CN114575184B - Production method of tipping paper with deep-grain frosted effect - Google Patents
Production method of tipping paper with deep-grain frosted effect Download PDFInfo
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- CN114575184B CN114575184B CN202210069486.9A CN202210069486A CN114575184B CN 114575184 B CN114575184 B CN 114575184B CN 202210069486 A CN202210069486 A CN 202210069486A CN 114575184 B CN114575184 B CN 114575184B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to a production method of tipping paper with deep grain frosted effect, which comprises a base film and paper, wherein the surface of the base film is provided with a corona layer, the corona layer is coated with a layer of coating resin, and the coating resin is provided with a 3D relief grating frosted laser pattern, and the production method sequentially comprises the following steps: s1 coating resin coating, S2 mould pressing, S3 aluminizing, S4 slitting, S5 composite paper compounding, S6 composite paper stripping and S7 varnish applying treatment, the invention has the advantages that: the coating resin in the S1 is prepared by mixing thermosetting resin, polyester acrylate, a photoinitiator, a defoaming agent, an active agent and a flatting agent, so that the solid content of the coating resin is greatly improved, the deep-grained 3D embossed smooth-deleted frosted surface can be perfectly imprinted and copied, the aesthetic feeling of stereoscopic vision of the appearance of the tipping paper is greatly improved, the packaging effect of the tipping paper is greatly improved, and the packaging is novel.
Description
Technical Field
The invention relates to a production method of tipping paper with deep-grained frosted effect.
Background
The tipping paper is used for wrapping the outside of a filter tip and bonding a filter stick to the paper at the tail end of a cigarette rod, in recent years, the tipping paper has great development and innovation in function and application, a cigarette factory not only limits the application of the tipping paper to simple packaging, but also pays more attention to decoration, higher requirements on the printing aesthetic property of the tipping paper are met, the existing tipping paper is directly printed by white cardboard, and therefore the prepared tipping paper cannot reflect stereoscopic vision aesthetic feeling, and the practical performance of the tipping paper is influenced.
Disclosure of Invention
The invention aims to provide a production method of tipping paper with deep-grained frosted effect, which can enable the appearance of the prepared tipping paper to have stereoscopic visual aesthetic feeling and greatly improve the packaging effect of the tipping paper.
In order to solve the technical problems, the invention is realized by the following technical scheme: the utility model provides a production method of dark line dull polish effect's china cypress paper, includes base film and paper, the paper is the china cypress body paper, the surface of base film is equipped with the corona layer, the coating has one deck coating resin on the corona layer, the coating resin includes following component: 30-60 parts by mass of thermosetting resin, 10-20 parts by mass of polyester acrylate, 2-8 parts by mass of photoinitiator, 5-10 parts by mass of defoaming agent, 8-15 parts by mass of active agent and 2-5 parts by mass of leveling agent, wherein a 3D embossed grating frosted laser pattern molded by a mold pressing process is arranged on the coating resin, an aluminum plating layer is plated on the outer surface of the 3D embossed grating frosted laser pattern in a vacuum manner, and the aluminum plating layer is adhered to paper by glue; the production method sequentially comprises the following steps:
s1: coating a coating resin formed by mixing thermosetting resin, polyester acrylate, a photoinitiator, a defoaming agent, an active agent and a leveling agent on a corona layer of a base film uniformly, and drying the coating resin to ensure that the molecules of the coating resin are leveled thoroughly;
s2: molding a 3D embossed grating frosted laser pattern on the surface of the coating resin which is completely leveled in the step S1, and immediately curing the laser pattern, wherein the molding temperature is 175-185 ℃;
s3: unreeling the base film solidified in the S2 by a vacuum aluminizing machine and transmitting the base film to an evaporation tank for vacuum aluminizing treatment, so that an aluminized layer is plated on the surface of the base film;
s4: cutting and finishing the aluminized base film of the step S3 into a finished product through a splitting machine;
s5: compounding the finished product obtained after the cutting of the S4 on paper by glue, drying the compounded paper,
s6: cooling and sizing the composite paper processed by the S5, and unreeling the composite paper through Cheng Qieji to carry out film and paper peeling treatment;
and S7, performing varnish coating treatment on the pattern surface of the paper stripped in the S6.
