WO2007087143A2 - System and method for electrically-coupled thermal cycle - Google Patents

System and method for electrically-coupled thermal cycle Download PDF

Info

Publication number
WO2007087143A2
WO2007087143A2 PCT/US2007/000313 US2007000313W WO2007087143A2 WO 2007087143 A2 WO2007087143 A2 WO 2007087143A2 US 2007000313 W US2007000313 W US 2007000313W WO 2007087143 A2 WO2007087143 A2 WO 2007087143A2
Authority
WO
WIPO (PCT)
Prior art keywords
piston
cylinder
working gas
thermal cycle
electrical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2007/000313
Other languages
English (en)
French (fr)
Other versions
WO2007087143A3 (en
Inventor
Jonathan R. Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Altor Ltd LC
Original Assignee
Altor Ltd LC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Altor Ltd LC filed Critical Altor Ltd LC
Priority to JP2008552311A priority Critical patent/JP2009524772A/ja
Priority to EP07716379A priority patent/EP1982048B1/en
Priority to KR1020087020755A priority patent/KR101374564B1/ko
Priority to CN2007800034557A priority patent/CN101375018B/zh
Priority to CA2637634A priority patent/CA2637634C/en
Publication of WO2007087143A2 publication Critical patent/WO2007087143A2/en
Publication of WO2007087143A3 publication Critical patent/WO2007087143A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G1/00Hot gas positive-displacement engine plants
    • F02G1/04Hot gas positive-displacement engine plants of closed-cycle type
    • F02G1/043Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
    • F02G1/045Controlling
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K7/00Arrangements for handling mechanical energy structurally associated with dynamo-electric machines, e.g. structural association with mechanical driving motors or auxiliary dynamo-electric machines
    • H02K7/18Structural association of electric generators with mechanical driving motors, e.g. with turbines
    • H02K7/1869Linear generators; sectional generators
    • H02K7/1876Linear generators; sectional generators with reciprocating, linearly oscillating or vibrating parts
    • H02K7/1884Linear generators; sectional generators with reciprocating, linearly oscillating or vibrating parts structurally associated with free piston engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01BMACHINES OR ENGINES, IN GENERAL OR OF POSITIVE-DISPLACEMENT TYPE, e.g. STEAM ENGINES
    • F01B11/00Reciprocating-piston machines or engines without rotary main shaft, e.g. of free-piston type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B71/00Free-piston engines; Engines without rotary main shaft
    • F02B71/04Adaptations of such engines for special use; Combinations of such engines with apparatus driven thereby
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G1/00Hot gas positive-displacement engine plants
    • F02G1/04Hot gas positive-displacement engine plants of closed-cycle type
    • F02G1/043Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
    • F02G1/0435Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines the engine being of the free piston type
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K7/00Arrangements for handling mechanical energy structurally associated with dynamo-electric machines, e.g. structural association with mechanical driving motors or auxiliary dynamo-electric machines
    • H02K7/18Structural association of electric generators with mechanical driving motors, e.g. with turbines
    • H02K7/1892Generators with parts oscillating or vibrating about an axis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G2280/00Output delivery
    • F02G2280/10Linear generators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]

