1298661 、 九、發明說明： 【發明所屬之技術領域】 ，金。料種金屬材料，特別是-種多元成分硬面銲合 【先前技術】 ▲隨著金屬材料研發的進步，金屬材料具備高強度、古五 鬲加工性、價格便宜等特性， 阿軔性、 機朽制、庄r目； 口此孟屬材料之應用廣泛，不論是 枝械製造，具加工、#建業、造船工業、汽車 使用量皆非常的龐大，因此造成全球性的金屬材料之需求^; 成為用料最多且運用最廣的結構材料。但由於=屬貝 需要更佳轉接解。觀低，批金料料之間的接合 p 疋 ，首大部分的m職發生失贿錢枝肇目_難壞，而 电===鮮嶋仏姆，目此如何有效克服 外5二 產生之問題，是—個很重要的讓題。此 H工境㈣，許錢11元件如壓鑄機、鍛造機且、 銅線堡延設#、擠黯備冷錢..·.·· 中作«作，因此其必須面對更嚴苛的高溫磨耗考驗；而=溫 材料之硬度明顯下降，抗拉強度變差與軟化情況嚴 口此其廷用硬面銲之銲覆材料更顯重要。 版jr解决“材料在高溫環境下的缺失，增加其表面抗磨耗 1 ’硬面技術處理是有效率的方法之一，一般而言利用焊 1298661 接、熱喷鋒···...等類似製程加工，可以有效的降低磨耗、鏽钱 等其他原因所造成的損失。 … 硬面技術處理是根據材料的應用，促進了硬面技術的發展和 #完善’硬面銲材料按其性質可分為··鐵基合金、鎖基合金:結基 合金、陶莞材料、自炫合金、石炭化鶊材料、特殊合金材料、複= 材料··.···等；依照硬面銲材料的產品的形式可分為：合金絲、合 金粉末及複合粉末、略粉末、金屬陶£粉末、奈米粉末、帶材、 棒材、裸焊條、電焊條、管狀焊條、管狀絲、軟線……等。 例如美國專⑧S4728493，此專利配方的原子及其百分比為 鉻(Cr)45-60%、_i)25_44%、鉬(Μ〇)6·5_12%、匈(cb)2 〇七％、 ^(C)l.:>-2.8%、硫⑸am，其屬於以絡基合金為主要成分， 適用於易遭水氣環境槪下的環境之中，因此可用於鑽油平台的 硬面建材，其硬面性質的構成要件是依靠其配方中添加的碳二素 與重金屬元素，·產生碳化物析出增加硬面強度，而其防雜 的主要機制是依靠鉻元素的大量添加。 此外，4 了接觸面硬度之需纟，也有專利廣泛採用鐵基合金 為配方主要成分，例如美國專利US5431136及US48i〇464。其中 US5431136強調可以在不使用銘元素和硼元素的情形之下，適合 於鑽油平台之鑽油頭之硬面銲，其配方成分除了鐵之外，其㈣ 子及其百分比分別為碳(C)1.3-2%、鉻(Cr)19_23%、钥（施爪11%、 鎳(Ni)17-21〇/〇、猛(塗)6-13〇/。、石夕(Si)<〇 5%、氧⑼ 樣是依靠碳化物析出增加硬面強度。而US4810464則是強調可以 1298661 '不使贿元素之情況下達到相同硬度的鐵基合金成分配方，其成 分配方除了鐵之外，其他原子及其百分比分別為硼⑽_5%、錄 (N!)27’43%、梦(Si)ai-5%、碳⑹似篇、_η)αι_2%以及大 =10%的鉻(Cr) ’其利用化物與碳化物析出增加硬面強度，但 疋其硬面辟·造過財必需於真空巾_電漿處縣合金配 方粉末’因此雜«㈣雜_財效大量應用。 …美國專利US679期屬於以錄合金粒要成分，具備高溫 2耐磨W及抗氧化雜。•國專利则迎1則屬於以錄基 合主為主要成分，具#高溫穩定耐磨特性，其配方成分除了錄之 外’其他原子及其百分比分別為路(0)27-30%、鉬（Mo)7_95%、 ,l(W)4-6〇/〇^(Mn)0.75.1.3〇/〇、鈦㈤0.05-0.5%、翅Cb)0.2_a75%、 ^(Ql.2-1.8% . ^(SOl-l.750/0 ^(Fe)<5〇/〇 , 碳=的形成增加硬面強度，但是其録條製造過程中，需配合使 用4寸疋大小之合金配方粉末，且需於真空中利用電漿處理法摔 作’因此其銲條製造枝性低大量魅使财其困難性。、 八^^’翻彻6723()揭露高亂度料合金材料使用之概 公’旦疋其並未針對硬面銲用途作其權力範圍之保障。 轉之組成齡可充分克服其所處的惡錢境，亦即 ^舰成:通吊都是針對特定環境而加以調配，期望能夠達到防 止鏽蝕、氣化···.··等特定作用。 銲之銲覆材料若是選擇不#會造成銲覆品質不 n、基材結合性不良等缺點’因此得覆材料之選擇 1298661 、有其重要性。 【發明内容】 -之銲覆品質不佳、銲覆層 ";、上的問崎’本發明的主要目的在於提供-種多元成分 更面鋒合金，藉萌決先前技術所揭露 與基材結合性不良的問題。 可具有在各種環境下 夕本發明的另—目的在於提供—種多元成分硬面銲合金，運用 夕疋成分的概念調配硬面銲材料成分配方， 最大泛用性的功能。 # 依照本發贿佳實施綱述之多域分硬φ銲合金包含添 加鋁元素，所添加的原子百分比為合金總組成的e%，2%$e% : m’而a% +b% +c% +d% +e%謂〇%。本發明更可依需要添加銘 兀*素，所添加的原子百分比為合金總組成的伐，17%$伐< 21%，而 a% +b% +c% +d% +f% $1〇〇〇/0。 本發明提出-種多元成分硬面銲合金，包括有：鐵、鐵、終 猛或鉬’其恤元纽転素可擇—使狀，而鐵域的原子芳 分比為合金總域的a% (寫^挪），鎳域的原子百分比 為合金總組成的b% (5%满迎％)，鉻元素的原子百分比為合 金總組成的e% (5%W幻5%)，猛或航素的原子百分比為: 金總組成的d% (5%鋪幻5%)，而a%璃+成墙幻〇〇%口。 本發明再提出一種多元成分硬面銲合金，包括有：鐵、錄、 鉻、錳及鉬，其中鐵元素的原子百分比為合金總組成的鸪‘ a% $35%)，鎳元素的原子百分比為合金總組成的城（5%$冰幺 1298661 Μ%)，鉻元素的原子百分比為合金總組成的c% (5%^c% ‘ 35%)，錳元素的原子百分比為合金總組成的d% (5%^ .35%)，以及鉬元素的原子百分比為合金總組成的e% (5%^e% ^ • J5%)，而 a% +b% +c% +d% +e% g 100%。 依照本發明較佳實施例所述之多元成分硬面銲合金包含添 加鋁元素，所添加的原子百分比為合金總組成的伤，伐‘ 12% ’而a% +b% +c% +d% +e% +伐$1〇〇%。本發明更可依需要添 •加鉛元素，所添加的原子百分比為合金總組成的g%，Π%細 $21%，而 a% +b% +c% +d% +e% +g% gi〇〇〇/〇。 本發明之-種多元成分硬面録合金，跳脫了傳統具備—個主 元素成分硬面銲合金配方設計架構，其多元成分硬面鋒合金之配 方所包含的每-齡要元素分·合金總組成的軒百分比现 以下，以同時在不同環境中展現其最大泛用性。 此外’本發明所提供之多元成分硬面銲合金，其該合金作為 φ ^騎料時之麵溫度與傳聽方她，具毅歡麵温紅 4推’ -般說來傳統之硬面薛合金用於為銲覆材料時需預熱達到 4〇〇°C以上，而本發明則只需預熱至2〇〇〇c即可，因此可大 低銲覆製程之成本。 本發明使用多元成分合金作為硬面銲材料，該合金鲜條製造 触可直接於大氣顧愤煉製造，其硬面贿触之顧機^ 是依循多元成分元素高I度排列的原理，與一般硬面輝合金成分 配方依靠碳化物或是硼化物析出的原理不同，也避免掉因為有碳 10 1298661 、化物或是硼化物而使硬轉材料較脆的問題。 有關本*_特徵與實作，茲配合圖雜最佳實施例詳細說 明如下。 【實施方式】 、+出/、版貝苑例以詳細說明本發明之内容，並以圖示作 為輔助制。說日种提及之符鶴參關式符號。 本發明提出—種多元成分硬面鮮合金，包括有:鐵、鎳、养、 猛或鉬’其恤元素及転素擇—使用，*鐵元素的原子百分比 為合金總組成的a%陶a%沾％)，錄元素的原子百分比為合 金總組成的b% (5%幺怵oc。/、 二士 —=35/()) ’鉻元素的原子百分比為合金總 組成的C% (5%么％ $35%)，以及經或钥元素的原子百分比為人 金總組成的d% (5%_沾％)，而a%谓+c%域幻_°。 上（之夕兀成分硬崎合金包含添純元素，其所添加的原 子百分比為合金總級成的e%，2%⑼$12% ’ *战,+成 +d% +e%扁0% ;更可依需要添加钻元素，其所添加的原子百分 比為合金總組成的f%，17%·。$21%，而a%韻+c%墙二 % 200% ;此外’本發明之多元成分硬面銲合金不包含例如 碳等等特定元素。 