TW200821256A - Manufacturing method of container final stage drink - Google Patents

Manufacturing method of container final stage drink Download PDF

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Publication number
TW200821256A
TW200821256A TW096126566A TW96126566A TW200821256A TW 200821256 A TW200821256 A TW 200821256A TW 096126566 A TW096126566 A TW 096126566A TW 96126566 A TW96126566 A TW 96126566A TW 200821256 A TW200821256 A TW 200821256A
Authority
TW
Taiwan
Prior art keywords
beverage
sterilization
container
sterilized
filling
Prior art date
Application number
TW096126566A
Other languages
Chinese (zh)
Inventor
Katsumi Senbon
Takeshi Iwashita
Original Assignee
Toyo Seikan Kaisha Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2006203825A external-priority patent/JP5136740B2/en
Priority claimed from JP2007004815A external-priority patent/JP5071622B2/en
Application filed by Toyo Seikan Kaisha Ltd filed Critical Toyo Seikan Kaisha Ltd
Publication of TW200821256A publication Critical patent/TW200821256A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C7/00Concurrent cleaning, filling, and closing of bottles; Processes or devices for at least two of these operations
    • B67C7/0073Sterilising, aseptic filling and closing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/04Sterilising wrappers or receptacles prior to, or during, packaging
    • B65B55/10Sterilising wrappers or receptacles prior to, or during, packaging by liquids or gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/12Sterilising contents prior to, or during, packaging
    • B65B55/14Sterilising contents prior to, or during, packaging by heat

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

A problem of this invention is to offer a manufacturing method of a container final stage drink which can maintain a flavor and flavor well without using a heat-resistant container and needing heat sterilization and cooling after sealing by enabling normal temperature filling which restrains the use of a medicine and sterile water and easing heat deterioration of a content. After the method of the present invention performs heat sterilization of the content to a predetermined sterilization value beforehand, the content is cooled to normal temperature rapidly, and accumulated in a storage tank sterilized on the condition more than equivalent to the condition of the heat sterilization of the content beforehand. By sending the content to a filler sterilized on the condition more than equivalent to the condition of the heat sterilization of the content beforehand while the storage tank is held by sterile gas at positive pressure, the system sending liquid from the storage tank to the filler is made into a closing liquid course without invasion of the air from the exterior, and normal temperature filling of the drink is carried out in the container sterilized with hot water in the environmental management air space isolated from the external world wherein the ambient surrounding is heat-sterilized and washed with hot water of 65-100 degrees celsius.

Description

200821256 九、發明說明: 【發明所屬之技術領域】 '容係關於—種容11裝飲料,㈣係容器裝茶飲料及 .备时衣齩性飲料等容器裝飲料之製造方法。 【先前技術】 例如PET瓶裝茶飲料等低酸性飲料、或摻有果汁 二:、:性飲料的容器裝飲料之製造方法,已知有熱裝填 舁無囷填充法。熱裝填法係例如當茶飲料等pH達4.6 =的低酸性飲料之情況,便施行12代、4分鐘同等級 的加熱殺菌,當pH在4·6以下的酸性飲料之情況, 勝%仃85 c、30分鐘同等級以上的加熱殺菌,再將内容 ^料液溫阶〜9代的狀態下,填充賴清洗過的容 f 、,藉此便利用内容物的熱施行容器的殺菌並密封。然 後,為執行容器頂部空間部或瓶蓋内面的殺菌,便在密封 刻將谷器倒轉’而使液體接觸到瓶蓋内面等處來施行 _二囷’執行所謂的「倒轉殺菌」同時藉由殺菌機將溫水朝 合-外周面噴射,經在7 5。〇下施行3分鐘加熱殺菌之後, 再/v部至常溫(其中一例,參照專利文獻工)。 &熱裝填法係將内容物長時間維持在6(rc以上的高溫狀 悲I因為在該狀態下進行填充的關係,因而會有内容物因 熱劣化而較早出現風味或香味劣化的大問題。另一方面, j谷為方面而言,因為在填充時處於與高溫飲料相接觸狀 =下,因而必需選用耐熱容器,例如ΡΈΤ瓶的情況便必需 施行耐熱處理,且因為在冷卻後容器内呈負壓,因而為能 πχρ__#(_/964ι/96ΐ26566 6 200821256 $保能承受負I的強度,必需形 :::r。再者’就設備方面而言,需要= 缺點。又機’因而有設置空間與設備成本增加的 溫水,導致有二:運成本方面而言’殺菌機需要大量的 蛉致有水置與能源成本龐大的缺點。 行:::==菌填充法係將在預先利用熱交換等手段施 门·旦寸Β木又菌後冷卻至常溫的 ,酸等藥劑施行殺菌,且在維持無菌環境中二工 ^充^利用無菌水施行清洗之不需耐熱性的容器中,並 二$因為該方法保證在完全無菌狀態下施行密封’ 主爷溫填充,仍可適用於諸如酸性飲料、茶之類, 肉毒桿菌等芽胞菌容易繁殖的摻有牛奶飲料之填充,r有 =物熱劣化較少的優點’但需要供施行容器殺菌用㈣ w处理^置與殺菌用藥劑,且需要供容器清洗用的清洗裝 置與大量無菌水等’導致實現該等步驟的裝置與潔淨室: 及f操控趨於龐大’而有設備成本與營運成本較為龐大的 問題。 所以,本發明者等針對解決上述習知熱裝填法與無菌填 =法之問題的方法,有提案將ρΗ4· 6以上、且兒茶素含有 畺30mg%以上的余飲料、或ρΗ未滿4.6的酸性飲料施行 加熱殺菌後,再維持於6〇°C〜70°C溫度下,另一方面,將 、ϋ为至夕内面利用6 5 C〜10 0 °C熱水施行加熱殺菌及清 洗,並在預先將填充及密封裝置與其周邊環境,利用防 c〜100 C熱水施行加熱殺菌且清洗之經與外界隔離的環 312XP/發明說明書(補件)/96·11/96126566 7 200821256 兄吕里二間中,將該飲料依填充溫度6(TC〜7(TC填充於該 =殺菌過的容器中,經密封後再冷卻纟40。。以下常溫的 新頭熱裝填法(參照專利文獻2)。 =為該方法並不需要填充及密封後的後殺菌步驟,因而 備的殺菌機’相較於習知熱裝填法,具有能 削減设備成本、瑩谨士、士 Q yu 扣A & 建烕本’且旎緩和容器減壓變形耐性相 關條件的優點,作在褒4 裝填法雖然較騎要冷卻㈣’相較於習知熱 …、,牙,可疋郃有因内容物熱劣化而造成風 h 降低,且無法避免容器減壓變形耐性之要求的問 題0 瓶裝 容器 (專利文獻1)日本專利㈣2()(π_278225號公報「 飲料之製造方法」2〇〇1年1Μ 10日公開 (專利文獻2)日本專利特開⑽6_69624號公報「 裝飲料之製造方法」2006年3月16日公開 【發明内容】 _ (發明所欲解決之問題) 為解决自知熱裝填法的上述缺點,更進—步降低殖充、, 土雖屬-種有效手段’但是若將内容物於殺菌後再冷卻: 則由於-般填充設備所使用的儲存槽至填充機間的 达液系統之接頭或襯墊部、送液泵等微細部分,盔法 有微生物污染的可能性,就從製品安全性的觀點而言^ 充溫度無法較上述提案更進一步降低。 /、 所以’本發明更進一步改善上述所提案的填充系統,苴 目的在於提供-種容器裝飲料之製造方法,其由能常温^ 312ΧΡ/發明說明書(補件)/96-11/96126566 q 200821256 緩和内容物的熱劣化情形,且可良好地維持風味愈香200821256 IX. Description of the invention: [Technical field to which the invention pertains] 'The system relates to the type 11 beverage, (4) the container-packed tea beverage, and the preparation method of the container-packed beverage such as the ready-to-wear beverage. [Prior Art] For example, a method for producing a low-acid beverage such as a PET bottled tea beverage or a container-packed beverage containing a juice 2:: a sexual beverage is known as a hot-filled 舁-free filling method. The hot filling method is for example, when a low-acid beverage with a pH of 4.6 = such as a tea beverage is used, the same level of heat sterilization is performed for 12 generations and 4 minutes, and when the pH is below 4. 6 for an acidic beverage, the percentage is 85. c. 30 minutes of heat sterilization at the same level or higher, and then filling the contents of the liquid to the ninth generation, and filling the container with the heat of the contents, thereby facilitating sterilization and sealing of the container by the heat of the contents. Then, in order to perform sterilization of the top space portion of the container or the inner surface of the bottle cap, the barn is inverted in the seal and the liquid is brought into contact with the inner surface of the cap or the like to perform the so-called "reverse sterilization". The sterilizer sprays warm water toward the combined-outer surface, passing through 75. After the heat is sterilized for 3 minutes under the armpit, the portion is further changed to the normal temperature (for example, refer to the patent document). & hot charging method maintains the content for a long time at 6 (the high temperature of rc or more, because of the relationship of filling in this state, there is a possibility that the content is deteriorated earlier due to thermal deterioration. On the other hand, in terms of the aspect, since it is in contact with the high-temperature beverage at the time of filling, it is necessary to use a heat-resistant container, for example, a heat-resistant treatment is required in the case of a bottle, and since the container is cooled Negative pressure inside, so it is πχρ__# (_/964ι/96ΐ26566 6 200821256 $ can withstand the strength of negative I, the required shape:::r. In addition, in terms of equipment, need = disadvantage. Therefore, there is warm water with increased installation space and equipment cost, resulting in two: in terms of transportation cost, 'the sterilizer needs a lot of defects, such as water and energy cost. Line:::== bacteria filling method will After pre-heating by means of heat exchange, etc., the bacteria are cooled to normal temperature, and the acid and the like are sterilized, and in the maintenance of the aseptic environment, the use of sterile water for cleaning does not require heat resistance. In the container And because of this method, it is guaranteed to be sealed under full sterility. The main warm filling can still be applied to the filling of milk beverages such as acidic beverages, tea, etc., which are easily propagated by botulinum such as botulinum. = the advantage of less heat deterioration - but it is necessary to perform sterilization of the container (4) w treatment and sterilization, and requires a cleaning device for washing the container and a large amount of sterile water, etc. There is a problem that the equipment cost and the operating cost are relatively large. Therefore, the inventors of the present invention have proposed a method for solving the above problems of the conventional hot charging method and the aseptic filling method. 6 or more, and the catechins contain 30 mg% or more of the remaining beverage, or the acidic beverage of ρΗ less than 4.6 is heat-sterilized, and then maintained at a temperature of 6 ° C to 70 ° C, on the other hand, For the inner eve of the day, use 6 5 C ~ 10 0 °C hot water for heat sterilization and cleaning, and in advance the filling and sealing device and its surrounding environment, using anti-c ~ 100 C hot water for heat sterilization and cleaning The isolated ring 312XP / invention manual (supplement) / 96 · 11 / 96126566 7 200821256 brother Lu Li two, the beverage according to the filling temperature 6 (TC ~ 7 (TC filled in the = sterilized container, After sealing, the crucible 40 is cooled. The following new hot-head filling method at room temperature (refer to Patent Document 2). = This method does not require a post-sterilization step after filling and sealing, so the prepared sterilization machine is compared with the habit The hot-filling method has the advantages of being able to reduce equipment costs, and the advantages of the 莹 士 士 士 士 士 士 士 士 旎 旎 旎 旎 旎 旎 旎 旎 旎 旎 旎 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器Cooling (4) 'There is a problem that the wind h is lowered due to the thermal deterioration of the contents, and the requirements for the pressure-reducing deformation resistance of the container cannot be avoided. (Bag Document 1) Patent (4) 2 () (Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 10-69624, "Method for Manufacturing Beverages", published on March 16, 2006. SUMMARY OF THE INVENTION _ (The problem to be solved by the invention) Solve the above-mentioned shortcomings of the self-conceived hot filling method, and further reduce the filling and filling, although the soil is an effective means 'but if the contents are sterilized and then cooled: then the storage tank used by the filling device is The fine portion such as the joint of the liquid-filled system of the filling machine, the pad portion, and the liquid feeding pump, and the helmet method may have microbial contamination, and the charging temperature cannot be further lowered from the viewpoint of product safety. /, Therefore, the present invention further improves the above-mentioned proposed filling system, and aims to provide a method for manufacturing a container-packed beverage, which can be used at room temperature 312 ΧΡ / invention specification (supplement) / 96-11/96126566 q 200821256 To alleviate the thermal deterioration of the contents, and to maintain the flavor more fragrant

Ci用繼器’亦不需要密封後的加熱殺菌與 〜 不而要如無菌填充法所使用的藥劑與盔菌水, 達到大幅設備成本與營運成本降低的充、: 所構成。 、凡山封糸統 、、再者’本發明之目的在於提供—種㈣裝飲料之製 法’其由能施行常溫填充,緩和内容物熱劣化情形 好地維持風味財味,不t要使料熱容g 2 ::的加熱殺菌與冷卻,且不需要大量使用如無 二使用的樂劑與無a水’可達到大幅設備成本與營運成本 牛低的新穎填充密封系統所構成。 (解決問題之手段) 為達成上述目的’本發明者等經深人鐵研與重複實驗, =果發現,將内容物的飲料限定於pH達4·6以上、、且兒 :素3有里3Gmg%以上的綠茶、烏龍茶等茶飲料,以及仙 t滿4·6的酸性飲料等經加熱後芽胞菌較難繁殖的飲料 =,則將内容物自加熱殺菌至填充為止的内容液送液路 =,在^經殺菌後的完全封閉空間内實施,且將容器與填充 =封%扰保持於經熱水殺菌且與外界隔離的潔淨環境 埶可不需要藉由藥劑對容器殺菌,内容物可在急速加 =後,再急速冷卻並施行常溫填充,遂完成本發明。 复即,達成上述目的之本發明容器裝飲料之製造方法, 24寸徵在於包括有:預先將對容器及瓶蓋施行殺菌清洗、 ,、充及密封的周邊環境,使用65°C〜100°C熱水或藥劑, 12xp/發明說明書(補件)/_醜126566 9 200821256The Ci repeater does not need to be heat-sterilized after sealing. ~ It is not necessary to use the medicinal agent and the Helmet water used in the aseptic filling method to achieve a significant reduction in equipment cost and operating cost.凡山封糸,和再者' The purpose of the present invention is to provide a method for producing (four) beverages, which can be filled at room temperature to alleviate the thermal deterioration of the contents to maintain the flavor and taste. The heat capacity g 2 :: heat sterilization and cooling, and does not require a large number of use of the use of the agent and no a water 'a new filling and sealing system that can achieve a large equipment cost and operating cost. (Means for Solving the Problem) In order to achieve the above object, the inventors of the present invention conducted a deep-seated research and repeated experiments, and found that the beverage of the content was limited to a pH of 4.6% or more, and the child: 3Gmg% or more of tea beverages such as green tea and oolong tea, and beverages that are more difficult to propagate after heating, such as acidic beverages such as scented 4.6, and the content liquid supply path from the heat sterilization to the filling =, implemented in a completely enclosed space after sterilization, and the container and the filling = sealing% are kept in a clean environment that is sterilized by hot water and isolated from the outside, and the container can be sterilized by the medicament, and the contents can be After the rapid addition of =, the mixture is rapidly cooled and subjected to room temperature filling, and the present invention is completed. In other words, in the method for manufacturing the packaged beverage of the present invention which achieves the above object, the 24-inch mark includes: pre-sterilizing the container and the cap, and filling and sealing the surrounding environment, using 65 ° C to 100 ° C hot water or medicine, 12xp / invention manual (supplement) / _ ugly 126566 9 200821256

