WO2008012996A1 - Process for producing packaged drink - Google Patents

Process for producing packaged drink Download PDF

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Publication number
WO2008012996A1
WO2008012996A1 PCT/JP2007/061608 JP2007061608W WO2008012996A1 WO 2008012996 A1 WO2008012996 A1 WO 2008012996A1 JP 2007061608 W JP2007061608 W JP 2007061608W WO 2008012996 A1 WO2008012996 A1 WO 2008012996A1
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WIPO (PCT)
Prior art keywords
beverage
sterilization
sterilized
container
filling
Prior art date
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PCT/JP2007/061608
Other languages
French (fr)
Japanese (ja)
Inventor
Katsumi Senbon
Takeshi Iwashita
Original Assignee
Toyo Seikan Kaisha, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from JP2006203825A external-priority patent/JP5136740B2/en
Priority claimed from JP2007004815A external-priority patent/JP5071622B2/en
Application filed by Toyo Seikan Kaisha, Ltd. filed Critical Toyo Seikan Kaisha, Ltd.
Priority to US12/374,037 priority Critical patent/US20090320415A1/en
Publication of WO2008012996A1 publication Critical patent/WO2008012996A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C7/00Concurrent cleaning, filling, and closing of bottles; Processes or devices for at least two of these operations
    • B67C7/0073Sterilising, aseptic filling and closing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/04Sterilising wrappers or receptacles prior to, or during, packaging
    • B65B55/10Sterilising wrappers or receptacles prior to, or during, packaging by liquids or gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/12Sterilising contents prior to, or during, packaging
    • B65B55/14Sterilising contents prior to, or during, packaging by heat

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

It is intended to provide a process for producing a packaged drink whereby filling can be performed at room temperature without resorting to using a chemical or sterile water, the favorable taste and flavor of the content can be maintained while relieving the thermal degradation thereof, it becomes unnecessary to employ a heat-resistant container or to thermally sterilize or cool after sealing, and thus both of the equipment cost and the running cost can be largely reduced. After thermally sterilizing the content to give a definite sterilization value, it is quickly cooled to room temperature and then stored in a storage tank that has been preliminarily sterilized under such conditions as being equal to or exceeding the thermal sterilization conditions for the contents. While maintaining the storage tank under positive pressure with the use of a sterile gas, the content is fed into a filling machine that has been preliminarily sterilized under such conditions as being equal to or exceeding the thermal sterilization conditions for the contents. Thus, the liquid-feeding system ranging from the storage tank to the filling machine is made a closed liquid-feeding pathway free from the invasion of air from the outside. The drink is filled into a container having been sterilized with hot water in an environment-controlled space isolated from the outside wherein the surroundings have been thermally sterilized and washed with hot water at 65oC to 100oC.

Description

明 細 書  Specification
容器詰め飲料の製造方法  Method for producing containerized beverage
技術分野  Technical field
[0001] 本発明は、容器詰め飲料、特に容器詰め茶飲料および容器詰め酸性飲料等の容 器詰飲料の製造方法に関する。  [0001] The present invention relates to a method for producing container-packed beverages, particularly container-packed beverages such as container-packed tea beverages and container-packed acidic beverages.
背景技術  Background art
[0002] 従来、例えば PETボトル詰めの茶飲料等の低酸性飲料や、果汁入り飲料等の酸性 飲料の容器詰め飲料の製造法としてホットパック法とァセブティック充填法が知られ ている。ホットパック法は、例えば茶飲料等 pHが 4.6以上の低酸性飲料の場合は 12 0°C、 4分と同等以上に、 pHが 4.6以下の酸性飲料の場合は 85°C、 30分と同等以上 にそれぞれ加熱殺菌し、洗浄された容器に内容物を液温が 65°C〜90°Cを維持した 状態で充填することによって、内容物の熱で容器の殺菌を行い密封する。その後、 容器のヘッドスペース部やキャップ内面の殺菌を行うために、密封直後に容器を反 転させてキャップ内面等に接液させて殺菌を行う、いわゆる転倒殺菌を行うと共にパ ストライザ一で温水を容器外周面に噴射して 75°Cで 3分間の加熱殺菌を行った後、 常温まで冷却をしている(一例として、特許文献 1参照)。  Conventionally, for example, a hot pack method and an ace boutique filling method are known as methods for producing low-acid beverages such as PET bottle-packed tea beverages and acidic beverages such as fruit juice-containing beverages. The hot pack method is, for example, tea beverages, etc., for low acid beverages with a pH of 4.6 or higher, equivalent to 120 ° C, 4 minutes or more, and for acidic beverages with a pH of 4.6 or lower, 85 ° C, equivalent to 30 minutes By sterilizing by heating and filling each of the cleaned containers with the liquid temperature maintained at 65 ° C to 90 ° C, the containers are sterilized with the heat of the contents and sealed. After that, in order to sterilize the head space part of the container and the inner surface of the cap, the container is inverted immediately after sealing and sterilized by contacting the inner surface of the cap and so on. After spraying on the outer peripheral surface of the container and sterilizing by heating at 75 ° C for 3 minutes, it is cooled to room temperature (see Patent Document 1 as an example).
[0003] ホットパック法は、内容物を長時間 60°C以上の高温状態を維持し、その状態で充 填する関係から内容物が熱劣化により風味や香味の劣化が早いという大きな問題点 力 Sある。一方、容器の面では充填時に高温の飲料と接触状態下におかれるので耐 熱容器でなければならず、例えば PETボトルの場合耐熱処理が必要であり、且つ冷 却後は容器内が負圧になるので負圧に耐え得る強度を確保するために肉厚にしな ければならず、容器コストが割高になるという欠点がある。さらに、設備の面では、後 殺菌及び冷却のための長大なパストライザ一を必要とし設置スペースと設備コストが 増大するという欠点がある。さらにまた、ランニングコストの面からは、パストライザ一で の多量の温水を必要とし、水量とエネルギーコストが嵩むという欠点がある。  [0003] The hot pack method has a major problem that the contents are maintained at a high temperature of 60 ° C or higher for a long time and the contents are filled in that state, so that the contents are quickly deteriorated in flavor and flavor due to thermal deterioration. There is S. On the other hand, the container surface must be in a heat-resistant container because it is in contact with a hot beverage at the time of filling. Therefore, in order to secure the strength that can withstand negative pressure, the thickness must be increased, and the container cost is high. Furthermore, in terms of equipment, there is a disadvantage that a long pastorizer for post sterilization and cooling is required, which increases installation space and equipment costs. Furthermore, from the viewpoint of running cost, there is a drawback that a large amount of hot water is required in the pastoriser, and the amount of water and energy cost increase.
[0004] 一方、ァセブティック充填法は、予め熱交換等の手段により高温短時間殺菌した後 常温まで冷却した飲料を、過酸化水素や過酢酸等の薬剤で殺菌し且つ無菌水で洗 浄した耐熱性を必要としない容器に無菌環境を維持した中で常温で充填'密封する ものである。この方法は、完全無菌状態での密封を保証するものであるので、常温充 填でありながら酸性飲料、茶をはじめ、ボツリヌス菌等の芽胞菌が繁殖しやすいミルク 入り飲料の充填にも適用可能であり、内容物の熱劣化も少ないという利点を有してい るが、容器殺菌のための薬剤処理装置および殺菌用薬剤が必要であり、また容器洗 浄のための洗浄装置および大量の無菌水が必要である等、これらの工程を実現する ための装置やクリーンノレームおよびその制御が大がかりとなり、多大な設備コストとラ ンユングコストを有するという問題点がある。 [0004] On the other hand, in the case of boutique filling method, beverages that have been sterilized at high temperature and short time by means such as heat exchange in advance and then cooled to room temperature are sterilized with chemicals such as hydrogen peroxide and peracetic acid and washed with sterile water. Filled and sealed at room temperature in a sterile environment in a clean container that does not require heat resistance. This method guarantees hermetic sealing in a completely aseptic condition, so it can be applied to filling beverages containing milk that are easy to grow acidic drinks, tea, and spore bacteria such as Clostridium botulinum, while filling at room temperature. It has the advantage of less heat deterioration of the contents, but requires a chemical treatment device and a sterilizing chemical for container sterilization, and also a cleaning device and a large amount of sterile water for container cleaning. Therefore, there is a problem that the equipment, clean noreme and control thereof for realizing these processes become large, and there is a great equipment cost and running cost.
そこで、本発明者らは、上記従来のホットパック法及びァセブティック充填法の問題 点を解決する方法として、 PH4.6以上でカテキン含有量が 30mg%以上の茶飲料ま たは PH4.6未満の酸性飲料を加熱殺菌した後 60°C〜70°Cの温度に維持する一方 、容器の少なくとも内面を 65°C〜: 100°Cの熱水で加熱殺菌 ·洗浄し、予め充填'密封 装置およびその周辺環境を 65°C〜 100°Cの熱水で加熱殺菌し洗浄した外界と隔離 した環境管理空間の中で該飲料を充填温度 60°C〜 70°Cで該殺菌済み容器に充填 し、密封後 40°C以下の常温まで冷却するという、新たなホットパック法を提案した(特 許文献 2参照)。  Therefore, as a method for solving the problems of the conventional hot pack method and the ase boutique filling method, the present inventors have made a tea beverage with a catechin content of PH 4.6 or more and a catechin content of 30 mg% or more or less than PH 4.6. After heat sterilization of the acidic beverage, maintain at a temperature of 60 ° C-70 ° C, while at least the inner surface of the container 65 ° C ~: heat sterilization with hot water of 100 ° C The beverage is filled into the sterilized container at a filling temperature of 60 ° C to 70 ° C in an environmental management space separated from the outside where the surrounding environment is sterilized by heating with hot water of 65 ° C to 100 ° C. We proposed a new hot-packing method that cools to room temperature below 40 ° C after sealing (see Patent Document 2).
この方法は、充填'密封後の後殺菌工程が不要であるので、長大な設備であるパス トライザ一が不要であり、従来のホットパック法と比べて設備コスト'ランニングコストを 削減できると共に、容器の減圧変形耐性に関する条件を緩和できるという利点を有 するものであるが、密封後の冷却工程を必要とすると共に、従来のホットパック法と比 ベて緩和はされている力 内容物の熱劣化による風味や香味の低下、且つ容器の減 圧変形耐性の要求は避けられなレ、とレ、う問題点がある。  Since this method does not require a post-sterilization step after filling and sealing, it eliminates the need for a pasteurizer, which is a long facility, and can reduce equipment costs and running costs compared to the conventional hot pack method. Although it has the advantage that the conditions related to the resistance to deformation under reduced pressure can be relaxed, it requires a cooling process after sealing, and it is less relaxed than the conventional hot pack method. Degradation of flavor and flavor due to aging, and the need for reduced pressure deformation resistance of the container are inevitable.
特許文献 1 :特開 2001— 278225号公報 「ボトル詰飲料の製造方法」 2001年 10 月 10日公開 Patent Document 1: Japanese Patent Laid-Open No. 2001-278225 “Manufacturing Method for Bottled Beverage” published on October 10, 2001
特許文献 2 :特開 2006— 69624号公報 「容器詰め飲料の製造方法」 2006年 3月 16日公開 Patent Document 2: Japanese Patent Application Laid-Open No. 2006-69624 “Method for Producing Container-Packed Beverage” Published on March 16, 2006
発明の開示 Disclosure of the invention
発明が解決しょうとする課題 [0006] 従来のホットパック法の上記欠点を解決するには、充填温度をより下げるのは有効 な手段であるが、内容物を殺菌後常温まで冷却すると一般の充填設備で使用されて レ、る貯留タンクから充填機までの送液系統の継ぎ手ゃパッキン部、送液ポンプなどの 微細部分力 微生物汚染の可能性が否定できず、製品安全性の観点から充填温度 を前記提案以上に落とすことはできなかった。 Problems to be solved by the invention [0006] In order to solve the above disadvantages of the conventional hot pack method, it is an effective means to lower the filling temperature. However, if the contents are cooled to room temperature after sterilization, they are used in general filling equipment. Micropartial force such as packing part, liquid pump, etc. of the liquid feed system from the storage tank to the filling machine The possibility of microbial contamination cannot be denied, and the filling temperature should be lowered more than the above proposal from the viewpoint of product safety I couldn't.
そこで、本発明は、上記提案した充填システムをさらに改善して、常温充填を可能 にして内容物の熱劣化を緩和して風味や香味を良好に維持することができ、耐熱容 器を用いる必要がなぐし力 密封後の加熱殺菌や冷却を必要とせず、且つァセプ ティック充填法のような薬剤や無菌水の使用を不要として、大幅な設備コストとラン二 ングコストの低下を図ることができる新規な充填密封システムからなる容器詰め飲料 の製造方法を提供することを目的とするものである。  Therefore, the present invention further improves the above-described filling system, enables normal temperature filling, reduces thermal deterioration of the contents, and maintains a good flavor and flavor, and requires the use of a heat-resistant container. Newly capable of drastically reducing equipment costs and running costs without requiring heat sterilization or cooling after sealing, and eliminating the need for chemicals and sterile water as in the aseptic filling method. It is an object of the present invention to provide a method for producing a container-packed beverage comprising a filling and sealing system.
[0007] また、本発明は常温充填を可能にして内容物の熱劣化を緩和して風味や香味を良 好に維持することができ、耐熱容器を用いる必要がなぐしかも密封後の加熱殺菌や 冷却を必要とせず、且つァセブティック充填法のような薬剤や無菌水の大量使用を 不要として、大幅な設備コストとランニングコストの低下を図ることができる新規な充填 密封システムからなる容器詰め飲料の製造方法を提供することを目的とするものであ る。 [0007] In addition, the present invention enables filling at room temperature to mitigate the thermal deterioration of the contents and maintain a good flavor and flavor, and it is not necessary to use a heat-resistant container. Manufacture of packaged beverages consisting of a new filling and sealing system that does not require cooling and eliminates the need to use large amounts of chemicals and sterile water, such as the Ace Boutique filling method, and can greatly reduce equipment costs and running costs It is intended to provide a method.
