WO2008030864A2 - Distributeur de films - Google Patents

Distributeur de films Download PDF

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Publication number
WO2008030864A2
WO2008030864A2 PCT/US2007/077623 US2007077623W WO2008030864A2 WO 2008030864 A2 WO2008030864 A2 WO 2008030864A2 US 2007077623 W US2007077623 W US 2007077623W WO 2008030864 A2 WO2008030864 A2 WO 2008030864A2
Authority
WO
WIPO (PCT)
Prior art keywords
film
reel
dispenser
cosmetic
user
Prior art date
Application number
PCT/US2007/077623
Other languages
English (en)
Other versions
WO2008030864A3 (fr
Inventor
Steven E. Brown
John S. Kurek
Arvind N. Shah
Original Assignee
Avon Products, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avon Products, Inc. filed Critical Avon Products, Inc.
Priority to US12/376,313 priority Critical patent/US20100158598A1/en
Priority to BRPI0715529-8A priority patent/BRPI0715529A2/pt
Priority to AU2007292368A priority patent/AU2007292368A1/en
Priority to JP2009527537A priority patent/JP2010502390A/ja
Priority to MX2009002027A priority patent/MX2009002027A/es
Publication of WO2008030864A2 publication Critical patent/WO2008030864A2/fr
Publication of WO2008030864A3 publication Critical patent/WO2008030864A3/fr

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Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D31/00Artificial nails
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/26Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D44/00Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
    • A45D44/22Face shaping devices, e.g. chin straps; Wrinkle removers, e.g. stretching the skin

