WO2008101727A1 - Katalysatorträgerkörper - Google Patents
Katalysatorträgerkörper Download PDFInfo
- Publication number
- WO2008101727A1 WO2008101727A1 PCT/EP2008/001443 EP2008001443W WO2008101727A1 WO 2008101727 A1 WO2008101727 A1 WO 2008101727A1 EP 2008001443 W EP2008001443 W EP 2008001443W WO 2008101727 A1 WO2008101727 A1 WO 2008101727A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal foam
- layers
- corrugated
- foam layers
- catalyst
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title abstract description 9
- 239000006262 metallic foam Substances 0.000 claims abstract description 68
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims description 47
- 239000011148 porous material Substances 0.000 claims description 10
- 239000006260 foam Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000007789 gas Substances 0.000 description 14
- 239000000919 ceramic Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 239000007769 metal material Substances 0.000 description 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 239000006261 foam material Substances 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 239000003863 metallic catalyst Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- -1 iron-chromium-nickel-aluminum Chemical compound 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- BIJOYKCOMBZXAE-UHFFFAOYSA-N chromium iron nickel Chemical compound [Cr].[Fe].[Ni] BIJOYKCOMBZXAE-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/02—Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present invention relates to a catalyst carrier body comprising a honeycomb body and a housing, wherein the honeycomb body consists of at least three superimposed metal layers, which are each wound with their end faces in a common center to spirally superimposed layers and fixed in the sleeve of the housing, and wherein the metal layers consist of a metal foam.
- the honeycomb bodies used hitherto consist of ceramic or metallic materials, which are usually coated with high-surface-area porous catalytically active metal oxides, which by means of a so-called “washcoat” (a slurry or dispersion of metal oxides, usually in powder form in a liquid) the honeycomb body was applied.
- washcoat a slurry or dispersion of metal oxides, usually in powder form in a liquid
- the catalytically active layer often also contains at least one catalytic active metal, for example platinum, palladium, rhodium, nickel, vanadium, tungsten, etc.
- catalyst is understood as meaning both so-called diesel oxidation catalysts (DOC), H catalysts and also SCR (Selective Catalytic Reduction) catalysts and also three-way catalysts.
- DOC diesel oxidation catalysts
- H catalysts H catalysts
- SCR Selective Catalytic Reduction
- the catalyst carrier body is exposed to high thermal and dynamic loads.
- the catalyst carrier bodies are usually designed in the form of a so-called honeycomb body in order to provide a relatively large surface area for the carrier layer.
- these honeycomb bodies have a plurality of fluid, i. especially for a gas, through-flow channels or openings.
- ceramic, extruded and metallic honeycomb bodies are known, which are typically introduced into a housing, which in turn can be integrated directly into the exhaust gas line or can also be used in front of a diesel particle filter.
- the known ceramic honeycomb bodies can be relatively easily coated with a high-surface-area porous carrier material by means of a washcoat, since ceramic honeycomb bodies have a relatively high surface roughness. sen and the washcoat and thus the porous carrier material can adhere firmly to the ceramic surface.
- metallic honeycomb body are often made of metal sheets or metal foils.
- the honeycomb bodies are produced by alternating arrangement of layer structures or sheets or foils. These can be arranged alternately to each other and then bent S-shaped and / or U-shaped.
- Further metallic honeycomb bodies are known, for example, from DE 10 2005034033. Still further metallic honeycomb bodies and processes for their preparation are described in EP 049 489 A1 or in DE 2856030, the disclosure content of which is incorporated herein by reference in its entirety.
- Catalyst support body (hereinafter also "support body”, “honeycomb body” or simply called “monolith” called) of metal have the advantage that they - compared to ceramic support bodies - heat or heat more quickly and thus usually based on metallic catalysts Carrier bodies have a better response under so-called KaIt start conditions.
- metallic monoliths have an increased mechanical stability as well as a better formability compared to the ceramic honeycomb bodies.
- a disadvantage of the metallic honeycomb bodies or monoliths is their smooth surface, so that they, compared with ceramic honeycomb bodies are much harder to coat, so that generally more binder must be used to achieve sufficient adhesion of the porous support material to the metal surface.
