WO2007060955A1 - Metal material for electrical and electronic component and method for manufacturing same, and electrical and electronic component using such metal material for electrical and electronic component - Google Patents

Metal material for electrical and electronic component and method for manufacturing same, and electrical and electronic component using such metal material for electrical and electronic component Download PDF

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Publication number
WO2007060955A1
WO2007060955A1 PCT/JP2006/323236 JP2006323236W WO2007060955A1 WO 2007060955 A1 WO2007060955 A1 WO 2007060955A1 JP 2006323236 W JP2006323236 W JP 2006323236W WO 2007060955 A1 WO2007060955 A1 WO 2007060955A1
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Prior art keywords
electrical
metal material
insulation
metal
coating layer
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PCT/JP2006/323236
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French (fr)
Japanese (ja)
Inventor
Toshio Tani
Akira Morii
Akihiro Suzukine
Chikahito Sugahara
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The Furukawa Electric Co., Ltd.
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Publication of WO2007060955A1 publication Critical patent/WO2007060955A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/002Inhomogeneous material in general
    • H01B3/004Inhomogeneous material in general with conductive additives or conductive layers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208Oxides, e.g. ceramics
    • C23C18/1212Zeolites, glasses
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208Oxides, e.g. ceramics
    • C23C18/1216Metal oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1225Deposition of multilayers of inorganic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/002Inhomogeneous material in general
    • H01B3/006Other inhomogeneous material

Definitions

  • an electrical / electronic component is inserted with a sheet-like insulating film at a required location in the electrical / electronic component in order to ensure sufficient insulation with the built-in component.
  • electric and electronic parts using a metal material having an insulating film on a metal base material which improved the workability of this method and reduced the manufacturing cost, were proposed. Disclosure of the invention
  • FIGS. 1 (A) and 1 (B) show a metal material for electrical and electronic parts showing a first embodiment of the present invention
  • FIG. 1 (A) is a plan view
  • FIG. B) is a cross-sectional view taken along the line AA in FIG.
  • Fig. 2 is a cross-sectional view of a metal material for electrical and electronic parts showing a second embodiment of the present invention. is there.
  • the metal material shown in the cross-sectional view of FIG. 2 includes two insulating coating layers 2 (the first insulating coating layer 2a, A second insulating coating layer 2b) is provided in a stripe shape in the longitudinal direction. (In addition to the illustration, the insulating coating layer 2 may be provided on one side (for example, the back side) of the metal base 1)
  • the multi-layer insulating coating layer is made safe by using a conventionally used apparatus or the like. Can be provided with good productivity.
  • the fluid coating must be applied with high accuracy.
  • the position in the width direction of the metal substrate needs to be set with high accuracy. For that purpose, guide both sides of the metal base
  • the cross-sectional shape of the insulating coating layer is arbitrary such as a rectangle, a trapezoid, and an inverted trapezoid, and many of them are narrower than the width of the metal substrate.
  • the cross-sectional shape is slanted at both ends, or the upper ends of both ends are partially protruding in a square shape.
  • the shape of the discharge port is preferably approximated to the cross-sectional shape of the insulating coating layer.

Abstract

A metal material for electrical and electronic components is provided. The metal material has two or more multilayer insulating coating layers (2) at least on an area where insulation is required on a metal base material (1), and has sufficient withstand voltage. A method for manufacturing such metal material is also provided. In the method, a coating step of coating with a fluid-state coating material at least the area where insulation is required on the metal base material (1) and drying the coating material is performed a plurality of times.

Description

明 細 書  Specification
電気電子部品用金属材料、その製造方法、および前記電気電子部品用 金属材料を用いた電気電子部品  Metal material for electric and electronic parts, method for producing the same, and electric and electronic parts using the metal material for electric and electronic parts
技術分野  Technical field
[0001] 本発明は、電気電子部品用の金属材料、その製造方法、および前記金属材料を 用 、た電気電子部品に関する。  [0001] The present invention relates to a metal material for electric and electronic parts, a method for producing the same, and an electric and electronic part using the metal material.