Definitions

  • the present invention is related to a device for and a method of application of one or more cosmetic and/or therapeutic agents in the form of a film, compositions, and film structures thereto.
  • Solutions in the field include dry enamel nail strips, self adhesive nail coatings, and nail appliqu ⁇ s.
  • Dry enamel nail strips are known in "Nail Strips Having a Crosslinked Polymer Topcoat” filed on 29 December 2004 as U.S. Serial No. 60/640,030 and which was filed as PCT/US05/46769 on 29 December 2005, which is herein incorporated by reference for all purposes.
  • the invention discloses nail strips for imparting long-lasting wear and shine to the fingernails and toenails and methods for making and applying such nail strips.
  • the nail enamel strip has a nail enamel film that has one or more nail enamel layers that provide the desired effects, such as long-lasting wear capabilities and shine, without the use of a U V light source.
  • At least one nail enamel layer, preferably the topmost layer in any multi-layer film, has a cross- linked polymer. The cross-linking of the polymer takes place during the manufacture of the nail strip, and any suitable curing means may be used, typically UV curing or thermal curing.
  • Nail strips are also known from U.S. Patent No.
  • the invention relates to a method of manufacturing a set of fingernail coalings or a manicure film in semi-solid form which, until desirably used, is stored in an air-tight envelope and to a product so formed.
  • the invention also relates to the product, itself, independent of the method of manufacture.
  • the user Upon application, the user removes the film from the package, separates the strip of film into individual nail coatings, removes the adhesive backing sheet from the film and places the film on an individual nail. The end or edge of the nail coatings are then trimmed to correspond precisely to the nail shape and dimensions. Then, the nail film, now in individual nail shapes, is adhesively secured to the nails, by pressing them firmly onto the nails. The nails are then further air dried or "cured" in a very short time period. During the drying time, however, the nail coatings will emit a pleasing aroma, quite similar to that generated by liquid nail enamel when it is drying but on a much reduced aromatic level.
  • a high viscosity liquid nail enamel of various formulations is heated above 100 0 F, preferably to between 100 and 150 degrees F. At least two layers of materials are deposited on a substrate of release liner paper or plastic film.
  • An adhesive coating is applied on the substrate and the heated liquid nail enamel is applied on top of the adhesive layer.
  • a second coat of the inventive high viscosity liquid nail enamel may be applied.
  • glitter or mica or similarly desirable particulate matter may be mixed with clear or translucent coating (i.e., similar to the nail enamel but mostly or completely devoid of color pigments).
  • a printing step may also be applied at this point, as may a holographic image.
  • a dispensing device comprises a housing, a first and a second reel, wherein the first reel supplies a film and the second reel stores same film after usage.
  • the reels are operably synchronized in a first rotational direction of the reels.
  • one of the reels is operably joined to a gear having a pinion.
  • a linear actuator accessible by a user includes a rack that turns the pinion.
  • the gear includes a ratchet wheel and the reel includes one or more pawls.
  • the ratcheting assembly permits rotational motion in a first direction but restrains it in a second direction.
  • the ratcheting assembly further provides incremental rotation in the first one direction, and, thus, the film remains tensioned in use.
  • An applicator tip is disclosed that acts cooperatively with the film to provide a reduced surface and allow greater control by the user.
  • the applicator tip comprises a reservoir that in cooperation with the film delivers further cosmetic and/or therapeutic agents.
  • films from fundi onalized non-woven film groups such as polymer based films, paper based fabrics, or polymer based foams (or combinations thereof) that deliver new experience and benefits.
  • These films are suitable to contain reactive mixtures of liquids, colored and non-colored cosmetics (optical blurring), makeup remover, or for targeted skin care applications and the like.
  • the film can range in utility from simple flocked surfaces to multi- layered composite films having unique functionality.
  • the base film could have strong adhesion to the skin
  • the t ⁇ p film could have properties such as gloss, color, and or optical blurrers.
  • a laminate film can be finely segmented such that independent, yet tightly meshed microdots are transferred to the skin from the carrier ribbon/film.
  • Films are disclosed that permit the delivery of cosmetic and or therapeutic agents based on (i) new skin adhesion chemistries and technologies, (ii) optical effects-ordered patterning on the skin (epidermal patterning) and blurring, (iii) reactive mixtures from sealed sachets that can be released upon application, and (iv) portability and integration of film technology into mascaras (mascara eraser), nail lacquers, etc, foundation concealers, eye shadows, skin treatment, and the like.
  • Fig. 1 is a front view of a portion of a cosmetic applicator comprising an inventive film dispenser in a first operational state in accordance with one embodiment of the present invention.
  • Fig. 2 is a side view of the portion of the cosmetic applicator comprising an inventive film dispenser of Fig. 1.
  • Fig. 3 is a front view of the portion of the cosmetic applicator comprising an inventive film dispenser in a second operational state of Fig. 1.
  • Fig. 4 is a cross-sectional view of Fig. 2.
  • Fig. 5A is an isometric view of an actuator in accordance with one embodiment of the present invention.
  • Fig. 5B is an elevational view of the actuator of Fig. 5 A.
  • Fig. 5C is an isometric view of an actuator in accordance with one embodiment of the present invention.
  • Fig. 5D is an elevational view of the actuator of Fig. 5C.
  • Fig. 6A is an isometric view of the second reel and gear in accordance with one embodiment of the present invention.
  • Fig. 6B is an isometric view of the second reel, gear, and arm wherein a simplified view of the pinion and rack is provided.
  • Fig. 6C is an isometric view of the underside of the second reel and the gear.
  • Fig. 7 is a front view of a portion of a cosmetic applicator comprising an inventive film dispenser in a first operational state in accordance with a further embodiment of the present invention.
  • Fig. 8 is a front view of a portion of the cosmetic applicator having the inventive film dispenser of Fig. 7 in a second operational state.
  • Fig. 9 is a cross-sectional view of the inventive film dispenser of Fig. 7.
  • Fig. 10 is a front cross-sectional view of a portion of a cosmetic applicator comprising an inventive film dispenser comprising a single reel actuator.
  • Fig. 1 1 is an isometric view of an actuator of the inventive film dispenser comprising a single reel actuator.
  • Fig. 12 is an isometric view of the underside of the reel and gear assembly of the actuator of Fig. 11.
  • Fig. 13 is a simplified isometric view of a film arrangement in accordance with one embodiment of the present invention.
  • Fig. 14 is a cross-sectional view of a cosmetic applicator comprising an inventive film dispenser in accordance with a further embodiment of the present invention.
  • Fig. 15 is a front view of a cosmetic applicator comprising an inventive film dispenser in accordance with a further embodiment of the present invention.
  • Fig. 16 is a cross-sectional view of the cosmetic applicator having the inventive film dispenser of Fig. 15 in accordance with a first embodiment.
  • Fig. 17 is a cross-sectional view of the cosmetic applicator having the inventive film dispenser of Fig. 15 in accordance with a second embodiment.
  • Fig. 18 is an isometric view of a cosmetic applicator comprising an inventive film dispenser in accordance with a further embodiment of the present invention.
  • Fig. 19 is a partial isometric cross-sectional view the cosmetic applicator comprising the inventive film dispenser of Fig. 18.
  • Fig. 20 is a partial isometric cross-section the cosmetic applicator comprising the inventive film dispenser of Fig. 18.
  • Fig. 21 is a partial isometric enlarged view of Fig. 18.
  • Fig. 22A is a see-through isometric view of the lop of a dispensing device according to a first embodiment of the present invention.
  • Fig. 22B is a see-through isometric view of the bottom of a dispensing device according to a first embodiment of the present invention.
  • Fig. 23 is a cross-sectional view of the bottom of the dispensing device of Fig. 22.
  • Fig. 24 is an isometric view of the dispensing device of Fig. 22.
  • Figs. 25 and 26 are isometric views of an arm and fixed post in an unengaged position and an engaged position, respectively, in accordance with one embodiment of the present invention.
  • Figs. 27-31 are isometric views of a film in accordance with one or more embodiments of the present invention and which may be used in coordination with one or more aforementioned embodiments of the dispenser and/or dispensing device.
  • Figs. 32 are isometric views of exemplary uses of one or more aforementioned films in accordance with one or more embodiments of the present invention and which may be used in coordination with one or more aforementioned embodiments of the dispenser and/or dispensing device.
  • Fig. 1 is a front view of a portion of a cosmetic applicator comprising an inventive film dispenser in a first operational state in accordance with one embodiment of the present invention.
  • Fig. 2 is a side view of a portion of the cosmetic applicator comprising an inventive film dispenser of Fig. 1.
  • Fig. 3 is a front view of the portion of the cosmetic applicator comprising an inventive film dispenser in a second operational state of Fig. I.
  • Fig. 4 is a cross-sectional view of Fig. 3.
  • a dispenser 10 is durably connected to a wand 11 that is joined to an applicator unit, such as mascara brush, gloss applicator, styling brush, or the like.
  • an applicator unit such as mascara brush, gloss applicator, styling brush, or the like.
  • the applicator unit may be protected and stored in a cap that includes a vial for dispensing a cosmetic agent, such as mascara, gloss, or styling gel.
  • Dispenser 10 includes an actuator 12 that in coordination with an inventive film 14, as further taught herein, can be used by a user to apply, dispense, and/or deliver a cleaning agent, a further cosmetic, and/or therapeutic agent ("dispensed agent").
  • the dispenser may provide a renewable cleaning surface by advancing a functional film or ribbon ("film") suitable for skin contact for removing a cosmetic agent that has been previously applied to the body of the user.
  • the dispenser further includes a body 16 that is usable as handle.
  • Body 16 may be substantially hollow and comprise a cavity 17 that preferably, but not necessarily, encompasses the entire inner space of body 16.
  • Body 16 includes a distal opening 16a from which the applicator tip (to be described below) protrudes.
  • a cover 18 that is movable relative to the handle is provided to protect portions of the actuator and the film.
  • the cover is joined to the body by via interlocking tabs that allow movement in the longitudinal axis of dispenser 12 and is joined to an arm 34.
  • One or more finger grips 20 are disposed at a convenient location relative to the body and are formed to be elevated from the body for more convenient usage.
  • the finger grips may be disposed fixedly on the body or, preferably, coupled to the cover to permit easy manipulation of the cover.
  • one finger grip 20a is disposed on one side of dispenser 10
  • a second finger grip 20b is disposed on an opposite side of dispenser 10 attached to cover 18.
  • Fig. 5 A is an isometric view of an actuator in accordance with one embodiment of the present invention.
  • Fig. 5B is an elevational view of the actuator of Fig. 5A.
  • Actuator 12 includes a first reel 30, which is preferably configured as a supply reel, and a second reel 32, which is preferably configured as a take-up reel. Each of the reels may be restrained from unwanted movement by axles that are integral with body 16 and pass through respective axle holes in the reels.
  • the first reel includes an axle hole 30a for an axle, a recessed core 30b, and a pair of walls 30c, 30d spaced apart by the core and protruding radially over core 30b.
  • the walls are spaced apart by a suitable distance to accommodate the film.