Preferably, the coating mass of the coating resin in the step S1 is 1.3 to 1.5g per square meter of the base film, and the coating resin in the step S1 is dried by four ovens, and the drying temperatures of the four ovens are 100 ℃, 145 ℃, 140 ℃ and 100 ℃.
Preferably, the laser pattern in the step S2 is cured by a UV light source having a main wavelength band of 380 to 400 um.
Preferably, the thickness of the aluminum plating layer in the S3 step is 380 to 420 angstroms.
Preferably, the mass of the glue on the paper per square meter in S5 is 5-5.5 g, and the composite paper after being compounded is dried by a section of drying oven, wherein the temperature of the drying oven is 60-70 ℃, and the speed of the drying oven is 80m/min.
Preferably, the base film has a thickness equal to 15 to 22 μm, and the corona layer has a dyne value of 48 to 56 dynes.
Preferably, the photoinitiator comprises the following components: 2-5 parts of 2-benzyl-2-dimethylamino-1- (4-morpholinylphenyl) -1-butanone, 3-10 parts of phenyl bis (2,4,6-trimethylbenzoyl) phosphine oxide and 1-4 parts of (2,4,6-trimethylbenzoyl) diphenyl phosphorus oxide (TPO).
Preferably, the defoaming agent comprises the following components: 8 to 25 portions of silicone oil, 0.5 to 1.8 portions of silicon dioxide, 6 to 12 portions of emulsifier, 2 to 5.5 portions of wetting dispersant, 0.3 to 0.2 portion of thickener, 0.05 to 0.2 portion of preservative and 65 to 85 portions of water.
Preferably, the active agent comprises the following components: 10 to 20 parts of hydroxyethyl methacrylate, 30 to 60 parts of 1,6-hexanediol diacrylate (HDDA) and 10 to 20 parts of dipropylene glycol diacrylate.
Preferably, the leveling agent comprises the following components: 1-6 parts of butyl acrylate, 3-10 parts of polyether modified polysiloxane, 10-20 parts of tetrasodium pyrophosphate, 10-20 parts of bamboo powder, 3-11 parts of low-temperature cured polyester resin, 2-6 parts of epoxy resin, 8-20 parts of calcium carbonate, 13-25 parts of organic silicon resin and 3-9 parts of fatty alcohol-polyoxyethylene ether.
In conclusion, the invention has the advantages that: the tipping paper is prepared by a production method of S1 coating resin coating, S2 mould pressing, S3 aluminium plating, S4 cutting, S5 composite paper compounding, S6 composite paper stripping and S7 varnish coating treatment, because the coating resin in S1 is prepared by mixing thermosetting resin, polyester acrylate, a photoinitiator, a defoaming agent, an active agent and a flatting agent, the solid content of the coating resin is greatly improved, a deep-grained 3D relief light-relief polished and polished surface can be perfectly imprinted and copied, the appearance aesthetic feeling of the tipping paper is greatly improved, the packaging effect of the tipping paper is greatly improved, the packaging is novel, the prepared coating resin can be coated on a glass panel, a plastic panel and a metal panel, the application range is greatly improved, various novel tipping papers can be manufactured, the grade of the coating resin is improved, the coating resin is deeply popular with the mass, the components are completely composed of resin molecules, no solvent component is added, the environment-friendly effect is good, the VOC emission is low, the national environment-friendly requirement of cigarette packets can be met, and the coating resin can be fully combined with the base film of cigarette packets.