背景技術  Background art
[0002] 電気電子機器のプリント基板などに実装されるセラミック発振子、水晶発振器、電圧 制御発振器 (VCO)、 SAWフィルタ、ダイプレクサ、力プラ、バラン、 LPF、 BPF、誘 電体デュプレクサなどの高周波部品、液晶ドライバ (LCD)、キーボード、マザ一ボー ドなどのプリント基板側の端子接続コネクタ、 FPCケーブル側の接続コネクタ、基板 対基板コネクタ、これらを複合した各種モジュールは、電磁波、通信ノイズ、静電気な どを遮断するために金属製のケース、カバー、筐体、キャップなどの電気電子部品で 覆って用いられている。そして、前記電気電子機器は、携帯化が進む中で、例えば、 メモリカードは、その体積が従来の 10分の 1以下になり、それに伴って前記電気電子 部品は小型薄型低背化され、その高さはモジュール部品で 5mm以下、個別部品で は 2mmを割り 1mm前後に突入しつつある。  [0002] High-frequency components such as ceramic resonators, crystal oscillators, voltage controlled oscillators (VCOs), SAW filters, diplexers, power plastics, baluns, LPFs, BPFs, dielectric duplexers, etc. mounted on printed circuit boards of electrical and electronic equipment , Liquid crystal drivers (LCDs), keyboards, motherboard connectors such as printed circuit board side connectors, FPC cable side connection connectors, board-to-board connectors, and various modules that combine these are electromagnetic waves, communication noise, and static electricity. It is used by covering it with electrical and electronic parts such as metal cases, covers, housings, and caps. As the electric and electronic devices are being ported, for example, the volume of a memory card is reduced to one-tenth or less of the conventional size, and accordingly, the electric and electronic components are reduced in size, thickness, and height. The height of module parts is 5mm or less, and individual parts are divided by 2mm and are approaching 1mm.
[0003] このような小型薄型低背化の中で、電気電子部品は内蔵部品との間で十分な絶縁 性を確保するために、電気電子部品内の所要箇所にシート状絶縁フィルムを挿入す る方法が提案され、さらに、この方法の作業性を改善し製造コストを下げた、予め金 属基材上に絶縁皮膜を有する金属材料を用いた電気電子部品が提案された。 発明の開示  [0003] In such a small, thin, and low profile, an electrical / electronic component is inserted with a sheet-like insulating film at a required location in the electrical / electronic component in order to ensure sufficient insulation with the built-in component. In addition, electric and electronic parts using a metal material having an insulating film on a metal base material, which improved the workability of this method and reduced the manufacturing cost, were proposed. Disclosure of the invention
[0004] 前記の従来の電気電子部品では、絶縁性、特に絶縁耐圧性が十分に得られず、ス イッチやコネクタ用途では、金属ケースと絶縁皮膜間に高電圧が掛カるため絶縁破 壊を起こすこともあった。絶縁耐圧性を高めるために絶縁皮膜を厚くするのは、電気 電子部品の小型薄型低背化に反する。つまり両者はトレードオフの関係にある。  [0004] In the conventional electric and electronic parts described above, insulation, particularly withstand voltage, cannot be sufficiently obtained. In switches and connectors, insulation is broken because a high voltage is applied between the metal case and the insulation film. Sometimes caused. Increasing the thickness of the insulation film to increase the dielectric strength is contrary to the small size, thinness, and low profile of electrical and electronic parts. In other words, both are in a trade-off relationship.
[0005] このようなことから、本発明者等は、電気電子部品において金属材料上の絶縁皮膜 を厚くすることなく絶縁性を高めることに着目し、その方法を検討した。その結果、絶 縁皮膜に混入して絶縁性を害する塵、ほこりなどの異物の影響は、金属基材上に絶 縁皮膜を多層に形成することで低減すること、また絶縁性に有害な気泡も減少するこ とを知見し、さらに検討を進めて本発明を完成させるに至った。 [0005] For these reasons, the present inventors have made an insulating film on a metal material in an electric / electronic component. Focusing on improving the insulation without increasing the thickness, the method was examined. As a result, the influence of foreign matter such as dust and dust mixed in the insulation film and deteriorating the insulation can be reduced by forming the insulation film on the metal substrate in multiple layers, and bubbles harmful to the insulation can be obtained. As a result, the present invention was completed through further studies.
