WO2008081792A1 - パラジウム含有金属担持触媒の再生処理方法、パラジウム含有金属担持触媒およびその製造方法 - Google Patents

パラジウム含有金属担持触媒の再生処理方法、パラジウム含有金属担持触媒およびその製造方法 Download PDF

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Publication number
WO2008081792A1
WO2008081792A1 PCT/JP2007/074885 JP2007074885W WO2008081792A1 WO 2008081792 A1 WO2008081792 A1 WO 2008081792A1 JP 2007074885 W JP2007074885 W JP 2007074885W WO 2008081792 A1 WO2008081792 A1 WO 2008081792A1
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Prior art keywords
palladium
containing metal
loaded catalyst
metal loaded
producing
Prior art date
Application number
PCT/JP2007/074885
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English (en)
French (fr)
Inventor
Naoko Yamada
Koichi Mizutani
Seiichi Kawatou
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Mitsubishi Rayon Co., Ltd.
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Publication date
Application filed by Mitsubishi Rayon Co., Ltd. filed Critical Mitsubishi Rayon Co., Ltd.
Priority to US12/521,626 priority Critical patent/US20100323879A1/en
Priority to CN2007800517938A priority patent/CN101622067B/zh
Priority to KR20097015761A priority patent/KR101489010B1/ko
Priority to JP2008504291A priority patent/JP5290746B2/ja
Publication of WO2008081792A1 publication Critical patent/WO2008081792A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　本発明は、オレフィンまたはα，β－不飽和アルデヒドからα，β－不飽和カルボン酸の製造に使用したパラジウム含有金属担持触媒の再生処理方法を提供する。 　本発明では、オレフィンまたはα，β－不飽和アルデヒドを分子状酸素により液相中で酸化してα，β－不飽和カルボン酸を製造するために使用したパラジウム含有金属担持触媒の再生処理方法において、使用後のパラジウム含有金属担持触媒を、分子状酸素の存在下、１５０～７００°Cの温度で焼成処理することによって、パラジウムの少なくとも一部をパラジウム酸化物に変える焼成工程と、焼成処理されて得られたパラジウム酸化物を還元処理する還元工程とを有する方法により、パラジウム含有金属担持触媒を再生する。
PCT/JP2007/074885 2006-12-28 2007-12-26 パラジウム含有金属担持触媒の再生処理方法、パラジウム含有金属担持触媒およびその製造方法 WO2008081792A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/521,626 US20100323879A1 (en) 2006-12-28 2007-12-26 Method for regenerating palladium-containing metal supported catalyst, palladium-containing metal supported catalyst and method for producing the same
CN2007800517938A CN101622067B (zh) 2006-12-28 2007-12-26 含钯金属负载催化剂的再生处理方法、含钯金属负载催化剂及其制备方法
KR20097015761A KR101489010B1 (ko) 2006-12-28 2007-12-26 팔라듐 함유 금속 담지 촉매의 재생 처리 방법, 팔라듐 함유 금속 담지 촉매 및 그 제조방법
JP2008504291A JP5290746B2 (ja) 2006-12-28 2007-12-26 パラジウム含有金属担持触媒の再生処理方法およびパラジウム含有金属担持触媒の製造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2006355862 2006-12-28
JP2006-355862 2006-12-28
JP2007-303163 2007-11-22
JP2007303163 2007-11-22

Publications (1)

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WO2008081792A1 true WO2008081792A1 (ja) 2008-07-10

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PCT/JP2007/074885 WO2008081792A1 (ja) 2006-12-28 2007-12-26 パラジウム含有金属担持触媒の再生処理方法、パラジウム含有金属担持触媒およびその製造方法