Detailed Description
The utility model provides a production method of dark line dull polish effect's china cypress paper, includes base film and paper, the paper is the china cypress body paper, the surface of base film is equipped with the corona layer, the coating has one deck coating resin on the corona layer, the coating resin includes following component: 30-60 parts by mass of thermosetting resin, 10-20 parts by mass of polyester acrylate, 2-8 parts by mass of photoinitiator, 5-10 parts by mass of defoaming agent, 8-15 parts by mass of active agent and 2-5 parts by mass of leveling agent, wherein a 3D embossed grating frosted laser pattern molded by a mold pressing process is arranged on the coating resin, an aluminum plating layer is plated on the outer surface of the 3D embossed grating frosted laser pattern in a vacuum manner, and the aluminum plating layer is adhered to paper by glue; the production method sequentially comprises the following steps:
s1: uniformly coating resin formed by mixing thermosetting resin, polyester acrylate, a photoinitiator, a defoaming agent, an active agent and a flatting agent on a corona layer of a base film, and drying the coating resin to thoroughly level molecules of the coating resin;
s2: molding a 3D embossed grating frosted laser pattern on the surface of the coating resin after the S1 is completely leveled, and immediately curing the laser pattern, wherein the molding temperature is 175-185 ℃;
s3: unreeling the cured base film obtained in the step S2 through a vacuum aluminizing machine and transmitting the base film to an evaporation tank for vacuum aluminizing treatment, so that an aluminized layer is plated on the surface of the base film;
s4: cutting and finishing the aluminized base film of S3 into a finished product by a splitting machine;
s5: compounding the finished product obtained after the cutting of the S4 on paper by glue, drying the compounded paper,
s6: cooling and shaping the composite paper processed by the S5, and unreeling the composite paper through Cheng Qieji to perform film and paper stripping treatment;
and S7, performing varnish painting treatment on the pattern surface of the paper stripped in the S6.
The tipping paper is prepared by a production method of S1 coating resin coating, S2 mould pressing, S3 aluminium plating, S4 cutting, S5 composite paper compounding, S6 composite paper stripping and S7 varnish coating treatment, because the coating resin in S1 is prepared by mixing thermosetting resin, polyester acrylate, a photoinitiator, a defoaming agent, an active agent and a flatting agent, the solid content of the coating resin is greatly improved, a deep-grained 3D relief light-relief polished and polished surface can be perfectly imprinted and copied, the appearance aesthetic feeling of the tipping paper is greatly improved, the packaging effect of the tipping paper is greatly improved, the packaging is novel, the prepared coating resin can be coated on a glass panel, a plastic panel and a metal panel, the application range is greatly improved, various novel tipping papers can be manufactured, the grade of the coating resin is improved, the coating resin is deeply popular with the mass, the components are completely composed of resin molecules, no solvent component is added, the environment-friendly effect is good, the VOC emission is low, the national environment-friendly requirement of cigarette packets can be met, and the coating resin can be fully combined with the base film of cigarette packets.
The coating quality of the coating resin in each square meter of the base film in the step S1 is 1.3-1.5g, the coating resin in the step S1 is dried by four sections of drying ovens, the drying temperatures of the four sections of drying ovens are respectively 100 ℃, 145 ℃, 140 ℃ and 100 ℃, the coating can be sufficiently leveled, the mould pressing of the 3D relief grating frosted laser pattern is facilitated, the laser pattern in the step S2 is cured by a UV light source with the main wave band of 380-400 mu m, the rapid curing can be realized, the whole body has the performances of yellowing resistance and friction resistance, the thickness of the aluminum plating layer in the step S3 is 380-420 angstroms, the uniformity of an aluminum-plated layer can be effectively improved, the overall brightness is more uniform, the mass of glue on each square meter of paper in S5 is 5-5.5 g, the composite paper is dried by a drying oven, the temperature of the drying oven is 60-70 ℃, the speed of the drying oven is 80m/min, the composite quality of the composite paper can be improved, the waste of the glue is avoided, the drying quality of the composite paper can be improved by the drying oven, the thickness of the base film is equal to 15-22 mu m, the dyne value of the corona layer is 48-56 dyne, and the base film has excellent heat resistance, cold resistance, corrosion resistance and water resistance.
