WO2007068172A1 - Forming methods of film label or packing material - Google Patents

Forming methods of film label or packing material Download PDF

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Publication number
WO2007068172A1
WO2007068172A1 PCT/CN2006/002494 CN2006002494W WO2007068172A1 WO 2007068172 A1 WO2007068172 A1 WO 2007068172A1 CN 2006002494 W CN2006002494 W CN 2006002494W WO 2007068172 A1 WO2007068172 A1 WO 2007068172A1
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WO
WIPO (PCT)
Prior art keywords
film
pattern
protective layer
layer
providing
Prior art date
Application number
PCT/CN2006/002494
Other languages
French (fr)
Chinese (zh)
Inventor
Huarong Li
Original Assignee
Huarong Li
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN 200510134302 external-priority patent/CN1982045A/en
Priority claimed from CNB2006100720239A external-priority patent/CN100519937C/en
Application filed by Huarong Li filed Critical Huarong Li
Publication of WO2007068172A1 publication Critical patent/WO2007068172A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • B32B2307/4023Coloured on the layer surface, e.g. ink
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/75Printability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2519/00Labels, badges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00Packaging equipment or accessories not otherwise provided for

Definitions

  • the present invention relates to a method of making a film label or packaging material.
  • Film labels or packaging materials can be widely used in trademarks, seals, various types of wrapping paper, and the like.
  • metallization treatment such as bronzing treatment or partial transfer treatment is required to obtain a certain visual effect, but both the hot stamping treatment and the partial transfer treatment require high processing cost and comparison. Long processing time.
  • a first aspect of the present invention provides a method for fabricating a film label or packaging material, comprising the steps of: providing a film; vacuum evaporating a metal plating layer on the surface of the film; and printing a chemical resistant protective layer on the metal plating layer, the protection
  • the shape of the layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the coverage area of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film; a bottom paper is provided; A film that requires a metal pattern or pattern is pressed against the backing paper to obtain a film label or packaging material.
  • a second aspect of the present invention provides a method for fabricating a film label or packaging material, comprising the steps of: providing a first film; vacuum evaporating a metal plating layer on the surface of the first film; and printing a chemical resistant protective layer on the metal plating layer
  • the shape of the protective layer corresponds to a desired metal pattern or pattern; removing a metal plating layer outside the cover layer of the protective layer on the surface of the first film by chemical etching to obtain a desired metal pattern or pattern on the surface of the first film; a second film for protecting a pattern layer prepared on the first film; and combining the first film with the second film.
  • a third aspect of the invention provides a method for fabricating another film label or packaging material, comprising the steps of: providing a film; vacuum evaporating a metal plating layer on the surface of the film; and printing a chemical resistant protective layer on the metal plating layer,
  • the shape of the protective layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the cover layer of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film; the surface of the film is coated with transparent or semi-coated Transparent ink for protection preparation a patterned layer on the film.
  • a fourth aspect of the present invention provides a method for fabricating a film label or packaging material, comprising the steps of: providing a film; vacuum evaporating a metal plating layer on the surface of the film; and printing a chemical resistant protective layer on the metal plating layer,
  • the shape of the protective layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the coverage of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film;
  • Non-metallic materials are examples of the shape of the protective layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the coverage of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film; Non-metallic materials.
  • the film may be made of chemically resistant insulating material such as ethylene terephthalate polyester (PET); the vapor deposited metal may be aluminum, copper or silver; the protective layer may be coated with an acid-resistant paint or ink such as poly An amide ink or the like; the chemical etching solution may be an acidic or alkaline etching solution such as sodium hydroxide or hydrochloric acid.
  • chemically resistant insulating material such as ethylene terephthalate polyester (PET)
  • PET ethylene terephthalate polyester
  • the vapor deposited metal may be aluminum, copper or silver
  • the protective layer may be coated with an acid-resistant paint or ink such as poly An amide ink or the like
  • the chemical etching solution may be an acidic or alkaline etching solution such as sodium hydroxide or hydrochloric acid.
  • a transparent non-metallic material such as zinc sulfide can enhance the protection of the printing ink while retaining a portion of the laser effect that remains of the removed metal coating.
  • a metal plating layer is deposited on the film and the metal plating layer is selectively etched to replace the conventional metallization process such as partial hot stamping or partial transfer, thereby obtaining a An inexpensive and efficient method of making film labels or packaging materials.
  • a flexible insulating film made of a material such as a thermosetting resin is vapor-deposited with an aluminum layer having a plating thickness of preferably 300 ⁇ to 500 ⁇ .
  • the aluminum-plated insulating film is taken out from the vacuum apparatus, and printed on the aluminized surface of the insulating film by a printing method known in the art to form a polyamide ink protective layer having a predetermined pattern or pattern thereon.
  • the predetermined graphic or pattern corresponds to the desired graphic or pattern.
  • the insulating film is introduced into an etching bath containing sodium hydroxide to etch away the aluminum layer outside the coverage area of the polyimide coating to obtain the desired metal pattern or pattern on the aluminized surface of the insulating film instead of obtaining hot stamping or The visual effect of local transfer;
  • the traditional process of cross-cutting, compounding, gluing and topping the insulating film can obtain a film label with a single-sided metal pattern.
  • the visual effect of such a label or packaging material is substantially the same as that obtained by bronzing or local transfer processing. Production of film labels or packaging materials with double-sided metal patterns.
  • an aluminum layer is vapor-deposited on both sides of a flexible insulating film made of polyethylene terephthalate polyester (PET), and the thickness of the plating layer is preferably 300 angstroms to 500 angstroms. PET is used as the film material. Due to its transparent nature, after the coating on both sides of the film is corroded by acid or alkali, the reaction part is transparent (either transparent or transparent on both sides), so that a predetermined special visual effect can be achieved. Those skilled in the art will appreciate that the thickness of the plating and/or plating on both sides may be the same or different, as desired.