本發明更提出一種多元成分硬面銲合金，包括有：鐵、鎳、 絡、猛及1目，其巾鐵元素的原子百分比為合金總喊的a% (5%$ 挪$35%)，鎮元素的原子百分比為合金總组成的b% (5%·。$ 35%)，鉻凡素的原子百分比為合金總組成的c% (5%$i $ 11 1298661 35%)，錳元素的原子百分比為合金總組成的收（5%-邶‘ 35〇/〇)，以及鉬元素的原子百分比為合金總組成的e%$ 35%)，而 a% +b% +c% +d% +e% $1〇〇%。 上述之多元成分硬面銲合金包含添純元素，其所添加的原 子百分比為合金總組成的槐，M $12%，而a% +b% +c% +d % Μ +ϋ1Ό0% ;更可依f要添加敍元素，其所添加的原子百 分比為合金總組成的g%，17%細迎％， % +战+g%識％ ;此外’本發明之多元成分硬面銲合全不包各 例如硼或碳等等特定元素。 ° 本表明之夕兀成分硬面銲合金可以被應用在硬面鋒技術，^ 熱源和方法，將所需性能或功能的材料以粉狀或; tr 融、魏或合金錄態，沉制工件表面制 良奸結合塗層的工藝方法，麵著的特徵表現在·· 〃 (1) 塗層材料，包括幾乎所有蝴(合金)和非蝴陶究、金肩 陶究)以及各種複合材料。 、 (2) 塗層製備，有火怡、本 射法等工電弧法、氣體保概、等離子法、鐘 方法，可麵房内加項在現場維修 ο)基體材質，如超人么亚沽万使 碳鋼替代、，或可焊性差)的基體材質可用低合金或 1二曰金屬消耗和改善硬面技術性能。 (),、、、貝塗、贺焊和堆焊莽人 效果。 夂3或％5使用，可達到更完美的技術 進一步延長使用壽命。 (5)工件可多次修復、修補重用 12 1298661 、本發明之多元成分硬面銲合金可則皮運用於— =工法操作，但是其預熱溫度達到就即_操作 像白知的硬轉合金一樣的預熱溫度需達到衡c以上，: 細地列出衫驗例及其試驗值，以便說明本發明之功效，但本^ 明的專利範目辦纟這些實驗觸完全絲。 ^ 貫驗例1之配方成分原子及其重量百分比為鐵㈣㈣％、 猛_)18-19%、鎳_0_31%、鉻_7·18%、銘(鄭挪，才夕 試片表面以本發明之多元成分硬_合金做—至四層的硬面㈣ 理之後’再1測其表面硬度並做比較，以證明其翻的硬面效果， 從實驗數據觀察其經過硬面銲第一層後硬度提/升為 3曰lHRC(R0ckwelIhardness，洛氏硬度），經過硬面焊第二層後硬度 提升為32HRC ’經過硬面銲第三層後硬度提升為42hrc，經過硬 面銲第四層後硬度維持42HRC。在同樣的概念中，也可以進一步 將本發明之多元成分硬面銲合金之配方做些許範圍的修改之後也 鲁可以達到類似的硬面處理效果。 圖1為本發明之多元成分硬面銲合金之較佳實施了列配方硬度 數據，如圖1所示^將本發明實驗例丨之重量百分比範圍區間改 文為如貫驗例1A-1D之範圍:鐵(Fe)14-29%、猛(Mn)i8-32%、鎳 . (Ni)l卜31%、鉻(Cr)14_31%、鋁(A1)2_8%，其硬面之硬度介於 4()dlHRC，具備不同大氣環境中使用之泛用性。 同樣地可以進一步將多元成分硬面銲合金之配方做些許範 圍的修改，做這些修改之後仍可以達到類似的硬面處理效果，例 13 ,1298661 如本發明之實驗例2，其重量百分比為Fe(24-26%)、Co(17-18%)、 Ni(16-18%)、Cr(14_16%)、Mo(13_15%)、Al(8-9%)，又如本發明 • 實驗例 3 其重量百分比為 Fe(17-20%)、Co(18-21%)、Ni(18-20%)、 ’. 以17-18%)、Al(4-5%)、Mn(18_19%)，又如本發明實驗例4其重 • 量百分比為 Fe(23-26°/〇)、Co(19-21%)、Ni(19-21%)、Cr(15-17%)、 Al(5-6%)、Mo(l(M2%)，皆達到有效提升硬面性質到4〇H；RC以上 的目地。 • 最後在本發明概念中，實驗例5A-5G以本發明之多元成分硬 面銲合金，在針對不包含鈷元素的情況下使用硬面銲技術，圖2 為本發明之多元成分硬面銲合金不包含鈷元素之較佳實施例配方 硬度數據，如圖2所示，實驗例5A-5G之原子及其重量百分比為1298661, IX, invention description: [Technical field to which the invention belongs], gold. Metal materials, especially - multi-component hard surface soldering [prior art] ▲ With the advancement of metal materials research and development, metal materials have high strength, ancient Wuji processability, low price and other characteristics, aunty, machine The genus of the genus and the genus of the genus; the application of this genus is extensive, whether it is manufacturing of branches, processing, construction, shipbuilding, and automobile use are very large, thus causing the demand for global metal materials ^; It is the most widely used and most widely used structural material. However, because of the genus, you need a better transfer solution. The view is low, the joint between the gold materials is p 疋, the first part of the m job is unfortunately _ difficult to bad, and electric === fresh 嶋仏 ,, how to effectively overcome the outside 5 The problem is a very important question. This H environment (four), Xu Qian 11 components such as die-casting machine, forging machine and copper wire fortification #, squeezed cold money ......···································· High temperature wear test; while = the hardness of the material is significantly reduced, the tensile strength is deteriorated and the softening condition is strict. This is more important for the hard surface welding of the welding material. Version jr solves "the lack of materials in high temperature environment, increasing the surface wear resistance 1 'hard surface technology treatment is one of the efficient methods, generally using welding 1298661, hot spray front ···...etc. Process processing can effectively reduce the losses caused by wear, rust and other reasons. ... Hard surface technology treatment is based on the application of materials, promotes the development of hard surface technology and #完美' hard surface welding materials can be divided according to their properties Iron-based alloys, lock-base alloys: base alloys, pottery materials, self-glazed alloys, carbonized bismuth materials, special alloy materials, complex materials, materials, etc.; products based on hard surface soldering materials The form can be divided into: alloy wire, alloy powder and composite powder, slightly powder, metal ceramic powder, nano powder, strip, bar, bare electrode, welding electrode, tubular electrode, tubular wire, flexible wire, etc. For example, the United States specializes in 8S4728493, the atom of the patent formula and its percentage are chromium (Cr) 45-60%, _i) 25_44%, molybdenum (Μ〇) 6·5_12%, Hungary (cb) 2 〇 7%, ^ (C ) l.:>-2.8%, sulfur (5) am, which belongs to the complex alloy It is suitable for use in environments where it is vulnerable to water and gas environment. Therefore, it can be used for hard-surface building materials of oil drilling platforms. The constituent elements of the hard surface properties depend on the carbon and the heavy metal elements added in the formulation. Precipitation increases the strength of the hard surface, and the main mechanism of its anti-aliasing is to rely on the large addition of chromium. In addition, 4 the need for contact surface hardness, there are patents widely used iron-based alloy as the main component of the formula, such as US patent US5431136 and US48i 〇 464. Among them, US5431136 emphasizes that it is suitable for the hard surface welding of the oil boring head of the oil rig without using the element and the boron element. The formula of the formula is in addition to iron, and the (four) and its percentages are respectively Carbon (C) 1.3-2%, chromium (Cr) 19_23%, key (11% claw, nickel (Ni) 17-21〇/〇, 猛 (涂) 6-13〇/., 石夕(Si) < 5%, oxygen (9) is based on the precipitation of carbides to increase the strength of the hard surface. And US4810464 is the formula of iron-based alloys that can be used to achieve the same hardness without the bribe element, the composition of which is in addition to iron In addition, the other atoms and their percentages are (10) _5%, recorded (N!) 27'43%, dream (Si) ai-5%, carbon (6) like, _η) αι_2% and large = 10% chromium (Cr) 'the use of compounds and carbide precipitation increased The hardness of the hard surface, but the hard surface of it has to be created in the vacuum towel _ plasma county alloy formula powder 'so miscellaneous « (four) miscellaneous _ financial effects a large number of applications. ... US patent US679 period belongs to the recording of alloy particles It has high temperature 2 wear-resistant W and anti-oxidation. • The national patent welcomes 1 with the main component of the record base, with #high temperature stability and wear resistance, and its formula ingredients are not recorded except 'other atoms and their percentages It is 27-30% of road (0), 7_95% of molybdenum (Mo), 1 (W) 4-6〇/〇^(Mn) 0.75.1.3〇/〇, titanium (5) 0.05-0.5%, wing Cb ) 0.2_a75%, ^(Ql.2-1.8%. ^(SOl-l.750/0 ^(Fe)<5〇/〇, the formation of carbon = increased hard surface strength, but during the production of the strip It is necessary to use a 4-inch bismuth alloy