杈囷先的步驟;對冷卻機、儲存槽及截至填 充棧為止的送液路徑’在所填充飲料之加熱殺菌條件同等 :以上的條件下,預先施行加熱殺菌及清洗的步驟;以及 ft器與瓶蓋至少内面,抑阶〜1()(^溫水施行加孰 的步驟;而將所填充的飲料施行加熱殺菌直到 :,疋权g值後,再急速冷卻至常溫,將該經冷卻的飲料 :子於上述儲存槽中’藉由將内容液送人於上述填充機 使上述送液路徑形成不會從外部滲人线的封閉路 t且开:成將上述周邊壤境與外界隔離的環境管理空間’ 並=管理空間中,將上述飲料於常溫下填充於上述殺菌 過容器中,並加以密封。 本案另一發明係就上述容器裝飲料之製造方法,其中, ^述飲料係ΡΗ4·6以上且兒茶素含有f 3()呢%以上的飲 料將技料依135 C、7· 58秒同等級以上的殺菌值施行 加熱殺菌。 再者,本案另一發明係就上述容器裝飲料之製造方法, 其中,上述飲料係pH未滿4· 6的酸性飲料;將該酸性飲 料依85 C、30分鐘同等級以上的殺菌值施行加熱殺菌。 制再者,本案另一發明係就上述任一記載的容器裝飲料之 衣w方法,其中,上述環境管理空間係收容於箱内的空間。 再者,本案另一發明,上述儲存槽係透過無菌氣體而保 持正壓,從該儲存槽往填充機的液體輸送係利用無菌氣體 施行壓送。 再者,本發明係就上述容器裝飲料之製造方法,其中, 312XP/發明說明書(補件)/96七/96126566 10 200821256 對周邊環境的藥劑使用後所施行之殺菌後的清洗,係使用 65°C〜100°C溫水,使其亦兼具殺菌功能。 ” 再者,本案再另一發明係就上述容器裝飲料之製造方 ^ ’其中,將對容ϋ與瓶蓋殺g清洗、填充及密封的周邊 裱境,預先施行殺菌及清洗的藥劑,係使用過醋酸系藥 劑、過氧化氫、臭氧系藥劑、含次氯酸的氯系殺菌劑中: (發明效果) 根據本發明的容H裝飲料之製造方法,可將諸如 =等酸,飲料、或摻有茶或牛奶飲料等,在無转容器、 =又備及%< & ’如無菌填充法般使用藥液施行殺菌、或利用 無菌水施行清洗等情況下,便能進行常溫填充,可減少如 ^填法般因内容物熱劣化而造成香味降低的情形,可# 得如無菌填充法般良好的容器裝飲料。同時,相較於無^ 填充法,設備較為簡易,且未使用藥液,因 降低 設備成本與營運成本,同時可達以低 丁 J運衣k生產線的效率化與高 :门。,因為容器亦無需要求耐熱性與減壓變形耐 性,因而可達容器薄壁化,亦可降低容器成本。更進一步: 因為不需要密封後的後殺菌與冷 法’設備較為簡單化,且不需要大量溫水,可 =營運成本’同時可達生產線的高速化二= 可達生產線的效率化、省空t驟、裝相步驟等,因而The first step; the liquid supply path to the cooler, the storage tank, and the filling stack is equal to the heat sterilization conditions of the filled beverage: the above steps are performed, the steps of heat sterilization and cleaning are performed in advance; and the ft device and the The cap is at least inside, and the step is ~1 () (the step of applying warm water to the twisting; and the filled beverage is heat-sterilized until: after the weight of g, the cooling is rapidly cooled to normal temperature, and the cooled Beverage: in the storage tank, 'by sending the content liquid to the filling machine, the liquid supply path is formed into a closed road t that does not infiltrate the outside from the outside: and is opened to isolate the surrounding soil from the outside. In the environmental management space, and in the management space, the beverage is filled in the sterilized container at a normal temperature and sealed. Another invention of the present invention relates to a method for producing the above-mentioned container-packed beverage, wherein the beverage system is described. 6 or more and catechins containing more than f 3 ()% of the beverages are heat-sterilized according to the sterilization value of 135 C, 7.58 seconds of the same grade or higher. Further, another invention of the present invention is to pack the beverages in the above container. System The method wherein the beverage is an acidic beverage having a pH less than 4.6; the acidic beverage is heat-sterilized according to a sterilization value of 85 C for 30 minutes or more. Further, another invention of the present invention is any of the above In the above-described environment for storing a beverage, the environmental management space is housed in a space inside the case. In another aspect of the invention, the storage tank is maintained in a positive pressure by a sterile gas, and is filled from the storage tank. The liquid transporting system of the machine is carried out by using a sterile gas. Further, the present invention relates to a method for producing a beverage in the above-mentioned container, wherein the 312XP/invention specification (supplement)/96 7/96126566 10 200821256 is used for the surrounding environment. After the sterilization after the sterilization, the use of 65 ° C ~ 100 ° C warm water, it also has a sterilization function." Furthermore, another invention in this case is the manufacture of the above-mentioned containered beverage ^ ' The agent that pre-sterilizes and cleans the surrounding environment for the cleaning, filling and sealing of the bottle and the cap, and uses the acetic acid-based agent, hydrogen peroxide, ozone-based agent, and hypochlorite. In the chlorine-based bactericide: (Effect of the invention) According to the method for producing a beverage containing H, the acid such as =, beverage, or tea or milk beverage can be used in a non-return container, %<& 'When sterilizing with a chemical solution or aseptic washing with a sterile filling method, it can be filled at room temperature, which can reduce the decrease in flavor due to thermal deterioration of the contents as in the filling method. In this case, it is possible to obtain a container-packed beverage that is as good as the aseptic filling method. At the same time, compared with the no-filling method, the equipment is relatively simple, and the liquid medicine is not used, because the equipment cost and operating cost are reduced, and at the same time, it can be lowered. The efficiency and highness of the J-clothing k production line: the door. Because the container does not require heat resistance and decompression deformation resistance, the container can be thinned and the container cost can be reduced. Further: Because there is no need for post-sealing sterilization and cold method, the equipment is simpler and does not require a large amount of warm water, and the operating cost can be increased to the speed of the production line. t, phase loading steps, etc., thus

根據對周邊環玲r彳Φ H 兄使用樂劑施行加熱殺菌及清洗的本發 312XP/發明說明書(補件)抓u顧跖施 11 200821256 =^裝飲料之製造方法,就諸如果汁飲料酸性飲料、 茶或牛奶飲料等而言,藥劑的使關限定直 =對容器清洗、填充及密封的周邊環境之殺8及清洗ΐ 已,因而將不需要如無菌填充法般的大量藥液‘ 囷水專,便可施行常溫填充,可減少如熱裝殖法 ^、 香味降低情形,可獲得如無菌填充: 少置樂劑與清洗液便可,因此可依小規模設備完成,S 2要密封後的後殺菌與冷卻,因而相較於熱裝填法,可 叹備間I化,並達大幅降低設備成本與營運成本。 ”本發明的容器裝飲料之製造方法,除上述效果之 :料二飲:係ΡΗ4.6以上、且兒茶素含有量30响以上的 ^將該飲料依13517,秒同等級以上的殺菌值 也仃加熱殺菌’在殺菌後便急速冷卻至常溫,因而將可緩 和熱劣化’可維㈣味。而且,ΡΗ4.6以、且兒茶素含 以上的茶飲料,因為經填充密封後的環境係屬 ^牙胞囷無法生存的環境,因而在對容器施行飲料填充 别’就利用溫水施行殺菌及清洗,便可在填充後不再需要 透過殺菌機施行殺菌。 根據本發明的容器裝飲料之製造方法,除上述發明的效 果之外,當上述飲料係pH未滿4·6的酸性飲料時,對咳 酸性飲料依啊、30分鐘同等級以上的殺菌值施行加孰 殺菌’便可防止密封後的細菌繁殖,且因為經加熱殺菌後 便急速冷卻,㈣可防止風味與成分出現劣化情形,並在 312ΧΡ/發明說明書(補件)/96-11/96126566 12 200821256 對谷#施行飲料填充前,就利用溫水施行殺菌及清洗,因 而在填充後不再需要透過殺菌機施行殺菌 根據本發明的容器裝飲料之製造方法,藉由將執行容器 熱水殺菌、内容物填充、容器密封的環境管理空間,設定 為收容於箱内的空間,便可將該空間與外部隔離,可防止 遭受外部環境的污染。According to the local 312XP/invention manual (supplement) for the heat sterilization and cleaning of the surrounding ring 彳 彳 彳 H H H 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 For tea, milk drinks, etc., the restriction of the drug is limited to the surrounding environment of the container cleaning, filling and sealing, and the cleaning solution is not required, so a large amount of liquid medicine such as aseptic filling method is not required. Specially, it can be filled at room temperature, which can reduce the hot filling method, and the fragrance can be reduced. For example, aseptic filling can be obtained: less agent and cleaning solution can be used, so it can be completed according to small-scale equipment, and S 2 should be sealed. After the sterilization and cooling, compared with the hot filling method, it can be sighed, and the equipment cost and operating cost are greatly reduced. The method for producing a packaged beverage according to the present invention has the above-mentioned effects: two drinks: ΡΗ 4.6 or more, and the catechin content is 30 or more. The bactericidal value of the beverage is 13517 or more. Also, the heat sterilization "slowly cools to room temperature after sterilization, so that it can alleviate the thermal deterioration of the 'weiwei (four) taste. Moreover, the tea beverage containing ΡΗ 4.6 and the catechins, because of the sealed and sealed environment It is an environment in which the dental plaque cannot survive, so that the beverage can be sterilized and cleaned by applying warm water to the container, so that it is no longer necessary to perform sterilization through the sterilizer after filling. The containerized beverage according to the present invention In addition to the effects of the above-described invention, when the beverage is an acidic beverage having a pH of less than 4·6, it is possible to prevent the sterilizing value of the cough acidic beverage from being 30 minutes or more. The sealed bacteria multiply, and because of the rapid cooling after heat sterilization, (4) can prevent the deterioration of flavor and composition, and in the 312 ΧΡ / invention manual (supplement) / 96-11/96126566 12 200821256 Before the beverage is filled, the sterilization and cleaning are performed by using warm water, so that it is no longer necessary to perform sterilization by the sterilizer after filling, and the method for manufacturing the packaged beverage according to the present invention is to perform hot water sterilization, content filling, and The environmental management space sealed by the container is set to be accommodated in the space inside the box, and the space can be isolated from the outside to prevent contamination from the external environment.

