WO2007068687A2 - Crystallizer - Google Patents

Crystallizer Download PDF

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Publication number
WO2007068687A2
WO2007068687A2 PCT/EP2006/069582 EP2006069582W WO2007068687A2 WO 2007068687 A2 WO2007068687 A2 WO 2007068687A2 EP 2006069582 W EP2006069582 W EP 2006069582W WO 2007068687 A2 WO2007068687 A2 WO 2007068687A2
Authority
WO
WIPO (PCT)
Prior art keywords
crystallizer
radius
curvature
holes
curved
Prior art date
Application number
PCT/EP2006/069582
Other languages
French (fr)
Other versions
WO2007068687A3 (en
WO2007068687A8 (en
Inventor
Nuredin Kapaj
Alfredo Poloni
Gianni Zomero
Original Assignee
Danieli & C. Officine Meccaniche S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danieli & C. Officine Meccaniche S.P.A. filed Critical Danieli & C. Officine Meccaniche S.P.A.
Priority to EP06819946A priority Critical patent/EP1979113A2/en
Publication of WO2007068687A2 publication Critical patent/WO2007068687A2/en
Publication of WO2007068687A3 publication Critical patent/WO2007068687A3/en
Publication of WO2007068687A8 publication Critical patent/WO2007068687A8/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/055Cooling the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/043Curved moulds

Definitions

  • the present invention refers to a curved crystallizer, in particular for the continuous casting of blooms and billets.
  • crystallizers for use with continuous casting plants for blooms or billets are known in the prior art. These crystallizers substantially consist of a hollow monolithic body, usually made of copper, the cross-section of which defines the shape of the cast product.
  • the outer wall of a first type of crystallizer is provided with a jacket through which a cooling fluid flows, said cooling fluid usually consisting of water.
  • crystailizers that incorporate, inside the thickness of their walls, holes through which the cooling water flows. This achieves a better heat transfer while continuing to ensure good crystallizer strength.
  • the main purpose of the present invention is to implement a curved crystallizer for continuous casting of blooms or billets that comprises a suitable cooling system capable of providing an optimum transfer of the heat from the liquid metal inside the curved crystallizer towards the outside.
  • a second purpose is to prevent, thanks to the curvature of the crystallizer, the generation of critical stresses in the cast product as it passes from the crystallizer to the casting machine.
  • Another purpose is to provide a complete casting plant, comprising the crystallizer and casting machine, that is as compact as possible in terms of its height.
  • the present invention achieves the purposes described above with a curved crystallizer for continuous casting of blooms or billets that, in accordance with that set forth in claim 1 , comprises a tubular structure, having a curved longitudinal axis that defines a first radius of curvature, the cross-section of which on a plane orthogonal to the longitudinal axis defines the shape of said blooms or billets, said tubular structure comprising between an outer wall and an inside wall longitudinal holes through which a cooling fluid can flow, said holes extending for the entire length of the crystallizer and having a substantially circular cross-section, said inside wall coming into contact with a molten metal, characterized in that said longitudinal holes have a curved longitudinal axis with the same radius of curvature, and in that the value of said first radius of curvature is between 1 and 5 times the value of a second radius of curvature, said second radius being the smallest radius of curvature of the curvilinear sections that constitute a casting machine, arranged immediately downstream of said crystallizer.
  • the crystallizer according to the present invention is provided with longitudinal cooling holes, arranged in the thickness of the walls of the crystallizer, very close to the inside wall of the crystallizer and having a curved shape with a curvature identical to that of the crystallizer; advantageously, said arrangement makes it possible to obtain:
  • Fig. 1 shows a perspective view of a crystallizer according to the invention
  • Fig. 2 schematically shows the curvatures of a crystallizer according to the invention and of a casting machine arranged downstream
  • Figs. 3, 4, 5 show top views of portions of the wall of the crystallizer
  • Fig. 6 shows a longitudinal cross-section of the crystallizer according to the inven- tion.
  • a curved crystallizer is shown, globally indicated by reference numeral 1 , said crystallizer having a quadrangular cross-section.
  • said crystallizer is advantageously provided with a predetermined radius of curvature R 0 so as to optimize the progressive and gradual deformation of the billet, that solidifies inside the crystallizer when it comes into contact with the inside wall 4, so as to guarantee an effective continuity of the line with a casting machine 2 arranged downstream. The generation of critical stresses that may lead to the formation of cracks inside the cast product is thus prevented.
  • cooling holes are provided inside the thickness of the curved crystallizer according to the invention, said cooling holes advantageously having a predetermined radius of curvature that is substantially equal to the radius of curvature R c of said crystallizer.
  • the value of said radius of curvature R c is between 1 and 5 times the value of the main radius R m of the casting machine 2, where the main radius R m is the minimum radius of curvature among the radii of curvature of the various sections that constitute the casting machine 2.
  • the distance "D" of the cooling holes 3 from the inside wall 4 of the crystallizer, over which the solidifying liquid metal flows, is constant along the entire length of the curved crystallizer, said distance being between approximately
  • the diameter "d" of said cooling holes 3 is advantageously chosen from between approximately 8 and 14 mm and their centre-to-centre distance "i" can vary between approximately 12 and 35 mm.
  • a further advantage consists of the fact that the cooling water can be made to flow through these holes 3 in a top-to-bottom direction. This prevents the water from boiling and thus prevents uneven cooling in the meniscus region where the majority of defects in the cast product originate.

