WO2008068139A1 - Agent de traitement de textiles - Google Patents

Agent de traitement de textiles Download PDF

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Publication number
WO2008068139A1
WO2008068139A1 PCT/EP2007/062559 EP2007062559W WO2008068139A1 WO 2008068139 A1 WO2008068139 A1 WO 2008068139A1 EP 2007062559 W EP2007062559 W EP 2007062559W WO 2008068139 A1 WO2008068139 A1 WO 2008068139A1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
liquid
textile treatment
preferred
textile
Prior art date
Application number
PCT/EP2007/062559
Other languages
German (de)
English (en)
Inventor
Rene-Andres Artiga Gonzalez
Jürgen HILSMANN
Anneliese Wilsch-Irrgang
Tobias Segler
Jan-Willem Ruizendaal
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Priority to MX2009005040A priority Critical patent/MX2009005040A/es
Publication of WO2008068139A1 publication Critical patent/WO2008068139A1/fr
Priority to EG2009060851A priority patent/EG25869A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/02—Floating bodies of detergents or of soaps

Definitions

  • the present invention relates to a textile treatment composition containing particles comprising a porous polymer support material, a liquid incorporated into the support material, fragrances, and a coating completely enclosing the support material, wherein the density of the total particle is ⁇ 1 g / cm 3 and wherein the incorporated liquid constitutes at least 30% by weight of the total weight of the porous carrier material loaded with the liquid.
  • the invention relates to the use of this textile treatment agent as an emollient and as a washing aid. It also relates to methods for textile treatment in an automatic washing machine, and a method for manual textile washing.
  • the liquid incorporated in the carrier material according to the invention contains at least 35% by weight, preferably at least 40% by weight, advantageously at least 45% by weight, in particular at least 50% by weight or also 60% by weight, 70% by weight. % or 80 wt .-% of the total weight of the loaded with the liquid porous support material, so is a preferred embodiment.
  • the mass of the coating does not flow into the total weight in this case. It is a great advantage that the carrier material according to the invention can absorb such large quantities of liquid. This corresponds to a liquid depot in the form of solid particles in a solid textile treatment agent.
  • apple-like odor preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) - ⁇ -damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenal-pentyl-methyl butyrate, ethyl methyl butyrate and / or methyl 2-methyl butanoate or
  • cocoa like odor preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal
  • coconut-like odor such as preferably ⁇ -octalactone, ⁇ -nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or ⁇ -decalactone or
  • (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
  • (x) jasmine-like odor preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
  • Pine-like odor preferably ⁇ -p-dimethylstyrene, ⁇ -pinene, bornyl benzoate, ⁇ -terpinene, dihydroterpinyl acetate and / or ⁇ -pinene or
  • Rose-like odor preferably ⁇ -phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1-) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
  • polyvinyl alcohols which are available as white-yellowish powders or granules with degrees of polymerization in the range of about 100 to 2500 (molar masses of about 4000 to 100,000 g / mol), have degrees of hydrolysis of 98-99 or 87-89 mol%. , so still contain a residual content of acetyl groups.
  • the polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis, the saponification number or the solution viscosity.
  • the entire coating is at least 20 wt .-%, more preferably at least 40 wt .-%, most preferably at least 60 wt .-% and in particular at least 80 wt .-% of a polyvinyl alcohol whose degree of hydrolysis 70 bis 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
  • polyethylene oxides are characterized by comprising polyethylene oxides.
  • Polyethylene oxides, PEOX for short, are polyalkylene glycols of the general formula H - [O-CH 2 -CH 2 J n -OH
  • Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
  • nonionic surfactants are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and used on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol in which the alcohol radical may be linear or preferably methyl branched in the 2-position or may contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten.
  • EO ethylene oxide
  • alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • [Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a reduced sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides, for example, by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
  • textile treatment agents which are e.g. at least 1 wt .-%, advantageously 5 to 40 wt .-%, preferably 10 to 30 wt .-% and in particular 15 to 25 wt .-%, of one or more bleaches, in each case based on the agent. It is also possible that the textile treatment agents are completely free of anionic surfactant.
  • bleach catalysts can also be incorporated into textile treatment agents according to the invention.
  • These substances are bleach-enhancing transition metal salts or transition metal complexes such as, for example, Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes.
  • Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with N-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
  • Cellulosic ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof can furthermore be used as graying inhibitors.
  • the agents according to the invention can contain fabric softeners or softening agents
  • the Disteraryldimethylammoniumchlorid but which is increasingly replaced because of its insufficient biodegradability by quaternary ammonium compounds containing ester groups in their hydrophobic residues as predetermined breaking points for biodegradation (Esterquats).
  • QACs are prepared by reacting tertiary amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethyl enoxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethyl enoxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethyl enoxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethyl enoxide produced.
  • alkylating agents e.g. Meth
  • the composition according to the invention contains those active substances which are beneficial to the fiber elasticity, shape retention and tear resistance of the textile fibers.
  • Substituting fibers of medium or high deformation force for example, by stretching the fiber by 80%, this may result in untreated fibers that the fiber is not or only partially returns to their original shape when the deformation force is eliminated. Under certain circumstances, the fiber can even break.
  • the consumer desires textile fibers which do not tear or lose their original shape even when exposed to medium or high deformation or stretching forces.
  • the particles according to the invention have been coated, suitable coating compositions having already been described.
  • the coatings may advantageously be e.g. water-soluble, water-dispersible and / or water-insoluble (co) polymers.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un agent de traitement de textiles contenant notamment des particules polymères qui peuvent contenir de très grandes quantités de parfum et qui en outre peuvent flotter sur l'eau. Cet agent de traitement de textiles permet d'obtenir de très bons résultats en termes d'odeur agréable, en particulier lors du lavage à la main des textiles, de sorte que non seulement les vêtements à laver mais aussi les mains sont parfumées de manière très intense, par exemple lors du lavage à la main de textiles.
PCT/EP2007/062559 2006-12-06 2007-11-20 Agent de traitement de textiles WO2008068139A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2009005040A MX2009005040A (es) 2006-12-06 2007-11-20 Composicion para el tratamiento de textiles.
EG2009060851A EG25869A (en) 2006-12-06 2009-06-07 Textile treatment composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200610057825 DE102006057825A1 (de) 2006-12-06 2006-12-06 Textilbehandlungsmittel
DE102006057825.2 2006-12-06

