Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/12—Water-insoluble compounds
  • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
  • C11D3/1246—Silicates, e.g. diatomaceous earth
  • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
  • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/04—Water-soluble compounds
  • C11D3/046—Salts
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/04—Water-soluble compounds
  • C11D3/08—Silicates
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/04—Water-soluble compounds
  • C11D3/10—Carbonates ; Bicarbonates
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/2075—Carboxylic acids-salts thereof
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/22—Carbohydrates or derivatives thereof
  • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/26—Organic compounds containing nitrogen
  • C11D3/32—Amides; Substituted amides
  • C11D3/323—Amides; Substituted amides urea or derivatives thereof

Definitions

• the invention relates to a solid, textile and / or skin care composition and their use and preparation. Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile and / or skin care composition.
• cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) - ammonium compounds or N, N-dimethyl-N, N-di (tallow acyloxyethyl) ammonium compounds.
• a solid, textile and / or skin care composition comprising a water-soluble carrier, a textile softening clay and a textile or skin care compound.
• Such a textile and / or skin care composition can be used in the main wash of an automatic washing or cleaning process.
• the textile and / or skin care composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine.
• This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser.
• this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during the dosage. Since textile-softening clays also have a water-softening effect, limescale deposits on the laundry are additionally prevented.
• the textile softening clay and the textile and / or skin care compound are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential.
• the water-soluble carrier is selected from the group consisting of inorganic alkali metal salts, organic alkali metal salts, inorganic alkaline earth metal salts, organic alkaline earth metal salts, organic acids, carbohydrates, silicates, urea and mixtures thereof.
• the water-soluble carrier comprises a carbohydrate and is selected from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose and mixtures thereof.
• a water-soluble carrier which consists of carbohydrates or at least predominantly of carbohydrates, the problem of corrosion in the washing machine is avoided, which can occur in particular when using inorganic salts as a water-soluble carrier.
• the solid, textile and / or skin care composition contains 50 to 99% by weight, preferably 75 to 95% by weight, of the water-soluble carrier.
• the textile- and / or skin care compound is selected from the group consisting of textile-softening polymers, fluorescers, antiredeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, Antioxidants, antistatic agents, ironing auxiliaries, UV absorbers, repellents, impregnating agents and mixtures thereof.
• the textiles treated with the textile and / or skin care composition according to the invention are given a further advantageous effect by the addition of one or more of these textile and / or skin care compounds or harmful or negative effects on the textiles during cleaning and / or conditioning and / or supporting fabrics, such as fading, graying, irritation of the skin, etc., diminished.
• the textile and / or skin care composition comprises a fabric softening polymer, preferably selected from the group consisting of polysiloxanes, cationic polymers and mixtures thereof.
• the textile softening effect of the textile and / or skin care composition can be further increased.
• the solid, textile and / or skin care composition contains additional ingredients, preferably selected from the group consisting of dyes, perfume, fillers, binders and mixtures thereof.
• the solid, textile and / or skin care composition additionally contains a perfume.
• the amount of perfume is 0.1 to 20 wt .-%, preferably 1 to 10 wt .-% and particularly preferably 2 to 7 wt .-%.
• Textile and / or skincare compositions are usually intended to impart a pleasant fragrance to the underwear and, for this reason, preferably contain a perfume.
• the perfume impression of the laundry can be reinforced by polysiloxanes and / or cationic polymers optionally present in the textile and / or skin care composition.
• Another advantage of the textile and / or skin care composition according to the invention, which is used in the main wash, is that the perfume is already transported directly to the laundry at the beginning of the washing and cleaning process and can thus develop its full potential.
• the water-soluble carrier is in particulate form and coated with a powder comprising the softening clay and the textile and / or skin care compound. It is particularly preferred that the water-soluble carrier has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
• Textile and / or skin care compositions having particle sizes in the range from 0.8 to 7 mm and particularly preferably in the range from 1 to 3 mm can be metered particularly well and in a targeted manner.
• the invention also relates to the use of a solid, textile and / or skin care composition according to the invention for conditioning textile fabrics.
• the invention relates to a process for the preparation of a solid, textile and / or skin care composition
• a process for the preparation of a solid, textile and / or skin care composition comprising a particulate water-soluble carrier, a textile softening clay and a textile and / or skin care compound in which the particulate carrier and the fabric softening Clay in the presence of the textile and / or skin care compound are mixed.
