WO2007143785A1 - Système et dispositif pour introduire de l'ozone dans un appareil de lavage - Google Patents

Système et dispositif pour introduire de l'ozone dans un appareil de lavage Download PDF

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Publication number
WO2007143785A1
WO2007143785A1 PCT/AU2007/000829 AU2007000829W WO2007143785A1 WO 2007143785 A1 WO2007143785 A1 WO 2007143785A1 AU 2007000829 W AU2007000829 W AU 2007000829W WO 2007143785 A1 WO2007143785 A1 WO 2007143785A1
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WO
WIPO (PCT)
Prior art keywords
ozone
fluid conduit
generator
wash liquid
wash
Prior art date
Application number
PCT/AU2007/000829
Other languages
English (en)
Inventor
Kevin Nagle
Peter Von Konigsmark
Paul Moutzouris
Original Assignee
Ozone Technologies Pty Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ozone Technologies Pty Limited filed Critical Ozone Technologies Pty Limited
Publication of WO2007143785A1 publication Critical patent/WO2007143785A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10—Preparation of ozone
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/001—Washing machines, apparatus, or methods not otherwise provided for using ozone
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/58—Indications or alarms to the control system or to the user
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/58—Indications or alarms to the control system or to the user
    • D06F2105/60—Audible signals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F34/00—Details of control systems for washing machines, washer-dryers or laundry dryers
    • D06F34/28—Arrangements for program selection, e.g. control panels therefor; Arrangements for indicating program parameters, e.g. the selected program or its progress

Definitions

  • the present invention relates generally to systems and devices for using ozone in washing applications. More specifically, the present invention relates to a system for introducing ozone into a washing apparatus, a device adapted for use in the system, and a method of washing items using said device or system.
  • Ozone (O 3 ) is comprised of three oxygen atoms, generally formed when a single oxygen atom collides with O 2 .
  • hydroxyls and hydroxyl radicals are formed when the ozone strips hydrogen atoms from wash liquid molecules (H 2 O), forming hydroxyl (OH).
  • the hydroxyl consists of a hydrogen atom and an oxygen atom with a shared electron.
  • a little hydrogen peroxide (H 2 O 2 ) is also typically formed, which helps with bleaching and disinfection.
  • a radical also called a. "free radical” is a cluster of atoms, one of which contains an unpaired electron in its outermost shell of electrons.
  • the complex, fast and poly-facetic reactions caused by ozone within the laundry context make it a particularly beneficial additive to a wash liquid for a laundry process.
  • ozone is produced by passing air through a high voltage electrical discharge, or corona.
  • a minimum of 5,000 volts of electricity is generally necessary to create the corona (14,000V is a practical design maximum voltage).
  • Air (containing 21% O 2 ) or concentrated oxygen (95% pure oxygen) dried to a minimum of - 60 0 C dew point passes through the corona. This causes the O 2 bond to break, freeing single oxygen atoms which then collide and temporarily bond with other O 2 molecules to create O 3 .
  • Ozone production can be regulated by adjusting either the applied voltage or feed-gas flow.
  • ozone concentration is increased, but the overall production rate decreases.
  • Reducing the applied voltage decreases concentration.
  • the ozone/gas mixture discharged from the CD ozone generator normally contains from 1% to 3% (by weight) ozone when using dry air, and 3% to 6% (by weight) ozone when using high purity oxygen as the feed-gas.
  • the feed-gas for the generator should have particulate material and moisture removed as a minimum. Any contaminants present in the gas stream build up quickly and affect the electrical discharge. Moisture in the feed-gas causes two serious problems. First, moisture will cause a significant drop in ozone production.
  • Feed-gas must be dried to below -63°C dew point to ensure that this does not occur.
  • Moisture can be removed by passing the air through molecular sieves, activated alumina, silica gel, or by a combination of refrigeration and desiccation.
  • oxygen molecule When an oxygen molecule (O 2 ) absorbs a photon of light with a wavelength shorter than 200 nanometers the energy splits the molecule into two oxygen atoms (2 x O).
  • the UV lamp in ultra violet (UV) lamp ozone generators, is preferably designed to generate light at a wavelength of about 185nm. This wavelength breaks apart the oxygen molecule and generates free oxygen atoms, and ozone is produced as described above. Dry, clean air is not necessary for use with UV lamps which makes such lamps more suitable for use in the laundry. UV lamps will produce ozone with little reduction in ozone concentration in most ambient air conditions. Over a period of time (generally 8000 hours of use), the lamps solarise and ozone output may reduce to 20% of the original.
  • the UV lamps are typically encased in a stainless steel, aluminium or PVC housing (approximately 50mm in diameter), and ambient air is fed through the housing via an air pump. As the air flows over the enclosed UV lamps, ozone is produced from the oxygen in the air and transferred to the wash liquid. Ozone production can be regulated by adding or removing UV lamps or adjusting the air flow.
  • laundry systems can be broken down into at least two broad categories. Some systems, referred to as “closed-loop laundry systems”, recycle the wash liquid used during each cycle of the wash load. Others apply an “open-loop laundry system”, in which the laundry waste wash liquid is drained after each wash cycle and after each rinse cycle of the laundry wash process.
  • ozone is introduced into the wash liquid before the wash liquid comes into contact with the items to be washed.
  • this is achieved by having ozone introduced or injected into the wash liquid via an open ended pipe.
  • ozone is typically more quickly absorbed by wash liquid when the bubble size is minimised, preferably in the form of micro-bubbles, the draw back of this system is that absorption of ozone is slow.
  • ozone is introduced into the washing machine with the assistance of a venturi injector in the wash liquid line.
  • Other conventional systems for introducing ozone into washing machines include a diffuser at the base of the wash cavity, which injects ozone bubbles up through the wash liquid which disperse or dissolve in the wash liquid. A problem with such systems is that the diffuser may become blocked with lint and scale, severely reducing the integration of ozone into the liquid.
  • ozone is introduced into the wash liquid during the washing step only, so as to reduce the consumption of ozone gas.
  • introducing ozone for such a short period in the entire wash cycle may prevent the limited amount of ozone used from working to its potential or achieving the desired result.