- a catalyst carrier body having a longitudinal axis comprising a honeycomb body and a housing, wherein the honeycomb body consists of at least three metal layers arranged one above the other, each of which is wound with its end sides from a common center to spirally superimposed layers and in the sleeve of Housing are fixed, wherein the metal layers consist of a metal foam, and wherein between two partially planar metal foam layers designed as a corrugated metal foam layer is disposed, wherein the corrugated casing is connected at its outer side to connecting portions with the partially planar Metallschaumlagen.
- Metallic foams as used in the present case are disclosed, for example, in DE 10 2004 014076, to which reference is also hereby made in full. It understands that any other suitable metal foam can also be used for it.
- metal foam as used herein means a foam material of any metal, or any alloy of metals, which may optionally contain other additives such as carbides, etc., and having a plurality of pores, which among themselves are connected so that, for example, a gas can be passed through the foam material.
- the foams can either consist of pure metal or of an alloy, preferably of iron-chromium-nickel alloys or of iron-chromium-nickel-aluminum alloys, for a good relationship between the parameters of strength, brittleness and flexibility cause.
- an alloy preferably of iron-chromium-nickel alloys or of iron-chromium-nickel-aluminum alloys, for a good relationship between the parameters of strength, brittleness and flexibility cause.
- other alloys known to those skilled in the art may also be used,
- metal foams are done, for example, by metal powder is mixed with a metal hydride, which are then compressed by hot pressing or extrusion to a starting material. The starting material is then heated to a temperature above the melting point of the metal, hydrogen being liberated from the hydride and the mixture being foamed. Further possibilities are disclosed in the aforementioned patent application. In addition, for example, gas can be blown into a molten metal, which was previously made foamable by adding solid constituents. For aluminum alloys, 10 to 20% by volume of silicon carbide or alumina is typically added for stabilization. A further production of metal foams from a metal alloy is carried out by a powder metallurgy process.
- Metal foams typically have a high surface area and a corresponding pore distribution. These metal foams are often referred to as open-cell metal foams.
- the use of such porous metal foams in particular allows a reduction in weight of up to 80% of the catalyst carrier body compared with catalyst carrier bodies made of solid sheet metal or of metal and, because of the high porosity, provides a larger flow-through surface for exhaust gases.
- the metal foams have good mechanical strength, which can absorb energy even at low stress levels.
- the open-pored metal foams typically have faster heating rates than the prior art metallic catalyst support bodies, as disclosed, for example, in DE 10 2005 034033.
- the metal foams have pore densities in the range of 110 ppi to 45 ppi (pores per inch) used in the present invention.
- the pores of the foam structures can ideally be described as pentagonal dodecahedra whose edges form the webs of the lattice structure.
- the ratio of large to small diameter of a pentagonal dodecahedron is theoretically 1.6.
- the large diameter varies from about 4 mm (10 ppi) to about 1 mm (45 ppi) and the small diameter from about 1.5 mm (10 ppi) to 0.5 mm (45 ppi).
- the pressure loss in the flow through the metal foam is proportional to the flow rate and the flow rate at lower flow speeds.
- the pressure loss at 10 ppi is about 0.5 bar per cm and 30 ppi about 0.2 bar per cm, which also gives a sufficiently long residence time for the catalytic reaction, which in the with a catalytically active coating provided open-pore metal foam is performed.
- the catalyst support of the present invention has the advantage of being permeable to the metal foam layers for gas components, allowing good mixing of fluids from adjacent channels separated by the foam material. It has also been shown that when passing an exhaust gas through the catalyst support body according to the invention, which is coated with a catalytically active component, a lower mechanical stress on the washcoat coating acts, in particular on the embedded in the metal foam washcoat. This results in a better mechanical long-term stability of the coated honeycomb body. Due to the low mechanical stress, it is also advantageous to have a lower binder content in the washcoat composition, resulting in a higher activity of the catalyst.
- the metallic open-cell foam materials have an extremely low density due to the pores and voids, but have considerable rigidity and strength.
- partially planar here means that only certain regions of the foam have to be planar, but in other regions also a corrugation may be present, for example, by means of the attachment segments, for example by brazing, at the planar sections of the upper and lower enclosures attached lower metal foam layers.