• the invention relates to a washing or cleaning agent comprising a solid, textile and / or skin care composition according to the invention.
• the consumer By introducing the textile and / or skin care composition according to the invention into a washing or cleaning agent, the consumer has a softening washing or cleaning agent ("2in1" washing or cleaning agent) available and he does not need to dose two agents when a perfume is added to the textile and / or skin care composition, the washing or cleaning agent and the textile and / or skin care composition are perfumed, but only one of the two agents, preferably the textile and / or skin care composition not only leads to lower costs but is also advantageous for consumers with sensitive skin and / or allergies Furthermore, it is advantageous that washing or cleaning agents with different textile and / or skin care effects are obtained in a simple and fast manner, since only the Composition of the textile and / or skin care compositions must be changed.
• 2in1 softening washing or cleaning agent
• the solid, textile and / or skin care composition contains as essential ingredients a water-soluble carrier, a fabric softening clay and a textile and / or skin care compound.
• the textile and / or skin care composition contains a fabric softening clay, such as a smectite clay.
• a fabric softening clay such as a smectite clay.
• Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
• Montmorillonite clays are the preferred softening clays.
• Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay.
• Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
• the amount of fabric softening clay in the textile and / or skin care composition is between 0.1 and 10% by weight and is preferably 1 to 5% by weight.
• the textile and / or skin care composition contains a textile and / or skin care compound.
• a textile and / or skin care compound is preferably selected from the group consisting of textile-softening polymers, fluorescers, anti-redeposition agents, optical brighteners, grayness inhibitors, shrinkage inhibitors, anti-crease agents, dye transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, UV absorbers, repellents, Impregnating agents and mixtures thereof.
• the textile and / or skin care composition contains a textile-softening polymer, in particular a polysiloxane and / or a cationic polymer.
• a preferably usable polysiloxane has at least the following structural unit
• R 1 independently of one another Ci-C 30 alkyl, preferably Ci-C 4 alkyl, in particular methyl or
• n 1 to 5000, preferably 10 to 2500, in particular 100 to 1500. It may be preferred that the polysiloxane additionally has the following structural unit:
• R 1 C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
• R 2 , R 3 independently of one another H or optionally substituted, linear or branched
• Ci-C 30 alkyl preferably with amino-substituted C 30 -alkyl, particularly preferably
• Polydimethylpolysiloxanes are known as efficient fabric care compounds.
• Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
• polysiloxane contains the structural units a) and b).
• a particularly preferred polysiloxane has the following structure:
• Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
• Suitable cationic polymers include, in particular, those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 and grouped under the collective name "Polyquaternium” The following are some of the more suitable polyquaternium compounds.
• CTFA International Cosmetic Ingredient Dictionary Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 and grouped under the collective name "Polyquaternium”
• POLYQUATERNIUM-1 CAS number: 68518-54-7
• Celquat® H 100 or Celquat® L200 available as Celquat® H 100 or Celquat® L200 (ex National Starch)
• Copolymer of acrylamide and ⁇ -methacrylyloxyethyltrimethylammonium methosulfate for example, available as Nalco 7113 (ex Nalco) or Reten® 210, Reten® 220, Reten® 230, Reten® 240, Reten® 1104, Reten® 1105 or Reten® 1106 (all ex Hercules)
• POLYQUATERNIUM-6 (CAS Number: 26062-79-3) Definition: Polymer of dimethyldiallylammonium chloride Available, for example, as Merquat® 100 (ex Ondeo-Nalco)
• Trimethylammonium substituted epoxide was reacted.
• Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
• Luviquat®PQ 11 PN ex BASF
• Gafquat® 734 Gafquat® 755
• Gafquat® 755N aternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
• Quaternary ammonium polymer salt obtainable by reacting the ethyl methacrylate / abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
• Luviquat® FC 370 available as Luviquat® FC 370, Luviquat® Style, Luviquat® FC 550 or
• Polymeric quaternary ammonium salt which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
• Polymeric quaternary ammonium salt which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
• Gafquat® HS-100 ex GAF
• Luviquat® Ultracare available as Luviquat® Ultracare (ex BASF)
• the cationic polymers do not necessarily have only a textile softening effect, but may additionally have a skin-care effect.