再者,根據本發明的容器裝飲料之製造方法,除具上述 效果,外,從上述儲存槽朝填充機利用無菌氣體進行壓 达,藉此便可在不使用微細部分較難殺菌的泵之情況下, 進行液體輸送,便可輕易地達到液體輸送機構的無菌化, 同時可防止路徑内因正壓化而造成外界氣體進人的情形 發生,不致有飲料會因外界氣體而遭受污染之虞。 根據本發明$同的容器裝飲料之製造方法,除具上述效 果之外纟使用藥劑殺菌後的周邊環境之清洗方面,當使 用阶〜10代溫水時,溫水亦具有殺菌功能,由此例如 騎無菌填充時,便可降低藥劑溫度使用。結果,可抑制 :劑T解:形’增加再利用的次數,同時可降低對機器造 :的ί月开/且’對具耐熱性芽胞菌亦可提升殺菌效果。 本發月的&明係利用指定藥劑,將對容器與瓶蓋 ^國填充及密封的周邊環境,預先施行殺菌及清 洗,因而可更確實地提升殺菌效果。 【實施方式】 以下參照所附圖式,斜 針對本發明實施形態進行說明。 本發明所適用的飲料係 係PH4.6以上、且兒茶素含有量 312^^/發明說明書(補件)/96·11/96126566 13 200821256 3 0 mg %以上的綠茶、烏龍茶等飲料,或ρ Η未滿4. 6的酸性 飫料。上述酸性飲料係包括:天然果汁、果汁飲料、果肉 •飫料、摻有果汁清涼飲料、摻有果粒水果飲料、檸檬茶、 運動飲料等。 再者、’本_發明方法所使用的容器係除PET瓶等聚酯瓶之 :尚涵盍諸如:聚酯製杯、托盤等聚酯容器在内的塑膠 合裔玻埚瓶、金屬瓶、罐頭等。本發明緩和PET瓶的減 壓耐性相關條件並達薄壁化的觀點下,尤其較佳適用於 PET瓶裝的上述飲料製造。 本發明實施形態的容器錢料之製造方法中,將内容物 2飲料利用s溫短時間殺菌法施行加熱殺菌,㈣既定殺 菌值為止,然後,馬上急速冷卻至常溫〇5它~4〇。〇後, 便儲存於預先依照上述飲料施行加_菌條㈣同等級 以上條件,施行殺菌、清洗過的儲存槽中。本發明中,諸 如上述儲存槽等所有設備,至少就液體接觸面的部分,預 Φ先利用蒸氣或熱水,依照内容物的飲料之殺菌值同等級以 士的殺菌值,施行加熱殺菌,且,對容器至少内面與及容 器施行殺菌清洗、填充、密封的空間環境、及設備外面, 利用65。(:〜lGGt:熱水施行加熱殺g及清洗,並形成該空 *間環境與外界隔離的管理空間。然後,將上述經冷卻飲二 -儲存於上述儲存槽中,在將該儲存槽利用無菌氣體保持正 壓的情況下,藉由將内容液輸送給上述填充機,便可將上 述送液路徑形成不會從外部滲入空氣的封閉液路徑,且在 與外界隔離並經殺菌過的環境管理空間中,將上述食^料於 312XP/發明說明書(補件)/96-11/96126566 14 200821256 吊/m下填充於上述經殺菌過的容器中,並將容器密封。經 山封後,不需要冷卻與加熱,可在此狀態下直接進行檢查 與裝箱步驟。 一 、當内f物的飲料係ΡΗ4·6以上、且兒茶素含有量30mg% 以j的余飲料時,便對該茶飲料依能獲得135°C、7· 58秒 同等級以上之殺菌值的方式,#用高溫短時間殺菌法等方 法施订加熱殺菌。本發明者針對兒茶素含有量 ⑩15mg%〜50mg%的飲料,調查兒茶素對各種微生物所產生的 ,菌仙。結果如表丨所示。表中,「〇」係有確認到抗 菌作用,△」係依菌種,有確認到具抗菌作用、與未具 有抗菌作用,「X」係未確認到抗菌作用。 [表1]Further, according to the method for producing a packaged beverage of the present invention, in addition to the above-described effects, it is pressed from the storage tank toward the filling machine by a sterile gas, whereby the pump which is difficult to sterilize without using a fine portion can be used. In the case of liquid transportation, the sterility of the liquid transport mechanism can be easily achieved, and at the same time, the situation in which the external gas enters due to the positive pressure in the path can be prevented, and the beverage will not be contaminated by the external gas. According to the method for producing a container-packed beverage of the present invention, in addition to the above-described effects, in the cleaning of the surrounding environment after the sterilization of the medicament, the warm water also has a sterilization function when the temperature is used in the order of 10 to 10 generations. For example, when riding a sterile filling, the temperature of the medicament can be lowered. As a result, it is possible to suppress the agent T solution: the shape 'increased the number of reuses, and at the same time, it is possible to reduce the sterilizing effect on the machine-made bacterium. In the present month, the sterilizing effect can be more reliably enhanced by pre-sterilizing and cleaning the surrounding environment in which the container and the cap are filled and sealed by the designated medicinal agent. [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. The beverage system to which the present invention is applied is PH 4.6 or higher, and the catechin content is 312 ^ ^ / invention specification (supplement) / 96 · 11 / 96126566 13 200821256 3 0 mg % or more of green tea, oolong tea, etc., or的 Η Η 4 4 饫 饫 饫 饫. The above acidic beverages include natural juices, fruit juice drinks, pulps, clams, fruit juice refreshing drinks, fruit fruit drinks, lemon tea, sports drinks, and the like. Furthermore, the container used in the method of the present invention is a polyester bottle such as a PET bottle, such as a polyester bottle such as a polyester cup or a tray, and a metal bottle. Canned food, etc. The present invention is particularly suitable for the above-mentioned beverage production of PET bottles, from the viewpoint of alleviating the pressure-resistant resistance conditions of PET bottles and achieving thinning. In the method for producing a container material according to the embodiment of the present invention, the content 2 beverage is subjected to heat sterilization by the s warm-time sterilization method, (4) the predetermined bactericidal value, and then rapidly cooled to a normal temperature 〇5 to 4 〇. After that, it is stored in a storage tank that has been sterilized and cleaned in advance according to the conditions of the above-mentioned beverages. In the present invention, all the equipment such as the above storage tank, at least the portion of the liquid contact surface, pre-Φ first uses steam or hot water, according to the sterilization value of the content of the beverage, the sterilization value of the same level, the heat sterilization, and Use 65 for the space environment where the inner surface of the container and the container are sterilized, cleaned, filled, sealed, and outside the device. (:~lGGt: The hot water is heated to kill and clean, and forms a management space that is isolated from the outside environment. Then, the cooled drink II is stored in the storage tank, and the storage tank is utilized. When the sterile gas is maintained at a positive pressure, by feeding the content liquid to the filling machine, the liquid supply path can be formed into a closed liquid path that does not infiltrate air from the outside, and is isolated from the outside and sterilized. In the management space, the above-mentioned food is filled in the above-mentioned sterilized container under the 312XP/invention manual (supplement)/96-11/96126566 14 200821256 hang/m, and the container is sealed. After the mountain seal, There is no need for cooling and heating, and the inspection and packing steps can be directly performed in this state. 1. When the beverage of the internal material is more than 4·6 and the catechin content is 30 mg%, the remaining beverage is The tea beverage can be obtained by a method of obtaining a bactericidal value of 135 ° C or 7.58 seconds of the same level or higher, and # heat sterilization by a method such as a high-temperature short-time sterilization method. The present inventors have a catechin content of 1015 mg% to 50 mg. % of drinks, investigating catechins The results are shown in Table 。. The results are shown in the table. In the table, "〇" is confirmed to have an antibacterial effect, and △" is based on the strain, and it has been confirmed to have an antibacterial effect and has no antibacterial effect. X" was not confirmed to have an antibacterial effect. [Table 1]

------JX X x 如表1所不,當兒茶素含有量27mg%之茶飲料的情況, 雖,認到對大部分的芽胞菌具有抗g作用,但是對部分芽 ,菌的抗菌效果則較少。由此種結果得知,本發明中相關 茶,料,就安全性而言,係以兒茶素含有量達3Gmg%以上 的^飲料為對象。另外,對部分無芽胞菌、及霉菌與酵母, 兒茶素並無具抗菌作用’該等細菌以低溫加熱便可殺菌。 如上述,t兒茶素含有量彡30mgUxjl的茶飲料之情況, 312XP/發明說明書(補件)/96-11/96126566 15 200821256 因為對牙胞囷顯不出抗囷效果,因而即使茶飲料仍無腐敗 的顧慮。此外,當上述飲料係pH未滿4· 6的酸性飲料之 情況,便對該飲料依8 5 °C、3 0分鐘加熱同等級以上的殺 囷政果’施4亍1¾溫短時間加熱殺菌。 以下的代表例係就在PET瓶中填充該等飲料的情況,參 如圖1所示製造生產線示意圖、及圖2所示流程圖進行說 明。 " 圖1所示本實施形態容器裝飲料之製造生產線中,瓶殺 2及清洗裝置10、填充機u、封蓋機12、及瓶蓋殺菌及 清洗裝置(未圖示),係設置於形成環境管理空間14的潔 淨箱15内。另外,本說明書中,所謂「環境管理空間^ 係指預先將填充及密封裝置與其周邊環境,利用65t~l⑽ C熱水施行加熱殺菌並清洗後與外界隔離的空間,對内邱 將供應無菌空氣,對外部則呈正壓化,形成外界氣體不; 輕易流入狀態。周邊環境的殺菌及清洗係在容器裝飲料紫 ❿造開始之前便實施,如圖!所示,在潔淨箱15内適當地 酉:置固定的熱水喷射喷嘴17,俾朝向旋轉式熱 ° ^容器殺菌及清洗裝践、填充機U、及封蓋機12 與谷器接觸的部分,隼中式哈 .芬、主、土七、+ 木干式贺射出熱水。周邊環境的殺菌 Π了法可以適當採用例如上述專利文獻2所示方 法’在此省略詳細說明。 本實施形態中,從環境管理介 ^ ^ ^ ^ . 二間外的瓶供應裝置,移送 至裱境官理空間14内的祢靳衿n ^ ft展m 圆及清洗裝置中之瓶的殺 囷’係至少對瓶内面(最好 野円外面)利用65t:〜100°C熱水 312XP/發明說明書(補件)/96七/96126566 16 200821256 施行加熱殺菌。殺ϋ時間係3秒至1()秒。根據 因為利用熱水同時施行瓶殺菌與殺’ 後的瓶便不需要再另外施行清洗的步驟。二,因同:殺: 從壤境管理空間外的瓶蓋供應裝置,朝管理空間内所’ 的瓶盍殺®及清洗裝置供應瓶蓋,並藉由對瓶蓋的内^面 贺射出65C〜100C熱水而施行加熱殺菌。------JX X x As shown in Table 1, when the catechin content is 27mg% of the tea beverage, although it is recognized that it has anti-g effect on most of the spores, it is partial to the bud. The antibacterial effect is less. As a result of the above, it is known that the tea and the material in the present invention are in the form of a beverage having a catechin content of 3 Gmg% or more. In addition, there is no antibacterial effect on some of the non-Cytobacteria, mold and yeast, and catechins. These bacteria can be sterilized by heating at a low temperature. As described above, the case of tea beverage containing t catechin in an amount of mg30 mg Uxjl, 312XP/invention specification (supplement)/96-11/96126566 15 200821256 because even the tea beverage is still not resistant to sputum No corruption concerns. In addition, when the beverage is in the form of an acidic beverage having a pH of less than 4.6, the beverage is heated at 85 ° C for 30 minutes, and the succulent fruit of the same grade or more is heated and sterilized for a short period of time. . The following representative examples are for filling the PET bottles with the beverages, as shown in the schematic diagram of the production line shown in Fig. 1, and the flow chart shown in Fig. 2. " In the manufacturing line of the packaged beverage of the present embodiment shown in Fig. 1, the bottle 2 and the cleaning device 10, the filling machine u, the capping machine 12, and the cap sterilization and cleaning device (not shown) are provided in The clean room 15 of the environmental management space 14 is formed. In addition, in this specification, the "environmental management space" refers to a space in which the filling and sealing device and its surrounding environment are heat-sterilized by 65t~l(10) C hot water and cleaned, and then isolated from the outside. It is positively pressurized to the outside, and the outside air is not formed; it is easy to flow into the state. The sterilization and cleaning of the surrounding environment is carried out before the start of the container-packed beverage purple enamel, as shown in the figure! : fixed hot water jet nozzle 17, 俾 旋转 旋转 旋转 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 容器 、 、 、 、 、 、 填充 填充 填充 填充 填充 填充 填充 填充 填充 填充 填充 填充 填充 哈 哈In addition, the method of the above-mentioned method of the above-mentioned Patent Document 2 can be appropriately employed, and the detailed description will be omitted here. In the present embodiment, the environmental management is based on ^^^. The external bottle supply device is transferred to the 祢靳衿n ^ ft exhibition m circle in the 官境官理空间 14 and the killing of the bottle in the cleaning device is at least 65t inside the bottle surface (best outside the picnic) :~100° C hot water 312XP / invention manual (supplement) / 96 seven / 96126566 16 200821256 The implementation of heat sterilization. Killing time is 3 seconds to 1 () seconds. According to the use of hot water while performing bottle sterilization and killing after the bottle There is no need to perform another cleaning step. Second, the same: Kill: Supply the cap from the bottle cap supply outside the management space to the bottle and the cleaning device in the management space. The inner surface of the cap is sprayed with 65C~100C hot water for heat sterilization.

另一方面,内容液的飲料係如圖丨所示,利用在潔淨箱 外所5又置的调合槽2 〇進行調合,並儲存於均衡槽2 1中, 再由此處供應給高溫短時間殺菌器22及急速冷卻器23, 以施行面溫短時間殺菌與急速冷卻。高溫短時間殺菌係利 利用熱水騎的瓶㈣面㈣,係可例如利用 置將瓶配置呈倒立狀態,再從熱水嘴霧噴嘴噴射出執水= 貫施。同樣的,利用熱水對槪蓋内外面殺菌,係可例 在由金屬絲形成的滑槽中移動的瓶蓋、或利用轉盤對開口 部朝下方進行移動的瓶蓋,從熱水噴霧噴嘴將其内外面喷 射熱水來實施。經殺菌清洗完成的瓶,便供應給殖充機 11二由填充機施行飲料的填充。此外,瓶蓋係分別供應給 封蓋機12,對已填充飲料的瓶施行蓋瓶,將瓶施行密封。On the other hand, the beverage of the content liquid is blended by the mixing tank 2 又 which is placed outside the clean box, and stored in the equalization tank 2 1 , and then supplied to the high temperature short. The time sterilizer 22 and the rapid cooler 23 perform short-time sterilization and rapid cooling of the surface temperature. High-temperature short-time sterilization is the use of hot water riding bottle (four) surface (four), for example, the bottle can be placed in an inverted state, and then sprayed from the hot water nozzle nozzle. Similarly, the inner and outer sides of the lid are sterilized by hot water, and the bottle cap that moves in the chute formed of the wire or the cap that moves the opening toward the lower side by the turntable is used from the hot water spray nozzle. The inside and outside are sprayed with hot water for implementation. The bottle that has been sterilized and cleaned is supplied to the filling machine. The filling of the beverage is performed by the filling machine. Further, the caps are supplied to the capping machine 12, respectively, and the caps of the filled beverages are bottled and the bottles are sealed.

用HTST殺菌法等方法施行加熱殺菌,本實施形態中,如 ‘述,當上述飲料係ρΗ4. 6以上、且兒茶素含有量3〇mg% 以上的茶飲料之情況,為了獲得135它、7·58秒同等級以 上的殺菌值,而施行高溫短時間殺菌。此外,當上述飲料 係pH未滿4.6的酸性飲料之情況,便對該飲料例如依 93〜95°C施行短時間加熱殺菌,以獲得85。〇、3〇分鐘同等 312XP/發明說明書(補件)/96-11/96126566 17 200821256 級以上的殺菌值。In the case of the tea beverage having the above-mentioned beverages of ρΗ4.6 or more and catechins of 3〇mg% or more, in order to obtain 135, 7.58 seconds of sterilization value of the same level or higher, and high temperature and short time sterilization. Further, when the above-mentioned beverage is an acidic beverage having a pH of less than 4.6, the beverage is subjected to heat sterilization for a short period of time, for example, at 93 to 95 ° C to obtain 85. 〇, 3〇 minutes equivalent 312XP / invention manual (supplement) / 96-11/96126566 17 sterilization value above 200821256.