- the ratio of the corrugation length to corrugation height of the corrugated sheath is 0.1: 1 to 1: 0.1, so that the channel structure through which a fluid is to be passed is optimized for the respective conditions and specific requirements will require, such as gas flow, type of gas or fluid.
- Typical size ranges for the corrugation length are in the range of 1.5 to 4 mm and for the corrugation height of 0.5 to 2 mm.
- the corrugated sheath has three-dimensional microstructures, which are, for example, paddable or hook-shaped, which cause even more reinforcing turbulences in the fluid being carried out, so that mixing and better catalysis on the catalytic washcoat are coated Catalyst carrier body can be achieved.
- the metallic material of the two region-wise planar metal foam layers and the metal foam layer formed as a corrugated layer may be the same or different from one another. So that means that e.g. However, the metallic material of the planar planar, the corrugated comprehensive metal foam layers is equal but different from that of the corrugated sheath. Likewise, of course, each individual metal foam layer may consist of a different metallic material.
- connection surfaces continue to have a large extent in the direction of the longitudinal axis, whereby the length available for bending the corrugated sheath length is shortened, resulting in faster destruction of the corrugated sheath under operating conditions.
- a remedy is provided according to the invention.
- the connecting sections may not be so small in their total area that they can no longer hold the corrugated casing under dynamic load, but according to the invention, a reduction of up to 80% of the connecting sections is made possible compared with the prior art.
- These areas have a length of less than 4, more preferably less than 2 mm.
- the mean pore size of the metal foam is more than 450 ⁇ m-1200 ⁇ m, preferably 800 ⁇ m-1200 ⁇ m.
- the partially planar layers on continuous perforations so that a better fluid exchange between see adjacent channels of the catalyst support body according to the invention is achieved.
- only the corrugated body has perforations, and in still other preferred embodiments, all the layers have continuous perforations, so that a particularly good fluid exchange between the separate channels is ensured, so that the catalytic reaction proceeds faster.
- the corrugated layer has a thickness of 2 to 10 mm, very particularly preferably 4 to 6 mm, so that a guaran- Compromise between thickness and mechanical strength or rigidity is achieved.
- the corrugated sheath can additionally comprise an insert which improves the rigidity of the corresponding open-cell metal foam, for example by attaching the metal foam to the Inlay.
- the insert is preferably formed of a very thin sheet or a mesh, such as a mesh of metal wire, which ensures the necessary rigidity and strength, even with thin open-pore metal foam layers.
- the insert will also have continuous perforations, so that the exchange of flowing medium between adjacent channels is not affected by the metal foam layer.
- the metal foam layers have an average density of 1000 to
- the open porosity of the metal foam layers is 80 to 100%.
- the specific surface area is 5 to 14 mm 2 and the thermal conductivity is in the range of 0.5 to 0.3 W / m * K, so that the heating rates are particularly low and the catalyst also cools down quickly after use.
- the at least three-layer structure of the catalyst support body according to the invention by the three different metal foam layers also allows a variation of the applied catalytic coatings.
- each metal foam layer may have a different catalytic coating or, in yet another preferred embodiment, to have the two catalytic layers coated on the planar metal foam layers and on the corrugated layer partially planar metal foam layers have the same catalytic coating and the Welllage a different catalytic coating. In this way, a large number of potential fields of application can be tapped or the function of normally two different catalysts in a single catalyst support body can be realized.
- Figure 1 a detailed view of a corrugated sheath
- Figure 2 a cross section of a spirally wound honeycomb body
- Figure 3 schematic cross sections through different shaped metal foam layers
- FIG. 1 shows a catalyst support body 100 according to the invention, wherein the housing is not shown.
- the honeycomb body consists of three metal layers 105, 106, 107 arranged one above the other, wherein between the two metal foam layers 105, 106, which are completely planar in this case, the metal foam layer formed as corrugated sheath 107 is arranged.
- the three layers are spirally wound with their end faces each starting from the common center about the longitudinal axis 103 and secured in the sleeve of the housing, not shown.
- the corrugated sheath 200 has a shell thickness 201, as well as a corrugation height 202 and a corrugation length 203.
- the shell thickness 201 is preferably in the range of 1,000 ⁇ m to 2,000 ⁇ m.