formula powder, and it needs to be treated by a plasma treatment method in a vacuum. Therefore, its welding rod manufacturing has a low degree of charm and makes it difficult. , eight ^ ^ 'turned through 6723 () to expose the use of high-altitude alloy materials. The age of the composition can fully overcome the evil situation in which it is located, that is, the shipbuilding: the crane is deployed for specific environments, and it is expected to achieve specific effects such as preventing corrosion, gasification, and the like. If the welding material is not selected, it will cause defects such as poor quality of the solder joint and poor bonding of the substrate. Therefore, the choice of the material to be coated is 1298661. SUMMARY OF THE INVENTION - The poor quality of the soldering coating, the solder coating layer, the upper part of the present invention, the main purpose of the present invention is to provide a multi-component, more facial alloy, which is disclosed by the prior art. Poor combination. The present invention has the object of providing a multi-component hard surface solder alloy, which utilizes the concept of a matte component to formulate a hard surface solder material composition formula, and has the most versatile function. # According to the implementation of this bribery, the multi-domain hard φ solder alloy contains aluminum added, the atomic percentage added is the e% of the total composition of the alloy, 2%$e%: m' and a% +b% + c% +d% +e% is 〇%. The invention can also add the sputum* as needed, the atomic percentage added is the total composition of the alloy, 17%$ slash < 21%, and a% + b% + c% + d% + f% $1 〇 〇〇/0. The invention proposes a multi-component hard surface soldering alloy, which comprises: iron, iron, final fierce or molybdenum, and the atomic aromatic fraction of the iron domain is the total area of the alloy. % (write ^ move), the atomic percentage of the nickel domain is b% of the total composition of the alloy (5% full %), the atomic percentage of chromium is the e% of the total composition of the alloy (5% W 5%), fierce or The atomic percentage of the element is: d% of the total composition of gold (5% 5%), and a% glass + % of the wall. The invention further provides a multi-component hard surface soldering alloy, comprising: iron, recorded, chromium, manganese and molybdenum, wherein the atomic percentage of iron is 鸪' a% of the total composition of the alloy is $35%), and the atomic percentage of the nickel element is The total composition of the alloy (5% $ hail 幺 1298661 Μ%), the atomic percentage of chromium is c% of the total composition of the alloy (5% ^ c% ' 35%), the atomic percentage of manganese is the total composition of the alloy d % (5%^ .35%), and the atomic percentage of molybdenum is e% of the total composition of the alloy (5%^e% ^ • J5%), while a% +b% +c% +d% +e% g 100%. The multi-component hard surface soldering alloy according to the preferred embodiment of the present invention comprises an aluminum element added, the atomic percentage added is the total composition of the alloy, and the cut is '12%' and a% + b% + c% + d% +e% + cut $1〇〇%. The invention can also add lead element as needed, the atomic percentage added is g% of the total composition of the alloy, Π% is fined by $21%, and a% + b% + c% + d% + e% + g% gi 〇〇〇/〇. The multi-component hard-surface recording alloy of the invention skips the traditional