WO2007064237A1 - Method for forming nano-dimensional clusters and setting ordered structures therefrom - Google Patents
Method for forming nano-dimensional clusters and setting ordered structures therefrom Download PDFInfo
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- WO2007064237A1 WO2007064237A1 PCT/RU2005/000514 RU2005000514W WO2007064237A1 WO 2007064237 A1 WO2007064237 A1 WO 2007064237A1 RU 2005000514 W RU2005000514 W RU 2005000514W WO 2007064237 A1 WO2007064237 A1 WO 2007064237A1
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- Prior art keywords
- clusters
- substrate
- solution
- formation
- nanopores
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- 238000000034 method Methods 0.000 title claims abstract description 56
- 239000000463 material Substances 0.000 claims abstract description 65
- 239000000758 substrate Substances 0.000 claims abstract description 55
- 239000011521 glass Substances 0.000 claims abstract description 13
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- 239000011368 organic material Substances 0.000 claims abstract description 6
- 239000002096 quantum dot Substances 0.000 claims abstract description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 37
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 claims description 6
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- 150000002739 metals Chemical class 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011022 opal Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/14—Decomposition by irradiation, e.g. photolysis, particle radiation or by mixed irradiation sources
- C23C18/143—Radiation by light, e.g. photolysis or pyrolysis
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/14—Decomposition by irradiation, e.g. photolysis, particle radiation or by mixed irradiation sources
- C23C18/145—Radiation by charged particles, e.g. electron beams or ion irradiation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0657—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
- H01L29/0665—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body the shape of the body defining a nanostructure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- H01L21/02667—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
- H01L21/02675—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth using laser beams
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Definitions
- the present invention relates to electronics, and more specifically to a technology for the formation of nanoscale clusters and the creation of nanoelectronic structures from them, used for the transmission, conversion, storage, generation of information signals.
- a known method of forming nanoscale clusters and creating nanoelectronic structures from them is that the corresponding substances are introduced into nanoscale cavities existing in the structure of some natural or artificial materials (see, for example, abstracts of the XI international conference of semiconductor materials March 22-25, 1999 g., Ohfogd - "And crustallip (amoghous) silisop 3-D bubble lattis ip and suptetis oral matih” VN Bogomolov and others).
- the voids of the synthetic opal are filled under pressure with a melt or a solution of tellurium to obtain a lattice of tellurium nanoclusters in an opal matrix.
- the clusters obtained in this way are arranged randomly, as well as nanoscale cavities in the body of the opal, which makes it impossible to create discrete nanoelements that are homogeneous in their electrical and optical properties and organize them into an ordered structure.
- This method allows the formation of clusters of uniform size and arrange them with the same pitch in the nodes of the two-dimensional lattice.
- the basis of the invention is the task of creating such a method for the formation of nanoscale clusters and the formation of ordered structures from them, which would allow the formation of clusters both on the surface of the substrate and in its body at a given depth, and create spatial structures from clusters.
- the problem is solved in that in the method of forming nanoscale clusters and creating ordered structures of them, which consists in introducing the materials from which the clusters form into the substrate from some natural or artificial materials with specified physical parameters, and creating composites with controlled properties, in accordance with the invention, the materials for the formation of clusters are introduced into the substrate material in the composition of the solution, act on the solution at predetermined points of the substrate by laser pulses They form a low-temperature plasma in the zone of the laser spot and create a gaseous medium in the region where the plasma exists to restore the ions of the cluster material in it to a pure material and, as the plasma cools, form clusters in the form of single-crystal quantum dots and wires spliced with the substrate material.
- SUBSTITUTE SHEET (RULE 26) special technologies for introducing into the substrate the material from which the clusters are formed.
- metals, metalloids and semiconductors are used as materials for the formation of clusters.
- the substrate is made of a material that is transparent to the laser radiation of the used wavelength and chemically inert to the solution at the temperature of its existence, and the solution is made with the possibility of good wetting of the substrate material, absorption of radiation of a given wavelength and the possibility of the formation of atomic hydrogen when exposed to low temperature plasma.
- the solution is introduced into many nanopores of natural or artificial origin in the substrate material, the laser beam is focused on a given section of its surface and cause the formation of clusters in the nanopore holes located within the laser spot.
- the simultaneous formation of nanoscale clusters occurs in all nanopores that are in the zone of the laser spot.
- the laser beam is focused on different points of the same layer in the body of the substrate and cause the formation of clusters in the channels of nanopores located in this layer.
- SUBSTITUTE SHEET (RULE 26) It is advisable that they form clusters sequentially in several layers of the substrate, starting from the bottom, and create a spatial structure of clusters in the substrate, while between the formation of clusters in adjacent layers the nanopores of the substrate are filled with a solution.
- nanopores are filled with a solution containing another material.