- the explicit configuration of the corrugated structure is always to be carried out with regard to the expected thermal and dynamic loads of the catalyst carrier body to the exhaust system. For example, well lengths of 1.5 to 4 mm and well heights of 0.5 to 2 mm have proven to be advantageous.
- FIG. 3 shows three different geometric design options for the partially planar metal foam layers 301 and 302 and the corrugated layer 303.
- the metal foam layers 301 and 302 are completely planar, whereas in FIG. 3b they are partially planar and have regions or notches or waves.
- the corrugated layer 303 can either be sinusoidal as shown in FIG. 3a or also have planar regions in regions, as shown in FIGS. 3b and 3c.
- the metallic material for the foams in a specific embodiment is an iron-nickel-chromium-aluminum alloy having a density of 1000 to 1300 g / cm 2 and of 0.3 to 0.9 g / cm 2, respectively.
- the alloy is composed of the following constituents: 50% nickel, 22% iron, 22% chromium, 6% aluminum and a carbon content of less than 0.1% (by weight). It will be understood that other alloys and compositions will find use depending on the field of application.
- the thickness of the individual layers is preferably in the range between 0.1 to 5 mm.
- metal foam layers used in the present invention are an open porosity of 80 to 100%, more preferably 90 to 95%.
- the specific surface area in contact with the gas flowing through is between 7 to 15 mm 2 .
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0916323A GB2459821A (en) | 2007-02-22 | 2008-02-22 | Catalytic converter support body |
US12/527,800 US8071505B2 (en) | 2007-02-22 | 2008-02-22 | Catalytic converter support body |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007008823.1 | 2007-02-22 | ||
DE102007008823A DE102007008823A1 (de) | 2007-02-22 | 2007-02-22 | Katalysatorträgerkörper |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008101727A1 true WO2008101727A1 (de) | 2008-08-28 |
Family
ID=39445805
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/001443 WO2008101727A1 (de) | 2007-02-22 | 2008-02-22 | Katalysatorträgerkörper |
Country Status (4)
Country | Link |
---|---|
US (1) | US8071505B2 (de) |
DE (1) | DE102007008823A1 (de) |
GB (1) | GB2459821A (de) |
WO (1) | WO2008101727A1 (de) |
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WO2009145910A1 (en) * | 2008-05-30 | 2009-12-03 | Corning Incorporated | Low back pressure porous honeycomb and method for producing the same |
DE102009034390B4 (de) * | 2009-07-23 | 2019-08-22 | Alantum Europe Gmbh | Verfahren zur Herstellung von in Gehäuse integrierten Metallschaumkörpern |
WO2014035382A1 (en) * | 2012-08-29 | 2014-03-06 | Otis Elevator Company | Friction brake assembly with an abradable metal foam brake pad |
CN103638985A (zh) * | 2013-11-29 | 2014-03-19 | 宁波科森净化器制造有限公司 | 一种使用螺旋气道延长反应时间的催化剂载体 |
US10598068B2 (en) | 2015-12-21 | 2020-03-24 | Emissol, Llc | Catalytic converters having non-linear flow channels |
US10302017B2 (en) | 2016-04-12 | 2019-05-28 | United Technologies Corporation | Light weight component with acoustic attenuation and method of making |
US10335850B2 (en) | 2016-04-12 | 2019-07-02 | United Technologies Corporation | Light weight housing for internal component and method of making |
US10399117B2 (en) | 2016-04-12 | 2019-09-03 | United Technologies Corporation | Method of making light weight component with internal metallic foam and polymer reinforcement |
US10619949B2 (en) * | 2016-04-12 | 2020-04-14 | United Technologies Corporation | Light weight housing for internal component with integrated thermal management features and method of making |
US10724131B2 (en) | 2016-04-12 | 2020-07-28 | United Technologies Corporation | Light weight component and method of making |
