WO2007115871A1 - Composition solide ayant une affinite pour les textiles a base de materiaux fusibles - Google Patents

Composition solide ayant une affinite pour les textiles a base de materiaux fusibles Download PDF

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Publication number
WO2007115871A1
WO2007115871A1 PCT/EP2007/052128 EP2007052128W WO2007115871A1 WO 2007115871 A1 WO2007115871 A1 WO 2007115871A1 EP 2007052128 W EP2007052128 W EP 2007052128W WO 2007115871 A1 WO2007115871 A1 WO 2007115871A1
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WO
WIPO (PCT)
Prior art keywords
textile
affine
solid
compound
composition
Prior art date
Application number
PCT/EP2007/052128
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German (de)
English (en)
Inventor
Wilfried Rähse
Peter Victor
Wolfgang Lahn
Rene-Andres Artiga Gonzalez
Hubert Harth
Mario Sturm
Tobias Segler
Karl-Heinz Scheffler
Konstanze Mayer
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2007115871A1 publication Critical patent/WO2007115871A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08—Processes in which the treating agent is applied in powder or granular form
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the invention relates to a solid, textile-affine composition and its use and preparation. Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile-affine composition.
  • cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl ) - ammonium compounds or N, N-dimethyl-N, N-di (tallow acyloxyethyl) ammonium compounds.
  • a solid, textile-affine composition comprising a matrix of a compound having a melting or softening point in the range of 45 0 C to 225 0 C, as well as distributed therein a textile-affine compound and a perfume.
  • Such a textile-affine composition can be used in the main wash of an automatic washing or cleaning process.
  • the textile-affine composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser.
  • the textile-affine compound and the perfume are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential.
  • the textile-affine compound is selected from polysiloxanes, fabric softening clays, cationic polymers, and mixtures thereof.
  • polysiloxanes and / or cationic polymers as a textile-affine compound in the textile-affine composition is advantageous because they not only have a softening effect, but also enhance the perfume impression on the laundry.
  • softening clays as a textile-affine compound in the textile-affine composition is advantageous since they additionally have a water-softening effect and thus lime deposits on the laundry are prevented.
  • the textile-affine composition contains a combination of at least two textile-affine compounds.
  • the amount of the perfume is 0.1 to 15% by weight, preferably 3 to 10% by weight, and particularly preferably 5 to 8% by weight.
  • the matrix of the solid, textile-affine composition is from 40 to 99.8 weight percent, preferably from 85 to 97 weight percent, of the compound having a melting or softening point in the range of from 45 ° C to 225 ° C contains.
  • the textile-affine composition may contain additional ingredients, preferably selected from the group consisting of dyes, perfume, fillers, pearlescing agents, textile and / or skin care compounds and mixtures thereof.
  • the solid textile-affine composition is in particulate form. It is particularly preferred that the solid textile-affine composition has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. Solid, textile-affine composition with these particle sizes can be particularly well and accurately dose.
  • the invention also relates to the use of a solid, textile-affine composition according to the invention for conditioning textile fabrics.
  • the invention relates to a process for the preparation of a solid, textile-affine composition according to the invention, comprising a matrix of a compound containing a Melting or softening point in the range of 45 ° C to 225 ° C, as well as distributed therein a textile-affine compound and a perfume in which the matrix compound is converted into a melt in the melt, the textile-affine compound and the Perfume be distributed and the resulting mixture is cooled below the melting or softening point of the matrix compound.
  • the invention further relates to a washing or cleaning agent comprising a solid, textile-affine composition according to the invention.
  • the consumer By introducing the textile-affine composition according to the invention into a washing or cleaning agent, the consumer has at his disposal a textile-affine washing or cleaning agent ("2in1" washing or cleaning agent) and he does not need to dose two agents
  • a textile-affine washing or cleaning agent (“2in1" washing or cleaning agent)
  • Introducing a textile-affine composition in the form of a fabric softening composition into a detergent or cleanser then provides the consumer with a fabric softening detergent ("2in1" detergent or cleanser) and does not need two agents (Detergent or fabric softener) and no separate rinse.
  • washing or cleaning agent and the textile-affine composition need not be perfumed, but only the textile-affine composition. Not only does this result in lower costs, it is also beneficial for consumers with sensitive skin and / or allergies.