• a skin-care compound is understood to mean a compound or a mixture of compounds which, upon contact of a textile with the solid, textile and / or skin-care composition, draw on the textile and, on contact of the textile with skin, confer an advantage on the skin compared with a textile which has not been treated with the textile and / or skin care composition according to the invention.
• This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
• the skin care composition is preferably hydrophobic, may be liquid or solid and must be compatible with the other ingredients of the solid, textile and / or skin care composition.
• the skin care compound may, for example, be: a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof; b) Plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, aloe vera, chamomile and mixtures thereof; c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty
• textile-care compounds preferably comprise fluorescers, antiredeposition agents, optical brighteners, grayness inhibitors, shrinkage inhibitors, anti-crease agents, dye transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, UV absorbers, repellents, impregnating agents.
• these textile-care compounds can be found in the description of the washing or cleaning agent according to the invention and can also be used in the solid, textile and / or skin care composition.
• the solid, textile and / or skin care composition may also contain mixtures of said compounds.
• the amount of textile and / or skin care compound in the textile and / or skin care composition is 0.1 to 10 wt .-% and preferably between 1 and 6 wt .-%.
• the water-soluble carrier preferably includes inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof, organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium sodium tartrate, inorganic alkaline earth metal salts such as calcium chloride or magnesium chloride, organic alkaline earth metal salts such as calcium lactate, carbohydrates, organic acids such as citric acid or tartaric acid, silicates such as water glass, sodium silicate or potassium silicate, urea and mixtures thereof.
• inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof
• organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium
• the water-soluble carrier may in particular comprise a carbohydrate, which is for example selected from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose and mixtures thereof.
• the carbohydrate used may be, for example, candy or hail sugar.
• the water-soluble carrier may also contain mixtures of said materials.
• the water-soluble carrier has particle sizes in the range from 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. Most preferably, the water-soluble carrier comprises sucrose crystals having a particle size of 1 to 2 mm.
• the textile and / or skin care compound is used as a liquid, either in pure form or in the form of a solution, an emulsion or a dispersion, in order to increase the adhesion of the coating to the water-soluble carrier.
• the textile and / or skin care composition according to the invention may optionally contain further ingredients.
• dyes In order to improve the aesthetic impression of the textile and / or skin care composition, they can be dyed with suitable dyes.
• Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of the laundry detergents or cleaners and to light and no pronounced substantivity to textile fibers so as not to stain them.
• the textile and / or skin care composition may contain a perfume. It is even particularly preferred that the textile and / or skin care composition contains a perfume.
• perfume oils or fragrances individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
• perfume oils may also contain natural fragrance mixtures as are available from plant sources.
• the amount of perfume in the textile and / or skin care composition is preferably between 0.1 and 20 wt .-%, particularly preferably between 1 and 10 wt .-%, and most preferably between 2 and 7 wt .-% ,
• the textile and / or skin care composition may contain a filler, such as silica or salts.
• the salts may include, for example, alkali or alkaline earth salts, such as, for example, sodium sulfate.
• the amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.
• the textile and / or skin care composition may also contain a pearlescing agent to increase gloss.
• suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina AGS from Cognis) and PEG-3-distearate.
• the textile and / or skin care composition may also contain a binder.
• Suitable binders include, for example, polyethylene glycols, fusible carbohydrates, polyesters, fatty acids, fatty acid soaps or quaternized ammonium compounds.
• the coating powder comprising the textile softening clay and the textile and / or skin care compound and optionally dyes, perfume, fillers and / or pearlescing agent, is applied to the water-soluble carrier in a mixer ,
• the textile and / or skin care composition is particularly suitable for conditioning textile fabrics and is used together with a conventional Washing or cleaning agent in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.
• the textile and / or skin care composition can be incorporated into a detergent or cleaning agent.
• a solid detergent or cleaning agent with 0.1 to 20 wt .-%, preferably 1 to 10 wt .-%, of the textile and / or skin care composition according to the invention is mixed.
• the washing or cleaning agents according to the invention contain, in addition to the textile and / or skin care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
• the total surfactant content of a detergent is preferably below 40% by weight and more preferably below 35% by weight, based on the total detergent.