design formula of a hard-weld alloy alloy with a main element component, and the elemental alloy of each age is included in the formula of the multi-component hard surface alloy. The percentage of the total composition is now below to show its maximum versatility in different environments. In addition, the multicomponent hard surface soldering alloy provided by the invention has the surface temperature and the audible side of the alloy as the φ ^ riding material, and the temperament surface is warm and red 4 pushes - the traditional hard surface Xue The alloy needs to be preheated to 4 ° C or more for the welding material, and the invention only needs to be preheated to 2 〇〇〇 c, so the cost of the welding process can be greatly reduced. The invention uses a multi-component alloy as a hard surface welding material, and the production of the fresh strip of the alloy can be directly produced in the atmosphere, and the hard-faced bribe is based on the principle that the multi-component elements are arranged at a high degree I, and generally The hard-faced alloy composition depends on the principle of carbide or boride precipitation, and also avoids the problem that the hard-turn material is brittle due to carbon 10 1298661, compound or boride. Regarding this *_feature and implementation, the best embodiment of the figure is described in detail below. [Embodiment] The contents of the present invention will be described in detail with reference to the examples of the present invention and the accompanying drawings. Say the Japanese-style symbol of the crane. The invention proposes a multi-component hard-faced fresh alloy, including: iron, nickel, nutrient, fierce or molybdenum, and its elemental content and use of the element, the atomic percentage of the iron element is the total composition of the alloy a% Tao a %%%), the atomic percentage of the recorded element is b% of the total composition of the alloy (5% 幺怵 oc. /, two 士 -= 35 / ()) 'The atomic percentage of chromium element is C% of the total composition of the alloy (5 %%% $35%), and the atomic percentage of the key element is the d% of the total composition of the person's gold (5%_%), while the a% is the +c% domain __. On the upper part of the 硬 兀 component hard alloy contains pure elements, the atomic percentage added is the e% of the total grade of the alloy, 2% (9) $12% ' * war, + into + d% + e% flat 0%; Further, a drill element may be added as needed, and the atomic percentage added is f% of the total composition of the alloy, 17%·.$21%, and a% rhyme+c% wall 2% 200%; in addition, the 'component of the invention is hard The surface soldering alloy does not contain specific elements such as carbon. The present invention further provides a multi-component hard surface soldering alloy comprising: iron, nickel, lanthanum, fission and 1 mesh, and the atomic percentage of the iron element of the towel is always called by the alloy. a% (5%$%$35%), the atomic percentage of the town element is b% (5%·.