  • a susceptor that rotatably supports the insulating film may be disposed in the vacuum evaporation apparatus. After one side of the insulating film is plated, the susceptor is rotated by 180 degrees to evaporate the other side of the insulating film; if the insulating film is In the case of a long strip, it is preferable to introduce the insulating film into another vapor deposition device after the one side of the insulating film is plated to evaporate the other side.
  • the insulating film on both sides of the aluminum-plated layer is taken out from the vacuum device, and printed on the front and back sides of the insulating film simultaneously by using a reverse printing machine known in the art to form a predetermined pattern on both sides of the insulating film or A patterned polyamide ink protective layer corresponding to the desired metal pattern or pattern.
  • a reverse printing machine known in the art to form a predetermined pattern on both sides of the insulating film or A patterned polyamide ink protective layer corresponding to the desired metal pattern or pattern.
  • the protective layer patterns or patterns on both sides may be the same or different as needed;
  • the insulating film is introduced into an etching bath containing sodium hydroxide to corrode and remove aluminum outside the coverage area of the polyimide coating.
  • a flexible insulating film made of a material such as a thermosetting resin is vapor-deposited with an aluminum layer having a plating thickness of preferably 300 ⁇ to 500 ⁇ .
  • the aluminum-plated insulating film is taken out from the vacuum apparatus, and printed on the aluminized surface of the insulating film by a printing method known in the art to form a polyamide ink protective layer having a predetermined pattern or pattern thereon.
  • the predetermined graphic or pattern corresponds to the desired graphic or pattern.
  • the insulating film is introduced into an etching bath containing sodium hydroxide to corrode the aluminum layer outside the coverage area of the polyacrylic acid sleeve protective layer to obtain a desired metal pattern or pattern on the aluminized surface of the insulating film instead of obtaining the bronzing. Or the visual effect of partial transfer.
  • the composite process can be dry composite or wet composite (so-called dry composite means that the composite film has been coated with a composite adhesive, directly compounded; and wet composite refers to the need
  • dry composite means that the composite film has been coated with a composite adhesive, directly compounded; and wet composite refers to the need
  • the composite film is coated and then compounded, or it can be laminated by means of a pre-adhesive method (film with glue).
  • the composite protective film enhances the protection of the printing ink while eliminating the residual laser portion of the metal coating that has been removed.
  • a method of a composite film instead of coating a surface of the film.
  • a layer of transparent or translucent ink such as varnish is used to protect the prepared pattern layer from scratching or wiping.
  • the composite two-layer material is compounded with a release film of silicone oil or paper with silicone oil to obtain a self-adhesive material, and the above materials are subjected to film cutting to obtain a self-adhesive label. If there is no composite liner (ie, a release film with silicone oil or paper with silicone oil), a packaging material is obtained.
  • the resulting film label or packaging material with a single-sided metal pattern has a visual effect that is substantially comparable to that obtained by bronzing or local transfer processing.
  • an aluminum layer is vapor-deposited on both sides of a flexible insulating film made of polyethylene terephthalate polyester (PET), and the thickness of the plating layer is preferably 300 angstroms to 500 angstroms. PET is used as the film material. Due to its transparent nature, after the coating on both sides of the film is corroded by acid or alkali, the reaction part is transparent (either transparent or transparent on both sides), so that a predetermined special visual effect can be achieved. Those skilled in the art will appreciate that the thickness of the plating and/or plating on both sides may be the same or different, as desired.
  • a susceptor that rotatably supports the insulating film may be disposed in the vacuum evaporation apparatus. After one side of the insulating film is plated, the susceptor is rotated by 180 degrees to evaporate the other side of the insulating film; if the insulating film is In the case of a long strip, it is preferable to introduce the insulating film into another vapor deposition device after the one side of the insulating film is plated to evaporate the other side.
  • the insulating film on both sides of which has been plated with aluminum is taken out from the vacuum apparatus, and the printing is performed simultaneously on both the front and back sides of the insulating film by using a reverse printing machine known in the art to form predetermined patterns on both sides of the insulating film. Or a patterned polyamide ink protective layer corresponding to the desired metallic pattern or pattern. It will be understood by those skilled in the art that the protective layer patterns or patterns on both sides may be the same or different (to obtain a desired visual effect) as needed;
  • the insulating film is introduced into an etching bath containing sodium hydroxide to etch away the ammonium chloride.
  • the ink protective layer covers the area
  • the outer aluminum layer and the desired metal pattern or pattern are respectively obtained on both sides of the insulating film, instead of obtaining the visual effect of bronzing or partial transfer; then, (if necessary, a non-laser effect pattern such as a character may be printed first) on the film.
  • a transparent non-metallic material zinc sulfide thinness 10A-100 A
  • this non-metallic material layer can retain the remaining part of the laser effect of the removed metal plating layer, of course, can also protect the prepared pattern layer from being Scratch or wipe the flowers.
  • the composite two-layer material is compounded with a release film of silicone oil or paper with silicone oil to obtain a self-adhesive material, and the above materials are subjected to film cutting to obtain a self-adhesive label. If there is no composite liner (ie, a release film with silicone oil or paper with silicone oil), a packaging material is obtained.
  • the visual effect of the finally obtained film label or packaging material with a double-sided metal pattern is even better than that obtained by bronzing or local transfer processing.
  • Two-sided metal graphics or patterns can be produced on some transparent film materials to produce predetermined special visual effects
  • the thickness of the plating layer can be conveniently controlled as needed, and can be accurate to several hundred angstroms;
  • the corrosion rate is relatively fast when the corrosive liquid is used for etching, and the production rate is greatly improved;
  • the protective film (or transparent or translucent ink) can eliminate the residual laser effect of the metal plating which has been removed, and at the same time strengthen the protection of the printing ink, so that the prepared pattern layer is not scratched or wiped.
  • a transparent non-metallic material such as zinc sulfide retains a portion of the remaining laser effect of the removed metal coating while enhancing the protection of the printing ink, so that the prepared pattern layer is not scratched or rubbed.