The photoinitiator comprises the following components: 2-5 parts by weight of 2-benzyl-2-dimethylamino-1- (4-morpholinyl phenyl) -1-butanone, 3-10 parts by weight of phenyl bis (2,4,6-trimethylbenzoyl) phosphine oxide, 1-4 parts by weight of (2,4,6-trimethylbenzoyl) diphenyl phosphorus oxide (TPO), and a photoinitiator prepared by mixing 2-benzyl-2-dimethylamino-1- (4-morpholinyl phenyl) -1-butanone, phenyl bis (2,4,6-trimethylbenzoyl) phosphine oxide and (2,4,6-trimethylbenzoyl) diphenyl phosphorus oxide (TPO) can improve the drying speed of the coating, has good drying uniformity, avoids coating caking and improves the production efficiency, and the defoaming agent comprises the following components: 8-25 parts of silicone oil, 0.5-1.8 parts of silicon dioxide, 6-12 parts of emulsifier, 2-5.5 parts of wetting dispersant, 0.3-0.2 part of thickener, 0.05-0.2 part of preservative and 65-85 parts of water by weight, and the defoaming agent prepared by mixing the components greatly reduces the preparation cost, has good product stability and good defoaming effect, and comprises the following components: 10-20 parts of hydroxyethyl methacrylate, 30-60 parts of 1,6-hexanediol diacrylate (HDDA) and 10-20 parts of dipropylene glycol diacrylate by weight, and the activator prepared by mixing the components can improve the stability of the product and is convenient for the storage of the whole coating, so that the activator does not need to be prepared on site during the production of the coating, and the production efficiency can be greatly improved, and the leveling agent comprises the following components: 1-6 parts of butyl acrylate, 3-10 parts of polyether modified polysiloxane, 10-20 parts of tetrasodium pyrophosphate, 10-20 parts of bamboo powder, 3-11 parts of low-temperature cured polyester resin, 2-6 parts of epoxy resin, 8-20 parts of calcium carbonate, 13-25 parts of organic silicon resin and 3-9 parts of fatty alcohol-polyoxyethylene ether.
Other embodiments of the present invention than the preferred embodiments described above will be apparent to those skilled in the art from the present invention, and various changes and modifications can be made therein without departing from the spirit of the present invention as defined in the appended claims.
Claims (8)
1. A production method of tipping paper with deep-grained frosted effect is characterized by comprising the following steps: including base film and paper, the paper is the china cypress body paper, the surface of base film is equipped with the corona layer, the coating has one deck coating resin on the corona layer, the coating resin includes following component: 30-60 parts by mass of thermosetting resin, 10-20 parts by mass of polyester acrylate, 2-8 parts by mass of photoinitiator, 5-10 parts by mass of defoaming agent, 8-15 parts by mass of active agent and 2-5 parts by mass of leveling agent, wherein a 3D embossed grating frosted laser pattern molded by a mold pressing process is arranged on the coating resin, an aluminum plating layer is plated on the outer surface of the 3D embossed grating frosted laser pattern in a vacuum manner, and the aluminum plating layer is adhered to paper by glue; the production method sequentially comprises the following steps:
s1: coating a coating resin formed by mixing thermosetting resin, polyester acrylate, a photoinitiator, a defoaming agent, an active agent and a leveling agent on a corona layer of a base film uniformly, and drying the coating resin to ensure that the molecules of the coating resin are leveled thoroughly;
s2: molding a 3D embossed grating frosted laser pattern on the surface of the coating resin after the S1 is completely leveled, and immediately curing the laser pattern, wherein the molding temperature is 175-185 ℃;
s3: unreeling the cured substrate in the S2 by a vacuum aluminizing machine and transmitting the substrate to an evaporation tank for vacuum aluminizing treatment, so that an aluminized layer is plated on the surface of the substrate;
s4: cutting and finishing the aluminized base film of the step S3 into a finished product through a splitting machine;
s5: compounding the finished product obtained by the cutting in the step S4 on paper by glue, drying the compounded paper,
s6: cooling and shaping the composite paper processed by the S5, and unreeling the composite paper through Cheng Qieji to perform film and paper stripping treatment;
s7, performing varnish painting treatment on the pattern surface of the paper stripped in the S6;
the thickness of the base film is equal to 15-22 mu m, and the dyne value of the corona layer is 48-56 dynes;
the photoinitiator comprises the following components: 2 to 5 weight portions of 2-benzyl-2-dimethylamino-1- (4-morpholinylphenyl) -1-butanone, 3 to 10 weight portions of phenyl bis (2,4,6-trimethylbenzoyl) phosphine oxide, and 1 to 4 weight portions of (2,4,6-trimethylbenzoyl) diphenyl phosphine oxide (TPO).