  • the textile-affine composition contains a matrix of a compound having a melting or softening point in the range of 45 ° C to 225 ° C, and distributed in the matrix a textile-affine compound and a perfume
  • melting point is meant the transition from a solid state to a liquid (free flowing) state.
  • the softening temperature describes the transition from a solid state to a rubbery to viscous melt.
  • the melting and softening temperatures may each be either a certain temperature or a smaller range within the range of 45 ° C to 225 ° C.
  • the matrix of the compound having a melting or softening point in the range of 45 ° C to 225 ° C may, for example, isomalt, polyalkylene glycols, polyvinyl alcohols, polyvinylpyrrolidones and mixtures thereof.
  • the matrix of the solid, textile-affine composition contains preferably 40 to 99.8% by weight, particularly preferably 85 to 97% by weight, of the compound having a melting or softening point in the range from 45 ° C. to 225 ° C. ,
  • Isomalt is a hydrogenated isomaltulose consisting of approximately equal parts of 6-O- ⁇ -D-glucopyranosyl-D-glucitol (GPS, isomaltitol) and 1-O- ⁇ -D-glucopyranosyl-D-mannitol (GPM).
  • Isomalt is a white, odorless powder with a melting point of 145 to 150 0 C.
  • Suitable polyalkylene glycols include in particular polyethylene glycols, which are liquid or solid polymers depending on the chain length. From a molecular weight of 3000, the polyethylene glycols are solid substances and are sold as flakes or powders. Hardness and melting range increase with increasing molecular weight.
  • Polyvinyl alcohols are commercially available as white-yellowish powders or granules with degrees of polymerization in the range of about 500-2500 (molar masses of about 20,000 - 100,000 g / mol).
  • the degree of hydrolysis is 98-99 or 87-89 mol% and thus the polyvinyl alcohols still contain a residual content of acetyl groups.
  • the polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis and / or the saponification number.
  • Fully saponified polyvinyl alcohols have a softening point of 85 ° C. and a melting point of 228 ° C.
  • the corresponding values for partially hydrolyzed (87-89%) products are significantly lower at about 58 ° C. (softening point) or 186 ° C. (melting point).
  • Polyvinylpyrrolidone is a hygroscopic, amorphous powder with a white to light yellow color. Due to its amorphous structure polyvinylpyrrolidone has no melting point, but only a softening temperature, which is about 160 0 C.
  • the matrix of the textile-affine composition may also contain blends of two or more of these materials.
  • the matrix preferably contains isomalt.
  • the textile-affine compound may include, for example, a fabric softening compound, a bleaching agent, a silicone oil, an anti-redeposition agent, an optical brightener, an anti-shrinkage agent, a crease inhibitor, antimicrobial agents, a germicide, a fungicide, an antioxidant, an antistatic agent Ironing aids, repellents and impregnating agents, swelling and sliding agents, UV absorbers and mixtures thereof.
  • these textile-affine compounds can be found in the description of the washing or cleaning agent according to the invention and can also be used as textile-affine compounds in the solid, textile-affine composition.
  • the textile-affine compound is preferably a fabric softening compound and the textile-affine composition is a fabric softening composition. More preferably, the textile-affine compound is a polysiloxane, a fabric softening clay, a cationic polymer or a mixture of at least two of these textile-affine compounds.
  • a preferably usable polysiloxane has at least the following structural unit
  • R 1 independently of one another Ci-C 3 o-alkyl, preferably Ci-C 4 alkyl, in particular methyl or
  • Ethyl, n 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
  • polysiloxane additionally has the following structural unit:
  • R 1 C-rC 3 o-alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
  • R 2 , R 3 independently of one another H or optionally substituted, linear or branched
  • Polydimethylpolysiloxanes are known as efficient textile-affine compounds.
  • Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
  • polysiloxane contains the structural units a) and b).
  • a particularly preferred polysiloxane has the following structure:
  • Suitable polysiloxanes having the structural units a) and b) are available, for example, commercially under the trade name DC2-8566 (ex Dow Corning). According to the invention also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
  • a suitable fabric softening clay is, for example, a smectite clay.
  • Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
  • Montmorillonite clays are the preferred softening clays.
  • Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay.
  • Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
  • the textile softening clays used have a particle diameter of less than 30 ⁇ m, preferably less than 15 ⁇ m, more preferably less than 10 ⁇ m and particularly preferably less than 5 ⁇ m.