Abstract

A forming method of film label or packing material is disclosed. The forming method comprises the following steps: providing a first film; depositing a metal layer on the first film surface by the vacuum vapor deposition; printing a protective layer having resistance to chemical etching on the metal layer, and the shape of the protective layer corresponds to the shape of desired metal image or pattern; removing the portion of the metal layer which is not covered by the protective layer from the first film surface by chemical etching, and yielding the desired metal image or pattern on the first film surface; providing a second film for protecting the pattern layer formed on the first film; laminating the first film with the second film. The cost of the forming method is low and the efficiency is high. Moreover, through laminating another film or applying a transparent or translucent ink, the protection effect for the printed ink can be improved, while some reflection effect remained by the removed metal layer can be eliminated.

Description

薄膜标签或包装材料的制作方法 技术领域  Film label or packaging material manufacturing method
本发明涉及一种薄膜标签或包装材料的制作方法。  The present invention relates to a method of making a film label or packaging material.
背景技术 Background technique
薄膜标签或包装材料可广泛用于商标、 封条、 各种类型包装纸等。 在 传统的薄膜标签或包装材料印刷过程中, 需要进行金属化处理例如烫金处理 或局部转移处理来获得一定的视觉效果, 但无论是烫金处理还是局部转移处 理, 都需要很高的处理成本和较长的处理时间。  Film labels or packaging materials can be widely used in trademarks, seals, various types of wrapping paper, and the like. In the traditional film label or packaging material printing process, metallization treatment such as bronzing treatment or partial transfer treatment is required to obtain a certain visual effect, but both the hot stamping treatment and the partial transfer treatment require high processing cost and comparison. Long processing time.
发明内容 Summary of the invention
本发明的目的是提供一种成本低且效率高的薄膜标签或包装材料的制作 方法。  It is an object of the present invention to provide a method of making a low cost and efficient film label or packaging material.
本发明的第一方面提供了一种薄膜标签或包装材料的制作方法, 包括步 骤: 提供一薄膜; 在薄膜表面真空蒸镀金属镀层; 在金属镀层上印刷耐化学 腐蚀性保护层, 所述保护层的形状相应于所需金属图形或图案; 通过化学腐 蚀在薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在薄膜表面得到所 需金属图形或图案; 提供一底纸; 将带有所需金属图形或图案的薄膜与底纸 压合, 从而获得薄膜标签或包装材料。  A first aspect of the present invention provides a method for fabricating a film label or packaging material, comprising the steps of: providing a film; vacuum evaporating a metal plating layer on the surface of the film; and printing a chemical resistant protective layer on the metal plating layer, the protection The shape of the layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the coverage area of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film; a bottom paper is provided; A film that requires a metal pattern or pattern is pressed against the backing paper to obtain a film label or packaging material.
本发明的第二方面还提供了一种薄膜标签或包装材料的制作方法, 包括 步骤: 提供第一薄膜; 在第一薄膜表面真空蒸镀金属镀层; 在金属镀层上印 刷耐化学腐蚀性保护层, 所述保护层的形状相应于所需金属图形或图案; 通 过化学腐蚀在第一薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在第 一薄膜表面得到所需金属图形或图案; 提供第二薄膜, 用于保护制备在第一 薄膜上的图案层; 将第一薄膜与第二薄膜复合。  A second aspect of the present invention provides a method for fabricating a film label or packaging material, comprising the steps of: providing a first film; vacuum evaporating a metal plating layer on the surface of the first film; and printing a chemical resistant protective layer on the metal plating layer The shape of the protective layer corresponds to a desired metal pattern or pattern; removing a metal plating layer outside the cover layer of the protective layer on the surface of the first film by chemical etching to obtain a desired metal pattern or pattern on the surface of the first film; a second film for protecting a pattern layer prepared on the first film; and combining the first film with the second film.
本发明的第三方面提供了另一种薄膜标签或包装材料的制作方法, 包括 步骤: 提供一薄膜; 在薄膜表面真空蒸镀金属镀层; 在金属镀层上印刷耐化 学腐蚀性保护层, 所述保护层的形状相应于所需金属图形或图案; 通过化学 腐蚀在薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在薄膜表面得到 所需金属图形或图案; 在薄膜表面涂覆透明或半透明的油墨, 用于保护制备 在薄膜上的图案层。 A third aspect of the invention provides a method for fabricating another film label or packaging material, comprising the steps of: providing a film; vacuum evaporating a metal plating layer on the surface of the film; and printing a chemical resistant protective layer on the metal plating layer, The shape of the protective layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the cover layer of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film; the surface of the film is coated with transparent or semi-coated Transparent ink for protection preparation a patterned layer on the film.
本发明的第四方面提供了又一种薄膜标签或包装材料的制作方法, 包括 步骤: 提供一薄膜; 在薄膜表面真空蒸镀金属镀层; 在金属镀层上印刷耐化 学腐蚀性保护层, 所述保护层的形状相应于所需金属图形或图案; 通过化学 腐蚀在薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在薄膜表面得到 所需金属图形或图案; 在薄膜表面蒸镀一层透明的非金属材料。  A fourth aspect of the present invention provides a method for fabricating a film label or packaging material, comprising the steps of: providing a film; vacuum evaporating a metal plating layer on the surface of the film; and printing a chemical resistant protective layer on the metal plating layer, The shape of the protective layer corresponds to the desired metal pattern or pattern; the metal plating layer outside the coverage of the protective layer is removed on the surface of the film by chemical etching, and the desired metal pattern or pattern is obtained on the surface of the film; Non-metallic materials.