  • the edges of each wall may be tapered on at least one side to prevent damage to the film during manufacturing and/or operation of dispenser 10.
  • the core preferably is deeply recessed relative to the walls to permit storage of an ample supply of film 14 and provide a desired amount of film when needed by the user.
  • the dimensions of core 30b, walls 30c, 30d are of sufficient size to accommodate film that is 0.125 to 0.500 inches wide and 6 to 24 inches long and having any suitable thickness which may vary as required by film function as further taught herein.
  • the film for example, may be 1/1000 th of an inch to 1/10 lh of inch thickness.
  • Reel 30 further includes a pulley 30e that engages an endless belt 33, made preferably from a pliable or elastic material.
  • Pulley 3Oe and belt 33 permit the first reel to be operably coupled to the second reel to advance film 14, or by gears that mesh directly or indirectly via gears and/or gear trains.
  • Fig. 6A is an isometric view of the second reel and gear in accordance with one embodiment of the present invention.
  • Fig. 6B is an isometric view of the second reel, gear, and arm wherein a simplified view of the pinion and rack is provided.
  • Fig. 6C is an isometric view of the underside of the second reel and the gear.
  • Second reel 32 includes a core 32a, and a pair of walls 32b, 32c that is spaced apart by the core and protruding radially over the core.
  • the core preferably is recessed relative to the walls to prevent film 14 from sliding off the reel
  • the walls are spaced apart by a suitable distance to accommodate the film.
  • the edges of each wall may be tapered on at least one side to prevent damage to the film during manufacturing and/or operation of dispenser 10.
  • the cores of reel 30 and/or 32 may be textured to advance the film.
  • the core or cores may include a further rubber layer, a chemical layer, or other means that interacts with the film to aid in advancing it.
  • each or both of the cores may include a reservoir or depositor)' of a further chemical agent that interacts with the film as the film is contact with core 30 and/or 32 and aids the film by rendering the film to a more functional state, e.g., cleaning it, depositing on it, or treating it.
  • the reservoir may be hollow space that includes a predetermined of the cosmetic and/or therapeutic agent.
  • the may comprise a material that may be impregnated the cosmetic and/or therapeutic agent.
  • the second reel is disposed in interaction with a gear 35 having a pinion 35a
  • the pinion is meshed with a rack 36 disposed on an arm 34 and becomes engaged when the finger grip moves the cover.
  • Second reel 32 further includes one or more pawls 32f that are preferably integrally molded with the second reel and engage a ratchet wheel 35b of gear 35 (Fig. 6C).
  • the pawl and ratchet wheel serve to permit incremental rotational motion of the second reel in a first rotational direction while restricting it in a second rotational direction.
  • the ratchet wheel is disposed on the reel and the pawls are disposed on the gear.
  • gear 35 further includes a disk 35c that protects the interior of second reel 32, but is rotatable independently with respect to the second reel.
  • Reel 32 is disposed on disk 35c.
  • disk 35c When rotational motion in the first direction is permitted, the gear and reel turn together.
  • disk 35c i.e. gear 35, rotates independently of the reel.
  • Rack 36 is coupled to cover 18 wherein finger grip 20a and 20b are coupled to cover 18.
  • cover 18 includes stop members 18a (Fig. 5B) disposed at the proximal end of the cover.
  • the stop members serve to limit displacement of the cover relative to body 16 and may have a short tab structures or may be shaped to extend the length of the rack and be shaped as a rail.
  • the stop members slide in guides (not shown) formed or notched into the inside of the body, preferably in the longitudinal direction. When the stop members reach the ends of the guide or an intermediately located predetermined position, cover 18 is restrained from further movement in lhat direction.
  • An applicator lip 37a is attached to the distal end of arm 34d as illustrated in Fig. 1.
  • the applicator tip is wedge shaped and constructed of a pliable material, such as silicon rubber.
  • the proximal end of arm 34d is rigidly attached to body 16 and preferably is not retractable. Arm 34d may be flexible to make application on the user's body more comfortable.
  • Fig. 5C is an isometric view of an actuator in accordance with one embodiment of the present invention.
  • Fig. 5D is an elevational view of the actuator of Fig. 5C.
  • Actuator 12 includes a first reel 30, which is preferably configured as a supply reel, and a second reel 32, which is preferably configured as a take-up reel. Each of the reels may be restrained from unwanted movement by axles that are integral with body 16 and pass through respective axle holes in the reels.
  • the first reel includes an axle hole 30a for an axle, a recessed core 30b, and a pair of walls 30c, 3Od spaced apart by the core and protruding radially over core 30b.
  • the walls are spaced apart by a suitable distance to accommodate the film.
  • the edges of each wall may be tapered on at least one side to prevent damage to the film during manufacturing and/or operation of dispenser 10.
  • the second reel is disposed in interaction with a gear 35 having a pinion 35a.
  • the pinion is meshed with a rack 36 disposed on an arm 34 and becomes engaged when the finger grip that is operably connected to the arm is displaced by a user.
  • Arm 34 includes a first portion 34a on which substantially all of rack 36 is disposed.
  • the first portion may be sized to have a length that matches the diameter second reel 32.
  • Arm 34 further includes an inclined portion 34b that joins the first portion to a second portion 34c that is disposed to have a central axis lie in plane X-X.
  • An actuator tip 37 is disposed adjacent to second portion 34c, i.e. at a distal end of arm 34.
  • the applicator tip is wedge shaped and constructed of a pliable material, such as silicon rubber.
  • Arm 34 further is coupled to finger grip 20a at a convenient position, but preferably on portion 34a, while finger grip 20b is coupled to cover 18, but not to arm 34.
  • film 14 is preferably situated so that it is held in supply in reel 30, travels over actuator tip 37 where it may meet the body of the user, and the used film is taken-up, i.e. stored, on second reel 32.
  • the film is preferably situated so that a longitudinal axis of film 14 lies in a working plane X-X.
  • a dispensing device 10 that has been stored for usage, the user via the finger grips displaces cover 18 to a distal end of dispenser 10.
  • finger grips 20 are used to displace cover 18.
  • the slop members 18a move in the guides of body 16 towards a proximal end of the body leaving film 14, arm 34d, and applicator tip 37a exposed at distal opening 16a.
  • rack 36 engages pinion 35a to rotate the pinion and via wheel 35c turn pawls 32f (Fig. 6C) to rotate second reel 32.
  • the pulley and belt arrangement, or a like gearing arrangement then turns first reel 30.
  • a predetermined portion of film 14 travels from the first reel in a travel direction A to the tip.
  • finger grip 20a causes arm 34 to displace toward the distal end of the dispenser.
  • rack 36 engages pinion 35a to rotate the pinion and via wheel 35c turn pawls 32f (Fig 6C) to rotate second reel 32.
  • the pulley and belt arrangement, or a like gearing arrangement then turns first reel 30.
  • a predetermined portion of film 14 travels from the first reel in a travel direction A to the tip.
  • the tip moves to protrude from the body 16 at distal opening 16a.
  • the user then directs the tip toward the part of the body where the dispensed agent is desired. Simultaneously, the portion of film 14 that has been previously used, travels in a travel direction B away from the applicator tip and toward the second reel for storage and preferably eventual discard.
  • ratchet and pawl assembly of Figs. 6A-6C may be used in any suitable embodiment of the present invention, but is particularly favored with respect to the embodiments of Figs. 5A-5D.
  • Fig. 7 is a front view of a portion of a cosmetic applicator comprising an inventive film dispenser in a first operational state in accordance with a further embodiment of the present invention.
  • Fig. 8 is a front view of a portion of the cosmetic applicator having the inventive film dispenser of Fig. 7 in a second operational state.
  • Fig. 9 is a cross-sectional view of the inventive film dispenser of Fig. 7.
  • a dispenser 40 is durably connected to a wand 41 to which an applicator unit, such as mascara brush, gloss applicator, styling brush, or the like is connected.
  • an applicator unit such as mascara brush, gloss applicator, styling brush, or the like
  • the applicator unit may be protected and stored in a cap that includes a vial for dispensing a cosmetic agent, such as mascara, gloss, or styling gel.
  • Dispenser 40 includes an actuator 42 that in coordination with an inventive film 44 can be used by a user to apply, dispense, and/or deliver a further cosmetic and/or one or more dispensed agent as taught with respect to other embodiments of the present invention.
  • Dispenser 40 includes a body 46 comprising a cavity 47 for housing the actuator and film.
  • the body includes a guide 48 configured as a slot wherein a button 51 is restrained to travel in a predetermined direction.
  • the body further includes an opening 46a at a distal end to permit at least an applicator tip 53 and a portion of film 44 to extend beyond the opening 46a
  • Actuator 42 includes a first reel 50 providing a supply of film 44, a second reel 52 for take- up, i.e. storage of used and/or unused portions that have advanced beyond applicator tip 53 disposed on arm 54 as taught with respect to Figs. 5C and 5D and especially with respect to arm 34b, second arm portion 34c, and actuator tip 37.
  • Reels 50 and 52 are preferably constructed similar to reels 30 and 32, respectively, and comprise cores and walls that are spaced apart by the core and protrude radially over the respective core.
  • Arm 54 includes a rack 56 that meshes with pinion 55a of gear 55 to rotate the second reel.
  • Button 51 is operably connected through the guide to the arm. Therein, a displacement of the button also displaces the arm.
  • Actuator 42 further includes a ratchet wheel associated with gear 55 that cooperates with one or more pawls associated with second reel 52 to permit rotational movement in a first direction and prevent it in a second direction.
  • the first and second reels are operably connected via pulleys and a belt.
  • the first and second reels may also be operably connected via direct or indirect gears.
  • button 51 is displaced and travels in guide 48 toward the distal end of the dispenser. Arm 54 moves with button 51 to feed film from the first reel. As the applicator tip is extended beyond opening 46a, the film is also advanced into the user's range. Thus, film 44 advances in a travel direction C. Therein, the pawl and ratchet wheels of the second reel do not turn second reel 52.
  • the button is slid back by the user wherein rack 56 meshes with pinion 55a.
  • the rotational movement of the pinion is transferred to the ratchet wheel, which turns the pawls of the second reel.
  • the rotational movement of the second reel causes the first reel to rotate and for the second reel to take up a portion, preferably, the used portion of the film.
  • film 44 advances in a travel direction D.
  • Figs. 10-12 illustrate further embodiments of the present invention.
  • Fig. 10 is a front cross- sectional view of a portion of a cosmetic applicator comprising an inventive film dispenser comprising a single reel actuator wherein a tip is fixedly attached to the body of the housing, and a cover and arm are fixedly connected toe ach other.
  • Fig. 1 1 is an isometric view of the actuator of the inventive film dispenser comprising a single reel actuator.
  • Fig. 12 is an isometric view of the underside of the reel and gear assembly of the actuator of Fig. 10 and 11.
  • a dispenser 60 is durably connected to a wand 61 to which an applicator unit, such as mascara brush, gloss applicator, styling brush, or the like is connected.
  • an applicator unit such as mascara brush, gloss applicator, styling brush, or the like
  • the applicator unit may be protected and stored in a cap that includes a vial for dispensing a cosmetic agent, such as mascara, gloss, or styling gel.
  • Dispenser 60 includes an actuator 62 that in coordination with an inventive film 64 can be used by a user to apply, dispense, and/or deliver a dispensed agent as taught with respect to other embodiments of the present invention.