• the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol residue can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
• alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
• Preferred ethoxylated alcohols include, for example, C 12 _ 14 - alcohols containing 3 EO, 7 EO or 4 EO, C9-11 alcohol containing 7 EO, C. 13 15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12 -i 8 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12 -i 4 -alcohol with 3 EO and C 12 . 18- alcohol with 7 EO.
• the stated degrees of ethoxylation represent statistical averages, which for a specific product may be an integer or a fractional number.
• Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
• fatty alcohols with more than 12 EO can also be used. Examples of these are tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
• Nonionic surfactants which contain EO and PO groups together in the molecule can also be used according to the invention.
• block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
• mixed alkoxylated nonionic surfactants can be used in which EO and PO units are not blockwise, but are statistically distributed. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.
• nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
• the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1, 2 to 1, 4.
• Alkyl glycosides are known, mild surfactants.
• nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
• Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable.
• the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.
• surfactants are polyhydroxy fatty acid amides of the formula (VII), R 1
• the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
• the group of polyhydroxy fatty acid amides also includes compounds of the formula (VIII)
• R 1 is a linear, branched or cyclic alkyl radical or an aryl radical with 2 to 8 carbon atoms
• R 2 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms
• C- ⁇ _ 4 alkyl or phenyl radicals are preferred
• [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted with at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives of this group.
• [Z] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
• a sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
• the N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
• the content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the total detergent or cleaning agent.
• anionic surfactants for example, those of the sulfonate type and sulfates are used.
• the surfactants of the sulfonate type are preferably C 9 . 13- Alkylbenzolsulfonate, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as obtained for example from C 12 -i 8 monoolefins with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation, in consideration.
• alkanesulfonates which are obtained from C 12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
• esters of .alpha.-sulfo fatty acids esters of .alpha.-sulfo fatty acids (ester sulfonates), for example the .alpha.-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
• Suitable anionic surfactants are sulfated fatty acid glycerol esters.
• Fatty acid glycerol esters are to be understood as meaning the mono-, di- and triesters and mixtures thereof, as they are known in the art Preparation can be obtained by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol.
• Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
• Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myrilecyl, cetyl or stearyl alcohol or the C 10 -C 2 o-oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
• the C 12 -C 16 -alkyl sulfates and C 12 -C 15 -alkyl sulfates and also C 14 -C 15 -alkyl sulfates are preferred.
• 2,3-alkyl sulfates which can be obtained as commercial products from Shell Oil Company under the name DAN ®, are suitable anionic surfactants.
• 2 alcohols such as 2-methyl-branched with an average of 3.5 moles of ethylene oxide (EO) or C 12 . 18 fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.
• Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and which are monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
• alcohols preferably fatty alcohols and in particular ethoxylated fatty alcohols.
• Preferred sulfosuccinates contain C 8 . 18- fatty alcohol residues or mixtures of these.
• Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants.
• sulfosuccinates whose fatty alcohol radicals are derived from ethoxylated fatty alcohols with a narrow homolog distribution are particularly preferred.
• alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the Al k (en) yl chain or salts thereof.
• Particularly preferred anionic surfactants are soaps.
• Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
• the anionic surfactants may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
• the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
• the content of preferred detergents or cleaning agents to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total washing or cleaning agent.
• washing or cleaning agents may contain other ingredients that further improve the performance and / or aesthetic properties of the detergent or cleaning agent.
• preferred washing or cleaning agents additionally comprise one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, antiredeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-caking agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, cursing agents, repellents and impregnating agents, swelling and anti-slip agents, neutral filling salts and UV absorbers.
• Suitable builders which may be present in the detergents or cleaners are in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
• Suitable crystalline, layered sodium silicates have the general formula NaMSi x O 2x + I H 2 O, where M is sodium or hydrogen, x is a number from 1, 9 to 4 and y is a number from 0 to 20 and preferred values for x 2 , 3 or 4 are.
• Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both ⁇ - and ⁇ -sodium disilicates Na 2 Si 2 O 5 .yH 2 O are preferred.
• amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties.
• the dissolution delay compared with conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying.
• the term "amorphous” is also understood to mean "X-ray amorphous”.