  • Suitable cationic polymers include, in particular, those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 and grouped under the collective name "Polyquaternium” The following are some of the more suitable polyquaternium compounds.
  • CTFA International Cosmetic Ingredient Dictionary Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 and grouped under the collective name "Polyquaternium”
  • POLYQUATERNIUM-1 CAS number: 68518-54-7
  • Polyquaternium-2 (CAS Number: 63451-27-4)
  • D Deeffiinniittiioonn [[--NN ((CCHH 33)) 22 22 --CCHH CCHH CCHH 22 22 --NNHH - CC ((OO)) - -NNHH - CCHH 22 CCH 2 CH 2 -N (CH 3 ) 2 -CH 2 CH 2 OCH 2 CH 2 -] 2+ (Cr) 2 Available for example as Mirapol® A-15 (ex Rhodia)
  • Celquat® H 100 or Celquat® L200 available as Celquat® H 100 or Celquat® L200 (ex National Starch)
  • Copolymer of acrylamide and ⁇ -methacrylyloxyethyltrimethylammonium methosulfate for example, available as Nalco 7113 (ex Nalco) or Reten® 210, Reten® 220, Reten® 230, Reten® 240, Reten® 1104, Reten® 1105 or Reten® 1106 (all ex Hercules)
  • POLYQUATERNIUM-6 (CAS Number: 26062-79-3) Definition: Polymer of dimethyldiallylammonium chloride Available, for example, as Merquat® 100 (ex Ondeo-Nalco)
  • POLYQUATERS IUM-10 (CAS Nouns: 53568-66-4; 55353-19-0; 54351-50-7; 81859-24-7; 68610-92-4; 81859-24-7) Definition: Polymeric quaternary ammonium salt of hydroxyethyl cellulose reacted with a trimethylammonium substituted epoxide.
  • Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
  • Luviquat®PQ 11 PN ex BASF
  • Gafquat® 734 Gafquat® 755
  • Gafquat® 755N aternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
  • Quaternary ammonium polymer salt which is obtained by reacting the ethyl methacrylate
  • Luviquat® FC 370 available as Luviquat® FC 370, Luviquat® Style, Luviquat® FC 550 or
  • Polymeric quaternary ammonium salt which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
  • Polymeric quaternary ammonium salt which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
  • Polymeric quaternary ammonium salt obtainable by reaction of polyvinyl octadecyl ether with 2,3-epoxypropylamine.
  • Quatrisoft® Polymer LM 200 (ex Amerchol)
  • Gafquat® HS-100 (ex GAF)
  • Luviquat® Ultracare available as Luviquat® Ultracare (ex BASF)
  • Another suitable textile-affine compound is an alkylamidoammonium lactate, which is available, for example, under the name Dehyquart® 2415 (ex Cognis).
  • the textile-affine composition contains a fabric softening compound and one or more other textile-affine compound (s).
  • the amount of textile-affine compound in the textile-affine composition is 0.1 to 10 wt .-%, and preferably between 2 and 10 wt .-%.
  • perfume oils or fragrances individual perfume compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons can be used. However, preference is given to using mixtures of different fragrances which together form a create an appealing scent. Such perfume oils may also contain natural fragrance mixtures as are available from plant sources.
  • the amount of perfume in the textile-affine composition is preferably between 0.1 and 15 wt .-%, particularly preferably between 3 and 10 wt .-% and most preferably between 5 and 8 wt .-%.
  • the textile-affine composition may optionally contain other ingredients.
  • dyes In order to improve the aesthetic impression of the textile-affine compound, they can be dyed with suitable dyes.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • the textile-affine composition may contain a filler, such as silica.
  • the amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.
  • the textile-affine composition may also contain a pearlescing agent to increase gloss.
  • suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina AGS from Cognis) and PEG-3-distearate.
  • the textile-affine composition may comprise a skin care compound.
  • a skin care compound is understood as meaning a compound or a mixture of compounds which, upon contact of a textile with the detergent, draw on the textile and give an advantage on contact of the textile with skin of the skin compared with a textile which does not interfere with the laundry detergent according to the invention. and detergent was treated.
  • This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
  • the skin care composition is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid, textile-affine composition.