  • mix when used in the context of the invention, includes combine, blend, disperse, dissolve, or any combination of these.
  • Conduit when used in the context of this invention, means a tube, hose, pipe, channel, duct, or other similar means for transmitting fluid, or a combination of any of these.
  • Fluid when used in the context of this invention, may mean a gas or liquid (depending on the context) and, in particularly preferred embodiments, means gas. Accordingly, "fluid conduit” preferably means a tube, hose, pipe, channel or duct capable of transmitting a liquid or gas.
  • venturi is a means, device or altered physical configuration of a portion of a conduit, tube, channel, duct, or like fluid transmission means, adapted to effect a reduction in pressure in the vicinity of the means, device or altered physical configuration which is capable of drawing a fluid (ie liquid or gas) in the direction of the means, device or altered physical configuration.
  • wash cycle in conventional systems, typically includes several phases or steps including, pre-wash, main wash, and one or more rinse phases or steps.
  • wash cycle is not intended to limit the number or order of phases or steps which the wash cycle may include.
  • the wash cycle of preferred embodiments typically commences when a user initiates the washing process, by for example, pressing the "start” button of the washing apparatus, and ends on completion of the last phase or step, for example, the last rinse phase.
  • the present invention provides a system for introducing ozone into a washing apparatus, the system comprising: ozone supply means; and ozone delivery means including: a first fluid conduit adapted to transfer ozone from the ozone supply means to a wash liquid inlet means, said wash liquid inlet means adapted to deliver wash liquid to a wash chamber of the washing apparatus, and a second fluid conduit adapted to deliver ozone to an above-liquid region of the wash chamber; wherein said system is adapted so that, during a wash cycle, ozone is introduced: into the wash chamber via the wash liquid inlet means, mixed in the wash liquid, and into the above-liquid region of the wash chamber via the second fluid conduit.
  • a first end of the second fluid conduit is connected to the first fluid conduit so that the second fluid conduit is in fluid communication with the first fluid conduit.
  • This connection between the first end of said second fluid conduit and the first fluid conduit may be a substantially T-shaped connection located intermediate two ends of the first fluid conduit.
  • Some preferred embodiments of the system further include gas redirection means adapted to substantially inhibit ozone from being introduced into the wash chamber via the second fluid conduit while wash liquid is being introduced into the wash chamber via the wash liquid inlet means.
  • the gas redirection means of preferred embodiments is a venturi adapted to draw ozone into the wash liquid inlet means.
  • the venturi (aided by forces created by wash liquid running past) effects a reduction in pressure in the vicinity of a junction between the first fluid conduit and the wash liquid inlet means, drawing ozone from the first fluid conduit into the wash liquid inlet means, mixing the ozone with the wash liquid.
  • the wash liquid inlet means typically communicates with an outlet from a water supply, such as the main water supply to a laundry.
  • a water supply such as the main water supply to a laundry.
  • the wash liquid inlet means may communicate with a separate reservoir containing wash liquid (eg water and detergent).
  • the system is further adapted so that, during the wash cycle, after the wash liquid has been introduced into the wash chamber, the ozone is introduced into the wash chamber via the second fluid conduit.
  • the ozone may be delivered into the ozone delivery means via a single outlet.
  • the system of the present invention further includes a pump adapted to deliver ozone into the ozone delivery means.
  • the pump may be interposed between the ozone supply means and the ozone delivery means.
  • positive pressure created by the pump enhances mixing of ozone into the wash liquid.
  • the ozone delivered via the second fluid conduit is provided to the wash chamber through a vent in the washing apparatus.
  • the ozone supply means may be adapted to supply ozone in response to a signal that the washing apparatus has been activated.
  • the activation signal is an electrical signal.
  • the ozone supply means is preferably an ozorie generator.
  • the ozone generator generates ozone by exposing air to ultraviolet light and, in particularly preferred embodiments, to ultraviolet light of a wavelength sufficient to generate from the air oxygen atoms capable of colliding with oxygen molecules to form ozone.
  • the wavelength of the ultraviolet light ranges from about 150nm to about 280nm and, in particularly preferred embodiments, the wavelength is about 185nm.
  • the washing apparatus is a laundry washing machine.
  • the system of the present invention could also be adapted for use with multiple washing machines, wherein there is at least one ozone delivery means for each washing machine.
  • the system of the present invention is not limited to use with laundry washing machines and it.could also be applied to other washing applications.
  • an ozone delivery arrangement for delivering ozone from an ozone supply means to a washing apparatus connected to wash liquid inlet means
  • said ozone delivery arrangement comprising: a first fluid conduit, for transferring ozone from the ozone supply means to the wash liquid inlet means; a mixer connection, connecting the first fluid conduit to the wash liquid inlet means, said mixer connection adapted to enable ozone to flow into the wash liquid inlet means and mix with wash liquid flowing through the wash liquid inlet means; and a second fluid conduit adapted to transfer ozone to a wash chamber of the washing apparatus when wash liquid ceases flowing through the wash liquid inlet means.
  • the second fluid conduit is preferably adapted to transfer the ozone to an above- liquid region of the wash chamber.
  • a first end of the second fluid conduit is connected to the first fluid conduit so that the second fluid conduit is in fluid communication with the first fluid conduit.
  • the connection between the first end of said second fluid conduit and the first fluid conduit may be a substantially T-shaped connection located intermediate two ends of the first fluid conduit.
  • the mixer connection is a venturi connection.
  • either or both of the first and second fluid conduit(s) comprise(s) a hose, a tube, a pipe or a combination of these.
  • a method of installing an ozone delivery arrangement of the second aspect of this invention comprising: connecting a first end of the first fluid conduit to an outlet of the ozone supply means; connecting a second end of the first fluid conduit to the wash liquid inlet means with a mixer connection adapted to enable ozone to flow into the wash liquid inlet means and mix with wash liquid flowing through the wash liquid inlet means; positioning a first end of the second fluid conduit so as to enable it to receive ozone from the ozone supply means; and connecting a second end of the second fluid conduit to the washing apparatus; wherein the installed ozone delivery arrangement is adapted to transfer ozone from the ozone supply means to the wash liquid inlet means, via the first fluid conduit, when wash liquid flows through the wash liquid inlet means, and to transfer ozone to the wash chamber, via the second fluid conduit, when wash liquid ceases flowing through the wash liquid inlet means.