課題を解決するための手段  Means for solving the problem
[0008] 上記目的を達成するため、本発明者らは、鋭意研究と実験を重ねた結果、内容物 である飲料を PH4.6以上でカテキン含有量が 30mg%以上の緑茶、ウーロン茶等の 茶飲料、および PH4.6未満の酸性飲料等加熱後の芽胞菌の生育が困難な飲料に 限定すれば、内容物の加熱殺菌から充填までの内容液の送液経路を殺菌された完 全な閉鎖空間内で行い、且つ容器と充填密封環境を熱水により殺菌された外界と隔 離されたクリーン環境に保てば、薬剤による容器の殺菌を必要とせず、内容物を急速 加熱殺菌後急速冷却して常温充填が可能であることを知見し、本発明に到達したも のである。 [0008] In order to achieve the above-mentioned object, the present inventors have conducted extensive research and experiments, and as a result, the content of the beverage is PH 4.6 or more and the catechin content is 30 mg% or more, such as green tea and oolong tea. If it is limited to beverages and beverages that are difficult to grow spores after heating, such as acidic beverages with a pH of less than 4.6, the liquid supply route from the heat sterilization of the contents to the filling is completely sterilized. If it is performed in a space and the container and the filling and sealing environment are kept in a clean environment separated from the external environment sterilized by hot water, the container is not sterilized by chemicals, and the contents are rapidly cooled after heat sterilization. Thus, the inventors have found that normal temperature filling is possible, and have reached the present invention.
[0009] すなわち、上記目的を達成する本発明の容器詰め飲料の製造方法は、容器及び キャップ殺菌洗浄 ·充填 ·密封をする周辺環境を予め 65°C〜100°Cの熱水または薬 剤を用いて加熱殺菌'洗浄する工程、冷却機、貯留タンク及び充填機までの送液経 路を充填する飲料の加熱殺菌条件と同等以上の条件で予め加熱殺菌'洗浄するェ 程、容器及びキャップの少なくとも内面を 65°C〜100°Cの温水で加熱殺菌 ·洗浄す る工程を有し、充填する飲料を所定の殺菌値まで加熱殺菌を行った後、常温まで急 速冷却し、該冷却された飲料を前記貯留タン外こ貯蔵し、前記充填機に内容液を送 ることによって前記送液経路を外部から空気の侵入のない閉鎖経路にし、且つ前記 周辺環境を外界と隔離した環境管理空間として、該管理空間の中で前記飲料を前 記殺菌済み容器に常温充填して密封することを特徴とするものである。 [0009] That is, in the method for producing a container-packed beverage of the present invention that achieves the above object, the surrounding environment for container and cap sterilization cleaning, filling, and sealing is preliminarily heated water or medicine at 65 ° C to 100 ° C Heat sterilization using a chemical agent, washing process, cooling, storage tank and process for pre-heating sterilization under conditions equivalent to or better than the heat sterilization conditions for beverages filling the liquid supply path to the filling machine, containers and At least the inner surface of the cap has a process of heat sterilization and washing with hot water of 65 ° C to 100 ° C. After the beverage to be filled is heat sterilized to a predetermined sterilization value, it is rapidly cooled to room temperature, An environment in which the cooled beverage is stored outside the storage tank, and the content liquid is sent to the filling machine to make the liquid supply path a closed path where no air enters from the outside, and the surrounding environment is isolated from the outside. As the management space, the beverage is filled in the sterilized container at room temperature and sealed in the management space.
[0010] 本願の他の発明は、上記の容器詰め飲料の製造方法において、前記飲料が pH4. [0010] Another invention of the present application is the method for producing a container-packed beverage, wherein the beverage has a pH of 4.
6以上でカテキン含有量が 30mg%以上の飲料であり、該飲料を 135°C、 7.58秒の 加熱殺菌と同等以上の殺菌値で加熱殺菌することを特徴とするものである。  A beverage having a catechin content of 6 mg or higher and a catechin content of 30 mg% or higher is characterized by being heat-sterilized at a sterilization value equal to or higher than that of 135 ° C and 7.58 seconds.
また、本願の他の発明は、上記の容器詰め飲料の製造方法において、前記飲料が PH4.6未満の酸性飲料であり、該酸性飲料を 85°C、 30分の加熱殺菌と同等以上の 殺菌値で加熱殺菌することを特徴とするものである。  Further, another invention of the present application is the above-described method for producing a container-packed beverage, wherein the beverage is an acidic beverage having a pH of less than 4.6, and the acidic beverage is sterilized at 85 ° C for 30 minutes or more. It is characterized by heat sterilization with a value.
さらに、本願の他の発明は、上記のいずれかに記載の容器詰め飲料の製造方法に おいて、前記環境管理空間がボックス内に収容された空間であることを特徴とするも のである。  Furthermore, another invention of the present application is characterized in that, in the method for producing a container-packed beverage according to any one of the above, the environmental management space is a space accommodated in a box.
また、本願の他の発明は、前記貯留タンクは無菌ガスで陽圧保持し、該貯留タンク 力 充填機への液送は、無菌ガスによる圧送であることを特徴とするものである。  Further, another invention of the present application is characterized in that the storage tank is maintained at a positive pressure with a sterile gas, and the liquid feeding to the storage tank force filling machine is a pressure feeding with a sterile gas.
[0011] また、本発明は、上記の容器詰め飲料の製造方法において、周辺環境の薬剤を用 いた殺菌後の洗浄には 65°C〜100°Cの温水を用いて殺菌機能も兼ねさせることを 特徴とするものである。 [0011] Further, according to the present invention, in the above-described method for producing a packaged beverage, washing after sterilization using a chemical in the surrounding environment is also performed with a sterilization function using hot water of 65 ° C to 100 ° C. It is characterized by.
また、本願の更なる発明は、上記の容器詰め飲料の製造方法において、容器及び キャップ殺菌洗浄 ·充填 '密封する周辺環境を予め殺菌 ·洗浄する薬剤として、過酢 酸系薬剤、過酸化水素、オゾン系薬剤、次亜塩素酸を含有する塩素系殺菌剤のい ずれかを用いるようにした。  Further, the invention of the present application further includes a peracetic acid-based agent, hydrogen peroxide, an agent for pre-sterilizing and cleaning the surrounding environment to be sterilized and filled and sealed in the container and the cap in the above-described method for producing a container-packed beverage. Either ozone-based chemicals or chlorine-based disinfectants containing hypochlorous acid were used.
発明の効果  The invention's effect
[0012] 本発明の容器詰め飲料の製造方法によれば、果汁飲料等の酸性飲料、又は茶'ミ ルク入り飲料等を容器や設備及び環境をァセブティック充填法のような薬液による殺 菌ゃ無菌水による洗浄等を必要とせずに常温充填を可能にすることができ、ホットパ ック法のような内容物の熱劣化による香味低下が少なぐァセブティック充填法のよう な良好な容器詰め飲料を得ることができる。しかも、ァセブティック充填法と比べて簡 易な設備ででき、且つ薬液を使用しないことで大幅な設備コストとランニングコストの 低減を図ることができると共に、製造ラインの効率化と高速化を図ることができる。また 、容器の耐熱性や減圧変形耐性も要求されないので、容器の薄肉化を図ることがで き、容器コストも低減すること力 Sできる。さらに、密封後の後殺菌や冷却を必要としな いので、ホットパック法に比べて設備を簡素化し、且つ多量の温水を必要とせず、設 備コストやランニングコストを低下させることができると共に、ラインの高速化を図ること ができる。そして、充填密封後直接製品を検査工程、箱詰め工程等に送ることができ 、ラインの効率化、省スペース化を図ることができる。 [0012] According to the method for producing a container-packed beverage of the present invention, an acidic beverage such as a fruit juice beverage or a tea Liquefied beverages can be filled at room temperature without the need to sterilize containers, equipment and the environment with chemicals such as the Asse boutique filling method, or with sterile water. As a result, it is possible to obtain a good container-packed beverage such as the ASE boutique filling method in which the flavor deterioration due to heat deterioration of the product is small. In addition, it can be done with simpler equipment compared to the ASSET boutique filling method, and not using chemicals can greatly reduce equipment costs and running costs, and increase the efficiency and speed of the production line. it can. Further, since the container is not required to have heat resistance or resistance to deformation under reduced pressure, the container can be thinned and the cost of the container can be reduced. In addition, since post-sterilization and cooling after sealing are not required, the equipment can be simplified compared to the hot pack method, a large amount of hot water is not required, and the equipment cost and running cost can be reduced. The line speed can be increased. And after filling and sealing, the product can be sent directly to the inspection process, the boxing process, etc., and the efficiency of the line and the space saving can be achieved.
[0013] 周辺環境を薬剤を用レ、て加熱殺菌 ·洗浄する本発明の容器詰め飲料の製造方法 によれば、果汁飲料等の酸性飲料、又は茶'ミルク入り飲料等において、薬剤の使用 を充填に先立って行う容器洗浄 ·充填 ·密封をする周辺環境の殺菌 ·洗浄工程に限 定したので、ァセブティック充填法のような大量の薬液や無菌水等を必要とせずに常 温充填を可能にすることができ、ホットパック法のような内容物の熱劣化による香味低 下が少なぐァセブティック充填法のような良好な容器詰め飲料を得ることができる。 しかも、ァセブティック充填法と比べて薬剤や洗浄液の使用が少なくて済む分、小規 模な設備ででき、さらに、密封後の後殺菌や冷却を必要としないので、ホットパック法 に比べて設備を簡素化し、大幅な設備コストとランニングコストの低減を図ることがで きる。  [0013] According to the method for producing a container-packed beverage of the present invention in which the surrounding environment is heated and sterilized and washed using a drug, the drug is used in an acidic beverage such as a fruit juice beverage or a tea'milk beverage. Container cleaning prior to filling ・ Filling ・ Sealing surrounding environment to be sterilized ・ Limited to cleaning process, so it is possible to fill at normal temperature without the need for large amounts of chemicals and sterile water as in the case of boutique filling method As a result, it is possible to obtain a good container-packed beverage such as the ASE boutique filling method in which the flavor lowering due to the heat deterioration of the contents such as the hot pack method is small. In addition, since the use of chemicals and cleaning liquids is less than that of the ASSET boutique filling method, it can be done with small-scale equipment.Furthermore, it does not require post-sterilization or cooling after sealing. This simplifies and can greatly reduce the equipment cost and running cost.
[0014] 本発明の容器詰め飲料の製造方法によれば、上記効果に加え、飲料力 ¾H4.6以 上でカテキン含有量が 30mg%以上の飲料の場合、該飲料を 135°C、 7.58秒の加 熱殺菌と同等以上の殺菌値で加熱殺菌するが、殺菌後常温まで急速冷却するので 、熱劣化を緩和することができ、香味を維持することができる。そして、 PH4.6以上で カテキン含有量が 30mg%以上の茶飲料は、充填密封後における環境が芽胞菌が 生存できない環境であるので、容器を飲料充填前に温水で殺菌 ·洗浄することで充 填後のパストライザ一での殺菌を必要としない。 [0014] According to the method for producing a container-packed beverage of the present invention, in addition to the above effects, in the case of a beverage having a beverage strength of ¾H4.6 or more and a catechin content of 30 mg% or more, the beverage is treated at 135 ° C for 7.58 seconds. Although heat sterilization is performed at a sterilization value equivalent to or higher than that of heat sterilization, rapid cooling to room temperature after sterilization can alleviate thermal degradation and maintain flavor. For tea drinks with a pH of 4.6 or more and a catechin content of 30 mg % or more, the environment after filling and sealing is an environment where spore bacteria cannot survive, so the container is filled by sterilizing and washing the container with warm water before filling the drink. There is no need to sterilize with a pasterizer after filling.
[0015] 本発明の容器詰め飲料の製造方法によれば、上記の発明の効果に加え、前記飲 料が PH4.6未満の酸性飲料の場合、該酸性飲料を 85°C、 30分と同等以上の殺菌 値で加熱殺菌することで、密封後の菌の生育を防止することができ、且つ加熱殺菌 後急速に冷却するので、風味や成分の劣化を防止することができ、しかも容器を飲 料充填前に温水で殺菌'洗浄することで充填後のパストライザ一での殺菌を必要とし ない。  [0015] According to the method for producing a packaged beverage of the present invention, in addition to the effects of the above-described invention, when the beverage is an acidic beverage having a pH of less than 4.6, the acidic beverage is equivalent to 85 ° C for 30 minutes. By heat sterilization with the above sterilization values, the growth of bacteria after sealing can be prevented, and since it cools rapidly after heat sterilization, flavor and components can be prevented from being deteriorated, and the container can be drunk. Disinfection with hot water before filling the material does not require sterilization with a pasteurizer after filling.
本発明の容器詰め飲料の製造方法によれば、容器の熱水殺菌、内容物の充填、 容器の密封を行なう環境管理空間をボックス内に収容された空間とすることにより、 該空間を外部と隔離し、外部環境力 の汚染を防止することができる。  According to the method for producing a container-packed beverage of the present invention, an environment management space for performing hot-water sterilization of a container, filling of contents, and sealing of the container is a space accommodated in the box, so that the space is outside. Isolation can prevent contamination of external environmental forces.