  • Film 64 may be an endless loop of a suitable size for actuator 62.
  • Dispenser 60 further includes a body 66 that is usable as handle and comprises a cavity 67. Further, dispenser 60 includes a cover 68 that is movable relative to the handle to protect portions of the actuator and the film. The cover is joined to rack 76 as previously taught with respect to cover 18 and rack 36 of Figs. 5 A and 5B.
  • One or more finger grips 70 are disposed at a convenient location relative to the body and are formed to be elevated from the body for more convenient usage.
  • the finger grips may be disposed fixedly on the cover to permit easy manipulation of the cover relative to the body.
  • one finger grip 70 is disposed on one side of dispenser 60, while a second finger grip is disposed on an opposite side of dispenser 60.
  • Rack 66c is coupled to cover 68 wherein finger grip 70a and 70b are coupled to cover 68.
  • cover 68 includes stop members that are disposed at the proximal end of the cover.
  • the stop members serve to limit displacement of the cover relative to body 66 and may have a short tab structures or may be shaped to extend the length of the rack and be shaped as a rail.
  • the stop members slide in guides (not shown) formed or notched into the inside of the body, preferably in the longitudinal direction. When the stop members reach the ends of the guide or an intermediately located predetermined position, cover 68 is restrained from further movement in that direction.
  • An applicator tip 66a is attached to the distal end of body 66 as illustrated in Fig. 10.
  • the applicator tip is wedge shaped and constructed of a pliable material, such as silicon rubber.
  • the proximal end of arm 66b is rigidly attached to cover 68 and preferably is not retractable. Arm 66b may be flexible to make application on the user's body more comfortable.
  • the user via the finger grips displaces cover 68 to a distal end of dispenser 60.
  • finger grips 70 are used to displace cover 68 relative to body 66.
  • the stop members move in the guides of body 66 towards a proximal end of the body leaving film 64, arm 66b, and applicator tip 66a exposed at a distal opening.
  • rack 66c engages pinion 75a to rotate the pinion and via wheel 75c turn pawls 72d to reel 72.
  • a predetermined portion of film 64 travels from the reel to the tip.
  • an actuator 71 includes a reel 72 having a core 72a and walls 72b, 72c that are spaced apart by the core and that extend radially beyond the core.
  • the reel is disposed in cooperation with a gear 75, having a pinion 75a that engages rack 76 on arm 78, which can be moved as previously taught with respect to the interaction of arm 54 and button 51.
  • Gear 75 includes an axle hole 75b that permits an axle preferably formed on the inside of a body to restrain the gear from moving.
  • Gear 75 further includes a ratchet wheel 75d that is operably connected with one or more pawls 72d of reel 72.
  • the pawl and ratchet wheel (“ratchet assembly”) serve to permit rotational motion of the second reel in a first rotational direction while restricting it in a second rotational direction.
  • the ratchet wheel is disposed on the reel and the pawls are disposed on the gear.
  • Gear 75 further includes a disk 75c that protects the interior of reel 72, but is rotatable independently with respect to the reel.
  • Reel 72 is disposed on disk 75c.
  • disk 75c When rotational motion in the first direction is permitted, the gear and reel turn together.
  • disk 75c i.e. gear 75, rotates independently of the reel.
  • Arm 78 may be linear or may include a bent portion 78 to place tip in a medial position. Arm 78 is connected to an applicator tip, such as the previously taught applicator tip 37 or may include an elongated applicator tip 77. Therein, tip 77 may be configured as a reservoir and hold a further cosmetic and/or therapeutic agent.
  • the reservoir may be hollow space in the tip or the arm that includes a predetermined of the cosmetic and/or therapeutic agent.
  • the may comprise a material that may be impregnated the cosmetic and/or therapeutic agent.
  • the applicator tip may be insertable in an opening provided in a stationary post 79 that is secured to a body as further taught herein.
  • the user when the user wishes to engage a dispenser 60, the user via the finger grips displaces cover 68 to expose the film disposed over the applicator tip.
  • the ratchet assembly restrains the reel from rotational motion and keeps the film stationary. The user then directs the tip toward the part of the body where the dispensed agent is desired.
  • dispenser 60 When the user desires to close dispenser 60, the cover is moved to a distal end of dispenser
  • the rack engages the pinion to rotate the pinion and via the ratchet wheel turn the pawls to rotate reel.
  • a predetermined portion of film 64 travels from the reel to the tip.
  • a portion of film that has been previously used is moved to be renewed or for storage.
  • Fig. 13 is a simplified isometric view of a film arrangement in accordance with one embodiment of the present invention.
  • film 64 is disposed on reel 72 and post 79.
  • the film is a M ⁇ bius strip so that both sides, i.e. the sole side, wears evenly.
  • the film may have any convenient chirality.
  • Fig. 14 is a cross-sectional view of a cosmetic applicator comprising an inventive film dispenser in accordance with a further embodiment of the present invention.
  • a dispenser 80 is durably connected to a wand 81 to which an applicator unit, such as mascara brush, gloss applicator, styling brush, or the like is connected.
  • an applicator unit such as mascara brush, gloss applicator, styling brush, or the like is connected.
  • the applicator unit may be protected and stored in a cap that includes a vial for dispensing a cosmetic agent, such as mascara, gloss, or styling gel.
  • Dispenser 80 includes an actuator 82 that in coordination with an inventive film 84 can be used by a user to apply, dispense, and/or deliver a dispensed agent as taught with respect to other embodiments of the present invention.
  • Film 84 may be an endless loop of a suitable size for actuator 82.
  • Dispenser 80 further includes a body 86.
  • body 86 comprises a cavity 87 for housing the actuator and film.
  • the body includes a guide configured as a slot wherein a button is restrained to travel in a predetermined direction.
  • the body further includes an opening 86a at a distal end to permit at least an applicator tip 91 and a portion of film 84 to extend beyond the opening 86a.
  • actuator 82 includes a reel 88 having a core and walls that extend radially beyond the core.
  • the reel is disposed in cooperation with a gear 90, having a pinion 90a that engages rack 92 on arm 94.
  • Gear 90 includes an axle hole 90b that permits an axle preferably formed on the inside of body 86 to restrain the gear from moving.
  • Gear 90 further includes a ratchet wheel that is operably connected with one or more pawls of reel 88.
  • the pawl and ratchet wheel (“ratchet assembly”) serve to permit rotational motion of the second reel in a first rotational direction while restricting it in a second rotational direction.
  • the ratchet wheel is disposed on the reel and the pawls are disposed on the gear.
  • Gear 90 further includes a disk 90c that protects the interior of the reel, but is rotatable independently with respect to the reel.
  • Reel 88 is disposed on disk 90c.
  • disk 90c When rotational motion in the first direction is permitted, the gear and reel turn together.
  • disk 9Oc 5 i.e. gear 90, rotates independently of the reel.
  • Arm 94 is connected to an applicator tip 91, such as the previously taught applicator tip 37 or may include an elongated applicator tip such as the previously taught applicator lip 77. Therein, the applicator tip may be configured to hold a further cosmetic or therapeutic agent. Arm 94 may be linear or may include a bent portion to place applicator tip 91 medial to the reel as, for example, previously taught with respect to Figs. 5C and 5D. In accordance with one embodiment of the present invention, the applicator tip may be slideable in an opening provided in a post that is proximal to the opening of the body, as for example, taught with respect to Fig. 7.
  • film 84 may be configured as a M ⁇ bius strip.
  • dispenser 80 To operate dispenser 80, a button illustrated, for example, in Fig. 7 is displaced and travels in the guide toward the distal end of the dispenser. Arm 94 moves with the button. As the applicator tip is extended beyond opening 86a, the film is also advanced into the user's range. Therein, the reel does not turn although gear 90 rotates. Furthermore, dispenser 80 may be configured similarly to actuator 62.
  • the button is slid back by the user wherein the rack meshes with the pinion.
  • the rotational movement of the pinion is transferred to the ratchet wheel, which turns the pawls of the reel and, thus, the reel.
  • the film is advanced.
  • Figs. 15-17 depict further embodiments of the present invention.
  • Fig. 15 is a front view of a cosmetic applicator comprising an inventive film dispenser in accordance with a further embodiment of the present invention.
  • Fig. 16 is a cross-sectional view of the cosmetic applicator having the inventive film dispenser of Fig. 15 in accordance with a first embodiment.
  • Fig. 17 is a cross-sectional view of the cosmetic applicator having the inventive film dispenser of Fig. 15 in accordance with a second embodiment.
  • a dispenser 100 is durably connected to a wand 101 to which an applicator unit, such as mascara brush, gloss applicator, styling brush, or the like is connected.
  • an applicator unit such as mascara brush, gloss applicator, styling brush, or the like
  • the applicator unit may be protected and stored in a cap that includes a vial for dispensing a cosmetic agent, such as mascara, gloss, or styling gel.
  • Dispenser 100 includes an actuator 102 that includes an applicator tip 103 over which an inventive film 104 can be used by a user to apply, dispense, and/or deliver a dispensed agent.
  • Dispenser further includes a body 106 that is usable as handle and comprises a cavity 107.
  • Dispenser 100 further includes a user operable dial 108 that is reachable on the exterior of body 106 in one or more locations. Therein, body 106 includes one or more slots 106a that are situated to permit rotation of the dial.
  • a dispenser 100a includes a dial 108a that is operably connected to an actuator 102a.
  • Actuator 102a includes a reel 11 Oa preferably having a core and sidewalls extending beyond the core for retaining film 104a.
  • a fixed applicator tip 103a is provided and extends beyond an opening 106a provided at a distal end of dispenser 100a.
  • Film 104a is provided in an endless loop having a length suitable for a length that traverses the reel and the applicator tip 103a and preferably is taught within the actuator.
  • Reel 11 Oa is preferably mounted on an axle.
  • reel 1 10a may be provided with pawls that engage a fixed ratchet wheel of the axle.
  • Reel 1 10a may also be provided with a ratchet wheel that engage pawls provided on the axle.
  • film 104a may be configured as a M ⁇ bius strip.
  • Wheel 108a may be connected with reel 11 Oa, preferably co-axial, so that 108a permits incremental movement of reel 100a.
  • the wheel and reel advantageously include a pawl and reel.
  • a dispenser 100b includes a dial 108b that is operably connected to an actuator 102b.
  • Actuator 102b includes a first reel 1 10b preferably having a core and sidewalls extending beyond the core for retaining film 104b.
  • a fixed applicator tip 103b is provided and extends beyond an opening 106b provided at a distal end of dispenser 100a.
  • Reel 110b is preferably mounted an axle. Therein, reel 110b may be provided with pawls that engage a fixed ratchet wheel of the axle.
  • Reel 1 10b may also be provided with a ratchet wheel that engage pawls provided on the axle.
  • a second reel 112 is secured to body 106.
  • the second reel and the first reel are operably connected to advance at least a portion of film 104 from the first reel toward the second reel.
  • the first reel and the second reel may be connected by pulleys and a belt 1 1 1 as taught with respect to other embodiments, or by gears that mesh directly or indirectly via gears and/or gear trains.
  • Film 104b is provided as a fixed length suitable for a predetermined number of uses.
  • the user rotates dial 108b, this causes the first reel to turn and transfers rotational movement to the second reel to advances the film a predetermined distance relative to the turning of the dial.