$35%) of the total composition of the alloy, and the atomic percentage of the chromium element is c% of the total composition of the alloy (5%$ i $ 11 1298661 35%), the atomic percentage of manganese is the total composition of the alloy (5% - 邶 '35 〇 / 〇), and the atomic percentage of molybdenum is e% $ 35% of the total composition of the alloy), and a% +b% +c% +d% +e% $1〇〇%. The above-mentioned multi-component hard surface soldering alloy comprises a pure element added, and the atomic percentage added is 槐 of the total composition of the alloy, M $12%, and a% + b% + c% + d % Μ + ϋ 1 Ό 0%; f to add a narrative element, the atomic percentage added is g% of the total composition of the alloy, 17% fine welcome %, % + war + g%%; in addition, the multi-component hard surface soldering of the present invention does not include each Specific elements such as boron or carbon. ° This shows that the 兀 兀 component hard surface soldering alloy can be applied to the hard surface technology, ^ heat source and method, the desired properties or functional materials in powder or; tr melt, Wei or alloy recording, sinking the workpiece The method of surface coating combined with coating is characterized by the appearance of · (1) coating materials, including almost all butterflies (alloys) and non-fancy ceramics, gold shoulder ceramics, and various composite materials. (2) Preparation of coatings, such as the fire method, the fire method, the gas protection method, the plasma method, the clock method, the addition of items in the room for on-site maintenance ο) the base material, such as Superman Aya Substrate materials that replace carbon steel, or poor weldability, can be used with low alloy or bismuth metal consumption and improve hard surface performance. (),,,, bead, congratulation, and surfacing.夂3 or %5 can be used to achieve a more perfect technology to further extend the service life. (5) The workpiece can be repaired and repaired multiple times. 12 1298661. The multi-component hard-surface soldering alloy of the present invention can be used for the operation of the method, but the preheating temperature is reached, ie, the hard-transfer alloy like Baizhi is operated. The same preheating temperature needs to reach the above level of c:, the case examples and their test values are carefully listed to illustrate the efficacy of the present invention, but the patent specifications of the present invention are completely touched. ^ The composition of the atom of the formula 1 and its weight percentage are iron (four) (four)%, fierce _) 18-19%, nickel_0_31%, chromium _7·18%, Ming (Zheng Yun, Cai Xi test piece surface to this The invention consists of a multi-component hard-alloy---------------------------------------- After the hardness increase / rise to 3曰lHRC (R0ckwelIhardness, Rockwell hardness), after the second layer of hard surface welding, the hardness is increased to 32HRC. After the third layer of hard surface welding, the hardness is increased to 42hrc, and the fourth layer is hard surface welded. The post-hardness is maintained at 42 HRC. In the same concept, the formulation of the multi-component hard-wrap alloy of the present invention can be further modified to achieve a similar hard surface treatment effect. The composition hardness data of the component hard surface soldering alloy is preferably implemented as shown in Fig. 1. The range of the weight percentage range of the experimental example of the present invention is changed to the range of the sample 1A-1D: iron (Fe) 14 -29%, Meng (Mn) i8-32%, nickel. (Ni) l 32%, chromium (Cr) 14_31%, aluminum (A1) 2 _8%, the hardness of the hard surface is between 4 () dlHRC, and it has the versatility used in different atmospheric environments. Similarly, the formula of the multi-component hard-surface solder alloy can be further modified to some extent, after