  • the skin care compound may, for example, be: a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof; b) Plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof; c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid
  • the amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the solid, textile affine composition. It may be that the skin care compound also has a textile care effect.
  • the matrix material is converted by heating into a melt.
  • liquids such as water, alcohol, glycerol or liquid polyethylene glycol
  • the amount of liquid added may be up to 15% by weight and is in particular in the range of 5 to 10% by weight.
  • the textile-affine compound, the perfume and, where appropriate, the further ingredients are mixed under the matrix material in the liquid or molten state.
  • the perfume is mixed as late as possible under the solidifying melt, so that the perfume ingredients are not expelled very quickly by evaporation.
  • the resulting mixture is cooled as quickly as possible. Particularly preferably, the cooling takes place within a few seconds.
  • the melt can be solidified in any shape with any (particle) size ,
  • the textile-affine composition has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
  • the textile-affine composition is particularly suitable for conditioning textile fabrics and is brought into contact with the textile fabrics together with a conventional washing or cleaning agent in the (main) wash cycle of a conventional washing and cleaning process.
  • the textile-affine composition can be incorporated into a detergent or cleaning agent.
  • a solid detergent or cleaning agent with 0.1 to 20 wt .-%, preferably 1 to 10 wt .-% of the textile-affine composition according to the invention is mixed.
  • the detergents or cleaners according to the invention contain, in addition to the textile-affine composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
  • the total surfactant content of a detergent is preferably below 40% by weight, and more preferably below 35% by weight, based on the total detergent.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol residue can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 C atoms, for example coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12 alcohols with 3 EO, 7 EO or 4 EO, C 9 n-alcohol with 7 EO, C 3- I 5 alcohols containing 3 EO, 5 EO, 7 EO or 8 EO, Ci 2 -i 8 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C
  • the stated degrees of ethoxylation represent statistical averages, which for a specific product may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples of these are tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants which contain EO and PO groups together in the molecule can also be used according to the invention.
  • block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
  • nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol representing a glucose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1, 2 to 1, 4.
  • Alkyl glycosides are known, mild surfactants.
  • nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
  • Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable.
  • the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.
  • Further suitable surfactants are polyhydroxy fatty acid amides of the formula (VII)
  • R-CO-N- [Z] (VII) in the RCO for an aliphatic acyl radical having 6 to 22 carbon atoms, R1 for hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the group of polyhydroxy fatty acid amides also includes compounds of the formula (VIII)
  • R 1 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms
  • R 2 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms
  • Ci_ 4 alkyl or phenyl radicals are preferred
  • [Z] is a linear polyhydroxyalkyl radical whose alkyl chain having at least two Is substituted hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives of this radical.
  • [Z] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
  • the content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the total detergent or cleaning agent.
  • anionic surfactants for example, those of the sulfonate type and sulfates are used.
  • surfactants of the sulfonate type preferably come C 9 .i 3 -alkylbenzenesulfonates, olefinsulfonate, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as they are, for example, from C 12 -i 8 monoolefins with terminal or internal double bond Containing sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation, into consideration.
  • alkanesulfonates from C 12 _ 18 - obtained alkanes, for example by sulfochlorination or sulfoxidation and subsequent hydrolysis or neutralization.
  • esters of .alpha.-sulfo fatty acids for example the .alpha.-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • sulfated fatty acid glycerol esters are to be understood as meaning the mono-, di- and triesters and mixtures thereof, as in the preparation by esterification of a monoglycerol with 1 to 3 mol fatty acid or in the transesterification of triglycerides with 0.3 to 2 mol Glycerol can be obtained.
  • Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids containing 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
  • Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myrilecyl, cetyl or stearyl alcohol or the C 10 -C 2 o-oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
  • the C 12 -C 16 -alkyl sulfates and C 12 -C 15 -alkyl sulfates and also C 14 -C 15 -alkyl sulfates are preferred.
  • 2,3-alkyl sulfates which can be obtained as commercial products from Shell Oil Company under the name DAN ®, are suitable anionic surfactants.
  • 21 -alcohols such as 2-methyl-branched C 9-11 alcohols having an average of 3.5 moles of ethylene oxide (EO) or C 12 .
  • 18 fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.
  • Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic esters and which are monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • alcohols preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Preferred sulfosuccinates contain C 8 -i 8 -fatty alcohol residues or mixtures of these.
  • Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which by themselves are nonionic surfactants.
  • Sulfosuccinates whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred.
  • alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the Al k (en) yl chain or salts thereof.
  • Particularly preferred anionic surfactants are soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • the content of preferred detergents or cleaning agents to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total washing or cleaning agent.
  • the detergents or cleaning agents may contain further ingredients which further improve the performance and / or aesthetic properties of the washing or cleaning agent.
  • preferred washing or cleaning agents additionally contain one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, diminuungsstoff, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, neutral filler salts and UV absorbers.
  • Suitable builders which may be present in the detergents or cleaners are in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
  • Suitable crystalline, layered sodium silicates have the general formula NaMSi x O 2x + I H 2 O, where M is sodium or hydrogen, x is a number from 1, 9 to 4 and y is a number from 0 to 20 and preferred values for x 2 , 3 or 4 are.
  • Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both ⁇ - and ⁇ -sodium disilicates Na 2 Si 2 O 5 .yH 2 O are preferred.
  • amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties.
  • the dissolution delay compared with conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying.
  • the term "amorphous” is also understood to mean "X-ray amorphous”.
  • the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to a maximum of 50 nm and in particular up to a maximum of 20 nm being preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
  • the finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P.
  • zeolite P zeolite MAP® (commercial product from Crosfield) is particularly preferred.
  • zeolite X and mixtures of A, X and / or P are particularly preferred.
  • Commercially available and preferably usable in the context of the present invention is, for example, also a co-crystallizate of zeolite X and zeolite A (about 80% by weight).
  • Zeolite X which is sold by SASOL under the brand name VEGOBOND AX ® and by the formula
  • zeolite can be used as a spray-dried powder or else as an undried, stabilized suspension which is still moist from its production.
  • the zeolite may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols having 2 to 5 ethylene oxide groups , C 12 -C 14 -FeH- alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols.
  • Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.
  • phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
  • Organic builders which may be present in the detergent or cleaning agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, poly-aspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or malonates, which are preferably used as sodium salts.
  • bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.
  • bleach activators can be incorporated into the detergents or cleaners.
  • bleach activators it is possible to use compounds which, under perhydrolysis conditions, have aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid, are used.
  • Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups.
  • polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxo-hexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2, 5-diacetoxy-2,5-dihydrofuran.
  • TAED tetraacety
  • bleach catalysts can be incorporated into the detergents or cleaning agents.
  • These substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes.
  • Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
  • the washing or cleaning agent may contain enzymes in encapsulated form and / or directly in the washing or cleaning agent.
  • Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, ⁇ -glucanases, oxidases, peroxidases, perhydrolases, mannanases and / or laccases and mixtures of said enzymes in question. All of these hydrolases in the laundry contribute to the removal of blemishes such as proteinaceous, greasy or starchy stains and graying.
  • cellulases and other glycosyl hydrolases can contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils.
  • Oxireductases can also be used for bleaching or inhibiting color transfer.
  • Particularly suitable are bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents.
  • subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
  • enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or Mixtures with lipolytic enzymes of particular interest.
  • lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases.
  • Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
  • As cellulases are preferably cellobiohydrolases, endoglucanases and ß-glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases.
  • the enzymes may be adsorbed to carriers to protect against premature degradation.
  • the proportion of enzymes or enzyme granules directly in the washing or cleaning agent may be, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-%.
  • washing or cleaning agent contains no enzymes.
  • the washing or cleaning agent optionally contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%.
  • the amount of perfume used is also dependent on the type of detergent or cleaning agent. However, it is particularly preferred that the perfume is introduced into the washing or cleaning agent via the textile-affine composition. However, it is also possible for the washing or cleaning agent to contain perfume which is not introduced into the washing or cleaning agent via the textile-affine composition.
  • Suitable dyes In order to improve the aesthetic impression of the detergents or cleaners, they may (optionally only partially) be colored with suitable dyes.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
  • Suitable soil release polymers include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 weight percent and hydroxypropyl groups of 1 to 15 weight percent, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives of Suitable derivatives include the sulfonated derivatives of the phthalic and terephthalic acid polymers
  • Another class of suitable soil release polymers, in particular for cotton-containing textiles are modified, for example alkoxylated and / or quaternized and / or oxidized, Polyamines.
