WO2008029307A2 - Method for manufacturing a non-woven fabric based on natural wool, plant for performing such method and product obtained by such method - Google Patents
Method for manufacturing a non-woven fabric based on natural wool, plant for performing such method and product obtained by such method Download PDFInfo
- Publication number
- WO2008029307A2 WO2008029307A2 PCT/IB2007/052930 IB2007052930W WO2008029307A2 WO 2008029307 A2 WO2008029307 A2 WO 2008029307A2 IB 2007052930 W IB2007052930 W IB 2007052930W WO 2008029307 A2 WO2008029307 A2 WO 2008029307A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fibres
- wool
- flocks
- needle
- woven fabric
- Prior art date
Links
- 210000002268 wool Anatomy 0.000 title claims abstract description 29
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 238000004080 punching Methods 0.000 claims abstract description 22
- 244000144992 flock Species 0.000 claims abstract description 17
- 238000009960 carding Methods 0.000 claims abstract description 6
- 239000004744 fabric Substances 0.000 claims description 10
- 229920002994 synthetic fiber Polymers 0.000 claims description 10
- 229920001410 Microfiber Polymers 0.000 claims description 8
- 239000003658 microfiber Substances 0.000 claims description 8
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 2
- 238000011282 treatment Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 241000196324 Embryophyta Species 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 2
- 238000003491 array Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 206010020112 Hirsutism Diseases 0.000 description 1
- 208000034530 PLAA-associated neurodevelopmental disease Diseases 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000124033 Salix Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4266—Natural fibres not provided for in group D04H1/425
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
Definitions
- the present invention concerns a method and a plant for the manufacture of a non-woven fabric, in particular a non-woven fabric based on natural wool, as well as the product obtained by- such method.
- a non-woven fabric is a substantially bi- dimensional, semi-processed product, which is obtained by- assembling a plurality of natural or synthetic fibres of a certain length. From this point of view, it is radically different from a classic woven fabric, which is instead put together starting from yarns of indefinite length and using weaving machines which accomplish a classic weft-warp configuration .
- a needle punching machine is a work station equipped with one or more pairs of arrays of opposite needles (having specific arrangements) , which are interpenetrated and alternately moved apart, while a veil of fibres to be processed is made to move between the same,- when the two opposite arrays of needles are repeatedly moved closer and further apart, causing the needles to interpenetrate, the interposed fibres are "needle punched", i.e. they interleave and mechanically connect with one another: this allows to impart a certain cohesion to the veil of fibres.
- the consistence and the physical properties of the natural wool fibres are such that the needle punching process may work - i.e. it may supply a stable non-woven fabric - only in specific conditions, i.e. when the veil of raw material is of an adequate basic weight and when the needles are arranged diagonally and/or characterised by the presence of special hooks .
- the object of the present invention is hence that of providing a plant and relative treatment method for obtaining non-woven fabrics based on natural wool.
- a further object of the invention is to provide a product of non-woven fabric based on natural wool which is soft, with a good handle, resistant (also to dying treatments) and suited to a number of applications.
- fig. 1 is a schematic view illustrating an exemplifying plant of the invention
- fig. 2 is an elevation side view of an exemplifying plant of the invention
- fig. 3 is a section view of an exemplifying plate of needles of the needle punching machine employed in the invention
- fig. 4 is an elevation view of a needle of the plate of fig. 3
- fig. 5 is a schematic view of an enlarged detail of the water jet station shown in fig. 2; figs.
- 6A and 6B are microscope pictures, with 4X lens, 40X eyepiece, 128X video enlargement and 1OX lens, IOOX eyepiece, 320X video enlargement, respectively, of the fabric according to the invention after needle punching;
- figs . 7A and 7B are pictures as in figs . 6A and 6B of the non-woven fabric after treatments with water jets,- and figs. 8A and 8B are pictures as in figs. 6A and 6B of the non-woven fabric after a dying treatment.
- the manufacturing process provides to start from processed wool, in a manner known per se, so as to have flocks of sufficient volume and uniformity.
- This first treatment may be performed for example with any known-type mechanical process.
- the wool flocks are then mixed with variously-sized flocks of synthetic fibres, such as fibres of polyester, polyamide, viscose, acrylic, bamboo, PLA and preferably microfibre, in an amount ranging from 20 to 50% by weight, better about 30%.
- synthetic fibres such as fibres of polyester, polyamide, viscose, acrylic, bamboo, PLA and preferably microfibre, in an amount ranging from 20 to 50% by weight, better about 30%.
- microfibre flocks are particularly preferred, which impart excellent mechanical and physical qualities to the final woollen fabric,- a particularly suited microfibre is the one called "mechanical splittable", made of polyester/polyamide, for example the one marketed by Far East Textile Ltd. under the name EASTLON SY1250SMS MICRO-SPLIT.
- microfibre in this context fibres are intended with a count below 1 dtex or conjugated fibres, with count above
- the mixed mass then undergoes a process by means of a carding machine/veil-forming machine 2, with subsequent possible pleating machine, to obtain a continuous processable veil, of a thickness from 6 to 8 cm and weight from 120 to 300 g/m 2 , depending on the thickness of the final product which it is intended to achieve .
