WO2007079849A1 - Agent de lavage, de rinçage ou de nettoyage multiphasique présentant une séparation de phase verticale - Google Patents

Agent de lavage, de rinçage ou de nettoyage multiphasique présentant une séparation de phase verticale Download PDF

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Publication number
WO2007079849A1
WO2007079849A1 PCT/EP2006/011755 EP2006011755W WO2007079849A1 WO 2007079849 A1 WO2007079849 A1 WO 2007079849A1 EP 2006011755 W EP2006011755 W EP 2006011755W WO 2007079849 A1 WO2007079849 A1 WO 2007079849A1
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Prior art keywords
washing
phases
cleaning agent
rinsing
acid
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PCT/EP2006/011755
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German (de)
English (en)
Inventor
Georg Meine
Hermann Jonke
Thomas FELDBRÜGGE
Piotr Malecki
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Henkel Kommanditgesellschaft Auf Aktien
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Publication of WO2007079849A1 publication Critical patent/WO2007079849A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means

Definitions

  • Multi-phase washing, rinsing or cleaning agent with vertical phase boundary
  • the invention relates to a washing, rinsing or cleaning agent containing Tens ⁇ d (e) and other conventional ingredients of detergents, wiping or cleaning agents, wherein the agent has at least two phases, and the use of the washing, rinsing or cleaning agent
  • the invention also relates to a dispensing container comprising a washing, rinsing or cleaning agent which contains surfactants (e) and other customary ingredients of washing, rinsing or cleaning agents, wherein the composition has at least two phases
  • liquid washing, rinsing or cleaning agent which develop their effect optimally even after storage and transport at the time of use. This requires that the contents of the liquid washing, rinsing or cleaning agent not previously deposited and / or have decomposed
  • Chemically incompatible components may be stored separately from the remaining components of the liquid washing, rinsing or cleaning agent and then dosed for use or the agent consists of two or more phases, which are stored in the dispensing container in different chambers and only in the dosage in contact come
  • This object is achieved by a washing, rinsing or cleaning agent containing surfactant (s) and other conventional ingredients of washing, rinsing or cleaning agents, wherein the agent has at least two phases, and wherein the agent in the storage state of the phases at least one having substantially vertical phase boundary.
  • surfactant s
  • other conventional ingredients of washing, rinsing or cleaning agents wherein the agent has at least two phases, and wherein the agent in the storage state of the phases at least one having substantially vertical phase boundary.
  • Such a washing, rinsing or cleaning agent has the advantage that incompatible ingredients can be integrated into a washing, rinsing or cleaning agent by incorporation into different phases without expensive packaging technology.
  • the incompatible ingredients of the individual phases can come into contact only in the limited area of the phase boundary and interact undesirably. Thus, only a small portion of the incompatible ingredients are optionally destroyed or deactivated during storage.
  • phase boundary is visible.
  • phase boundary By visualizing the phase boundary, the consumer can also visually be made clear that the different phases have different properties.
  • the density of the at least two phases is substantially equal.
  • the yield point of the at least two phases is substantially equal.
  • the yield point is the force that has to be expended to make a material flow.
  • a substantially equal yield point of the individual phases ensures that the phases start to flow when the same force is applied and thus the dosage of the washing, winding It can also be advantageous if the yield point of the individual phases is high and the phases start to flow only with targeted application of force. High flow limits of the individual phase can compensate for greater differences in the densities of the individual phases and prevent mixing
  • the viscosity of the at least two phases is substantially equal
  • the at least two phases each have a viscosity in the range of 15,000 mPas to 50,000 mPas (Brookfield Viscometer LVT-II at 20 U / min and 20 ° C, spindle 5)
  • the viscosity characterizes the flow behavior of a liquid
  • An equal and preferably high viscosity (from 15,000 mPas to 50,000 mPas) of the individual phases prevents mixing of the phases with time (storage).
  • An equal and preferably high viscosity also prevents the occurrence of strong currents the phase boundary on delivery of the washing, rinsing or cleaning agent (dosage), which lead to a mixing of the phases
  • the washing, rinsing or cleaning agent has two phases
  • a biphasic washing, rinsing or cleaning agent is easier to manufacture and handle compared to multiphase detergents, wipers or cleaners
  • one phase contains one or more ingredients that are incompatible with at least one ingredient of the other phase
  • the invention further relates to a dispenser, comprising a washing, rinsing or cleaning agent containing Tens ⁇ d (e) and other conventional ingredients of detergents, wipes or cleaning agents, wherein the agent has at least two phases, the agent in the storage state of the phases has at least one substantially vertically extending phase boundary and the dispensing container is designed so that upon delivery of the washing, rinsing or cleaning agent, the delivery takes place along the phase boundary.
  • a dispenser comprising a washing, rinsing or cleaning agent containing Tens ⁇ d (e) and other conventional ingredients of detergents, wipes or cleaning agents, wherein the agent has at least two phases, the agent in the storage state of the phases has at least one substantially vertically extending phase boundary and the dispensing container is designed so that upon delivery of the washing, rinsing or cleaning agent, the delivery takes place along the phase boundary.
  • Such a dispensing container has the advantage that for the dosage of the washing, rinsing or cleaning agent not always complete and above all homogeneous mixing of the phases must be achieved in order to ensure a uniform dosage of at least two phases.
  • the dispensing container is transparent or translucent. As a result, the consumer can see the different phases and, above all, can follow that a uniform dosage of the different phases takes place.
