Corning Incorporated Gravity-flow water filtration device
US6589426B1 (en) * 1999-09-29 2003-07-08 Zenon Environmental Inc. Ultrafiltration and microfiltration module and system
DE10024137A1 (de) * 2000-05-18 2001-11-22 Gert Schlueter Probenzylinder, insbesondere mit einer Filtriervorrichtung für die Wiedergewinnung von Zellmaterial aus Körperflüssigkeiten
US20020175166A1 (en) * 2001-02-12 2002-11-28 Daniel Robinson Panel bin apparatus
US6402949B1 (en) * 2001-06-15 2002-06-11 Jed Ben Banks Portable water filtration system
CN100408160C (zh) * 2001-06-22 2008-08-06 阿尔戈耐德公司 纳米大小的正电性非纺织滤器
IL155435A0 (en) * 2003-04-14 2003-11-23 Bromine Compounds Ltd Solid biocide formulations
US7282147B2 (en) * 2003-10-07 2007-10-16 Phase Inc. Cleaning hollow core membrane fibers using vibration
IL162934A0 (en) * 2004-07-08 2005-11-20 Bromine Compounds Ltd Novel solid compositions for disinfecting water
CN1317056C (zh) * 2005-03-28 2007-05-23 天津大学 中空纤维膜滤装置的冲洗方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3327859A (en) * 1963-12-30 1967-06-27 Pall Corp Portable unit for potable water
US4769143A (en) * 1987-02-17 1988-09-06 Or-Tsurim Device for purifying water
EP0364111A1 (fr) * 1988-09-20 1990-04-18 Kabushiki Kaisha Aiaishi Purificateur d'eau
EP0617951A2 (fr) * 1993-03-31 1994-10-05 Tomey Technology Corporation Dispositif portable pour purifier des liquides
WO1994027914A1 (fr) * 1993-06-01 1994-12-08 Alpine Water Purification, Inc. Dispositif de purification d'eau en flux continu
US5518613A (en) * 1994-12-14 1996-05-21 Harrison First International, Inc. Portable water purifying and drinking device

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120298583A1 (en) * 2009-12-18 2012-11-29 Vestergaard Frandsen Sa Drinking straw with Hollow Fibre Liquid Filter
US8852439B2 (en) * 2009-12-18 2014-10-07 Lifestraw Sa Drinking straw with hollow fibre liquid filter
WO2011110173A1 (fr) 2010-03-08 2011-09-15 Vestergaard Sa Dispositif de purification de l'eau possédant un élément soupape surmoulé
US8173018B2 (en) 2010-08-25 2012-05-08 Dow Global Technologies Llc Fluid filter module including sealed boss
US8261919B2 (en) 2010-08-25 2012-09-11 Dow Global Technologies Llc Fluid filter module including handle
US9352252B2 (en) 2011-04-27 2016-05-31 Lifestraw Sa Water purification device
US9447259B2 (en) 2012-09-28 2016-09-20 Applied Nanostructured Solutions, Llc Composite materials formed by shear mixing of carbon nanostructures and related methods
US20140097146A1 (en) * 2012-10-04 2014-04-10 Applied Nanostructured Solutions, Llc Carbon nanostructure separation membranes and separation processes using same
US9133031B2 (en) 2012-10-04 2015-09-15 Applied Nanostructured Solutions, Llc Carbon nanostructure layers and methods for making the same
US9327969B2 (en) 2012-10-04 2016-05-03 Applied Nanostructured Solutions, Llc Microwave transmission assemblies fabricated from carbon nanostructure polymer composites
WO2014055700A1 (fr) * 2012-10-04 2014-04-10 Applied Nanostructured Solutions, Llc Membranes de séparation à nanostructures de carbone et procédés de séparation
US9107292B2 (en) 2012-12-04 2015-08-11 Applied Nanostructured Solutions, Llc Carbon nanostructure-coated fibers of low areal weight and methods for producing the same
US11053141B2 (en) 2013-10-28 2021-07-06 Vestergaard Sa Water purification device
US10399322B2 (en) 2014-06-11 2019-09-03 Applied Nanostructured Solutions, Llc Three-dimensional printing using carbon nanostructures
US9802373B2 (en) 2014-06-11 2017-10-31 Applied Nanostructured Solutions, Llc Methods for processing three-dimensional printed objects using microwave radiation
USD783773S1 (en) 2015-07-14 2017-04-11 Lifestraw Sa Water purifier
USD782609S1 (en) 2015-07-14 2017-03-28 Lifestraw Sa Water purifier
USD782610S1 (en) 2015-11-09 2017-03-28 Lifestraw Sa Water purifier
WO2019130356A1 (fr) * 2017-12-30 2019-07-04 INDIAN INSTITUTE OF TECHNOLOGY MADRAS (IIT Madras) Dispositif de filtration d'eau portable pour éliminer les impuretés de l'eau à l'aide de cartouches de purification spécifiques aux contaminants
WO2020023993A1 (fr) * 2018-08-01 2020-02-06 Membrane Systems Australia Pty Ltd Système et procédé d'élimination de polluants polyfluorés de l'eau
US11952294B2 (en) 2018-08-01 2024-04-09 Enviropacific Services Limited System and process for removing polyfluorinated pollutants from water
EP3935946A1 (fr) 2020-07-06 2022-01-12 AgXX Dispositif de réduction des microorganismes actifs dans des fluides
WO2022008520A1 (fr) 2020-07-06 2022-01-13 Agxx Intellectual Property Holding Gmbh Dispositif d'appauvrissement de fluides en micro-organismes actifs