- the veil of fibres is preferably stretched by a gill box and then placed on a first needle-punching station 3, where it is needle-punched with techniques known per se.
- a needle punching machine manufactured by Fehrer AG may be used.
- Needle punching may also be carried out through one or more subsequent steps, for example carrying out also a pre-needle- punching .
- a first mechanical interleaving between the fibres making up the veil takes place. Needle-punching is performed until a carpet of non-woven fabric is obtained of thickness 2.5-4.0 mm.
- the fabric undergoes an interleaving treatment with water jets 4 (a so-called "spunlace” treatment) , which dignifies the non-woven, needle-punched fabric.
- a so-called "spunlace” treatment a so-called "spunlace” treatment
- the Applicant has detected that this stage is very advantageous for the good outcome of the process with woollen fibres, because the number and solidity of the bonds between the fibres is increased.
- the microfibres are divided (split) by the water jets and the ultrathin fibres thereby forming further bind the woollen fibres.
- Water-jet interleaving hence allows to complete and dignify the non-woven, needle-punched fabric, making it more close-knit, uniform and soft, which result is critical to be able to obtain the desired product based on woollen fibres.
- Water-jet interleaving is preferably carried out with a jet density of 12-18 per linear cm, preferably 16 per linear cm, at a pressure of 250-400 bar, preferably 150-250 bar, at a low advancement speed .
- Needle-punching allows to provide a first compaction and intersecting of the mixed woollen/synthetic fibres, also starting from a veil of a significant width (for example above 8 cm) .
- This allows to obtain a substrate suitable to make the subsequent water-jet interleaving effective - which would otherwise be unable to interact with the deeper fibres - which imparts desired characteristics of handle, feel, porosity and cohesion.
- It is thereby possible to obtain soft and close- knit fabrics, starting from a veil of a thickness even above 8 cm, without nevertheless excessively forcing the needle-punching process which would inevitably lead to a felt-type product.
- the non-woven fabric based on natural wool has the characteristic pore fineness and hairiness as the "spunlace", as well as the good edge shear resistance. Due to the high cohesion obtainable through coupling the two treatments, the woollen, non-woven fabric also has a high resistance to tearing and withstands multiple washing cycles. Moreover, precisely in the light of these qualities, the non-woven fabric of the invention can perfectly withstand a dying treatment even at the end of the process, which dying would instead be much more difficult to carry out on the raw material (i.e., upstream of the processing, directly on the fibres) . Also this last feature further extends the field of application of the product according to the invention.
- the Applicant was able to ascertain that the woollen fabric obtained through the process and the plant of the inventions surprisingly has features never obtained so far by using needle- punching processes only or of water-jet interleaving only.
- the number of and variety of applications which this original woollen fabric meets are remarkable, also thanks to the characteristics of the woollen fibre itself, such as the fire- retarding and insulating character.
- the non-woven fabric manufactured according to the invention may find application ' in the field of blankets or insulating panels, in lining materials and tapestry (including the automotive industry) - also as a replacement of foams, provided it is manufactured with a suitable thickness/volume - in filters, both dry ones and wet ones, in the field of cleaning cloths (wherein it develops a polishing effect, thanks to the wool component) , in the clothing industry and other.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Woven Fabrics (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009521405A JP2009544862A (en) | 2006-07-27 | 2007-07-24 | Method for producing a natural wool-based nonwoven, plant for applying the method, and product obtained by the method |
US12/375,227 US20090305593A1 (en) | 2006-07-27 | 2007-07-24 | Method for manufacturing a non-woven fabric based on natural wool, plant for applying such method, and product obtained by such method |
EP20070825957 EP2049719A2 (en) | 2006-07-27 | 2007-07-24 | Method for manufacturing a non-woven fabric based on natural wool, plant for performing such method and product obtained by such method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT001484A ITMI20061484A1 (en) | 2006-07-27 | 2006-07-27 | METHOD OF MANUFACTURE OF A NON-WOVEN FABRIC BASED ON NATURAL WOOL, PLANT FOR SUCH PROCESS AND PRODUCT OBTAINED BY IT |
ITMI2006A001484 | 2006-07-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008029307A2 true WO2008029307A2 (en) | 2008-03-13 |