本発明の課題は、電気電子機器に搭載される電気電子部品の小型化、薄型化あ るいは低背化に適した金属材料、その製造方法、および前記金属材料を用いた電 気電子部品を提供することである。  An object of the present invention is to provide a metal material suitable for miniaturization, thinning, or low profile of an electric / electronic component mounted on an electric / electronic device, a manufacturing method thereof, and an electric / electronic component using the metal material. Is to provide.
[0006] 本発明によれば、以下の手段が提供される:  [0006] According to the present invention, the following means are provided:
(1)金属基材上の少なくとも絶縁を要する箇所に 2層以上の多層絶縁コーティング 層が設けられ、絶縁耐圧性を有することを特徴とする電気電子部品用金属材料。  (1) A metal material for electrical and electronic parts, which is provided with two or more multilayer insulation coating layers on at least a place where insulation is required on a metal substrate, and has a dielectric strength resistance.
[0007] (2)前記多層絶縁コーティング層の少なくとも 1層が着色され、前記着色によって該 多層絶縁コーティング層の絶縁欠陥の自動検知率を向上させたことを特徴とする(1) 項記載の電気電子部品用金属材料。 [0007] (2) The electricity according to item (1), wherein at least one layer of the multilayer insulating coating layer is colored, and the automatic detection rate of insulation defects of the multilayer insulating coating layer is improved by the coloring. Metal materials for electronic parts.
[0008] (3)金属基材上の少なくとも絶縁を要する箇所に、流動状塗布物を塗布し乾燥させ る塗装工程を複数回施すことを特徴とする(1)項記載の電気電子部品用金属材料 の製造方法。 [0008] (3) The metal for electrical and electronic parts as set forth in (1), wherein a coating step of applying a fluid coating material and drying it is applied to at least a place on the metal substrate that requires insulation. Material manufacturing method.
[0009] (4)金属基材上の少なくとも絶縁を要する箇所に、流動状塗布物を塗布し乾燥させ る塗装工程を複数回施す電気電子部品用金属材料の製造方法であって、前記塗装 工程の少なくとも 1回の工程で塗布する流動状塗布物に着色剤が添加されているこ とを特徴とする (2)項記載の電気電子部品用金属材料の製造方法。  [0009] (4) A method for producing a metal material for electrical and electronic parts, in which a coating process is applied a plurality of times to apply and dry a fluidized coating on at least a place requiring insulation on a metal substrate, the coating process A method for producing a metal material for electrical and electronic parts as described in (2) above, wherein a colorant is added to the fluid coating material applied in at least one step.
[0010] (5) (1)または(2)項記載の電気電子部品用金属材料が用いられていることを特徴 とする電気電子部品。  [0010] (5) An electrical / electronic component characterized in that the metal material for electrical / electronic component described in (1) or (2) is used.
[0011] 本発明の上記及び他の特徴及び利点は、適宜添付の図面を参照して、下記の記 載力もより明らかになるであろう。  [0011] The above and other features and advantages of the present invention will become more apparent from the following description with reference to the accompanying drawings as needed.
図面の簡単な説明  Brief Description of Drawings
[0012] [図 1]図 1 (A)及び 1 (B)は、本発明の第 1実施形態を示す電気電子部品用金属材 料を示し、図 1 (A)は平面図、図 1 (B)は図 1 (A)の A— A断面図である。  [FIG. 1] FIGS. 1 (A) and 1 (B) show a metal material for electrical and electronic parts showing a first embodiment of the present invention, FIG. 1 (A) is a plan view, and FIG. B) is a cross-sectional view taken along the line AA in FIG.
[図 2]図 2は、本発明の第 2実施形態を示す電気電子部品用金属材料の横断面図で ある。 [Fig. 2] Fig. 2 is a cross-sectional view of a metal material for electrical and electronic parts showing a second embodiment of the present invention. is there.
[図 3]図 3は、本発明の第 3実施形態を示す電気電子部品用金属材料の平面図であ る。  FIG. 3 is a plan view of a metal material for electric and electronic parts showing a third embodiment of the present invention.
[図 4]図 4は、本発明の第 4実施形態を示す電気電子部品用金属材料の平面図であ る。  FIG. 4 is a plan view of a metal material for electrical and electronic parts showing a fourth embodiment of the present invention.