  • the polyamines are for example, polyalkyleneamines, such as polyethyleneamines, or polyalkylenimines, such as polyethylenimines.
  • Preferred examples of this class of soil release polymers are ethoxylated polyethylenimines and ethoxylated polyethyleneamines.
  • Optical brighteners may be added to detergents to eliminate graying and yellowing of the treated fabrics which will attract the fiber and cause lightening and fake bleaching by turning invisible ultraviolet radiation into visible longer wavelength convert light, wherein the absorbed from sunlight ultraviolet light is radiated as pale bluish fluorescence and produces the yellow shade of the grayed or yellowed laundry pure white Suitable compounds originate for example from the substance classes of 4.4.
  • optical brighteners are usually e in amounts between 0 and 0.3 wt .-%, based on the finished detergent or cleaning agent used.
  • Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt.
  • water-soluble colloids are usually organic nature suitable, for example, glue, gelatin, salts of ether sulfonic acids of starch or cellulose or salts of acidic sulfuric acid esters Cellulose or starch.
  • water-soluble polyamides containing acidic groups are suitable for this purpose.
  • soluble starch preparations and other than the above starch products can be used, for example, degraded starch, aldehyde starches, etc.
  • polyvinylpyrrolidone is useful.
  • cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the washing or Detergent used.
  • the laundry detergent or cleaning agent may contain a color transfer inhibitor.
  • the color transfer inhibitor is a polymer or copolymer of cyclic amines such as vinylpyrrolidone and / or vinylimidazole.
  • Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof.
  • polyvinylpyrrolidone PVP
  • polyvinylimidazole PVI
  • copolymers of vinylpyrrolidone and vinylimidazole PVP / PVI
  • the polyvinylpyrrolidones (PVP) used preferably have an average molecular weight of 2,500 to 400,000 and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan® HP 50 or Sokalan® HP 53 available.
  • the copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used preferably have a molecular weight in the range from 5,000 to 100,000.
  • a PVP / PVI copolymer for example from BASF under the name Sokalan® HP 56th
  • the amount of dye transfer inhibitor based on the total amount of the detergent or cleaning agent is preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight, and more preferably from 0.1 to 0.5% by weight. -%.
  • enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which removes hydrogen peroxide in water as a color transfer inhibitor.
  • a mediator compound for the peroxidase for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, it also being possible to additionally use the abovementioned polymeric color transfer inhibitors.
  • textile fabrics in particular of rayon, rayon, cotton and their mixtures, can tend to wrinkle, because the individual fibers are sensitive to bending, buckling, pressing and squeezing transverse to the fiber direction, the detergents or cleaning agents may contain synthetic crease inhibitors.
  • washing or cleaning agents may contain antimicrobial agents.
  • antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostatic agents and bactericides, fungistats and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate, and the compounds according to the invention can be completely dispensed with in these detergents or cleaners ,
  • the detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a slight skin-sensitizing potential.
  • preservatives examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof.
  • a suitable preservative is the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.
  • the detergents or cleaners may contain antioxidants.
  • This class of compounds includes, for example, substituted phenols, hydroquinones, pyrocatechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
  • Antistatic agents increase the surface conductivity and thus allow an improved drainage of formed charges.
  • External anti-aging Statics are usually substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
  • Lauryl (or stearyl) dimethylbenzylammonium chlorides are suitable as antistatic agents for textile fabrics or as an additive to detergents or cleaners, wherein additionally a softening effect is achieved.
  • silicone derivatives can be used in the detergents or cleaners. These additionally improve the rinsing behavior of the washing or cleaning agents by their foam-inhibiting properties.
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
  • the viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C., wherein the silicones can be used in amounts of between 0.2 and 5% by weight, based on the total detergent or cleaning agent.
  • the detergents or cleaners may also contain UV absorbers which are applied to the treated fabrics and improve the light fastness of the fibers.
  • Compounds which have these desired properties are, for example, the compounds which are active by radiationless deactivation and derivatives of benzophenone with substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid.
  • Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • a preferred class of complexing agents are the phosphonates, which in preferred detergents or cleaners in amounts of 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1, 5 wt .-% are included.
  • organophosphonates such as 1-hydroxyethane-1, 1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylene phosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane -1, 2,4-tricarboxylic acid (PBS-AM), which are mostly used in the form of their ammonium or alkali metal salts.