Abstract

A curved crystallizer for continuous casting of blooms or billets comprises a suitable cooling system capable of providing an optimum transfer of the heat from the liquid metal inside the crystallizer towards the outside. The crystallizer according to the present invention satisfies the need to prevent the generation of critical stresses in the cast product during its passage from said crystallizer to the casting machine arranged downstream thereof, and also the need to implement a complete casting plant, comprising the crystallizer and casting machine, which is extremely compact in terms of its height.

Description

Crystallizer
Field of the invention
The present invention refers to a curved crystallizer, in particular for the continuous casting of blooms and billets. Prior art
Numerous crystallizers for use with continuous casting plants for blooms or billets are known in the prior art. These crystallizers substantially consist of a hollow monolithic body, usually made of copper, the cross-section of which defines the shape of the cast product. To cool the molten metal during casting, and start the process of progressive solidification of the metal, the outer wall of a first type of crystallizer is provided with a jacket through which a cooling fluid flows, said cooling fluid usually consisting of water. Several problems have arisen in connection with the use of this type of crystallizer, due to the very thick copper wall between the cooling water in the jacket and the solidifying metal inside the crystallizer. These problems include:
- the high temperatures that are reached on the wall that comes into contact with the liquid metal;
- the high temperature gradients along the thickness and along the length of the crystallizer;
- excessive deformation of the walls of the crystallizer due to the high thermal stresses, particularly in case of thin walls;
- uneven cooling over the cross-section;
- the impossibility of controlling the internal taper so that the crystallizer cannot correctly follow the shrinkage of the solidifying shell;
- limited life due to the formation of cracks on the chrome coating in the meniscus region;
- the surface quality is not good and oscillation marks are clearly visible;
- the formation of geometrical defects such as rhomboidity; - the formation of structural defects such as cracks near the corners, known as "off-corner" cracks, that can cause the shell to rupture and the subsequent breakout of liquid metal, etc. Many of these problems have been solved with a subsequent generation of crystailizers that incorporate, inside the thickness of their walls, holes through which the cooling water flows. This achieves a better heat transfer while continuing to ensure good crystallizer strength.
One drawback that has not yet been overcome however regards longitudinally curved crystailizers, used to progressively and gradually deform the billet so as to prevent the generation of critical stresses that can result in the formation of cracks inside the cast product.
In order to achieve an effective continuity of the line with the casting machine, which is arranged immediately after the crystallizer, and to create a complete casting plant that is as compact as possible, in particular in terms of its height, it has been found that the crystailizers known in the prior art are not provided with a suitable primary cooling system capable of providing an optimum transfer of the heat from the liquid metal towards the outside of the curved crystallizer. The need is therefore felt to implement a crystallizer capable of overcoming the drawbacks described above. Summary of the invention
The main purpose of the present invention is to implement a curved crystallizer for continuous casting of blooms or billets that comprises a suitable cooling system capable of providing an optimum transfer of the heat from the liquid metal inside the curved crystallizer towards the outside.
A second purpose is to prevent, thanks to the curvature of the crystallizer, the generation of critical stresses in the cast product as it passes from the crystallizer to the casting machine. Another purpose is to provide a complete casting plant, comprising the crystallizer and casting machine, that is as compact as possible in terms of its height.
The present invention achieves the purposes described above with a curved crystallizer for continuous casting of blooms or billets that, in accordance with that set forth in claim 1 , comprises a tubular structure, having a curved longitudinal axis that defines a first radius of curvature, the cross-section of which on a plane orthogonal to the longitudinal axis defines the shape of said blooms or billets, said tubular structure comprising between an outer wall and an inside wall longitudinal holes through which a cooling fluid can flow, said holes extending for the entire length of the crystallizer and having a substantially circular cross-section, said inside wall coming into contact with a molten metal, characterized in that said longitudinal holes have a curved longitudinal axis with the same radius of curvature, and in that the value of said first radius of curvature is between 1 and 5 times the value of a second radius of curvature, said second radius being the smallest radius of curvature of the curvilinear sections that constitute a casting machine, arranged immediately downstream of said crystallizer.