  • phase boundary is visible, sp so that the consumer can also optically track that there is a uniform metering of the various phases.
  • the container is deformable.
  • the consumer can also easily dispense or dispense highly viscous multiphase detergents, dishwashing or cleaning agents for use in the dispensing container.
  • PET polyethylene terephthalate
  • the multiphase washing, rinsing or cleaning agent according to the invention has at least one essentially vertically extending phase boundary.
  • state of storage of the phases in this context means the usual storage or presentation of the washing, rinsing or cleaning agent, preferably in a dispensing container, wherein it is preferred that the dispensing container has an area that is particularly preferably used as a base ,
  • substantially vertical means that the phase boundary is substantially vertical in relation to the footprint of a dispensing container containing the detergent, rinse or cleaning agent. limit in relation to the floor space of a containing the detergent, dishwashing or cleaning agent dispenser for the most part at an angle greater than 45 ° and less than 135 °
  • phase boundary in this case describes the abrupt change in the properties of two adjoining phases of the washing, rinsing or cleaning agent.
  • the phase boundary is not hard but has mixing conditions over a range. It is preferred that the range of mixing states as small as possible
  • the washing, rinsing or cleaning agent has at least two different phases, wherein the phases differ in their composition by at least one ingredient.
  • the two or more different phases of a washing, rinsing or cleaning agent have a substantially equal density, one in the Essentially equal means that the three properties mentioned (density, yield point or viscosity) of the individual phases can vary within a certain range, but the variation does not lead to spontaneous mixing preferably that values for one of the mentioned properties of two adjacent phases do not vary more than 30%, preferably not more than 20 and particularly preferably not more than 10%
  • the viscosity of the individual phases of the washing, rinsing or cleaning agent can be measured by conventional standard methods (in this case Brookfield® / Iskosimeter LVT-II at 20 U / min and 2O 0 C, spindle 5) and is for the washing, rinsing or Cleaning agent in each case preferably in the range from 15,000 to 50,000 mPas
  • Preferred washing, rinsing or cleaning agents preferably have viscosities of from 25,000 to 40,000 mPas in the respective phases, with values around 35,000 mPas being particularly preferred
  • the yield point of the individual phases of the washing, rinsing or cleaning agent is preferably 0.8 Pa (determined on an AR 1000-N rheometer from Texas Instruments at a temperature of 25 ° C.).
  • the density of the individual phases of the washing, rinsing or cleaning agent is preferably between 0.8 g / cm 3 and 1.6 g / cm 3
  • the individual phases of the washing, rinsing or cleaning agent contain surfactants (e), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
  • the total surfactant content of a phase of the liquid washing, rinsing or cleaning agent is preferably below 40% by weight and more preferably below 35% by weight, based on the total phase.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol residue can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • EO ethylene oxide
  • alcohol residue can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms for example from coconut, palm, Taigfett- or Oleylalkohol.i and an average of 2 to 8 EO per mole
  • Alcohol preferred.
  • the stated degrees of ethoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples of these are tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention.
  • block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
  • mixed alkoxylated niotic side can be used in which EO and PO units are not distributed blockwise, but statistically distributed. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.
  • nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1, 2 to 1, 4.
  • Alkyl glycosides are known, mild surfactants and are therefore preferably used in the surfactant mixture.
  • nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
  • nonionic surfactants of the amine oxide type for example N-Kokosalky] -N, N-dimethyl amine oxide and N-tallow alkyl-N, N-dihydroxyethylaminoxid, and the fatty acid alkanolamides may be suitable.
  • the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.
  • surfactants are polyhydroxy fatty acid amides of the formula (VII)
  • R-CO-N- [Z] (VII) in the RCO for an aliphatic acyl radical having 6 to 22 carbon atoms, R1 for hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the group of polyhydroxy fatty acid amides also includes compounds of the formula (VIII)
  • R 1 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms
  • R 2 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxy-alkyl radical having 1 to 8 carbon atoms, where d. 4 alkyl or phenyl radicals preferred are and [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted with at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives of this radical
  • [Z] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be prepared by reaction with fatty acid methyl esters in the presence of an alkoxide be converted as a catalyst into the desired polyhydroxy fatty acid amides
  • the content of nonionic surfactants in one phase of the washing, rinsing or cleaning agent is preferably 5 to 30% by weight, preferably 7 to 20% by weight and in particular 9 to 15% by weight, in each case based on the particular phase of the washing , Wiping or cleaning agent
  • a phase of the washing, rinsing or cleaning agent may also contain anionic surfactants.
  • anionic surfactants are those of the sulfonate and sulfates type.
  • the surfactants of the sulfonate type are preferably C 13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkane sulfonates, and the disulfonates obtained, for example 12 -i 8 monoolefins with a terminal or C obtained from innenstandi- ger double bond by sulfonation with gaseous Jschwefelt ⁇ oxid and subsequent alkaline or acidic hydrolysis of the sulfonation products are also suitable Al i kannsulfonate, which are obtained from Ci ⁇ -is-alkanes, for example by Sulfochlo ⁇ réelle or sulfoxidation and subsequent hydrolysis or neutralization Likewise
  • Suitable anionic surfactants are sulfonated fatty acid glycyl esters.
  • Fatty acid glyceryl esters are the mono-, di- and tri-esters and mixtures thereof, as in the preparation by esterification of a monoglycerine with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 mol of glycene are obtained.