薄膜可采用耐化学腐蚀性绝缘材料如对苯二甲酸乙二醇聚酯 (PET)等; 蒸镀金属可釆用铝、 铜或银等; 保护层可釆用耐酸碱涂料或油墨如聚酰胺油 墨等; 化学腐蚀液可采用酸性或碱性腐蚀液如氢氧化钠或盐酸等。  The film may be made of chemically resistant insulating material such as ethylene terephthalate polyester (PET); the vapor deposited metal may be aluminum, copper or silver; the protective layer may be coated with an acid-resistant paint or ink such as poly An amide ink or the like; the chemical etching solution may be an acidic or alkaline etching solution such as sodium hydroxide or hydrochloric acid.
通过复合另一层薄膜或者涂覆透明或半透明油墨, 可以起到加强保护印 刷油墨的作用,同时可以消除已被去除的金属镀层仍然残余的部分镭射效果。  By compounding another film or applying a transparent or translucent ink, it is possible to enhance the protection of the printing ink while eliminating the residual laser effect of the metal plating that has been removed.
通过蒸镀透明的非金属材料例如硫化锌可以起到加强保护印刷油墨的作 用, 同时可以保留已被去除的金属镀层仍然残余的部分镭射效果。  The evaporation of a transparent non-metallic material such as zinc sulfide can enhance the protection of the printing ink while retaining a portion of the laser effect that remains of the removed metal coating.
在本发明的薄膜标签或包装材料制作方法中, 由于采用在薄膜上蒸镀金 属鍍层并对金属镀层进行选择性腐蚀来取代传统的金属化工艺例如局部烫金 或局部转移,从而获得了一种低廉且高效的薄膜标签或包装材料的制作方法。 具体实施方式  In the method for fabricating a film label or packaging material of the present invention, a metal plating layer is deposited on the film and the metal plating layer is selectively etched to replace the conventional metallization process such as partial hot stamping or partial transfer, thereby obtaining a An inexpensive and efficient method of making film labels or packaging materials. detailed description
实施例 1  Example 1
生产带有单面金属图案的薄膜标签或包装材料。 在真空装置中, 将由热 固性树脂等材料制成的柔性绝缘薄膜的一面蒸镀一铝层,镀层厚度优选为 300 埃至 500埃。 此后, 将镀过铝层的绝缘薄膜从真空装置中取出, 利用本领域 公知的印刷方法在绝缘薄膜的镀铝面进行印刷处理, 在其上形成预定图形或 图案的聚酰胺油墨保护层, 该预定图形或图案与所需图形或图案相应。接着, 将绝缘薄膜引入装有氢氧化钠的腐蚀槽, 腐蚀去除聚酰铵油墨保护层覆盖区 域以外的铝层而在绝缘薄膜的镀铝面得到所需金属图形或图案, 以替代获取 烫金或局部转移的视觉效果; 最后对绝缘薄膜进行横切、 复合、 上胶以及上 底纸等传统工序, 即可得到带有单面金属图案的薄膜标签。 这种标签或包装 材料的视觉效果基本不亚于进行烫金或局部转移处理所获得的视觉效果。 生产带有双面金属图案的薄膜标签或包装材料。 在真空装置中, 将由对 苯二甲酸乙二醇聚酯 (PET)制成的柔性绝缘薄膜的两面分别蒸镀一铝层, 镀层厚度优选为 300埃至 500埃。采用 PET作为薄膜材料,由于其透明特性, 薄膜两面的镀层经酸或碱进行腐蚀反应后, 反应部分呈现透明状 (可一面透 明或两面同时透明), 从而可以达到预定的特殊视觉效果。本领域技术人员可 以理解, 根据需要, 两面的镀层和 /或镀层厚度也可相同或不同。 蒸镀时, 可 以在真空蒸镀装置中设置可旋转支撑绝缘薄膜的基座, 当绝缘薄膜的一面镀 好镀层以后, 使基座旋转 180度来蒸镀绝缘薄膜的另一面; 如果绝缘薄膜为 长带状, 则最好在镀好绝缘薄膜的一面后, 将绝缘薄膜引入另一个蒸镀装置 来对其另一面进行蒸镀。 此后, 将两面镀过铝层的绝缘薄膜从真空装置中取 出, 利用本领域所已知的反转印刷机, 在绝缘薄膜的正反两面同时进行印刷, 分别在绝缘薄膜的两面形成预定图形或图案的聚酰胺油墨保护层, 该预定图 形或图案与所需金属图形或图案相应。本领域技术人员可以理解,根据需要, 两面的保护层图形或图案可相同或不同; 接着, 将绝缘薄膜引入装有氢氧化 钠的腐蚀槽, 腐蚀去除聚酰铵油墨保护层覆盖区域以外的铝层而在绝缘薄膜 的两面分别得到所需金属图形或图案, 以替代获取烫金或局部转移的视觉效 果; 最后对绝缘薄膜进行横切、 复合、 上胶以及上底纸等传统工序, 即可得 到带有双面金属图案的薄膜标签或包装材料。 这种标签或包装材料的视觉效 果甚至优于进行烫金或局部转移处理所获得的视觉效果。 Production of film labels or packaging materials with single-sided metal patterns. In the vacuum apparatus, one side of a flexible insulating film made of a material such as a thermosetting resin is vapor-deposited with an aluminum layer having a plating thickness of preferably 300 Å to 500 Å. Thereafter, the aluminum-plated insulating film is taken out from the vacuum apparatus, and printed on the aluminized surface of the insulating film by a printing method known in the art to form a polyamide ink protective layer having a predetermined pattern or pattern thereon. The predetermined graphic or pattern corresponds to the desired graphic or pattern. Next, the insulating film is introduced into an etching bath containing sodium hydroxide to etch away the aluminum layer outside the coverage area of the polyimide coating to obtain the desired metal pattern or pattern on the aluminized surface of the insulating film instead of obtaining hot stamping or The visual effect of local transfer; Finally, the traditional process of cross-cutting, compounding, gluing and topping the insulating film can obtain a film label with a single-sided metal pattern. The visual effect of such a label or packaging material is substantially the same as that obtained by bronzing or local transfer processing. Production of film labels or packaging materials with double-sided metal patterns. In the vacuum apparatus, an aluminum layer is vapor-deposited on both sides of a flexible insulating film made of polyethylene terephthalate polyester (PET), and the thickness of the plating layer is preferably 300 angstroms to 500 angstroms. PET is used as the film material. Due to its transparent nature, after the coating on both sides of the film is corroded by acid or alkali, the reaction part is transparent (either transparent or transparent on both sides), so that a predetermined special visual effect can be achieved. Those skilled in the art will appreciate that the thickness of the plating and/or plating on both sides may be the same or different, as desired. During vapor deposition, a susceptor that rotatably supports the insulating film may be disposed in the vacuum evaporation apparatus. After one side of the insulating film is plated, the susceptor is rotated by 180 degrees to evaporate the other side of the insulating film; if the insulating film is In the case of a long strip, it is preferable to introduce the insulating film into another vapor deposition device after