WO2008034282A1 - A cooking pot - Google Patents

A cooking pot Download PDF

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Publication number
WO2008034282A1
WO2008034282A1 PCT/CN2006/002389 CN2006002389W WO2008034282A1 WO 2008034282 A1 WO2008034282 A1 WO 2008034282A1 CN 2006002389 W CN2006002389 W CN 2006002389W WO 2008034282 A1 WO2008034282 A1 WO 2008034282A1
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WO
WIPO (PCT)
Prior art keywords
pot
composite structure
layered composite
nano
layer
Prior art date
Application number
PCT/CN2006/002389
Other languages
French (fr)
Chinese (zh)
Inventor
Guohua Wang
Original Assignee
Guohua Wang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Guohua Wang filed Critical Guohua Wang
Priority to PCT/CN2006/002389 priority Critical patent/WO2008034282A1/en
Publication of WO2008034282A1 publication Critical patent/WO2008034282A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J36/00Parts, details or accessories of cooking-vessels
    • A47J36/02Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/021Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only

Definitions

  • the invention relates to a metal kitchen utensil, in particular to an electrochemical method obtained with good corrosion resistance, internal stress ⁇ , low embrittlement, good thermal conductivity, wear resistance, non-toxicity, heat storage and good gloss. Potware. Background technique
  • the pot with stainless steel as the base material still can not completely solve the problem of magnetic permeability of the pot body, which is suitable for the new generation of cooker-electromagnetic furnace which is becoming more and more popular.
  • the heat conduction and heat storage performance are improved only by partial (bottom) with the composite bottom process.
  • the manufacturing cost has risen sharply, and a set of high-quality stainless steel composite bottom pots often cost hundreds of dollars.
  • the new materials and new technologies make the kitchen utensils also have the qualities of heat conduction, heat storage and magnetic permeability, which become the cravings of the market and have broad application. prospect.
  • the object of the present invention is to overcome the defects of the existing pots and provide a new type of knot.
  • the technical problem to be solved is that it has a strong adhesion nano-deposited layer, which can simultaneously have the properties of wear resistance, corrosion resistance, heat conduction and heat storage, and good magnetic permeability, thereby being more suitable for practical use.
  • a pot includes a bottom and a pot, wherein the bottom of the pot is a layered composite structure, the layered composite structure comprises: a base layer; and two implant layers are respectively located on both sides of the base And two nano-deposited layers, respectively, outside the implant layer described above.
  • the layered composite structure comprises: a base layer; two implant layers respectively located on both sides of the base; and two nano-deposited layers, respectively located in the above-mentioned plant Beyond the layer.
  • the aforementioned cookware further includes a lid.
  • the outer side of the pot is symmetrically provided with two pot ears.
  • the base layer is a metal plate layer composed of an alloy formed of steel, copper, aluminum or a combination of the above materials.
  • a wok according to the present invention has a pot body, the pot body is a layered composite structure, the layered composite structure comprises: a base layer; two implant layers, respectively located on both sides of the base; and two nanometers The deposited layers are located outside of the implant layers described above.
  • the outer side of the pot body is provided with a pot handle.
  • the outer side of the pot body is further provided with a pot ear, and the pot ear is symmetrically arranged with the above-mentioned pot handle.
  • the pot of the present invention has at least the following advantages:
  • the pot Since the invention has a multi-layer composite structure, the pot has excellent heat conduction, heat storage and magnetic permeability, which fundamentally overcomes the shortcomings of the existing stainless steel kitchen utensils, and is more suitable for a new generation of cooker-electromagnetic furnace.
  • the pot improves the surface properties of substrates such as steel, copper and aluminum, which are not only non-toxic, wear-resistant, glossy to mirror, and A strong protective mold is added to the surface to prevent contamination by water, mold, acid and alkali liquid, and dust, which is easier to clean and greatly improves the cooking environment.
  • the pot of the special structure of the invention has a strong adhesion nano-deposited layer, and can have the functions of wear resistance, corrosion resistance, heat conduction and heat storage, and good magnetic permeability, so that it is more suitable for practical use. It has many advantages and practical values as described above, and it has no similar structural design published in the same kind of products.
  • FIG. 1 is a schematic illustration of a preferred embodiment of the pan of the present invention.
  • Figure 2 is a schematic view showing the structure of the wok of the present invention.
  • Figure 3 is a schematic view of a layered composite structure of an embodiment of the present invention.
  • Fig. 5 is an electron micrograph of a nano-deposited layer of a layered composite structure of an embodiment of the present invention.
  • Fig. 6 is a photograph of a particle electron diffraction of a nano-deposited layer of the present invention.
  • Figure 7 is an energy spectrum of the nano-deposited layer of the present invention. The best way to achieve the invention
  • FIG. 1 and FIG. 3 are schematic views of a preferred embodiment of the present invention and a schematic view of a layered composite structure.
  • the preferred embodiment is a pot, which is a steel container having a pot bottom 1 brazed with a steel plate or a copper plate or an aluminum plate or a combination thereof; the pot 2 is connected to the bottom 1 of the pan and is equipped with a solder joint Or riveted handle or pot ear 3.
  • the bottom 1 of the pan is a five-layer laminated composite structure including a base layer 11; two layers of implant layers 12 respectively located on both sides of the base layer; and two layers of nano-deposited layers 13, They are located outside of the implant layer 12 described above.