さらに、本発明の容器詰め飲料の製造方法によれば、以上の効果に加え、前記貯 留タンクから充填機へ無菌ガスによって圧送することで、微細部分の殺菌が困難なポ ンプを使用せずに液送することができ、液送機構の無菌化を容易に図ることができる とともに、経路内の陽圧化による外気の進入を防止でき、飲料が外気によって汚染さ れるおそれがない。  Furthermore, according to the method for producing a container-packed beverage of the present invention, in addition to the above-described effects, a pump that is difficult to sterilize a fine part is not used by pumping from the storage tank to the filling machine with aseptic gas. In addition to being able to easily sterilize the liquid feeding mechanism, it is possible to prevent the entry of outside air due to positive pressure in the passage, and there is no possibility that the beverage is contaminated by outside air.
[0016] 本発明の異なる容器詰め飲料の製造方法によれば、上記効果に加え、薬剤を用い た殺菌後の周辺環境の洗浄には 65°C〜100°Cの温水を用いたときは温水が殺菌機 能も果たすことにより、例えばァセブティック充填の場合より、薬剤温度を低くして用 レ、ることが可能となる。この結果、薬剤の分解を抑えることができ再利用の回数を増 やすと共に機器へのダメージを低くすることができる。さらに耐熱性のある芽胞菌に 対しても滅菌効果が上げられる。  [0016] According to the method for producing a container-packed beverage according to the present invention, in addition to the above-described effects, hot water of 65 ° C to 100 ° C is used for cleaning the surrounding environment after sterilization using a medicine. Since it also has a sterilizing function, for example, it can be used at a lower drug temperature than in the case of filling with a boutique. As a result, the decomposition of the drug can be suppressed, the number of reuse can be increased, and the damage to the device can be reduced. Furthermore, the sterilization effect can be improved against heat-resistant spore bacteria.
さらに、本発明の発明は、指定される薬剤によって、容器及びキャップ殺菌洗浄 '充 填'密封をする周辺環境を予め殺菌'洗浄するので、より確実な滅菌効果が上げられ る。  Furthermore, the invention of the present invention sterilizes and cleans the surrounding environment in which the container and cap sterilization cleaning “filling” and sealing are performed in advance with a specified medicine, so that a more reliable sterilization effect can be achieved.
図面の簡単な説明  Brief Description of Drawings
[0017] [図 1]本発明の実施形態に係る容器詰飲料の製造方法を実施するための製造システ ムの模式図である。  FIG. 1 is a schematic diagram of a production system for carrying out a method for producing a packaged beverage according to an embodiment of the present invention.
[図 2]本発明に係る容器詰飲料の製造方法の 1実施形態を示すフローチャートであ る。 FIG. 2 is a flowchart showing one embodiment of a method for producing a packaged beverage according to the present invention. The
園 3]環境管理空間となるクリーンボックス内の薬剤を用いた本発明の殺菌 ·洗浄方 法について説明する図である。  3] It is a diagram for explaining a sterilization / cleaning method of the present invention using a chemical in a clean box serving as an environmental management space.
園 4]本発明に係る容器詰飲料の製造方法の他の実施形態を示すフローチャートで ある。  4] A flow chart showing another embodiment of the method for producing a packaged beverage according to the present invention.
符号の説明  Explanation of symbols
1 薬剤タンク 2 温水タンク  1 chemical tank 2 hot water tank
3 排水タンク 4, 5 切替弁  3 Drain tank 4, 5 selector valve
10 ボトル殺菌 ·洗浄装置 11 充填機  10 Bottle sterilization and cleaning equipment 11 Filling machine
12 キヤッパー 14 環境管理空間  12 Capper 14 Environmental management space
15 クリーンボックス 16 回転式の熱水噴射ノズル  15 Clean box 16 Rotating hot water spray nozzle
17 固定式の熱水噴射ノズノレ 20 調合タンク  17 Fixed hot-water injection nozzle 20 Mixing tank
21 ノくランスタンク 22 高温短時間殺菌機  21 Knock lance tank 22 High temperature short time sterilizer
23 急速冷却機 25 貯留タンク  23 Rapid cooler 25 Storage tank
26 ヘッドタンク  26 Head tank
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0019] 以下添付図面を参照して、本発明の実施の形態について説明する。  Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings.
本発明が適用される飲料は、 PH4.6以上でカテキン含有量が 30mg%以上の緑茶 、ウーロン茶等の飲料、 pH4.6未満の酸性飲料である。前記酸性飲料には、天然果 汁、果汁飲料、果肉飲料、果汁入り清涼飲料、果粒入り果実飲料、レモンティー、ス ポーッドリンク等が含まれる。  Beverages to which the present invention is applied are beverages such as green tea and oolong tea having a pH of 4.6 or more and a catechin content of 30 mg% or more, and acidic beverages having a pH of less than 4.6. Examples of the acidic beverage include natural fruit juice, fruit juice drink, pulp drink, soft drink with fruit juice, fruit drink with fruit granules, lemon tea, and a sprinkling link.
また、本発明の方法に使用する容器は、 PETボトル等のポリエステルボトルの他ポ リエステル製カップ、トレー等のポリエステル容器を含むプラスチック容器、ガラス瓶、 金属ボトル、食缶等である。本発明は特に PETボトルの減圧耐性に関する条件を緩 和し、その薄肉化が図れる点で PETボトル詰めの上記飲料の製造に好適である。  Containers used in the method of the present invention include polyester bottles such as PET bottles, plastic cups including polyester cups such as trays, polyester containers such as trays, glass bottles, metal bottles, food cans, and the like. The present invention is particularly suitable for the production of PET bottled beverages in that the conditions relating to reduced pressure resistance of PET bottles can be relaxed and the thickness can be reduced.
[0020] 本発明の実施形態における容器詰め飲料の製造方法においては、内容物となる 飲料を所定の殺菌値まで、高温短時間殺菌法による加熱殺菌し、その後すぐに常温 (15°C〜40°C)まで急速冷却した後、予め前記飲料の加熱殺菌条件と同等以上の 条件で殺菌、洗浄してある貯留タンクに貯留する。本発明においては、前記貯留タン クをはじめ全ての設備の少なくとも接液面となる部分は、蒸気又は熱水で予め内容 物となる飲料の殺菌値と同等以上の殺菌値で加熱殺菌してあり、また、容器の少なく とも内面、及び容器殺菌洗浄 ·充填 ·密封を行う空間環境、設備外面を 65°C〜: 100 °Cの熱水で加熱殺菌 ·洗浄してあり、該空間環境を外界と隔離した管理空間としてい る。そして、前記冷却された飲料を前記貯留タンクに貯蔵し、該貯留タンクを無菌ガ スで陽圧保持しながら前記充填機に内容液を送ることによって前記送液経路を外部 から空気の侵入のない閉鎖液経路にし、且つ外界と隔離した殺菌済みの環境管理 空間の中で前記飲料を前記殺菌済み容器に常温充填し、容器を密封する。密封後 は、冷却や加熱を必要とすることなぐその状態で直接検查 '箱詰め工程に移行させ ること力 Sできる。 [0020] In the method for producing a container-packed beverage according to an embodiment of the present invention, the beverage as a content is heat-sterilized by a high-temperature and short-time sterilization method to a predetermined sterilization value, and immediately thereafter at room temperature (15 ° C to 40 ° C). ° C) after rapid cooling to a temperature equal to or higher than the heat sterilization conditions of the beverage. Store in a storage tank that has been sterilized and washed under conditions. In the present invention, at least a portion that becomes a wetted surface of all the equipment including the storage tank is preliminarily heat sterilized with steam or hot water at a sterilization value equal to or higher than the sterilization value of the beverage that is the content. In addition, at least the inner surface of the container and the sterilization cleaning, filling, and sealing of the container, and the outer surface of the facility are sterilized by heating with hot water at 65 ° C to 100 ° C. This is an isolated management space. Then, the cooled beverage is stored in the storage tank, and the liquid supply path is sent to the filling machine while keeping the storage tank at a positive pressure with a sterilized gas, so that there is no air intrusion from the outside. The sterilized container is filled into the sterilized container at room temperature in a sterilized environmental management space that is closed and separated from the outside, and the container is sealed. After sealing, it can be transferred directly to the inspection and packing process without requiring cooling or heating.
内容物となる飲料が、 pH4.6以上でカテキン含有量が 30mg%以上の茶飲料であ る場合、該茶飲料を 135°C、 7.58秒と同等以上の殺菌値を得るように、高温短時間 殺菌法等により加熱殺菌する。本発明者がカテキン含有量が 15mg%〜50mg%の 飲料について種々の微生物に対するカテキンによる制菌作用を調べた。その結果を 表 1に示す。表中〇は制菌作用が確認されたもの、△は菌種によって制菌作用のあ るものと制菌作用のないものが確認されたもの、 Xは制菌作用が確認されなかったも のである。  If the beverage is a tea beverage with a pH of 4.6 or higher and a catechin content of 30 mg% or higher, the high temperature and short temperature of the tea beverage should be as high as 135 ° C and 7.58 seconds. Time Sterilize by heat sterilization method. The present inventor investigated the bactericidal action of catechins against various microorganisms on beverages having a catechin content of 15 mg% to 50 mg%. The results are shown in Table 1. In the table, ○ indicates that antibacterial activity has been confirmed, △ indicates that antibacterial activity has been confirmed and no antibacterial activity has been confirmed, and X indicates that antibacterial activity has not been confirmed. is there.
[表 1] [table 1]
Figure imgf000010_0001
表 1に示すように、カテキン含有量が 27mg%の茶飲料の場合、殆どの芽胞菌に対 して制菌作用が確認されたが、一部の芽胞菌に対しては制菌効果が少なレ、ものがあ つた。そのような結果から、本発明では茶飲料については安全性をみて 30mg%以 上の力テンキン含有量の茶飲料を対象にした。なお、無芽胞菌の一部、及びカビゃ 酵母に対しては、カテキンの制菌作用はなぐこれらの菌は低温加熱で滅菌すること ができる。以上のように、カテキン含有量が 30mg%以上の茶飲料の場合は、芽胞菌 に対して制菌効果を示すので、茶飲料であっても変敗する恐れがない。また、前記 飲料力 ¾H4.6未満の酸性飲料である場合、該飲料を 85°C、 30分間加熱と同等以上 の殺菌効果で高温短時間の加熱殺菌を行う。
Figure imgf000010_0001
As shown in Table 1, antibacterial activity was confirmed against most spore bacteria in the case of tea beverages with a catechin content of 27 mg%, but the antibacterial effect was small against some spore bacteria. I have something. From such results, in the present invention, for tea drinks, 30 mg% or less is considered for safety. The tea drink with the upper force tenkin content was targeted. It should be noted that, for some of the non-spore-forming bacteria and mold yeast, these bacteria, which do not have the antibacterial action of catechin, can be sterilized by low-temperature heating. As described above, in the case of a tea beverage having a catechin content of 30 mg% or more, since it shows an antibacterial effect against spore bacteria, there is no risk of deterioration even if it is a tea beverage. In the case of an acidic beverage having a beverage strength of less than ¾H4.6, the beverage is sterilized by heating at a high temperature for a short time with a sterilization effect equivalent to or better than heating at 85 ° C for 30 minutes.
[0022] 以下代表的な例として PETボトルにこれらの飲料を充填する場合について、図 1に 示す製造ラインの模式図及び図 2に示すフローチャートを参照しながら説明する。 図 1に示す本実施形態の容器詰飲料の製造ラインにおいて、ボトル殺菌'洗浄装 置 10、充填機 11、キヤッパー 12及びキャップ殺菌 ·洗浄装置(図示してない)は、環 境管理空間 14を形成するクリーンボックス 15内に設置されている。なお、本明細書 において、「環境管理空間」とは、予め充填'密封装置およびその周辺環境を 65°C 〜100°Cの熱水で加熱殺菌し洗浄して外界と隔離した空間を意味し、内部には無菌 エアが供給され、外部に対して陽圧化され、外気が容易に流入しないようにしている 。周辺環境の殺菌'洗浄は、容器詰飲料の製造開始に先立って行うものであり、図 1 に示すように、クリーンボックス 15内に、回転式の熱水噴射ノズル 16及び容器殺菌 · 洗浄装置 10、充填機 11、キヤッパー 12の容器と接触する部分に向けて集中的に熱 水を噴射する固定の熱水噴射ノズル 17を適宜配置してある。周辺環境の殺菌'洗浄 方法は、例えば前記特許文献 2に示された方法が好適に採用できるので、詳細な説 明は省略する。 [0022] As a typical example, filling a PET bottle with these beverages will be described with reference to the schematic diagram of the production line shown in FIG. 1 and the flowchart shown in FIG. In the production line for packaged beverages of the present embodiment shown in FIG. 1, the bottle sterilization / cleaning device 10, the filling machine 11, the capper 12, and the cap sterilization / cleaning device (not shown) use the environment management space 14. It is installed in the clean box 15 to be formed. In this specification, “environmental management space” means a space where the filling and sealing device and its surrounding environment are preliminarily heat sterilized with hot water of 65 ° C to 100 ° C and washed away from the outside. The inside is supplied with aseptic air and is positively pressurized to the outside so that the outside air does not flow easily. The sterilization of the surrounding environment 'cleaning is performed prior to the start of the manufacture of packaged beverages. As shown in Fig. 1, a rotary hot water jet nozzle 16 and a container sterilization / washing device 10 are provided in a clean box 15. A fixed hot water injection nozzle 17 for injecting hot water intensively toward the portion of the filling machine 11 and the capper 12 that comes into contact with the container is appropriately arranged. As the method for disinfecting and cleaning the surrounding environment, for example, the method disclosed in Patent Document 2 can be suitably employed, and thus detailed description thereof is omitted.