  • ratchet interaction of the reel and axle permits only incremental movement of the film. Because the reels operate together, the belt may be maintained taut.
  • Fig. 18 is an isometric view of a cosmetic applicator comprising an inventive film dispenser in accordance with a further embodiment of the present invention.
  • Fig. 19 is a partial isometric cross-sectional view the cosmetic applicator comprising the inventive film dispenser of Fig. 18.
  • Fig. 20 is a partial isometric cross-section the cosmetic applicator comprising the inventive film dispenser of Fig. 18.
  • Fig. 21 is a partial isometric enlarged view of Fig. 18.
  • a dispenser 120 is durably connected with a wand 121 (having a recessed portion 121a for mating with a portion of dispenser 120, to which an applicator unit, such as mascara brush, gloss applicator, styling brush, or the like is connected.
  • the applicator unit may be protected and stored in a cap that includes a vial for dispensing a cosmetic agent, such as mascara, gloss, or styling gel.
  • Dispenser 120 includes an actuator 122 that includes an applicator lip 123 over which an inventive film that can be used by a user to apply, dispense, and/or deliver a further cosmetic and/or one or more therapeutic effects.
  • the dispenser provides a renewable cleaning surface by advancing a functional film or ribbon suitable for skin contact for removing a cosmetic agent that has been previously applied to the body of the user.
  • Dispenser further includes a body 126 that is usable as handle and comprises a cavity 127.
  • Dispenser 120 further includes a user operable dial 128 that is located in medial to distal position relative to the dispenser and is reachable on the exterior of body 126 in one or more locations. Therein, body 126 includes one or more slots 126a that are situated to permit rotation of the dial.
  • dispenser 120 is dimensioned to have a diameter similar to or suitable to the diameter of the wand.
  • a fixed applicator tip 123 is provided and extends beyond an opening 126b provided at a distal end of dispenser 120.
  • Dial 128 is operably connected to actuator 122.
  • Actuator 122 includes a first reel 130 and a second reel 132. Both reels may be smooth faced, but may also include a core and sidewalls extending beyond the core for retaining a film. Both reels are preferably on axles that are formed in the interior of body 126 and are operably coupled. Therein, the first reel and the second reel may be connected by pulleys and a belt as taught with respect to other embodiments, or by gears that mesh directly or indirectly via gears and/or gear trains.
  • dial 128 is connected to the first reel.
  • the first reel preferably includes one or more pawls that engage a fixed ratchet wheel of the respective axle.
  • Reel 130 may also be provided with a ratchet wheel that engage pawls provided on the axle.
  • the film preferably is a fixed length film.
  • the user rotates dial 128 and advances the film a predetermined distance relative to the turning of the dial. Therein, ratchet interaction of the reel and axle permits only incremental movement of the film.
  • Fig. 22A is a see-through isometric view of the top of a dispensing device according to a first embodiment of the present invention.
  • Fig. 22B is a see-through isometric view of the bottom of a dispensing device according to a first embodiment of the present invention.
  • Fig. 23 is a cross-sectional view of the bottom of the dispensing device of Fig. 22 and
  • Fig. 24 is an isometric view of the dispensing device of Figs. 22 A and 22B
  • a dispensing device 200 includes an actuator 202 that advances at least a portion of film 204 from a first position to a second position. Film 204 may be used by a user to apply, dispense, and/or deliver a cosmetic and/or one or more therapeutic effects. Film 204 may be an endless loop of a suitable size for actuator 202.
  • the dispensing device includes a body 206 having an ergonomic shape that has a broad rear portion and a narrower front portion that preferably is comfortable to be held in the hand of a user, especially a user who may have smaller hands than average.
  • body may be approximately 2 inches in length to be conveniently sized.
  • the body is preferably substantially hollow to form cavity 207 that preferably encompasses the majority of the inner space of body 206.
  • An opening 206a is provided at the distal end of the body so that film 204 may be brought into reach of the user.
  • a guide is disposed in the body at preferably a medial position.
  • a burton 210 operable by the user travels in the guide to engage the actuator.
  • Actuator 202 is situated in cavity 207 and includes a reel 212, which is preferably configured to have a core and walls spaced apart by the core and which extends beyond the core to protect and guide film 204 as it interacts with the reel.
  • the reel is disposed in interaction with a gear 214 having a pinion 214a.
  • the pinion is engaged by a rack 216 on arm 218 in response to the button that is operably connected to the arm.
  • Gear 214 includes an axle hole 214b that permits an axle (not shown) that is preferably formed on the inside of body 206.
  • Gear 214 further includes a ratchet wheel 214c that is operably connected with one or more pawls 212a of the reel.
  • the pawl and ratchet wheel assembly (“'ratchet assembly”) serve to permit rotational motion of the reel in a first rotational direction while retraining it in a second direction.
  • the ratchet wheel is disposed on the reel and the pawls are disposed on gear 214.
  • reel 212 is disposed on a disk 214d of gear 214.
  • disk 214d i.e. gear 214, rotates independently of the reel.
  • Actuator 202 further includes a fixed post 220 mounted fixedly with respect to the body on, for example, an axle formed on the inside of body 206.
  • the fixed post includes an axle hole 220a.
  • An applicator tip 222 is disposed at a distal end of arm 218 and extends through an aperture of the post and through opening 206a of the body.
  • Arm 218 may include a first portion 218a on which substantially all of rack 216 is disposed.
  • the first portion may be sized to have a length that matches the diameter of reel 212.
  • Arm 218 further includes an inclined portion 218b that joins the first portion to a second portion 218c that is disposed to have a central axis in plane Y-Y.
  • the user slides button 210 from its rearward "parked” location away to the distal end. This causes the arm to move forward and extend the applicator tip through the aperture in the fixed post and through opening 206a. As the arm is advanced, the rack engages the pinion and transfers the rotational motion to the ratchet wheel.
  • the ratchet assembly is coordinated so that reel 212 does not engage in rotational motion and keeps the film stationary.
  • Film 204 is disposed in actuator 202 to travel over reel 212 and fixed post 222.
  • film 14 is preferably situated so that a longitudinal axis of film 14 lies in the working plane X-X. However, as the applicator is moved forward this causes the applicator tip to catch the film to extend it through opening 206a to be placed in reach of the user. The user can then apply the film to their body.
  • the user slides button to it rearward "parked" position.
  • the rack again engages the pinion.
  • the rotational motion is transferred to the ratchet wheel.
  • the above preferably ratchet assembly now cause the ratchet wheel to engage the pawls of reel 212 to engage in rotational motion causing the film to advance.
  • the ratchet assembly is coordinated to advance the film when the user first advances the button from the parked position and for the film to remain in a stationary position when the button is returned to its parked position.
  • film 204 is a M ⁇ bius strip so that both sides, i.e. the sole side, wear evenly.
  • the film may have any convenient chirality.
  • Figs. 25 and 26 are isometric views of an arm and fixed post in an unengaged position and an engaged position, respectively, in accordance with one embodiment of the present invention.
  • the actuator 71 of Fig. 1 1 may include an arm and fixed post.
  • the post preferably facilitates smooth and/or unencumbered movement of the film over the post.
  • An actuator such as one taught previously includes an arm 300 that may or may not include a rack 302. Further, the arm may or may not include a reservoir 303, which may contain a cosmetic and/or therapeutic agent. Reservoir 303 may be hollow space in the arm that includes a predetermined of the cosmetic and/or therapeutic agent. In addition or instead, reservoir 303 may comprise a material that may be impregnated the cosmetic and/or therapeutic agent.
  • An applicator tip 307 is disposed on the distal end of the arm.
  • a fixed post 306 is disposed the body of the device and is stationary relative to the arm.
  • a film 304 is arranged to travel over the fixed post and covers a distal end of an aperture 306a that extends through the post.
  • the applicator tip travels through the aperture and displaces the film bringing the film in a favorable position for application to the body of the user.
  • film 304 includes areas that are coated and/or made of non- wicking material on both or one side such that the cosmetic and/or therapeutic agent is applied only in predetermined locations of the film.
  • Figs. 27-31 are isomelric views of film in accordance with one or more embodiments of the present invention and which may be used in coordination with one or more aforementioned embodiments of the dispenser and/or dispensing device.
  • the functional films of the present invention may be used by a user to apply (a) a dispensed agent provided in the film, as, for example, with regard to the embodiments related to films 400, 410a, and 410b taught below; or (b) a dispensed agent in the form of a transfer film, as, for example, with regard to the embodiments related to films 420, 430, 440a, and 440b taught below.
  • Fig. 27 is an isometric view of a flocked film in accordance with one embodiment of the present invention.
  • Film 400 may be 0.125 inches to 0.500 inches wide and have a length of 12 inches and may comprise eye makeup removing waxes or be suitable as a mascara remover.
  • Film 400 may be made from non-woven fabrics or from polymeric materials.
  • Non-woven fabrics for example, be formed as spun bond, sonic bond, needle punch, point bond, and thermal bond fabric and may comprise poly rayon, polyester, and/or polypropylene.
  • a film made of non-woven fabric may be configured to comprise desired physical properties by varying the porosity, elastic modulus, and/or surface texture, i.e. the feel of the fabric.
  • the fabric may be configured to have one or more types of finishes such that a surface layer 402 may have texture that ranges from smooth to flocked that may be, advantageously, useful when laminated on vinyl substrates.
  • Film 400 may comprise a general polymeric material and/or, thus, be selected from the group of polyesters, polyethylene, ethylene methyl acrylale, polyvinyl chloride, chlorotrifiuoroethlene, vinyl acetate, polyurethane, nylon, polystyrene, and ethylene vinyl alcohol, cellulose, and/or nitrocellulose.
  • a film 400 is selected from the general polymer class may be surface modified to promote or inhibit adhesion to cosmetic and/or therapeutic agent effect compositions.
  • the dispensed agent i.e. cosmetic or therapeutic compositions
  • the dispensed agent may be printed onto film 400 regardless whether the film is made of non-woven fabric or of polymers using printing techniques known in the art or suitable for only printing the dispensed agent.
  • printing techniques known in the art or suitable for only printing the dispensed agent.
  • screen-printing, ink jet printing, and aerosol printing (dry & wet), thermal printing (waxes), including lithographic techniques may be used to achieve mono-chromatic or multi-chromatic effects.
  • the dispensed agent comprises a solid, semi-solid, and/or finely divided powder that is suitable for being incorporated in a medium such as a fluid (printing, ink jet printing, and aerosol printing (wet)), paste (lithographic printing), or wax (thermal printing) that permits the printing process to suitable operate.
  • a fluid printing, ink jet printing, and aerosol printing (wet)
  • paste lithographic printing
  • wax thermo printing
  • an eye application comprises a film 400.
  • the eye application comprises a single composition.
  • a top surface 402 includes a dispensed agent comprising a powdered based eye shadow composition that is deposited on a non- woven substrate via a printing technique as described above.
  • a suitable composition is provided in Table 1.