  • Preferred sulfated fatty acid esters are the sulfonation products of saturated fatty acids containing 6 to 22 carbon atoms, for example caprylic caprylic acid, capric acid, myrotic acid, lauric acid, p-mitic acid, stearic acid or behenic acid
  • Suitable alk (en) ylsulfates are the alkali metal salts and, in particular, the sodium salts of the sulfuric acid monoesters of C 12 -C 18 -FeUaIkOhOIe, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, My ⁇ styl, cetyl or stearyl alcohol or the C 10 - C 2 o-Oxoalcohols and those half-esters of secondary alcohols of these chain lengths are also preferred.
  • Alk (en) ylsulfates of said chain length which contain a synthetic, petrochemical-based straight-chain alkyl radical which has an analogous decomposition behavior to those of the adequate compounds based on
  • the C 12 -C 16 -alkyl sulfates and C 12 -C 15 -alkyl sulfates and also C 14 -C 15 -alkyl sulfates are also preferred.
  • 2,3-Alkyl sulfates which are marketed as commercial products of the Shell Oil Company under the name DAN ® can be obtained, are suitable anionic surfactants
  • 21 -alcohols such as 2-methyl-branched C 9-11 -AIkOhOIe with an average of 3.5 moles of ethylene oxide (EO) or C 12 18 -fatty alcohols with 1 to 4 EO, are suitable They are in detergents due to their high foaming behavior only used in relatively small amounts, for example in amounts of 1 to 5% by weight
  • Suitable anionic surfactants are the salts of the Alkylsulfobernsteinsaure, which also sulfosuccinates as sulfonic or be referred to as Sulfobernsteinsaureester and Monoester and / or di- esters of Sulfobemsteinsaure with alcohols, preferably fatty alcohols and especially ethoxylated fatty alcohols represent Preferred sulfosuccinates contain C 8 18 fatty alcohol or mixtures of these particularly preferred sulfosuccinates contain a fatty alcohol radical derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants (see description below).
  • alk (en) ylbernic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof
  • anionic surfactants are soaps. Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myripic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and in particular derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids soap mixtures
  • the anionic surfactants, including the soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • the content of a phase of a washing, rinsing or cleaning agent to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the single phase of the wash , Rinsing or cleaning agent.
  • the phases of the washing, rinsing or cleaning agent may contain softening compounds.
  • the softening compounds include, for example, quaternary ammonium compounds such as monoalk (en) yltrimethylammonium compounds, dialk (en) yldimethylammonium compounds, mono-, di- or triesters of fatty acids with alkanolamines.
  • quaternary ammonium compounds are shown, for example, in the formulas (I) and (II):
  • R is an acyclic alkyl radical having 12 to 24 carbon atoms
  • R 1 is a saturated C 1 -C 4 alkyl or hydroxyalkyl radical
  • R 2 and R 3 are either R or R 1 or are an aromatic radical
  • X " is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof
  • Examples of cationic compounds of the formula (I) are monotaltrimethylammonium chloride, monostearyltrimethylammonium chloride, didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.
  • R 4 is an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents
  • R 5 is H, OH or O (CO) R 7
  • R 6 is, independently of R 5, H, OH or O (CO) R 8
  • R 7 and R 8 are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with O, 1, 2 or 3 double bonds
  • m, n and p may each independently have the value 1, 2 or 3 have.
  • X " can be either a halide, methosulfate, methophosphate or phosphate ion and mixtures of these be an ion.
  • R 5 represents the group 0 (CO) R 7 .
  • R 5 is the group O (CO) R 7 and R 4 and R 7 are alk (en) yl radicals having 16 to 18 carbon atoms.
  • R 6 is also OH.
  • Examples of compounds of the formula (I) are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium methosulphate, bis (palmitoyloxyethyl) -hydroxyethylmethylammonium methosulphate, I Bis-tallowacyloxyl-S-trimethylammonium propane chloride or methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate.
  • the acyl groups are preferred whose corresponding fatty acids have an iodine number between 1 and 100, preferably between 5 and 80, more preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio (in% by weight) of greater than 30:70, preferably greater than 50:50 and in particular equal to or greater than 60:40.
  • Stepan under the tradename Stepantex ® Methyihydroxyalkyldialkoyloxyalkylammoniummethosulfate or those known under Dehyquart ® products from Cognis or under the known Rewoquat® products from Degussa or those known under Tetranyl® products of Kao.
  • Further preferred compounds are the diester quats of the formula (III) which are obtainable under the name Rewoquat® W 222 LM or CR 3099.
  • R 21 and R 22 are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.
  • ester group 0 (CO) R where R is a long-chain alk (en) yl radical
  • softening compounds which have the following groups: RO (CO), N (CO) R or RN (CO), where of these groups, N (CO) R groups are preferred.
  • quaternary imidazolinium compounds of the formula (IV) where R 9 is H or a saturated alkyl radical having 1 to 4 carbon atoms, R 10 and R 11 independently of one another may each be an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R 10 may alternatively also be 0 (CO) R 20 where R 20 is an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X "is an anion, q can have integer values between 1 and 4.
  • R 14 is CH 2 -O (CO) R 16 where R 12 , R 13 and R 14 independently of one another are a C 1-4 -alkyl, alkenyl or hydroxyalkyl group, R 15 and R 16 are each independently selected C 8 - 28 -alkyl, X "is an anion and r is a number between 0 and 5.