  • the ozone transferred to the wash chamber is transferred to an above-liquid region of the wash chamber.
  • the present invention provides an ozone generator adapted for use in the system of the first aspect of this invention, the ozone generator comprising: air inlet means adapted to receive air, a controller adapted to cause at least one ultraviolet light source to expose received air to ultraviolet light in response to an activation signal corresponding to activation of the washing apparatus, and ' : ozone outlet means adapted to deliver generated ozone to the ozone delivery means.
  • the activation signal is an electrical signal.
  • the abovementioned controller is preferably further adapted to monitor, and indicate any deficiency or malfunction of, the function of each ultraviolet light source.
  • an indication of deficiency or malfunction of an ultraviolet light source is provided by illuminating a first indicator light associated with the generator.
  • the air inlet means may further include a pump adapted to deliver air into the generator under the control of the controller.
  • the controller is further adapted to monitor, and indicate any deficiency or malfunction of, the function of the pump.
  • an indication of deficiency or malfunction of the pump is provided by illuminating a second indicator light associated with the generator.
  • the controller is further adapted to monitor and measure the concentration of ozone in ambient air outside the system, the measurements being provided by an ozone sensor.
  • the controller is adapted to indicate if the ozone concentration measured by the ozone sensor exceeds a predetermined level, typically about O.IOppm ozone gas.
  • An indication that the predetermined level has been exceeded is preferably provided by illuminating a third indicator light associated with the generator.
  • the above generator may further include an audible alarm which, under the control of the- controller, is adapted to sound when the controller detects a deficiency or malfunction in one or more components of the generator.
  • the audible alarm is adapted to be sounded when the controller detects: any deficiency or malfunction of the function of an ultraviolet light source, any deficiency or malfunction of the function of the pump; and/or that the concentration measured by the ozone sensor has exceeded the predetermined level.
  • the generator may further include reset means adapted to turn-off the alarm when activated by a user.
  • the generator may include data logging means adapted to log generator activities selected from the group consisting of generator on, generator off, generator power-up, pump OK, pump deficiency or malfunction, ultraviolet light source OK, ultraviolet light source deficiency or malfunction, reset means activated.
  • a method of washing material in a washing apparatus connected to wash liquid inlet means comprising: providing wash liquid to a washing chamber of the washing apparatus via the wash liquid inlet means, said wash liquid including a material cleaning-effective amount of ozone; and after the wash liquid has been provided to the washing apparatus, and whilst the washing apparatus is in a wash cycle, providing ozone to an above-liquid region of the washing chamber.
  • Figure 1 is a schematic representation of the system of a preferred embodiment of the invention.
  • Figures 2A, 2B and 2C are simplified representations of part of the system of a preferred embodiment of the invention, illustrating how ozone from the second fluid conduit may be mixed into the wash liquid with the aid of kinetic forces from wash activity in the wash chamber.
  • Figure 3 is a graphical representation showing comparisons of O 3 concentration versus time (in the wash cycle) for a typical corona discharge system and for a UV light source of a system of a preferred embodiment of the present invention.
  • Figure 4 is a graphical representation showing comparisons of O 3 concentration versus time (in the wash cycle) in the wash liquid as delivered by the first fluid conduit (via the wash liquid inlet means) and the second fluid conduit respectively in the system of a preferred embodiment of the invention.
  • Figures 5A and 5B are schematic representations of various views of an ozone generator of one preferred embodiment of the invention.
  • Figure 5C is a schematic representation of the ozone generator of Figure 5A and 5B showing a preferred wiring arrangement.
  • Figure 6 is a schematic representation of one preferred configuration of the system incorporating a power control means.
  • Figure 7 is a schematic representation of a power control means of a preferred embodiment.
  • Figure 8 is a preferred circuit layout for one embodiment of the power control means of the present invention. Mode(s) for Carrying Out the Invention System
  • Generated ozone is then delivered to or pumped into first fluid conduit 14, where it is free to travel between the ozone generator 11 and wash liquid inlet means 15 (adapted to deliver wash liquid 20 to the wash cavity 30 of a washing apparatus 40); and/or along a second fluid conduit 16 between the ozone generator 11 and an above-liquid section 31 of the wash cavity 30.
  • a first end of the second fluid conduit 16 is connected to the first fluid conduit 14 so that the second fluid conduit 16 is in fluid communication with the first fluid conduit 14.
  • This connection may be a substantially T-shaped connection 13.
  • the ozone generator 11 operates under control of a control means 71.
  • the control means 71 is discussed in more detail below.
  • the control means 71 is adapted to cause the ozone generator 11 to turn on in response to an activation signal corresponding to activation of the washing apparatus 40.
  • the wash cavity 30 begins to fill with wash liquid from wash liquid outlet 60.
  • the control means 71 has now activated the ozone generator 11 , and generated ozone is being pumped or delivered into the first fluid conduit 14, generated ozone is available for being mixed in wash liquid being delivered to wash cavity 30.
  • a venturi injector 17 is operably coupled to the wash liquid inlet means 15 so as to draw generated ozone into the wash liquid as the wash liquid is delivered into the wash cavity 30. Consequently, in this preferred embodiment, generated ozone is typically inhibited from entering the second fluid conduit 16 while the wash cavity 30 is being filled with wash liquid from the wash liquid outlet 60.
  • generated ozone is then free to be delivered via the second fluid conduit 16 to the above- liquid section 31 of the wash cavity 30.
  • generated ozone that has been introduced into the above-liquid section 31 is available to be mixed into the wash liquid 20, aided by kinetic forces from wash activity in the wash cavity 30.
  • the system 10 of preferred embodiments is, therefore, only required to generate small amounts of ozone in order to maintain a relatively consistent concentration of ozone sufficient to contribute to the washing process.
  • generated ozone is preferably mixed in the wash liquid 20 by the first fluid conduit 14 at a rate of about 0.05 to 0.2 ppm dissolved ozone.