Also Published As

Publication number Publication date
TW200906475A (en) 2009-02-16
IL200805A0 (en) 2010-05-17
MX2009009609A (es) 2009-10-20
AP2454A (en) 2012-08-31
BRPI0721407A8 (pt) 2017-06-06
BRPI0808473A8 (pt) 2015-07-07
CN101668580A (zh) 2010-03-10
WO2008110172A2 (fr) 2008-09-18
US20100044321A1 (en) 2010-02-25
BRPI0721407A2 (pt) 2013-04-24
AP2009004999A0 (en) 2009-10-31
BRPI0808473A2 (pt) 2014-07-15
EP2136683A2 (fr) 2009-12-30
AP2009004981A0 (en) 2009-10-31
HK1141215A1 (en) 2010-11-05
AP3005A (en) 2014-10-31
US20100051527A1 (en) 2010-03-04
WO2008110167A1 (fr) 2008-09-18
KR101547362B1 (ko) 2015-08-25
CN101677701A (zh) 2010-03-24
CN101668580B (zh) 2013-06-19
MA31302B1 (fr) 2010-04-01
KR101828603B1 (ko) 2018-03-22
KR20100015483A (ko) 2010-02-12
IL200806A0 (en) 2010-05-17
CN101677701B (zh) 2011-12-28
KR20090127163A (ko) 2009-12-09
EP2139590A1 (fr) 2010-01-06
WO2008110165A1 (fr) 2008-09-18
WO2008110172A3 (fr) 2009-01-15
MA31301B1 (fr) 2010-04-01
KR20150121188A (ko) 2015-10-28
MX2009009608A (es) 2009-10-12
TW200918146A (en) 2009-05-01

Similar Documents

Publication Publication Date Title
US20100051527A1 (en) Microporous filter with an antimicrobial source
EP2512299B1 (fr) Paille pour boisson qui comporte un filtre à liquide à fibres creuses
CA2834281C (fr) Dispositif de purification d'eau portatif entraine par gravite
US20210340029A1 (en) Water Purification Device
ES2485915T3 (es) Dispositivo de purificación de agua que comprende un filtro alimentado por gravedad
WO2009106084A1 (fr) Filtre centrifuge pour liquide
NL1015384C2 (nl) Waterfiltratie-inrichting.
CN104986829B (zh) 净水装置
DK201500144Y3 (da) Filterapparat med hule mikro-porøse membranfibre

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200780052902.8

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07785726

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 200806

Country of ref document: IL

WWE Wipo information: entry into national phase

Ref document number: MX/A/2009/009608

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 5916/CHENP/2009

Country of ref document: IN

ENP Entry into the national phase

Ref document number: 20097021082

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2007785726

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 12450046

Country of ref document: US

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
ENP Entry into the national phase

Ref document number: PI0721407

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20090908