  • the eye application comprises two or more dispensed agents each comprising a different powdered based eye shadow composition.
  • an eye shadow effect with an eyeliner effect may be created by the use of multiple dispensed agents, one delivering a powdered based eye shadow composition while another delivers an eyeliner composition.
  • a top surface 402 includes a plurality of dispensed agents each comprising a powdered based eye shadow composition differing from another that is deposited on a non- woven substrate via a printing technique as described above.
  • a dispensed agent creating the effect of eyeliner may be deposited in a thin line while another dispensed agent is disposed in a wider area of the surface to simulate the eyeliner.
  • a suitable composition of a semi solid eyeliner composition is provided in Table 2 and a powdered based eye shadow composition is provided in Table 1.
  • a face application suitable for use as a foundation comprises a film 400.
  • the face application comprises a dispensed agent and having one or more compositions.
  • a top surface 402 includes a dispensed agent comprising a powdered base composition that is deposited on a non-woven substrate via a printing technique as described above.
  • a suitable composition is provided in Table 3.
  • Powder compositions may comprise one or more special effect pigments and/or pearlescent that provide the face added dimensionality and improved surface appearance.
  • incorporating the composition in a film targeted application of specially pigments and pearls to specific regions of the face are possible.
  • a face application suitable for use as a concealer comprises a film 400.
  • the face application comprises a dispensed agent and has one or more wax based compositions.
  • a top surface 402 includes a dispensed agent comprising one or more wax based compositions that preferably comprise a high pigment load.
  • the pigments provide high coverage to conceal local areas of tone variation, discoloration, and minor surface defects.
  • film 400 comprises a polymer-base or a non-woven base.
  • the non-woven film preferably comprises a low porosity.
  • the composition is melted and deposited in liquid form on film 400 via a technique as described above.
  • a suitable composition is provided in Table 4.
  • Figs. 28 A and 28B are isometric views of film in accordance with a further embodiment of the present invention.
  • Films 410a and 410b are preferably made as a laminate of two materials, which may each be a film.
  • the laminate is arranged so that films 410a and 410b include or more sachets 412 and 414 that each comprise a space or chamber for a dispensed agent, E , F that may be a single liquid compositions or dual liquid compositions.
  • the compositions may be one or more reactants wherein, for example, a reactant E is disposed in sachet 412 and a reactant F is disposed in sachet 414.
  • E and F may be liquid compositions.
  • the sachets may arrange in any suitable orientation such as transverse to or with the length the film.
  • Reactants preferably are compositions in liquid or liquid crystal form to permit easy flow from the sachet to the body of the user.
  • Films 410a and 410b may be made and filled using packaging equipment designed for the pharmaceutical industry.
  • equipment for blister and tablet packaging, continuous web processing, and/or syringe and injection technology may be suitable.
  • means for microencapsulating liquids as a dispensed agent may be used to fill the sachets.
  • each sachet releases the respect reactant and are mixed at the point of application.
  • the reactants are preferably selected so that the reactants cause a reactive mixture having a beneficial action to the user.
  • a reactive mixture i.e. dispensed agent, may result in self-heating, polymerization, alternating actives sensitive to pH, adhesion, and/or basecoat/top coat, etc.
  • films 410a and 410b may be used in lip, eye, face, and/or nail applications.
  • a lip application comprises a film 410a or 410b.
  • sachets 412 and/or 414 hold one or more liquid lip compositions that preferably provide a high gloss appearance.
  • a liquid lip composition comprises a single composition.
  • dispensed agent E and F are substantially identical and may be non-reactive with each other.
  • a suitable composition is provided in Table 5.
  • liquid lip-gloss formulations rely on thick films being deposited on the lip to achieve a glossy finish, resulting in a heavy feel and color migration.
  • composition of the present invention provides high gloss appearance in a very thin film, providing excellent look and light feeling.
  • liquid lip composition comprises a dual composition.
  • a first dispensed agent E may be comprised as a first composition in the form of a liquid base coat composition having substantially the composition of Table 6.
  • the base coat preferably provides long lasting color and preferential adhesion to the lip via polyurethane derivative.
  • a second dispensed agent F may be comprised as a second composition in the form of a liquid top coat and having substantially the composition of Table7.
  • the top coat preferably has a non-color transfer top coat. This allows a single step application wherein traditionally the base coat and topcoat are not compatible (tend to separate) in a single formulation, thus requiring two applications of the different products.
  • the inventive films 410a and 410b permit the delivery of non-compatible ingredients that react upon application.
  • the first composition comprises one or more low molecular weight polymers that are on release of the second composition cross-linked by activators in the second composition.
  • the present invention permits reactive mixture compositions that have a lower solvent and greater formulation flexibility to achieve new levels of performance (wear) and experience.
  • compositions of Table 6 and 7 include compositions comprising anionic acrylic polymers, silicone/acrylate co-polymers and carbomers in the first composition and polyamide, cationic acrylic polymers (dimethylaminoethyl acrylate polymer) in the second composition. These will react to provide a composition with increased molecular weight and, thus, increased viscosity and better film formation resulting in improved wear.
  • a liquid foundation application comprises a film 410a or 410b.
  • sachets 412 and/or 414 hold one or more liquid foundation compositions that preferably permit targeted application to the face areas with known wear problems.
  • liquid foundation compositions that have high concentrations in make the foundation uncomfortable to wear.
  • lower polymer content decreases wear.
  • liquid foundation such as the one in Table 8, having acrylate copolymer in a film 41 Oa or 410b, a strong film formation on the skin of the user.
  • the polymer content is increased to provide superior wear in problematic areas of the face.
  • FIG. 29 is an isometric view of a film in accordance with a further embodiment of the present invention.
  • a film 420 comprises a carrier film 422 and a transfer film 424 that act together as a simple laminate film.
  • the carrier film 422 preferably comprises a polyester.
  • the transfer film has thickness that is reduced over similar films known in the art.
  • Manufactures such as Biodermis, SiI-K, Rejevness, and others offer silicone based films in a wide range of geometries films. While these have good adhesion to the skin and medicinal attributes, they have not been utilized to achieve instant cosmetic effects.
  • transfer film 424 may comprise a silicone or polymer elastomer having a reduced thickness of 0.05 mm to 0.5 mm that are created as the dispensed agent is deposited on the carrier film in layers and/or in functionalized surfaces, such as those described further below.
  • known films have a thickness of 0.5 mm to 2 mm and are provided in sheets or strips. Such a reduced thickness is difficult to handle and to transfer to a surface if the dispensed agent comprises a traditional polymer base.
  • the transfer film of the present invention preferably comprises a silicone or polymer elastomer film based dispensed agent that achieve new aesthetics and performance as discussed further below.
  • the silicone elastomer may comprise materials generally known in the medical industry for the management of hypertrophic and keloid scars as a result of burn injuries or surgery and, thus, film 424 is preferably made of medical grade silicone polymers.
  • film 424 is preferably made of medical grade silicone polymers.
  • the physico-chemical properties of the silicone are tailored to specific applications to deliver hydration and medicinal effects to the skin and film 424 is preferably optimized to achieve a comprise silicone wherein the mechanical properties are optimized by increasing or decreasing polymer cross-linking and utilizing specific polymer chemistry' to mimic natural skin.
  • transfer film 424 may comprise a general polymer preferably selected from the group of polyesters, polyethylene, ethylene methyl acrylate, polyvinyl chloride, chlorotrifluorocthlcnc, vinyl acetate, polyurcthanc, nylon, polystyrene, ethylene vinyl alcohol, cellulose, and nitrocellulose.
  • the film may be surface modified to promote or inhibit adhesion to the skin surface.
  • the transfer film may comprise colorants, optical blurrers, and/or other types of cosmetic and/or or therapeutic effects.
  • a polymeric film layer is configured to have a refractive index of at least 0.005 from a second polymeric film layer.
  • the layers are laminated during manufacture to provide unique optical effects such as angular refractions, Fresnel lens effect, and/or surface patterning effect that provide one or more unique scattering effects.
  • the polymer based transfer film may be fabricated with a wide range of mechanical properties to achieve the desired elasticity and tensile strength.
  • transfer film 424 may be formed using partially gelled, semi dry polymer solvent systems.
  • the transfer film is applied to body of the user while the carrier film is retained with the dispenser or dispensing device.
  • FIG. 30 is an isometric view of a film in accordance with a further embodiment of the present invention.
  • a film 430 comprises a carrier film 432 and a transfer film 434.
  • Transfer film 434 further comprises a skin adhesive layer 436 and a surface layer 438, each of which may be a separately produced film manufactured together.
  • film 430 is preferably constructed as a multi-laminate film as opposed to a simple laminate film, such as film 420.
  • Skin adhesive layer 436 may comprise a thin film, such a silicone or polymer elastomer film or any other suitable film.
  • the film is preferably treated with a biocompatible adhesive preferably based on dextrine derivatives, silicone, acrylate, and/or synthetic rubber adhesives designed for biomedical applications to promote skin adhesion.
  • a biocompatible adhesive preferably based on dextrine derivatives, silicone, acrylate, and/or synthetic rubber adhesives designed for biomedical applications to promote skin adhesion.
  • Dow Coring Bio PSA silicone pressure sensitive adhesives, Silicone adhesives, MD7-4502 and MD7- 4602, acrylic and synthetic rubber adhesives MG-0560 and MG 0153/PA may be used.
  • the transfer film is applied to body of the user while the carrier film is retained with the dispenser or dispensing device. Since the transfer film comprises more than one layer the transfer film may provide unique optical properties (using interference films) or special physico-chemical properties such as preferential adhesion. Thus, one or more aforementioned embodiments of the dispenser and/or dispensing devices and include the compounds that are detailed below.
  • Film 420 and/or film 430 may be suitably used for lip cosmetics and face cosmetics.
  • a lip cosmetic comprises a film 430 that includes transfer film 434 having a thickness of 0.05 mm - 0.5 mm.
  • the transfer film comprises adhesive layer 436, which is preferably made of one or more thin films of silicone elastomer having similar elastic modulus to lip tissue.
  • a pressure sensitive adhesive is added to a side of the adhesive layer that will be proximate to the carrier film. Sufficient adhesion between the elastomer and the lip surface allow the transferable film to be deposited as the application device is moved along the contour of the lip.
  • the elastomer film are preferably is fabricated to have sufficient tensile strength to allow transfer yet readily separate post application.
  • Surface layer 438 of the transfer film preferably comprises a material that has a suitable gloss and shine to give visual appeal when applied to the lips of the user.