the one side of the insulating film is plated to evaporate the other side. Thereafter, the insulating film on both sides of the aluminum-plated layer is taken out from the vacuum device, and printed on the front and back sides of the insulating film simultaneously by using a reverse printing machine known in the art to form a predetermined pattern on both sides of the insulating film or A patterned polyamide ink protective layer corresponding to the desired metal pattern or pattern. It will be understood by those skilled in the art that the protective layer patterns or patterns on both sides may be the same or different as needed; Next, the insulating film is introduced into an etching bath containing sodium hydroxide to corrode and remove aluminum outside the coverage area of the polyimide coating. Layers on the two sides of the insulating film to obtain the desired metal pattern or pattern, instead of obtaining the visual effect of bronzing or local transfer; finally, the traditional process of cross-cutting, compounding, gluing and uppering the insulating film can be obtained. Film label or packaging material with a double-sided metal pattern. The visual effect of such labels or packaging materials is even better than that obtained by bronzing or local transfer processing.
实施例 3  Example 3
生产带有单面金属图案的薄膜标签或包装材料。 在真空装置中, 将由热 固性树脂等材料制成的柔性绝缘薄膜的一面蒸镀一铝层,镀层厚度优选为 300 埃至 500埃。 此后, 将镀过铝层的绝缘薄膜从真空装置中取出, 利用本领域 公知的印刷方法在绝缘薄膜的镀铝面进行印刷处理, 在其上形成预定图形或 图案的聚酰胺油墨保护层, 该预定图形或图案与所需图形或图案相应。接着, 将绝缘薄膜引入装有氢氧化钠的腐蚀槽, 腐蚀去除聚酰铵袖墨保护层覆盖区 域以外的铝层而在绝缘薄膜的镀铝面得到所需金属图形或图案, 以替代获取 烫金或局部转移的视觉效果。 此后, 根据需要印刷非镭射效果的图案(例如 字符等);然后在薄膜表面复合另外一层保护薄膜,例如 OPP (聚丙稀)、 PVC (聚氯乙烯)、 PET等薄膜, 复合工艺可以是干式复合也可以是湿式复合(所 谓干式复合是指复合膜上面已经涂有复合胶, 直接复合就可以; 而湿式复合 是指需要在复合膜上进行涂胶然后再复合),或也可以用预涂胶方式(带有胶 的膜)通过设备进行压合复合。 复合的这种保护薄膜加强了保护印刷油墨的 作用, 同时可以消除已被去除的金属镀层仍然残余的部分镭射效果。 可选择 地, 在选择性腐蚀 (获取具有镭射效果的图案)和非镭射效果印刷 (例如印 刷一般视觉效果的字符等)后, 也可以不采用复合薄膜的方法, 而是在薄膜 表面涂覆一层透明或者半透明的油墨例如光油, 来保护制备的图案层不被刮 伤或者擦花。 随后将复合好的双层材料与有硅油的离型膜或带有硅油的纸张 复合, 从而获得不干胶材料, 对上述材料进行膜切从而获得不干胶标签。 如 果没有复合底纸 (即有硅油的离型膜或带有硅油的纸张) 即获得一种包装材 料。 最后获得的带有单面金属图案的薄膜标签或包装材料的视觉效果基本不 亚于进行烫金或局部转移处理所获得的视觉效果。 Production of film labels or packaging materials with single-sided metal patterns. In the vacuum apparatus, one side of a flexible insulating film made of a material such as a thermosetting resin is vapor-deposited with an aluminum layer having a plating thickness of preferably 300 Å to 500 Å. Thereafter, the aluminum-plated insulating film is taken out from the vacuum apparatus, and printed on the aluminized surface of the insulating film by a printing method known in the art to form a polyamide ink protective layer having a predetermined pattern or pattern thereon. The predetermined graphic or pattern corresponds to the desired graphic or pattern. Next, the insulating film is introduced into an etching bath containing sodium hydroxide to corrode the aluminum layer outside the coverage area of the polyacrylic acid sleeve protective layer to obtain a desired metal pattern or pattern on the aluminized surface of the insulating film instead of obtaining the bronzing. Or the visual effect of partial transfer. Thereafter, print a non-laser effect pattern (such as characters, etc.) as needed; then combine another layer of protective film on the film surface, such as OPP (polypropylene), PVC (Polyvinyl chloride), PET and other films, the composite process can be dry composite or wet composite (so-called dry composite means that the composite film has been coated with a composite adhesive, directly compounded; and wet composite refers to the need The composite film is coated and then compounded, or it can be laminated by means of a pre-adhesive method (film with glue). The composite protective film enhances the protection of the printing ink while eliminating the residual laser portion of the metal coating that has been removed. Alternatively, after selective etching (obtaining a pattern having a laser effect) and non-laser effect printing (for example, printing characters of general visual effects, etc.), it is also possible to apply a method of a composite film instead of coating a surface of the film. A layer of transparent or translucent ink such as varnish is used to protect the prepared pattern layer from scratching or wiping. Subsequently, the composite two-layer material is compounded with a release film of silicone oil or paper with silicone oil to obtain a self-adhesive material, and the above materials are subjected to film cutting to obtain a self-adhesive label. If there is no composite liner (ie, a release film with silicone oil or paper with silicone oil), a packaging material is obtained. The resulting film label or packaging material with a single-sided metal pattern has a visual effect that is substantially comparable to that obtained by bronzing or local transfer processing.
实施例 4  Example 4