The crystallizer according to the present invention is provided with longitudinal cooling holes, arranged in the thickness of the walls of the crystallizer, very close to the inside wall of the crystallizer and having a curved shape with a curvature identical to that of the crystallizer; advantageously, said arrangement makes it possible to obtain:
- very low temperatures on the wall that comes into contact with the liquid metal;
- low temperature gradients along the thickness and along the length of the crys- tallizer;
- substantially no deformation of the walls of the crystallizer thanks to its high strength;
- very even cooling over the cross-section;
- good control of its internal taper; - longer life, three times that of the crystallizers known in the prior art, also thanks to the fact that no cracks are formed on the chrome coating in the meniscus region;
- excellent surface quality with a very small number of oscillation marks;
- excellent structural properties without cracks near the corners; - no geometrical defects along the cross-sections transversal to the curved longitudinal axis.
The claims attached hereto describe preferred embodiments of the invention.
Brief description of the drawings
Further characteristics and advantages of this invention will become clear from the following detailed description of a preferred, but not exclusive embodiment of a crystallizer, that is merely illustrative and not limitative, with the help of the drawings attached hereto, in which:
Fig. 1 shows a perspective view of a crystallizer according to the invention; Fig. 2 schematically shows the curvatures of a crystallizer according to the invention and of a casting machine arranged downstream; Figs. 3, 4, 5 show top views of portions of the wall of the crystallizer; Fig. 6 shows a longitudinal cross-section of the crystallizer according to the inven- tion.
Detailed description of a preferred embodiment of the invention With reference to Figs. 1 and 2 a curved crystallizer is shown, globally indicated by reference numeral 1 , said crystallizer having a quadrangular cross-section. According to this preferred but not exclusive embodiment, said crystallizer is advantageously provided with a predetermined radius of curvature R0 so as to optimize the progressive and gradual deformation of the billet, that solidifies inside the crystallizer when it comes into contact with the inside wall 4, so as to guarantee an effective continuity of the line with a casting machine 2 arranged downstream. The generation of critical stresses that may lead to the formation of cracks inside the cast product is thus prevented.
Furthermore, to guarantee the optimum transfer of the heat towards the outer wall
5 of the crystallizer and overcome the drawbacks typically associated with the curved crystallizers known in the prior art, longitudinal through holes or ducts 3, called cooling holes, are provided inside the thickness of the curved crystallizer according to the invention, said cooling holes advantageously having a predetermined radius of curvature that is substantially equal to the radius of curvature Rc of said crystallizer. The value of said radius of curvature Rc is between 1 and 5 times the value of the main radius Rm of the casting machine 2, where the main radius Rm is the minimum radius of curvature among the radii of curvature of the various sections that constitute the casting machine 2.
Advantageously, the distance "D" of the cooling holes 3 from the inside wall 4 of the crystallizer, over which the solidifying liquid metal flows, is constant along the entire length of the curved crystallizer, said distance being between approximately
6 and 20 mm, thus ensuring an even cooling along said length. The diameter "d" of said cooling holes 3 is advantageously chosen from between approximately 8 and 14 mm and their centre-to-centre distance "i" can vary between approximately 12 and 35 mm. A further advantage consists of the fact that the cooling water can be made to flow through these holes 3 in a top-to-bottom direction. This prevents the water from boiling and thus prevents uneven cooling in the meniscus region where the majority of defects in the cast product originate.
The specific embodiments described in this document are not limitative and this patent application covers all the alternative embodiments of the invention as set forth in the claims.

