WO2007093702A3 - Compose comprenant l ' association d ' une premiere phase cristalline de type phosphomolybdique et d ' une deuxieme phase cristalline, et utilisation de ce compose en tant que catalyseur pour l ' oxydation d ' alcanes. - Google Patents

Compose comprenant l ' association d ' une premiere phase cristalline de type phosphomolybdique et d ' une deuxieme phase cristalline, et utilisation de ce compose en tant que catalyseur pour l ' oxydation d ' alcanes. Download PDF

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Publication number
WO2007093702A3
WO2007093702A3 PCT/FR2007/000260 FR2007000260W WO2007093702A3 WO 2007093702 A3 WO2007093702 A3 WO 2007093702A3 FR 2007000260 W FR2007000260 W FR 2007000260W WO 2007093702 A3 WO2007093702 A3 WO 2007093702A3
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WO
WIPO (PCT)
Prior art keywords
crystal phase
compound
combination
phosphomolybdenum
oxidation catalyst
Prior art date
Application number
PCT/FR2007/000260
Other languages
English (en)
Other versions
WO2007093702A2 (fr
Inventor
Jean-Marc Millet
Philippe Lacorre
Quyen Huynh
Original Assignee
Centre Nat Rech Scient
Univ Maine
Jean-Marc Millet
Philippe Lacorre
Quyen Huynh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre Nat Rech Scient, Univ Maine, Jean-Marc Millet, Philippe Lacorre, Quyen Huynh filed Critical Centre Nat Rech Scient
Priority to JP2008554809A priority Critical patent/JP5225865B2/ja
Priority to EP07730972A priority patent/EP1984114A2/fr
Priority to US12/279,420 priority patent/US8207080B2/en
Publication of WO2007093702A2 publication Critical patent/WO2007093702A2/fr
Publication of WO2007093702A3 publication Critical patent/WO2007093702A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

L'invention concerne un composé comprenant l'association de deux phases cristallines. La première phase cristalline répond à la formule : AaEbVcModPeOfHg dans laquelle A est un métal alcalin, E est Te, Sb ou Bi, et 0 ≤ a ≤ 3, 0 < b ≤ 3, 0 ≤ c ≤ 3, 0 < d ≤ 13, 0 < e ≤ 2, 0 ≤ g ≤ 3. La deuxième phase cristalline répond à la formule: ZgMohXiOj dans laquelle Z est choisi parmi les terres rares trivalentes, X est choisi parmi les éléments V, Ga, Fe, Bi, Ce, Ti, Sb, Mn, Zn, Te et 0 < g ≤ 3, 0 ≤ h ≤ 3, 0 ≤ i ≤ 1. Les indices f et j représentent le nombre d'atomes d'oxygène nécessaire pour satisfaire la valence et les proportions atomiques relatives des éléments présents. L'invention a également pour objet le procédé de préparation de ce composé, ainsi que son utilisation notamment en tant que catalyseur pour l'oxydation d'alcanes.
PCT/FR2007/000260 2006-02-14 2007-02-14 Compose comprenant l ' association d ' une premiere phase cristalline de type phosphomolybdique et d ' une deuxieme phase cristalline, et utilisation de ce compose en tant que catalyseur pour l ' oxydation d ' alcanes. WO2007093702A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2008554809A JP5225865B2 (ja) 2006-02-14 2007-02-14 ２つの結晶相の組合せを含む化合物の製造
EP07730972A EP1984114A2 (fr) 2006-02-14 2007-02-14 Preparation d'un compose comprenant l'association de deux phases cristallines
US12/279,420 US8207080B2 (en) 2006-02-14 2007-02-14 Preparing a compound comprising a combination of two crystal phases

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0601284A FR2897350B1 (fr) 2006-02-14 2006-02-14 Preparation d'un compose comprenant l'association de deux phases cristallines
FR0601284 2006-02-14

Publications (2)

Publication Number Publication Date
WO2007093702A2 WO2007093702A2 (fr) 2007-08-23
WO2007093702A3 true WO2007093702A3 (fr) 2007-10-04

Family

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Application Number Title Priority Date Filing Date
PCT/FR2007/000260 WO2007093702A2 (fr) 2006-02-14 2007-02-14 Compose comprenant l ' association d ' une premiere phase cristalline de type phosphomolybdique et d ' une deuxieme phase cristalline, et utilisation de ce compose en tant que catalyseur pour l ' oxydation d ' alcanes.