Definitions

  • a thermal cycle of a heat engine that employs a quantity of gas as an operating medium can be described by reference to a pressure-volume (P-V) diagram.
  • Figs. 1 and 2 show P-V diagrams for two well-known thermal cycles, the
  • the net energy delivered from one thermal cycle is the area of the loop swept out by the operating path in the P-V plane.
  • energy is delivered by the engine for part of the cycle, and is absorbed by the engine for the remainder of the cycle.
  • energy is neither stored nor delivered.
  • mechanical energy is neither absorbed nor delivered during those parts of the cycle where the trajectory is parallel to the P-axis.
  • part of the system used for extracting a net positive average power output must include a device for storing and returning energy out of and into the heat engine, on a cyclic basis.
  • this cyclic energy storage is accomplished by mechanical means, for example via the rotational inertia of a crankshaft with flywheel attached.
  • an embodiment of the invention provides a method for generating electrical energy using a thermal cycle of a working gas.
  • the method comprises using the motion of a piston in a cylinder, containing the working gas performing the thermal cycle, to electromagnetically induce current in an electrical circuit coupled to the cylinder.
  • the electrical circuit is used to store the electrical energy, produced by the current induced in the electrical circuit, in an electrical storage device; and the electrical energy stored in the electrical storage device is used to electromagnetically provide a motive force to the piston. Cyclically using the electrical circuit to store the electrical energy and using the stored energy to provide a motive force to the piston effect a net positive average power transfer into the electrical storage device over the course of the thermal cycle.
  • the electrical circuit may comprise an electronic power converter, and the method may further comprise using the electronic power converter to perform closed-loop electronic control of the motion of the piston.
  • the electronic power converter may perform the closed-loop control based on electrical signals related to the state of the working gas.
  • At least one of a temperature sensor, a pressure sensor, and a position sensor may be used to deliver the electrical signals related to the state of the working gas to the electronic power converter.
  • the thermal cycle may approximate a Sterling cycle, a Carnot cycle, an Otto cycle, or another thermal cycle.
  • the thermal cycle may receive heat from external combustion, or the working gas may be cycled through an internal combustion cycle.
  • Compression and expansion of the working gas between a first piston and a second piston may be used to perform the thermal cycle.
  • the electrical circuit may comprise a set of windings coupled to the cylinder, and the method may comprise using the motions of a first permanent magnet attached to the first piston and a second permanent magnet attached to the second piston to electromagnetically induce current in the set of windings.
  • the motions of the first piston and the second piston may be used to move the working gas along the cylinder to effect successive heat transfer with a heating zone and a cooling zone of the cylinder. At least part of the shaft of the first piston may move concentrically within a shaft of the second piston.
  • the electronic power converter may be used to control timing of the thermal cycle by controlling the motions of the first piston and the second piston; including by controlling the motions of the first piston and the second piston such that the working gas moves between a heating zone, a cooling zone, and a neutral zone of the cylinder.
  • a thermal shade may be attached to the first piston or the second piston to insulate non-working gas within the cylinder; and a paddle may be attached to the first piston or the second piston to create turbulence in the working gas.
  • An external flow return may be used to flow non-working gas between a first end zone and a second end zone of the cylinder.
  • the first piston and the second piston may be mounted around a common centering shaft.
  • Two cylinders operating according to the invention may be operated in axial opposition to each other.
  • four cylinders may be operated in a bundle with parallel axes of the cylinders, two of the cylinders being operated antiparallel to the other two cylinders of the bundle.
  • a method for powering a heat pump using electrical energy the heat pump performing a thermal cycle.
  • the method comprises using electrical energy stored in an electrical storage device to electromagnetically provide a motive force to a piston in a cylinder containing the working gas performing the thermal cycle.
  • the " motion of the piston is used to electromagnetically induce current in an electrical circuit coupled to the cylinder; and the electrical circuit is used to store the electrical energy, produced by the current induced in the electrical circuit, in the electrical storage device. Cyclically using the stored energy to provide the motive force to the piston and using the electrical circuit to store the electrical energy effect a net positive average power transfer out of the electrical storage device over the course of the thermal cycle. Similar methods as those used with the method for generating electrical energy, above, may be used with the method for powering a heat pump.
  • Fig. 1 shows a pressure-volume diagram for a Carnot cycle, known in the art
  • Fig. 2 shows a pressure-volume diagram for an ideal Sterling cycle, known in the art
  • Fig. 3 A shows an arrangement of coils, magnets, and pistons for an external combustion cylinder according to an embodiment of the invention
  • Fig. 3B shows a separate view of a piston for the embodiment of Fig. 3 A
  • Fig. 4 is a schematic diagram of electrical components that are coupled to the external combustion cylinder arrangement of Figs. 3A-3B;
  • FIG. 5A illustrates an alternative embodiment that may be used in place of the mechanical arrangement of Fig. 3A 5 in accordance with an embodiment of the invention
  • Figs. 5B and 5C show separate views of pistons for the embodiment of Fig.
  • Fig. 6 is a timing diagram for the heat engines of Figs. 3 A and 5 A when operated as electricity generators per the Sterling cycle depicted in Fig. 2, in accordance with an embodiment of the invention
  • Fig. 7 is a P-V diagram for a Sterling cycle heat pump operated in accordance with an embodiment of the invention
  • Fig. 8 is a timing diagram for the Sterling cycle heat pump of Fig. 7;
  • Fig. 9 illustrates an alternative embodiment that may be used in place of the mechanical arrangements of Figs. 3A-3B and 5A-5C, in accordance with an embodiment of the invention
  • Fig. 10 shows an axially opposed heat engine according to an embodiment of the invention
  • Figs. 1 IA and 1 IB illustrate an arrangement of four of the cylinder assemblies of the type shown in Fig. 5 A placed side-by-side with parallel central axes, according to an embodiment of the invention
  • Fig. 12 is a timing diagram for the heat engines of Figs. 3 A and 5 A when operated as electricity generators per the Carnot cycle depicted in Fig. 1, in accordance with an embodiment of the invention
  • Fig. 13 is a cross-sectional view of a piston arrangement for an internal combustion generator, in accordance with an embodiment of the invention.
  • Fig. 14 is a timing diagram for an internal combustion generator, in accordance with an embodiment of the invention.
  • Fig. 15 is a P-V diagram of an Otto cycle by which an internal combustion generator may be operated, in accordance with an embodiment of the invention.
  • Rotational inertia has been the method of choice for cyclic energy storage in heat engines since their development in the eighteenth century.
  • the devices used for cyclically storing and returning energy out of and into the heat engine are typically mechanical.