Claims

1. A curved crystallizer for continuous casting of blooms or billets comprising a tubular structure, having a curved longitudinal axis that defines a first radius of curvature (Rc), the cross-section of which on a plane orthogonal to the longitudinal axis defines the shape of said blooms or billets, said tubular structure comprising between an outer wall (5) and an inside wall (4) longitudinal holes (3) through which a cooling fluid can flow, said holes extending for the entire length of the crystallizer and having a substantially circular cross-section, said inside wall coming into contact with a molten metal, characterized in that said longitudinal holes (3) have a curved longitudinal axis with the same radius of curvature (Rc), and in that the value of said first radius of curvature (Rc) is between 1 and 5 times the value of a second radius of curvature (Rm), said second radius being the smallest radius of curvature of the curvilinear sections that constitute a casting machine (2), arranged immediately downstream of said crystallizer.
2. Crystallizer according to claim 1 , wherein the distance (D) between said longitudinal holes (3) and said inside wall (4) is constant along the entire length of the crystallizer, said distance being between approximately 6 and 20 mm.
3. Crystallizer according to claim 1 or 2, wherein said longitudinal holes (3) have a diameter (d) of between approximately 8 and 14 mm.
4. Crystallizer according to one or more of the previous claims, wherein the centre- to-centre distance (i) between said holes (3) is between approximately 12 and 35 mm.
PCT/EP2006/069582 2005-12-13 2006-12-12 Crystallizer WO2007068687A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06819946A EP1979113A2 (en) 2005-12-13 2006-12-12 Crystallizer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2005A002367 2005-12-13
ITMI20052367 ITMI20052367A1 (en) 2005-12-13 2005-12-13 crystallizer

Publications (3)

Publication Number Publication Date
WO2007068687A2 true WO2007068687A2 (en) 2007-06-21
WO2007068687A3 WO2007068687A3 (en) 2007-08-16
WO2007068687A8 WO2007068687A8 (en) 2008-06-05

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EP (1) EP1979113A2 (en)
IT (1) ITMI20052367A1 (en)
WO (1) WO2007068687A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010015399A1 (en) * 2008-08-06 2010-02-11 Sms Siemag Ag Strand casting mold for liquid metal, particularly for liquid steel
CN102335729A (en) * 2011-10-24 2012-02-01 中冶连铸技术工程股份有限公司 Hyperbolic-type crystallizer copper pipe

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109940141A (en) * 2019-04-25 2019-06-28 芜湖新兴铸管有限责任公司 Square blank crystallizer on-line tuning technique

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0071401A1 (en) * 1981-07-24 1983-02-09 Nippon Steel Corporation A curved mold for continuous casting
GB2177956A (en) * 1985-07-26 1987-02-04 Kabel Metallwerke Ghh Mould for the continuous casting of metal
US6367539B1 (en) * 1999-01-13 2002-04-09 Danieli & C. Officine Meccaniche Spa Crystalliser for continuous casting

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0071401A1 (en) * 1981-07-24 1983-02-09 Nippon Steel Corporation A curved mold for continuous casting
GB2177956A (en) * 1985-07-26 1987-02-04 Kabel Metallwerke Ghh Mould for the continuous casting of metal
US6367539B1 (en) * 1999-01-13 2002-04-09 Danieli & C. Officine Meccaniche Spa Crystalliser for continuous casting

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010015399A1 (en) * 2008-08-06 2010-02-11 Sms Siemag Ag Strand casting mold for liquid metal, particularly for liquid steel
CN102335729A (en) * 2011-10-24 2012-02-01 中冶连铸技术工程股份有限公司 Hyperbolic-type crystallizer copper pipe

Also Published As

Publication number Publication date
ITMI20052367A1 (en) 2007-06-14
WO2007068687A3 (en) 2007-08-16
WO2007068687A8 (en) 2008-06-05
EP1979113A2 (en) 2008-10-15

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