WO2008060977A3 - Layered catalyst composition - Google Patents

Layered catalyst composition Download PDF

Info

Publication number
WO2008060977A3
WO2008060977A3 PCT/US2007/084207 US2007084207W WO2008060977A3 WO 2008060977 A3 WO2008060977 A3 WO 2008060977A3 US 2007084207 W US2007084207 W US 2007084207W WO 2008060977 A3 WO2008060977 A3 WO 2008060977A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst composition
precursor catalyst
precursor
refractory oxide
layered catalyst
Prior art date
Application number
PCT/US2007/084207
Other languages
French (fr)
Other versions
WO2008060977A2 (en
Inventor
Dean E Rende
Robert L Bedard
Original Assignee
Uop Llc
Dean E Rende
Robert L Bedard
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc, Dean E Rende, Robert L Bedard filed Critical Uop Llc
Publication of WO2008060977A2 publication Critical patent/WO2008060977A2/en
Publication of WO2008060977A3 publication Critical patent/WO2008060977A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J35/30—
    • B01J35/58—
    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B01J35/394—
    • B01J35/397—
    • B01J35/612—

Abstract

A layered catalyst composition, useful for many chemical processes, comprises an inner core and an outer layer comprising an outer refractory oxide and a precursor catalyst composition, with one or more functional surface active constituents integrated on and/or in the substrate surface. The precursor catalyst composition comprises a substantially non-porous substrate having a total surface area between about 0.01 m2/g and 10 m2/g; and, preferably, a predetermined isoelectric point (IEP) obtained in a pH range greater than 0, preferably greater than 6.0, but less than or equal to 14. At least one catalytically-active region may be contiguous or discontiguous and has a mean thickness ≤ about 30 nm. Preferably, the precursor catalyst composition is a functional surface catalyst composition comprising a glass having a SARCNa ≤ about 0.5. The outer refractory oxide and the precursor catalyst composition are intermixed after the precursor catalyst composition is produced.
PCT/US2007/084207 2006-11-11 2007-11-09 Layered catalyst composition WO2008060977A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86542506P 2006-11-11 2006-11-11
US60/865,425 2006-11-11

Publications (2)

Publication Number Publication Date
WO2008060977A2 WO2008060977A2 (en) 2008-05-22
WO2008060977A3 true WO2008060977A3 (en) 2008-07-03

Family

ID=39144309

Family Applications (3)

Application Number Title Priority Date Filing Date
PCT/US2007/084211 WO2008060979A2 (en) 2006-11-11 2007-11-09 Compound catalyst composition
PCT/US2007/084207 WO2008060977A2 (en) 2006-11-11 2007-11-09 Layered catalyst composition
PCT/US2007/084193 WO2008060965A2 (en) 2006-11-11 2007-11-09 Functional surface catalyst composition

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2007/084211 WO2008060979A2 (en) 2006-11-11 2007-11-09 Compound catalyst composition

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US2007/084193 WO2008060965A2 (en) 2006-11-11 2007-11-09 Functional surface catalyst composition

Country Status (6)

Country Link
EP (1) EP2081678A2 (en)
CN (1) CN101583419A (en)
BR (1) BRPI0718718A2 (en)
RU (1) RU2009122378A (en)
TW (3) TW200902146A (en)
WO (3) WO2008060979A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107847913A (en) 2015-07-22 2018-03-27 巴斯夫公司 The high geometrical surface catalyst prepared is produced for vinyl acetate monomer
US11084021B2 (en) 2015-10-27 2021-08-10 W.R. Grace & Co.—Conn Acid-resistant catalyst supports and catalysts
CA3071238A1 (en) * 2017-07-28 2019-01-31 Rohm And Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN115025781B (en) * 2022-06-13 2023-08-29 中国石油大学(华东) Catalyst for catalyzing non-hydrogenation and preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0258942A2 (en) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
US4916107A (en) * 1987-11-27 1990-04-10 Degussa Aktiengesellschaft Catalyst for the selective reduction of nitrogen oxides with ammonia
EP0852966A1 (en) * 1997-01-10 1998-07-15 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying catalyst and exhaust gas purifying method
EP1044935A1 (en) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne A low weight resistant porous glass fiber having physical, chemical or biological properties
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
JP2003284954A (en) * 2002-03-28 2003-10-07 Nippon Shokubai Co Ltd Gold ultra-fine particle carrier, manufacture method therefor and catalyst comprising the carrier
WO2006025613A1 (en) * 2004-09-03 2006-03-09 Toyota Jidosha Kabushiki Kaisha Process for producing exhaust gas purifying catalyst, and exhaust gas purifying catalyst

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0258942A2 (en) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
US4916107A (en) * 1987-11-27 1990-04-10 Degussa Aktiengesellschaft Catalyst for the selective reduction of nitrogen oxides with ammonia
EP0852966A1 (en) * 1997-01-10 1998-07-15 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying catalyst and exhaust gas purifying method
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
EP1044935A1 (en) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne A low weight resistant porous glass fiber having physical, chemical or biological properties
JP2003284954A (en) * 2002-03-28 2003-10-07 Nippon Shokubai Co Ltd Gold ultra-fine particle carrier, manufacture method therefor and catalyst comprising the carrier
WO2006025613A1 (en) * 2004-09-03 2006-03-09 Toyota Jidosha Kabushiki Kaisha Process for producing exhaust gas purifying catalyst, and exhaust gas purifying catalyst