;:郃係藉由使已施行高溫短時間殺菌過的飲料,接 :通過急速冷卻器23’而在通過的期間與冷媒進行敎交 !二紐,内便冷卻至常溫者,常溫係設定為約35t: 。乂口田’但隨飲料種類與季節等因素而異,則可採用U;: The 郃 郃 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉 藉About 35t: .乂口田' but depending on factors such as the type of drink and the season, U can be used

範ϋ。㈣速冷卻的飲錢儲存於由無菌槽構成 25中。該儲存槽25、上述急速冷卻器23、後述 :截:二、填充機u、及其所連接的配管等所有的液體接 ’句預先依能獲得所填充飲料的殺菌條件同等級以上 用洛氣或熱水施行殺菌清洗,而形成無菌化封閉路徑。尤 其儲存槽25利用無菌氣體保持正壓狀態’俾防止外界氣 體進入,且將所儲存的飲料透過無菌氣體之壓送自該儲存 槽經♦由頂槽26而運送飲料至充填機。藉由此方式,便可 不必错由在構造上較難完全殺菌與密封,且較難無菌化的 ^來進行液體輸送,即使飲料在常溫下仍能維持無菌狀 ^。頂槽26亦形成完全密閉型,在該頂槽26中所儲存的 飲料係利用無菌氣體的壓送,而輸送給填充機,並在無菌 化環境管理空間中填充於瓶中。 已填充飲料的瓶便從填充機中移送於在環境管理空間 内所設置的封蓋機12,並利用從在環境管理空間外所配 ^的瓶蓋供應裝置,朝在環境管理空間内所配置的瓶蓋殺 菌及清洗裝置供應,且於瓶蓋殺菌及清洗裝置中,以與瓶 為相同條件來施行殺菌及清洗的瓶蓋,進行完全密封。然 3l2XP/發明說明書(補件)/9641/96126566 18 200821256 後,經密封的瓶不需要如習知熱裝填法般,於通過殺菌機 與冷卻器之後,需要施行後殺菌步驟與冷卻步驟等後處 理,可直接進行製品檢查步驟、裝箱步驟等。 圖3所示係針對環境管理空間的潔淨箱内,使用藥劑施 行本發明殺菌/清洗方法的說明圖,圖4所示係本發明容 器裝飲料之製造方法的流程圖。本發明另一實施形態的容 器裝飲料之製造方法,係依照圖4所示流程圖的步驟實 行。圖中,黑色三角箭頭係指生產線上的流向,而普通的 ® 箭頭係指處理。本發明實施形態的容器裝飲料之製造方 法,在將内容物的飲料依高溫短時間殺菌法施行加熱殺 菌,直到既定殺菌值,然後,經馬上急速冷卻至常溫(15 〜40\:)後,便儲存於儲存槽中的生產線1,及將飲料填 充及密封於瓶中的生產線2之運轉前,便預先施行圖4中 由單點鍵線所圍繞的殺菌及清洗處理。該事前處理係就急 速冷卻器23、該儲存槽25、及頂槽26,依照上述飲料加 φ 熱殺菌條件的同等級以上條件,利用蒸氣或熱水施行殺 菌、清洗,而將執行容器殺菌清洗、填充及密封的空間環 境形成為與外界隔離的管理空間,就該空間在施行飲料填 充之前,使用藥劑施行殺菌及清洗。此外,針對容器與瓶 ~ 蓋亦是至少内面利用65°C〜100°C熱水施行加熱殺菌及清 * 洗之後才使用。然後,將上述經冷卻過的飲料儲存於上述 儲存槽中,在將該儲存槽利用無菌氣體保持於正壓的情況 下,藉由將内容液輸送至上述填充機,便使上述送液路徑 形成不會從外部滲入空氣的封閉液路徑(圖4中,虛線所 312XP/發明說明書(補件)/96-11/96126566 19 200821256 包圍的區域),並在上述與外界隔離且殺菌完成的環境管 理空間中,將上述飲料於常溫下填充於上述殺菌完成的容 裔中,亚將容器密封。經密封後,不需要冷卻與加熱,可 ‘在此狀態下便直接移往檢查及裝箱步驟。 針對在環境管理空間14的潔淨箱15内,使用藥劑施行 的本發明殺菌及清洗方法,利用圖3所示系統圖進行說 明。圖中,το件符號丨係藥劑槽,元件符號2係溫水槽, 兀件符號3係排水槽,元件符號4、5及6係流路切換用 閥,7係藥劑供應管,8係溫水供應管。首先,將切換閥 4、5及6安裝成圖示狀態。藥劑係在從藥劑槽丨加壓供 應之後,便通過供應管7,送達潔淨箱15内的各旋轉式 喷射喷嘴16與固定喷射喷嘴丨7,並朝潔淨箱i 5内施行 喷射。透過所喷射出藥劑的作用便對環境管理空間14施 行殺菌,所噴射出的藥劑流至室内的地板部,並從排出管 流放出,此時的切換閥5處於圖示狀態,因此便朝圖中右 馨侧流動。在右側設置有排水槽3,因為開閉閥6如圖示, 處於與排水槽3阻斷的狀態,因而藥劑回流於藥劑槽工 中。所使用的藥劑便不致僅使用單次便丟棄,可在能保證 其殺菌功能的期間内重複使用。另外,因為藥品的酸性較 .強,因而在使用後的廢液處理時,將需要施行還原處理或 ^ pH處理。 在殺菌處理結束時,切換閥4切換成為與藥劑供應管7 阻斷,並連通於溫水供應管8,且切換閥6被設置成連通 於排水扎3的狀態。然後,這次從溫水槽2中,將溫水經 312灣明說明書(補件)抓11/9612祕 2〇 200821256 由溫水供應管8而到達潔淨箱 16、及固糊嘴嘴17,而;==轉输嘴嘴 出的溫水便將潔淨箱! 5内所殘留相\5 _射。所喷射 洗時所制的溫水崎清洗,在清 出,因為此時的切換閥5將處 ^而從排出管中流 右侧流動。此時,因為切換門fi ’因而將朝圖中 水样3…广 與藥劑槽1阻斷,並與排 ^ 3 4通狀悲’因㈣清洗處理水便流人排水槽3Fan Wei. (4) The fast-cooled drinking money is stored in a sterile tank. The storage tank 25, the rapid cooler 23, and the following: the liquid interception: the filling machine u, the piping connected thereto, and the like, all of the liquids are connected in advance to obtain the sterilization condition of the filled beverage. Or hot water is sterilized and cleaned to form a sterile closed path. In particular, the storage tank 25 maintains a positive pressure state by means of a sterile gas 俾 to prevent the entry of outside air, and the stored beverage is sent from the storage tank through the pressure of the sterile gas to transport the beverage from the top tank 26 to the filling machine. In this way, it is possible to carry out liquid transport without erroneously sterilizing and sealing, and it is difficult to sterilize, even if the beverage maintains sterility at normal temperature. The top tank 26 is also formed in a completely sealed type, and the beverage stored in the top tank 26 is delivered to the filling machine by pressurization of the sterile gas and filled in the bottle in the sterilizing environment management space. The bottle filled with the beverage is transferred from the filling machine to the capping machine 12 provided in the environmental management space, and is configured in the environmental management space by using the cap supply device disposed outside the environmental management space. The bottle cap sterilization and cleaning device is supplied, and in the cap sterilization and cleaning device, the bottle cap which is sterilized and cleaned under the same conditions as the bottle is completely sealed. However, after the 3l2XP/invention manual (supplement)/9641/96126566 18 200821256, the sealed bottle does not need to be subjected to a post-sterilization step and a cooling step after passing through the sterilizer and the cooler as in the conventional hot filling method. The product inspection step, the packing step, and the like can be directly performed. Fig. 3 is an explanatory view showing a sterilization/cleaning method of the present invention using a pharmaceutical agent in a clean box for an environmental management space, and Fig. 4 is a flow chart showing a method of manufacturing the container-packed beverage of the present invention. A method of manufacturing a container-packed beverage according to another embodiment of the present invention is carried out in accordance with the steps of the flow chart shown in Fig. 4. In the figure, the black triangle arrow refers to the flow direction on the production line, while the normal ® arrow refers to the processing. In the method for producing a packaged beverage according to the embodiment of the present invention, the beverage of the content is heat-sterilized by a high-temperature short-time sterilization method until a predetermined sterilization value, and then immediately cooled to a normal temperature (15 to 40%:). Before the operation of the production line 1 stored in the storage tank and the production line 2 for filling and sealing the beverage in the bottle, the sterilization and cleaning treatment surrounded by the single-point key line in Fig. 4 is performed in advance. In the pre-treatment, the rapid cooling device 23, the storage tank 25, and the top tank 26 are sterilized and cleaned by steam or hot water according to the conditions of the above-mentioned beverage plus φ heat sterilization conditions. The filled, sealed space environment is formed as a management space that is isolated from the outside world, and the space is sterilized and cleaned using the medicament before the beverage is filled. In addition, the container and the bottle-cover are also used after at least the inner surface is heated and sterilized by hot water of 65 ° C to 100 ° C. Then, the cooled beverage is stored in the storage tank, and when the storage tank is maintained at a positive pressure by a sterile gas, the liquid supply path is formed by conveying the content liquid to the filling machine. The closed liquid path that does not infiltrate the air from the outside (in Figure 4, the area enclosed by the dotted line 312XP / invention manual (supplement) / 96-11/96126566 19 200821256), and the above-mentioned environmental management that is isolated from the outside and sterilized In the space, the beverage is filled in the above-mentioned sterilized living body at a normal temperature, and the container is sealed. After sealing, no cooling or heating is required, and ‘in this state, it is directly moved to the inspection and packing step. The sterilization and cleaning method of the present invention which is carried out using a chemical in the clean box 15 of the environmental management space 14 will be described using the system diagram shown in Fig. 3. In the figure, the symbol τ is a medicinal tank, the symbol 2 is a warm water tank, the 符号 symbol 3 is a drain groove, the component symbols 4, 5 and 6 are flow path switching valves, the 7 series drug supply pipe, and the 8 series warm water. Supply pipe. First, the switching valves 4, 5, and 6 are mounted in the illustrated state. After being supplied from the chemical tank, the chemical system is supplied to the rotary spray nozzles 16 and the fixed spray nozzles 7 in the clean tank 15 through the supply pipe 7, and is sprayed into the clean tank i5. The environmental management space 14 is sterilized by the action of the ejected medicine, and the ejected medicine flows to the floor portion of the room and is discharged from the discharge tube. At this time, the switching valve 5 is in the illustrated state, so The middle right side flows sideways. The drain tank 3 is provided on the right side, and since the opening and closing valve 6 is in a state of being blocked from the drain tank 3 as shown, the medicine is returned to the tank. The agent to be used is not discarded in a single use, and can be reused during the period in which the sterilization function can be ensured. In addition, since the acidity of the drug is relatively strong, it is necessary to carry out a reduction treatment or a pH treatment at the time of the waste liquid treatment after use. At the end of the sterilization process, the switching valve 4 is switched to be blocked from the drug supply tube 7, and is connected to the warm water supply pipe 8, and the switching valve 6 is provided in a state of being connected to the drain line 3. Then, this time from the warm water tank 2, the warm water through the 312 Bay Ming manual (supplement) grab 11/9612 secret 2〇200821256 from the warm water supply pipe 8 to the clean box 16, and the solid mouth mouth 17, and; == Turning the warm water from the mouth will clean the box! The residual phase in 5 is 5 _ shot. The warm water washing prepared by the jet washing is cleared, because the switching valve 5 at this time will flow from the discharge pipe to the right side. At this time, since the door fi ′ is switched, the water sample 3 is widened toward the medicinal tank 1 in the drawing, and the ventilator is blocked with the ventilator.