- the substrate with through nanopores is placed on the sheet material, the nanopores are filled with a solution, the laser pulses act on the solution, and clusters are formed on the surface of the sheet material opposite the nanopore outlet openings.
- FIG. 1 illustrates the proposed method in the formation of a two-dimensional lattice of clusters in nanopores of artificial origin
- FIG. 2 illustrates the proposed method in the formation of a three-dimensional lattice of clusters in nanopores of artificial origin
- FIG. 3 illustrates the proposed method in the formation of a three-dimensional lattice of intergrown clusters in nanopores of artificial origin
- FIG. 4 and FIG. 5 illustrate the proposed method when forming on the surface of the substrate ruffled with it wires of a given topology
- FIG. 6 illustrates the proposed method when a two-dimensional lattice of nanoclusters is formed on the surface of a sheet material
- FIG. 7 illustrates the proposed method for the formation of nanoclusters inside a layer of organic material deposited on glass
- FIG. 8 illustrates copper single crystals obtained by the proposed method of high-speed crystallization on a liquid substrate.
- a two-dimensional lattice of nanopores 3 of the same cross section and predetermined depth perpendicular to the surface 4 of the substrate is made by any known method, in particular by the nanolithography method.
- SUBSTITUTE SHEET (RULE 26) A solution containing material for forming clusters 5 is introduced into nanopores 3, for example, in the form of a salt of this material. Remove the remains of this solution from the surface 4 of the substrate 1 and cover this surface with a material transparent to laser radiation, for example, glass 6.
- a laser pulse 2 with a power sufficient to cause a low-temperature plasma to create a gaseous medium in the region of its existence during the action of the pulse during the pulse action is directed through a glass 6 to a solution located in nanopores 3 and a laser pulse 2 with a power sufficient to cause the solution to fill the nanopores 3 within the laser spot.
- the cluster material is restored to pure material as a result of its crystallization on a liquid substrate in an atmosphere of atomic hydrogen. This is because the composition of the solution is selected with the calculation of the formation of atomic hydrogen when exposed to low-temperature plasma.
- the cluster crystallizes in a protective atmosphere of atomic hydrogen, which allows it to achieve high-structural perfection with a low concentration of impurities and the absence of processes of its oxidation.
- FIG. 8 shows copper single crystals obtained by the proposed method of high-speed crystallization on a liquid substrate in a protective atmosphere of atomic hydrogen.
- the proposed method allows you to create ruffled clusters of different materials in the body of the substrate (Fig. 3). For this, after the formation of clusters in the lower layer of the substrate, the nanopores are filled with a solution containing other material for the formation of clusters.
- the proposed method allows to obtain wire 7 of any given topology on the surface of the substrate (Fig. 4 and 5). In this case, the solution is introduced into the nanoscale grooves and the process described above is repeated. In this way, it is also possible to obtain spliced wires from two materials, as described above in the preparation of spliced clusters from different materials.
- the method of formation of nanoscale clusters and the creation of ordered structures from them make it possible to create two- and three-dimensional lattices from single-crystal quantum dots and wires spliced with the substrate material.
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- General Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Computer Hardware Design (AREA)
- Mathematical Physics (AREA)
- Theoretical Computer Science (AREA)
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Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05825078.8A EP1975121A4 (en) | 2005-11-29 | 2005-11-29 | METHOD FOR THE PRODUCTION OF CLUSTERS WITH NANOA DIMENSIONS AND THE CREATION OF REGULATED STRUCTURES THEREOF |
PCT/RU2005/000514 WO2007064237A1 (en) | 2005-11-29 | 2005-11-29 | Method for forming nano-dimensional clusters and setting ordered structures therefrom |
CN2005800524913A CN101356115B (zh) | 2005-11-29 | 2005-11-29 | 形成纳米尺寸簇群并由此建立有序结构的方法 |
JP2008543227A JP2009521384A (ja) | 2005-11-29 | 2005-11-29 | ナノ寸法クラスターを形成してそこから秩序構造を構築する方法 |
US12/095,309 US8206505B2 (en) | 2005-11-29 | 2005-11-29 | Method for forming nano-dimensional clusters and setting ordered structures therefrom |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/RU2005/000514 WO2007064237A1 (en) | 2005-11-29 | 2005-11-29 | Method for forming nano-dimensional clusters and setting ordered structures therefrom |