• the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to a maximum of 50 nm and in particular up to a maximum of 20 nm being preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
• the finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P.
• zeolite P zeolite MAP® (commercial product from Crosfield) is particularly preferred.
• zeolite X and mixtures of A, X and / or P are also suitable.
• Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) ), which is sold by SASOL under the brand name VEGOBOND AX ® and by the formula
• zeolite can be used as a spray-dried powder or else as an undried, stabilized suspension which is still moist from its production.
• the zeolite may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols having 2 to 5 ethylene oxide groups , C 12 -C 14 -FeH- alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols.
• Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution; Coulter Counter) and preferably contain from 18 to 22% by weight, in particular from 20 to 22% by weight, of bound water.
• phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
• Organic builders which may be present in the detergent or cleaning agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, poly-aspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or malonates, which are preferably used as sodium salts.
• sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance.
• Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.
• bleach activators can be incorporated into the detergents or cleaners.
• bleach activators it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid.
• Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups.
• polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy- 2,5-dihydrofuran.
• TAED tetraacet
• bleach catalysts can also be incorporated into the detergents or cleaners.
• bleach-enhancing transition metal salts or transition metal complexes such as, for example, Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes.
• Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
• the washing or cleaning agent may contain enzymes in encapsulated form and / or directly in the washing or cleaning agent.
• Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other Glykosylhydrolasen, hemicellulase, cutinases, ß-glucanases, oxidases, peroxidases, perhydrolases and / or laccases and mixtures the enzymes mentioned in question. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying.
• cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils.
• Oxireductases can also be used for bleaching or inhibiting color transfer.
• Particularly suitable are bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents.
• subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
• enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
• lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases.
• Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
• Cellulases used are preferably cellobiohydrolases, endoglucanases and .beta.-glucosidases, which are also called celiotrises, or mixtures thereof. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by means of targeted mixtures of the cellulases.
• the enzymes may be adsorbed to carriers to protect against premature degradation.
• the proportion of enzymes or enzyme granules directly in the washing or cleaning may, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.
• washing or cleaning agent contains no enzymes.
• the washing or cleaning agent optionally contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%.
• the amount of perfume used is also dependent on the type of detergent or cleaning agent. However, it is particularly preferred that the perfume is introduced into the washing or cleaning agent via the textile and / or skin care composition. However, it is also possible for the washing or cleaning agent to contain perfume which is not introduced into the washing or cleaning agent via the textile and / or skin care composition.
• the detergents or cleaners may (optionally only partially) be colored with suitable dyes.
• Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
• Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
• Suitable soil release polymers also referred to as "anti-redeposition agents” include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 wt% and hydroxypropyl groups of 1 to 15 wt%, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof.
• nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30 wt% and hydroxypropyl groups of 1 to 15 wt%, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and
• Suitable derivatives include the sulfonated derivatives of phthalic acid and Terephthalic acid polymers.
• Another class of suitable soil-release polymers in particular for cotton-containing textiles, are modified, for example alkoxylated and / or quaternized and / or oxidized, polyamines.
• the polyamines are, for example, polyalkyleneamines, such as polyethyleneamines, or polyalkylenimines, such as polyethyleneimines.
• Preferred examples of this class of soil release polymers are ethoxylated polyethylenimines and ethoxylated polyethyleneamines.
• Optical brighteners can be added to laundry detergents or cleaners to eliminate graying and yellowing of the treated fabrics, which will attract the fiber and cause lightening and fake bleaching by exposing invisible ultraviolet radiation to visible . convert longer wavelength light, wherein the absorbed from sunlight ultraviolet light is radiated as pale bluish fluorescence and produces the yellow shade of the grayed or yellowed laundry pure white Suitable compounds originate for example from the substance classes of the 4,4 '- diamino-2,2 stilbenedisulfonic acids (flavonic), 4,4'-biphenylene -Distyryl, Methylumbelliferone, coumarins, dihydroquinolinones, 1, 3-diaryl pyrazolines, naphthalimides, benzoxazole, benzisoxazole, and benzimidazole systems, and are heterocycles pyrene derivatives.
• the optical brighteners usually in amounts of between 0% and 0.3% by weight, based
• Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt.
• Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
• water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful.
• cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the detergents or cleaners used.
• the washing or detergents contain a dye transfer inhibitor.