Non-Patent Citations (10)

* Cited by examiner, † Cited by third party
Title
HOELLER VOLKER ET AL: "Three-phase nitrobenzene hydrogenation over supported glass fiber catalysts:reaction kinetics study", CHEMICAL ENGINEERING AND TECHNOLOGY, WEINHEIM, DE, vol. 23, no. 3, March 2000 (2000-03-01), pages 251 - 255, XP009097523, ISSN: 0930-7516 *
KIWI-MINSKER L ET AL: "Glass fiber catalysts for total oxidation of CO and hydrocarbons in waste gases", CATALYSIS TODAY, ELSEVIER, vol. 54, 1999, pages 39 - 46, XP002362223, ISSN: 0920-5861 *
KIWI-MINSKER L ET AL: "Supported glass fibers catalysts for novel multi-phase reactor design", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 54, November 1999 (1999-11-01), pages 4785 - 4790, XP002299322, ISSN: 0009-2509 *
RAINONE F ET AL: "Structural and catalytic properties of vanadia-based fibrous catalysts in toluene partial oxidation", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 244, no. 2, 15 May 2003 (2003-05-15), pages 251 - 263, XP004421334, ISSN: 0926-860X *
SIMONOVA L G ET AL: "Catalysts Based on Fiberglass Supports: I. Physicochemical Properties of Silica Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 5, September 2001 (2001-09-01), pages 693 - 702, XP009097809, ISSN: 1608-3210 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: II. Physicochemical Properties of Alumina Borosilicate Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 6, November 2001 (2001-11-01), pages 828 - 836, XP009097808, ISSN: 1608-3210 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: III. Properties of Supported Metals Pt and Pd) According to Electron-Microscopic and XPS Datana Borosilicate Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 6, 2001, pages 837 - 846, XP009097609 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: IV. Platinum Catalysts Based on Fiberglass Support in Oxidation of Hydrocarbons (Propane and n-Butane) and Sulfur Dioxide", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 43, no. 1, 2002, pages 61 - 66, XP009097611 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fibergless Support in the Selective Hydrogenation of an Ethylen-Acetylene Mixture", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 43, no. 4, 2002, pages 542 - 549, XP009097610 *
YU MATATOV-MEYTAL ET AL: "Cloth catalysts for water denitrification: I. Pd on glass fibers", APPLIED CATALYSIS B: ENVIRONMENTAL, ELSEVIER, vol. 27, 2000, pages 127 - 135, XP009097566, ISSN: 0926-3373 *

Also Published As

Publication number Publication date
TW200848157A (en) 2008-12-16
WO2008060979A3 (en) 2008-10-02
TW200843852A (en) 2008-11-16
WO2008060965A2 (en) 2008-05-22
WO2008060965A3 (en) 2008-08-07
CN101583419A (en) 2009-11-18
WO2008060977A2 (en) 2008-05-22
EP2081678A2 (en) 2009-07-29
WO2008060979A2 (en) 2008-05-22
BRPI0718718A2 (en) 2013-12-03
TW200902146A (en) 2009-01-16
RU2009122378A (en) 2010-12-20

Similar Documents

Publication Publication Date Title
FR2866643A1 (en) Substrate, notably of glass, with a hydrophobic surface having an improved durability of the hydrophobic properties for a wide range of building and vehicle glazing applications
WO2008060989A3 (en) Selective hydrogenation processes using functional surface catalyst composition
WO2008059170A3 (en) Porous layer, its manufacturing process and its applications
EP1394884A3 (en) Electrolyte membrane for fuel cell operable in medium temperature range, fuel cell using the same, and manufacturing methods therefor
WO2008085185A3 (en) Functional porous substrates for attaching biomolecules
EP1813658A3 (en) Polishing liquid for barrier layer
WO2008102902A8 (en) Optical member, optical system using the same, and method for producing optical member
WO2007003826A3 (en) Method for making nanostructures
WO2006036366A3 (en) Method of forming a solution processed device
WO2006112995A3 (en) Glass-based semiconductor on insulator structures and methods of making same
WO2009055572A4 (en) Semiconductor structure and method of manufacture
WO2006055144A3 (en) Gas diffusion medium with microporous bilayer
EP1559677A3 (en) Mixed metal oxide layer and method of manufacture
WO2004102635A3 (en) Methods for preserving strained semiconductor layers during oxide layer formation
WO2007078686A3 (en) Method of polishing a semiconductor-on-insulator structure
WO2008060977A3 (en) Layered catalyst composition
WO2006062902A3 (en) Hydrophilic coating and method of making same
WO2005033367A8 (en) Electrode
WO2009057620A1 (en) Pressure sensor and method for manufacturing the same
WO2008060970A3 (en) Hydrogenation processes using functional surface catalyst composition
WO2008060988A3 (en) Layered catalyst composition
EP1863082A3 (en) Method of producing semiconductor substrate
WO2008060986A3 (en) Layered catalyst composition
WO2008060985A3 (en) Oxidation processes using functional surface catalyst composition
EP1818978A4 (en) Semiconductor storage device and manufacturing method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07864184

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 07864184

Country of ref document: EP

Kind code of ref document: A2