  • the system 10 may further include a pump 18 adapted to pump generated ozone into the first fluid conduit 14.
  • the pump 18 is operably connected to the ozone generator 11 such that it is adapted also to deliver ambient air into the ozone generator 11 for conversion to ozone.
  • the pump 18 is interposed between the ozone generator 11 and first fluid conduit 14.
  • Generated ozone is then drawn into the wash liquid inlet means 15 via negative pressure in the venturi injector 17, and is also pressurised into the venturi injector 17 via the air pump 18. This increases the absorption of ozone by the wash liquid as per Henry's law in some such preferred embodiments.
  • the form of the equilibrium constant shows that the concentration of a solute gas in a solution is directly proportional to the partial pressure of that gas above the solution.
  • the system 10 uses an ozone generator 11 reliant on a UV light source 12 to generate, ozone.
  • a UV light source 12 to generate, ozone.
  • Figure 3 provides a graphical illustration of a comparison in concentration of ozone generated by corona discharge versus UV light source.
  • Table 1 (below) provides a tabulated form of the data illustrated in the graphical representation, with reference to the various activities comprising the wash cycle. Table 1:
  • a comparison of ozone concentrations between a corona discharge system and a UV light system (Based on field testing with a ozone detection kit, for example, one such as that manufactured by the HACH Company)
  • CT value is the disinfectant concentration required to inactivate a certain microbiological population percentage under specific conditions (i.e., pH, temperature) according to, for example, the Chick-Watson model of disinfection kinetics. This value is used as an index to the effectiveness of the disinfection process.
  • Scientific guidelines such as CT Values are used as a standard of measurement for applications such as treatment of drinking water, and are generally accepted in a range of jurisdictions by, for example, the US Environmental Protection Agency (EPA), Occupational Safety and
  • Ozone disinfection systems achieve adequate disinfection with a CT of 1.6 or greater.
  • Adequate disinfection may not occur when:
  • the quantity of ozone introduced into the wash liquid is too low to reach the proper CT value.
  • the concentration of applied ozone is too low to achieve the proper CT value.
  • the wash liquid temperature is too high (above 50 0 C) causing rapid decomposition of ozone.
  • the microbiological and/or organic content of the wash liquid is too high for the available ozone.
  • the system 10 preferably introduces ozone into the wash liquid 20 by the first fluid conduit 14 (delivering ozone to wash liquid via wash liquid inlet means 15) and by the second fluid conduit 16 (delivering ozone into the above-liquid section 31 of the wash cavity 30).
  • Figure 4 provides a graphical illustration of the differences in the concentration of ozone over time (during the wash cycle) in the wash liquid 20 as delivered by the first fluid conduit 14 (via the wash liquid inlet means 15) and the second fluid conduit 16, respectively.
  • Table 2 (below) provides a tabulated form of the data illustrated in the graph in Figure 4.
  • the system 10 also improves on conventional systems by enhancing the safety of personnel and equipment.
  • Table 3 (below) provides an analysis of a test for free ozone in the work environment which was conducted using the system 10 of preferred embodiments. As can be seen, the table illustrates various locations in the vicinity of the washing apparatus 40. Table 3
  • the very small concentration of ozone in the washing apparatus 40 will minimise damage to the laundry equipment as the corrosive effect of the ozone is less than that of the laundry chemicals.
  • the system 10 of the present invention can be installed on any size of laundry machine from domestic top-loading 5kg machines to 1000kg per hour batch washers.
  • the installation of equipment to the system 10 is relatively straightforward.
  • the laundry can continue to operate while the installation takes place. Downtime of the laundry is thereby minimised.
  • the system 10 may also be adapted to operate in a range of different water and/or wash liquid conditions, air temperatures and humidity.
  • Ozone generator Preferred embodiments of the present invention also include an ozone generator 11 adapted for use in the system 10.
  • Figure 5A and B are schematic representations of various views of an ozone generator 11 of a preferred embodiment of the present invention.
  • Figure 5C is a schematic representation of the ozone generator 11 of Figure 5A and B showing a preferred wiring arrangement.
  • the ozone generator 11 comprises an air inlet means 70 adapted to receive air (including ambient air), a control means 71 adapted to cause at least one ultraviolet light source 12 to expose received air to ultraviolet light in response to an activation signal corresponding to activation of the washing apparatus 40, and an ozone outlet means 72 adapted to deliver generated ozone to the first fluid conduit 14.
  • the air inlet means 70 and ozone outlet means 72 are respectively connected to opposing sides of a tube 73.
  • the tubes 73 may be formed of any suitable material, including metals or plastics or combinations of these.
  • the tubes 73 are formed of aluminium.
  • One end of one of the tubes 73 has an aperture 74, for receiving a UV lamp 75.
  • the UV lamp 75 may be held in place via an ozone resistant "O" - ring (not shown) and if desired a plastic collar (not shown) may be engaged in the body of the tube 73.
  • Each tube 73 itself may further include two end caps 78 and 79 respectively.
  • One end cap 78 incorporates the aperture 74 for receiving the UV lamp 75.
  • the other end cap 79 has a shape, such as an indentation, which corresponds to the shape of an end of the UV lamp 75.
  • An example of a suitable UV lamp 75 is one produced by Heraeus, a German company, and is identified by product number UW480HO.
  • the ozone generator 11 may further include a ballast means 80 for providing energy to the UV lamp 75.
  • the ballast means 80 is preferably a digital ballast.
  • An example of an appropriate digital ballast is that produced by Tridonic with product No. PC1 /26/32/42 TCT PRO.
  • the UV light source 12 is comprised of the UV lamp 75 and the ballast means 80.
  • the components of the ozone generator 11 are preferably housed in a housing 81.
  • the housing 81 includes at least one aperture 82 for ventilation.
  • the housing may include multiple apertures 82 for ventilation.
  • a pump 18 may be incorporated into the ozone generator 11 , or it may be adapted to operably communicate with the ozone generator 11.
  • the pump 18 may serve the dual purpose of causing ambient air to be delivered into the ozone generator 11 and increasing the pressure with which generated ozone is delivered into the first fluid conduit 14.