  • an engine may use the rotational inertia of a crankshaft with flywheel attached for cyclical energy storage.
  • conventional heat engines can be said to use mechanically-coupled thermal cycles.
  • the motion of the pistons is constrained by the motion of the crankshaft. The pistons therefore cannot move in a manner that allows the state of the working gas to closely follow the desired P-V cycle.
  • an embodiment according to the invention uses an electricity storage device to accommodate the cyclic flow of energy from a thermal cycle.
  • the thermal cycle can therefore be described as electrically-coupled.
  • An embodiment uses direct electric drive of pistons by means of electromagnetic shear.
  • Electricity storage devices suitable for this application include, for example, capacitors, batteries, and (if available) superconducting coils. Direct electric drive using electromagnetic shear may be accomplished with the use of permanent magnets attached to each piston assembly, and with the use of controlled electric currents in coils or windings to provide force to, or electromagnetic induction from, the permanent magnets.
  • Embodiments of an electrically-coupled thermal cycle may be used for the generation of electricity from a thermal cycle, such as to charge a battery using the external or internal combustion of a gas; or for electrical powering of a thermal cycle, such as using a battery or other source of direct current to power a heat pump.
  • power electronic circuits can be built which permit the motion of the pistons to be controlled so as to follow as closely as possible any desired path in the P-V plane.
  • the necessary energy cycling required to extract average power from a heat engine can be effected via electrical energy storage.
  • the use of electric coupling in this manner allows for variation of the amounts of time spent in each segment of a P-V cycle, thereby allowing for high thermal cycle efficiencies. Therefore, by comparison with prior systems in which energy was cyclically stored mechanically, an embodiment according to the invention uses electrical storage of cyclical energy flow.
  • use of electrical circuitry allows closed- loop electrical control of piston motion.
  • refrigeration devices are known that are driven by electronic linear drive motors, such as in U.S. Pat. No. 4,761,960 of Higham et al.; U.S. Pat. No. 4,697,113 of Young; and U.S. Pat. No. 5,040,372 of Higham.
  • linear drive motors may be battery-powered, with the delivery of current from the battery being electrically controlled, as in U.S. Pat. No. 5,752,385 of Nelson and U.S. Pat. No. 4,434,617 of Walsh.
  • free-piston hydraulic engines are known, such as in U.S. Pat. No. 4,215,548 of Beremand.
  • an embodiment according to the present invention is fundamentally different from such previously known systems because it employs electrical storage of cyclical energy flows to and from the thermal cycle.
  • an embodiment according to the invention cycles energy into and out of an electrical storage device that is electrically coupled to a cylinder containing the piston.
  • electrical storage of cyclical energy flow did not use electrical storage of cyclical energy flow.
  • Some such prior systems may instead use a form of mechanical resonance for cyclical energy flow.
  • a mechanical. resonance is used between the mass of the piston and the compressed end-zone gas, which acts as a spring, for cyclical energy flow.
  • Figs. 3 A and 3B show an arrangement of coils, magnets, and pistons for an external combustion generator according to an embodiment of the invention.
  • a closed gas containment cylinder 301 contains a body of gas, a portion of which becomes the working gas 302.
  • the working gas 302 is the subset of the total gas within the cylinder 301 that lies between two pistons
  • the pistons 303 and 304 which slide within the cylinder 301.
  • the pistons 303 and 304 maintain a tolerably good gas seal with the inner wall of the cylinder 301 without creating undue friction.
  • Conventional piston rings for example, may be employed for this purpose.
  • the cylinder 301 will typically be of circular cross section, but may have other cross sectional shapes.
  • the working gas 302 may be any gas suitable for the purpose, such as air, nitrogen, helium, or hydrogen.
  • each of the two pistons 303 and 304 is in the form of a plate. Attached centrally and perpendicular to each plate 303 and 304 is a shaft 307 and 308 attached at its other end to a permanent magnet plate 305 and 306.
  • the permanent magnet plates 305 and 306 contain permanent magnets within them, suitably arranged, together with magnetic path material such as iron or a suitable grade of steel. The arrangement of the permanent magnets and magnetic path material is such as to produce magnetic flux emanating from the outer edges of the permanent magnet plates 305 and 306, which cuts through the drive windings 309 ⁇ and 310 surrounding the cylinder 301 (Fig. 3A).
  • the cylinder 301 is made of nonmagnetic materials.
  • a plurality of such materials may be employed to construct cylinder 301.
  • a material such as aluminum may be used for regions such as 313 and 314, where no heat flow is required; and a material such as ceramic or fiberglass may be used for regions such as 317, where heat flow is not required.
  • Surrounding the drive windings 309 and 310 are magnetic field return paths 31 1 and 312 made of magnetic path material.
  • Also surrounding the cylinder 301 are two heat transfer zones 313 and 314 made of thermally conductive material such as copper or an aluminum alloy.
  • a heating zone 313 accepts heat from an external heat source, for example a flame or solar collector, and transfers that heat into the working gas 302 at an appropriate time, as described below.
  • a cooling zone 314 extracts heat from the working gas 302 at an appropriate time, also described below.
  • the heat transfer zones 313 and 314 are separated from each other by a thermally insulated neutral zone 317.
  • the three zones 313, 314, and 317 are shown in the accompanying figures to be of comparable lengths, which is not necessarily required, but may be advantageous with regard to optimization of overall power output.
  • Fig. 4 is a schematic diagram of electrical components that are coupled to the external combustion cylinder arrangement of Figs. 3A-3B, in order to accommodate the cyclic flow of energy from the thermal cycle in accordance with an embodiment of the invention.
  • Drive windings 409, 410, 443, which are the drive windings depicted as 309, 310 of Fig.
  • FIG. 4 shows three isolated windings 409, 410, 443 for illustrative convenience, but any number of separate windings may be employed, as necessary.
  • the position sensors 436 give the electronic power converter 435 the information it needs to know the exact location of each piston at any instant in time.
  • the temperature sensor 440 and pressure sensor 441 inform the electronic power converter 435 of the state of the working gas 302 at any instant.
  • Electronic power converter 435 is connected to a DC Bus 442, to which is connected a capacitor 437 and/or a battery 438, and an electric load 439.
  • the electric load 439 may be disconnected from the DC Bus 442 when not required, while the electronic power converter 435 continues to charge the battery 438.
  • Suitable batteries for battery 438 include lithium or other modern types of batteries configured for energy cycling applications, with better performance gained by lithium or other types of batteries capable of cycling energy at a rate of a few cycles per second or faster.
  • the electronic power converter 435 of Fig. 4 controls the flow of electric current into and out of the windings 309 and 310 of Fig.
  • the capacitor 437 and battery 438 act as the energy reservoir for the system, and absorb the cyclic energy variations which are integral to the cycles of heat engines.