  • the material of the base layer 11 described above is an alloy formed by a combination of steel, copper, aluminum or the above materials.
  • the implant layer 12 is formed by electrochemically implanting nickel molecules between the layers of the substrate layer 11, and the physical properties are between the base layer 11 and the nano-deposited layer 13, and the function is to deposit nano-deposits.
  • the layer 11 is tightly bonded to the base layer 11 and forms a transition zone of physical properties between the base layer 11 and the nano-deposited layer 13, thereby eliminating stress concentration, stress and high temperature between the base layer 11 and the nano-deposited layer 13.
  • the nano-deposited layer 13 does not peel off.
  • the nano-deposited layer 13 has a particle size of less than 45 nm. Color silvery white yellow; specific gravity 9. Og / cm 3 , atomic weight 60. 69-63. 88; atomic order 29-35; melting point greater than 1800 ° C; tensile strength greater than 500 Mpa; wear resistance greater than 35 TWI; 4. 0%; hardness 400-600HV; corrosion resistance: salt spray test face greater than 1000 hours; oxidation resistance: chemical stability at atmospheric temperature, oxidation and color change at 700 °C. Easy to polish into mirror surface; good flexibility; argon welding, soldering; internal stress 0- 50Mpa; good processability.
  • the above-mentioned pot 2 also adopts the same five-layer laminated composite structure as the bottom 1 of the pot.
  • the pan may also include a lid 4 for covering the pan to provide a wider range of use.
  • FIG. 2 is a schematic structural view of the wok set forth in the present invention. It has a pot body 21 which is a layered composite structure which is the same as the layered composite structure described in the above embodiment; a pot handle 22 is provided outside the pot body 21; The pot handle 22 is symmetrically disposed with a pot ear 23 on the outside of the pot body 21.
  • the manufacturing method of the pan according to the present invention mainly comprises the following steps:
  • the pot body is formed.
  • the material is made of SPCD 5 1. 5 steel plate to make the pot; Q235 5 3 steel plate is used as the raw material to make the composite pot bottom; the shape is formed into a pot by the press; then it is expanded by the press; then the edge is cut by the press; Frequency brazing, forming a composite pot bottom; forming the entire pot body in the bottom turning and chamfering along the pot; surface cleaning and sand blasting of the pot body, the standard is no rust, no oil.
  • Nano-depositing, nano-depositing on both the inner and outer surfaces of the pot The pot of the invention
  • the nano-deposition is realized by electroplating method, and the composition of the electroplating solution is: using nickel sulfamate as the main liquid boric acid
  • PH value stabilizer sulfamic acid is the main agent for lowering the pH value
  • nickel carbonate is the main agent for increasing the pH value
  • pure nickel with a purity greater than 99.99% is selected as the target; the circulation rate of the bath is controlled to ensure the groups of the bath The ion concentration of the fraction is uniform.
  • the surface is polished
  • Test method The pot formed according to the above method was tested on the layered composite structure, and the results were as follows: Test method:
  • the surface of the vertical steel plate coating of J0-780 type EDM machine was used to cut the thickness of 0. 2 hidden test piece, ground to a thickness of 100 ⁇ m, and then ion thinned until the center of the sample was perforated.
  • the observation of the structure and the electron diffraction phase were carried out on a Hitachi H-800 transmission electron microscope, and the composition was measured using a Phillips PV900 spectrometer.
  • the transmission electron microscope has an accelerating voltage of 150 kV.
  • FIG. 4 there is an electron micrograph of the layered composite structure of the present invention. It can be seen that there is a three-layer structure in which the black portion is the base layer, the gray portion outside the base layer is the implant layer, and the implant layer is the nano-deposited layer.
  • FIG. 5 it is an electron micrograph of the nano-deposited layer. Its microstructure is granular, measured by a ruler, and the particle size is between 25 - 60 nm.
  • FIG. 7 is an energy spectrum of the nano-deposited layer of the present invention. Quantitative analysis of its components Fruit is (% by weight): Ni: 99. 90%; Si: 0. 10°/. .
  • the pot of the present invention employs a five-layered layered composite structure comprising a base layer; two layers of implanted layers, respectively located on either side of the base layer; and two layers of nano-deposited layers, respectively located outside of the implanted layer.
  • the above-mentioned base material t is an alloy formed by a combination of steel, copper, aluminum or the above materials.
  • the pot of the special structure of the invention has a strong adhesion nano-deposited layer, and can have the functions of abrasion resistance, corrosion resistance, heat conduction and heat storage, and magnetic permeability, so that it is more suitable for practical use.

Abstract

A cooking pot includes a pot bottom, a pot side and a handle or a lug welded or riveted together. The pot bottom is made up of five layers, that is, a basal body layer, two embedded layers arranged at the both sides of the basal body layer respectively, and two nanometer deposites arranged at the outsides of the embedded layers respectively. The material of the basal body can be steel, Cu, Al or alloy made up of the said materials.