2. The method for producing the tipping paper with the deep grain frosted effect as claimed in claim 1, wherein the method comprises the following steps: the coating quality of the coating resin in each square meter of the base film in the step S1 is 1.3-1.5 g, the coating resin in the step S1 is dried by four sections of drying ovens, and the drying temperatures of the four sections of drying ovens are 100 ℃, 145 ℃, 140 ℃ and 100 ℃.
3. The method for producing the tipping paper with the deep-grained frosted effect as claimed in claim 1, wherein the method comprises the following steps: and (3) curing the laser pattern in the step (S2) by using a UV light source with a main wave band of 380-400 um.
4. The method for producing the tipping paper with the deep grain frosted effect as claimed in claim 1, wherein the method comprises the following steps: the thickness of the aluminum plating layer in the step S3 is 380 to 420 angstroms.
5. The method for producing the tipping paper with the deep grain frosted effect as claimed in claim 1, wherein the method comprises the following steps: and in the S5, the mass of the glue on the paper per square meter is 5-5.5 g, and the composite paper after being compounded is dried by a section of drying oven, wherein the temperature of the drying oven is 60-70 ℃, and the speed of the drying oven is 80m/min.
6. The method for producing the tipping paper with the deep grain frosted effect as claimed in claim 1, wherein the method comprises the following steps: the defoaming agent comprises the following components: 8 to 25 portions of silicone oil, 0.5 to 1.8 portions of silicon dioxide, 6 to 12 portions of emulsifier, 2 to 5.5 portions of wetting dispersant, 0.3 to 0.2 portion of thickener, 0.05 to 0.2 portion of preservative and 65 to 85 portions of water.
7. The method for producing the tipping paper with the deep grain frosted effect as claimed in claim 1, wherein the method comprises the following steps: the active agent comprises the following components: 10 to 20 parts of hydroxyethyl methacrylate, 30 to 60 parts of 1,6-hexanediol diacrylate (HDDA) and 10 to 20 parts of dipropylene glycol diacrylate.
8. The method for producing the tipping paper with the deep-grained frosted effect as claimed in claim 1, wherein the method comprises the following steps: the leveling agent comprises the following components: 1-6 parts of butyl acrylate, 3-10 parts of polyether modified polysiloxane, 10-20 parts of tetrasodium pyrophosphate, 10-20 parts of bamboo powder, 3-11 parts of low-temperature cured polyester resin, 2-6 parts of epoxy resin, 8-20 parts of calcium carbonate, 13-25 parts of organic silicon resin and 3-9 parts of fatty alcohol-polyoxyethylene ether.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210069486.9A CN114575184B (en) | 2022-01-21 | 2022-01-21 | Production method of tipping paper with deep-grain frosted effect |
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| CN202210069486.9A CN114575184B (en) | 2022-01-21 | 2022-01-21 | Production method of tipping paper with deep-grain frosted effect |
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| CN114575184B true CN114575184B (en) | 2023-02-28 |
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| CN116213229B (en) * | 2023-02-15 | 2024-03-19 | 苏大维格(盐城)光电科技有限公司 | Preparation method of deep-grain laser film |
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| CN114575184A (en) | 2022-06-03 |
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