WO2008068398A3 - Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede dηydrocraquage/hydroconversion et d'hydrotraitement de charges hydrocarbonees - Google Patents

Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede dηydrocraquage/hydroconversion et d'hydrotraitement de charges hydrocarbonees Download PDF

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Publication number
WO2008068398A3
WO2008068398A3 PCT/FR2007/001805 FR2007001805W WO2008068398A3 WO 2008068398 A3 WO2008068398 A3 WO 2008068398A3 FR 2007001805 W FR2007001805 W FR 2007001805W WO 2008068398 A3 WO2008068398 A3 WO 2008068398A3
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Prior art keywords
silicon
containing material
hydroconversion
hydrocracking
group
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PCT/FR2007/001805
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English (en)
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WO2008068398A2 (fr
Inventor
Alexandra Chaumonnot
Patrick Bourges
Original Assignee
Inst Francais Du Petrole
Alexandra Chaumonnot
Patrick Bourges
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Filing date
Publication date
Application filed by Inst Francais Du Petrole, Alexandra Chaumonnot, Patrick Bourges filed Critical Inst Francais Du Petrole
Priority to EP07866473A priority Critical patent/EP2097169A2/fr
Priority to JP2009537666A priority patent/JP5292301B2/ja
Priority to US12/515,862 priority patent/US8821714B2/en
Priority to CN200780043331.1A priority patent/CN101541426B/zh
Publication of WO2008068398A2 publication Critical patent/WO2008068398A2/fr
Publication of WO2008068398A3 publication Critical patent/WO2008068398A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

On décrit un catalyseur comprenant, au moins un matériau à porosité hiérarchisée comprenant du silicium et au moins un élément hydro-deshydrogénant du groupe VIB et/ou du groupe VIII de la classification périodique. Ledit matériau à porosité hiérarchisée comprenant du silicium est constitué d'au moins deux particules sphériques élémentaires, chacune desdites particules sphériques comprenant des nanocristaux zéolithiques ayant une taille de pores comprise entre 0,2 et 2 nm et une matrice à base d'oxyde de silicium, mésostructurée, ayant une taille de pores comprise entre 1,5 et 30 nm et présentant des parois amorphes d'épaisseur comprise entre 1 et 30 nm, lesdites particules sphériques élémentaires ayant un diamètre maximal de 100 μm. La matrice à base d'oxyde de silicium peut contenir de l'aluminium. Le catalyseur renferme également éventuellement au moins un élément dopant en quantité contrôlée choisi parmi le phosphore, le bore et le silicium, éventuellement au moins un élément du groupe VB de la classification périodique des éléments, et éventuellement un élément du groupe VIIA. L'invention concerne également les procédés d'hydrocraquage/hydroconversion et d'hydrotraitement mettant en œuvre ce catalyseur.
PCT/FR2007/001805 2006-11-23 2007-10-29 Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede dηydrocraquage/hydroconversion et d'hydrotraitement de charges hydrocarbonees WO2008068398A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP07866473A EP2097169A2 (fr) 2006-11-23 2007-10-29 Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede d'hydrocraquage/hydroconversion et d'hydrotraitement de charges hydrocarbonees
JP2009537666A JP5292301B2 (ja) 2006-11-23 2007-10-29 階層的多孔度を有する含ケイ素材料をベースとする触媒および炭化水素仕込原料の水素化分解／水素化転化および水素化処理のための方法
US12/515,862 US8821714B2 (en) 2006-11-23 2007-10-29 Catalyst based on a material with a hierarchical porosity comprising silicon, and a process for hydrocracking/hydroconversion and hydrotreatment of hydrocarbon feeds
CN200780043331.1A CN101541426B (zh) 2006-11-23 2007-10-29 基于具有分级孔隙率的含硅材料的催化剂，以及烃进料的加氢裂化/加氢转化和加氢处理的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0610270A FR2909012B1 (fr) 2006-11-23 2006-11-23 Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede d'hydrocraquage/ hydroconversion et d'hydrotraitement de charges hydrocarbonees.
FR0610270 2006-11-23