Description

锅 具 技术领域  Cookware technology
本发明涉及一种金属厨具 , 特别是涉及一种经电化学方法获得的具有 耐蚀性佳、 内应力氐、 低脆化、 导热性好、 耐磨、 无毒、 蓄热、 光泽度好 的锅具。 背景技术  The invention relates to a metal kitchen utensil, in particular to an electrochemical method obtained with good corrosion resistance, internal stress 氐, low embrittlement, good thermal conductivity, wear resistance, non-toxicity, heat storage and good gloss. Potware. Background technique
业界基于厨具市场的需求, 为了能够使厨具更加美观、 实用、 性能优 越,传统的铁、 铝制厨具渐被各种新厨具所取代,不锈钢厨具美观亮丽、 耐 磨、 耐蚀的性能使不锈钢作为厨具的首选基材。 同时, 不锈钢的导热、 蓄 热、 导磁性差成为不锈钢厨具的重要缺陷, 尤其是应用在锅具上, 上述缺 陷更为明显。 为弥补不锈钢的导磁、 导热性能差的缺陷, 普遍采用铜、 铝 等导热、 蓄热性能好的金属材料制成复合底的锅具。 但以不锈钢作为基材 的锅具仍不能完全解决锅体导磁问题以适用于日渐普及的新一代灶具-电 磁炉; 导热、 蓄热性能只在局部 (底部) 以复合底工艺求得改善。 同时使 制造成本大幅上升, 一套品质优良的不锈钢复合底锅具售价常达数百美元。  In the industry based on the needs of the kitchenware market, in order to make the kitchen utensils more beautiful, practical and superior in performance, the traditional iron and aluminum kitchen utensils are gradually replaced by various new kitchen utensils. The stainless steel kitchen utensils are beautiful, bright, wear-resistant and corrosion-resistant. The preferred substrate for kitchenware. At the same time, the heat conduction, heat storage and magnetic permeability difference of stainless steel have become an important defect of stainless steel kitchen utensils, especially when applied to pots, and the above defects are more obvious. In order to make up for the defects of the magnetic permeability and thermal conductivity of stainless steel, a ceramic material with a heat-conducting and heat-storing property such as copper or aluminum is generally used as a composite bottom. However, the pot with stainless steel as the base material still can not completely solve the problem of magnetic permeability of the pot body, which is suitable for the new generation of cooker-electromagnetic furnace which is becoming more and more popular. The heat conduction and heat storage performance are improved only by partial (bottom) with the composite bottom process. At the same time, the manufacturing cost has risen sharply, and a set of high-quality stainless steel composite bottom pots often cost hundreds of dollars.
因此, 在保持厨具美观亮丽、 耐磨、 耐蚀性能的前提下,以新材料、 新 技术使厨具还同时兼具导热、 蓄热、 导磁性好的品质, 成为市场的渴求,具 有广阔的应用前景。  Therefore, under the premise of maintaining the beautiful, bright, wear-resistant and corrosion-resistant performance of the kitchen utensils, the new materials and new technologies make the kitchen utensils also have the qualities of heat conduction, heat storage and magnetic permeability, which become the cravings of the market and have broad application. prospect.
由此可见,上述现有的金属厨具尤其是锅具显然仍存在有不便与缺陷, 而亟待加以进一步改进。 有鉴于上述现有的锅具存在的缺陷, 本发明人基 于从事此类产品设计制造多年丰富的实务经验及专业知识, 并配合学理的 运用, 积极加以研究创新, 以期创设一种新的锅具, 能够改进一般现有的 锅具存在的缺陷, 使其更具有实用性。 经过不断的研究、 设计, 并经反复 试作样品及改进后, 终于创设出确具实用价值的本发明。 发明内容  It can be seen that the above-mentioned existing metal kitchen utensils, especially the pots, obviously still have inconveniences and defects, and need to be further improved. In view of the defects of the above-mentioned existing pots, the inventors have actively researched and innovated based on the practical experience and professional knowledge of designing and manufacturing such products for many years, in order to create a new pot. , can improve the defects of the existing existing pots, making it more practical. After continuous research, design, and repeated trials of samples and improvements, the invention has finally been created with practical value. Summary of the invention
本发明的目的在于, 克服现有的锅具存在的缺陷, 而提供一种新型结 构的锅具, 所要解决的技术问题是使其具有强附着力纳米沉积层, 能够同 时具备耐磨耐蚀与导热蓄热、 导磁性好的性能, 从而更加适于实用。 The object of the present invention is to overcome the defects of the existing pots and provide a new type of knot. The technical problem to be solved is that it has a strong adhesion nano-deposited layer, which can simultaneously have the properties of wear resistance, corrosion resistance, heat conduction and heat storage, and good magnetic permeability, thereby being more suitable for practical use.
本发明的 ϋ的及解决其技术问题采用以下技术方案来实现。 依据本发 明提出的一种锅具, 包括锅底和锅帮, 其中所述的锅底为层状复合结构,该 层状复合结构包括: 基体层; 二植入层, 分别位于基体的两侧;以及二纳米 沉积层, 分别位于上述的植入层之外。  The technical problems of the present invention and solving the technical problems are achieved by the following technical solutions. According to the present invention, a pot includes a bottom and a pot, wherein the bottom of the pot is a layered composite structure, the layered composite structure comprises: a base layer; and two implant layers are respectively located on both sides of the base And two nano-deposited layers, respectively, outside the implant layer described above.