  • An example of a suitable pump 18 for use with the present invention is that produced by Hailea, known as the Oil-Less 40LPM Diaphragm Air Pump.
  • the pump 18 may further include an electrical connection 86 adapted to draw power to operate the pump 18.
  • Some preferred embodiments of the ozone generator 11 and/or system 10 further include an ozone concentration sensor (the connection for which is identified with reference numeral 87) adapted to measure the concentration of ozone in ambient air surrounding the washing apparatus 40.
  • an ozone concentration sensor is that produced by Aeroqual, identified as the series-100 ozone sensor.
  • the control means 71 is adapted to cause at least one ultra violet light source 12 to expose received ambient air to ultra violet light in response to an activation signal corresponding to activation of the washing apparatus 40.
  • the control means 71 may also be responsible for the control and monitoring of other functions of the ozone generator 11.
  • control means 71 controls power to, and monitors function of, the UV light source 12, and controls, and monitors the function of, the pump 18.
  • the control means 71 may further monitor and control the ozone concentration sensor.
  • the ozone generator 11 is typically connected to a power control means 90.
  • the power control means 90 generally supplies power to the ozone generator 11 and its operation is discussed in more detail below.
  • the power control means 90 When the power control means 90 senses that the washing apparatus 40 is operating, it sends an activation signal to the control means 71, which in turn switches on the pump 18 and UV light source 12. The power control means 90 releases the activation signal when the washing apparatus 40 has stopped.
  • the ozone generator 11 is typically fed mains power by the power control means 90. However, the ozone generator 11 is only considered to be “running" whilst the activation signal is received by the power control means 90.
  • control means 71 Upon receiving the activation signal from the power control means 90, the control means 71 supplies power to each of the UV lamps 75 in the generator 11.
  • the ozone generator 11 includes at least one indicator light 83 adapted to illuminate to warn a user of a particular condition of one of the components of the ozone generator 11. (When this activation signal is received, the control means 71 lights a fourth indicator light 83D).
  • different size ozone generators may have different numbers of UV lamps.
  • the number of indicators 83A will correspond to the number of UV lamps 75 in a particular embodiment. Each indicator 83A will remain on while its UV lamp 75 is operating correctly.
  • the control means 71 detects failure of the lamp 75 and, for example, disconnection of the connection between the ballast means 80 and the corresponding UV lamp 75. If a UV lamp 75 is not operating, the control means 71 causes the audible alarm speaker 84 to sound an alarm and flashes the relevant indicator 83 for that UV lamp 75.
  • the indicator 83A continues to flash until the lamp 75 is operational or the reset switch 85 has been activated. In some preferred embodiments, the indicator 83A shall continue to flash even after the power control means 90 has released the activation signal.
  • the control means 71 Upon receiving the activation signal from the power control means 90, the control means 71 supplies power to the pump 18. The pump 18 remains on until the power control means 90 releases the activation signal. There is an indicator 83B that is lit whilst the pump 18 is operating. The pump 18 is typically externally mounted and plugs into the generator 11. The control means 71 monitors the current fed to the pump 18 and detects when the pump is not operating (eg due to disconnection). If this occurs, the control means 71 causes the audible alarm speaker 84 to sound an alarm and flashes the pump indicator 83B. The indicator 83B will continue to flash until the pump 18 is operational. The alarm will sound until the pump 18 is operational or the reset switch 85 is activated.
  • the audible alarm speaker 84 sounds an alarm whenever an error connection is triggered and shall continue to sound until the user activates the reset switch 85 or until the error is corrected.
  • the indicator relating to that error condition shall continue to flash until the error is corrected, or until power to the generator 11 is removed. If a new alarm condition is triggered after a previous alarm condition has been silenced, the audible alarm speaker 84 shall sound again, until the new alarm condition is reset.
  • the ozone concentration sensor (the connection for which is identified with reference numeral 87) is incorporated, this sensor is preferably powered and controlled by the control means 71. An alarm is sounded and the third indicator light 83C flashes if ozone levels in the ambient air around the washing apparatus 40 exceed a predetermined level of ozone. In Australia, the predetermined level would typically be the Australian standard of 0.10 ppm ozone gas in ambient air.
  • the factors indicated by the first, second, third and fourth indicator lights 83A, 83B, 83C and 83D are examples of the types of factors which would desirably be monitored by the ozone generator 11.
  • the present invention contemplates further indicator lights associated with monitoring and indicating the status of other components of, or factors associated with, the ozone generator 11 or system 10.
  • the ozone generator 11 may further include a cooling fan adapted to inhibit the ozone generator 11 and/or control means 71 from exceeding a predetermined temperature.
  • the ozorie generator 11 may also include data logging means adapted to log ozone generator 11 activities.
  • the data logging means comprises a quantity of nonvolatile memory for data logging.
  • a plurality of events within the generator 11 are logged to the non-volatile memory with a time and date stamp in preferred embodiments.
  • the memory is, preferably, erasable under firmware control.
  • the non-volatile memory is sufficiently large to store at least 20 events per day for a period of at least 3 years. Examples of generator 11 activities that may be logged by the data logging means include generator on, generator off, generator power-up, pump ok, pump deficiency or malfunction, ultraviolet light source ok, ultraviolet light source deficiency or malfunction, and reset switch activated.
  • control means 71 provides an RS-232 port 200 for connection to a PC for transmission of logged data.
  • this communication port operates at 115-200 bps and provides hardware handshaking via RPS/CPS RS 232 control lines.
  • the connector is preferably a female DB 9, mounted on the generator housing 81, and wired into the control means 71.
  • the generator 11 may further include a real time clock means for time keeping.
  • the real time clock means keeps track of time and assists in the time and date stamp function of the data logging means.
  • the system 10 or the ozone generator 11 further includes power control means 90.
  • the power control means 90 is adapted to monitor the power supply supplying the washing apparatus 40 and to convey the activation signal (corresponding to activation of the washing apparatus 40) to the control means 71.
  • the power control means 90 monitors the power fed to the washing apparatus 40 using a contactless current sensor.