[0023] 本実施形態において、環境管理空間外のボトル供給装置から環境管理空間 14内 のボトル殺菌 ·洗浄装置 10に移送されたボトルの殺菌は、少なくともボトルの内面、好 ましくは内外面を 65°C〜: 100°Cの熱水で加熱殺菌することにより行う。殺菌時間は 3 秒ないし 10秒である。この方法によれば、熱水によりボトルの殺菌と殺菌後の洗浄を 同時に行うので、殺菌後のボトルを別途洗浄する工程は不要である。また、同様に環 境管理空間外のキャップ供給装置から、管理空間内に設置されたキャップ殺菌-洗 浄装置にキャップを供給し、キャップの内外面に 65°C〜: 100°Cの熱水を噴射するこ とにより加熱殺菌する。 [0024] 熱水によるボトル内外面の殺菌は、たとえばボトル洗浄装置でボトルを倒立状態に 配置し、熱水スプレーノズルから熱水を噴射することにより行うことができる。同様に、 熱水によるキャップ内外面の殺菌は、例えば針金で形成されたシュートを移動するか 又はターレットにより開口部を下方に向けて移動するキャップの内外面に熱水スプレ 一ノズルから熱水を噴射することにより行うことができる。殺菌洗浄が終了したボトノレ は、充填機 11に供給され、充填機で飲料が充填される。また、キャップはキヤッパー 12にそれぞれ供給され、飲料が充填されたボトルにキヤッビングされてボトルを密封 する。 In this embodiment, the bottle sterilized from the bottle supply device outside the environment management space to the bottle sterilization / cleaning device 10 inside the environment management space 14 is at least the inner surface, preferably the inner and outer surfaces of the bottle. 65 ° C ~: Performed by heat sterilization with 100 ° C hot water. Sterilization time is 3 to 10 seconds. According to this method, since the bottle is sterilized with hot water and washed after sterilization at the same time, a step for separately washing the sterilized bottle is unnecessary. Similarly, a cap is supplied from a cap supply device outside the environmental management space to a cap sterilization / cleaning device installed in the management space, and hot water of 65 ° C to 100 ° C is applied to the inner and outer surfaces of the cap. Sterilize by heating. [0024] Sterilization of the inner and outer surfaces of the bottle with hot water can be performed, for example, by placing the bottle in an inverted state with a bottle cleaning device and injecting hot water from a hot water spray nozzle. Similarly, sterilization of the inner and outer surfaces of the cap with hot water is performed by, for example, moving hot water from a hot water spray nozzle on the inner and outer surfaces of the cap moving the chute formed of a wire or moving the opening downward with a turret. This can be done by spraying. The bottlenole that has been sterilized and washed is supplied to the filling machine 11, and the beverage is filled in the filling machine 11. The caps are respectively supplied to the caps 12, and are capped in bottles filled with beverages to seal the bottles.
[0025] 一方、内容液である飲料は、図 1に示すようにクリーンボックス外に設置されている 調合タンク 20で調合されて、バランスタンク 21に貯留され、そこから高温短時間殺菌 器 22及び急速冷却器 23に供給されて高温短時間殺菌及び急速冷却が行われる。 高温短時間殺菌は、 HTST殺菌法等により加熱殺菌するものであり、本実施形態で は、前述したように前記飲料力 H4.6以上でカテキン含有量が 30mg%以上の茶飲 料の場合は、 135°C、 7.58秒と同等以上の殺菌値を得るように、高温短時間殺菌を 行う。また、前記飲料力 ¾H4.6未満の酸性飲料である場合は、該飲料を 85°C、 30分 と同等以上の殺菌値が得られるように、例えば 93〜95°Cで短時間の加熱殺菌を行う  On the other hand, the beverage as the content liquid is prepared in the preparation tank 20 installed outside the clean box as shown in FIG. 1 and stored in the balance tank 21, from which the high temperature and short time sterilizer 22 and Supplied to the rapid cooler 23, high temperature short time sterilization and rapid cooling are performed. High temperature and short time sterilization is heat sterilization by HTST sterilization method, etc., and in this embodiment, as described above, in the case of a tea drink having a beverage power of H4.6 or more and a catechin content of 30 mg% or more. , Sterilize at a high temperature for a short time to obtain a sterilization value equivalent to or higher than 135 ° C and 7.58 seconds. In addition, in the case of an acidic beverage having a beverage strength of less than ¾H4.6, for example, the beverage is sterilized by heating at 93 to 95 ° C for a short time so that a sterilization value equal to or higher than 85 ° C and 30 minutes can be obtained. I do
[0026] 急速冷却は、高温短時間殺菌が行われた飲料を引き続き急速冷却器 23を通過さ せることにより、通過する間に冷媒と熱交換を行って常温まで短時間に冷却するもの であり、常温としては略 35°Cが適当である力 飲料の種類や季節等によって異なり、 15°C〜40°Cの範囲が採用できる。急速冷却された飲料は、ァセブティックタンク力 なる貯留タンク 25に貯留される。当該貯留タンク 25、前記急速冷却器 23および後述 するヘッドタンク 26、充填機 11及びこれを接続する配管等の全ての接液面は、予め 充填する飲料の殺菌条件と同等以上、すなわち 135°C、 7.58秒と同等以上の殺菌 条件を得るように蒸気又は熱水で殺菌洗浄されて無菌化した閉鎖経路を形成してい る。特に、貯留タンク 25は、無菌ガスで陽圧保持して外気の進入を阻止し、且つ貯留 された飲料を無菌ガスによる圧送で該貯留タンクからヘッドタンク 26を介して充填機 に飲料を送っている。それにより、構造的に完全な殺菌とシールが困難で無菌化が 難しいポンプに寄らずに液送することができ、飲料を常温でもより無菌状態に維持す ること力 Sできる。ヘッドタンク 26も完全密閉型に形成され、該ヘッドタンク 26に貯蔵さ れた飲料は無菌ガスの圧送により充填機に送られ、無菌化された環境管理空間でボ トルに充填される。 [0026] Rapid cooling is a method in which a beverage that has been sterilized at a high temperature for a short time is passed through a rapid cooler 23 to exchange heat with a refrigerant while it is passing and cools to room temperature in a short time. About 35 ° C is appropriate for room temperature. Depending on the beverage type and season, the range of 15 ° C to 40 ° C can be used. The rapidly cooled beverage is stored in a storage tank 25 which is a powerful boutique tank. All the wetted surfaces such as the storage tank 25, the quick cooler 23 and the head tank 26, the filling machine 11, and the pipes connecting the storage tank 25 are equal to or higher than the sterilization conditions of the beverage to be filled in advance, that is, 135 ° C. In order to obtain a sterilization condition equal to or better than 7.58 seconds, it is sterilized and washed with steam or hot water to form a sterilized closed path. In particular, the storage tank 25 holds positive pressure with aseptic gas to prevent outside air from entering, and the stored beverage is pumped from the storage tank to the filling machine via the head tank 26 by pumping with aseptic gas. Yes. This makes structural sterilization and sealing difficult and sterilization difficult The liquid can be pumped without going to a difficult pump, and the ability to keep the beverage more sterile at room temperature can be achieved. The head tank 26 is also formed in a completely sealed type, and the beverage stored in the head tank 26 is sent to the filling machine by sending sterile gas under pressure, and the bottle is filled in the sterilized environmental management space.
[0027] 飲料が充填されたボトルは充填機から環境管理空間内に設けられたキヤッパー 12 に移送され、環境管理空間外に配置されたキャップ供給装置から環境管理空間内に 配置されたキャップ殺菌 ·洗浄装置に供給されたキャップ殺菌 ·洗浄装置においてボ トルと同一条件で殺菌 ·洗浄されたキャップで完全に密封される。その後密封された ボトルは、従来のホットパック法のようなパストライザ一やクーラーを通す後殺菌工程 や冷却工程等の後処理を必要とすることなぐ直接製品検査工程、箱詰工程等に送 ること力 Sできる。  [0027] The bottle filled with the beverage is transferred from the filling machine to the capper 12 provided in the environmental management space, and the cap sterilizer arranged in the environmental management space from the cap supply device arranged outside the environmental management space. Cap sterilization supplied to the cleaning device. Completely sealed with a cap sterilized and cleaned under the same conditions as the bottle in the cleaning device. The sealed bottle is then sent directly to the product inspection process, packaging process, etc. without requiring post-treatment such as past sterilization and cooling processes through a pastrizer or cooler as in the conventional hot pack method. Power S can be.
[0028] 図 3は環境管理空間となるクリーンボックス内の薬剤を用いた本発明の殺菌 '洗浄 方法について説明する図、そして図 4は本発明に係る容器詰飲料の製造方法のフロ 一チャートである。本発明の他の実施形態における容器詰め飲料の製造方法は図 4 のフローチャートに沿ったステップで実行される。図中で黒三角の矢印はライン上の 流れを示し、ただの矢印は処理を示す。本発明の実施形態における容器詰め飲料 の製造方法においては、内容物となる飲料を所定の殺菌値まで、高温短時間殺菌 法による加熱殺菌し、その後すぐに常温(15°C〜40°C)まで急速冷却した後貯留タ ンクに貯留するライン 1および飲料をボトルへ充填 ·密封するライン 2の稼働前に、図 4において一点鎖線で囲んだ殺菌'洗浄処理を予め施しておく。この事前処理は急 速冷却器 23、該貯留タンク 25そしてヘッドタンク 26については前記飲料の加熱殺菌 条件と同等以上の条件で蒸気または熱水により殺菌、洗浄し、容器殺菌洗浄 '充填' 密封を行う空間環境は外界と隔離した管理空間としておき、この空間については飲 料充填に先立ち薬剤を用いて殺菌 ·洗浄を行うようにする。また、容器とキャップにつ いても少なくとも内面は 65°C〜: 100°Cの熱水で加熱殺菌 ·洗浄して使用する。そして 、前記冷却された飲料を前記貯留タンクに貯蔵し、該貯留タンクを無菌ガスで陽圧保 持しながら前記充填機に内容液を送ることによって前記送液経路を外部から空気の 侵入のない閉鎖液経路(図 4において破線で囲んだ領域)にし、且つ前記の外界と 隔離した殺菌済みの環境管理空間の中で前記飲料を前記殺菌済み容器に常温充 填し、容器を密封する。密封後は、冷却や加熱を必要とすることなぐその状態で直 接検査 ·箱詰め工程に移行させることができる。 [0028] Fig. 3 is a diagram for explaining a sterilization 'cleaning method of the present invention using chemicals in a clean box serving as an environmental management space, and Fig. 4 is a flowchart of a method for producing a packaged beverage according to the present invention. is there. The manufacturing method of the container-packed drink in other embodiment of this invention is performed by the step along the flowchart of FIG. In the figure, black triangle arrows indicate the flow on the line, and simple arrows indicate processing. In the method for producing a container-packed beverage according to an embodiment of the present invention, the beverage as a content is sterilized by heating by a high-temperature and short-time sterilization method to a predetermined sterilization value, and immediately thereafter at room temperature (15 ° C to 40 ° C). Before the operation of the line 1 for rapid cooling to the storage tank 1 and the line 2 for filling and sealing beverages in bottles, the sterilization and washing process enclosed by the one-dot chain line in FIG. 4 is performed in advance. This pre-treatment is performed by sterilizing and cleaning the rapid cooler 23, the storage tank 25 and the head tank 26 with steam or hot water under the same or better conditions as the heat sterilization condition of the beverage, and then sterilizing and filling the container. The space environment to be used is a management space separated from the outside world, and this space should be sterilized and washed with chemicals before filling with drinks. For containers and caps, at least the inner surface should be sterilized and washed with hot water at 65 ° C to 100 ° C. Then, the cooled beverage is stored in the storage tank, and the liquid content is sent to the filling machine while keeping the storage tank at a positive pressure with aseptic gas, so that air does not enter from the outside through the liquid supply path. A closed fluid path (area surrounded by a broken line in FIG. 4) and The beverage is filled into the sterilized container at room temperature in the isolated sterilized environmental management space, and the container is sealed. After sealing, it can be directly transferred to the inspection / boxing process without requiring cooling or heating.
[0029] 環境管理空間 14となるクリーンボックス 15内の薬剤を用いた本発明の殺菌 '洗浄 方法について図 3のシステム図によって説明する。図中 1は薬剤タンク、 2は温水タン ク、 3は排水タンクであって、 4と 5そして 6は流路切替え用の弁であり、 7は薬剤供給 管、 8は温水供給管である。当初は切替弁 4, 5と 6は図示の状態にセットされる。薬 剤が薬剤タンク 1から加圧供給されると供給管 7を通ってクリーンボックス 15内の各回 転式の噴射ノズル 16及び固定の噴射ノズル 17に至りクリーンボックス 15内に噴射さ れる。噴射された薬剤の作用で環境管理空間 14を殺菌し、噴射された薬剤は室内 の床部に流れ落ちて排出管から流出されるが、この際の切替弁 5は図示された状態 にあることから、図中の右側へ流れる。右側には排水タンク 3が設置されている力 開 閉弁 6が図示されているように排水タンク 3とは遮断された状態であるから薬剤は薬剤 タンク 1へ環流される。使用される薬剤は 1回の使用で廃棄してしまわずにその殺菌 機能が保証できる間繰り返し使用する。なお、薬品は酸性が強いため、使用後の廃 液処理に当たっては還元処理または pH処理が必要となる。  [0029] The sterilization and cleaning method of the present invention using the chemical in the clean box 15 serving as the environmental management space 14 will be described with reference to the system diagram of FIG. In the figure, 1 is a chemical tank, 2 is a hot water tank, 3 is a drainage tank, 4 and 5 and 6 are valves for switching the flow path, 7 is a chemical supply pipe, and 8 is a hot water supply pipe. Initially, the switching valves 4, 5 and 6 are set to the state shown in the figure. When the chemical is pressurized and supplied from the chemical tank 1, it passes through the supply pipe 7, reaches each rotary injection nozzle 16 and the fixed injection nozzle 17 in the clean box 15, and is injected into the clean box 15. The environment control space 14 is sterilized by the action of the injected drug, and the injected drug flows down to the floor in the room and flows out from the discharge pipe, but the switching valve 5 at this time is in the state shown in the figure. , Flows to the right in the figure. On the right side, the power open / close valve 6 in which the drainage tank 3 is installed is cut off from the drainage tank 3 as shown in the figure, so that the drug is circulated to the drug tank 1. Do not dispose of the medicine used in one use, but use it repeatedly as long as its sterilization function can be guaranteed. Since chemicals are highly acidic, reduction treatment or pH treatment is required for treatment of waste liquid after use.