生产带有双面金属图案的薄膜标签或包装材料。 在真空装置中, 将由对 苯二甲酸乙二醇聚酯 (PET)制成的柔性绝缘薄膜的两面分别蒸镀一铝层, 镀层厚度优选为 300埃至 500埃。采用 PET作为薄膜材料,由于其透明特性, 薄膜两面的镀层经酸或碱进行腐蚀反应后, 反应部分呈现透明状 (可一面透 明或两面同时透明), 从而可以达到预定的特殊视觉效果。本领域技术人员可 以理解, 根据需要, 两面的镀层和 /或镀层厚度也可相同或不同。 蒸镀时, 可 以在真空蒸镀装置中设置可旋转支撑绝缘薄膜的基座, 当绝缘薄膜的一面镀 好镀层以后, 使基座旋转 180度来蒸镀绝缘薄膜的另一面; 如果绝缘薄膜为 长带状, 则最好在镀好绝缘薄膜的一面后, 将绝缘薄膜引入另一个蒸镀装置 来对其另一面进行蒸镀。 此后, 将两面镀过铝层的绝缘薄膜从真空装置中取 出,利用本领域所已知的反转印刷机,在绝缘薄膜的正反两面同时迸行印刷, 分别在绝缘薄膜的两面形成预定图形或图案的聚酰胺油墨保护层, 该预定图 形或图案与所需金属图形或图案相应。本领域技术人员可以理解, 根据需要, 两面的保护层图形或图案可相同或不同(以获取所需视觉效果); 接着, 将绝 缘薄膜引入装有氢氧化钠的腐蚀槽, 腐蚀去除聚酰铵油墨保护层覆盖区域以 外的铝层而在绝缘薄膜的两面分别得到所需金属图形或图案, 以替代获取烫 金或局部转移的视觉效果; 然后, (根据需要也可先印刷文字等非镭射效果图 案)在该薄膜上蒸镀一层透明的非金属材料硫化锌(厚度为 10A-100 A), 这 种非金属材料层可以保留被去除的金属镀层仍然残余的部分镭射效果, 当然 也可以保护制备的图案层不被刮伤或者擦花。 随后将复合好的双层材料与有 硅油的离型膜或带有硅油的纸张复合, 从而获得不干胶材料, 对上述材料进 行膜切从而获得不干胶标签。 如果没有复合底纸 (即有硅油的离型膜或带有 硅油的纸张) 即获得一种包装材料。 最后获得的带有双面金属图案的薄膜标 签或包装材料的视觉效果甚至优于进行烫金或局部转移处理所获得的视觉效 果。 Production of film labels or packaging materials with double-sided metal patterns. In the vacuum apparatus, an aluminum layer is vapor-deposited on both sides of a flexible insulating film made of polyethylene terephthalate polyester (PET), and the thickness of the plating layer is preferably 300 angstroms to 500 angstroms. PET is used as the film material. Due to its transparent nature, after the coating on both sides of the film is corroded by acid or alkali, the reaction part is transparent (either transparent or transparent on both sides), so that a predetermined special visual effect can be achieved. Those skilled in the art will appreciate that the thickness of the plating and/or plating on both sides may be the same or different, as desired. During vapor deposition, a susceptor that rotatably supports the insulating film may be disposed in the vacuum evaporation apparatus. After one side of the insulating film is plated, the susceptor is rotated by 180 degrees to evaporate the other side of the insulating film; if the insulating film is In the case of a long strip, it is preferable to introduce the insulating film into another vapor deposition device after the one side of the insulating film is plated to evaporate the other side. Thereafter, the insulating film on both sides of which has been plated with aluminum is taken out from the vacuum apparatus, and the printing is performed simultaneously on both the front and back sides of the insulating film by using a reverse printing machine known in the art to form predetermined patterns on both sides of the insulating film. Or a patterned polyamide ink protective layer corresponding to the desired metallic pattern or pattern. It will be understood by those skilled in the art that the protective layer patterns or patterns on both sides may be the same or different (to obtain a desired visual effect) as needed; Next, the insulating film is introduced into an etching bath containing sodium hydroxide to etch away the ammonium chloride. The ink protective layer covers the area The outer aluminum layer and the desired metal pattern or pattern are respectively obtained on both sides of the insulating film, instead of obtaining the visual effect of bronzing or partial transfer; then, (if necessary, a non-laser effect pattern such as a character may be printed first) on the film. Evaporating a transparent non-metallic material zinc sulfide (thickness 10A-100 A), this non-metallic material layer can retain the remaining part of the laser effect of the removed metal plating layer, of course, can also protect the prepared pattern layer from being Scratch or wipe the flowers. Subsequently, the composite two-layer material is compounded with a release film of silicone oil or paper with silicone oil to obtain a self-adhesive material, and the above materials are subjected to film cutting to obtain a self-adhesive label. If there is no composite liner (ie, a release film with silicone oil or paper with silicone oil), a packaging material is obtained. The visual effect of the finally obtained film label or packaging material with a double-sided metal pattern is even better than that obtained by bronzing or local transfer processing.
本发明具有以下优点- The invention has the following advantages -
1、可以在一些透明薄膜材料上生产两面金属图形或图案, 以产生预定的 特殊视觉效果; 1. Two-sided metal graphics or patterns can be produced on some transparent film materials to produce predetermined special visual effects;
2、 由于采用真空蒸镀在薄膜上镀金属,可以根据需要方便地控制镀层厚 度, 可精确至数百埃;  2. Since the metal is plated on the film by vacuum evaporation, the thickness of the plating layer can be conveniently controlled as needed, and can be accurate to several hundred angstroms;
3、 由于金属层为真空蒸镀形成,在采用腐蚀液对其进行腐蚀时腐蚀速率 相当快, 大大提高了生产速率;  3. Since the metal layer is formed by vacuum evaporation, the corrosion rate is relatively fast when the corrosive liquid is used for etching, and the production rate is greatly improved;
4、保护薄膜(或透明或半透明油墨)可以消除已被去除的金属镀层仍然 残余的部分镭射效果, 同时加强了保护印刷油墨的作用, 使制备的图案层不 被刮伤或者擦花。  4. The protective film (or transparent or translucent ink) can eliminate the residual laser effect of the metal plating which has been removed, and at the same time strengthen the protection of the printing ink, so that the prepared pattern layer is not scratched or wiped.
5、透明的非金属材料例如硫化锌可以保留已被去除的金属镀层仍然残余 的部分镭射效果, 同时加强了保护印刷油墨的作用, 使制备的图案层不被刮 伤或者擦花。  5. A transparent non-metallic material such as zinc sulfide retains a portion of the remaining laser effect of the removed metal coating while enhancing the protection of the printing ink, so that the prepared pattern layer is not scratched or rubbed.
6、 生产成本低、 生产效率高。  6. Low production cost and high production efficiency.
本领域技术人员应当理解, 上述实施方式仅起解释本发明的作用, 而不 应当理解为对其作出的任何限制。  It should be understood by those skilled in the art that the above-described embodiments are merely illustrative of the scope of the invention and are not to be construed as limiting.