本发明的目的及解决其技术问题还采用以下技术措施来进一步实现。  The object of the present invention and solving the technical problems thereof are further achieved by the following technical measures.
前述的锅具, 其中所述的锅帮为层状复合结构, 该层状复合结构包括: 基体层; 二植入层, 分别位于基体的两侧; 以及二纳米沉积层, 分别位于 上述的植入层之外。  In the above-mentioned pot, wherein the pot is a layered composite structure, the layered composite structure comprises: a base layer; two implant layers respectively located on both sides of the base; and two nano-deposited layers, respectively located in the above-mentioned plant Beyond the layer.
前述的锅具, 其还包括一锅盖。  The aforementioned cookware further includes a lid.
前述的锅具, 其中所述的其中所述的锅帮的外侧对称设有两只锅耳。 前述的锅具, 其中所述的基体层为钢、 铜、 铝或上述材料组合而形成 的合金构成的金属板层。  In the above-mentioned pot, the outer side of the pot is symmetrically provided with two pot ears. In the above-mentioned pan, the base layer is a metal plate layer composed of an alloy formed of steel, copper, aluminum or a combination of the above materials.
本发明的目的及解决其技术问题还采用以下技术方案来实现。 依据本 发明提出的一种炒锅, 其具有一锅体, 该锅体为层状复合结构,该层状复合 结构包括: 基体层; 二植入层, 分别位于基体的两侧; 以及二纳米沉积层, 分别位于上述的植入层之外。  The object of the present invention and solving the technical problems thereof are also achieved by the following technical solutions. A wok according to the present invention has a pot body, the pot body is a layered composite structure, the layered composite structure comprises: a base layer; two implant layers, respectively located on both sides of the base; and two nanometers The deposited layers are located outside of the implant layers described above.
本发明的目的及解决其技术问题还采用以下技术措施来进一步实现。  The object of the present invention and solving the technical problems thereof are further achieved by the following technical measures.
前述的炒锅, 其中所述的锅体外侧设有锅柄。  In the aforementioned wok, the outer side of the pot body is provided with a pot handle.
前述的炒锅, 其中所述的锅体外侧还设有一锅耳, 该锅耳与上述的锅 柄为对称设置。  In the aforementioned wok, the outer side of the pot body is further provided with a pot ear, and the pot ear is symmetrically arranged with the above-mentioned pot handle.
借由上述技术方案, 本发明的锅具至少具有下列优点:  With the above technical solution, the pot of the present invention has at least the following advantages:
由于本发明具有多层复合结构,使锅具具有优良的导热、 蓄热、 导磁性 能,从根本上克服了现有不锈钢厨具的缺点, 使其更适用于新一代灶具一电 磁炉。  Since the invention has a multi-layer composite structure, the pot has excellent heat conduction, heat storage and magnetic permeability, which fundamentally overcomes the shortcomings of the existing stainless steel kitchen utensils, and is more suitable for a new generation of cooker-electromagnetic furnace.
另外, 由于在基体层外具有了植入层和纳米沉积层, 使锅具改进了如 钢, 铜和铝等基材的表面性能, 不仅无毒、 耐磨、 光泽度可达镜面, 而且 如同在表面增加了一层坚固的保护模,防止水,霉菌,酸碱液体,和灰尘等污 染, 更易于清洁, 大大改善了烹饪作业环境。 综上所述, 本发明特殊结构的锅具, 其具有强附着力纳米沉积层,能够 同时具备耐磨耐蚀与导热蓄热、 导磁性好的性能, 从而更加适于实用。 其 具有上述诸多的优点及实用价值, 并在同类产品中未见有类似的结构设计 公开发表或使用而确属创新, 其不论在结构上或功能上皆有较大的改进,在 技术上有较大的进步, 并产生了好用及实用的效果, 且较现有的锅具有增 进的多项功效, 从而更加适于实用, 而具有产业的广泛利用价值,诚为一新 颖、 进步、 实用的新设计。 In addition, due to the presence of an implant layer and a nano-deposited layer outside the substrate layer, the pot improves the surface properties of substrates such as steel, copper and aluminum, which are not only non-toxic, wear-resistant, glossy to mirror, and A strong protective mold is added to the surface to prevent contamination by water, mold, acid and alkali liquid, and dust, which is easier to clean and greatly improves the cooking environment. In summary, the pot of the special structure of the invention has a strong adhesion nano-deposited layer, and can have the functions of wear resistance, corrosion resistance, heat conduction and heat storage, and good magnetic permeability, so that it is more suitable for practical use. It has many advantages and practical values as described above, and it has no similar structural design published in the same kind of products. It is truly innovative, and it has great improvement in structure or function. Great progress, and has produced a good and practical effect, and has more enhanced effects than the existing pot, which is more suitable for practical use, and has extensive use value of the industry, sincerely a novel, progressive, practical New design.
上述说明仅是本发明技术方案的概述, 为了能够更清楚了解本发明的 技术手段, 并可依照说明书的内容予以实施, 以下以本发明的较佳实施例 并配合附图详细说明如后。  The above description is only an overview of the technical solutions of the present invention, and the technical means of the present invention can be more clearly understood and implemented in accordance with the contents of the specification. Hereinafter, the preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
本发明的具体实施方式由以下实施例及其附图详细给出。 附图的简要说明  Specific embodiments of the present invention are given in detail by the following examples and the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS
图 1是本发明锅具较佳实施例的示意图。  BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic illustration of a preferred embodiment of the pan of the present invention.