  • a schematic representation of a preferred configuratipn of the power control means 90 incorporated into the system 10 is provided in Figure 6, a schematic representation of the preferred power control means 90 is shown in Figure 7, and a preferred circuit layout for one embodiment of a power control means 90 is shown in Figure 8.
  • the power control means 90 is preferably adapted to connect with, and form part of, the electrical circuit from the junction box 94 to the washing apparatus 40.
  • the installer connects the Earth 97, Neutral (not shown) and the 3 phases 98 coming from the junction box 94 each to a terminal block mounted on the DIN rail 96A.
  • the installer also connects the cables coming from the washing apparatus 40 to the other side of each respective DIN rail mounted terminal block 96B.
  • One of the phases 98 is threaded through a current sensing transformer 91.
  • the DIN rail mounted terminal blocks 96 preferably serve several purposes. They allow termination of the cable runs to the junction box 94 and the washing apparatus 40, whilst allowing access to a single phase of the washing apparatus' 40 power supply. In addition, they provide access to the 3 phase 98 supply for the power transformer 91.
  • the power transformer 91 taps off the 415V supply connected to the DIN rail terminal blocks 96. This transformer 91 generates the local low voltage supply for the power control means' 90 electronics, also 240V (when used in Australia at least) for the ozone generator 11.
  • the power transformer 91 is protected by a DIN rail mounted fuse 100, whilst the 240V secondary of the transformer 91 is protected by a panel mount fuse 101.
  • the power control means 90 contains a power control board 92 (a preferred circuit layout of which is shown in Figure 8) which contains electronics used for sensing washing apparatus 40 current, and hence making the decision as to whether the washing apparatus 40 is operating or not.
  • Two 240V mains power signals are made available at power connector 102.
  • One mains power signal is connected irrespective of washing apparatus 40 operation. This is used for keeping the ozone generator 11 in standby mode, during which times no ozone will be produced.
  • the other mains power signal at the power connector 102 is preferably connected when the washing apparatus 40 is operating. This is used as the activation signal for turning the ozone generator 11 ON so it will start producing ozone.
  • the power switch 103 enables and disables both 240V mains power signals presented at the power connector 102. Power is preferably not available at the power connector 102 if this switch 103 is set to OFF. When the power switch 103 is set to ON 1 the power indicator 95 is illuminated to show that power is available at the connector. This function is generally not influenced by washing apparatus 40 operation.
  • the power pontrol means 90 preferably, therefore, adaptively senses the current drawn through a single phase by the washing apparatus 40 using a current transformer 91.
  • a sensing circuit generally housed by a power control board 92 generates an activation signal which is then forwarded to the control means 71 of the ozone generator 11.
  • the power control means 90 provides power to a power outlet (not shown) which is adapted to supply the power to the ozone generator 11.
  • the sensing circuit generally has a sufficiently large time constant so that the ozone generator 11 remains switched on during a standard wash cycle of the washing apparatus 40, and is not switched off during momentary drops in power usage of the washing apparatus 40. For example, when the washing apparatus' 40 motors change direction, there is a momentary drop in current as the motors stop and restart.
  • the large time constant means that the ozone generator 11 will not switch off until several seconds after the washing apparatus 40 has switched off. As the ozone generator 11 of preferred embodiments uses UV lamps, it may be undesirable to have them switching on and off too frequently. Preferably, this time constant is approximately 5 seconds.
  • the power control means 90 may further include a control knob (not shown) to enable a user to set the sensitivity of the power control means 90 to the washing apparatus' 40 operation.
  • the control knob may take the form of a small potentiometer which is accessed by inserting a screw-driver into a small aperture (not shown) on the side of the housing 81. This feature may be particularly desirable in circumstances where the amount of current draw from a power source is particularly low or inconsistent.
  • the power control means 90 may additionally include an override switch (not shown) which can be used for, for example, the purpose of testing the operation of the ozone generator 11.
  • the override switch is operably connected to the power control board 92 and is adapted to override the current sensor and supply power to the power outlet (not shown) when the washing apparatus 40 is not operating.
  • This particular optional feature provides yet another mechanism to enable a user to exercise control over the operation of the power control means 90.
  • the power control means 90 also includes at least one indicator 95, generally housed in the power control board 92.
  • the indicators 95 are adapted to indicate under a number of different circumstances including those selected from the group consisting of power being present from the junction box 94, detection by the power control means 90 that the washing apparatus 40 is operating, and power being available at the power outlet (not shown).
  • the power control means 90 may accept a nominal power input of 3 phase 415 VAC.
  • the power control means 90 preferably provides a suitable low voltage (for example, 15V) for powering the internal circuitry of the power control means 90, such as the current transformer 91 , the power control board 92, the power outlet switch and the sensing circuit.
  • the power outlet (not shown) supplies an appropriate voltage to the ozone generator 11 for operation.
  • the power supply provided via the power outlet shall be 240VAC, and be rated 15OW. This output is preferably further protected from excessive current draw.
  • the electronics on the power control board 92 is typically powered by an onboard voltage regulator which is powered by the 15V secondary 104 of the power transformer 91. This secondary 104 is protected by a fuse (not shown) mounted on the power control board 92.
  • the power control means 90 may use a current transformer 91 mounted on the power control board 92 to sense the current drawn by the washing apparatus 40.
  • One of the 3 phase 98 cables to the washing apparatus 40 is passed through the centre of the current transformer 91 during installation of the power control means 90. This cable forms the primary side of the current transformer 91.
  • the power control means may include a housing which is adapted to be wall mounted, typically on the wall behind the washing apparatus 40.
  • the power control means 90 is preferably adapted to operate in an ambient air temperature in the range of -1O 0 C to +60°C.