  • the electronic power converter 435 stores little or no energy, and transfers power between the DC Bus 442 and the windings 309 and 310 in a highly efficient manner.
  • Figs. 3A-4 provides an electrically-coupled external combustion generator. Energy released from external combustion is transferred into the cylinder 301 through heating zone 313, a pressure-volume cycle is produced in working gas 302, and cyclic energy storage is performed by the electrical circuitry of Fig. 4. In one application, for example, the external combustion of a gas may therefore be used to store electrical charge in battery 438 without using any moving parts other than the pistons 303 and 304.
  • Figs. 5A-5C illustrate an alternative embodiment that may be used in place of the mechanical arrangement of Figs. 3A-3B, wherein the drive windings 509 and 510 are placed adjacent to each other and away from the heating zone 513.
  • the inner shaft 507 which connects piston 503 to its permanent magnet plate 505, is constructed to give minimal heat conduction from the hot upper end 503 to the permanent magnet plate 505 and to the shaft 508 surrounding it. This may be effected by using a thermally insulating material such as ceramic for shaft 507, possibly with a metallic core for strength.
  • the drive windings 509 for the longer piston assembly 503 are located further away from the cooling zone 514 than the drive windings 510 for the shorter piston assembly 504.
  • permanent magnet plate 506 is located above permanent magnet plate 505, because piston assembly 503 is longer than piston assembly 504.
  • the operation of the heat engine depicted in Fig. 5 A is just as described above for the heat engine depicted in Fig. 3 A, with similar electrical coupling to circuitry such as that of Fig. 4.
  • Fig. 6 is a timing diagram for the heat engines of Figs. 3 A and 5 A when operated as electricity generators per the Sterling cycle depicted in Fig. 2, in accordance with an embodiment of the invention.
  • Curve 644 is the piston position profile for piston 303, 503, and curve 645 is the piston position profile for piston 304, 504, for a repeating cycle A-B-C-D-A.
  • the piston positions are indicated by position levels 0 through 3 on the y-axis of Fig. 6, which correspond to cylinder positions indicated in Figs. 3 A and 5 A.
  • the cooling zone 314, 514 extends from position level 0 to level 1; the neutral zone 317, 517 extends from position level 1 to level 2; and the heating zone 313, 513 extends from position level 2 to level 3.
  • Fig. 6 shows the amount of time spent in each of the four segments of the thermal cycle as approximately equal, it is to be understood that the duration of each segment can be varied independently of the others, thereby allowing for power output variation and efficiency maximization. In varying the duration of the segments, there is an inherent conflict between the objectives of maximizing power output and maximizing efficiency; either objective can be satisfied, but not both simultaneously.
  • piston 304, 504 is held at position Level 0 (shown on the y-axis of Fig. 6, and in Figs. 3 A and 5A) as shown by curve 645, while piston 303, 503 is moved from position Level 2 to Level 1 as shown by curve 644, thereby compressing the working gas 302, 502.
  • the motion 644 of piston 303, 503 for this segment is depicted as having a straight-line shape in Fig. 6, although in practice the motion will typically be nonlinear.
  • both pistons initially move quickly together such that piston 303, 503 is moved from position Level 1 to Level 3, while piston 304, 504 is moved from position Level 0 to Level 2, as indicated by curves 644 and 645.
  • piston 304, 504 is held at position Level 2 (curve 645), and piston 303, 503 is held at position Level 3 (curve 644).
  • the working gas 302, 502 expands at constant temperature T2.
  • piston 303, 503 is held at position Level 3 (curve 644), while piston 304, 504 is moved from position Level 2 to Level 1 (curve 645).
  • the motion of piston 304, 504 for this segment is depicted as having a straight-line shape in curve 645 of Fig. 6, although in practice the motion will typically be nonlinear.
  • both pistons initially move quickly together such that piston 303, 503 is moved from position Level 3 to Level 2 (curve 644), while piston 304 is moved from position Level 1 to Level 0 (curve 645).
  • piston 304, 504 is held at position Level 0 (curve 645), and piston 303, 503 is held at position Level 2 (curve 644).
  • Such mechanical hard stops could, in principle, take the form of a mechanical barrier, or they may be effected by means of permanent magnets (and/or magnetic poles) attached rigidly either to the cylinder 301, 501 and/or to the piston assemblies. If a mechanical barrier is used, the power electronics can control the motion of the piston as it approaches the barrier so as to effect a "soft landing". A soft, springy material attached to the barrier or to the piston may assist with ensuring a soft landing. Permanent magnets would have the advantage of maintaining a physical impediment to further motion, without the practical concerns of physical contact associated with mechanical barriers. The permanent magnets can be used either in the attraction mode or in the repulsion mode. If they are used in the attraction mode, the control electronics will need to provide an excess impulse of current in order to break the piston free from its magnetic confinement at the end of the stationary period.
  • Figs. 3A-5C can be used for other types of thermal cycle, including one which approximates the Carnot cycle of Fig. 1.
  • a Carnot Engine may operate, for example, via the timing diagram of Fig. 12, which applies to a physical arrangement in which the length of the neutral zone 317, 517 is three times that of the heating 313, 513 and cooling 314, 514 zones.
  • curve 1244 is the piston position profile for piston 303, 503
  • curve 1245 is the piston position profile for piston 304, 504, for a repeating cycle A-B-C-D-A.
  • Time interval A-B corresponds to isothermal compression
  • interval B-C corresponds adiabatic compression
  • interval C-D corresponds to isothermal expansion
  • interval D-A corresponds to adiabatic expansion.
  • Figs. 3A-5C have been described as generators, by which heat is converted to electricity, it is also possible to use an electrically- coupled thermal cycle in accordance with an embodiment of the invention to create an electrically-powered heat pump.
  • the embodiments of Figs. 3A-5C are essentially operated in reverse: energy stored in electrical circuitry such as that of Fig. 4 is cycled in and out of a cylinder 301, 501 via windings 309, 509 and 310, 510, so that the pistons 303-304 and 503-504 perform a heat pump cycle.
  • Such a heat pump may be used to generate heat or to receive heat, which can be transferred to or from an external object through heating and cooling zones 313-314 and 513- 514.
  • Fig. 7 shows a P-V diagram for such a Sterling cycle heat pump (i.e., a refrigerator) operated in accordance with an embodiment of the invention. It can be seen that the path followed is that of Fig. 2, taken in reverse.
  • Fig. 8 gives the corresponding timing diagram, which can be understood by reference to the similar preceding explanation for Fig. 6.
  • Curve 844 is the piston position profile for piston 303, 503, and curve 845 is the piston position profile for piston 304, 504, for a repeating cycle A-B-C-D-A.
  • the piston positions are indicated by position levels 0 through 3 on the y-axis of Fig. 8, which correspond to cylinder positions indicated in Figs. 3 A and 5 A.
  • the cooling zone 314, 514 extends from position level 0 to level 1; the neutral zone 317, 517 extends from position level 1 to level 2; and the heating zone 313, 513 extends from position level 2 to level 3.
  • Fig.9 shows an alternative embodiment that may be used in place of the mechanical arrangements of Figs. 3A-3B and 5A-5C.