Publications (1)
Publication Number | Publication Date |
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WO2007064237A1 true WO2007064237A1 (en) | 2007-06-07 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/RU2005/000514 WO2007064237A1 (en) | 2005-11-29 | 2005-11-29 | Method for forming nano-dimensional clusters and setting ordered structures therefrom |
Country Status (5)
Country | Link |
---|---|
US (1) | US8206505B2 (ru) |
EP (1) | EP1975121A4 (ru) |
JP (1) | JP2009521384A (ru) |
CN (1) | CN101356115B (ru) |
WO (1) | WO2007064237A1 (ru) |
Families Citing this family (1)
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RU2646441C1 (ru) * | 2016-12-21 | 2018-03-05 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Сибирский государственный университет геосистем и технологий" | Способ упорядочения расположения наночастиц на поверхности подложки |
Citations (4)
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US6068800A (en) * | 1995-09-07 | 2000-05-30 | The Penn State Research Foundation | Production of nano particles and tubes by laser liquid interaction |
WO2001038940A2 (en) | 1999-11-24 | 2001-05-31 | Yeda Research And Development Co. Ltd. | Method for surface patterning using a focused laser |
DE10006905A1 (de) * | 2000-02-16 | 2001-09-06 | Boneberg Johannes | Optisches Herstellungsverfahren für nanostrukturierte Oberflächen |
RU2214359C1 (ru) | 2002-09-05 | 2003-10-20 | Санкт-Петербургский государственный институт точной механики и оптики (технический университет) | Способ формирования решетки нанокластеров кремния на структурированной подложке |
Family Cites Families (11)
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JPH0891818A (ja) * | 1994-09-16 | 1996-04-09 | Sumitomo Osaka Cement Co Ltd | 炭素クラスター含有硬質膜の製造方法 |
JP3142784B2 (ja) * | 1996-11-19 | 2001-03-07 | 株式会社三菱総合研究所 | 半導体微粒子の製造 |
JP3241629B2 (ja) * | 1997-03-31 | 2001-12-25 | 株式会社三菱総合研究所 | 半導体微粒子の製造 |
US6277740B1 (en) * | 1998-08-14 | 2001-08-21 | Avery N. Goldstein | Integrated circuit trenched features and method of producing same |
TW447013B (en) * | 2000-05-18 | 2001-07-21 | Nat Science Council | Manufacturing method for self-polymerized silicon quantum dots |
US6419998B1 (en) * | 2000-06-19 | 2002-07-16 | Mcgrath Thomas | Method for deposition of metal catalysts on inert supports |
EP1223615A1 (en) * | 2001-01-10 | 2002-07-17 | Eidgenössische Technische Hochschule Zürich | A method for producing a structure using nanoparticles |
JP2003139951A (ja) * | 2001-10-31 | 2003-05-14 | Fuji Photo Film Co Ltd | 光学異方性薄膜およびその製造方法 |
EP1513621A4 (en) * | 2002-05-21 | 2005-07-06 | Eikos Inc | METHOD FOR CONFIGURING COATING OF CARBON NANOTUBES AND WIRING OF CARBON NANOTUBES |
CN1301212C (zh) * | 2002-09-17 | 2007-02-21 | 清华大学 | 一维纳米材料方向及形状调整方法 |
RU2267408C2 (ru) * | 2004-02-02 | 2006-01-10 | Сергей Николаевич Максимовский | Способ получения металлизированного изображения на листовом материале и устройство для его осуществления |
-
2005
- 2005-11-29 US US12/095,309 patent/US8206505B2/en not_active Expired - Fee Related
- 2005-11-29 WO PCT/RU2005/000514 patent/WO2007064237A1/ru active Application Filing
- 2005-11-29 JP JP2008543227A patent/JP2009521384A/ja active Pending
- 2005-11-29 CN CN2005800524913A patent/CN101356115B/zh not_active Expired - Fee Related
- 2005-11-29 EP EP05825078.8A patent/EP1975121A4/en not_active Withdrawn
Patent Citations (4)
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US6068800A (en) * | 1995-09-07 | 2000-05-30 | The Penn State Research Foundation | Production of nano particles and tubes by laser liquid interaction |
WO2001038940A2 (en) | 1999-11-24 | 2001-05-31 | Yeda Research And Development Co. Ltd. | Method for surface patterning using a focused laser |
DE10006905A1 (de) * | 2000-02-16 | 2001-09-06 | Boneberg Johannes | Optisches Herstellungsverfahren für nanostrukturierte Oberflächen |
RU2214359C1 (ru) | 2002-09-05 | 2003-10-20 | Санкт-Петербургский государственный институт точной механики и оптики (технический университет) | Способ формирования решетки нанокластеров кремния на структурированной подложке |
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Title |
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See also references of EP1975121A4 |
V.N. BOGOMOLOV: "A crystalline (amorphous) silicon 3-D bubble lattice in a synthetic opal matrix", XI INTERNATIONAL CONFERENCE ON SEMICONDUCTING MATERIALS, 22 March 1999 (1999-03-22) |
Also Published As
Publication number | Publication date |
---|---|
EP1975121A1 (en) | 2008-10-01 |
CN101356115A (zh) | 2009-01-28 |
EP1975121A4 (en) | 2014-01-15 |
CN101356115B (zh) | 2011-08-10 |
US8206505B2 (en) | 2012-06-26 |
US20090008833A1 (en) | 2009-01-08 |
JP2009521384A (ja) | 2009-06-04 |
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