[0030] 殺菌処理を終えた時点で、切替弁 4が薬剤供給管 7とは遮断されて温水供給管 8と 連通するように切替えられると共に切替弁 6は排水タンク 3と連通された状態にセット する。そして、今度は温水タンク 2から温水が温水供給管 8を経てクリーンボックス 15 内の各回転式の噴射ノズノレ 16及び固定の噴射ノズル 17に至りクリーンボックス 15内 に噴射される。噴射された温水はクリーンボックス 15内に残留している薬剤を洗浄し 、洗浄に使用された温水は室内の床部に流れ落ちて排出管から流出されるが、この 際の切替弁 5は図示された状態にあることから、図中の右側へ流れる。このとき、切替 え弁 6は薬剤タンク 1とは遮断され、排水タンク 3と連通状態にあるため、この洗浄処 理水は排水タンク 3へ流入される。以上の工程でクリーンボックス 15内の環境管理空 間 14の薬剤による殺菌と洗浄処理が完了し、切替弁 5が図において左側の温水タン ク 2と連通されるように切替えられ、次なる工程に備えられる。 1回の充填'密封作業 における洗浄水等の処理量は設備規模にもよるが 2〜3tであり、ァセブティック充填 システムの場合の様な容器の洗浄を含めて概ね 20t/時といった大量排水が出るこ とはなぐ本発明の方式では排水タンク 3に溜めるバッチ処理で対応できる。薬剤に よる環境管理空間の殺菌は、製造ロット単位毎に行っても良いし、例えば 2〜3ロット 毎に行っても良い。 [0030] When the sterilization process is completed, the switching valve 4 is disconnected from the chemical supply pipe 7 and switched to communicate with the hot water supply pipe 8, and the switching valve 6 is set to communicate with the drainage tank 3. To do. Then, hot water from the hot water tank 2 passes through the hot water supply pipe 8 and reaches each rotary injection nozzle 16 and the fixed injection nozzle 17 in the clean box 15 and is injected into the clean box 15. The sprayed hot water cleans the chemicals remaining in the clean box 15, and the hot water used for cleaning flows down to the floor of the room and flows out from the discharge pipe. The switching valve 5 at this time is shown in the figure. Because it is in the state of being, it flows to the right side in the figure. At this time, the switching valve 6 is disconnected from the chemical tank 1 and is in communication with the drainage tank 3, so that this cleaning water flows into the drainage tank 3. The sterilization and cleaning process with chemicals in the environmental management space 14 in the clean box 15 is completed by the above process, and the switching valve 5 is switched to communicate with the hot water tank 2 on the left side in the figure, and the next process is performed. Provided. Depending on the scale of the equipment, the processing volume of washing water, etc. in one filling and sealing operation is 2 to 3 tons. In the method of the present invention in which a large amount of drainage of about 20 tons / hour including the washing of containers as in the case of the system does not occur, it can be handled by batch processing stored in the drainage tank 3. Sterilization of the environmental management space by chemicals may be performed for each production lot unit, for example, every 2 to 3 lots.
[0031] 薬剤に過酢酸系薬剤を用いた場合、 40°Cの使用では 3分間の殺菌が必要であり、 このときの分解率が 1であるとすると、 50°Cの使用では殺菌に 1分かければよいが分 解率は 1.5となるまた、 60°Cの使用では殺菌には 10秒かければ足りる力 分解率は 4となる。すなわち、分解率が高くなると言うことは薬剤を再利用できる回数がそれだ け少なくなり薬剤の保ちが悪くなると言うことを意味し、使用温度を高くすれば殺菌効 果は上がるものの保ちが悪くなるという関係にある。上記のように薬剤使用後の洗浄 に 60〜100°Cの温水を用いる場合は、温水による殺菌機能が働くため、その分薬剤 の使用温度を低く抑えることができることによって薬剤の保ちを良くすることができる。 また薬剤が高温であると部品を劣化させ機器へダメージを与えるという問題もある。 また、本発明はクリーンボックスを薬剤で殺菌するので、使用薬剤や濃度によって は殺菌処理後の洗浄には上記のように温水を使用せずに無菌水を用いて洗浄する だけでも良い。この場合は切替弁 4には三方弁を用い無菌水のタンクとも接続する変 形構成をとることが必要である。  [0031] When a peracetic acid-based drug is used as the drug, sterilization is required for 3 minutes when used at 40 ° C. If the decomposition rate is 1, the sterilization is effective when used at 50 ° C. If it is understood, the degradation rate is 1.5. Also, if it is used at 60 ° C, the power degradation rate is 4, which is enough for 10 seconds to sterilize. In other words, a higher decomposition rate means that the number of times that the drug can be reused is reduced, and the retention of the drug is worsened.If the use temperature is increased, the bactericidal effect increases but the retention becomes worse. There is a relationship. When warm water of 60-100 ° C is used for washing after use of the drug as described above, the sterilization function by the warm water works, so that the use temperature of the drug can be kept low by that amount to improve the maintenance of the drug. Can do. There is also a problem that when the medicine is at a high temperature, parts are deteriorated and the device is damaged. In the present invention, the clean box is sterilized with chemicals, and depending on the chemicals used and the concentration, cleaning after sterilization may be performed using aseptic water instead of hot water as described above. In this case, it is necessary to adopt a modified configuration in which the switching valve 4 is connected to a tank of sterile water using a three-way valve.
またオゾン系のものなど使用する薬剤によっては洗浄が必要とされないものもある。  Also, some chemicals used, such as ozone-based ones, do not require cleaning.
[0032] 本実施形態において、環境管理空間外のボトル供給装置から環境管理空間 14内 のボトル殺菌 ·洗浄装置 10に移送されたボトルの殺菌は、少なくともボトルの内面、好 ましくは内外面を 65°C〜100°Cの熱水で加熱殺菌することにより行う。殺菌時間は 3 秒ないし 10秒である。この方法によれば、熱水によりボトルの殺菌と殺菌後の洗浄を 同時に行うので、殺菌後のボトルを別途洗浄する工程は不要であるが、軽量化した 容器の変形防止やボトルに付着した菌を洗い流す等の目的で、無菌水による洗浄を 行う場合がある。また、同様に環境管理空間外のキャップ供給装置から、管理空間内 に設置されたキャップ殺菌 ·洗浄装置にキャップを供給し、キャップの内外面に 65°C 〜100°Cの熱水を噴射することにより加熱殺菌する。  In this embodiment, the bottle transferred from the bottle supply device outside the environment management space to the bottle sterilization / cleaning device 10 inside the environment management space 14 is sterilized at least on the inner surface, preferably the inner and outer surfaces of the bottle. It is performed by heat sterilization with hot water at 65 ° C to 100 ° C. Sterilization time is 3 to 10 seconds. According to this method, since the bottle is sterilized with hot water and washed after sterilization at the same time, there is no need for a separate washing step for the bottle after sterilization. Washing with aseptic water may be performed for the purpose of washing away water. Similarly, a cap is supplied from a cap supply device outside the environmental management space to a cap sterilization / cleaning device installed in the management space, and hot water of 65 ° C to 100 ° C is sprayed to the inner and outer surfaces of the cap. Sterilize by heating.
[0033] 熱水によるボトル内外面の殺菌は、たとえばボトル洗浄装置でボトルを倒立状態に 配置し、熱水スプレーノズルから熱水を噴射することにより行うことができる。同様に、 熱水によるキャップ内外面の殺菌は、例えば針金で形成されたシュートを移動するか 又はターレットにより開口部を下方に向けて移動するキャップの内外面に熱水スプレ 一ノズルから熱水を噴射することにより行うことができる。殺菌洗浄が終了したボトノレ は、充填機 11に供給され、充填機で飲料が充填される。また、キャップはキヤッパー 12にそれぞれ供給され、飲料が充填されたボトルにキヤッビングされてボトルを密封 する。 [0033] Sterilization of the inner and outer surfaces of the bottle with hot water is performed, for example, by turning the bottle upside down with a bottle cleaning device. It can be done by placing and injecting hot water from a hot water spray nozzle. Similarly, sterilization of the inner and outer surfaces of the cap with hot water is performed by, for example, moving hot water from a hot water spray nozzle on the inner and outer surfaces of the cap moving the chute formed of a wire or moving the opening downward with a turret. This can be done by spraying. The bottlenole that has been sterilized and washed is supplied to the filling machine 11, and the beverage is filled in the filling machine 11. The caps are respectively supplied to the caps 12, and are capped in bottles filled with beverages to seal the bottles.
飲料をボトルへ充填'密封するライン 2の稼働中は、充填前の容器に熱水を噴射す ることによって加熱殺菌が行われる力 その際には図 3においてボトル殺菌'洗浄室 力、らの切替弁 5は図の左側すなわち、温水タンク 2に連通した形態でなされるので、 その処理水は温水タンク 2に環流され、再利用される。予め薬剤によって殺菌された 環境管理空間 14に外部から搬入されるボトルは一般的に清潔であり、仮に若干の菌 付着があつたとしてもここで殺菌 ·洗浄処理されているため、処理水の汚染はほとんど 無いので再利用が可能であって、この点も排水量の削減に貢献する。外部から搬入 されるキャップはボトノレほど清潔でないので、キャップを殺菌 ·洗浄したキヤッビング室 力 の処理水は切替弁 5を図の右側すなわち、排水タンク 3に連通した形態とし、再 利用せずに排水タンクに流される。 1回の充填'密封作業における洗浄水等の処理 量は先の薬剤洗浄水とこのキャップの殺菌 ·洗浄用処理水の合計となる。  During the operation of line 2 for filling and sealing beverages into bottles, the power to heat sterilize by injecting hot water into the container before filling is shown. Since the switching valve 5 is connected to the left side of the figure, that is, in a form communicating with the hot water tank 2, the treated water is circulated to the hot water tank 2 and reused. Bottles brought into the environment management space 14 sterilized by chemicals in advance from the outside are generally clean, and even if some bacteria adhere to them, they are sterilized and washed here, so the treated water is contaminated. Since there is almost no wastewater, it can be reused. This also contributes to the reduction of wastewater. Caps brought in from the outside are not as clean as the bottles, so the treated water in the cabbing chamber that has sterilized and washed the caps is connected to the right side of the figure, that is, to the drainage tank 3, and drained without being reused. Poured into the tank. The processing amount of cleaning water, etc. in one filling and sealing operation is the sum of the chemical cleaning water and the processing water for sterilization / cleaning of this cap.
[0034] —方、内容液である飲料は、図 1に示すようにクリーンボックス外に設置されている 調合タンク 20で調合されて、バランスタンク 21に貯留され、そこから高温短時間殺菌 器 22及び急速冷却器 23に供給されて高温短時間殺菌及び急速冷却が行われる。 高温短時間殺菌は、 HTST殺菌法等により加熱殺菌するものであり、本実施形態で は、前述したように前記飲料力 ¾H4.6以上でカテキン含有量が 30mg%以上の茶飲 料の場合は、 135°C、 7.58秒と同等以上の殺菌値を得るように、高温短時間殺菌を 行う。また、前記飲料力 ¾Η4.6未満の酸性飲料である場合は、該飲料を 85°C、 30分 と同等以上の殺菌値が得られるように、例えば 93〜95°Cで短時間の加熱殺菌を行う [0034] On the other hand, the beverage as the content liquid is prepared in the preparation tank 20 installed outside the clean box as shown in FIG. 1 and stored in the balance tank 21, from which the high temperature and short time sterilizer 22 And it is supplied to the rapid cooler 23 to perform high temperature short time sterilization and rapid cooling. The high temperature short time sterilization is a heat sterilization by the HTST sterilization method or the like. In the present embodiment, as described above, in the case of a tea drink having a beverage power of ¾H4.6 or more and a catechin content of 30 mg% or more. , Sterilize at a high temperature for a short time to obtain a sterilization value equivalent to or higher than 135 ° C and 7.58 seconds. In addition, in the case of an acidic beverage having a beverage strength of less than ¾Η4.6, the pasteurized beverage is sterilized at a temperature of, for example, 93 to 95 ° C for a short time so that a sterilization value equal to or higher than 85 ° C and 30 minutes can be obtained. I do
[0035] 急速冷却は、高温短時間殺菌が行われた飲料を引き続き急速冷却器 23を通過さ せることにより、通過する間に冷媒と熱交換を行って常温まで短時間に冷却するもの であり、常温としては略 35°Cが適当である力 飲料の種類や季節等によって異なり、 15°C〜40°Cの範囲が採用できる。急速冷却された飲料は、ァセブティックタンク力 なる貯留タンク 25に貯留される。当該貯留タンク 25、前記急速冷却器 23および後述 するヘッドタンク 26、充填機 11及びこれを接続する配管等の全ての接液面は、予め 充填する飲料の殺菌条件と同等以上、すなわち 135°C、 7.58秒と同等以上の殺菌 条件を得るように蒸気又は熱水で殺菌洗浄されて無菌化した閉鎖経路を形成してい る。特に、貯留タンク 25は、無菌ガスで陽圧保持して外気の進入を阻止し、且つ貯留 された飲料を無菌ガスによる圧送で該貯留タンクからヘッドタンク 26を介して充填機 に飲料を送っている。それにより、構造的に完全な殺菌とシールが困難で無菌化が 難しいポンプに寄らずに液送することができ、飲料を常温でもより無菌状態に維持す ること力 Sできる。ヘッドタンク 26も完全密閉型に形成され、該ヘッドタンク 26に貯蔵さ れた飲料は無菌ガスの圧送により充填機に送られ、無菌化された環境管理空間でボ トルに充填される。 [0035] Rapid cooling continues with the rapid cooler 23 for beverages that have been sterilized at high temperatures for a short time. By passing the heat, it exchanges heat with the refrigerant while passing, and cools to room temperature in a short time, and a power of about 35 ° C is appropriate for room temperature. A range of ~ 40 ° C can be adopted. The rapidly cooled beverage is stored in a storage tank 25 which is a powerful boutique tank. All the wetted surfaces such as the storage tank 25, the quick cooler 23 and the head tank 26, the filling machine 11, and the pipes connecting the storage tank 25 are equal to or higher than the sterilization conditions of the beverage to be filled in advance, that is, 135 ° C. In order to obtain a sterilization condition equal to or better than 7.58 seconds, it is sterilized and washed with steam or hot water to form a sterilized closed path. In particular, the storage tank 25 holds positive pressure with aseptic gas to prevent outside air from entering, and the stored beverage is pumped from the storage tank to the filling machine via the head tank 26 by pumping with aseptic gas. Yes. As a result, it is possible to pump the liquid without relying on a pump which is difficult to sterilize and seal structurally and is difficult to sterilize, and can maintain the beverage in a more sterile state even at room temperature. The head tank 26 is also formed in a completely sealed type, and the beverage stored in the head tank 26 is sent to the filling machine by sending sterile gas under pressure, and the bottle is filled in the sterilized environmental management space.