  • a centering shaft 921 is located centrally and within the shaft 907 of piston assembly 903, which in turn is located within the shaft 908 of piston assembly 904. Again, the mechanical fit between the shafts 921, 907, and 908 is such as to give a tolerably good gas seal between them without creating undue friction.
  • Centering shaft 921 holds both piston assemblies 903, 904 centered within the cylinder 901, so that they do not cling to one side of the cylinder via magnetic attraction, thereby causing excess friction and compromised gas sealing. The centering shaft 921 therefore assists to improve system efficiency.
  • portions of centering shaft 921 may be made of magnetic path material encircled by field coils, to create an electromagnet, thereby providing a means for the elimination of permanent magnets in the plates 305 and 306 of Fig. 3 A.
  • portions of centering shaft 921 may be made of magnetic path material encircled by field coils, to create an electromagnet, thereby providing a means for the elimination of permanent magnets in the plates 305 and 306 of Fig. 3 A.
  • two electromagnets may be created, to replace the functional role of permanent magnets in plates 305 and 306.
  • Plates 305 and 306 are then made of magnetic path material.
  • thermal shades 922 can be fitted to, or made part of, the pistons 903 and 904.
  • thermal shades 922 The function of these thermal shades 922 is to impede the flow of heat through the heating 913 and cooling 914 zones during appropriate portions of the heat cycle.
  • the thermal shades 922 are made of thermally insulating material, and are located close to, but not in contact with, the inside walls of the cylinder 901.
  • the thermal shades 922 extend around the entire inner perimeter of the inside walls of the cylinder 901. They impede the flow of heat via radiation, conduction, and convection into and out of the non- working gas within the cylinder 901, thereby improving system efficiency.
  • An external flow return 923 is a tube allowing non-working gas to flow from the upper end zone 915 to the lower end zone 916 to permit pressure equalization, which may be necessary to improve system efficiency.
  • An alternative means for achieving this pressure equalizing gas flow is to provide an internal flow return in the form of a passageway inside the centering shaft 921, which then takes the form of a hollow tube.
  • the volume of the upper end zone 915 and lower end zone 916 relative to the size of the working region (that is, the region between piston position levels 0 and 3) may need to be adequately large in order to maintain system efficiency, by eliminating the requirement for excessive forces to compress the gas in the end zones 915 and 916.
  • the external flow return 923 may include one or more expansion chambers (not shown in Fig. 9) along its length.
  • paddles 924 may be attached to the pistons 903 and 904. These paddles 924 stir the working gas 902 as the pistons 903 and 904 move relative to each other, thereby causing turbulence and motion of the working gas 902, and helping improve system efficiency.
  • the paddles 924 also improve the rate of heat transfer from the working gas 902 through the walls of the cooling zone 914.
  • the paddles 924 may have a variety of shapes, consistent with not making contact with each other or with the other piston.
  • Figs. 10-1 IB illustrate methods for reducing vibrations in a power conversion system according to an embodiment of the invention. In Fig. 10, two of the cylinder assemblies of the type shown in Fig.
  • FIG. 5 A (or any other cylinder assemblies according to the invention) are arranged so that their central axes are coincident and opposing.
  • the motion of the pistons for the system of Fig. 10 is controlled by their power conversion electronics such that the corresponding pistons move in synchronism in exactly equal and opposite movements.
  • the two piston assemblies 1003/1005 move toward or away from each other at exactly the same speed, and likewise the two piston assemblies 1004 move toward (or away from) each other in synchronism.
  • the upper end zone 1015 is common to both sides of the engine, while there is a separate lower end zone 1016 at each end.
  • Such an arrangement may be referred as an engine with “horizontally opposed” cylinders; or more generally, “axially opposed” cylinders, since the common axis need not necessarily be horizontal.
  • a horizontal placement may have advantages for arrangement of the flow of combustion gases past the heating zones.
  • Figs. 1 IA and 1 IB four of the cylinder assemblies of the type shown in Fig. 5A (or any other cylinder assemblies according to the invention) are placed side-by-side so that their central axes are parallel and arranged in a diamond pattern as viewed end-on (shown in Fig. 1 IB).
  • the controlling power electronics ensures that the pistons in cylinders A and C move together in the same direction and in exact synchronism.
  • the pistons in cylinders B and D also move together in the same direction and in exact synchronism, but in exactly the opposite direction to those in A and C, as indicated by the cross and dot vector notation of Fig. 1 IB.
  • the two pairs of cylinders may need to be displaced axially relative to each other rather than having their ends coplanar.
  • Fig. 13 is a cross-sectional view of one possible such mechanical arrangement, which can be seen to incorporate features already explained with reference to Figs. 3A, 5A, and 9.
  • two concentric piston assemblies 1303 and 1304 surround a centering shaft 1321 in a cylinder 1301, as in Fig. 9.
  • An arrangement corresponding to Fig. 3 A could also be implemented, wherein the piston assemblies are physically separate, with or without a centering shaft.
  • a fuel/air mixture is fed into the working gas region
  • a spark plug 1331 is located at the upper end of the working gas region 1302.
  • the walls of the working gas region 1302 are thermally insulated, and are made strong enough to withstand the forces associated with ignition of the fuel/air mixture.
  • Other features may be similar to those described above, including concentric shafts 1307 and 1308, permanent magnet plates 1305 and 1306, drive windings 1309 and 1310, magnetic field return paths 1311 and 1312, and end zones 1315 and 1316.
  • Exhaust port 1334 provides a means of escape for gas in region 1316, so that excessive compression forces are not required to compress the gas in region 1316.
  • Fig. 14 shows a timing diagram that the internal combustion generator of Fig. 13 may follow while performing an Otto cycle shown in the P-V diagram of Fig. 15, in accordance with an embodiment of the invention.
  • Curve 1444 is the piston position profile for piston 1303, and curve 1445 is the piston position profile for piston 1304, for a repeating cycle A-B-C-D-A.
  • the piston positions are indicated by position levels 0 and 1 on the y-axis of Fig. 14, which correspond to cylinder positions indicated in Figs. 13.
  • embodiments according to the invention provide a variety of different possible ways of using electrical storage of the cyclical energy required by a thermal cycle, including external and internal combustion generators, and electrically-driven heat pumps.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Compressors, Vaccum Pumps And Other Relevant Systems (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Dynamo-Electric Clutches, Dynamo-Electric Brakes (AREA)
PCT/US2007/000313 2006-01-24 2007-01-09 System and method for electrically-coupled thermal cycle Ceased WO2007087143A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2008552311A JP2009524772A (ja) 2006-01-24 2007-01-09 電気的に結合された熱サイクルのためのシステムおよび方法
EP07716379A EP1982048B1 (en) 2006-01-24 2007-01-09 System and method for electrically-coupled thermal cycle
KR1020087020755A KR101374564B1 (ko) 2006-01-24 2007-01-09 전기적으로-커플링된 사이클을 위한 시스템 및 방법
CN2007800034557A CN101375018B (zh) 2006-01-24 2007-01-09 电耦合热循环系统及方法
CA2637634A CA2637634C (en) 2006-01-24 2007-01-09 System and method for electrically-coupled thermal cycle