  • a preferred example of a cationic Abborgungs bamboo according to formula (V) is 2,3-bis [tallowacyloxy] -3-trimethylammoniumpropanchlorid.
  • plasticizing compounds which can be used according to the invention are quaternized protein hydrolyzates or protonated amines.
  • cationic polymers are also suitable softening compounds.
  • Suitable cationic polymers include the polyquaternium polymers as described in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, Polyquaternium, also referred to as Merquats.
  • polymers Polymer JR, LR and KG series from Amerchol
  • polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups, which are bonded via allyldimethylammonium chloride
  • cationic cellulose derivatives such as cationic guar, such as guar hydro- xypropyl triammonium chloride, and similar quaternized guar derivatives (eg Cosmedia Guar from Cognis or the Jaguar series from Rhodia), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), eg the commercial product Glucquat® 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 Hydroxypropyl Dimonium Chloride ", copolymers of PVP and dimethylamino methacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone polymers
  • polyquaternized polymers for example Luviquat® Care from BASF
  • cationic biopolymers based on chitin and derivatives thereof for example the polymer available under the trade name Chitosan® (manufacturer Cognis)
  • R 17 can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds s can assume values between 0 and 5 R 18 and R 19 independently of one another in each case represent H, C 1-4 Alkyl or hydroxyalkyl and X " is an anion
  • plasticizing compounds include protonated or quaternized polyamines
  • plasticizing compounds are alkylated quaternary ammonium compounds, of which at least one alkyl chain is interrupted by an ester group and / or amido group.
  • alkylated quaternary ammonium compounds of which at least one alkyl chain is interrupted by an ester group and / or amido group.
  • Very particular preference is given to N-methyl-N- (2-hydroxyethyl) -N, N- (dicycloacyloxyethyl) -ammonium compounds.
  • softening compounds are nonionic softening compounds, in particular polyoxyalkylene glycol alkanoates, polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, alkyl polyglucosides, in particular sorbitan mono-, di- and n-esters, and fatty acid esters of polycarboxylic acids,
  • the individual phases of the washing, rinsing or cleaning agent may contain further ingredients which further improve the performance and / or aesthetic properties of the washing, rinsing or cleaning agent individual phases of the washing, rinsing or cleaning agent preferably additionally one or more substances from the group scaffolds, bleaches, bleach activators, enzymes, electrolytes, non-aqueous solvents, pH adjusters, perfumes, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, antiredeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobial agents, Germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, Bugelosstoff, repellents and impregnating agents, swelling and anti-sliding agents, neutral full salts and UV absorbers
  • scaffolds which may be contained in the phases of the washing, rinsing or cleaning agents, particular mention may be made of silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances
  • Suitable crystalline, layered Nat ⁇ umsilikate have the general formula NaMSi x O 2x + I H 2 O, wherein M is sodium or hydrogen, x is a number from 1, 9 to 4 and y is a number from 0 to 20 and preferred values for x , 3 or 4 are Preferred crystalline sheet silicates of the formula given are those in which M is Natminum and x assumes the values 2 or 3.
  • both ⁇ - and ⁇ -Nat ⁇ umdisilikate Na 2 Si 2 O 5 • yH 2 O are preferred
  • amorphous sodium silicates having a modulus Na 2 O SiO 2 of 1 2 to 1 3,3, preferably of 1 2 to 1 2,8 and in particular of 1 2 to 1 2,6, which are loosely delayed and have secondary washing properties
  • amorphous Nat ⁇ umsilikaten can thereby be caused in various ways, for example by surface treatment, compounding, compaction / compression or by overdrying.
  • amorphous is also "X-ray amorphous" means This means that the silicates in Rontgenbeugungsexpe ⁇ menten provide no sharp X-rays, as they are typical for crystalline substances, but at best one or more maxima of the scattered X-rays, which have a width of several degrees of the diffraction angle However, it may well lead to particularly good builder properties, if the silicate particles in electron diffraction This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to 50 nm and in particular up to a maximum of 20 nm being preferred.
  • compacted / compacted ones amorphous silicates, compounded amorphous silicates and dried X-ray amorphous silicates
  • the finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P.
  • zeolite P zeolite MAP® (commercial product from Crosfield) is particularly preferred.
  • zeolite X and mixtures of A, X and / or P are particularly preferred.
  • zeolite can be used as a spray-dried powder or else as an undried, stabilized suspension which is still moist from its production.
  • the zeolite may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols having 2 to 5 ethylene oxide groups , C 12 -C 14 fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols.
  • Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.
  • phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
  • Organic builders which may be present in the textile treatment agent are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function.
  • polycarboxylic acids meaning those carboxylic acids which carry more than one acid function.
  • these are, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and their derivatives and mixtures thereof.
  • Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof. The acids themselves can also be used.
  • the acids also typically have the property of an acidifying component and thus also serve to set a lower and milder pH of detergents, dishwashing detergents or cleaners.
  • an acidifying component such as citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixtures of these can be mentioned here.
  • Further useable acidulants are known pH regulators, such as sodium bicarbonate and sodium hydrogen sulfate.
  • polymeric polycarboxylates for example the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example those having a relative molecular mass of from 500 to 70,000 g / mol.