  • a face cosmetic includes a film 430 that includes transfer film 434 having a thickness of 0.01 mm - 0.5 mm.
  • film 430 will optically blur and fill topical defects in a face area of the user.
  • the transfer film comprises adhesive layer 436, which is preferably made of one or more thin films of silicone elastomer having similar elastic modulus to skin tissue.
  • a pressure sensitive adhesive is added to a side of the adhesive layer that will be proximate to the carrier film.
  • Surface layer 438 preferably comprises one or more optical properties such as diffuse transmittance and/or reflectance.
  • the optical properties may comprise nanoparticulates of nylon, boron nitride, and/or alumina and/or inherent properties of the elastomeric material.
  • Sufficient adhesion between the elastomer and the face skin surface allow the transferable film to be deposited as the application device is moved along the contour of the face.
  • the elastomer film are preferably is fabricated to have sufficient tensile strength to allow transfer yet readily separate post application.
  • Figs. 31 A and 31B are isometric views of film in accordance with a further embodiment of the present invention.
  • Films 440a and 440b comprise a plurality of segments 442a, 442b, respectively, that provide a cosmetic and/or therapeutic agent.
  • Each of the segments is associated with a carrier film 444.
  • the dispenser and/or dispensing device when a user applies film 440 one or more of the plurality of segments are applied to body of the user while the carrier film is retained with the dispenser or dispensing device.
  • Film 440a comprises a plurality of micro-segmented regions 442a that are disposed relative to an axis of the film.
  • segments 442a may be disposed transverse to the longitudinal axis.
  • Film 440b comprises a plurality of micro-segments 442b that are intercalated, i.e. disposed next to another segment, forming a region having a contiguous surface of a cosmetic and/or therapeutic agent.
  • segments 442b serve to provide a flexible transfer film with superior abilities to maintain a continuous surface.
  • the segments 442a, 442b may be functional ized for the specific purpose such as application to the lips, nail, etc.
  • a liquid composition is painted onto the nail using a brush type implement.
  • a nail application comprises a film 440a or 440b, which preferably are continuous films of polyester.
  • a semi-dried the nail liquor is incorporate in layer 442a, i.e. 442b.
  • a suitable compaction for the nail liquor is provided in Table 9.
  • a nail liquor is disposed between two polymer layers, of a film.
  • One layer comprises a base layer and the second a protective layer.
  • the protective film is removed exposing the nail liquor film upon contact with the nail surface.
  • the semi-dried liquor film adheres to the nail during application.
  • the liquor film is deposited on the nail surface leaving a dry to the touch, thin film.
  • the films can be printed with various graphics or multi color designs, such as French tips pictures and other designs.
  • a suitable composition for the nail liquor is provided in Table 9.
  • Figs. 32A-32E are isometric view of a film 450 comprising one or more discontinuous transfer elements 454 in accordance with one or more embodiments of the present invention.
  • Film 450 may be any of the films previously taught. In accordance with one or more embodiments of the present invention, film 450 is substantially similar to film 420. Therein, film 450 comprises a carrier film 456 and a one or more discontinuous transfer element 454 that in coordination with one or more aforementioned embodiments of the dispenser and/or dispensing device deliver a dispensed agent on a transfer element.
  • a plurality of discontinuous transfer elements comprises sequential segments suitable to color the lips of the user with a dispensed agent that comprise the lip compositions previously taught.
  • a first transfer element is configured to be suitable for the upper lip by being larger than a second immediately adjacent transfer element that is configured to be suitable for the lower lips. Subsequent transfer elements are provided in like pairs.
  • a plurality of discontinuous transfer elements comprises sequential segments suitable to color the eye area of the user.
  • a first transfer element is configured to be suitable for, for example, an upper eye area by being suitably shaped.
  • a second transfer immediately adjacent to the second transfer element is configured to be suitable for, for example, a lower eye area.
  • a third transfer immediately adjacent to the second transfer element is configured to be suitable for, for example, an eye lid area. Subsequent transfer elements are provided for the next series of applications by the user.
  • each transfer area comprises a dispensed agent having a different yet complimentary eye shadow composition as taught previously herein to achieve a total look.
  • Each transfer element may be applied by pressing from a first to a consumer feels satisfied with appropriate application on that part and then advances to another segment by rotating the wheel or spool and goes on with second body part application.
  • film 450 is substantially similar to film 430.
  • Film 450 in coordination with one or more aforementioned embodiments of the dispenser and/or dispensing device delivers a dispensed agent on a transfer element.
  • film 450 comprises a carrier film 456 and a one or more discontinuous transfer element 454 joined to a skin adhesive layer that is substantially similar to layer 436 and preferably is sized to be identical in plan as transfer element 454.
  • transfer element 454 may be configured to have a shape and design of a Bindi (Fig. 32C), which are typical of South Asia and South East Asia. When the user applies the transfer element, the skin adhesive layer will aid in retaining the Bindi on the forehead of the user.
  • Other exemplary' shapes of transfer elements 454 include lips (Fig. 32B) and cheek blush (Fig. 32D).
  • the transfer element 454 is configured as an eye shadow that includes a number of shade areas that have been provided in the film.
  • the assignee of this invention has also filed U.S. patent application 60/953,362 entitled “COSMETIC APPLICATOR” on August 1, 2007, and which is herein incorporated by reference for all purposes, that discloses an applicator and methods of screen printing eye shadow.
  • transfer element 454a comprises a plurality of cosmetics disposed substantially in a thin layer on frontward surface of substrate 450a
  • the transfer element comprises a pattern of one or more application areas, generally indicated as 458a-458e
  • the application areas are preferably gaplessly adjacent to each other to comprise a coordinated effects or enhancement.
  • the thin layer of cosmetic is believed to be cohesively maintained on the substrate in light of the presence of wet and dry binders, as disclosed hereinafter.
  • Each application area may have a cosmetic effect, such coloration or shade, when applied to the human body that when considered as whole provides a sophisticated look.
  • the shades for a cosmetic applicator of an eye shadow are preferably predetermined and suitably coordinated to permit ease of use for the user.
  • the size of each application area is preferably predetermined to provide a favored arrangement or to provide a coordinated effect and further permit ease of use for the user.
  • the quantity of cosmetic in each application area preferably is carefully calibrated to deliver a suitable unit dose. Since the skin of each user varies the unit does for each consumer is different. Thus, the cosmetic may be changed to accommodate seasonal variations, differences in skin properties of the target user, and other suitable factors.
  • Transfer element 454a may be configured to have one application area, such as area 458a, suitable for the eye area crease, and have one or more other areas of varying shade, i.e. areas 458b-458e extend on the eyelid to the lash line.
  • application areas 458a-458e three to five color shades may be present, i.e. application areas 458a-458e.
  • one or more are distinct shades, for example, the shades of application areas 458a, 458c, and 458e and one or more are blended shades, i.e. the shades of application areas 458b (a blend of distinct shades 458a and 458c) and 458d ( a blend of distinct shades 458c and 458e).
  • the user positions film 450a using one of the dispensers taught previously positions the dispenser as need. Upon a satisfactory location, the user applies pressure with one or more digits to the rearward surface of the substrate. The cosmetic comprised in the transfer element is transferred to the body of the user.
  • Light pressure may be applied to the directly, in a rolling motion about a finger of the user on the lid and brow, or may be accomplished by lightly massaging or rubbing the top of the film using the dispenser.
  • at least one of the transferable cosmetics has been formulated to have improved wear quality as will be taught further herein.
  • Film 450a may be manufactured using a flat screen printing process, i.e. serigraphic printing, as illustrated herein and/or as disclosed in U.S. Patent No. 5,192,386, which is herein incorporated by reference in its entirety for all purposes. However, film 450a or other films 450 may also be manufactured according to any other suitable process.
  • a screen printing unit applies a cosmetic to form a first application area 458a of the transfer element onto the substrate and prepares it for a subsequent manufacturing step.
  • the screen printing unit includes a printer having a screen prepared as is generally known in the art.
  • the screen comprises an impermeable surface having one or more screened apertures in the surface that correspond to the shape and size of application area 458a
  • a plurality of targets on the screen and the substrate may be provided to aid in the precise positioning and printing of the application area.
  • a reservoir provides a suitable amount of slum' to the screen and a suitable portion exits through the screened aperture onto the subslrale to create application area 458a
  • Afler application area 458a has been deposited, the excess slurry is removed.
  • the screen is removed and the substrate travels a distance to a dryer.
  • the distance is preferably predetermined to permit the evaporation of some or all of the solvent from the composition for application area 458a and may be adjusted with respect to differences in composition.
  • the distance may instead be configured as drying rack wherein the roll stock or sheet stock of film substrate 450a remain for a predetermined time to suitably evaporate the solvents.
  • Further screen printing units are provided to print application areas 458b-458e.
  • the cosmetic composition used herein is preferably formulated so that it has a greater affinity for the skin than the substrate. It has been found that the transfer of the cosmetic from the substrate around the eye area is improved when the composition contains a filler such as mica having a platelet crystalline structure. It is believed also that transfer is facilitated around the eye area because the skin around the eye has a higher concentration of natural oils.
  • dispenser and/or dispensing device film for quick installation and customization of the film.
  • Such customization may be made directly by the user to create a pleasing or unique design, or may be made in accordance with medical needs to deliver a medically necessary product in a device that would make such medicinal product less obvious and/or more convenient.
  • a user may utilize a personal computing device, such as a personal computer, wireless telecommunications device, communicates over one or more networks, such as the Internet, with a server.
  • the user may go through an authentication process or may simply access a plurality of information of interest including information regarding cosmetics, including information regarding the dispensed agent. Thereto, the user may choose to select information for their use and or manipulate information.
  • This information may include new and novel designs for the dispensed agent.
  • the user may find a particular design of lip color interesting.
  • the user may desire to create a unique design such as nail color that may be applied as a film.
  • the user may then select this lip color and obtain it via direct purchase and/or delivery through an authorized salesperson.
  • a quantity of film as taught previously may be delivered to the user via the salesperson for gratis or remuneration.
  • the film preferably comes packaged such that quick installation in one or more aforementioned embodiments of the dispenser and/or dispensing device.