[0036] 飲料が充填されたボトルは充填機から環境管理空間内に設けられたキヤッパー 12 に移送され、環境管理空間外に配置されたキャップ供給装置から環境管理空間内に 配置されたキャップ殺菌 ·洗浄装置に供給されたキャップ殺菌 ·洗浄装置にぉレ、てボ トルと同一条件で殺菌 ·洗浄されたキャップで完全に密封される。その後密封された ボトルは、従来のホットパック法のようなパストライザ一やクーラーを通す後殺菌工程 や冷却工程等の後処理を必要とすることなぐ直接製品検査工程、箱詰工程等に送 ること力 Sできる。  [0036] The bottle filled with the beverage is transferred from the filling machine to the capper 12 provided in the environmental management space, and from the cap supply device arranged outside the environmental management space, the cap sterilization arranged in the environmental management space. Cap sterilization supplied to the cleaning device · The cleaning device is completely sealed with a cap that has been sterilized and cleaned under the same conditions as the bottle. The sealed bottle is then sent directly to the product inspection process, packaging process, etc. without requiring post-treatment such as past sterilization and cooling processes through a pastrizer or cooler as in the conventional hot pack method. Power S can be.
実施例  Example
[0037] [実施例 1] [0037] [Example 1]
容量 2Lの PETボトルを用いて、緑茶飲料 (pH5.9、カテキン含有量 52mg%)を上 記の製造方法および装置を用いて製造した。  A green tea beverage (pH 5.9, catechin content 52 mg%) was produced using the above-described production method and apparatus using a 2 L PET bottle.
すなわち、熱水で 90°C、 3秒間の加熱殺菌'洗浄したボトルに、 135°C、 30秒の高 温短時間の加熱殺菌後、常温まで急速冷却した緑茶飲料を、予め内容物の殺菌値 以上に殺菌 ·洗浄されて無菌ガスで陽圧化されている貯留タンクに貯留し、そこから ヘッドタンクに無菌ガスで圧送して充填機に供給して、管理空間内で予め熱水で殺 菌洗浄されたボトルに充填し、且つ予め殺菌 ·洗浄されたキャップで密封した。なお、 急速冷却器力 充填機までの液経路は、無菌ガスで陽圧化され外気と遮断された閉 鎖経路となっている。 That is, heat-sterilized with hot water at 90 ° C for 3 seconds and then washed at 135 ° C for 30 seconds at a high temperature for a short time, and then rapidly cooled to room temperature before sterilizing the contents. Stored in a storage tank that has been sterilized and cleaned and positively pressurized with sterile gas. The head tank was pumped with aseptic gas and supplied to a filling machine, filled in a bottle that had been sterilized and washed with hot water in a control space, and sealed with a cap that had been sterilized and washed in advance. The liquid path to the quick cooler power filling machine is a closed path that is positively pressurized with sterile gas and cut off from the outside air.
以上のようにして得られた、製造終了直後の緑茶飲料について従来のホットパック 法によって製造した場合との緑茶の色調、風味の変化を調べるために、緑茶の pH値 、色調、ビタミン Cをそれぞれ測定した。また、嗜好性について官能試験を実施した。 それらの結果を表 2、表 3及び表 4に示す。  In order to examine the changes in the color tone and flavor of green tea obtained by the conventional hot-pack method for green tea beverages immediately after the end of production, the pH value, color tone and vitamin C of green tea were It was measured. Moreover, the sensory test was implemented about palatability. The results are shown in Table 2, Table 3 and Table 4.
[0038] 上記色調測定は、 L * a * b表色系で測定した。 L値は明るさを、 a値は赤一緑の軸 を、 b値は黄—青の軸を表わす混色系の表色系であり、 L値が大きい程明るくなり、 a 値がプラスの方向になる程赤みが強くなり、マイナスの方向になるほど緑みが強くなり 、 b値がプラスの方向になる程黄みが強くなり、マイナスの方向になるほど青みが強く なる。また、 Δ Ε値は、この色空間での 2つの色間の直線距離がどのくらい離れている 力を計算により求めたものである。 [0038] The color tone was measured in the L * a * b color system. L value is brightness, a value is red-green axis, b value is yellow-blue color system. The larger the L value, the brighter the color, and the a value is positive. The red becomes stronger, the green becomes stronger as the value becomes negative, the yellow becomes stronger as the b value becomes positive, and the blue becomes stronger as the value becomes negative. The Δ Ε value is calculated by calculating how far the linear distance between two colors in this color space is.
また、ビタミン Cの測定は、調合後の未加熱状態の濃度を測定し、且つ製造終了直 後の飲料における濃度を測定し、残存率を調べた。  Vitamin C was measured by measuring the concentration in the unheated state after preparation, and measuring the concentration in the beverage immediately after the end of production, and examining the residual rate.
官能試験は、二点識別法に比べて正確性が高い三点識別法で実施し、比較対象 とする 2種類の茶飲料 (実施例 1の A、比較例 1の B)を、 A— A— B、 A— B— B等 3本 を適宜組合せて用意し、それを 15名のパネラーに試飲させて、両者の識別と嗜好性 官能評価をさせた。  The sensory test was performed using the three-point identification method, which is more accurate than the two-point identification method. Two types of tea beverages (A in Example 1 and B in Comparative Example 1) were compared as A—A. — B, A— B— B, etc. were prepared in appropriate combinations, and 15 panelists were allowed to taste them, and both were discriminated and their palatability was evaluated.
[0039] [実施例 2] [0039] [Example 2]
容量 1.5Lの PETボトルを用いて、 100%オレンジジュース(pH3.61)の酸性飲料 を上記の製造方法および装置を用いて製造した。  Using a 1.5L PET bottle, an acidic beverage of 100% orange juice (pH 3.61) was produced using the production method and apparatus described above.
すなわち、熱水で 90°C、 3秒間の加熱殺菌'洗浄したボトルに、 94.5〜96°C、 30 秒の高温短時間の加熱殺菌を行った後、常温 (本実施例では 31°C〜32°C)まで急 速冷却した酸性飲料を、予め内容物の殺菌値以上に殺菌'洗浄されて無菌ガスで陽 圧化されている貯留タンクに貯留し、以下実施例 1と同様な方法でボトル詰酸性飲料 を得た。なお、その場合の充填温度は 30°Cであった。そして、実施例 1の場合と同様 、製造終了直後の酸性飲料について従来のホットパック法によって製造した場合との 酸性飲料の色調、風味の変化を調べるために、緑茶の pH値、色調、ビタミン Cをそ れぞれ測定した。それらの結果を表 5、表 6に示す。 In other words, after sterilization with hot water at 90 ° C for 3 seconds and washing at 94.5 to 96 ° C for 30 seconds at high temperature and short time, the bottle was washed at room temperature (in this example, from 31 ° C to The acidic beverage rapidly cooled to (32 ° C) is stored in a storage tank that has been previously sterilized and washed to a level equal to or greater than the sterilization value of the contents and pressurized with aseptic gas. A bottled acidic beverage was obtained. In this case, the filling temperature was 30 ° C. And the same as in Example 1 In order to examine the changes in the color tone and flavor of acidic beverages immediately after the end of production, the pH value, color tone, and vitamin C of green tea were measured. The results are shown in Tables 5 and 6.
[0040] [比較例 1] [0040] [Comparative Example 1]
比較例 1として、実施例 1と同様容量 2Lの PETボトルを用いて、緑茶飲料 (pH5.9 、カテキン含有量 52mg%)を、前記特許文献 2に記載の製造方法及び装置を用い て製造した。すなわち、 90°C、 3秒の熱水で殺菌'洗浄したボトルに、 135°C、 30秒 の高温短時間殺菌後、 65°Cまで冷却した緑茶飲料を、予めボックスにより外界と遮 断した環境管理空間内に設置され、容器と同一条件で殺菌 '洗浄した充填機、キヤッ パーにより充填、密封した。その後、簡易的な冷却水シャワーで PETボトル詰め緑茶 飲料を常温まで冷却して茶飲料を得た。  As Comparative Example 1, a green tea beverage (pH 5.9, catechin content 52 mg%) was produced using the production method and apparatus described in Patent Document 2, using a PET bottle with a capacity of 2 L as in Example 1. . In other words, a green tea beverage that had been sterilized and washed with hot water at 90 ° C for 3 seconds and then sterilized at a high temperature of 135 ° C for 30 seconds and then cooled to 65 ° C was blocked from the outside by a box in advance. It was installed in an environmental management space and sterilized and cleaned under the same conditions as the container, and filled and sealed with a capper. Thereafter, a green tea beverage packed in a PET bottle was cooled to room temperature with a simple cooling water shower to obtain a tea beverage.
以上のようにして得られた緑茶飲料について、製造終了直後(この場合は冷却後) の飲料について、実施例 1と同様にして、緑茶の色調、風味の変化を調べるために、 緑茶の pH値、色調、ビタミン Cをそれぞれ測定した。また、実施例と同様な方法で三 点識別法を用いて両者の識別と官能評価を行った。それらの結果を実施例 1と共に 表 2〜表 4に示す。  For the green tea beverage obtained as described above, the pH value of the green tea was examined in the same manner as in Example 1 for the beverage immediately after the end of production (after cooling in this case) in the same manner as in Example 1. , Color tone, and vitamin C were measured. In addition, the identification and sensory evaluation of both were performed using the three-point identification method in the same manner as in the examples. The results are shown in Table 2 to Table 4 together with Example 1.
[0041] [比較例 2] [0041] [Comparative Example 2]
比較例 2として、実施例 2と同様容量 1.5Lの PETボトルを用いて、 100%オレンジ ジュース (PH3.61)を、比較例 1と同様に前記特許文献 2に記載の製造方法及び装 置を用いて製造した。すなわち、 90°C、 3秒の熱水で殺菌'洗浄したボトルに、 94.5 〜96°C、 30秒の高温短時間の加熱殺菌後、 67〜68°Cまで冷却した酸性飲料を、 予めボックスにより外界と遮断した環境管理空間内に設置され、容器と同一条件で殺 菌 '洗浄した充填機、キヤッパーにより充填温度 65°Cで充填、密封した。その後、簡 易的な冷却水シャワーで PETボトル詰め酸性飲料を常温まで冷却して酸性飲料を 得た。  As Comparative Example 2, 100% orange juice (PH3.61) was obtained using a PET bottle having a capacity of 1.5 L as in Example 2, and the production method and apparatus described in Patent Document 2 were used as in Comparative Example 1. Manufactured. In other words, a bottle that has been sterilized and washed with hot water at 90 ° C for 3 seconds, then baked at 94.5 to 96 ° C for 30 seconds at a high temperature for a short time, and then cooled to 67 to 68 ° C with an acidic beverage in advance. It was installed in an environmental management space that was cut off from the outside by sterilization under the same conditions as the container, and was filled and sealed at a filling temperature of 65 ° C with a filling machine and capper that had been cleaned. Then, the acidic beverage was obtained by cooling the acidic beverage packed in a PET bottle to room temperature with a simple cooling water shower.
以上のようにして得られた酸性飲料について、製造終了直後(この場合は冷却後) の飲料について、実施例 2と同様にして、 100%オレンジジュースの色調、風味の変 化を調べるために、その pH値、色調、ビタミン Cをそれぞれ測定した。それらの結果 を実施例 2と共に表 5、表 6に示す。 In order to investigate the color tone and flavor change of 100% orange juice in the same manner as in Example 2 for the acidic beverage obtained as described above, the beverage immediately after the end of production (in this case after cooling), Its pH value, color tone, and vitamin C were measured. Those results Are shown in Table 5 and Table 6 together with Example 2.
[実施例と比較例の評価]  [Evaluation of Examples and Comparative Examples]
茶飲料の場合  For tea drinks
pH値、色調:  pH value, color:
[表 2]  [Table 2]
Figure imgf000020_0001
表 2から明らかなように、実施例 1と比較例 1を比較した場合、実施例 1のものが比 較例 1と比べて明らかに色調が調合未加熱品に近ぐ新鮮な色調を保持できている ことが分かる。また、 pH値も実施例 1のものが、調合未加熱品に近い状態を維持して いることが分かる。
Figure imgf000020_0001
As is clear from Table 2, when Example 1 and Comparative Example 1 are compared, the color of Example 1 clearly retains the fresh color tone that is close to the unheated product compared to Comparative Example 1. You can see that In addition, it can be seen that the pH value of Example 1 maintains a state close to that of the unheated product.