  • the molecular weights given for polymeric polycarboxylates are weight-average molar masses M w of the particular form of acidic acid which were determined in principle by means of gel permeation chromatography (GPC), in which case a UV detector was used. The measurement was carried out against an external Polyac'rylklare standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data in which polystyrenesulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.
  • Suitable polymers are, in particular, polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility, the short-chain polyacrylates, which have molecular weights of from 2,000 to 10,000 g / mol, and particularly preferably from 3,000 to 5,000 g / mol, may again be preferred from this group.
  • Suitable polymers may also include substances consisting partly or wholly of units of vinyl alcohol or its derivatives.
  • copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid.
  • Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable.
  • Their molecular weight relative to free acids is generally 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol
  • the (co) polymeric polycarboxylates can be used either as an aqueous solution or preferably as a powder
  • the polymers may also contain allylsulfonic acids, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer
  • biodegradable polymers of more than two different monomer units for example those containing as monomers salts of acrylic acid and maleic acid and vinyl alcohol or vinyl alcohol derivatives or as monomers, salts of acrylic acid and 2-alkylallylsulfonic acid and sugar derivatives
  • copolymers are those which preferably have acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate as monomers
  • polymeric aminodicarboxylic acids, their salts or their precursors are particularly preferred polyaspartic acids or their salts and derivatives which have not only builder properties but also a bleach-stabilizing effect
  • polyacetals which can be obtained by reacting dialdehydes with Polyolcarbonsauren which have 5 to 7 C-atoms and at least 3 hydroxyl groups.
  • Preferred polyacetals are selected from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from Polycarbonsauren such as gluconic acid and / - or glucoheptonic acid
  • Suitable organic scaffolds are dextrins, for example, oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches.
  • the hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes.
  • the hydrolysis products have average molecular weights in the range of 400 up to 500,000 g / mol.
  • a polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30, is preferred, DE being a customary measure of the reducing action of a polysaccharide in comparison with dextrose, Useful are both Maltodext ⁇ ne with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 as well as so-called yellow dextrins and white dextrins with higher molecular weights in the range of 2,000 to 30,000 g / mol
  • the oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function. Also suitable is an oxidized oligosaccharide.
  • a product oxidized to C 6 of the saccharide ring may be particularly advantageous.
  • Oxydisuccinates and other derivatives of disuccinates are also other suitable builders.
  • ethylenediamine-N, N'-disuccinate (EDDS) preferably used in the form of its sodium or magnesium salts.
  • glycerol disuccinates and glycerol trisuccinates are also preferred.
  • organic builders are, for example, acetylated hydroxycarboxylic acids or their salts, which may optionally also be present in lactic form and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups.
  • bleaching agents are, for example, peroxy pyrophosphates, citrate perhydrates and peroxygenic salts or peracids which yield H 2 O 2 , such as perbenzoates, peroxophthalates, diperazelaic acid, diperdodecanedioic acid or, more preferably, phthalimidoperoxycarboxylic acids, such as 6-phthalimidoperachexanoic acid (6-phthaloylimidopercapric acid, PAP).
  • peroxy pyrophosphates citrate perhydrates and peroxygenic salts or peracids which yield H 2 O 2
  • perbenzoates peroxophthalates
  • diperazelaic acid diperdodecanedioic acid
  • phthalimidoperoxycarboxylic acids such as 6-phthalimidoperachexanoic acid (6-phthaloylimidopercapric acid, PAP).
  • organic peracids, alkali metal perborates and / or alkali metal percarbonate in amounts of 0.1 to 40% by weight, preferably 3 to 30 wt .-%, in particular 5 to? 5 wt .-% based on a phase of a washing, Rinsing or cleaning agent used.
  • a light-active bleaching agent which comprises titanium dioxide, preferably modified titanium dioxide, in particular carbon-modified titanium dioxide, may also be used.
  • these bleaches absorb in the visible region of the spectrum and form hydroxy radicals with water.
  • compounds which under perhydrolysis conditions are peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted Perbenzoic acid, are used.
  • Suitable are substances which contain O- and / or N-acyl groups of the stated C atom number and / or optionally substituted Wear etched benzoyl groups.
  • polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexa-hydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular 1,3 , 4,6-tetraacetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic acid hydrides, in particular phthalic anhydride, isoic anhydride and / or succinic anhydride, glycolide, acylated polyhydric alcohols, in particular triacetin, ethylene glycol di
  • Hydrophilic substituted acyl acetals and acyl lactams are also preferably used. Combinations of conventional bleach activators can also be used. Likewise, nitrile derivatives such as cyanopyridines, nitrile quats and / or cyanamide derivatives can be used.
  • Preferred bleach activators are sodium 4- (octanoyloxy) benzenesulfonate, undeceloyl oxybenzenesulfonate (UDOBS) 1 sodium dodecanoyloxybenzenesulfonate (DOBS) 1 decanoyloxybenzoic acid (DOBA, OBC 10) and / or dodecanoyloxybenzenesulfonate (OBS 12).
  • Such bleach activators are optionally in the usual amount range of 0.01 to 20 wt .-%, preferably in amounts of 0.1 to 15 wt .-%, in particular 1 wt .-% to 10 wt .-%, based on a phase of Washing, rinsing or cleaning agent.
  • the phases of the washing, rinsing or cleaning agents may each contain a thickener.