fV14 :二上的步驟’便完成潔淨箱15内的環境管理空 ㈣施行殺菌與清洗處理,__ 5則切換 =在圖中連通於左侧之溫水槽2,準備進行下一步驟。 一次填充及密封作辈中之、、主、、杰> @ ^ /月洗水荨的處理量係依照設備 規,而異,大約2〜3t’並無含蓋如無菌填充系統情況時 之备益清洗在内約# 2Gt/時的大量排水之情形,本發明 式:因應在排水槽3所儲存的批次處理。利用藥劑施 打環境管理空間的殺g,係可依每個製造批號單位實施, 例如每次實施2〜3個批號。 田‘劑係使用過醋酸系藥劑的情況,便使用它,且 必需施打3分鐘的殺菌,若將此時的分解率設定為丨,則 若使用5(TC的話,便殺菌只要丨分鐘便可,分解率係15, 且右使用60 C,則殺菌只要10秒鐘便足夠,分解率係4。 換s之,所謂分解率提高,便意味著藥劑能再利用的次數 將減少,藥劑的可使用壽命將變差,若提高使用溫度,則 殺菌效果雖提高,但是卻有可使用壽命變差的關係。如上 述’當樂劑使用後的清洗係使用⑽〜丨〇〇t溫水的情況, 312XP/發明說明書(補件)/96·11/96126566 21 200821256 2為溫水之殺菌功能的作用,因此可降低藥劑的使用溫 度,便能增加藥劑的可使用#命。此外,若藥劑處於高溫, -亦有零件劣化,導致對機器造成損傷的問題。 再者,因為本發明係利用藥劑對潔淨箱施行殺菌,因此 依照使用藥劑與濃度,於殺菌處理後的清洗時,並不需要 如上述使用溫水,僅使用無菌水來清洗便可。此情況下, 切換閥4將必需使用三通閥,採用亦連接於無菌 化構造。 再者,藉由使用臭氧系等藥劑,亦有時不需要清洗。 π本實施形態中,從環境管理空間外的瓶供應裝置,移往 :裒境管理空間14内的瓶殺菌及清洗裝置1〇中之瓶的殺 囷,係至少對瓶内面(最好内外面)以65它〜1〇〇。〇熱水加 熱殺菌來施行。殺菌時間係3秒至1〇秒。根據該方法, 因為利用熱水同時施行瓶殺菌與殺菌後的清洗,因而不需 要另外進行殺菌後的瓶的清洗步驟,但在防止_ ⑩之變形、與對附著於瓶上的細菌沖洗等之目的下,有時; 利用無菌水來施行清洗。此外,同樣的,從環境管理空^ 外的瓶蓋供應裝置,朝管理空間内所設置的瓶蓋殺菌及清 洗裝置供應瓶蓋,並藉由對瓶蓋的内外面喷射出65t:〜1〇〇 °c熱水來施行加熱殺菌。 利用熱水施行的瓶内外面殺菌,係可例如利用瓶清洗裝 置將瓶配置呈倒立狀態,再從熱水喷霧噴嘴喷射出熱水來 實施。同樣的,利用熱水施行的瓶蓋内外面殺菌,係可例 如就在由金屬絲形成的滑槽中移動的瓶蓋、或利用轉盤將 312XP/發明說明書(補件)/96·11/96126566 22 200821256 開:部朝下π進行移動的瓶蓋,㈣水喷霧喷嘴對其内外 面喷射熱水來實施。經殺菌清洗完的瓶,便供應給填充機 11 ’亚利料充機施行飲料的填充。此外,瓶蓋係分別供 應給封蓋機12,並對已填充飲料的瓶施行蓋瓶,將瓶密 封。 ,在飲料對瓶施行填充及密封的生產線2運轉中,對填充 丽的容器喷射出熱水來施行加熱殺菌,此時,圖3中,從 鲁瓶殺菌及清洗室因為切換閥5處於圖中左侧,即連通於= 水槽2的形恕,因而該處理水便回流於溫水槽2中而再利 用。從在外部搬入於預先由藥劑施行殺菌過的環境管理空 間14—中之瓶’係屬於一般性的清潔,即使假設附著有若 干細囷,但是因為在此已施行殺菌及清洗處理,因而幾乎 沒有處理水的污染情形,因而將可再利用,就此點而言, 亦有助於排水量的削減。從外部所搬入的瓶蓋因為並非如 瓶般的清潔’因而從對瓶蓋施行殺菌及清洗的蓋瓶室中所 籲μ出的處理水’將切換閥$ ^ ^成朝圖中右側,即連通於 排水槽3的形態,於未供再利用的情況下流入於排水槽 中。單次填充及密封作業中的清洗水等處理量,係先前^ .樂劑清洗水、與該瓶蓋的殺菌及清洗用處理水之合計。 另方面内谷液的飲料係如圖1所示,利用在潔淨箱 •外所設置的調合槽20進行調合,並儲存於均衡槽21中, 從此f供應給高溫短時間殺菌器22與急速冷卻器,並 加仃同概短#間殺菌與急速冷卻。高溫短時間殺菌係利用 HTST殺菌法等方法施行加熱殺菌,本實施形態中,如前 312XP/發明說明書(補件)/96·!寒126566 200821256 u ’當上述飲料係pH46以上、且兒茶素含有量响以 ^的茶飲料之情況,便施行高溫短時間殺菌以獲得135 C、7.58秒同等級以上的殺菌值。此外,當上述飲料係 j) Η未滿4 · 6的酸性飲料之情況,便對該飲料,在例如9 39 $ c施行短時間的加熱殺菌,以獲得㈣、3fV14: The second step is to complete the environmental management in the clean box 15 (4) to carry out sterilization and cleaning treatment, __ 5 to switch = in the figure to communicate with the left side of the warm water tank 2, ready for the next step. The amount of treatment for a fill and seal in the middle of the generation, the main, the Jie > @ ^ / month wash water 系 according to the equipment rules, about 2~3t' no cover, such as the case of aseptic filling system In the case of a large amount of drainage at about #2 Gt/hour, the present invention is treated in accordance with the batch stored in the drain tank 3. The killing of the environmental management space by the use of the medicament can be carried out according to each manufacturing batch number unit, for example, 2 to 3 batch numbers are implemented each time. In the case of using the acetic acid-based drug, the field's agent is used, and it must be sterilized for 3 minutes. If the decomposition rate at this time is set to 丨, if 5 (TC) is used, it will take only minutes to sterilize. However, if the decomposition rate is 15, and 60 C is used on the right, sterilization is sufficient for 10 seconds, and the decomposition rate is 4. In other words, the increase in the decomposition rate means that the number of times the drug can be reused is reduced, and the drug is reduced. The service life will be deteriorated. If the use temperature is increased, the sterilization effect is improved, but there is a relationship that the service life is deteriorated. For example, the above-mentioned cleaning agent after use of the agent is used (10)~丨〇〇t warm water. Case, 312XP/Invention Manual (Supplement)/96·11/96126566 21 200821256 2 is the function of the sterilizing function of warm water, so that the use temperature of the medicine can be lowered, and the usable life of the medicine can be increased. At high temperatures, there are also problems in which the parts are deteriorated, causing damage to the machine. Furthermore, since the present invention uses a chemical to sterilize the clean box, it is not necessary to clean the sterilized treatment according to the use of the drug and the concentration. To use warm water as described above, use only sterile water for cleaning. In this case, the three-way valve must be used for the switching valve 4, and it is also connected to the aseptic structure. Furthermore, by using an ozone system or the like, In this embodiment, the bottle supply device outside the environmental management space is moved to the bottle sterilization and cleaning device in the environment management space 14 for at least the bottle. The inner surface (preferably the inner and outer surfaces) is carried out by heating it with water. The sterilization time is 3 seconds to 1 second. According to this method, since the bottle is sterilized and sterilized by hot water. Therefore, it is not necessary to separately perform the washing step of the bottle after sterilization, but the purpose of preventing the deformation of _10 and the rinsing of the bacteria attached to the bottle may be performed by using sterile water. The bottle cap supply device from the environmental management space supplies the cap to the cap sterilization and cleaning device provided in the management space, and ejects 65t:~1〇〇°c heat to the inside and outside of the cap. Water to perform heat sterilization The inside and outside of the bottle which is performed by the hot water can be carried out by, for example, using a bottle washing device to place the bottle in an inverted state, and then spraying the hot water from the hot water spray nozzle. Similarly, the bottle cap is used by the hot water. External sterilization, for example, a bottle cap that moves in a chute formed of a wire, or a 312XP/invention specification (supplement)/96·11/96126566 22 200821256 is opened by a turntable: the portion is moved downward π The bottle cap, (4) water spray nozzle is sprayed on the inside and outside of the hot water. The bottle that has been sterilized and cleaned is supplied to the filling machine 11 'Yali filling machine for filling the beverage. In addition, the bottle cap is supplied separately. The capping machine 12 applies a cap bottle to the bottle filled with the beverage to seal the bottle. In the operation of the production line 2 for filling and sealing the bottle, the hot water is sprayed on the filled container to perform heat sterilization. At the time of Fig. 3, since the switching valve 5 is on the left side of the figure, that is, the switch is connected to the water tank 2, the treated water is returned to the warm water tank 2 for reuse. The bottle from the outside of the environmental management space 14 that has been previously sterilized by the drug is a general cleaning, and even if a certain fineness is attached, it is hardly sterilized and cleaned. The treatment of water contamination is therefore reusable and, in this regard, contributes to the reduction of displacement. Since the cap that is carried from the outside is not cleaned like a bottle, the treatment water that is called out from the cap chamber that sterilizes and cleans the cap is turned to the right side of the figure, that is, The form that communicates with the drain tank 3 flows into the drain tank when it is not reused. The amount of treatment such as washing water in a single filling and sealing operation is the total of the previous cleaning water, the sterilization of the cap, and the treated water for cleaning. In addition, as shown in FIG. 1 , the beverage of the gluten solution is blended by the mixing tank 20 provided outside the clean box, and stored in the equalization tank 21, from which f is supplied to the high-temperature short-time sterilizer 22 and rapidly cooled. And add the same short and short between # sterilization and rapid cooling. The high-temperature short-time sterilization system is heat-sterilized by a method such as HTST sterilization method. In the present embodiment, as in the previous 312XP/invention specification (supplement)/96·! cold 126566 200821256 u 'when the above-mentioned beverage is pH 46 or higher, and catechin In the case of a tea beverage containing a quantity of ^, a high-temperature short-time sterilization is performed to obtain a sterilization value of 135 C or 7.58 seconds or more. In addition, when the beverage system j) is not in the case of an acidic beverage of 4.6, the beverage is subjected to a short-time heat sterilization at, for example, 9 39 $c to obtain (4), 3