图 2是本发明炒锅的结构示意图。  Figure 2 is a schematic view showing the structure of the wok of the present invention.
图 3是本发明的实施例的层状复合结构示意图。  Figure 3 is a schematic view of a layered composite structure of an embodiment of the present invention.
图 4是本发明的实施例的层状复合结构的电镜照片。  4 is an electron micrograph of a layered composite structure of an embodiment of the present invention.
图 5是本发明的实施例的层状复合结构的纳米沉积层的电镜照片 图 6是本发明的纳米沉积层的颗粒电子衍射照片。  Fig. 5 is an electron micrograph of a nano-deposited layer of a layered composite structure of an embodiment of the present invention. Fig. 6 is a photograph of a particle electron diffraction of a nano-deposited layer of the present invention.
图 7是本发明的纳米沉积层的能谱图。 实现发明的最佳方式  Figure 7 is an energy spectrum of the nano-deposited layer of the present invention. The best way to achieve the invention
为更进一步阐述本发明为达成预定发明目的所采取的技术手段及功 效,以下结合附图及较佳实施例, 对依据本发明提出的金属厨具及其制造方 法其具体实施方式、 结构、 制造方法、 步骤、特征及其功效,详细说明如后。  In order to further explain the technical means and efficacy of the present invention for achieving the intended purpose of the present invention, the metal kitchen utensil and the manufacturing method thereof according to the present invention, the specific embodiment, structure and manufacturing method thereof are described below with reference to the accompanying drawings and preferred embodiments. , steps, features and their effects, as detailed below.
请参阅图 1和图 3所示, 是本发明一较佳实施例的示意图以及层状复 合结构示意图。 该较佳实施例是锅具, 是钢制的容器, 其具有与钢板或铜 板或铝板或其组合经钎焊制成的锅底 1; 锅帮 2与锅底 1连接, 并配有焊合 或铆合而成的把手或锅耳 3。 其中锅底 1是采用五层层状复合结构,其包括 基体层 11;两层植入层 12,分别位于基体层的两侧;以及两层纳米沉积层 13, 分别位于上述的植入层 12之外。 上述的基体层 11的材质是钢、 铜、 铝或 上述材料之间的组合而形成的合金。 Please refer to FIG. 1 and FIG. 3, which are schematic views of a preferred embodiment of the present invention and a schematic view of a layered composite structure. The preferred embodiment is a pot, which is a steel container having a pot bottom 1 brazed with a steel plate or a copper plate or an aluminum plate or a combination thereof; the pot 2 is connected to the bottom 1 of the pan and is equipped with a solder joint Or riveted handle or pot ear 3. The bottom 1 of the pan is a five-layer laminated composite structure including a base layer 11; two layers of implant layers 12 respectively located on both sides of the base layer; and two layers of nano-deposited layers 13, They are located outside of the implant layer 12 described above. The material of the base layer 11 described above is an alloy formed by a combination of steel, copper, aluminum or the above materials.
上述的该植入层 12,是经电化学方法使镍分子在基体层 11组织间的植 入形成的, 其物理性质介于基体层 11与纳米沉积层 13之间, 其作用是使 纳米沉积层 11与基体层 11紧密结合、 并在基体层 11与纳米沉积层 13之 间形成物理性质的过渡带, 从而消除了基体层 11与纳米沉积层 13之间的 应力集中、 受力与高温作用时纳米沉积层 13不剥脱。  The implant layer 12 is formed by electrochemically implanting nickel molecules between the layers of the substrate layer 11, and the physical properties are between the base layer 11 and the nano-deposited layer 13, and the function is to deposit nano-deposits. The layer 11 is tightly bonded to the base layer 11 and forms a transition zone of physical properties between the base layer 11 and the nano-deposited layer 13, thereby eliminating stress concentration, stress and high temperature between the base layer 11 and the nano-deposited layer 13. The nano-deposited layer 13 does not peel off.
上述的纳米沉积层 13, 其主要成份是含镍量大于 98. 3%; 钴 0. 2-15%; 碳 0. 006-0. 01% ; 铜 0. 003-0. 007% ; 铁 0. 2-1. 4% ; 硫 0. 02-0. 04%; 0. 0003-0. 0006%; 铅 0. 0003-0. 0006%。 该纳米沉积层 13的粒度小于 45nm。 色泽银白偏黄; 比重 9. Og/cm3 ,原子量 60. 69-63. 88; 原子序 29-35; 熔点 大于 1800°C ; 抗拉强度大于 500Mpa;耐磨性大于 35TWI ; 延伸性 1-4. 0%;硬 度 400-600HV;抗蚀性: 盐雾试脸大于 1000小时; 抗氧化性: 大气常温中化 学性质稳定, 在 700 °C以上始被氧化与色变。 易于抛光成镜面;耐挠性佳; 可氩焊、 锡焊; 内应力 0- 50Mpa; 可加工性好。 007-0. 007% ; 铁 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2-1. 4% ; sulfur 0. 02-0. 04%; 0. 0003-0. 0006%; lead 0. 0003-0. 0006%. The nano-deposited layer 13 has a particle size of less than 45 nm. Color silvery white yellow; specific gravity 9. Og / cm 3 , atomic weight 60. 69-63. 88; atomic order 29-35; melting point greater than 1800 ° C; tensile strength greater than 500 Mpa; wear resistance greater than 35 TWI; 4. 0%; hardness 400-600HV; corrosion resistance: salt spray test face greater than 1000 hours; oxidation resistance: chemical stability at atmospheric temperature, oxidation and color change at 700 °C. Easy to polish into mirror surface; good flexibility; argon welding, soldering; internal stress 0- 50Mpa; good processability.