  • the thickener may include, for example, a polyacrylate thickener, xanthan gum, gellan gum, guar gum, alginate, carrageenan, carboxymethyl cellulose, bentonites, wellan gum, locust bean gum, agar, tragacanth, gum arabic, pectins, polyoses, starch, dextrins, gelatin and casein include.
  • modified natural substances such as modified starches and celluloses, examples which may be mentioned here include carboxymethylcellulose and other cellulose ethers, hydroxyethyl and -propylcellulose and core flour ethers, can be used as thickeners.
  • the polyacrylic and polymethacrylic thickeners include, for example, the high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI name according to "International Dictionary of Cosmetic Ingredients of The Cosmetic, Toiletry and Fragrance Association (CTFA): Carbomer), also referred to as carboxyvinyl polymers.
  • CTF Cosmetic, Toiletry and Fragrance Association
  • Such polyacrylic acids are available, inter alia, from the company 3V Sigma under the trade name Polygel®, for example Polygel DA, and from the company BF Goodrich under the trade name Carbopol®, for example Carbopol 940 (molecular weight about 4,000,000), Carbopol 941 (Molecular weight about 1. 250,000) or Carbopol 934 (molecular weight about 3,000,000).
  • acrylic acid copolymers include the following acrylic acid copolymers: (i) copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple esters, preferably formed with C 1-4 -alkanols (INCI acrylates copolymer), to which approx the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS designation according to Chemical Abstracts Service: 25035-J69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and the example of the company.
  • acrylic acid copolymers (i) copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple esters, preferably formed with C 1-4 -alkanols (INCI acrylates copolymer), to which approx the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS designation according to Chemical Abstracts Service: 25035-
  • Rohm & Haas under the trade names Aculyn® and Acusol®, as well as from Degussa (Goldschmidt) under the trade name Tego® Polymer, for example the atpionic non-associative polymers Aculyn 22, Aculyn 28, Aculyn 33 (crosslinked), Acusol 81 ⁇ , Acusol 820, Acusol 823 and Acusol 830 (CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of Cio 3 o-alkyl acrylates with one or more monomers selected from the group of acrylic acid, methacrylic acid and their simple, preferably C- M alkanols formed esters (INCI Acrylates / Cio 30 alkyl acrylate crosspolymer) include and which are available, for example, from the company.
  • Carbopol® eg the hydrophobic Carbopol ETD 2623 and Carbopol 1382 (INCI Acrylates / C 1o -3 o alkyl acrylate crosspolymer) and Carbopol Aqua 30 (formerly Carbopol EX 473).
  • xanthan gum a microbial anionic heteropolysaccharide produced by Xanthomonas campestris and some other species under aerobic conditions and having a molecular weight of 2 to 15 million daltons.
  • Xanthan is formed from a chain of ⁇ -1,4-linked glucose (cellulose) with side chains.
  • the structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate, the number of pyruvate units determining the viscosity of the xanthan gum.
  • a fatty alcohol is also suitable.
  • Fatty alcohols may be branched or unbranched, of native origin or of petrochemical origin.
  • Preferred fatty alcohols have a C chain length of 10 to 20 C atoms, preferably 12 to 18.
  • Preferred Mixtures of different C-chain lengths such as Taigfettalkohol or coconut oil, used. Examples are Lorol® Spezial (C12- 14 -ROH) or Lorol® Technical (C 12 -i 8 -ROH) (both ex Cognis).
  • One phase of the washing, rinsing or cleaning agent may contain 0.01 to 3% by weight and preferably 0.1 to 1% by weight of thickener.
  • the amount of thickener used depends on the type of thickener and the desired degree of thickening.
  • the phases of the washing, rinsing or cleaning agent may contain enzymes.
  • Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, ⁇ -glucanases, oxidases, peroxidases, perhydrolases and / or laccases and mixtures of said enzymes in question. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying.
  • cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils.
  • Oxireductases can also be used for bleaching or inhibiting color transfer.
  • Particularly suitable are bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents.
  • subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
  • enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
  • lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases.
  • Suitable amylases include, in particular, ⁇ -amylases, iso-amylases, pullulanases and pectinases.
  • As cellulases are preferably cellobiohydrolases, endoglucanases and ß-glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ in their CMCase and avicelase activities, targeted mixtures of the cellulases can be used to set the desired activities.
  • the enzymes may be encapsulated or adsorbed to carriers to protect against premature degradation.
  • the proportion of the enzymes, the enzyme liquid formulation (s) or the enzyme granules in one phase of a washing, rinsing or cleaning agent may be, for example, about 0.01 to 5% by weight, preferably 0.12 to about 2.5% by weight. be.
  • electrolytes from the group of inorganic salts a wide number of different salts can be used.
  • Preferred cations are the alkali and alkaline earth metals, preferred anions are the halides and sulfates.
  • the use of NaCl or MgCl 2 in the textile treatment agents is preferred.
  • the proportion of electrolyte in one phase of the washing, rinsing or cleaning agent is usually 0.1 to 5 wt .-%.
  • Non-aqueous solvents that can be used in the phases of the washing, rinsing or cleaning agent, for example, come from the; Group of mono- or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible with water in the specified concentration range.