上的殺菌值。 ^ f A W /急速冷卻係藉由使已施行高溫短時間殺菌過的飲料,接 .著通過急速冷部器23,而在通過的期間與冷媒進行孰交 換,而於短時間内便冷卻至常溫,常溫係設定為約阶 較恰當?旦隨飲料種類與季節等因素而異’則可採用15 C〜40 C範圍。經急速冷卻的飲料便儲存於由無菌槽構成 的儲存槽25中。該儲存槽25、上述急速冷卻器^、後述 真:機u、及其所連接的配管等所有的液體接 化封門0]用蒸氣或熱水施行殺菌清洗,而形成無菌 *。位’以可獲得所填充飲料的殺菌條件同等級以上 即,135°C、7. 58秒的同等級以上)殺菌條件之方式。特 別係儲存槽25利用無菌氣體保持正屢狀態,防止外界氣 體進入,且將所儲存的飲料利用無菌氣體施行壓送,而將 ,料從該館存槽經由頂槽26輸送於填充機中。藉由此方 ^便可不必藉由構造上較難完全殺菌與密封,且較難盈 二體輸送,即使飲料在常溫下仍能維持無、 菌氣體的壓送,而輸送給填充機= 在無囷化裱扰管理空間中填充於瓶中。 312ΧΡ/發明說明書(補件)/96_11/96126566 24 200821256 已填充飲料的瓶便從填充機中移送於在環境管理空間 内所設置的封盍機12,並利用從在環境管理空間外所配 •置的舨蓋供應裝置,朝在環境管理空間内所配置的瓶蓋殺 菌及清洗裝置供應,且於瓶蓋殺菌及清洗裝置中,在與瓶 為相同條件下施行殺菌及清洗的瓶蓋,進行完全密封。然 後,經密封的瓶不需要如習知熱裝填法般,於通過殺菌機 與冷卻器之後,施行後殺菌步驟與冷卻步驟等後處理,可 直接進行製品檢查步驟、裝箱步驟等。 @ [實施例] [實施例1] 使用谷置2L的PET瓶,並採取上述之製造方法及裝置 進行綠茶飲料(pH 5· 9、兒茶素含有量52mg%)的製造。 即,將對經熱水90°C、3秒鐘加熱殺菌及清洗過的瓶, 施行135°C、30秒的高溫短時間加熱殺菌後,再急速冷卻 至常溫的綠茶飲料,儲存於預先施行殺菌及清洗達内容物 φ殺菌值以上而利用無菌氣體呈正壓化的儲存槽中,並從此 處利用無菌氣體壓送入頂槽中,再供應給填充機,並在管 理空間内,填充於已預先利用熱水施行殺菌清洗過的瓶 中,且利用已預先施行殺菌及清洗過的瓶蓋進行密封。另 .外,從急速冷卻器起至填充機的液路徑,利用無菌氣體正 ' 壓化,且形成與外界空氣隔絕的封閉路徑。 針對依如上述所獲得剛製造完成後的綠茶飲料,為調查 與依照習知熱裝填法進行製造情況時比較後的綠茶色 調、風味變化,便分別測定綠茶的pH值、色調、維他命 312XP/發明說明書(補件)/96·11/96126566 25 200821256 此外,相關愛好性係實施官能試驗。該等結果係如表 2、表3及表4所示。 . 上述色調測定係依L*a*b表色系進行測定。l值係指亮 度,a值係指紅-綠轴,b值係指黃藍軸的混色系表色系, L值越大則越明亮,a值越朝正方向則偏紅越強,越朝負 方向則偏綠越強,b值越朝正方向則偏黃越強,越朝負方 向則偏藍越強。此外,值係利用計算在該色空間中的 參2個顏色間之直線距離分開何種程度而求得。 再者,維他命C的測定係測定經調合後的未加熱狀態下 的濃度,且測定在剛製造完後的飲料中之濃度,並調查殘 存率·。 官能試驗係採用較二點鑑定法具更高正確性的三點鑑 疋法來實施,準備將比較對象的2種茶飲料(實施例丨之 A、比較例1之b),依Α-Α-Β、α—β—β等3種的適當組合, 並由15位審查人員試飲,而施行二者的鑑定與愛好性官 _ 能評估。 ” [實施例2] 使用谷里1 · 5L的PET瓶,並採取上述之製造方法及裝 置進行100%柳橙汁(ΡΗ3· 61)酸性飲料的製造。 即將對經熱水90 C、3秒鐘加熱殺菌及清洗過的瓶, •施行94· 5〜96。(:、30秒的高溫短時間加熱殺菌後,再急速 冷卻至常溫(本實施例中為31t:〜32t)的酸性飲料,儲存 於預先施行殺菌及清洗達内容物殺菌值以上而利用無菌 氣體呈正壓化的儲存槽中,之後便依照與實施例丨相同的 312ΧΡ/發明說明書(補件)/9641/96126566 26 200821256 方法獲得瓶裝酸性飲料。另外,此情況的填充溫度係3〇 C。然後’與實施例1的情況相同’針對剛製造完後的酸 ‘性飲料’為了調查與依照f知熱裝填法製造之情況比較後 的酸性飲料色調、風味變化,便分別測定綠茶# pH值、 色調、維他命c。該等結果係如表5、表6所示。 [比較例1] ’ 比較例1係使用與實施例丨相同的容量2L之PET瓶, ⑩=採用上述專利文獻2所記載的製造方法及裝置,進行綠 余飲料(ρΗ5·9、兒茶素含有量52mg%)的製造。即,將經 135 C、30秒高溫短時間殺菌後,再冷卻至65。〇的綠茶飲 料,設置於預先透過箱而與外界隔絕的環境管理空間内, 並利用經在與容器相同條件下殺菌及清洗過的填充機、封 蓋機,填充於經9(TC、3秒熱水殺菌/清洗過的瓶中,且 密封。然後,利用簡易的冷卻水沖淋將PET瓶裝綠茶飲料 冷卻至常溫,便獲得茶飲料。 • 針對依如上述所獲得的綠茶飲料,就剛製造完成後(此 情況係經冷卻後)的飲料,與實施例丨相同,為調查綠茶 的色調、風味變化,便分別測定綠茶的pH值、色調、維 他命C。此外’依照與實施例相同的方法,使用三點鐘定 .法,施行二者的鑑定與官能評估。該等結果係與實施例玉 ' 一併記於表2〜表4中。 [比較例2 ] 比較例2係使用與實施例2相同的容量1 · 5L之pET瓶, 與比較例1相同地採用上述專利文獻2所記載的製造方法 312XP/發明說明書(補件)/96-11/96126566 27 200821256 及裝置,進行100%柳橙汁(ρΗ3·61)的製造。即,將經 94.5〜96°0:、30秒高溫短時間殺菌後,再冷卻至67〜68 = 的酸性飲料,设置於預先透過箱而與外界隔絕的環境管理 空間内,並利用經在與容器相同條件下殺菌及清洗過的填 充機、封盍機,依填充溫度65°C填充於經9(TC、3秒的 熱水殺菌及清洗過的瓶中,且密封。然後,利用簡易的冷 卻水沖淋將PET瓶裝酸性飲料冷卻至常溫,便獲得酸性^ 料。 針對依如上述所獲得的酸性飲料,就剛製造完成後(此 情況係經冷卻後)的飲料,與實施例2相同般,為了調杳 100%柳橙汁的色調、風味變化,便分別測定其pH值、色 調、維他命C。該等結果係與實施例2 —併記於表5、表 6中。 [實施例與比較例的評估] (茶飲料的情況) pH值、色調: [表2] pH L值 a值 b值 ΔΕ 調合未加熱品 6. 38 90· 90 -9· 90 29. 49 基準 實施例1 6. 23 89. 25 -8· 44 32. 23 3. 52 比較例1 6. 19 89. 00 - 8· 14 33. 88 5· 10 由表2中得知’將實施例1與比較例1進行比較時,實 施例1物相較於比較例1 ’明顯地色調接近調合未加熱 品’可保持新鮮的色調。此外,得知pH值亦是實施例i 維持著比較接近調合未加熱品的狀態。 312XP/發明說明書(補件)/96-11/96126566 28 200821256 維他命C殘存率· [表3] 遭度 (ppm) 殘存率 (%) 調合未加熱品 283 100. 0 實施例1 236 83. 4 比較例1 215 76. 0 1 % 8¾ .〇/ 〜π千你就调合未加熱品,實 施例1為83· 4%,而比較例1 7沾絡从入π 、〗為76/0 ’明顯地實施例情 況的維他命C殘率較高。 4 a 愛好性官能評估: [表4] 審查人員1 5位 鑑定試驗 答對者9名'^ 9位鑑定試驗答對 嗜好試驗 中’吾好實施例1物者 有7位、喜好比較例1 物者有2位 j%危險率屬有效差 在5%危險率内,喜好實 施例物(常溫填充) 備註 能區 7 _ ^ n &此5丁巧石箱禾甲,能 分實施例物與比較例物者的9位中,喜好實施例物者有 位’顯示"實施例丨物愛好性’壓倒性高於對喜好比較 例1物愛好性的結果。 (長時間變化觀察) A將依上述實施例1所製得2L的PET瓶裝綠茶飲料,在 2溫下保管2週後,依目視觀察内容物的微生物劣變狀 心結果,觀察到綠茶飲料的狀態良好,完全無因微生物 劣交而造成的渾濁情形。 312XP/發明說明書(補件)/96-11/96126566 29 200821256 (100%柳橙汁(酸性飲料)的情況) pH值、色調: [表5] 調合未加熱品 pH L值 a值 b值 ΔΕ 3. 61 66. 66 22. 6 42. 98 基準 實施例2 3. 51 65. 35 23. 48 42. 61 1. 62 比較例2 3. 51 64. 95 24. 78 42. 2 2. 88 由表5中得知,將實施例2與比較例2進行比較時,實 施例2物相較於比較例2,明顯地色調接近調合未加熱 品,可保持新鮮的色調。即,比較例2的1〇〇%柳橙汁相 較於實施例2,L值(亮度)較低,a值(紅色)上升,且b 值(黃色)降低。 維他命C殘存率: [表6 ] 濃度 (ppm) 殘存率 (%) 調合未加熱品 283 100. 0 實施例2 270 95· 4 比較例2 245 86. 6 如表6所示,維他命C的殘存銮铖▲田人主t | y 、 %仔+就调合未加熱品,實施 例2為95· 4%,而比較例2則a rr β。/ 〇〇 θ ^ ⑴馬86· 6%,明顯地實施例2 十月況的維他命C殘率較高。 (综合評估) 針對實施例1、2與比較例1、9 定 物 J 1 2的色調測定、pH值測 、維他命C殘存率任一項,约後电 g係只%例物較優於比較例 ,且保持新鮮的色調,維他+ 他p C殘存率亦較高,確認到 312Χρ/發明說明書(補件)/96-11/96126566 30 200821256 可獲得品質優異的飲料。且,即使在實施例1與比較例l 的審查人員官能試驗結果,亦是對實施例物之愛好性呈現 壓倒性較高的結果,故確認到將本發明的容器裝飲料之製 造方法’適用於茶飲料與酸性飲料時的有效性。 [實施例3] 使用容量2L的PET瓶,並採取上述之製造方法及裝置 進行綠茶飲料(ΡΗ5· 9、兒茶素含有量52mg%)的製造。 馨 即’對容器清洗、填充及密封的管理空間,預先使用 40°C、濃度20〇〇ppm的過醋酸系藥劑(商品名:T〇yo Active) 施行10分鐘殺菌後,再利用9〇ac熱水施行清洗,確認到 對通稱「B· subti 1 is, B· coagulans」的芽胞菌,具有 6D以上的殺菌效果。此外,將對經熱水9〇。(::、3秒鐘加 熱殺菌及清洗過的瓶,施行13 5 °C、3 0秒的高溫短時間加 熱殺菌後,再急速冷卻至常溫的綠茶飲料,儲存於預先施 行殺菌及清洗達内容物殺菌值以上且透過無菌氣體呈正 _壓化的儲存槽中,並從此處利用無菌氣體壓送於頂槽中, 再供應給填充機,並在管理空間内,填充於預先經熱水殺 菌清洗過的瓶中,且利用預先施行殺菌及清洗過的瓶蓋來 密封。另外,從急速冷卻器起至填充機的液路徑,利用無 菌氣體正壓化,且形成與外界空氣隔絕的封閉路徑。 ^ 針對依如上述所獲得剛製造完成後的綠茶飲料,為了調 查與依照習知熱裝填法進行製造情況比較後的綠茶色 調、風味變化,便分別測定綠茶的pH值、色調、維他命 C。此外,相關愛好性係實施官能試驗。該等結果係如表 312XP/發明說明書(補件)/96·11/96126566 31 200821256 7、表8及表9所示。 上述色調測定係如同上述,利用L>ica)|cb>KL star · a star • b star)表色系施行測定。 再者’維他命C的測定係測定經調合後的未加熱狀態下 的濃度,且測定在剛製造完後的飲料中之濃度,並調查殘 存率。 官能試驗係採用較二點鑑定法具較高正確性的三點鑑 定法實施,準備將比較對象的2種茶飲料(實施例3之A、 _比較例3之B),依A-A-B、A-B-B等3種的適當組合,並 由20位審查人員試飲,而施行二者的鑑定與愛好性官能 評估。 [實施例4] 使用容量1· 5L的PET瓶,並採用上述之製造方法及裝 置進行100%柳橙汁(ρΗ3· 61)酸性飲料的製造。 即,對容器清洗、填充及密封的管理空間,預先使用 φ 、濃度2〇〇〇PPm的過醋酸系藥劑(商品名:T〇y〇 Active) 施行10分鐘殺菌後,再利用90°c熱水施行清洗。此外, 將對經熱水90°C、3秒鐘加熱殺菌及清洗過的瓶,施行 94· 5〜96°C、30秒的高溫短時間加熱殺菌後,再急速冷卻 • 至常溫(本實施例中為31°C〜32。〇的酸性飲料,儲存於預 ' 先施行殺菌及清洗達内容物殺菌值以上,且利用無菌氣體 呈正壓化的儲存槽中,之後便依照與實施例3相同的方法 獲得瓶裝酸性飲料。另外,此情況的填充溫度係3〇 t。 然後,與實施例3的情況相同地,針對剛製造完後的酸性 312XP/發明說明書(補件)/96-11/96126566 32 200821256 飲料,調查與依照習知熱裝填法來製造之情況比較後的酸 性飲料色調、風味變化,便分別測定綠茶pH值 、 維他命c。該等結果係如表1 〇、表】丨所示。 [比較例3 ] 比較例3係使用與實施例3相同的容量2LipET瓶, 並採用上述專利文獻2所記载的製造方法及裝置,進行綠 茶飲料(PH5.9、兒茶素含有量52mg%)的製造。即,將經 籲135°C、30秒高溫短時間殺菌後,再冷卻至65〇c的綠茶飲 料,設置於預先透過箱而與外界隔絕的環境管理空間内, 並利用經在與容器相同條件下施行殺菌/清洗過的填充 機、封蓋機,填充於經9(TC、3秒的熱水殺菌/清洗過的 瓶中,且加以密封。然後,利用簡易的冷卻水沖淋將PET 瓶裝綠茶飲料冷卻至常溫,便獲得茶飲料。 針對依上述所獲得的綠茶飲料,就剛製造完後(此情況 係經冷卻後)的飲料’與實施例3相同,為了調查綠^的 •色調、風味變化,便分別測定綠茶的pH值、色調、維他 命C。此外,依照與實施例相同的方法,使用三點鑑定法 來施行二者的鑑定與官能評估。該等結果係與實施例3 一 併記於表7〜表9中。 * (比較例4 ) ' 比較例4係使用與實施例4相同容量1 · 5L之pet瓶, 與比較例1同樣地採用上述專利文獻2所記載的製造方法 及裝置,進行100%柳橙汁(ΡΗ3·61)的製造。即,將經 94.5〜96°(:、30秒高溫短時間加熱殺菌後,再冷卻至67〜68 312XP/發明說明書(補件)/96·11/96126566 33 200821256 °c的酸性飲料,設置於預先透過箱而與外界隔絕的環境管 理空間内,並利用經在與容器相同條件下殺菌及清洗過的 填充機、封蓋機,依填充溫度^。(:填充於經9(rc、3秒 熱水殺菌及清洗過的瓶中,且加以密封。然後,利用簡易 的冷卻水沖淋將P E T瓶裝酸性飲料冷卻至常溫,便獲得酸 性飲料。 針對如上述所獲得的酸性飲料,就剛製造完後(此情況 係經冷卻後)的飲料,與實施例4相同地,為了調查f〇〇% 柳橙汁的色調、風味變化,便分別測定其pH值、色碉、 維他命C。該等結果係與實施例4 一併記於表丨〇、表°上上 中〇 [實施例與比較例的評估] (茶飲料的情況) pH值、色調: [表7] pH L值 a值 b值 △ E 调合未加熱品 6. 44 91. 50 -10.30 30. 05 基準 實施例3 6. 30 89. 95 -8· 50 33. 35 3· 69 比較例3 6· 25 88. 91 -8.20 34. 11 5. 25 由表7中得知,將實施例3與比較例3進科仏 1丁比較睡,與 施例3物相較於比較例3,明顯地色調接近,人貝 品’可保持新鮮的色調。此外,得知pH值亦I二力…、 者維持比較接近調合未加熱品的狀態。 、⑰例3 維他命C殘存率: [表8] 312XP/發明說明書(補件)/96-11/96126566 34 200821256 濃度 (ppm) 殘存率 (¾) 調合未加熱品 305 100. 0 實施例3 260 85. 2 比較例3 236 77. 4 a如表8所示,維他命(^的殘存率係就調合未加熱品,實 施例3為85. 2% ’而比較例3料77. 4%,明顯地實施例 情況的維他命C殘率較高。 愛好性官能評估: [表9] 鑑定試驗 _ 答對者12名 嗜好試驗 12位鑑定試驗答對者 中,喜好實施例3物者 有8位、喜好比較例3 物者有4位 5%危險率屬有效差 施例物(常溫填充) 能區 分實施例物與比較例物者的12位中,喜好實施例物者有 8位,顯示出對實施例3物之愛好性壓倒性高於對喜好比 較例3物之愛好性的結果。 (長時間變化觀察) 將依上述實施例3所製得2L的PET瓶裝綠茶飲料,在 常溫下保管2週後,依目視觀察内容物的微生物劣變狀 態。結果’觀察到綠茶飲料的狀態良好,完全無因微生物 劣變而造成的渾濁情形。 (100%柳橙汁(酸性飲料)的情況) pH值、色調: 312XP/發明說明書(補件)/96-11/96126566 35 200821256 [表 10] pH L值 a值 b值 △ E 調合未加熱品 3· 55 67. 61 22. 00 43· 32 基準 實施例4 3· 46 65· 90 24· 10 43. 01 2. 73 比較例4 3. 46 65. 03 25· 04 42. 60 4. 05 - 由表10中得知,將實施例4與比較例4進行比較時, 實施例4物相較於比較例4,明顯地色調接近調合未加熱 品,可保持新鮮的色調。即,比較例4的1〇〇%柳橙汁相 較於實施例4物,L值(亮度)較低,a值(紅色)上升,且 _ 1)值(黃色)降低。 維他命C殘存率: [表 11 ] 濃度 (ppm) 殘存率 (%) 調合未加熱品 320 100. 0 實施例4 295 92. 2 比較例4 276 86. 3 如表11所示,維他命c的殘存率就調合未加熱品,實 _施例4為92· 2%,而比較例4則為86. 3%,明顯地實施例 4情況的維他命c殘率較高。 (綜合評估) /關於實施例3、4與比較例3、4的色調測定、pH值測 定、維他命C殘存率任一項,確認到實施例物均優於比較 例物,可保持新鮮的色調,維他命c殘存率亦較高,可獲 得品質優越的飲料。而且,即使在實施例3與比較例3的 番查人員g能試驗結果,亦是對實施例物之愛好性呈現壓 312XP/發明說明書(補件)/96-11/96126566 36 200821256 倒性較高的結果,由此可確認將本 、生古、土 a « +义明的谷斋裝飲料之製 每方法適用於茶飲料與酸性飲料時的有效性。 (產業上之可利用性) η的容器裝飲料之製造方法,可使用於諸如_·6 以及备素含有量3〇ing%以上的綠茶、烏龍茶等飲料, 6酸性飲料與财水等,經加熱後芽胞菌 ”的非豐富營養性飲料之容器裝飲料之製造。容哭 並不僅侷限於PET瓶等合成樹脂製瓶,尚可適用於金屬。 瓶、金屬罐、玻璃瓶等。 【圖式簡單說明】 、圖1為本發明實施形態中,供實施容器裝飲料之製造方 法用的製造系統示意圖。 圖2為本發明的容器裝飲料之製造方法中,-實施形態 的流程圖。 圖3為在作為環境管理”的潔淨箱内,使用藥劑施行 的本發明殺菌及清洗方法說明圖。 此圖4為本I a月的容器裝飲料之製造方法之另—實施形 悲流程圖。 、 【主要元件符號說明】 1 藥劑槽 3 2 溫水槽 排水才曹 6 7 流路切換用閥 藥劑供應管 312XP/發明說明書(補件)/%七/96126566 37 200821256 8 溫水供應管 10 瓶殺菌及清洗裝置 11 填充機 12 封蓋機 14 環境管理空間 15 潔淨箱 16 旋轉式熱水喷射噴嘴 17 固定式熱水喷射喷嘴 20 調合槽 21 均衡槽 22 南溫短時間殺囷機 23 急速冷卻機 25 儲存槽 26 頂槽Sterilization value on. ^ f AW / rapid cooling system allows the beverage that has been sterilized at a high temperature for a short period of time to pass through the rapid cold unit 23, and exchanges with the refrigerant during the passage, and then cools to the normal temperature in a short time. Is it appropriate to set the normal temperature system to approximate? It can vary from 15 C to 40 C depending on the type of beverage and the season. The rapidly cooled beverage is stored in a storage tank 25 composed of a sterile tank. The storage tank 25, the above-described rapid cooler, and all of the liquid sealing doors 0, which will be described later, and the pipes to which they are connected, are sterilized by steam or hot water to form a sterilized product. The position is such that the sterilization condition of the filled beverage can be obtained at the same level or higher, that is, at the same level or higher than 135 ° C and 7.58 seconds. The special storage tank 25 is maintained in a regular state by means of a sterile gas to prevent entry of outside air, and the stored beverage is pressurized by a sterile gas, and the material is conveyed from the hall storage tank through the top tank 26 to the filling machine. By this means, it is not necessary to be completely difficult to completely sterilize and seal by construction, and it is difficult to carry out the two-body transport, even if the beverage can maintain the pressure of the non-bacterial gas at normal temperature, and is fed to the filling machine = The flawless turbulence management space is filled in the bottle. 312ΧΡ/Invention Manual (Supplement)/96_11/96126566 24 200821256 The bottle filled with beverage is transferred from the filling machine to the sealing machine 12 installed in the environmental management space, and is used outside the environmental management space. The cap supply device is supplied to the cap sterilization and cleaning device disposed in the environmental management space, and in the cap sterilization and cleaning device, the bottle cap which is sterilized and cleaned under the same conditions as the bottle is performed. Completely sealed. Then, the sealed bottle does not need to be post-treated after passing through the sterilizer and the cooler, and then subjected to post-sterilization step and cooling step, as in the conventional hot-filling method, and the product inspection step, the packing step, and the like can be directly performed. [Examples] [Example 1] A 2 L green PET bottle was used, and the green tea beverage (pH 5·9, catechin content 52 mg%) was produced by the above-described production method and apparatus. In other words, the bottle that has been heat-sterilized and cleaned at 90 ° C for 3 seconds is subjected to high-temperature sterilization at 135 ° C for 30 seconds, and then rapidly cooled to a room temperature green tea beverage, and stored in advance. Sterilize and clean up to a content of φ sterilizing value and use a sterile gas in a positive pressure storage tank, and from here using sterile gas pressure into the top tank, and then supply to the filling machine, and in the management space, filled in The bottle is sterilized and cleaned in advance using hot water, and sealed by a bottle cap that has been previously sterilized and cleaned. In addition, the liquid path from the rapid cooler to the filling machine is positively pressurized with a sterile gas and forms a closed path from the outside air. In order to investigate the green tea color and flavor change after comparison with the conventional hot-fill method, the green tea beverages obtained after the above-mentioned production were measured, and the pH value, color tone, vitamin 312XP/invention of green tea were measured. Instruction manual (supplement)/96·11/96126566 25 200821256 In addition, the relevant hobby is to carry out a functional test. These results are shown in Table 2, Table 3 and Table 4. The above color tone measurement was carried out according to the L*a*b color system. l value refers to brightness, a value refers to red-green axis, b value refers to mixed color system color of yellow-blue axis, the larger the L value, the brighter the a value is, the more positive the value is, the stronger the redness is. In the negative direction, the greener is stronger. The more the b value is toward the positive direction, the stronger the yellowing is. The more negative the direction is, the stronger the blue is. Further, the value is obtained by calculating the degree to which the linear distance between the two colors in the color space is separated. Further, the measurement of the vitamin C was carried out by measuring the concentration in the unheated state after the blending, and measuring the concentration in the beverage immediately after the production, and investigating the residual rate. The functional test was carried out by a three-point method with higher accuracy than the two-point identification method, and two kinds of tea drinks (A of the examples, b of the comparative example 1) of the comparison object were prepared, and the Α-Α - Appropriate combination of three kinds of Β, α-β-β, and 15 drinkers, and the identification and hobbyist evaluation of both. [Example 2] A 100% orange juice (ΡΗ3·61) acidic beverage was produced by using a PET bottle of 1 5 L in a grain, and the above-mentioned manufacturing method and apparatus were used. Heat-sterilized and cleaned bottle, • Execution of 94·5 to 96. (:, 30 seconds of high-temperature heat sterilization for a short period of time, and then rapidly cooled to room temperature (31t: ~32t in this example) of acidic beverages, storage The bottle is preliminarily sterilized and cleaned to a volume greater than the sterilizing value of the contents and is positively compressed by a sterile gas, and then obtained in accordance with the same 312 ΧΡ / invention specification (supplement) / 9641/96126566 26 200821256 method as in the embodiment 瓶In addition, the filling temperature in this case is 3 〇 C. Then, 'the same as in the case of the first embodiment, 'for the acid-type beverage immediately after the manufacture, in order to investigate the comparison with the case of manufacturing according to the hot charging method. Green tea #pH value, color tone, and vitamin C were measured for the color tone and flavor change of the acidic beverage. The results are shown in Tables 5 and 6. [Comparative Example 1] 'Comparative Example 1 was used in the same manner as in Example 系Capacity 2L PET bottle, 10 = The production method and apparatus described in the above Patent Document 2 were used to produce a green beverage (ρΗ5·9, catechin content: 52 mg%), that is, a high temperature of 135 C for 30 seconds. After sterilization, it is cooled to 65. The green tea beverage is placed in an environmental management space that is separated from the outside by a box, and is filled with a filling machine and a capper that are sterilized and cleaned under the same conditions as the container. After 9 (TC, 3 seconds hot water sterilization / cleaning bottle, and sealed. Then, use a simple cooling water shower to cool the PET bottled green tea beverage to room temperature, you will get a tea drink. The green tea beverage obtained immediately after the completion of the production (in this case, after cooling) was the same as in Example ,. In order to investigate the color tone and flavor change of green tea, the pH value, color tone, and vitamin C of green tea were measured. 'According to the same method as the examples, the identification and functional evaluation of the two were carried out using the three-point method. These results are shown in Tables 2 to 4 together with the examples. [Comparative Example 2] Comparative example 2 In the same manner as in the first embodiment, the production method 312XP/invention specification (supplement)/96-11/96126566 27 200821256 and the apparatus described in the above Patent Document 2 are used in the same manner as in the first embodiment. The production of 100% orange juice (ρΗ3·61) is carried out. That is, the acidic beverage which has been sterilized by a high temperature for a short period of time of 94.5 to 96° 0:30 seconds, and then cooled to 67 to 68 = is placed in the pre-passing box. In the environmental management space that is isolated from the outside world, and using a filling machine and a sealing machine that have been sterilized and cleaned under the same conditions as the container, and filled with water at a filling temperature of 65 ° C for 9 (TC, 3 seconds of hot water sterilization and cleaning) In the bottle, and sealed. Then, the PET bottled acidic beverage is cooled to room temperature by a simple cooling water shower to obtain an acid material. With respect to the acidic beverage obtained as described above, the beverage immediately after the completion of the production (in this case, after cooling) was measured in the same manner as in Example 2, in order to adjust the color tone and flavor change of the 100% orange juice. pH, color, vitamin C. These results are shown in Table 2 and Table 6 together with Example 2. [Evaluation of Examples and Comparative Examples] (In the case of tea beverage) pH value, color tone: [Table 2] pH L value a value b value ΔΕ Blending unheated product 6. 