• the color transfer inhibitor is a polymer or copolymer of cyclic amines such as vinylpyrrolidone and / or vinylimidazole.
• Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof.
• polyvinylpyrrolidone PVP
• polyvinylimidazole PVI
• copolymers of vinylpyrrolidone and vinylimidazole PVP / PVI
• the polyvinylpyrrolidones (PVP) used preferably have an average molecular weight of 2,500 to 400,000 and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan® HP 50 or Sokalan® HP 53 available.
• the copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used preferably have a molecular weight in the range from 5,000 to 100,000.
• a PVP / PVI copolymer for example from BASF under the name Sokalan® HP 56th
• the amount of dye transfer inhibitor based on the total amount of the detergent or cleaning agent is preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight, and more preferably from 0.1 to 0.5% by weight. -%.
• enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which removes hydrogen peroxide in water as a color transfer inhibitor.
• a mediator compound for the peroxidase for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, it also being possible to additionally use the abovementioned polymeric color transfer inhibitors.
• the detergents or cleaning agents may contain synthetic crease inhibitors. These include, for example, synthetic products based on fatty acids, fatty acid esters, fatty acid amides, alkylol esters, -alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester. To combat microorganisms washing or cleaning agents may contain antimicrobial agents.
• bacteriostats and bactericides Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostats and bactericides, fungistatics and fungicides, etc.
• Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate, and it is entirely possible to dispense with these compounds in the detergents and cleaning agents according to the invention ,
• the detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a slight skin-sensitizing potential.
• preservatives examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof.
• a suitable preservative is the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.
• the detergents or cleaners may contain antioxidants.
• This class of compounds includes, for example, substituted phenols, hydroquinones, pyrocatechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
• Antistatic agents increase the surface conductivity and thus allow an improved drainage of formed charges.
• External antistatic agents are generally substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
• Lauryl (or stearyl) dimethylbenzylammonium chlorides are suitable as antistatic agents for textile fabrics or as an additive to detergents or cleaners, wherein additionally a softening effect is achieved.
• silicone derivatives can be used in the detergents or cleaners. These additionally improve the rinsing behavior of the washing or cleaning agents by their foam-inhibiting properties.
• Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
• Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
• the viscosities of the preferred silicones at 25 0 C in the range between 100 and 100,000 mPas, wherein the silicones in amounts between 0.2 and 5 wt .-%, based on the total detergent or cleaning agent can be used.
• the detergents or cleaners may also contain UV absorbers which are applied to the treated fabrics and improve the light fastness of the fibers.
• Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid.
• Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
• EDTA ethylenediaminetetraacetic acid
• NTA nitrilotriacetic acid
• anionic polyelectrolytes such as polymaleates and polysulfonates.
• a preferred class of complexing agents are the phosphonates, which in preferred detergents or cleaners in amounts of 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1, 5 wt .-% are included.
• These preferred compounds include, in particular, organophosphonates such as, for example, 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriaminepenta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane -1, 2,4-tricarboxylic acid (PBS-AM), which are mostly used in the form of their ammonium or alkali metal salts.
• neutral fillers such as sodium sulfate or sodium carbonate may be included in the solid detergents or cleaners.
• washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.
• the washing or cleaning agent without the textile and / or skin care composition by known methods, which include, for example, drying steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post addition")
• the resulting product may then be mixed with a solid, textile and / or skin care composition
• the compaction step may be followed by further compaction and / or shaping steps.
• Table 1 shows textile and / or skin care compositions E1 to E5 according to the invention.
• the textile and / or skin care compositions according to the invention exhibited a softening effect in comparison with water (the fabrics treated with water or with the textile and / or skin care compositions were treated after treatment and suspended drying from a panel consisting of 5 persons ) tapped.
• the textile and / or skin care compositions of the present invention are capable of reducing the hardness of water. This determination was carried out with analysis sticks "total hardness test" (Merck) according to the manufacturer's instructions.
• washing or cleaning agent prepared according to the invention, a solid, unparfumed washing or cleaning agent was mixed with 10% by weight (based on the total amount of finished washing or cleaning agent) of the textile and / or skin care composition E6.
• the washing or cleaning agent according to the invention showed good cleaning and conditioning properties.

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