  • the solvents are preferably selected from ethanol, n- or i-propanol, butanols, glycol, propane- or butanediol, glycerol, diglycol, propyl- or butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether , Diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, dipropylene glycol monomethyl or ethyl ether, diisopropylene glycol monomethyl or ethyl ether, methoxy, ethoxy or butoxy triglycol, 1-butoxyethoxy-2-propanol , 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether, di
  • pH adjusters In order to bring the pH of the phases of the washing, rinsing or cleaning agent in the desired range, the use of pH adjusters may be indicated. Can be used here are all known acids or alkalis, unless their use is not for technical application or environmental reasons or for reasons of consumer protection prohibited. Usually, the amount of these adjusting agents does not exceed 10% by weight of the total formulation of one phase.
  • the pH of a phase of the washing, rinsing or cleaning agent is preferably between 4 and 10 and preferably between 5.5 and 8.5.
  • a phase of the washing, rinsing or cleaning agent contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.01 to 5 wt .-%, in particular 0.3 to 3 wt. -%.
  • perfume oils or fragrances individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
  • perfume oils may also contain natural fragrance mixtures as are available from plant sources.
  • the washing, rinsing or cleaning agents can be dyed with suitable dyes.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of the textile treatment agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • the respective phases of the washing, rinsing or cleaning agent contain different dyes, so that the phase boundary and thus the multiphase nature of the washing, rinsing or cleaning agent is visually more pronounced.
  • foam inhibitors which can be used in the phases of the washing, rinsing or cleaning agent, for example, soaps, paraffins or silicone oils come into consideration, which may optionally be applied to support materials.
  • Suitable soil release polymers also referred to as "anti-redeposition agents” include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 wt% and hydroxypropyl groups of 1 to 15 wt%, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives of Suitable derivatives include the sulfonated derivatives of the phthalic and terephthalic acid polymers.
  • Optical brighteners can be added to textile treatment agents to eliminate graying and yellowing of treated flat textile fabrics which will attract the fiber and cause lightening and fake bleaching by turning invisible ultraviolet radiation into visible longer wavelength convert light, wherein the absorbed from sunlight ultraviolet light is radiated as pale bluish fluorescence and produces the yellow shade of the grayed or yellowed laundry pure white.
  • Suitable compounds originate for example from the substance classes of the 4,4 '-Diamino- 2,2' stilbenedisulfonic acids (flavonic), 4,4'-biphenylene -Distyryl, Methylumbelliferone, coumarins, dihydroquinolinones, 1, 3-diaryl pyrazolines, naphthalimides, benzoxazole, benzisoxazole and benzimidazole systems, and the heterocycle-substituted pyrene derivatives.
  • the optical brighteners are usually in Amounts between 0% and 0.3 wt .-%, based on the total amount of a phase of the washing, rinsing or cleaning agent used.
  • Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt.
  • Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful.
  • cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose 1 and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the total amount of one phase the washing, Spüloder cleaning agent used.
  • the detergents, rinse or cleaning agents may contain synthetic crease inhibitors. These include, for example, synthetic products based on fatty acids, fatty acid esters, fatty acid amides, alkylol esters, alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester.
  • the textile treatment agents may contain antimicrobial agents.
  • bacteriostatic agents bactericides, fungistatics and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate, with the washing, rinsing or cleaning agents according to the invention also being entirely based on these compounds can be waived.
  • the textile treatment agents according to the invention may contain preservatives, it being preferred to use only those which have no or only a slight skin-sensitizing potential.
  • preservatives examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, formic acid and its salts, 3-iodo-2-propynyl-butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof
  • a suitable preservative is the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.
  • the washing, rinsing or cleaning agents may contain antioxidants.
  • This class of compounds includes, for example, substituted phenols, hydroquinones, catechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
  • Antistatic agents increase the surface conductivity and thus allow an improved drainage of formed charges.
  • External antistatic agents are generally substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
  • Lauryl (or stearyl) dimethylbenzylammonium chlorides are suitable as antistatics for textile fabrics or as an additive to textile treatment agents, wherein additionally a softening effect is achieved.
  • silicone derivatives may be used in the fabric treatment agents.
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
  • the viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C., the silicones being used in amounts of between 0.2 and 5% by weight, based on the total amount of one phase of the washing, rinsing or cleaning agent can.
  • a phase of the washing, rinsing or cleaning agent can also contain UV absorbers, which are absorbed by the treated textile fabrics and improve the light resistance of the fibers.
  • UV absorbers which are absorbed by the treated textile fabrics and improve the light resistance of the fibers.
  • Compounds which have these desired properties are, for example, the compounds and derivatives of the benzophenone having substituents in the 2- and / or 4-position which are active by radiationless deactivation.
  • substituted benzotriazoles in the 3-position phenyl-substituted acrylates (cinnamic acid derivatives), optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the endogenous urocanic acid.
  • Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) i or nitrilotriacetic acid (NTA), methylglycinediacetic acid trisodium salt (MGDA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • MGDA methylglycinediacetic acid trisodium salt
  • anionic polyelectrolytes such as polymaleates and polysulfonates.
  • a preferred class of complexing agents are the phosphonates, which in one phase of the washing, rinsing or cleaning agent in amounts of from 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular of 0 , 03 to 1, 5 wt .-% are included.
  • organophosphonates such as 1-hydroxyethane-1, 1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane -1, 2,4-tricarboxylic acid (PBS-AM), which are mostly used in the form of their ammonium or alkali metal salts.