these modifications are still made. A similar hard surface treatment effect can be attained. Example 13, 1 298 861 As in Experimental Example 2 of the present invention, the weight percentages are Fe (24-26%), Co (17-18%), Ni (16-18%), Cr. (14_16%), Mo (13_15%), Al (8-9%), and as in the present invention • Experimental Example 3 The weight percentages are Fe (17-20%), Co (18-21%), Ni (18) -20%), '. at 17-18%), Al (4-5%), Mn (18_19%), and as in Experimental Example 4 of the present invention, the weight percentage is Fe (23-26°/〇). , Co (19-21%), Ni (19-21%), Cr (15-17%), Al (5-6%), Mo (l (M2%), all achieve effective improvement of hard surface properties to 4 〇H; RC above. • Finally, in the concept of the present invention, Experimental Examples 5A to 5G use the multi-component hard surface soldering alloy of the present invention, and use a hard surface soldering technique for the case where cobalt is not contained, and FIG. 2 The multi-component hardfacing alloy of the present invention does not contain the hardness data of the preferred embodiment of the cobalt element, as shown in FIG. , the atoms of Experimental Examples 5A-5G and their weight percentages are
Al(6-12%)、Cr(12-22%)、Mn(l3-23°/〇)、Fe(9-29%)、Ni(8-30%)、 M〇(13-30%)，其硬面之硬度介於45_65RRC，也同樣具備不同環 境中使用之泛用性。總和以上種種實驗例證明多元成分硬面銲合 鲁 孟之配方，具備提升硬面效能的可行性，可以同時在不同環境中 展現其最大泛用性。 本發明使用多元成分的概念調配硬面銲材料成分配方，其合 至配方成分之銲條製造過程可直接於大氣環境中熔煉製造，其硬 面強度強化之原理機制是依循多元成分元素高亂度排列的原理， ^叙硬面銲合金成分配方依賴碳化物或是硼化物析出的原理不 同也因為無碳化物或是硼化物，所以也不會有因為碳化物或是 硼化物的存在而使硬面銲材料較脆的問題。 疋 14 1298661 古n；¥ :於本考又明之少凡成刀付合熱力學第二定理之高篆度 喊疋性_ ’耻具有例如抗氧倾抗腐_特性，因此將可 以達到在各種環境下最大可使用性與泛用性的功能，進—牛可以 =為硬面銲㈣成分配方之整體解決转，為本發明之盘既有前 本不同之獨特點具有新穎性。 為了製造具林種觀下最大泛雜的硬崎合金配方 ^明提供_種多核分所組合而成的硬面銲合金，其跳脫了傳統 二備-個主7C素成分硬面銲合金配方設計賴，多元成分硬面彈 5金配方触含的每—齡要元素分職合錢喊的原子百分 比Μ以下，以同時在不同環境中展現其最大泛用性。此外本發 明所提供之硬面銲合金配方齡之操作溫度與傳、方相比，1 之特性，一般說來傳統配方的硬面銲合金預熱溫 又而達到伽C以上，本發明之預熱溫度只要鮮c即可進行產曰 覆的刼作，具備使用方便與操作簡易之進步性。 干 本發批個職分合金細m師轉為使用元 素，其中每-種元素分別佔合金總組成的原子百分比挪以下， 亚且經過實際的測試證明，多元成分硬面缚合金配方在不同環产 ^約_硬面性f。本發分合健供了硬面輝= 更大的自由度，同時其成分比例可以針對所需之各種不 口以微調整和改變。而本發明即根據多元成分的設計理 ^，找㈣於如在㈣環射衫域分硬面銲合金的成 合0 ' 15 1298661 本發明之多兀成分硬面銲合金以多元成分之概念，合金中每 :元素原子百分比小於35%，運用多元成分的概念調配硬面鋒人 金材料成分配方’達到各種環境下最大泛雜的功能，作為频 封料的基本配方成分，此#覆材料具備較㈣操作溫度與較佳的 物理強度抗性、耐酸驗性、抗氧化性、介面填塞性......等優點， 具備進步性與實用性。 雖然本發明以祕之健實施例如上，然其並非用以限 定本發明，任何熟習相像技藝者，在不脫離本發明之精神和範園 内二當可魅软更__，因此本發批翻保縣圍須視 本說明書所附之申請專利範圍所界定者為準。 【圖式簡單說明】 ♦圖1為本糾之多元成分硬面銲合金之較佳實關配方硬度 數據；以及Al (6-12%), Cr (12-22%), Mn (l3-23°/〇), Fe (9-29%), Ni (8-30%), M〇 (13-30%) The hardness of the hard surface is between 45_65 RRC, and it also has the versatility used in different environments. The sum of the above experiments demonstrates that the multi-component hard-face soldering Lu Meng's formula has the feasibility of improving the hard surface performance and can exhibit its maximum versatility in different environments at the same time. The invention adopts the concept of multi-component composition to formulate the composition of the hard surface welding material component, and the welding rod manufacturing process which is combined with the formula component can be directly smelted and manufactured in the atmospheric environment, and the principle mechanism of the hard surface strength strengthening is arranged according to the high degree of disorder of the multi-component elements. The principle of ^ hard surface solder alloy composition depends on the principle of carbide or boride precipitation is also because there is no carbide or boride, so there will be no hard surface due to the presence of carbide or boride The problem of brittle material is brittle.