WO2007118870A3 - Verfahren zur herstellung von olefinen, aldehyden und carbonsäuren durch oxidation von alkanen - Google Patents

Verfahren zur herstellung von olefinen, aldehyden und carbonsäuren durch oxidation von alkanen Download PDF

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Publication number
WO2007118870A3
WO2007118870A3 PCT/EP2007/053670 EP2007053670W WO2007118870A3 WO 2007118870 A3 WO2007118870 A3 WO 2007118870A3 EP 2007053670 W EP2007053670 W EP 2007053670W WO 2007118870 A3 WO2007118870 A3 WO 2007118870A3
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Prior art keywords
elements selected
several elements
group encompassing
aldehydes
carboxylic acids
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PCT/EP2007/053670
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English (en)
French (fr)
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WO2007118870A2 (de
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Uwe Dingerdissen
Uwe Rodemerck
David Linke
Stephan Kolf
Daniel Herein
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Leibniz Inst Fuer Katalyse E V
Uwe Dingerdissen
Uwe Rodemerck
David Linke
Stephan Kolf
Daniel Herein
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Application filed by Leibniz Inst Fuer Katalyse E V, Uwe Dingerdissen, Uwe Rodemerck, David Linke, Stephan Kolf, Daniel Herein filed Critical Leibniz Inst Fuer Katalyse E V
Publication of WO2007118870A2 publication Critical patent/WO2007118870A2/de
Publication of WO2007118870A3 publication Critical patent/WO2007118870A3/de

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/652—Chromium, molybdenum or tungsten
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die Erfindung betrifft Verfahren zur Herstellung von Olefinen, Aldehyden und/oder Carbonsäuren durch Oxidation von Alkanen mit 2 bis 4 C-Atomen, umfassend die Schritte: (i) Bereitstellen eines wenigstens ein Alkan mit 2 bis 4 C-Atomen und Sauerstoff enthaltenden Gasgemisches; (ii) In Kontakt bringen des Gasgemisches mit einem Katalysator bei einer Reaktionstemperatur im Bereich von 200 bis 500 °C, wobei der Katalysator ein Mischoxid mit orthorhombischer Struktur des Cs(WNb)5O14-Typs der Formel (1) M1VpAqBrCsOn (1 ) ist, worin M für ein oder mehrere Elemente ausgewählt aus der Gruppe Molybdän und Wolfram steht; V für Vanadium steht; A für ein oder mehrere Elemente ausgewählt aus der Gruppe Niob, Tantal, Wismut, Phosphor, Zirkonium, Titan, Hafnium, Gallium, Chrom, Eisen, Kobalt, Aluminium, Rhenium, Mangan, Ruthenium, Germanium, Indium, Zinn, Bor und Seltene Erdmetalle steht; B für ein oder mehrere Elemente ausgewählt aus der Gruppe der Alkalimetalle, Erdalkalimetalle, Thallium und Zink steht; C für ein oder mehrere Elemente ausgewählt aus der Gruppe Palladium, Platin, Gold, Silber, Rhodium, Iridium, Nickel und Kupfer steht; O für Sauerstoff steht; p, q, r, s und n jeweils für die Atomverhältnisse von M, V, A, B, C und O stehen, mit der Maßgabe, dass p = 0,001 bis 2,0; q = 0 bis 0,9; r = 0 bis 0,2; s = 0 bis 0,1; und n eine durch die Valenzerfordernisse der vorhandenen Elemente festgelegte Zahl bedeutet.
PCT/EP2007/053670 2006-04-18 2007-04-16 Verfahren zur herstellung von olefinen, aldehyden und carbonsäuren durch oxidation von alkanen WO2007118870A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006018885.3 2006-04-18
DE102006018885A DE102006018885A1 (de) 2006-04-18 2006-04-18 Verfahren zur Herstellung von Olefinen, Aldehyden und Carbonsäuren durch Oxidation von Alkanen

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WO2007118870A2 WO2007118870A2 (de) 2007-10-25
WO2007118870A3 true WO2007118870A3 (de) 2007-12-06

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2179793A1 (de) 2008-10-21 2010-04-28 Sued-Chemie AG Mischoxidkatalysator enthaltend Phosphor
EP2179790A1 (de) 2008-10-21 2010-04-28 Sued-Chemie AG Mischoxidkatalysator enthaltend Bismut
WO2014167482A1 (en) 2013-04-08 2014-10-16 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
US6030920A (en) * 1997-12-24 2000-02-29 Saudi Basic Industries Corporation Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same
WO2001083103A2 (en) * 2000-04-28 2001-11-08 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid and ethylene, methods of making and using the same
WO2005018804A1 (en) * 2003-08-21 2005-03-03 Bp Chemicals Limited Catalyst composition and use thereof in ethane oxidation
US20060052635A1 (en) * 2003-01-27 2006-03-09 Rosen Bruce I Oxidation catalyst and its preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1096891A (en) * 1975-10-01 1981-03-03 Frank G. Young Low temperature oxydehydrogenation of ethane to ethylene

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
US6030920A (en) * 1997-12-24 2000-02-29 Saudi Basic Industries Corporation Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same
WO2001083103A2 (en) * 2000-04-28 2001-11-08 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid and ethylene, methods of making and using the same
US20060052635A1 (en) * 2003-01-27 2006-03-09 Rosen Bruce I Oxidation catalyst and its preparation
WO2005018804A1 (en) * 2003-08-21 2005-03-03 Bp Chemicals Limited Catalyst composition and use thereof in ethane oxidation

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
KATOU T ET AL: "HYDROTHERMAL SYNTHESIS OF NEW MO-V-O COMPLEX METAL OXIDE AND ITS CATALYTIC ACTIVITY FOR THE OXIDATION OF PROPANE", CHEMISTRY LETTERS, NIPPON KAGAKUKAI, TOKYO, JP, vol. 32, no. 11, 2003, pages 1028 - 1029, XP001176654, ISSN: 0366-7022 *
ROUSSEL ET AL: "MoVO-based catalysts for the oxidation of ethane to ethylene and acetic acid", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 308, 10 July 2006 (2006-07-10), pages 62 - 74, XP005488842, ISSN: 0926-860X *
ROUSSEL M ET AL: "Oxidation of ethane to ethylene and acetic acid by MoVNbO catalysts", CATALYSIS TODAY, ELSEVIER, vol. 99, no. 1-2, 15 January 2005 (2005-01-15), pages 77 - 87, XP004780827, ISSN: 0920-5861 *
WATANABE N ET AL: "Comparative Study on the Catalytic Performance of Single-Phase Mo-V-O-Based Metal Oxide Catalysts in Propane Ammoxidation to Acrylonitrile", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, AMERICAN CHEMICAL SOCIETY. WASHINGTON, US, vol. 45, no. 2, 18 January 2006 (2006-01-18), pages 607 - 614, XP002445131, ISSN: 0888-5885 *

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WO2007118870A2 (de) 2007-10-25

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