Publications (2)

Publication Number Publication Date
WO2008068398A2 WO2008068398A2 (fr) 2008-06-12
WO2008068398A3 true WO2008068398A3 (fr) 2008-09-18

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PCT/FR2007/001805 WO2008068398A2 (fr) 2006-11-23 2007-10-29 Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede dηydrocraquage/hydroconversion et d'hydrotraitement de charges hydrocarbonees

Country Status (6)

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US (1) US8821714B2 (fr)
EP (1) EP2097169A2 (fr)
JP (1) JP5292301B2 (fr)
CN (1) CN101541426B (fr)
FR (1) FR2909012B1 (fr)
WO (1) WO2008068398A2 (fr)

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FR2909012B1 (fr) 2006-11-23 2009-05-08 Inst Francais Du Petrole Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede d'hydrocraquage/ hydroconversion et d'hydrotraitement de charges hydrocarbonees.
FR2929264B1 (fr) * 2008-03-31 2010-03-19 Inst Francais Du Petrole Materiau inorganique forme de particules spheriques de taille specifique et presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
FR2931834B1 (fr) * 2008-05-28 2010-07-30 Inst Francais Du Petrole Procede de production de distillats moyens par hydrocraquage de charges issues du procede fischer-tropsch avec un catalyseur a base d'un materiau cristallise
FR2931833B1 (fr) * 2008-05-28 2011-06-10 Inst Francais Du Petrole Procede de production de distillats moyens par hydrocraquage de charges issues du procede fischer-tropsch avec un catalyseur a base d'un materiau amorphe
FR2950897B1 (fr) * 2009-10-06 2012-12-07 Inst Francais Du Petrole Procede d'hydrocraquage classique de charges hydrocarbonees mettant en oeuvre un catalyseur a base de carbure de silicium
US8546286B2 (en) * 2009-12-15 2013-10-01 Exxonmobil Research And Engineering Company Preparation of hydrogenation and dehydrogenation catalysts
RU2012131680A (ru) * 2009-12-24 2014-01-27 Консистенс Ллс Увеличение выхода дистиллятов в процессе низкотемпературного крекинга с использованием наночастиц
FR2969511B1 (fr) * 2010-12-22 2012-12-28 IFP Energies Nouvelles Materiau spherique comprenant des nanoparticules metalliques piegees dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage
FR2969509B1 (fr) * 2010-12-22 2012-12-28 IFP Energies Nouvelles Materiau spherique a base d'heteropolyanions pieges dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage
CN103120948B (zh) * 2011-11-18 2014-12-03 中国科学院兰州化学物理研究所 生物质重油加氢裂化催化剂及其制备方法
FR2984759B1 (fr) * 2011-12-22 2013-12-20 IFP Energies Nouvelles Catalyseur comprenant au moins une zeolithe nu-86, au moins une zeolithe usy et une matrice minerale poreuse et procede d'hydroconversion de charges hydrocarbonees utilisant ce catalyseur
ES2907515T3 (es) 2012-10-16 2022-04-25 Martin Bakker Catálisis por nanopartículas metálicas dispersas en un material de carbono jerárquicamente poroso
CN104043478B (zh) * 2013-03-15 2016-11-16 中国石油化工股份有限公司 一种加氢裂化催化剂及其制备和应用
ES2670004T3 (es) * 2013-07-02 2018-05-29 Saudi Basic Industries Corporation Método para convertir una carga de hidrocarburos de punto de ebullición elevado en productos de hidrocarburos más ligeros en ebullición
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CN104722327B (zh) * 2013-12-18 2018-05-22 武汉凯迪工程技术研究总院有限公司 一种用于费-托合成的金属基整体式膜催化剂及其制备方法
CN105439168B (zh) * 2014-08-28 2018-05-25 中国科学院大连化学物理研究所 一种制备高硅铝比y型分子筛的方法
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WO2008068398A2 (fr) 2008-06-12
FR2909012A1 (fr) 2008-05-30
US8821714B2 (en) 2014-09-02
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FR2909012B1 (fr) 2009-05-08
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