38 90· 90 -9· 90 29. 49 Reference Example 1 6. 23 89. 25 -8· 44 32. 23 3. 52 Comparative Example 1 6. 19 89. 00 - 8· 14 33. 88 5· 10 It is known from Table 2 that 'Example 1 and In Comparative Example 1, when compared, Comparative Example 1 'apparently the color tone was close to the blended unheated product' maintained a fresh color tone. Further, it was found that the pH value was also maintained in the state in which i was maintained closer to the unheated product. 312XP/Inventive Manual (supplement)/96-11/96126566 28 200821256 Vitamin C Residual Rate · [Table 3] Degree of Sustainability (ppm) Residual Rate (%) Blended Unheated Product 283 100. 0 Example 1 236 83. 4 Comparative Example 1 215 76. 0 1 % 83⁄4 .〇/ 〜 千千You blended unheated product, Example 1 is 83·4%, and Comparative Example 1 7 is entangled from π, 〗 〖76/0 ' The vitamin C residual rate is higher in the case of the obvious embodiment. 4 a hospitality evaluation: [Table 4] Examiner 1 5 identification test corrects 9 ''^ 9 identification test Affected hobby test 'Who good example 1 has 7 people, like comparison case 1 There are 2 j% hazards, the effective difference is within 5% hazard rate, prefer the example (normal temperature filling) Remarks energy zone 7 _ ^ n & 5 Dingqiao stone box and armor, can be divided into examples and comparative examples Among the 9th place, those who like the embodiment have a 'display' and the embodiment is more overwhelming than the preference of the preference. (observation of long-term change) A A 2 L PET bottled green tea beverage prepared in the above Example 1 was stored at 2 °C for 2 weeks, and the microbial deterioration of the contents was visually observed, and the green tea beverage was observed. The condition is good and there is no turbidity caused by poor microbial cross. 312XP/Inventive Manual (Supplement)/96-11/96126566 29 200821256 (In case of 100% orange juice (acidic beverage)) pH value, color tone: [Table 5] Blending unheated product pH L value a value b value ΔΕ 3 61 66. 66 22. 6 42. 98 Reference example 2 3. 51 65. 35 23. 48 42. 61 1. 62 Comparative example 2 3. 51 64. 95 24. 78 42. 2 2. 88 It is understood from the above that when Example 2 is compared with Comparative Example 2, the object of Example 2 is significantly closer to the blended unheated product than Comparative Example 2, and a fresh color tone can be maintained. That is, the 1%% orange juice of Comparative Example 2 was lower in L value (brightness) than in Example 2, the a value (red) was increased, and the b value (yellow) was lowered. Vitamin C Residual Rate: [Table 6] Concentration (ppm) Residual Rate (%) Blended Unheated Product 283 100. 0 Example 2 270 95· 4 Comparative Example 2 245 86. 6 As shown in Table 6, the residual of vitamin C銮铖 ▲ Tianren master t | y, % 仔+ blended unheated product, Example 2 was 95. 4%, and Comparative Example 2 was a rr β. / 〇〇 θ ^ (1) Ma 86 · 6%, apparently Example 2 The vitamin C residual rate was higher in the October condition. (Comprehensive evaluation) For the color tone measurement, the pH value measurement, and the residual rate of vitamin C of the object J 1 2 of Examples 1, 2 and Comparative Examples 1 and 9, it is better to compare only the % of the sample after the electricity g system. For example, and maintaining a fresh color tone, the Vita + his p C residual rate is also high, and it is confirmed that 312 Χ ρ / invention manual (supplement) / 96-11/96126566 30 200821256 can obtain a beverage of excellent quality. Further, even in the results of the examiner functional test of the first embodiment and the comparative example 1, the result of the preference for the article was highly overwhelming, and it was confirmed that the method for producing the packaged beverage of the present invention was applied. The effectiveness of tea drinks and acidic drinks. [Example 3] A PET bottle having a capacity of 2 L was used, and a green tea beverage (ΡΗ5.9, catechin content: 52 mg%) was produced by the above-described production method and apparatus. Xin is the management space for cleaning, filling and sealing the container. Pre-use of a peracetic acid-based drug (trade name: T〇yo Active) at a concentration of 20 °C at 40 ° C for 10 minutes, then use 9 〇 ac The hot water was cleaned and it was confirmed that the bacterium having a general name of "B·subti 1 is, B· coagulans" had a bactericidal effect of 6D or more. In addition, it will be 9 times for hot water. (::, 3 seconds heat-sterilized and cleaned bottle, subjected to 13 5 ° C, 30 seconds high temperature for short-time heat sterilization, then rapidly cooled to room temperature green tea beverage, stored in pre-sterilized and cleaned up content The sterilizing value is higher than the sterilizing value and is passed through the aseptic gas in a positive-pressured storage tank, and is then sent to the top tank by means of sterile gas, and then supplied to the filling machine, and filled in the management space, pre-sterilized by hot water. The bottle is sealed by a bottle cap that has been previously sterilized and cleaned, and the liquid path from the rapid cooler to the filling machine is pressurized with a sterile gas to form a closed path from the outside air. ^ For the green tea beverages that have been manufactured as described above, in order to investigate the green tea color and flavor changes after comparison with the conventional hot-filling method, the pH value, color tone, and vitamin C of green tea were measured. The related hobby system is subjected to a functional test. The results are shown in Table 312XP/Invention Manual (Supplement)/96·11/96126566 31 200821256 7, Table 8 and Table 9. Tone-based assay as above, using the L > ica) | cb > KL star · a star • b star) color system determination purposes. Further, the measurement of vitamin C measures the concentration in the unheated state after blending, and measures the concentration in the beverage immediately after the production, and investigates the residual ratio. The functional test was carried out by a three-point identification method with higher accuracy than the two-point identification method, and two kinds of tea drinks (A of Example 3, A of Comparative Example 3) were prepared, according to AAB, ABB, etc. Appropriate combinations of the three types, and 20 applicators to try to drink, and the identification and hospitable function evaluation of the two. [Example 4] A PET bottle having a capacity of 1·5 L was used, and a 100% orange juice (ρΗ3·61) acidic beverage was produced by the above-described production method and apparatus. In other words, in the management space for cleaning, filling, and sealing the container, a peracetic acid-based chemical (trade name: T〇y〇Active) of φ and a concentration of 2〇〇〇PPm is used for sterilization for 10 minutes, and then 90°c heat is used. Water is cleaned. In addition, the bottle which has been heat-sterilized and cleaned by hot water at 90 ° C for 3 seconds is subjected to high temperature and short-time sterilization at 94·5 to 96 ° C for 30 seconds, and then rapidly cooled to room temperature (this embodiment) In the example, the acidic beverage of 31 ° C to 32 is stored in a storage tank which is pre-sterilized and cleaned up to the sterilization value of the contents and is positively compressed by a sterile gas, and then is the same as in the third embodiment. The method of obtaining a bottled acidic beverage. In addition, the filling temperature in this case is 3 〇 t. Then, as in the case of Example 3, for the acid 312XP/invention specification (supplement)/96-11/ after the production. 96126566 32 200821256 Beverages, the green tea pH and vitamin C were measured by comparing the color tone and flavor change of the acidic beverages prepared according to the conventional hot filling method. The results are shown in Table 1. [Comparative Example 3] In Comparative Example 3, the same capacity 2LipET bottle as in Example 3 was used, and the green tea beverage (PH5.9, catechin content) was produced by the production method and apparatus described in Patent Document 2 described above. Manufacture of 52mg%). The green tea beverage which has been sterilized at 135 ° C for 30 seconds and then cooled to 65 ° C, is placed in an environmental management space that is separated from the outside by a box, and is used under the same conditions as the container. The sterilized/cleaned filling machine and capping machine are filled in a 9 (TC, 3 second hot water sterilized/cleaned bottle and sealed. Then, the PET bottle is filled with green tea by simple cooling water. When the beverage is cooled to a normal temperature, the tea beverage is obtained. The green tea beverage obtained as described above is the same as in the third embodiment after the production (in this case, after cooling), in order to investigate the color and flavor of the green tea. The change was carried out to determine the pH, color tone, and vitamin C of green tea, respectively. Further, according to the same method as in the examples, the identification and functional evaluation of the two were performed using a three-point identification method. These results were recorded together with Example 3. In the case of the comparative example 4, the PET bottle of the same capacity as the case of the example 4 was used, and the manufacturing method of the above-mentioned patent document 2 was used similarly to the comparative example 1. Device, into 100% orange juice (ΡΗ3·61). That is, it will be heat-sterilized by 94.5~96° (:, 30 seconds high temperature for a short time, then cooled to 67~68 312XP / invention manual (supplement) / 96·11 /96126566 33 The acidic beverage of 200821256 °c is placed in an environmental management space that is separated from the outside by the box, and is filled with a filling machine and a capping machine that have been sterilized and cleaned under the same conditions as the container. (: Filled in a 9 (rc, 3 second hot water sterilized and cleaned bottle, and sealed. Then, use a simple cooling water shower to cool the PET bottled acidic beverage to room temperature, then get an acidic drink. With respect to the acidic beverage obtained as described above, the beverage immediately after the production (in this case, after cooling) was measured in the same manner as in Example 4, in order to investigate the color tone and flavor change of the orange juice. pH, color, vitamin C. These results are shown in Table 丨〇, Table 上上上〇 [Evaluation of Examples and Comparative Examples] (in the case of tea beverage) pH value, color tone: [Table 7] pH L value a value b value △ E blended unheated product 6. 44 91. 50 -10.30 30. 05 Reference example 3 6. 30 89. 95 -8· 50 33. 35 3· 69 Comparative example 3 6· 25 88. 91 - 8.20 34. 11 5. 25 It is known from Table 7 that Example 3 and Comparative Example 3 are relatively sleepy, and compared with Comparative Example 3, the color of the sample is similar to that of Comparative Example 3. 'Keep fresh tones. In addition, it is known that the pH value is also the same as that of the unheated product. , 17 cases of 3 vitamin C residual rate: [Table 8] 312XP / invention manual (supplement) / 96-11/96126566 34 200821256 concentration (ppm) residual rate (3⁄4) blended unheated product 305 100. 0 Example 3 260 85. 2 Comparative Example 3 236 77. 4 a As shown in Table 8, the residual rate of vitamins (^ is blended unheated, Example 3 is 85.2%) and Comparative Example 3 is 77.4%, obviously In the case of the example, the vitamin C residual rate is higher. Hobbyist evaluation: [Table 9] Identification test _ Affected 12 hobby test 12 Appraisal test Affected, 8 people who like Example 3 have a preference Example 3: 5% of the 5% risk rate is effective variability (normal temperature filling) Among the 12 digits which can distinguish between the examples and the comparative examples, 8 of the preferred examples are shown, and the examples are shown. (3) The taste of the object is more overwhelming than the preference for the object of Comparative Example 3. (Long-term change observation) 2L PET bottled green tea beverage prepared in the above Example 3 was stored at room temperature for 2 weeks. According to the visual observation of the microbial deterioration state of the contents. The result 'observed that the green tea beverage was in good condition. There is no turbidity caused by microbial deterioration. (100% orange juice (acidic beverage)) pH, color tone: 312XP / invention manual (supplement) / 96-11/96126566 35 200821256 [Table 10] pH L value a value b value △ E blended unheated product 3· 55 67. 61 22. 00 43· 32 Reference example 4 3· 46 65· 90 24· 10 43. 01 2. 73 Comparative example 4 3. 46 65 03 25· 04 42. 60 4. 05 - It is known from Table 10 that when Example 4 is compared with Comparative Example 4, the material of Example 4 is significantly closer to the blended unheated product than Comparative Example 4. The fresh color tone can be maintained. That is, the 1%% orange juice of Comparative Example 4 has a lower L value (brightness), a value (red) rises, and _1) value (yellow) compared to the example 4. reduce. Vitamin C Residual Rate: [Table 11] Concentration (ppm) Residual Rate (%) Blended Unheated Product 320 100. 0 Example 4 295 92. 2 Comparative Example 4 276 86. 3 As shown in Table 11, the residual of vitamin C The rate was adjusted to the unheated product, and the actual example 4 was 92. 2%, while the comparative example 4 was 86.3%, and the vitamin c residual rate was significantly higher in the case of Example 4. (Comprehensive evaluation) / Regarding the color tone measurement, the pH value measurement, and the vitamin C residual ratio of Examples 3 and 4 and Comparative Examples 3 and 4, it was confirmed that the examples were superior to the comparative examples, and the color tone was kept fresh. The residual rate of vitamin C is also high, and a beverage of superior quality can be obtained. Moreover, even in the case of the tester g of the third embodiment and the comparative example 3, the result of the test is 312XP/invention specification (supplement)/96-11/96126566 36 200821256 As a result of this, it is confirmed that the method of applying the method of applying the method of the present invention to the tea beverage and the acidic beverage. (Industrial Applicability) The method for producing a container-packed beverage of η can be used for beverages such as green tea and oolong tea, such as _·6 and 含有 含有 含有 , 6 6 6 6 6 6 6 6 6 6 6 6 The manufacture of container-packed beverages for non-rich nutritious beverages after heating. The crying is not limited to synthetic resin bottles such as PET bottles, but is also applicable to metals. Bottles, metal cans, glass bottles, etc. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a manufacturing system for carrying out a method for producing a packaged beverage according to an embodiment of the present invention. Fig. 2 is a flow chart showing an embodiment of a method for producing a packaged beverage according to the present invention. The illustration of the sterilization and cleaning method of the present invention which is carried out using a chemical in a clean box as an environmental management. Figure 4 is a flow chart showing another embodiment of the method for manufacturing a container-packed beverage of the month I. [Main component symbol description] 1 Pharmacy tank 3 2 Warm water tank draining Cao 6 7 Flow path switching valve drug supply pipe 312XP / invention manual (supplement) /% seven /96126566 37 200821256 8 Warm water supply pipe 10 bottles sterilization And cleaning equipment 11 Filling machine 12 Capping machine 14 Environmental management space 15 Clean box 16 Rotary hot water jet nozzle 17 Fixed hot water jet nozzle 20 Blending tank 21 Equalization tank 22 South temperature short time killer 23 Rapid cooler 25 Storage tank 26 top slot