Claims

权利 要求 书 Claim
1.一种薄膜标签或包装材料的制作方法, 其特征在于, 包括步骤: 提供一薄膜; A method for fabricating a film label or packaging material, comprising the steps of: providing a film;
在薄膜表面真空蒸镀金属镀层;  Vacuum-depositing the metal plating on the surface of the film;
在金属镀层上印刷耐化学腐蚀性保护层, 所述保护层的形状相应于所需 金属图形或图案;  Printing a chemically resistant protective layer on the metal plating layer, the protective layer having a shape corresponding to the desired metal pattern or pattern;
通过化学腐蚀在薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在 薄膜表面得到所需金属图形或图案;  Removing a metal plating layer outside the coverage of the protective layer on the surface of the film by chemical etching to obtain a desired metal pattern or pattern on the surface of the film;
提供一底纸;  Providing a bottom paper;
将带有所需金属图形或图案的薄膜与底纸压合, 从而获得薄膜标签。 The film with the desired metal pattern or pattern is pressed against the backing paper to obtain a film label.
2.如权利要求 1所述的方法, 其特征在于: 薄膜为透明的聚合物薄膜。2. The method of claim 1 wherein: the film is a transparent polymeric film.
3.如权利要求 2所述的方法, 其特征在于: 在薄膜两面分别蒸镀金属。The method according to claim 2, wherein the metal is vapor-deposited on both sides of the film.
4.如权利要求 3 所述的方法, 其特征在于: 在薄膜两面形成的镀层和 / 或镀层厚度不同。 4. The method of claim 3, wherein: the plating and/or the plating layer formed on both sides of the film are different in thickness.
5.如权利要求 1-4之任一项所述的方法,其特征在于:金属镀层为铝层。 The method according to any one of claims 1 to 4, wherein the metal plating layer is an aluminum layer.
6.一种薄膜标签或包装材料的制作方法, 其特征在于, 包括步骤- 提供第一薄膜; 6. A method of making a film label or packaging material, comprising the steps of: providing a first film;
在第一薄膜表面真空蒸镀金属镀层;  Vacuum-depositing the metal plating on the surface of the first film;
在金属镀层上印刷耐化学腐蚀性保护层, 所述保护层的形状相应于所需 金属图形或图案;  Printing a chemically resistant protective layer on the metal plating layer, the protective layer having a shape corresponding to the desired metal pattern or pattern;
通过化学腐蚀在第一薄膜表面去除所述保护层覆盖区域以外的金属镀 层, 在第一薄膜表面得到所需金属图形或图案;  Removing a metal plating layer outside the cover layer of the protective layer on the surface of the first film by chemical etching to obtain a desired metal pattern or pattern on the surface of the first film;
提供第二薄膜, 用于保护制备在第一薄膜上的图案层;  Providing a second film for protecting a pattern layer prepared on the first film;
将第一薄膜与第二薄膜复合。  The first film is composited with the second film.
7.如权利要求 6所述的方法, 其特征在于, 在复合步骤以后, 还包括步 骤:  7. The method of claim 6 further comprising the step of: after the compounding step:
提供一底纸;  Providing a bottom paper;
将带有所需金属图形或图案的复合薄膜与底纸压合。 The composite film with the desired metal pattern or pattern is pressed against the backing paper.
8. 如权利要求 6或 7所述的方法, 其特征在于: 第一和第二薄膜均为透 明的聚合物薄膜。 8. A method according to claim 6 or claim 7 wherein: both the first and second films are transparent polymeric films.
9.如权利要求 6或 7所述的方法, 其特征在于: 在提供第二薄膜的步骤 之前、 腐蚀步骤之后还包括在第一薄膜上施加印刷图案的步骤。  9. A method according to claim 6 or claim 7 wherein: prior to the step of providing the second film, the step of etching further comprises the step of applying a printed pattern on the first film.
10. 一种薄膜标签或包装材料的制作方法, 其特征在于, 包括步骤: 提供一薄膜;  10. A method of making a film label or packaging material, comprising the steps of: providing a film;
在薄膜表面真空蒸镀金属镀层;  Vacuum-depositing the metal plating on the surface of the film;
在金属镀层上印刷耐化学腐蚀性保护层, 所述保护层的形状相应于所需 金属图形或图案;  Printing a chemically resistant protective layer on the metal plating layer, the protective layer having a shape corresponding to the desired metal pattern or pattern;
通过化学腐蚀在薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在 薄膜表面得到所需金属图形或图案;  Removing a metal plating layer outside the coverage of the protective layer on the surface of the film by chemical etching to obtain a desired metal pattern or pattern on the surface of the film;
在薄膜表面涂覆透明或半透明的油墨,用于保护制备在薄膜上的图案层。 A transparent or translucent ink is applied to the surface of the film to protect the patterned layer formed on the film.
11.如权利要求 10所述的方法, 其特征在于, 在涂覆步骤以后, 还包括 提供一底纸; 11. The method of claim 10, further comprising providing a backing paper after the coating step;
将带有所需金属图形或图案的薄膜与底纸压合。  The film with the desired metal pattern or pattern is pressed against the backing paper.
12. 如权利要求 10或 11所述的方法, 其特征在于: 在涂覆步骤之前、 腐蚀步骤之后还包括在薄膜上施加印刷图案的步骤。  12. The method according to claim 10 or 11, wherein the step of applying a printed pattern on the film before the etching step and after the etching step is further included.
13. 一种薄膜标签或包装材料的制作方法, 其特征在于, 包括步骤- 提供一薄膜;  13. A method of making a film label or packaging material, comprising the steps of: providing a film;
在薄膜表面真空蒸镀金属镀层;  Vacuum-depositing the metal plating on the surface of the film;
在金属镀层上印刷耐化学腐蚀性保护层, 所述保护层的形状相应于所需 金属图形或图案;  Printing a chemically resistant protective layer on the metal plating layer, the protective layer having a shape corresponding to the desired metal pattern or pattern;
通过化学腐蚀在薄膜表面去除所述保护层覆盖区域以外的金属镀层, 在 薄膜表面得到所需金属图形或图案;  Removing a metal plating layer outside the coverage of the protective layer on the surface of the film by chemical etching to obtain a desired metal pattern or pattern on the surface of the film;
在薄膜表面蒸镀一层透明的非金属材料。  A transparent non-metallic material is evaporated on the surface of the film.
14. 如权利要求 13所述的方法, 其特征在于, 在蒸镀非金属材料的步骤 以后, 还包括步骤:  14. The method according to claim 13, wherein after the step of vaporizing the non-metallic material, the method further comprises the steps of:
提供一底纸; 将带有所需金属图形或图案的薄膜与底纸压合。 Providing a bottom paper; The film with the desired metal pattern or pattern is pressed against the backing paper.
15.如权利要求 13或 14所述的方法, 其特征在于: 在蒸镀非金属材料 的步骤之前、 腐蚀步骤之后还包括在薄膜上施加印刷图案的步骤。  The method according to claim 13 or 14, wherein the step of applying a printed pattern on the film before the step of vaporizing the non-metallic material and after the etching step is further included.
PCT/CN2006/002494 2005-12-14 2006-09-22 Forming methods of film label or packing material WO2007068172A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN200510134302.9 2005-12-14
CN 200510134302 CN1982045A (en) 2005-12-14 2005-12-14 Production of thin-film label
CNB2006100720239A CN100519937C (en) 2006-04-04 2006-04-04 Method for producing film label or package material
CN200610072023.9 2006-04-04