  • the power control means 90 also may include appropriate and adequate heat sinking provisions to maintain component temperature appropriately.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

La présente invention concerne un système pour introduire de l'ozone dans un appareil de lavage, le système comprenant un moyen d'alimentation en ozone ; et un moyen de distribution d'ozone comprenant un premier conduit de fluide apte à transférer de l'ozone à partir du moyen d'alimentation en ozone à un moyen d'entrée de liquide de lavage, ledit moyen d'entrée de liquide de lavage étant apte à livrer du liquide de lavage à une chambre de lavage de l'appareil de lavage, et un second conduit de fluide apte à livrer de l'ozone à une région au–dessus du liquide de la chambre de lavage, ledit système étant adapté de telle sorte que, pendant un cycle de lavage, de l'ozone soit introduit dans la chambre de lavage par l'intermédiaire du moyen d'entrée de liquide de lavage, mélangé dans le liquide de lavage et dans la région au-dessus du liquide de la chambre de lavage par l'intermédiaire du second conduit de fluide. L'invention concerne également un dispositif apte à être utilisé dans le système, un dispositif et des procédés correspondants.
PCT/AU2007/000829 2006-06-15 2007-06-14 Système et dispositif pour introduire de l'ozone dans un appareil de lavage WO2007143785A1 (fr)

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AU2006202541 2006-06-15
AU2006202541A AU2006202541A1 (en) 2006-06-15 2006-06-15 System and Device for Introducing Ozone into a Washing Apparatus

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WO2008119631A1 (fr) * 2007-03-29 2008-10-09 Arcelik Anonim Sirketi Lave-linge
WO2009132952A1 (fr) * 2008-05-02 2009-11-05 Arcelik Anonim Sirketi Machine à laver
WO2010052146A1 (fr) * 2008-11-06 2010-05-14 Arcelik Anonim Sirketi Appareil électroménager utilisant du gaz d'ozone
DE102009026827A1 (de) 2009-06-08 2010-12-09 BSH Bosch und Siemens Hausgeräte GmbH Hausgerät mit einem Ozongenerator und einer Ozonbeseitigungsvorrichtung
DE102010027795A1 (de) * 2010-04-15 2011-10-20 BSH Bosch und Siemens Hausgeräte GmbH Hausgerät mit Plasmagenerator und Verfahren zu seinem Betrieb
DE102010027796A1 (de) 2010-04-15 2011-10-20 BSH Bosch und Siemens Hausgeräte GmbH Waschmaschine mit einer Gasbeseitigungsvorrichtung und Verfahren zu ihrem Betrieb
DE102010028447A1 (de) 2010-04-30 2011-11-03 BSH Bosch und Siemens Hausgeräte GmbH Verfahren zum Erkennen eines Betriebszustands in einem Hausgerät und hierfür geeignetes Hausgerät
WO2011154277A1 (fr) 2010-06-09 2011-12-15 BSH Bosch und Siemens Hausgeräte GmbH Procédé pour traiter du linge dans un lave-linge à basse température et lave-linge correspondant
US20120017379A1 (en) * 2010-07-26 2012-01-26 Mark Edward Moore Ozone laundry systems and related methods
WO2011161069A3 (fr) * 2010-06-23 2012-04-12 BSH Bosch und Siemens Hausgeräte GmbH Procédé de détermination de propriétés spécifiques du linge dans un appareil de traitement de linge et appareil de traitement de linge approprié à cet effet
EP2465993A1 (fr) * 2010-12-14 2012-06-20 Whirlpool Corporation Appareil de traitement du linge doté d'un cycle de traitement du biofilm
EP2465992A1 (fr) * 2010-12-14 2012-06-20 Whirlpool Corporation Appareil de traitement du linge doté d'un cycle de traitement du biofilm
WO2012121721A1 (fr) * 2011-03-09 2012-09-13 Empire Technology Development, Llc Détection des radicaux d'hydroxyle dans des systèmes de lavage à l'ozone
DE102011089116A1 (de) 2011-12-20 2013-06-20 BSH Bosch und Siemens Hausgeräte GmbH Haushaltsgerät mit einem Speicherbehälter und einem Oxidationsmittelgenerator sowie Verfahren zu seinem Betrieb
DE102011089386A1 (de) 2011-12-21 2013-06-27 BSH Bosch und Siemens Hausgeräte GmbH Verfahren zum Betrieb eines Hausgeräts mit einem Speicherbehälter und einem Oxidationsmittelgenerator sowie hierfür geeignetes Hausgerät
WO2014090755A1 (fr) * 2012-12-11 2014-06-19 Buske Christiane Dispositif de nettoyage et procédé de nettoyage d'objets au moyen d'eau
WO2016055310A1 (fr) * 2014-10-08 2016-04-14 BSH Hausgeräte GmbH Appareil d'entretien du linge comportant un dispositif de production d'ozone
EP3495326A1 (fr) * 2018-04-17 2019-06-12 Dbg Group Investments, LLC Dispositif de lavage du linge par oxydation photocatalytique
WO2019139549A1 (fr) * 2018-01-10 2019-07-18 Yagcilar Ali Procédé de réduction de couleurs dans une machine à laver
IT201900007671A1 (it) * 2019-05-30 2020-11-30 Rg Italia Production S R L Dispositivo di igienizzazione per lavabiancheria
US11198968B2 (en) 2016-08-10 2021-12-14 Omni Solutions Llc Washing systems
US11384468B2 (en) 2013-07-31 2022-07-12 Omni Solutions Llc Ozone injection systems
WO2023144428A1 (fr) * 2022-01-25 2023-08-03 Lopar Factory, S.L. Système pour le traitement de l'eau/l'air pour le secteur de l'agriculture et l'industrie
US12024808B2 (en) 2016-05-09 2024-07-02 Omni Solutions Llc Ozone and hydroxyl injection systems

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US9085842B2 (en) 2007-03-29 2015-07-21 Arcelik Anonim Sirketi Washing machine
WO2008119631A1 (fr) * 2007-03-29 2008-10-09 Arcelik Anonim Sirketi Lave-linge