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/338,421 US7690199B2 (en) 2006-01-24 2006-01-24 System and method for electrically-coupled thermal cycle
US11/338,421 2006-01-24

Publications (2)

Publication Number Publication Date
WO2007087143A2 true WO2007087143A2 (en) 2007-08-02
WO2007087143A3 WO2007087143A3 (en) 2007-12-06

Family

ID=38070685

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/000313 Ceased WO2007087143A2 (en) 2006-01-24 2007-01-09 System and method for electrically-coupled thermal cycle

Country Status (7)

Country Link
US (6) US7690199B2 (enExample)
EP (1) EP1982048B1 (enExample)
JP (1) JP2009524772A (enExample)
KR (1) KR101374564B1 (enExample)
CN (1) CN101375018B (enExample)
CA (1) CA2637634C (enExample)
WO (1) WO2007087143A2 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7690199B2 (en) * 2006-01-24 2010-04-06 Altor Limited Lc System and method for electrically-coupled thermal cycle
JP5309146B2 (ja) * 2007-10-04 2013-10-09 シーレイト リミテッド ライアビリティー カンパニー 電磁エンジン
FR2924762A1 (fr) * 2007-12-05 2009-06-12 Pascot Philippe Machine thermodynamique, en particulier de type stirling.
KR101045871B1 (ko) * 2008-11-27 2011-07-01 채수조 선형 열기관
AT508410B1 (de) * 2009-07-13 2013-08-15 Ve Vienna Engineering Forschungs Und Entwicklungs Gmbh Schwingungskompensierter freikolbenmotor
US8726857B2 (en) * 2010-01-19 2014-05-20 Altor Limited Lc System and method for electrically-coupled heat engine and thermal cycle
DE102010018654B4 (de) * 2010-04-28 2014-12-24 Martin Degener Zyklisch arbeitende Wärme-Kraftmaschine
US8653678B2 (en) * 2010-06-29 2014-02-18 Marc Henness Method and apparatus for a thermo-electric engine
US8413617B2 (en) 2010-11-23 2013-04-09 Etagen, Inc. High-efficiency two-piston linear combustion engine
US8453612B2 (en) 2010-11-23 2013-06-04 Etagen, Inc. High-efficiency linear combustion engine
US8662029B2 (en) 2010-11-23 2014-03-04 Etagen, Inc. High-efficiency linear combustion engine
AU2011352118B2 (en) * 2010-12-29 2016-12-01 Gravaton Energy Resources Ltd, Llc Thermal energy conversion system
US8997699B2 (en) 2011-02-15 2015-04-07 Etagen, Inc. Linear free piston combustion engine with indirect work extraction via gas linkage
US8720317B2 (en) 2011-12-29 2014-05-13 Etagen, Inc. Methods and systems for managing a clearance gap in a piston engine
US9097203B2 (en) 2011-12-29 2015-08-04 Etagen, Inc. Methods and systems for managing a clearance gap in a piston engine
US9169797B2 (en) 2011-12-29 2015-10-27 Etagen, Inc. Methods and systems for managing a clearance gap in a piston engine
US9004038B2 (en) 2011-12-29 2015-04-14 Etagen, Inc. Methods and systems for managing a clearance gap in a piston engine
US20130167797A1 (en) 2011-12-29 2013-07-04 Matt Svrcek Methods and systems for managing a clearance gap in a piston engine
US10215229B2 (en) 2013-03-14 2019-02-26 Etagen, Inc. Mechanism for maintaining a clearance gap
EP3084319B1 (en) * 2013-11-21 2021-10-20 Thermolift Inc. A four-process cycle for a vuilleumier heat pump
JP6230484B2 (ja) * 2014-05-23 2017-11-15 学校法人 名城大学 リニアスターリングエンジン発電装置及びそれを利用した発電方法
RU2630364C1 (ru) * 2016-06-08 2017-09-07 федеральное государственное бюджетное образовательное учреждение высшего образования "Ижевский государственный технический университет имени М.Т. Калашникова" Экспедиционный генератор
US11168609B2 (en) 2017-04-24 2021-11-09 General Electric Company Adaptive linear linked piston electric power generator
WO2019060890A1 (en) * 2017-09-25 2019-03-28 Thermolift, Inc. LINEAR ACTUATORS LOCATED AT THE CENTER TO DRIVE TRAVEL ELEMENTS IN A THERMODYNAMIC APPARATUS
EP3728849A1 (en) * 2017-12-21 2020-10-28 Ceme S.p.A. A mass shifting mechanism between twin equilibrium points, and electro-pump or electro-valve having such shifting mechanism
KR102798615B1 (ko) 2018-07-24 2025-04-18 메인스프링 에너지, 인크. 선형 전자기 머신
CA3124179A1 (en) 2018-12-18 2020-06-25 Mainspring Energy, Inc. Integrated linear generator system
CN113396326A (zh) 2018-12-19 2021-09-14 核酸有限责任公司 用于分子诊断的设备和方法
US10724470B1 (en) 2019-05-21 2020-07-28 General Electric Company System and apparatus for energy conversion
US10598125B1 (en) * 2019-05-21 2020-03-24 General Electric Company Engine apparatus and method for operation
US10711733B1 (en) 2019-05-21 2020-07-14 General Electric Company Closed cycle engine with bottoming-cycle system
US12129812B2 (en) 2019-05-21 2024-10-29 Hyliion Holdings Corp Engine apparatus and method for operation
EP4118230A4 (en) 2020-03-09 2024-04-24 Nuclein, LLC DEVICE AND METHOD FOR MOLECULAR DIAGNOSIS
WO2023249505A2 (en) * 2022-06-21 2023-12-28 Arpad Torok New process for isothermal compression and expansion of gases and some devices for its application
US12078066B1 (en) 2023-06-26 2024-09-03 Hyliion Holdings Corp Pressure control system for a closed-cycle engine