疋14 1298661 古n;¥: In this test, it is clear that the singularity of the second theorem of thermodynamics is screaming _ 'shame has anti-oxidation anti-corrosion _ characteristics, so it can be achieved in various environments Under the maximum usability and versatility of the function, Jinniu can = the overall solution for the hard surface welding (four) component formulation, which is the novelty of the invention. In order to manufacture the hard-skinned alloy with the largest variety of hard-skinned alloys, the combination of the multi-cores and the multi-cores, which has escaped the traditional two-main 7C component hard-surfaced alloy formula Design Lai, the multi-component hard-faced elastic 5 gold formula touches the atomic percentage below each age-related element, so as to show its maximum versatility in different environments. In addition, the operating temperature of the hardfacing alloy of the present invention is compared with that of the transmission, and the characteristics of the first surface are generally preheated by the conventional surface of the hard surface soldering alloy to reach a gamma C or higher. As long as the hot temperature is fresh, it can be used for the production of glutinous rice, which is easy to use and easy to operate. The dry part of the job is transferred to the use of elements, in which each element accounts for the atomic percentage of the total composition of the alloy, and the actual test proves that the multi-component hard-bound alloy formula is in different rings. Produce about _ hard surface f. This is a combination of the hard surface and the greater degree of freedom, and its composition ratio can be adjusted and changed for the various needs. However, the present invention is based on the design of the multi-component composition, and finds (4) the combination of the hard-surface soldering alloy as in the (4) ring-shaped shirt field. 0 ' 15 1298661 The multi-component hard surface soldering alloy of the present invention has the concept of multi-component composition, alloy Each of the elements: the atomic percentage of the elements is less than 35%, and the concept of multi-components is used to formulate the formula of the hard-faced gold material composition to achieve the largest and most complex functions in various environments. As the basic formula of the frequency-sealing material, this #覆材料 has a comparative (4) The advantages of operating temperature and better physical strength resistance, acid resistance, oxidation resistance, interface packing, etc., are progressive and practical. The present invention is not limited to the present invention, and any skilled person skilled in the art can revive the __, even if it is not detached from the spirit of the present invention. The county shall be subject to the definition of the scope of the patent application attached to this specification. [Simple description of the drawings] ♦ Figure 1 shows the hardness of the better solidity formula of the multi-component hard surface soldering alloy;
元素之較佳實 圖2為本發明之多元成分硬φ銲合金不包含銘 施例配方硬度數據。 【主要元件符號說明】 16DETAILED DESCRIPTION OF THE ELEMENTS Figure 2 shows that the multicomponent hard φ solder alloy of the present invention does not contain the hardness data of the formulation of the embodiment. [Main component symbol description] 16