ビタミン C残存率:  Vitamin C survival rate:
[表 3] [Table 3]
Figure imgf000020_0002
表 3に示すように、ビタミン Cの残存率は、調合未加熱品に対して実施例 1が 83.4 %であるのに対して、比較例 1が 76%であり、明らかに実施例の場合がビタミン Cの 残率が高かった。
Figure imgf000020_0002
As shown in Table 3, the residual ratio of vitamin C was 83.4% in Example 1 with respect to the unheated product, while it was 76% in Comparative Example 1. The residual rate of vitamin C was high.
嗜好性官能評価:  Taste sensory evaluation:
[表 4] パネラー 1 5名 備考 [Table 4] Paneler 1 5 Remarks
識別試験 正解者 9名 5 %危険率で有意差あり 識別試験正解者 9名のう 5 %危険率で実施例のも 嗜好試験 ち実施例 1のものを好む の (常温充填) が好まれる 者 7名、比較例 1のものを  Discrimination test correct answer 9 people 5% Risk rate has a significant difference Discrimination test correct answer 9 people 5% risk rate Example of preference test Preference test of Example 1 Those who prefer (normal temperature filling) are preferred 7 people, those of Comparative Example 1
好む者 2名 表 4に示すように、 15名のパネラーの官能評価の結果、実施例と比較例のものを区 別できた 9名のうち、実施例のものを好むものが 7名おり、実施例 1のものが比較例 1 のものと比べて圧倒的に嗜好性が高い結果が示された。  As shown in Table 4, as a result of sensory evaluation of 15 panelists, among the 9 people who could distinguish the example and the comparative example, 7 people preferred the example, The results of Example 1 were overwhelmingly higher in preference than those of Comparative Example 1.
[0045] 経時変化観察 [0045] Observation of changes over time
上記実施例 1で製造した 2Lの PETボトル詰緑茶飲料を、常温で 2週間の保管後内 容物の微生物変敗状態を目視により観察した。その結果、緑茶飲料の状態は良好で 、微生物変敗による濁りはまったく観察されなかった。  The 2L PET bottled green tea beverage produced in Example 1 above was visually observed for microbial degradation of the contents after storage at room temperature for 2 weeks. As a result, the state of the green tea beverage was good and no turbidity due to microbial degradation was observed.
[0046] 100%オレンジジュース(酸性飲料)の場合 [0046] In the case of 100% orange juice (acid drink)
pH値、色調:  pH value, color:
[表 5]  [Table 5]
Figure imgf000021_0001
表 5から明らかなように、実施例 2と比較例 2を比較した場合、実施例 2のものが比 較例 2と比べて明らかに色調が調合未加熱品に近ぐ新鮮な色調を保持できている ことが分かる。即ち、比較例 2の 100%オレンジジュースは、実施例 2のものと比べて L値(明度)が低下し、 a値 (赤色)が上昇し、且つ b値 (黄色)が低下している。
Figure imgf000021_0001
As is clear from Table 5, when Example 2 and Comparative Example 2 are compared, the color of Example 2 clearly retains the fresh color tone that is close to the unheated product compared to Comparative Example 2. You can see that That is, the 100% orange juice of Comparative Example 2 has a lower L value (lightness), higher a value (red), and lower b value (yellow) than that of Example 2.
ビタミン C残存率:  Vitamin C survival rate:
[表 6] 濃度 残存率 [Table 6] Concentration remaining rate
(ppm) (%)  (ppm) (%)
調合未加熱品 283 100.0  Unheated product 283 100.0
実施例 2 270 95.4  Example 2 270 95.4
比較例 2 245 86.6 表 6に示すように、ビタミン Cの残存率は、調合未加熱品に対して実施例 4が 95.4 %であるのに対して、比較例 2が 86.6%であり、明らかに実施例 2の場合がビタミン C の残率が高かった。  Comparative Example 2 245 86.6 As shown in Table 6, the residual ratio of vitamin C was 95.4% in Example 4 with respect to the unheated product, compared with 86.6% in Comparative Example 2, clearly In the case of Example 2, the residual ratio of vitamin C was high.
[0048] 総合評価  [0048] Overall evaluation
実施例 1、 2と比較例 1、 2についての、色調測定、 pH値測定、ビタミン C残存率の 何れの点においても、実施例のものが比較例に比べて優れており、新鮮な色調を保 持しビタミン Cの残存率も高ぐ品質に優れた飲料が得られていることが確認された。 そして、実施例 1と比較例 1についてのパネラー官能試験の結果でも圧倒的に実施 例のものが嗜好性が高い結果となっており、本発明の容器詰飲料の製造方法を茶飲 料及び酸性飲料に適用した場合の有効性が確認された。  Examples 1 and 2 and Comparative Examples 1 and 2 are superior to the comparative example in terms of color tone measurement, pH value measurement, and vitamin C residual rate, and have a fresh color tone. It was confirmed that beverages with excellent quality and retained vitamin C remaining rate were obtained. The results of the panelist sensory test for Example 1 and Comparative Example 1 are overwhelmingly preferred for the examples, and the method for producing a packaged beverage according to the present invention is used for tea beverages and acidic beverages. The effectiveness when applied to beverages was confirmed.
[0049] [実施例 3] [0049] [Example 3]
容量 2Lの PETボトルを用いて、緑茶飲料(pH5.9、カテキン含有量 52mg%)を上 記の製造方法および装置を用いて製造した。  A green tea beverage (pH 5.9, catechin content 52 mg%) was produced using the above-described production method and apparatus using a 2 L PET bottle.
すなわち、容器洗浄 ·充填 ·密封をする管理空間を予め 40°C,濃度 2000ppmの過 酢酸系薬剤(商品名:トーョーアクティブ)を用いて 10分間殺菌した後 90°Cの熱水で 洗浄し、 B. subtilis, B. coagulansといった芽胞菌に対し 6D以上の殺菌効果が確認さ れた。また、熱水で 90°C、 3秒間の加熱殺菌 '洗浄したボトルに、 135°C、 30秒の高 温短時間の加熱殺菌後、常温まで急速冷却した緑茶飲料を、予め内容物の殺菌値 以上に殺菌 ·洗浄されて無菌ガスで陽圧化されている貯留タンクに貯留し、そこから ヘッドタンクに無菌ガスで圧送して充填機に供給して、管理空間内で予め熱水で殺 菌洗浄されたボトルに充填し、且つ予め殺菌 '洗浄されたキャップで密封した。なお、 急速冷却器から充填機までの液経路は、無菌ガスで陽圧化され外気と遮断された閉 鎖経路となっている。 以上のようにして得られた、製造終了直後の緑茶飲料について従来のホットパック 法によって製造した場合との緑茶の色調、風味の変化を調べるために、緑茶の pH値 、色調、ビタミン Cをそれぞれ測定した。また、嗜好性について官能試験を実施した。 それらの結果を表 7、表 8及び表 9に示す。 In other words, the control space for container cleaning, filling, and sealing is sterilized in advance using a peracetic acid-based chemical (trade name: Too Active) with a concentration of 2000 ppm at 40 ° C and then washed with hot water at 90 ° C. Bactericidal effects of 6D or more were confirmed against spores such as B. subtilis and B. coagulans. In addition, heat sterilization at 90 ° C for 3 seconds with hot water.After sterilization of the washed tea bottle at 135 ° C for 30 seconds at a high temperature for a short time and then rapidly cooled to room temperature, the green tea beverage is sterilized in advance. More than the value Sterilized · Stored in a storage tank that has been cleaned and positively pressurized with sterile gas, and then pumped to the head tank with sterile gas and supplied to the filling machine, killed beforehand with hot water in the control space The fungus-washed bottle was filled and sealed with a pre-sterilized 'washed cap. The liquid path from the quick cooler to the filling machine is a closed path that is positively pressurized with sterile gas and shut off from the outside air. In order to examine the changes in the color tone and flavor of green tea obtained by the conventional hot-pack method for green tea beverages immediately after the end of production, the pH value, color tone and vitamin C of green tea were It was measured. Moreover, the sensory test was implemented about palatability. The results are shown in Table 7, Table 8 and Table 9.
[0050] 上記色調測定は、先と同様 L * a * b * (エルスタ一'エースタ一'ビースター)表色 系で測定した。 [0050] The color tone was measured in the L * a * b * (Elster's' Aester''Biester) color system as before.
また、ビタミン Cの測定は、調合後の未加熱状態の濃度を測定し、且つ製造終了直 後の飲料における濃度を測定し、残存率を調べた。  Vitamin C was measured by measuring the concentration in the unheated state after preparation, and measuring the concentration in the beverage immediately after the end of production, and examining the residual rate.
官能試験は、二点識別法に比べて正確性が高レ、三点識別法で実施し、比較対象 とする 2種類の茶飲料(実施例 3の A、比較例 3の B)を、 A_A_B、 A—B— B等 3本 を適宜組合せて用意し、それを 20名のパネラーに試飲させて、両者の識別と嗜好性 官能評価をさせた。  The sensory test is performed with the three-point identification method, which is more accurate than the two-point identification method. Two types of tea beverages (A in Example 3 and B in Comparative Example 3) are compared as A_A_B. , A—B—B, etc. were prepared in appropriate combinations, and 20 panelists sampled them for discrimination and sensory evaluation of both.
[0051] [実施例 4] [0051] [Example 4]
容量 1.5Lの PETボトルを用いて、 100%オレンジジュース(pH3.61)の酸性飲料 を上記の製造方法および装置を用いて製造した。  Using a 1.5L PET bottle, an acidic beverage of 100% orange juice (pH 3.61) was produced using the production method and apparatus described above.
すなわち、容器洗浄 ·充填 ·密封をする管理空間を予め 40°C,濃度 2000ppmの過 酢酸系薬剤(商品名:トーョーアクティブ)を用いて 10分間殺菌した後 90°Cの熱水で 洗浄。また、熱水で 90°C、 3秒間の加熱殺菌'洗浄したボトルに、 94.5〜96°C、 30 秒の高温短時間の加熱殺菌を行った後、常温 (本実施例では 31°C〜32°C)まで急 速冷却した酸性飲料を、予め内容物の殺菌値以上に殺菌'洗浄されて無菌ガスで陽 圧化されている貯留タンクに貯留し、以下実施例 3と同様な方法でボトル詰酸性飲料 を得た。なお、その場合の充填温度は 30°Cであった。そして、実施例 3の場合と同様 、製造終了直後の酸性飲料について従来のホットパック法によって製造した場合との 酸性飲料の色調、風味の変化を調べるために、緑茶の pH値、色調、ビタミン Cをそ れぞれ測定した。それらの結果を表 10、表 11に示す。  In other words, the control space for container cleaning, filling and sealing was sterilized in advance using a peracetic acid chemical (trade name: Too Active) with a concentration of 2000 ppm at 40 ° C and then washed with hot water at 90 ° C. In addition, after sterilization with hot water at 90 ° C for 3 seconds and washing at 94.5 to 96 ° C for 30 seconds at high temperature and short time, the bottle is washed at room temperature (31 ° C in this example) The acidic beverage rapidly cooled to (32 ° C) is stored in a storage tank that has been sterilized and washed in advance to the sterilization value of the contents and then positively pressurized with aseptic gas. A bottled acidic beverage was obtained. In this case, the filling temperature was 30 ° C. Then, as in Example 3, in order to examine the changes in the color tone and flavor of the acidic beverage immediately after the end of production, the pH value, color tone, vitamin C Each was measured. The results are shown in Tables 10 and 11.
[0052] [比較例 3] [0052] [Comparative Example 3]
比較例 3として、実施例 3と同様容量 2Lの PETボトルを用いて、緑茶飲料 (pH5.9 、カテキン含有量 52mg%)を、前記特許文献 2に記載の製造方法及び装置を用い て製造した。すなわち、 90°C、 3秒の熱水で殺菌'洗浄したボトルに、 135°C、 30秒 の高温短時間殺菌後、 65°Cまで冷却した緑茶飲料を、予めボックスにより外界と遮 断した環境管理空間内に設置され、容器と同一条件で殺菌 '洗浄した充填機、キヤッ パーにより充填、密封した。その後、簡易的な冷却水シャワーで PETボトル詰め緑茶 飲料を常温まで冷却して茶飲料を得た。 As Comparative Example 3, using a PET bottle with a capacity of 2 L as in Example 3, a green tea beverage (pH 5.9, catechin content 52 mg%) was prepared using the production method and apparatus described in Patent Document 2. Manufactured. In other words, a green tea beverage that had been sterilized and washed with hot water at 90 ° C for 3 seconds and then sterilized at a high temperature of 135 ° C for 30 seconds and then cooled to 65 ° C was blocked from the outside by a box in advance. It was installed in an environmental management space and sterilized and cleaned under the same conditions as the container, and filled and sealed with a capper. Thereafter, a green tea beverage packed in a PET bottle was cooled to room temperature with a simple cooling water shower to obtain a tea beverage.
以上のようにして得られた緑茶飲料について、製造終了直後(この場合は冷却後) の飲料について、実施例 3と同様にして、緑茶の色調、風味の変化を調べるために、 緑茶の pH値、色調、ビタミン Cをそれぞれ測定した。また、実施例と同様な方法で三 点識別法を用いて両者の識別と官能評価を行った。それらの結果を実施例 3と共に 表 7〜表 9に示す。  For the green tea beverage obtained as described above, the pH value of the green tea was examined in order to examine the change in the color tone and flavor of the green tea in the same manner as in Example 3 for the beverage immediately after the end of production (after cooling in this case). , Color tone, and vitamin C were measured. In addition, the identification and sensory evaluation of both were performed using the three-point identification method in the same manner as in the examples. The results are shown in Table 7 to Table 9 together with Example 3.