为了或者更好的使用效果, 上述的锅帮 2也采用与锅底 1相同的五层 层状复合结构。 前述的把手或锅耳 3有两个, 对称设置于锅帮 2的外侧,使 该锅具在使用中便于操控。 该锅具还可以包括一锅盖 4 , 用于盖在锅具上, 以使该锅具具有更广泛的使用范围。  For the purpose of better use or better, the above-mentioned pot 2 also adopts the same five-layer laminated composite structure as the bottom 1 of the pot. There are two handles or pot ears 3, which are symmetrically disposed on the outer side of the pot 2, so that the pot is easy to handle during use. The pan may also include a lid 4 for covering the pan to provide a wider range of use.
请参与图 2所示, 是本发明提出的炒锅的结构示意图。 其具有一锅体 21 , 该锅体 21为层状复合结构, 该层状复合结构与上述实施例中所述的层 状复合结构相同; 在锅体 21外侧设有锅柄 22; 以及与上述的锅柄 22对称 设置锅体 21外侧还设有一锅耳 23。  Please refer to FIG. 2, which is a schematic structural view of the wok set forth in the present invention. It has a pot body 21 which is a layered composite structure which is the same as the layered composite structure described in the above embodiment; a pot handle 22 is provided outside the pot body 21; The pot handle 22 is symmetrically disposed with a pot ear 23 on the outside of the pot body 21.
本发明所述的锅具的制造方法主要包括以下步骤:  The manufacturing method of the pan according to the present invention mainly comprises the following steps:
1、 锅体成型。 选用材质为 SPCD 5 1. 5钢板,制作锅帮; Q235 5 3钢板作 为原料制作复合锅底; 通过压力机拉伸成锅形状; 然后通过压力机胀型;接 着用压力机切边; 底部高频钎焊、 形成复合锅底; 在进行底部车削和锅沿 倒角加工形成整个锅体; 对锅体进行表面清理、 喷砂, 标准是无锈蚀、 无 油污。  1. The pot body is formed. The material is made of SPCD 5 1. 5 steel plate to make the pot; Q235 5 3 steel plate is used as the raw material to make the composite pot bottom; the shape is formed into a pot by the press; then it is expanded by the press; then the edge is cut by the press; Frequency brazing, forming a composite pot bottom; forming the entire pot body in the bottom turning and chamfering along the pot; surface cleaning and sand blasting of the pot body, the standard is no rust, no oil.
2、 纳米沉积, 在锅的内外两个表面都进行纳米沉积。 本发明采的锅具 用电镀方法实现纳米沉积, 电镀液的组成为: 以氨基磺酸镍为主液硼酸为2. Nano-depositing, nano-depositing on both the inner and outer surfaces of the pot. The pot of the invention The nano-deposition is realized by electroplating method, and the composition of the electroplating solution is: using nickel sulfamate as the main liquid boric acid
PH值稳定剂; 氨基磺酸为降低 PH值主剂;碳酸镍为提高 PH值主剂;选用纯 度大于 99. 99%的纯镍作为靶材; 控制浴液循环速率以保证浴液的各组分的 离子浓度均匀。 PH value stabilizer; sulfamic acid is the main agent for lowering the pH value; nickel carbonate is the main agent for increasing the pH value; pure nickel with a purity greater than 99.99% is selected as the target; the circulation rate of the bath is controlled to ensure the groups of the bath The ion concentration of the fraction is uniform.
电镀的作业条件:  Electroplating operating conditions:
①浴液温度 10 - 60° C  1 bath temperature 10 - 60 ° C
② PH值 3. 5 - 4. 5  2 PH value 3. 5 - 4. 5
③浴液镍离子浓度 70 - 90g/L  3 bath nickel ion concentration 70 - 90g / L
④浴液循环速率 5 - 12次 /小时  4 bath circulation rate 5 - 12 times / hour
⑤工件酸洗去污去脂  5 workpiece pickling decontamination and degreasing
⑥沉积作业电流密度 1 - 1. 5ASD  6 deposition current density 1 - 1. 5ASD
⑦沉积厚度为 100 - 300um  7 deposition thickness is 100 - 300um
3、 表面抛光;  3, the surface is polished;
4、 装配把手、 提耳、 配盖。  4, assembly handles, lifting ears, with cover.