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2068093A5 (enExample) 1969-11-27 1971-08-20 Commissariat Energie Atomique
DE2820526C2 (de) 1978-05-11 1982-04-22 Schneider, Christian, Dipl.-Ing., 8650 Kulmbach Heißgas-Hubkolbenmotor mit elektromagnetisch angetriebenem Verdränger
US4215548A (en) 1978-10-12 1980-08-05 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Free-piston regenerative hot gas hydraulic engine
FR2510181A1 (fr) * 1981-07-21 1983-01-28 Bertin & Cie Convertisseur d'energie thermique en energie electrique a moteur stirling et generateur electrique integre
JPS58139532U (ja) * 1982-03-17 1983-09-20 日産自動車株式会社 対向ピストン式フリ−ピストンエンジンのピストン同期装置
US4434617A (en) 1982-07-27 1984-03-06 Mechanical Technology Incorporated Start-up and control method and apparatus for resonant free piston Stirling engine
US4589380A (en) 1983-07-20 1986-05-20 Avalon Research Cyclic dwell engine
US4697113A (en) 1985-08-01 1987-09-29 Helix Technology Corporation Magnetically balanced and centered electromagnetic machine and cryogenic refrigerator employing same
US4642547A (en) 1985-08-19 1987-02-10 Sunpower, Inc. Adaptive regulation system for a linear alternator driven by a free-piston stirling engine
US4761960A (en) 1986-07-14 1988-08-09 Helix Technology Corporation Cryogenic refrigeration system having an involute laminated stator for its linear drive motor
JPS643235A (en) * 1987-06-24 1989-01-09 Aisin Seiki Free piston engine
US5040372A (en) 1990-04-06 1991-08-20 Helix Technology Corporation Linear drive motor with flexure bearing support
US4926639A (en) 1989-01-24 1990-05-22 Mitchell/Sterling Machines/Systems, Inc. Sibling cycle piston and valving method
US4888951A (en) 1989-07-03 1989-12-26 Sunpower, Inc. Phase synchronization and vibration cancellation for free piston Stirling machines
US5103645A (en) 1990-06-22 1992-04-14 Thermon Manufacturing Company Internal combustion engine and method
US5329768A (en) 1991-06-18 1994-07-19 Gordon A. Wilkins, Trustee Magnoelectric resonance engine
US5329678A (en) * 1993-09-20 1994-07-19 Bagnasco Dante Victor Molded safety pin
US5752385A (en) 1995-11-29 1998-05-19 Litton Systems, Inc. Electronic controller for linear cryogenic coolers
US5994881A (en) * 1997-10-07 1999-11-30 Hitachi, Ltd. Control apparatus for a synchronous generator system and a hybrid-type electric vehicle using it
US5775273A (en) 1997-07-01 1998-07-07 Sunpower, Inc. Free piston internal combustion engine
US6694731B2 (en) 1997-07-15 2004-02-24 Deka Products Limited Partnership Stirling engine thermal system improvements
US6385972B1 (en) 1999-08-30 2002-05-14 Oscar Lee Fellows Thermoacoustic resonator
US20030121259A1 (en) 1999-12-17 2003-07-03 Conrad Wayne Ernest Heat engine
JP2001241302A (ja) * 2000-02-29 2001-09-07 Mitsubishi Heavy Ind Ltd フリーピストンエンジン駆動リニア発電装置
JP3367507B2 (ja) * 2000-04-04 2003-01-14 雄造 川村 フリーピストン形スターリングエンジン
US6541875B1 (en) 2000-05-17 2003-04-01 Caterpillar Inc Free piston engine with electrical power output
FR2819555B1 (fr) 2001-01-17 2003-05-30 Conservatoire Nat Arts Groupe electrogene a mouvement lineaire alternatif a base de moteur stirling, et procede mis en oeuvre dans ce groupe electrogene
US6968688B2 (en) * 2001-10-24 2005-11-29 Enerlyt Potsdam Gmbh Two-cycle hot-gas engine
CA2482336A1 (en) 2002-02-28 2003-09-12 Nikolay Shkolnik Liquid piston internal combustion power system
SE525796C2 (sv) 2002-09-16 2005-04-26 Volvo Technology Corp Energiomvandlare inrättad så att den anpassar sin uteffekt beroende på den erforderliga lasten
CN100406708C (zh) * 2003-07-02 2008-07-30 蒂艾克思股份有限公司 自由活塞斯特林发动机控制系统
NZ527999A (en) 2003-09-02 2005-08-26 Fisher & Paykel Appliances Ltd Controller improvements
JP2005155345A (ja) * 2003-11-20 2005-06-16 Denso Corp フリーピストンエンジンおよびこれを用いた発電装置
US7353786B2 (en) * 2006-01-07 2008-04-08 Scuderi Group, Llc Split-cycle air hybrid engine
US7690199B2 (en) * 2006-01-24 2010-04-06 Altor Limited Lc System and method for electrically-coupled thermal cycle
US7318506B1 (en) 2006-09-19 2008-01-15 Vladimir Meic Free piston engine with linear power generator system
US7426910B2 (en) 2006-10-30 2008-09-23 Ford Global Technologies, Llc Engine system having improved efficiency
DE102006056349A1 (de) 2006-11-29 2008-06-05 Gerhard Schilling Vorrichtung zur Umwandlung thermodynamischer Energie in elektrische Energie
US7777357B2 (en) 2007-10-05 2010-08-17 The Invention Fund I, LLC Free piston electromagnetic engine
US7856714B2 (en) 2007-10-10 2010-12-28 The Invention Science Fund I, Llc Method of retrofitting an engine
US7622814B2 (en) * 2007-10-04 2009-11-24 Searete Llc Electromagnetic engine
US7950356B2 (en) * 2007-10-09 2011-05-31 The Invention Science Fund I, Llc Opposed piston electromagnetic engine
US8376070B2 (en) 2009-01-29 2013-02-19 General Electric Company Modular auxiliary power unit assembly for an electric vehicle
EP2406485B1 (en) 2009-03-12 2017-09-06 Joseph B. Seale Heat engine with regenerator and timed gas exchange
US8726857B2 (en) 2010-01-19 2014-05-20 Altor Limited Lc System and method for electrically-coupled heat engine and thermal cycle