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104952361A (en) * 2015-06-12 2015-09-30 广东万昌印刷包装股份有限公司 Plastic label with metal positioning effect and preparation method thereof
CN114575184A (en) * 2022-01-21 2022-06-03 浙江亚欣包装材料有限公司 Production method of tipping paper with deep-grain frosted effect

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2721788A1 (en) * 1994-06-24 1995-12-29 Bernard Tavernier Heating film
CN2277546Y (en) * 1996-11-22 1998-04-01 葛万福 Hidden anti-forging complex film
US5773112A (en) * 1996-02-29 1998-06-30 Lintec Corporation Label with a metallic layer of controlled thickness
CN2371624Y (en) * 1999-05-25 2000-03-29 深圳大学反光材料厂 Concealed holographic pressure-sensitive label
CN1333998A (en) * 1999-03-26 2002-01-30 Ga-Tek公司(商业活动中称哥德电子公司) Multi-layer laminate and method of producing same
CN1362329A (en) * 2002-01-11 2002-08-07 中包云梦塑料薄膜厂 Biaxial stretching polypropylene base film for laser coining evaporation-coating and its production process
CN1553416A (en) * 2003-10-08 2004-12-08 河南天畅图像有限公司 Engraved holographic antifakery labels checked by take-off and their production

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2721788A1 (en) * 1994-06-24 1995-12-29 Bernard Tavernier Heating film
US5773112A (en) * 1996-02-29 1998-06-30 Lintec Corporation Label with a metallic layer of controlled thickness
CN2277546Y (en) * 1996-11-22 1998-04-01 葛万福 Hidden anti-forging complex film
CN1333998A (en) * 1999-03-26 2002-01-30 Ga-Tek公司(商业活动中称哥德电子公司) Multi-layer laminate and method of producing same
CN2371624Y (en) * 1999-05-25 2000-03-29 深圳大学反光材料厂 Concealed holographic pressure-sensitive label
CN1362329A (en) * 2002-01-11 2002-08-07 中包云梦塑料薄膜厂 Biaxial stretching polypropylene base film for laser coining evaporation-coating and its production process
CN1553416A (en) * 2003-10-08 2004-12-08 河南天畅图像有限公司 Engraved holographic antifakery labels checked by take-off and their production

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104952361A (en) * 2015-06-12 2015-09-30 广东万昌印刷包装股份有限公司 Plastic label with metal positioning effect and preparation method thereof
CN114575184A (en) * 2022-01-21 2022-06-03 浙江亚欣包装材料有限公司 Production method of tipping paper with deep-grain frosted effect
CN114575184B (en) * 2022-01-21 2023-02-28 浙江亚欣包装材料有限公司 Production method of tipping paper with deep-grain frosted effect

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