按照上述方法形成的锅具, 对其层状复合结构进行测试, 结果如下: 测试方法:  The pot formed according to the above method was tested on the layered composite structure, and the results were as follows: Test method:
用 J0-780 型电火花线切割机床垂直钢板镀层表面截取厚度 0. 2隱试 片, 研磨至厚 100微米, 然后进行离子减薄, 直至样品中心穿孔。 组织观 察与电子衍射相分析在日立 H- 800透射电子显微镜上进行, 成分测定使用 菲利普 PV900型能谱仪。 透射电镜的加速电压为 150kV。  The surface of the vertical steel plate coating of J0-780 type EDM machine was used to cut the thickness of 0. 2 hidden test piece, ground to a thickness of 100 μm, and then ion thinned until the center of the sample was perforated. The observation of the structure and the electron diffraction phase were carried out on a Hitachi H-800 transmission electron microscope, and the composition was measured using a Phillips PV900 spectrometer. The transmission electron microscope has an accelerating voltage of 150 kV.
测试结果:  Test Results:
请参阅图 4 所示, 是本发明的层状复合结构的电镜照片。 可以看出有 三层结构, 其中黑色部分是基体层, 基体层之外灰色部分是植入层,植入层 外是纳米沉积层。  Referring to Figure 4, there is an electron micrograph of the layered composite structure of the present invention. It can be seen that there is a three-layer structure in which the black portion is the base layer, the gray portion outside the base layer is the implant layer, and the implant layer is the nano-deposited layer.
请参阅图 5 所示, 是纳米沉积层的电镜照片,其组织形态均呈颗粒状, 经标尺测定, 颗粒尺寸在 25 - 60纳米之间。  Referring to Figure 5, it is an electron micrograph of the nano-deposited layer. Its microstructure is granular, measured by a ruler, and the particle size is between 25 - 60 nm.
请参阅图 6 所示, 是纳米沉积层的颗粒电子衍射照片。 电子衍射指数 标定与点阵常数计算结果表明, 这些纳米级粒子是面心立方结构的 Ni的固 容体。  See Figure 6 for a particle electron diffraction photograph of a nano-deposited layer. Electron diffraction index calibration and lattice constant calculations show that these nanoscale particles are Ni-solids of face-centered cubic structure.
请参阅图 7 所示, 是本发明纳米沉积层的能谱图。 其成分定量分析结 果为 (重量百分比): Ni: 99. 90 % ; Si: 0. 10°/。。 Please refer to FIG. 7, which is an energy spectrum of the nano-deposited layer of the present invention. Quantitative analysis of its components Fruit is (% by weight): Ni: 99. 90%; Si: 0. 10°/. .
以上所述, 仅是本发明的较佳实施例而已, 并非对本发明作任何形式 上的限制, 虽然本发明已以较佳实施例揭露如上,然而并非用以限定本发 明, 任何熟悉本专业的技术人员在不脱离本发明技术方案范围内, 当可利 用上述揭示的技术内容作出些许更动或修饰为等同变化的等效实施例,但 凡是未脱离本发明技术方案的内容, 依据本发明的技术实质对以上实施例 所作的任何简单修改、 等同变化与修饰,均仍属于本发明技术方案的范围 内。 工业应用性  The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. Although the present invention has been disclosed in the above preferred embodiments, it is not intended to limit the present invention, any The skilled person can make some modifications or modifications to the equivalent embodiments by using the above-disclosed technical contents without departing from the technical scope of the present invention, but without departing from the technical solution of the present invention, according to the present invention. It is still within the scope of the technical solution of the present invention to make any simple modifications, equivalent changes and modifications to the above embodiments. Industrial applicability
本发明的锅具采用五层层状复合结构, 其包括基体层.;两层植入层, 分 别位于基体层的两侧; 以及两层纳米沉积层, 分别位于上述的植入层之外。 上述的基体层材 t是钢、 铜、 铝或上述材料之间的组合而形成的合金。 本 发明特殊结构的锅具, 其具有强附着力纳米沉积层,能够同时具备耐磨耐蚀 与导热蓄热、 导磁性好的性能, 从而更加适于实用。  The pot of the present invention employs a five-layered layered composite structure comprising a base layer; two layers of implanted layers, respectively located on either side of the base layer; and two layers of nano-deposited layers, respectively located outside of the implanted layer. The above-mentioned base material t is an alloy formed by a combination of steel, copper, aluminum or the above materials. The pot of the special structure of the invention has a strong adhesion nano-deposited layer, and can have the functions of abrasion resistance, corrosion resistance, heat conduction and heat storage, and magnetic permeability, so that it is more suitable for practical use.

Claims

权 利 要 求 Rights request
1、 一种锅具, 包括锅底和锅帮, 其特征在于其中所述的锅底为层状复 合结构, 该层状复合结构包括: A pot, comprising a pot bottom and a pot top, wherein the bottom of the pot is a layered composite structure, the layered composite structure comprising:
基体层;  Base layer
二植入层, 分别位于基体的两侧; 以及  Two implant layers, respectively located on both sides of the substrate;
二纳米沉积层, 分别位于上述的植入层之外。  Two nano-deposited layers, respectively, are located outside of the implant layer described above.
2、 根据权利要求 1所述的锅具, 其特征在于其中所述的锅帮为层状复 合结构, 该层状复合结构包括:  2. The pan according to claim 1, wherein the pot is a layered composite structure, the layered composite structure comprising:
基体层;  Base layer
二植入层,.分别位于基体的两侧; 以及  Two implant layers, respectively located on both sides of the substrate;
二纳米沉积层, 分别位于上述的植入层之外。  Two nano-deposited layers, respectively, are located outside of the implant layer described above.