Publications (1)

Publication Number Publication Date
WO2008068139A1 true WO2008068139A1 (fr) 2008-06-12

Family

ID=39015702

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/062559 WO2008068139A1 (fr) 2006-12-06 2007-11-20 Agent de traitement de textiles

Country Status (4)

Country Link
DE (1) DE102006057825A1 (fr)
EG (1) EG25869A (fr)
MX (1) MX2009005040A (fr)
WO (1) WO2008068139A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107100012B (zh) * 2017-05-25 2021-01-01 浙江汉邦新材料股份有限公司 多功能温敏色变窗帘用智能材料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247498A (en) * 1976-08-30 1981-01-27 Akzona Incorporated Methods for making microporous products
US4973422A (en) * 1989-01-17 1990-11-27 The Procter & Gamble Company Perfume particles for use in cleaning and conditioning compositions
EP0657489A1 (fr) * 1993-12-08 1995-06-14 "Brugg"-Kabel Ag Matière de support poreuse chargée d'additifs
US20030045446A1 (en) * 2001-02-12 2003-03-06 Dihora Jiten Odhavji Delivery system having encapsulated porous carrier loaded with additives
WO2003054130A2 (fr) * 2001-12-20 2003-07-03 Henkel Kommanditgesellschaft Auf Aktien Capsules polymeres parfumees et leur production
DE10247289A1 (de) * 2002-10-10 2004-04-22 Symrise Gmbh & Co. Kg Riechstoffhaltige feste Reinigungsmittel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247498A (en) * 1976-08-30 1981-01-27 Akzona Incorporated Methods for making microporous products
US4973422A (en) * 1989-01-17 1990-11-27 The Procter & Gamble Company Perfume particles for use in cleaning and conditioning compositions
EP0657489A1 (fr) * 1993-12-08 1995-06-14 "Brugg"-Kabel Ag Matière de support poreuse chargée d'additifs
US20030045446A1 (en) * 2001-02-12 2003-03-06 Dihora Jiten Odhavji Delivery system having encapsulated porous carrier loaded with additives
WO2003054130A2 (fr) * 2001-12-20 2003-07-03 Henkel Kommanditgesellschaft Auf Aktien Capsules polymeres parfumees et leur production
DE10247289A1 (de) * 2002-10-10 2004-04-22 Symrise Gmbh & Co. Kg Riechstoffhaltige feste Reinigungsmittel

Also Published As

Publication number Publication date
MX2009005040A (es) 2009-05-25
DE102006057825A1 (de) 2008-06-12
EG25869A (en) 2012-09-12

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