WO2009132952A1 (fr) * 2008-05-02 2009-11-05 Arcelik Anonim Sirketi Machine à laver
WO2010052146A1 (fr) * 2008-11-06 2010-05-14 Arcelik Anonim Sirketi Appareil électroménager utilisant du gaz d'ozone
US8394349B2 (en) 2009-06-08 2013-03-12 Bsh Bosch Und Siemens Hausgeraete Gmbh Household appliance having an ozone generator and an ozone eliminating device, and related method
DE102009026827A1 (de) 2009-06-08 2010-12-09 BSH Bosch und Siemens Hausgeräte GmbH Hausgerät mit einem Ozongenerator und einer Ozonbeseitigungsvorrichtung
DE102010027795A1 (de) * 2010-04-15 2011-10-20 BSH Bosch und Siemens Hausgeräte GmbH Hausgerät mit Plasmagenerator und Verfahren zu seinem Betrieb
DE102010027796A1 (de) 2010-04-15 2011-10-20 BSH Bosch und Siemens Hausgeräte GmbH Waschmaschine mit einer Gasbeseitigungsvorrichtung und Verfahren zu ihrem Betrieb
WO2011141208A1 (fr) 2010-04-15 2011-11-17 BSH Bosch und Siemens Hausgeräte GmbH Lave-linge doté d'un dispositif d'élimination de gaz, et procédé de fonctionnement
DE102010028447A1 (de) 2010-04-30 2011-11-03 BSH Bosch und Siemens Hausgeräte GmbH Verfahren zum Erkennen eines Betriebszustands in einem Hausgerät und hierfür geeignetes Hausgerät
WO2011134753A1 (fr) 2010-04-30 2011-11-03 BSH Bosch und Siemens Hausgeräte GmbH Procédé de détection d'un état de fonctionnement d'un appareil ménager et appareil ménager adapté
DE102010029885A1 (de) 2010-06-09 2011-12-15 BSH Bosch und Siemens Hausgeräte GmbH Verfahren zur Behandlung von Wäsche in einer Waschmaschine bei niedriger Temperatur und hierzu geeignete Waschmaschine
WO2011154277A1 (fr) 2010-06-09 2011-12-15 BSH Bosch und Siemens Hausgeräte GmbH Procédé pour traiter du linge dans un lave-linge à basse température et lave-linge correspondant
WO2011161069A3 (fr) * 2010-06-23 2012-04-12 BSH Bosch und Siemens Hausgeräte GmbH Procédé de détermination de propriétés spécifiques du linge dans un appareil de traitement de linge et appareil de traitement de linge approprié à cet effet
US20120017379A1 (en) * 2010-07-26 2012-01-26 Mark Edward Moore Ozone laundry systems and related methods
EP2465993A1 (fr) * 2010-12-14 2012-06-20 Whirlpool Corporation Appareil de traitement du linge doté d'un cycle de traitement du biofilm
EP2465992A1 (fr) * 2010-12-14 2012-06-20 Whirlpool Corporation Appareil de traitement du linge doté d'un cycle de traitement du biofilm
US8844082B2 (en) 2010-12-14 2014-09-30 Whirlpool Corporation Laundry treating appliance with biofilm treating cycle
WO2012121721A1 (fr) * 2011-03-09 2012-09-13 Empire Technology Development, Llc Détection des radicaux d'hydroxyle dans des systèmes de lavage à l'ozone
US8809064B2 (en) 2011-03-09 2014-08-19 Empire Technology Development Llc Sensing hydroxyl radicals in ozone washing systems
DE102011089116A1 (de) 2011-12-20 2013-06-20 BSH Bosch und Siemens Hausgeräte GmbH Haushaltsgerät mit einem Speicherbehälter und einem Oxidationsmittelgenerator sowie Verfahren zu seinem Betrieb
WO2013092400A1 (fr) 2011-12-20 2013-06-27 BSH Bosch und Siemens Hausgeräte GmbH Appareil ménager présentant un réservoir d'alimentation et un générateur d'agents oxydants, et procédé pour le faire fonctionner
DE102011089386A1 (de) 2011-12-21 2013-06-27 BSH Bosch und Siemens Hausgeräte GmbH Verfahren zum Betrieb eines Hausgeräts mit einem Speicherbehälter und einem Oxidationsmittelgenerator sowie hierfür geeignetes Hausgerät
WO2013092488A1 (fr) 2011-12-21 2013-06-27 BSH Bosch und Siemens Hausgeräte GmbH Procédé de fonctionnement d'un appareil ménager comprenant un réservoir accumulateur et un générateur de moyen d'oxydation, et appareil ménager correspondant
WO2014090755A1 (fr) * 2012-12-11 2014-06-19 Buske Christiane Dispositif de nettoyage et procédé de nettoyage d'objets au moyen d'eau
US12104307B2 (en) 2013-07-31 2024-10-01 Omni Solutions Llc Ozone injection systems
US11702785B2 (en) 2013-07-31 2023-07-18 Omni Solutions Llc Ozone injection systems
US11384468B2 (en) 2013-07-31 2022-07-12 Omni Solutions Llc Ozone injection systems
WO2016055310A1 (fr) * 2014-10-08 2016-04-14 BSH Hausgeräte GmbH Appareil d'entretien du linge comportant un dispositif de production d'ozone
US12024808B2 (en) 2016-05-09 2024-07-02 Omni Solutions Llc Ozone and hydroxyl injection systems
US11655581B2 (en) 2016-08-10 2023-05-23 Gurtler Industries, Inc. Washing systems
US11198968B2 (en) 2016-08-10 2021-12-14 Omni Solutions Llc Washing systems
WO2019139549A1 (fr) * 2018-01-10 2019-07-18 Yagcilar Ali Procédé de réduction de couleurs dans une machine à laver
EP3495326A1 (fr) * 2018-04-17 2019-06-12 Dbg Group Investments, LLC Dispositif de lavage du linge par oxydation photocatalytique
US11008236B2 (en) 2018-04-17 2021-05-18 Dbg Group Investments, Llc Photocatalytic oxidation laundry device
WO2019203906A1 (fr) * 2018-04-17 2019-10-24 Dbg Group Investments, Llc Dispositif de blanchisserie à oxydation photocatalytique
IT201900007671A1 (it) * 2019-05-30 2020-11-30 Rg Italia Production S R L Dispositivo di igienizzazione per lavabiancheria
WO2023144428A1 (fr) * 2022-01-25 2023-08-03 Lopar Factory, S.L. Système pour le traitement de l'eau/l'air pour le secteur de l'agriculture et l'industrie

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