WO2008060988A3 - Layered catalyst composition - Google Patents

Layered catalyst composition Download PDF

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Publication number
WO2008060988A3
WO2008060988A3 PCT/US2007/084222 US2007084222W WO2008060988A3 WO 2008060988 A3 WO2008060988 A3 WO 2008060988A3 US 2007084222 W US2007084222 W US 2007084222W WO 2008060988 A3 WO2008060988 A3 WO 2008060988A3
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WO
WIPO (PCT)
Prior art keywords
catalyst composition
precursor catalyst
precursor
refractory oxide
layered catalyst
Prior art date
Application number
PCT/US2007/084222
Other languages
French (fr)
Other versions
WO2008060988A2 (en
Inventor
Dean E Rende
Robert L Bedard
Original Assignee
Uop Llc
Dean E Rende
Robert L Bedard
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc, Dean E Rende, Robert L Bedard filed Critical Uop Llc
Publication of WO2008060988A2 publication Critical patent/WO2008060988A2/en
Publication of WO2008060988A3 publication Critical patent/WO2008060988A3/en

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    • B01J35/30—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J35/58—
    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B01J35/394—
    • B01J35/397—
    • B01J35/612—
    • B01J35/613—
    • B01J35/615—
    • B01J35/647—
    • B01J35/651—

Abstract

A layered catalyst composition, useful for many chemical processes, comprises an inner core and an outer layer comprising an outer refractory oxide and a precursor catalyst composition with one or more functional surface active constituents integrated on and/or in the substrate surface. The precursor catalyst composition comprises a substantially nonmicroporous substrate having mesopores and macropores, having a total surface area between about 5 m2/g and 300 m2/g; and preferably, a predetermined isoelectric point (IEP) obtained in a pH range less than or equal to 14, preferably ≤ 7.8, but greater than 0. At least one catalytically-active region may be contiguous or discontiguous and has a mean thickness ≤ about 30 nm. Preferably, the precursor catalyst composition is a functional surface catalyst composition comprising a glass having a SARCNa ≤ about 0.5. The outer refractory oxide and the precursor catalyst composition are intermixed after the precursor catalyst composition is produced.
PCT/US2007/084222 2006-11-11 2007-11-09 Layered catalyst composition WO2008060988A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86541006P 2006-11-11 2006-11-11
US60/865,410 2006-11-11

Publications (2)

Publication Number Publication Date
WO2008060988A2 WO2008060988A2 (en) 2008-05-22
WO2008060988A3 true WO2008060988A3 (en) 2008-07-10

Family

ID=39322518

Family Applications (3)

Application Number Title Priority Date Filing Date
PCT/US2007/084216 WO2008060983A2 (en) 2006-11-11 2007-11-09 Compound catalyst composition
PCT/US2007/084196 WO2008060968A2 (en) 2006-11-11 2007-11-09 Functional surface catalyst composition
PCT/US2007/084222 WO2008060988A2 (en) 2006-11-11 2007-11-09 Layered catalyst composition

Family Applications Before (2)

Application Number Title Priority Date Filing Date
PCT/US2007/084216 WO2008060983A2 (en) 2006-11-11 2007-11-09 Compound catalyst composition
PCT/US2007/084196 WO2008060968A2 (en) 2006-11-11 2007-11-09 Functional surface catalyst composition

Country Status (2)

Country Link
TW (3) TW200836829A (en)
WO (3) WO2008060983A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2935103B1 (en) * 2008-08-19 2011-02-11 Inst Francais Du Petrole PROCESS FOR PREPARING A HEART-LAYER MATERIAL HAVING GOOD MECHANICAL RESISTANCE
EP3325144A4 (en) 2015-07-22 2019-01-16 BASF Corporation High geometric surface area catalysts for vinyl acetate monomer production
CN116139923B (en) * 2022-12-28 2024-04-05 济南大学 Method for preparing Cu-based small-pore molecular sieve catalyst by gradient loading method, obtained product and application

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0258942A2 (en) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
US4916107A (en) * 1987-11-27 1990-04-10 Degussa Aktiengesellschaft Catalyst for the selective reduction of nitrogen oxides with ammonia
EP0852966A1 (en) * 1997-01-10 1998-07-15 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying catalyst and exhaust gas purifying method
EP1044935A1 (en) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne A low weight resistant porous glass fiber having physical, chemical or biological properties
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
WO2006025613A1 (en) * 2004-09-03 2006-03-09 Toyota Jidosha Kabushiki Kaisha Process for producing exhaust gas purifying catalyst, and exhaust gas purifying catalyst

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0258942A2 (en) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
US4916107A (en) * 1987-11-27 1990-04-10 Degussa Aktiengesellschaft Catalyst for the selective reduction of nitrogen oxides with ammonia
EP0852966A1 (en) * 1997-01-10 1998-07-15 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifying catalyst and exhaust gas purifying method
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
EP1044935A1 (en) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne A low weight resistant porous glass fiber having physical, chemical or biological properties
WO2006025613A1 (en) * 2004-09-03 2006-03-09 Toyota Jidosha Kabushiki Kaisha Process for producing exhaust gas purifying catalyst, and exhaust gas purifying catalyst

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
KIWI-MINSKER L ET AL: "Glass fiber catalysts for total oxidation of CO and hydrocarbons in waste gases", CATALYSIS TODAY, ELSEVIER, vol. 54, 1999, pages 39 - 46, XP002362223, ISSN: 0920-5861 *
KIWI-MINSKER L ET AL: "Supported glass fibers catalysts for novel multi-phase reactor design", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 54, November 1999 (1999-11-01), pages 4785 - 4790, XP002299322, ISSN: 0009-2509 *
RAINONE F ET AL: "Structural and catalytic properties of vanadia-based fibrous catalysts in toluene partial oxidation", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 244, no. 2, 15 May 2003 (2003-05-15), pages 251 - 263, XP004421334, ISSN: 0926-860X *
SIMONOVA L G ET AL: "Catalysts Based on Fiberglass Supports: I. Physicochemical Properties of Silica Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 5, September 2001 (2001-09-01), pages 693 - 702, XP009097809, ISSN: 1608-3210 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: II. Physicochemical Properties of Alumina Borosilicate Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 6, November 2001 (2001-11-01), pages 828 - 836, XP009097808, ISSN: 1608-3210 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: III. Properties of Supported Metals Pt and Pd) According to Electron-Microscopic and XPS Datana Borosilicate Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 6, 2001, pages 837 - 846, XP009097609 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: IV. Platinum Catalysts Based on Fiberglass Support in Oxidation of Hydrocarbons (Propane and n-Butane) and Sulfur Dioxide", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 43, no. 1, 2002, pages 61 - 66, XP009097611 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fibergless Support in the Selective Hydrogenation of an Ethylen-Acetylene Mixture", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 43, no. 4, 2002, pages 542 - 549, XP009097610 *

Also Published As

Publication number Publication date
WO2008060983A2 (en) 2008-05-22
WO2008060988A2 (en) 2008-05-22
TW200836829A (en) 2008-09-16
WO2008060968A2 (en) 2008-05-22
TW200843853A (en) 2008-11-16
WO2008060968A3 (en) 2008-08-07
WO2008060983A3 (en) 2008-07-03
TW200841929A (en) 2008-11-01

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