[0053] [比較例 4] [0053] [Comparative Example 4]
比較例 4として、実施例 4と同様容量 1.5Lの PETボトルを用いて、 100%オレンジ ジュース (PH3.61)を、比較例 1と同様に前記特許文献 2に記載の製造方法及び装 置を用いて製造した。すなわち、 90°C、 3秒の熱水で殺菌'洗浄したボトルに、 94.5 〜96°C、 30秒の高温短時間の加熱殺菌後、 67〜68°Cまで冷却した酸性飲料を、 予めボックスにより外界と遮断した環境管理空間内に設置され、容器と同一条件で殺 菌 '洗浄した充填機、キヤッパーにより充填温度 65°Cで充填、密封した。その後、簡 易的な冷却水シャワーで PETボトル詰め酸性飲料を常温まで冷却して酸性飲料を 得た。  As Comparative Example 4, 100% orange juice (PH3.61) was obtained using a PET bottle with a capacity of 1.5 L as in Example 4, and the production method and apparatus described in Patent Document 2 were used as in Comparative Example 1. Manufactured. In other words, a bottle that has been sterilized and washed with hot water at 90 ° C for 3 seconds, then baked at 94.5 to 96 ° C for 30 seconds at a high temperature for a short time, and then cooled to 67 to 68 ° C with an acidic beverage in advance. It was installed in an environmental management space that was cut off from the outside by sterilization under the same conditions as the container, and was filled and sealed at a filling temperature of 65 ° C with a filling machine and capper that had been cleaned. Then, the acidic beverage was obtained by cooling the acidic beverage packed in a PET bottle to room temperature with a simple cooling water shower.
以上のようにして得られた酸性飲料について、製造終了直後(この場合は冷却後) の飲料について、実施例 4と同様にして、 100%オレンジジュースの色調、風味の変 化を調べるために、その pH値、色調、ビタミン Cをそれぞれ測定した。それらの結果 を実施例 4と共に表 10、表 11に示す。  In order to examine the change in color and flavor of 100% orange juice in the same manner as in Example 4 for the beverage immediately after production (in this case, after cooling), the acidic beverage obtained as described above was used. Its pH value, color tone, and vitamin C were measured. The results are shown in Table 10 and Table 11 together with Example 4.
[0054] [実施例と比較例の評価] [Evaluation of Examples and Comparative Examples]
茶飲料の場合  For tea drinks
pH値、色調:  pH value, color:
[表 7] P H 直 a値 b値 厶 E [Table 7] PH direct a value b value 厶 E
調合未加熱品 6.44 91 .50 -10.30 30.05 基準  Unheated product 6.44 91 .50 -10.30 30.05 Standard
実施例 3 6.30 89.95 -8.50 33.35 3.69  Example 3 6.30 89.95 -8.50 33.35 3.69
比較例 3 6.25 88.91 -8.20 34.1 1 5.25 表 7から明らかなように、実施例 3と比較例 3を比較した場合、実施例 3のものが比 較例 3と比べて明らかに色調が調合未加熱品に近ぐ新鮮な色調を保持できている ことが分かる。また、 pH値も実施例 3のものが、調合未加熱品に近い状態を維持して いることが分かる。  Comparative Example 3 6.25 88.91 -8.20 34.1 1 5.25 As is clear from Table 7, when Example 3 and Comparative Example 3 are compared, the color of Example 3 is clearly mixed with that of Comparative Example 3 and the color tone is not mixed. It can be seen that the fresh colors close to the product can be maintained. It can also be seen that the pH value of Example 3 maintains a state close to that of the unheated product.
ビタミン C残存率:  Vitamin C survival rate:
[表 8] [Table 8]
Figure imgf000025_0001
表 8に示すように、ビタミン Cの残存率は、調合未加熱品に対して実施例 3が 85.2 %であるのに対して、比較例 3が 77.4%であり、明らかに実施例の場合がビタミン C の残率が高かった。
Figure imgf000025_0001
As shown in Table 8, the residual ratio of vitamin C was 85.2% in Example 3 with respect to the unheated product, whereas it was 77.4% in Comparative Example 3, which was clearly the case in Example. The residual rate of vitamin C was high.
嗜好性官能評価:  Taste sensory evaluation:
[表 9] [Table 9]
Figure imgf000025_0002
表 9に示すように、 20名のパネラーの官能評価の結果、実施例と比較例のものを区 別できた 12名のうち、実施例のものを好むものが 8名おり、実施例 3のものが比較例 3 のものと比べて圧倒的に嗜好性が高い結果が示された。 [0057] 経時変化観察
Figure imgf000025_0002
As shown in Table 9, as a result of sensory evaluation of 20 panelists, out of 12 people who could distinguish between the examples and the comparative examples, there were 8 people who preferred the examples. The result showed that the product was overwhelmingly higher in preference than that of Comparative Example 3. [0057] Observation over time
上記実施例 3で製造した 2Lの PETボトル詰緑茶飲料を、常温で 2週間の保管後内 容物の微生物変敗状態を目視により観察した。その結果、緑茶飲料の状態は良好で 、微生物変敗による濁りはまったく観察されなかった。  The 2L PET bottled green tea beverage produced in Example 3 above was visually observed for microbial degradation of the contents after storage at room temperature for 2 weeks. As a result, the state of the green tea beverage was good and no turbidity due to microbial degradation was observed.
[0058] 100%オレンジジュース(酸性飲料)の場合 [0058] In the case of 100% orange juice (acid drink)
pH値、色調:  pH value, color:
[表 10]  [Table 10]
Figure imgf000026_0001
表 10から明らかなように、実施例 4と比較例 4を比較した場合、実施例 4のものが比 較例 4と比べて明らかに色調が調合未加熱品に近ぐ新鮮な色調を保持できている ことが分かる。即ち、比較例 4の 100%オレンジジュースは、実施例 4のものと比べて L値(明度)が低下し、 a値 (赤色)が上昇し、且つ b値 (黄色)が低下している。
Figure imgf000026_0001
As is apparent from Table 10, when Example 4 and Comparative Example 4 are compared, the color of Example 4 clearly retains a fresh color tone that is close to the unheated product compared to Comparative Example 4. You can see that That is, the 100% orange juice of Comparative Example 4 has a lower L value (lightness), higher a value (red), and lower b value (yellow) than that of Example 4.
ビタミン C残存率:  Vitamin C survival rate:
[表 11]  [Table 11]
Figure imgf000026_0002
表 11に示すように、ビタミン Cの残存率は、調合未加熱品に対して実施例 2が 92.2 %であるのに対して、比較例 4が 86.3%であり、明らかに実施例 4の場合がビタミン C の残率が高かった。
Figure imgf000026_0002
As shown in Table 11, the residual ratio of vitamin C was 92.2% in Example 2 with respect to the unheated product, while it was 86.3% in Comparative Example 4, clearly in the case of Example 4. However, the residual rate of vitamin C was high.
総合評価  Comprehensive evaluation
実施例 3、 4と比較例 3、 4についての、色調測定、 pH値測定、ビタミン C残存率の 何れの点においても、実施例のものが比較例に比べて優れており、新鮮な色調を保 持しビタミン cの残存率も高ぐ品質に優れた飲料が得られていることが確認された。 そして、実施例 3と比較例 3についてのパネラー官能試験の結果でも圧倒的に実施 例のものが嗜好性が高い結果となっており、本発明の容器詰飲料の製造方法を茶飲 料及び酸性飲料に適用した場合の有効性が確認された。 Examples 3 and 4 and Comparative Examples 3 and 4 are superior to the Comparative Example in terms of color tone measurement, pH value measurement, and vitamin C residual rate, and have a fresh color tone. Protection It was confirmed that beverages with high quality and high residual rate of vitamin c were obtained. The results of the panelist sensory test for Example 3 and Comparative Example 3 are overwhelmingly preferred for the examples, and the method for producing a packaged beverage according to the present invention is used for tea drinks and acidic drinks. The effectiveness when applied to beverages was confirmed.
産業上の利用可能性 Industrial applicability
本発明の容器詰飲料の製造方法は、 PH4.6以上でカテキン含有量が 30mg%以 上の緑茶、ウーロン茶等の飲料、および PH4.6未満の酸性飲料乃至はミネラルゥォ 一ター等加熱後の芽胞菌の生育が困難な非富養性飲料の容器詰め飲料の製造に 好適に利用することができる。容器は PETボトノレ等の合成樹脂製ボトルに限らず、金 属ボトルや金属缶、ガラスボトル等に適用可能である。  The method for producing a packaged beverage according to the present invention comprises a beverage such as green tea or oolong tea having a catechin content of 30 mg% or more with a pH of 4.6 or more, and an acidic beverage or a spore after heating such as mineral water or less. It can be suitably used for the production of container-packed beverages of non-nutrient beverages in which fungal growth is difficult. The container is not limited to plastic bottles such as PET bottles, but can be applied to metal bottles, metal cans, glass bottles, and the like.

Claims

請求の範囲 The scope of the claims
[1] 容器及びキャップ殺菌洗浄 ·充填 ·密封をする周辺環境を予め 65°C〜: 100°Cの熱 水または薬剤を用レ、て加熱殺菌 ·洗浄する工程、冷却機、貯留タンク及び充填機ま での送液経路を充填する飲料の加熱殺菌条件と同等以上の条件で予め加熱殺菌- 洗浄する工程、容器及びキャップの少なくとも内面を 65°C〜: 100°Cの温水で加熱殺 菌 '洗浄する工程を有し、充填する飲料を所定の殺菌値まで加熱殺菌を行った後、 常温まで急速冷却し、該冷却された飲料を前記貯留タンクに貯蔵し、前記充填機に 内容液を送ることによって前記送液経路を外部から空気の侵入のない閉鎖経路にし 、且つ前記周辺環境を外界と隔離した環境管理空間として、該管理空間の中で前記 飲料を前記殺菌済み容器に常温充填して密封することを特徴とする容器詰め飲料 の製造方法。  [1] Sterilization and cleaning of containers and caps · Filling · Preliminary surrounding environment to be sealed from 65 ° C to 100 ° C using hot water or chemicals · Heat sterilization · Cleaning process, cooler, storage tank and filling Heat sterilization under the same or better condition as the heat sterilization condition of the beverage filling the liquid supply path to the machine-At least the inner surface of the container and the cap 65 ° C ~: Heat sterilization with 100 ° C hot water 'After washing, the beverage to be filled is heat sterilized to a predetermined sterilization value, then rapidly cooled to room temperature, the cooled beverage is stored in the storage tank, and the content liquid is stored in the filling machine. By making the liquid supply path into a closed path that does not allow air to enter from outside, and the surrounding environment is isolated from the outside, the beverage is filled in the sterilized container at room temperature in the management space. Packed in a container characterized by sealing Method of manufacturing a fee.
[2] 前記飲料力 H4.6以上でカテキン含有量が 30mg%以上の飲料であり、該飲料を 135°C、 7.58秒と同等以上の殺菌値で加熱殺菌する請求項 1に記載の容器詰め飲 料の製造方法。  [2] The container according to claim 1, wherein the beverage is a beverage having a beverage power of H4.6 or more and a catechin content of 30 mg% or more, and the beverage is heat-sterilized at a sterilization value equal to or higher than 135 ° C and 7.58 seconds. A method for producing beverages.
[3] 前記飲料力 H4.6未満の酸性飲料であり、該酸性飲料を 85°C、 30分と同等以上 の殺菌値で加熱殺菌する請求項 1に記載の容器詰め飲料の製造方法。  [3] The method for producing a packaged beverage according to claim 1, wherein the beverage is an acidic beverage having a beverage strength of less than H4.6, and the acidic beverage is heat sterilized at a sterilization value equal to or higher than 85 ° C for 30 minutes.
[4] 該環境管理空間はボックス内に収容された空間であることを特徴とする請求項 1に 記載の容器詰め飲料の製造方法。 [4] The method for producing a packaged beverage according to claim 1, wherein the environmental management space is a space accommodated in a box.
[5] 前記貯留タンクは無菌ガスで陽圧保持し、該貯留タンクから充填機への液送は、無 菌ガスによる圧送であることを特徴とする請求項 1に記載の容器詰め飲料の製造方 法。 [5] The container-packed beverage production according to claim 1, wherein the storage tank is maintained at a positive pressure with a sterile gas, and the liquid feeding from the storage tank to the filling machine is a pressure feeding with a sterilized gas. Method.
[6] 周辺環境を薬剤を用いて加熱殺菌 ·洗浄した後の洗浄には 65°C〜100°Cの温水 を用いて殺菌機能も兼ねさせることを特徴とする請求項 1に記載の容器詰め飲料の 製造方法。  [6] Container stuffing according to claim 1, characterized in that the surrounding environment is also heat sterilized with a chemical and the cleaning after cleaning is performed by using hot water of 65 ° C to 100 ° C also serving as a sterilization function. A method for producing beverages.
[7] 容器及びキャップ殺菌洗浄 '充填'密封をする周辺環境を予め殺菌洗浄する薬剤 として、過酢酸系薬剤、過酸化水素、オゾン系薬剤、次亜塩素酸を含有する塩素系 殺菌剤のレ、ずれ力を用いるようにしたことを特徴とする請求項 1に記載の容器詰め飲 料の製造方法。  [7] Container and cap sterilization cleaning As a chemical for pre-sterilization and cleaning of the surrounding environment to be 'filled' and sealed, a record of chlorine-based disinfectant containing peracetic acid-based chemicals, hydrogen peroxide, ozone-based chemicals, and hypochlorous acid. 2. The method for producing a container-packed beverage according to claim 1, wherein a displacement force is used.
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