[図 5]図 5は、本発明の第 5実施形態を示す電気電子部品用金属材料の横断面図で ある。  FIG. 5 is a cross-sectional view of a metal material for electrical and electronic parts showing a fifth embodiment of the present invention.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0013] 本発明の電気電子部品用金属材料の実施形態の例を図 1〜5を参照して具体的 に説明する。 [0013] An example of an embodiment of the metal material for electric and electronic parts of the present invention will be specifically described with reference to Figs.
本発明の電気電子部品用金属材料は、金属基材(1)上の表面及び Z又は裏面の 少なくとも絶縁を要する箇所に 2層以上の多層絶縁コーティング層 (2)が設けられて なり、良好な絶縁耐圧性を有するものである。  The metal material for electrical and electronic parts of the present invention is excellent in that two or more multilayer insulation coating layers (2) are provided at least on the surface of the metal substrate (1) and on the Z or back surface where insulation is required. It has dielectric strength.
図 1 (A)及び 1 (B)に示す金属材料は、板状の金属基材 1の片側表面上に 2層のコ 一ティング層 2 (2a、 2b)を長手方向にストライプ状に設けたものである。図 1 (A)及び 1 (B)中、図 1 (A)は平面図を、図 1 (B)は図 1 (A)の A— A断面図をそれぞれ示す。 ここで、板状の金属基材の厚さ方向を含む面を除いた 2つの面の内、一方を表面 (to p or front surface)と他方を袅面 (back surface)と呼ふ。  In the metal material shown in FIGS. 1 (A) and 1 (B), two coating layers 2 (2a, 2b) are provided in stripes in the longitudinal direction on one surface of a plate-like metal substrate 1. Is. 1 (A) and 1 (B), FIG. 1 (A) is a plan view, and FIG. 1 (B) is a cross-sectional view taken along the line AA in FIG. 1 (A). Here, one of the two surfaces excluding the surface including the thickness direction of the plate-like metal substrate is called a top or front surface and the other is called a back surface.
[0014] 図 2の横断面図に示す金属材料は、板状の金属基材 1の両側表面 (表面と裏面) 上にそれぞれ 2層の絶縁コーティング層 2 (—層目の絶縁コーティング層 2a、二層目 の絶縁コーティング層 2b)を長手方向にストライプ状に設けたものである。(図示した 以外に、金属基材 1の片面 (例えば裏面)全体に絶縁コーティング層 2を設けてもよい o ) [0014] The metal material shown in the cross-sectional view of FIG. 2 includes two insulating coating layers 2 (the first insulating coating layer 2a, A second insulating coating layer 2b) is provided in a stripe shape in the longitudinal direction. (In addition to the illustration, the insulating coating layer 2 may be provided on one side (for example, the back side) of the metal base 1)
[0015] 図 3の平面図に示す金属材料は、板状の金属基材 1の片側表面上に 2層の絶縁コ 一ティング層 2 (2a、 2b)を長手方向にスポット状に設けたものである。  [0015] The metal material shown in the plan view of Fig. 3 is obtained by providing two insulating coating layers 2 (2a, 2b) in the form of spots in the longitudinal direction on one surface of a plate-like metal base 1 It is.
[0016] 図 4の平面図に示す金属材料は、板状の金属基材 1の片側表面上に 2層の絶縁コ 一ティング層 2 (2a、 2b)をドーナツ状に設けたものである。本発明において、絶縁コ 一ティング層の形状は特に限定されるものではなぐ例えば、ストライプ状、スポット状 、円形、ドーナツ状、周辺がギザギザになったもの、これらが混在したものなど任意で ある。 The metal material shown in the plan view of FIG. 4 is one in which two insulating coating layers 2 (2a, 2b) are provided in a donut shape on one surface of a plate-like metal substrate 1. In the present invention, the shape of the insulating coating layer is not particularly limited. , Round, donut-shaped, jagged edges, or a mixture of these.
[0017] 図 5の横断面図に示す金属材料は、板状の金属基材 1の両側表面上にそれぞれ 1 層目の絶縁コーティング層 2aを設け、次いで特に高い絶縁性を要する箇所に 2層目 の絶縁コーティング層 2bを設けてなり、 2層の絶縁コーティング層(2)を有するもので ある。  [0017] The metal material shown in the cross-sectional view of FIG. 5 is provided with a first insulating coating layer 2a on each side surface of the plate-like metal substrate 1, and then two layers in places where particularly high insulation is required. The first insulating coating layer 2b is provided and has two insulating coating layers (2).