Also Published As

Publication number Publication date
US20100115941A1 (en) 2010-05-13
US8720198B2 (en) 2014-05-13
US20140283511A1 (en) 2014-09-25
KR101374564B1 (ko) 2014-03-17
US7690199B2 (en) 2010-04-06
CA2637634A1 (en) 2007-08-02
WO2007087143A3 (en) 2007-12-06
US20070169476A1 (en) 2007-07-26
CA2637634C (en) 2014-07-08
US20100115942A1 (en) 2010-05-13
US20160222915A1 (en) 2016-08-04
JP2009524772A (ja) 2009-07-02
US8196402B2 (en) 2012-06-12
CN101375018B (zh) 2012-08-15
US8701404B2 (en) 2014-04-22
EP1982048B1 (en) 2012-08-29
EP1982048A2 (en) 2008-10-22
US20100127506A1 (en) 2010-05-27
KR20080100349A (ko) 2008-11-17
CN101375018A (zh) 2009-02-25

Similar Documents

Publication Publication Date Title
CA2637634C (en) System and method for electrically-coupled thermal cycle
US9228490B2 (en) System and method for electrically-coupled heat engine and thermal cycle
RU2255232C2 (ru) Устройство, включающее в себя двигатель внутреннего сгорания, использование такого устройства, а также транспортное средство
US7152404B2 (en) Power unit with reciprocating linear movement based on stirling motor, and method used in said power plant
JP4138669B2 (ja) 内燃機関に駆動される電力セル
JP4656840B2 (ja) 電気直線駆動部を有するフリーピストン装置
US5473205A (en) Double-duct liquid metal magnetohydrodynamic engine
JP2006505235A (ja) 電気機械とその使用
WO2007035102A1 (en) Free piston linear generator
US5637935A (en) Double-duct liquid metal magnetohydrodynamic engine
JP3367507B2 (ja) フリーピストン形スターリングエンジン
CN103827465B (zh) 活塞和在该活塞上施加力的方法
US20240128831A1 (en) Hybrid compressed gas-electric piston engine
Ross et al. Innovative Stirling engine driven heat pump concepts
RU2630364C1 (ru) Экспедиционный генератор
CN119519256A (zh) 一种自由活塞式斯特林热封闭光热发电机
CN101509475A (zh) 将热能转换成电能的装置
JPS61152951A (ja) スタ−リングエンジン

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2637634

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 6303/DELNP/2008

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 2008552311

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 200780003455.7

Country of ref document: CN

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2007716379

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 1020087020755

Country of ref document: KR