Abstract

L'invention concerne un distributeur de films cosmétique comprenant un corps tenu par un utilisateur et un actionneur logé dans le corps et utilisé en coordination avec un film afin de fournir un agent délivré. L'actionneur comprend une bobine débitrice destinée à tenir le film et une bobine réceptrice destinée à recevoir le film. Un bras met en prise la bobine réceptrice pour faire avancer le film et une pointe au niveau d'une extrémité du bras place le film à proximité de l'utilisateur. Des films innovants sont également présentés.
PCT/US2007/077623 2006-09-07 2007-09-05 Distributeur de films WO2008030864A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/376,313 US20100158598A1 (en) 2006-09-07 2007-09-05 Film Dispenser
BRPI0715529-8A BRPI0715529A2 (pt) 2006-09-07 2007-09-05 aplicador de pelÍcula
AU2007292368A AU2007292368A1 (en) 2006-09-07 2007-09-05 Film dispenser
JP2009527537A JP2010502390A (ja) 2006-09-07 2007-09-05 フィルムディスペンサ
MX2009002027A MX2009002027A (es) 2006-09-07 2007-09-05 Dispensador de pelicula.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US84291506P 2006-09-07 2006-09-07
US60/842,915 2006-09-07

Publications (2)

Publication Number Publication Date
WO2008030864A2 true WO2008030864A2 (fr) 2008-03-13
WO2008030864A3 WO2008030864A3 (fr) 2008-08-21

Family

ID=39157998

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/077623 WO2008030864A2 (fr) 2006-09-07 2007-09-05 Distributeur de films

Country Status (9)

Country Link
US (1) US20100158598A1 (fr)
JP (1) JP2010502390A (fr)
CN (1) CN101511605A (fr)
AR (1) AR062712A1 (fr)
AU (1) AU2007292368A1 (fr)
BR (1) BRPI0715529A2 (fr)
MX (1) MX2009002027A (fr)
TW (1) TW200819084A (fr)
WO (1) WO2008030864A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2475759A (en) * 2009-11-26 2011-06-01 Plus Kk Refillable application-film transfer tool with a reverse rotation prevention mechanism
EP2393392A1 (fr) * 2009-02-06 2011-12-14 Stephanie Porter Pty Ltd Instrument pour enlever et corriger un cosmétique
FR2973236A1 (fr) * 2011-03-31 2012-10-05 Oreal Utilisation d'un dispositif de transfert d'un film cosmetique anti-transpirant applique sur la peau

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11064785B2 (en) * 2018-09-12 2021-07-20 Spin Master Ltd. Apparatus, kit, and method for decorating nails
CN111713826A (zh) * 2020-06-23 2020-09-29 江苏省健尔康医用敷料有限公司 一种口罩储藏装置

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5512128A (en) * 1993-07-02 1996-04-30 Pritt Produktionsgesellschaft Mbh Easy-load film applicator
US5904806A (en) * 1994-10-18 1999-05-18 Tapelicator, Inc. Tape dispensing applicator and replaceable tape cartridge
US6000455A (en) * 1996-09-02 1999-12-14 Tipp Ex Gmbh & Co Kg Hand-held implement for transferring a film of e. g. adhesive or coating or colored material from a backing strip wound on a supply reel to a substrate
US6808565B1 (en) * 1995-10-06 2004-10-26 Seed Rubber Co., Ltd. Clutch mechanism of coat film transfer tool and coat film transfer tool

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2566016A (en) * 1947-06-07 1951-08-28 Clarence W Cochran Container for disposable tissues
NL275525A (fr) * 1961-12-26
KR880013498A (ko) * 1987-05-29 1988-12-21 소대섭 메니큐어용 필름의 성형장치

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5512128A (en) * 1993-07-02 1996-04-30 Pritt Produktionsgesellschaft Mbh Easy-load film applicator
US5904806A (en) * 1994-10-18 1999-05-18 Tapelicator, Inc. Tape dispensing applicator and replaceable tape cartridge
US6808565B1 (en) * 1995-10-06 2004-10-26 Seed Rubber Co., Ltd. Clutch mechanism of coat film transfer tool and coat film transfer tool
US6000455A (en) * 1996-09-02 1999-12-14 Tipp Ex Gmbh & Co Kg Hand-held implement for transferring a film of e. g. adhesive or coating or colored material from a backing strip wound on a supply reel to a substrate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2393392A1 (fr) * 2009-02-06 2011-12-14 Stephanie Porter Pty Ltd Instrument pour enlever et corriger un cosmétique
EP2393392A4 (fr) * 2009-02-06 2014-07-16 Stephanie Porter Pty Ltd Instrument pour enlever et corriger un cosmétique
GB2475759A (en) * 2009-11-26 2011-06-01 Plus Kk Refillable application-film transfer tool with a reverse rotation prevention mechanism
GB2475759B (en) * 2009-11-26 2012-10-24 Plus Kk Application-film transfer tool
FR2973236A1 (fr) * 2011-03-31 2012-10-05 Oreal Utilisation d'un dispositif de transfert d'un film cosmetique anti-transpirant applique sur la peau
WO2012131070A3 (fr) * 2011-03-31 2013-06-13 L'oreal Utilisation d'un dispositif pour le transfert d'un film cosmétique anti-transpirant appliqué à la peau

Also Published As

Publication number Publication date
BRPI0715529A2 (pt) 2013-07-09
JP2010502390A (ja) 2010-01-28
WO2008030864A3 (fr) 2008-08-21
TW200819084A (en) 2008-05-01
AR062712A1 (es) 2008-11-26
MX2009002027A (es) 2009-03-05
CN101511605A (zh) 2009-08-19
US20100158598A1 (en) 2010-06-24
AU2007292368A1 (en) 2008-03-13

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