312XP/發明說明書(補件)/9641/96126566 38312XP / invention manual (supplement) /9641/96126566 38

Claims (1)

200821256 十、申請專利範圍: 1. 一種容器裝飲料之製造方法,其特徵在於包括有:預 先將對容器及瓶蓋施行殺U清洗、填充及密封的周邊環 & ’使用65°C〜lGGt熱7jc或藥劑,施行加熱殺菌及清洗 时驟;對冷卻機、儲存槽及截至填充機為止的送液路 徑,在所填充飲料之加熱殺菌條件同等級以上的條件下, 預先化行加熱殺g及清洗的步驟;以及將容器與瓶雲至少 内面’利用阶〜丨_溫水施行加熱殺g及清洗的;驟; 而將所填充的飲㈣行加熱㈣直到達既定殺菌值後,再 急速冷卻至常溫’將該經冷卻的飲料儲存於上述儲存押 中’藉由㈣容液送人於上述填充機中,使上述送液路^ 开f成不會從外部渗人空氣的封閉路徑,且形成將上述周邊 %境與外界隔離的環境管理空間,並在該管理空間中,將 上述飲料於常溫下填充於上述殺菌過容器中,並加以宓 封。 山 2. 如申請專利範圍第丨項之容器裝飲料之製造方法,豆 ::上述飲料係pH4.6以上且兒茶素含有量以上的 純料们阶、7.58秒同等級以上的殺菌值施 订加熱殺菌。 3. 如申請專利範圍第丨項之容器歧料之製造方法,里 312XP/mmm(mm/96^1/96126566 39 200821256 5. 如申請專利範圍第1項之容器裝飲料之製造方法,其 中,上述儲存槽係透過無菌氣體而保持正壓,從該儲存槽 往填充機的液體輸送係利用無菌氣體施行壓送。 6. 如申請專利範圍第1項之容器裝飲料之製造方法,其 ^ 中,對周邊環境使用藥劑施行加熱殺菌及洗淨後的清洗, 係使用65义〜100°C溫水,且其亦兼具殺菌功能。 7. 如申請專利範圍第1項之容器裝飲料之製造方法,其 中,將對容器與瓶蓋殺菌清洗、填充及密封的周邊環境, 馨預先施行殺菌及清洗的藥劑,係使用過醋酸系藥劑、過氧 化氳、臭氧系藥劑、含次氯酸的氯系殺菌劑中之任一者。200821256 X. Patent application scope: 1. A method for manufacturing a container-packed beverage, which comprises: pre-treating a container and a bottle cap to clean, fill and seal the peripheral ring & 'Use 65 ° C ~ lGGt Heat 7jc or medicinal agent, performing heat sterilization and cleaning; the liquid feeding path to the cooling machine, the storage tank and the filling machine is preheated and heated under the condition that the heating and sterilizing conditions of the filled beverage are the same or higher. And the step of cleaning; and at least the inner surface of the container and the bottle cloud is heated and killed by using the step ~ 丨 _ warm water; and the heated (four) line of the filled drink (four) is heated until the predetermined sterilization value is reached, and then the rapid Cooling to normal temperature 'storing the cooled beverage in the above-mentioned storage hopper' is sent to the filling machine by the liquid (4), so that the liquid supply path is opened to a closed path that does not infiltrate the air from the outside. And forming an environmental management space that isolates the surrounding environment from the outside, and in the management space, the beverage is filled in the sterilization container at a normal temperature, and is sealed. 2. The method for producing a packaged beverage according to the scope of the patent application, the bean: the above-mentioned beverage is a sterilizing value of a grading amount of 4.6 or more and a catechin content of more than 7.5 sec. Order heat sterilization. 3. The manufacturing method of the container material according to the scope of the patent application, 312XP/mmm (mm/96^1/96126566 39 200821256 5. The method for manufacturing a containerized beverage according to claim 1 of the patent scope, wherein The storage tank is maintained at a positive pressure by a sterile gas, and the liquid transport from the storage tank to the filling machine is pressurized by a sterile gas. 6. The method for manufacturing a packaged beverage according to claim 1 of the patent scope is For the use of the medicinal agent in the surrounding environment, the sterilizing and washing after washing, the use of 65 ° ~ 100 ° C warm water, and it also has a bactericidal function. 7. Manufacture of the containerized beverage according to the scope of claim 1 A method in which a container for sterilizing, filling, and sealing a container and a cap is sterilized and cleaned in advance, and a peracetic acid-based agent, a cerium peroxide, an ozone-based agent, or a hypochlorous acid-containing chlorine is used. Any of the fungicides. 312XP/發明說明書(補件)/96-11/96126566 40312XP/Invention Manual (supplement)/96-11/96126566 40
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CN112079311B (en) * 2015-12-22 2022-06-28 大日本印刷株式会社 Method for converting sterilization treatment and product filling device
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