Country Status (5)

Country Link
US (1) US8207080B2 (fr)
EP (1) EP1984114A2 (fr)
JP (1) JP5225865B2 (fr)
FR (1) FR2897350B1 (fr)
WO (1) WO2007093702A2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109731592B (zh) * 2019-01-16 2020-12-01 中国科学院过程工程研究所 甲基丙烯醛选择性氧化制甲基丙烯酸的催化剂及其制备方法和用途
JP2022001542A (ja) * 2020-06-22 2022-01-06 国立大学法人東京工業大学 ランタン・モリブデン複合酸化物、抗菌性焼結体及び抗ウイルス性焼結体

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0418657A2 (fr) * 1989-09-18 1991-03-27 Sumitomo Chemical Company, Limited Procédé pour la fabrication de l'acide méthacrylique et de méthacroléine par oxydation catalytique d'isobutane
US5138100A (en) * 1990-06-06 1992-08-11 Mitsui Toatsu Chemicals, Inc. Method for preparing methacrolein
JPH09299803A (ja) * 1996-05-16 1997-11-25 Mitsubishi Chem Corp 酸化触媒及びその製造方法並びにメタクリル酸の製造方法
FR2756499A1 (fr) * 1996-12-03 1998-06-05 Atochem Elf Sa Systeme catalytique notamment pour l'oxydation menagee et selective des alcanes en alcenes et aldehydes insatures

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JPH0459739A (ja) * 1990-06-27 1992-02-26 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
JPH1017523A (ja) * 1996-07-01 1998-01-20 Mitsubishi Chem Corp 酢酸の製造方法
JPH10174877A (ja) * 1996-10-15 1998-06-30 Nitto Chem Ind Co Ltd モリブデン含有金属酸化物触媒の活性維持法
US6060419A (en) * 1998-01-05 2000-05-09 Sunoco, Inc. (R&M) Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts
JP2000143244A (ja) * 1998-07-24 2000-05-23 Mitsubishi Chemicals Corp 複合金属酸化物の製造方法
US6339037B1 (en) * 1999-04-27 2002-01-15 Nippon Shokubai Co. Ltd Catalysts for methacrylic acid production and process for producing methacrylic acid
FR2807421B1 (fr) * 2000-04-07 2002-07-12 Rhodia Terres Rares Composes derives de la2mo2o9 et leur utilisation comme conducteurs ioniques
JP4629886B2 (ja) * 2001-02-20 2011-02-09 三菱レイヨン株式会社 メタクロレインおよび／またはメタクリル酸製造用触媒、その製造方法、および、メタクロレインおよび／またはメタクリル酸の製造方法
JP4811977B2 (ja) * 2001-06-20 2011-11-09 三菱レイヨン株式会社 メタクリル酸合成用触媒の製造方法
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Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0418657A2 (fr) * 1989-09-18 1991-03-27 Sumitomo Chemical Company, Limited Procédé pour la fabrication de l'acide méthacrylique et de méthacroléine par oxydation catalytique d'isobutane
US5138100A (en) * 1990-06-06 1992-08-11 Mitsui Toatsu Chemicals, Inc. Method for preparing methacrolein
JPH09299803A (ja) * 1996-05-16 1997-11-25 Mitsubishi Chem Corp 酸化触媒及びその製造方法並びにメタクリル酸の製造方法
FR2756499A1 (fr) * 1996-12-03 1998-06-05 Atochem Elf Sa Systeme catalytique notamment pour l'oxydation menagee et selective des alcanes en alcenes et aldehydes insatures

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 199806, Derwent World Patents Index; AN 1998-057172, XP002400028 *

Also Published As

Publication number Publication date
EP1984114A2 (fr) 2008-10-29
US20090171118A1 (en) 2009-07-02
JP5225865B2 (ja) 2013-07-03
FR2897350A1 (fr) 2007-08-17
JP2009526730A (ja) 2009-07-23
WO2007093702A2 (fr) 2007-08-23
FR2897350B1 (fr) 2008-05-16
US8207080B2 (en) 2012-06-26

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