WO2008029307A3 WO2008029307A3 (en) | 2008-05-15 |
Family
ID=38951266
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2007/052930 WO2008029307A2 (en) | 2006-07-27 | 2007-07-24 | Method for manufacturing a non-woven fabric based on natural wool, plant for performing such method and product obtained by such method |
Country Status (5)
Country | Link |
---|---|
US (1) | US20090305593A1 (en) |
EP (1) | EP2049719A2 (en) |
JP (1) | JP2009544862A (en) |
IT (1) | ITMI20061484A1 (en) |
WO (1) | WO2008029307A2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010109273A1 (en) * | 2009-03-27 | 2010-09-30 | Csir | Process for producing a nonwoven air filter medium |
ITBZ20090025A1 (en) * | 2009-05-27 | 2010-11-28 | Johannes Winkler | PROTECTIVE CARPET FOR PLANTS, IN PARTICULAR SCREWS AND A PROCESS FOR ITS REALIZATION. |
ITMI20100068A1 (en) * | 2010-01-21 | 2011-07-22 | Marco Maranghi | PROCESS TO PREPARE A NON-WOVEN FABRIC WITH A SURFACE COVERED WITH A MICROFIBER AND FABRIC THAT CAN BE OBTAINED WITH THE PROCESS |
CN108738306A (en) * | 2016-03-08 | 2018-11-02 | 宝洁公司 | Comb non-woven webs and its use in absorbent article |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9731436B2 (en) * | 2014-09-22 | 2017-08-15 | Mary Anderle | Blended fiber pad |
CN109537354A (en) * | 2018-11-28 | 2019-03-29 | 山东昌诺新材料科技有限公司 | A kind of bamboo fibre and wood pulp spun lacing composite cleaning cloth and preparation method thereof |
CN112831912B (en) * | 2021-02-05 | 2023-10-03 | 刘超 | Production line of ultrathin coconut palm fiber flat pad and manufacturing method of coconut fiber flat pad |
Family Cites Families (11)
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JP2582994Y2 (en) * | 1992-12-25 | 1998-10-15 | 富一 中辻 | Felt material for OA equipment |
JPH0719333U (en) * | 1993-09-13 | 1995-04-07 | 株式会社フジコー | UV protection hood |
JPH0719455U (en) * | 1993-09-20 | 1995-04-07 | 株式会社フジコー | UV protection shade |
CN1034879C (en) * | 1994-08-11 | 1997-05-14 | 宁波德艺成服装辅料实业公司 | Technology for preparation of collar bottom wool fabric |
EP0884413A1 (en) * | 1997-06-13 | 1998-12-16 | Bonded Fibre Fabric Limited | A non-woven fabric |
JPH11200213A (en) * | 1998-01-19 | 1999-07-27 | Unitika Ltd | Nonwoven fabric and its production |
NL1010029C1 (en) * | 1998-09-08 | 2000-03-09 | Proeco B V I O | Recycling cotton articles, by shredding the articles, blending cotton fibres with longer fibres, needling and subjecting to fine water jets, to form a nonwoven material |
US6378179B1 (en) * | 2001-01-05 | 2002-04-30 | Gary F. Hirsch | System and method for reconstituting fibers from recyclable waste material |
DE10163548C1 (en) * | 2001-12-21 | 2003-10-30 | Freudenberg Carl Kg | Flame-resistant interlining for protective clothing against thermal effects, process for its production and its use |
JP2006171046A (en) * | 2004-12-13 | 2006-06-29 | Fujikoo:Kk | Oil supply device and cleaning device |
EP1922203A2 (en) * | 2005-08-10 | 2008-05-21 | Reliance Industries Ltd. | Process of producing ultra fine microdenier filaments and fabrics made thereof |
-
2006
- 2006-07-27 IT IT001484A patent/ITMI20061484A1/en unknown
-
2007
- 2007-07-24 JP JP2009521405A patent/JP2009544862A/en active Pending
- 2007-07-24 EP EP20070825957 patent/EP2049719A2/en not_active Withdrawn
- 2007-07-24 US US12/375,227 patent/US20090305593A1/en not_active Abandoned
- 2007-07-24 WO PCT/IB2007/052930 patent/WO2008029307A2/en active Application Filing
Non-Patent Citations (1)
Title |
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None |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010109273A1 (en) * | 2009-03-27 | 2010-09-30 | Csir | Process for producing a nonwoven air filter medium |
ITBZ20090025A1 (en) * | 2009-05-27 | 2010-11-28 | Johannes Winkler | PROTECTIVE CARPET FOR PLANTS, IN PARTICULAR SCREWS AND A PROCESS FOR ITS REALIZATION. |
ITMI20100068A1 (en) * | 2010-01-21 | 2011-07-22 | Marco Maranghi | PROCESS TO PREPARE A NON-WOVEN FABRIC WITH A SURFACE COVERED WITH A MICROFIBER AND FABRIC THAT CAN BE OBTAINED WITH THE PROCESS |
EP2348146A1 (en) * | 2010-01-21 | 2011-07-27 | Marco Maranghi | Process for preparing a non-woven fabric having a surface covered with microfiber |
US8584328B2 (en) | 2010-01-21 | 2013-11-19 | Marco Maranghi | Process for preparing a non-woven fabric having a surface covered with microfiber and fabric obtainable with said process |
CN108738306A (en) * | 2016-03-08 | 2018-11-02 | 宝洁公司 | Comb non-woven webs and its use in absorbent article |
CN108738306B (en) * | 2016-03-08 | 2021-04-02 | 宝洁公司 | Carded nonwoven webs and their use in absorbent articles |
Also Published As
Publication number | Publication date |
---|---|
EP2049719A2 (en) | 2009-04-22 |
US20090305593A1 (en) | 2009-12-10 |
WO2008029307A3 (en) | 2008-05-15 |
JP2009544862A (en) | 2009-12-17 |
ITMI20061484A1 (en) | 2008-01-28 |
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