  • organophosphonates such as 1-hydroxyethane-1, 1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylene phosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane -1, 2,4-tricarboxylic acid (PBS-AM), which are mostly used in the form of their ammonium or alkali metal salts.
  • neutral filler salts such as sodium sulfate or sodium carbonate may be included in the detergent or cleaning agent.
  • washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.
  • the detergent or cleaning agent without the textile-affine composition is first prepared by known processes, which may comprise, for example, drying steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post-addition")
  • the resulting product is then mixed with a solid, textile-affine composition.
  • the compaction step may be followed by further compaction and / or shaping steps.
  • Table 1 shows the composition of four textile-affine compositions E1 to E4 according to the invention.
  • anhydrous isomalt was heated to about 145 ° C and thus transferred into a melt.
  • the melt immediately solidified when poured into a cold mold.
  • the textile-affine composition E1 according to the invention exhibited a softening effect on fabrics treated therewith in comparison with water.
  • the textile-affine composition E1 is able to reduce the hardness of the water.
  • washing or cleaning agent a solid, unperfumed washing or cleaning agent with 10% by weight (based on the total amount of finished washing or cleaning agent) of the textile-affine composition E1 (particle size: 1 to 5 mm ) mixed.
  • the washing or cleaning agent according to the invention showed good cleaning and conditioning properties.

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  • Oil, Petroleum & Natural Gas (AREA)
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Abstract

L'invention concerne une composition solide, ayant une affinité pour les textiles, comprenant une matrice d'un composé ayant un point de fusion ou de ramollissement compris entre 45 °C et 225 °C, dans laquelle sont dispersés un composé ayant une affinité avec les textiles et un parfum. L'invention concerne également des agents de lavage ou de nettoyage comprenant ladite composition ayant une affinité pour les textiles.
PCT/EP2007/052128 2006-04-06 2007-03-07 Composition solide ayant une affinite pour les textiles a base de materiaux fusibles WO2007115871A1 (fr)

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DE200610016579 DE102006016579A1 (de) 2006-04-06 2006-04-06 Feste, Textil-weichmachende Zusammensetzung auf Basis eines schmelzbaren Materials
DE102006016579.9 2006-04-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009071373A1 (fr) * 2007-12-07 2009-06-11 Henkel Ag & Co. Kgaa Détergents ou nettoyants à effet soin

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2702162A1 (de) * 1976-02-09 1977-08-18 Procter & Gamble Teilchenfoermiges textilkonditionierungsmittel und dieses enthaltende waschmittel
US4152272A (en) * 1976-10-29 1979-05-01 The Procter & Gamble Company Fabric conditioning composition
EP0036720A1 (fr) * 1980-03-11 1981-09-30 Unilever Plc Composition détergente
EP0469228A1 (fr) * 1990-07-31 1992-02-05 The Procter & Gamble Company Système amélioré de support et de délivrance de parfums pour le lavage du linge
US20050176599A1 (en) * 2000-11-09 2005-08-11 Bergquist Catharine J. Controlled delivery system for household products
WO2005085404A1 (fr) * 2004-02-27 2005-09-15 The Procter & Gamble Company Composition de conditionnement de textile polyvalente presentant un parfum ameliore

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2702162A1 (de) * 1976-02-09 1977-08-18 Procter & Gamble Teilchenfoermiges textilkonditionierungsmittel und dieses enthaltende waschmittel
US4152272A (en) * 1976-10-29 1979-05-01 The Procter & Gamble Company Fabric conditioning composition
EP0036720A1 (fr) * 1980-03-11 1981-09-30 Unilever Plc Composition détergente
EP0469228A1 (fr) * 1990-07-31 1992-02-05 The Procter & Gamble Company Système amélioré de support et de délivrance de parfums pour le lavage du linge
US20050176599A1 (en) * 2000-11-09 2005-08-11 Bergquist Catharine J. Controlled delivery system for household products
WO2005085404A1 (fr) * 2004-02-27 2005-09-15 The Procter & Gamble Company Composition de conditionnement de textile polyvalente presentant un parfum ameliore

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009071373A1 (fr) * 2007-12-07 2009-06-11 Henkel Ag & Co. Kgaa Détergents ou nettoyants à effet soin

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