US10323325B2 (en) | 2016-04-12 | 2019-06-18 | United Technologies Corporation | Light weight housing for internal component and method of making |
ES2875507T3 (es) * | 2017-01-31 | 2021-11-10 | Alantum Europe Gmbh | Procedimiento para producir una pastilla de espuma metálica, pastilla de espuma metálica, llenado de catalizador y mezclador estático |
DE102018214929B4 (de) | 2018-09-03 | 2022-01-27 | Vitesco Technologies GmbH | Katalysator mit metallischem Wabenkörper |
CN111022166A (zh) * | 2019-12-29 | 2020-04-17 | 广西辉煌朗洁环保科技有限公司 | 一种汽车发动机的金属泡沫催化净化消声器 |
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WO1999056853A1 (en) * | 1998-05-01 | 1999-11-11 | Engelhard Corporation | Catalyst members having electric arc sprayed substrates and methods of making the same |
WO2004092553A1 (en) * | 2003-04-17 | 2004-10-28 | Ecocat Oy | Porous sheet and substrate having porous sheet(s) for treating exhaust gases of combustion engines |
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DE2856030C2 (de) | 1978-12-23 | 1987-02-12 | Süddeutsche Kühlerfabrik Julius Fr. Behr GmbH & Co KG, 7000 Stuttgart | Verfahren zum Herstellen einer aus Metallfolien gewickelten Trägermatrix für eine Abgaspatrone |
DE3037796C2 (de) | 1980-10-07 | 1983-06-30 | Interatom Internationale Atomreaktorbau Gmbh, 5060 Bergisch Gladbach | Verfahren zum Löten und dessen Verwendung |
DE3743723C1 (de) | 1987-12-23 | 1989-04-20 | Sueddeutsche Kuehler Behr | Verfahren und Vorrichtung zur Herstellung eines Traegerkoerpers fuer einen katalytischen Reaktor |
WO1997032119A1 (en) * | 1996-02-27 | 1997-09-04 | Astro Met, Inc. | Catalytic converter for exhaust gases having a high surface area catalytic core element |
US20010027165A1 (en) * | 1998-05-01 | 2001-10-04 | Michael P. Galligan | Catalyst members having electric arc sprayed substrates and methods of making the same |
DE10217259A1 (de) | 2002-04-18 | 2003-11-13 | Emitec Emissionstechnologie | Katalysator-Trägerkörper mit Wellmantel und Verfahren zu dessen Herstellung |
DE102004014076B3 (de) | 2004-03-19 | 2005-12-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Metallschaumkörper mit offenporiger Struktur sowie Verfahren zu seiner Herstellung |
JP4720101B2 (ja) * | 2004-04-26 | 2011-07-13 | 三菱マテリアル株式会社 | ハニカム触媒の製造方法 |
DE102004051376A1 (de) * | 2004-09-13 | 2006-03-30 | Matthias Mangold | Herstellungsverfahren für ein Abgasreinigungsmittel und Abgasreinigungsmittel |
DE102005034033A1 (de) | 2005-07-20 | 2007-02-15 | Emitec Gesellschaft Für Emissionstechnologie Mbh | Verfahren und Vorrichtung zur Verminderung des Partikelanteils in Abgasen |
JP2009525161A (ja) * | 2005-08-05 | 2009-07-09 | ビーエーエスエフ、カタリスツ、エルエルシー | ディーゼル排気装置及びそのための触媒組成物 |
-
2007
- 2007-02-22 DE DE102007008823A patent/DE102007008823A1/de active Pending
-
2008
- 2008-02-22 WO PCT/EP2008/001443 patent/WO2008101727A1/de active Application Filing
- 2008-02-22 US US12/527,800 patent/US8071505B2/en active Active
- 2008-02-22 GB GB0916323A patent/GB2459821A/en not_active Withdrawn
Patent Citations (2)
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WO1999056853A1 (en) * | 1998-05-01 | 1999-11-11 | Engelhard Corporation | Catalyst members having electric arc sprayed substrates and methods of making the same |
WO2004092553A1 (en) * | 2003-04-17 | 2004-10-28 | Ecocat Oy | Porous sheet and substrate having porous sheet(s) for treating exhaust gases of combustion engines |
Also Published As
Publication number | Publication date |
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GB2459821A (en) | 2009-11-11 |
DE102007008823A1 (de) | 2008-08-28 |
US8071505B2 (en) | 2011-12-06 |
US20100331173A1 (en) | 2010-12-30 |
GB0916323D0 (en) | 2009-10-28 |
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