  • HEDP 1-hydroxyethane-1, 1-diphosphonic acid
  • ATMP aminotri (methylenephosphonic acid)
  • DTPMP or DETPMP diethylenetriamine penta
  • PBS-AM 2-phosphonobutane -1, 2,4-tricarboxylic acid
  • the washing, rinsing or cleaning agents according to the invention can be used for cleaning and / or conditioning of textile fabrics.
  • washing, rinsing or cleaning agents according to the invention can furthermore be used for cleaning hard surfaces.
  • the invention also relates to a dispensing container which comprises a washing, rinsing or cleaning agent which contains surfactant (s) and other customary ingredients of washing, rinsing or cleaning agents, wherein the agent has at least two phases, and the agent in the Storage state of the phases has at least one substantially vertically extending phase boundary, is designed such that upon delivery of the washing, rinsing or cleaning agent, the delivery along the phase boundary.
  • a dispensing container which comprises a washing, rinsing or cleaning agent which contains surfactant (s) and other customary ingredients of washing, rinsing or cleaning agents, wherein the agent has at least two phases, and the agent in the Storage state of the phases has at least one substantially vertically extending phase boundary, is designed such that upon delivery of the washing, rinsing or cleaning agent, the delivery along the phase boundary.
  • the dispensing container for this purpose, it has a dispensing device extending the substantially vertical phase boundary of the washing, rinsing or cleaning agent.
  • the dispensing device is, for example, a cap with a concentric opening, wherein the latter is preferably also arranged in extension of the substantially vertical phase boundary of the washing, rinsing or cleaning agent.
  • a dispensing container is transparent or translucent when the light transmission of a dispensing container wall at a wavelength of 410 to 800 nm is greater than 25%.
  • the dispensing container preferably has a surface which is preferably suitable as a base.
  • the dispensing container is preferably made of metal, glass, polyethylene terephthalate (PET) or a textile-based base body.
  • the dispensing container can be flexible and, for example, have the shape of a bottle or a tube.
  • the dispensing container may be emptied and present, for example, in the form of a dispenser system.
  • the dispensing container may be, for example, a polyethylene terephthalate (PET) bottle.
  • PET polyethylene terephthalate
  • a base formulation is first prepared by means of customary and known methods and processes, in which the ingredients of the base formulation are simply mixed in stirred tanks, water, non-aqueous solvents and surfactants are conveniently presented and the other ingredients are added in portions. Separate heating in the preparation is not required, if desired, the temperature of the mixture should not exceed 80 ° C. To set the desired viscosities of the phases, it may be necessary initially to introduce only a portion of the surfactants and to add a surfactant which adjusts the viscosity to the desired value only at the end.
  • At least two differently modified base-formulation parts are filled into a transparent or translucent dispensing container.
  • the filling process of the respective base formulation parts takes place in parallel and sufficiently slowly, so that no mixing of the resulting phases takes place.
  • Table 1 shows the composition of a base formulation. Table 1 :
  • the viscosity of the base formulation was 30,000 mPas.
  • the pH of the base formulation was 6.2. This may, depending on the ingredients of the later phases of a washing, rinsing or cleaning agent, for example by adding acids such as citric acid, sulfamic acid, D-lactic acid, L-lactic acid, formic acid, maleic acid, a mixture of dicarboxylic acids (for example Sokalan DCS ex BASF), monoethanolamine, diethanolamine, triethanolamine, KOH, NaOH, LiOH, Mg (OH) 2 or Al (OH) 3 can be adjusted to a desired value.
  • acids such as citric acid, sulfamic acid, D-lactic acid, L-lactic acid, formic acid, maleic acid, a mixture of dicarboxylic acids (for example Sokalan DCS ex BASF), monoethanolamine, diethanolamine, triethanolamine, KOH, NaOH, LiOH, Mg (OH) 2 or Al (OH) 3 can be adjusted to a desired value.
  • the washing, rinsing or cleaning agent had a clearly visible, substantially vertical phase boundary even after 4 weeks of standing storage and showed no mixing of the two phases.
  • the washing, rinsing or cleaning agents 3 to 9 had a clearly visible, essentially vertical phase boundary after 4 weeks of storage and showed no mixing of the two phases.

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Abstract

L’invention concerne un agent de lavage, de rinçage ou de nettoyage présentant au moins deux phases, ledit agent présentant dans les conditions de stockage des phases au moins une séparation de phase sensiblement verticale. L’invention concerne également un contenant distributeur comprenant un agent de lavage, de rinçage ou de nettoyage multiphasique présentant au moins une séparation de phase sensiblement verticale, ledit contenant distributeur étant conçu de manière à ce que l'agent de lavage, de rinçage ou de nettoyage soit distribué au niveau de la séparation de phase.
PCT/EP2006/011755 2005-12-21 2006-12-07 Agent de lavage, de rinçage ou de nettoyage multiphasique présentant une séparation de phase verticale WO2007079849A1 (fr)

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DE102005061726.3 2005-12-21
DE200510061726 DE102005061726A1 (de) 2005-12-21 2005-12-21 Wasch-, Spül- oder Reinigungsmittel mit vertikaler Phasengrenze

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WO2007079849A1 true WO2007079849A1 (fr) 2007-07-19

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JPH01247499A (ja) * 1988-03-28 1989-10-03 Sanwa Kagaku Kogyo Kk 多色透明石鹸及びその製造方法
WO1999047635A2 (fr) * 1998-03-16 1999-09-23 Henkel Kommanditgesellschaft Auf Aktien Detergent liquide polyphase
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