3、 根据权利要求 1或 2所述的锅具, 其特征在于其还包括一锅盖。 3. A pan according to claim 1 or 2, further comprising a lid.
4、根据权利要求 1或 2所述的锅具, 其特征在于其中所述的锅帮的外 侧对称设有两只锅耳。 4. A pan according to claim 1 or 2, wherein the outer side of the pot is symmetrically provided with two pan ears.
.  .
5、根据权利要求 1或 2所述的锅具, 其特征在于其中所述的基体层为 钢、 铜、 铝或上述材料组合而形成的合金构成的金属板层。 The cookware according to claim 1 or 2, wherein the base layer is a metal plate layer composed of an alloy of steel, copper, aluminum or a combination of the above materials.
6、根据权利要求 1或 2所述的锅具, 其特征在于其中所述的纳米沉积 层的成份的重量百分含量是:镍量大于 98. 3%;钴 0. 2-15%;碳 0. 006-0. 01%; 铜 0. 003-0. 007%; 铁 0. 2-1. 4%; ^ 0. 02-0. 04%; 0. 0003-0. 0006%; 铅 0. 0003-0. 0006%。  The carbon content of the composition of the nano-deposited layer is: more than 98.3%; cobalt 0. 2-15%; carbon; 0. 006-0. 01%; copper 0. 003-0. 007%; iron 0. 2-1. 4%; ^ 0. 02-0. 04%; 0. 0003-0. 0006%; lead 0 0003-0. 0006%.
7、根据权利要求 1或 1所述的锅具, 其特征在于其中所述的层状复合 结构是通过电镀方式形成的, 所使用的电镀液的组成为: 以氣基磺酸镍为 主液硼酸为 PH值稳定剂; 氨基磺酸为 P争低 PH值主剂;碳酸镍为提高 PH值 主剂;选用纯度大于 99. 99%的纯镍作为靶材;控制浴液循环速率以保证浴液 的各组分的离子浓度均匀;  The pot according to claim 1 or 1, wherein the layered composite structure is formed by electroplating, and the composition of the plating solution used is: using a gas-based nickel sulfonate as a main liquid Boric acid is a pH stabilizer; sulfamic acid is P as a low pH main agent; nickel carbonate is a pH-enhancing agent; pure nickel having a purity greater than 99.99% is used as a target; and the bath circulation rate is controlled to ensure a bath The ion concentration of each component of the liquid is uniform;
电镀的作业条件:  Electroplating operating conditions:
① 浴液温度 10 - 60。 C  1 bath temperature 10 - 60. C
② PH值 3. 5— 4. 5  2 PH value 3. 5— 4. 5
③ 浴液镍离子浓度 70 - 90g/L ④ 浴液循环速率 5 - 12次 /小时 3 bath nickel ion concentration 70 - 90g / L 4 bath circulation rate 5 - 12 times / hour
⑤ 工件酸洗去污去脂 .  5 workpiece pickling decontamination and degreasing.
⑥ 沉积作业电流密度 1 - 1. 5ASD  6 Deposition operation current density 1 - 1. 5ASD
⑦ 沉积厚度为 100 - 30 Oum。  7 Deposition thickness is 100 - 30 Oum.
8、 一种炒锅, 其具有一锅体, 其特征在于该锅体为层状复合结构, 该 层状复合结构包括:  8. A wok having a pot body characterized in that the pot body is a layered composite structure, the layered composite structure comprising:
基体层;  Base layer
二植入层, 分别位于基体的两侧; 以及  Two implant layers, respectively located on both sides of the substrate;
二纳米沉积层, 分别位于上述的植入层之外。  Two nano-deposited layers, respectively, are located outside of the implant layer described above.
9、根据权利要求 8所述的炒锅, 其特征在于其中所述的锅体外侧设有 锅柄。  A wok according to claim 8, wherein said pot body is provided with a pan handle on the outside.
10、 根据权利要求 9所述的炒锅, 其特征在于其中所述的锅体外侧还 设有一锅耳, 该锅耳与上述的锅柄为对称设置。  10. The wok according to claim 9, wherein the outer side of the pot body is further provided with a pot ear, and the pot ear is symmetrically disposed with the pot handle.
PCT/CN2006/002389 2006-09-14 2006-09-14 A cooking pot WO2008034282A1 (en)

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CN1425804A (en) * 2003-01-13 2003-06-25 卢能晓 Process for producing electroplating plate for drawing
CN1457737A (en) * 2003-05-19 2003-11-26 黎明星 Iron pot with tin-nickle alloy protective layer and its producing method
US6756134B2 (en) * 2002-09-23 2004-06-29 United Technologies Corporation Zinc-diffused alloy coating for corrosion/heat protection

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1389598A (en) * 2002-07-07 2003-01-08 余泽玲 Low-temperature and low-concentration electroplating process to form multilayer nano nickel coating
US6756134B2 (en) * 2002-09-23 2004-06-29 United Technologies Corporation Zinc-diffused alloy coating for corrosion/heat protection
CN1425804A (en) * 2003-01-13 2003-06-25 卢能晓 Process for producing electroplating plate for drawing
CN1457737A (en) * 2003-05-19 2003-11-26 黎明星 Iron pot with tin-nickle alloy protective layer and its producing method

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