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US (1) US20100323879A1 (ja)
JP (1) JP5290746B2 (ja)
KR (1) KR101489010B1 (ja)
CN (1) CN101622067B (ja)
WO (1) WO2008081792A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010104938A (ja) * 2008-10-31 2010-05-13 Daicel Chem Ind Ltd 銅触媒の再生方法
JP2010279876A (ja) * 2009-06-03 2010-12-16 Jx Nippon Oil & Energy Corp 有機ハイドライドの脱水素システム
JP2013123665A (ja) * 2011-12-13 2013-06-24 Japan Atomic Energy Agency 使用済み触媒金属坦持炭素系触媒を用いた再生触媒金属坦持炭素系触媒の製造方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090023952A1 (en) 2005-02-18 2009-01-22 Mitsubishi Rayon Co., Ltd. Palladium-containing catalyst, method for producing same, and method for producing alpha, beta-unsaturated carboxylic acid
CN106102911B (zh) * 2014-03-12 2020-06-09 陶氏环球技术有限责任公司 再生用于氢化芳香族环氧化物的催化剂的方法
CN111974388B (zh) * 2014-05-23 2023-10-31 三菱化学株式会社 负载金属催化剂、负载金属催化剂的保存方法以及醇的制造方法
CN104399492A (zh) * 2014-11-17 2015-03-11 张立军 一种钯催化剂焙烧再生工艺
CN105646196B (zh) * 2014-12-03 2018-02-23 中国科学院大连化学物理研究所 一种对甲基环己烯甲醛制备4‑甲基‑环己‑3‑烯‑1‑羧酸的方法

Citations (3)

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JPS531693A (en) * 1976-06-29 1978-01-09 Japan Synthetic Rubber Co Ltd Regeneration of unsaturated diester production catalyst
JPS60102939A (ja) * 1983-11-09 1985-06-07 Ube Ind Ltd パラジウム塩触媒の回収再生方法
JPH0220293B2 (ja) * 1981-01-23 1990-05-08 Basf Ag

Family Cites Families (5)

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CN1015513B (zh) * 1988-10-22 1992-02-19 金陵石油化工公司烷基苯厂 非酸性负载型铂催化剂的再生
JP3884695B2 (ja) * 2002-10-28 2007-02-21 三菱レイヨン株式会社 α，β−不飽和カルボン酸製造用触媒
KR101154764B1 (ko) * 2004-02-10 2012-06-18 미츠비시 레이온 가부시키가이샤 α,β-불포화 카복실산 제조용 촉매 및 그의 제조방법, 및α,β-불포화 카복실산의 제조방법
US7446223B2 (en) * 2004-06-04 2008-11-04 Mitsubishi Rayon Co., Ltd. Palladium-containing catalyst and method for producing same
JP4917549B2 (ja) * 2005-01-14 2012-04-18 ダウ グローバル テクノロジーズ エルエルシー チタノシリケートの再生、及び活性な酸化触媒の再構成

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS531693A (en) * 1976-06-29 1978-01-09 Japan Synthetic Rubber Co Ltd Regeneration of unsaturated diester production catalyst
JPH0220293B2 (ja) * 1981-01-23 1990-05-08 Basf Ag
JPS60102939A (ja) * 1983-11-09 1985-06-07 Ube Ind Ltd パラジウム塩触媒の回収再生方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010104938A (ja) * 2008-10-31 2010-05-13 Daicel Chem Ind Ltd 銅触媒の再生方法
JP2010279876A (ja) * 2009-06-03 2010-12-16 Jx Nippon Oil & Energy Corp 有機ハイドライドの脱水素システム
JP2013123665A (ja) * 2011-12-13 2013-06-24 Japan Atomic Energy Agency 使用済み触媒金属坦持炭素系触媒を用いた再生触媒金属坦持炭素系触媒の製造方法

Also Published As

Publication number Publication date
JP5290746B2 (ja) 2013-09-18
KR101489010B1 (ko) 2015-02-02
CN101622067A (zh) 2010-01-06
US20100323879A1 (en) 2010-12-23
JPWO2008081792A1 (ja) 2010-04-30
CN101622067B (zh) 2012-08-15
KR20090101285A (ko) 2009-09-24

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