[0018] 本発明の電気電子部品用金属材料は、例えば、次のようにして製造することができ る。  [0018] The metal material for electrical and electronic parts of the present invention can be produced, for example, as follows.
即ち、走行する金属基材の表面に塗装装置の吐出口から流動状塗布物を供給し て塗布し、次いで加熱して溶剤を揮発させると同時に、硬化および化学反応させて 1 層目の絶縁コーティング層を形成する。次にその上に 2層目のコーティング層を 1層 目と同様にして形成する。必要に応じて 3層目、 4層目を形成する。  In other words, a fluidized coating is supplied to the surface of a traveling metal substrate from the discharge port of a coating device, applied, and then heated to volatilize the solvent, and at the same time, cured and chemically reacted to form the first insulating coating. Form a layer. Next, a second coating layer is formed on the same as the first layer. Form third and fourth layers as required.
[0019] 本発明において、金属基材には、打抜加工性および絞り成形性に優れ、良好な延 性およびばね性を備えた洋白(Cu— Ni系合金)、リン青銅 (Cu— Sn— P系合金)、 4 2ァロイ (Fe—Ni系合金)、ステンレスなどが好適に用いられる。中でもリン青銅は各 性能のバランスが良く好ま 、。金属基材の導電率は電磁シールド性の観点から 5 %IACS以上が好ましぐ特に 10%IACS以上が好ましぐ比透磁率は 1以上が好ま しい。 [0019] In the present invention, the metal base material is a white (Cu—Ni alloy), phosphor bronze (Cu—Sn) having excellent punchability and drawability, and good ductility and springiness. — P-type alloy), 42 alloy (Fe—Ni-type alloy), stainless steel, etc. are preferably used. Among them, phosphor bronze is preferred because it has a good balance of performance. The electrical conductivity of the metal substrate is preferably 5% IACS or more, particularly preferably 10% IACS or more from the viewpoint of electromagnetic shielding, and the relative permeability is preferably 1 or more.
[0020] 本発明にお ヽて、金属基材は所定の金属原料を溶解铸造して得られる铸塊に熱 間圧延、冷間圧延、均質化処理、脱脂処理をこの順に施す常法により製造できる。 金属基材の形状は板、条などであり、その厚みは 0. 01-0. 5mmが好ましぐ特に 0 . 05〜0. 2mm力好まし!/ヽ。  [0020] In the present invention, the metal substrate is produced by a conventional method in which hot rolling, cold rolling, homogenization treatment, and degreasing treatment are performed in this order on the koji obtained by melting and forging a predetermined metal raw material. it can. The shape of the metal substrate is a plate, strip, etc., and its thickness is preferably 0.01-0. 5 mm, especially 0.05-0.2 mm force! / ヽ.
[0021] 本発明の電気電子部品用金属材料は、前記金属基材上の絶縁を要する箇所に絶 縁コーティング層を多層に設けて、絶縁性を害する異物や気泡の影響を低減したも のである。なお、前記金属基材上の絶縁を要する箇所とは、金属材料を用いて電気 電子部品(筐体やケースなど)を形成したとき、絶縁を要する内蔵部品が近接または 接触する箇所である。  [0021] The metal material for electrical and electronic parts of the present invention has an insulating coating layer provided in multiple layers on the metal base where insulation is required, thereby reducing the influence of foreign matter and bubbles that impair insulation. . The location on the metal substrate that requires insulation is a location where a built-in component that requires insulation approaches or comes into contact when an electrical / electronic component (such as a casing or case) is formed using a metal material.
[0022] 異物や気泡が混入した箇所は絶縁コーティング層が薄くなつているため高電圧が 掛かると金属基材と内蔵部品間にスパークが発生し絶縁破壊を起こす。異物などが 存在しなければ絶縁コーティング層の厚みが 3 μ m程度でも直流 lkVの絶縁耐圧性 が得ることができる。異物などの多くは絶縁コーティング層を形成する際のクリーンブ ースゃクリーンボックスなどで混入する。 [0022] In places where foreign matter or bubbles are mixed, the insulation coating layer is thin, so high voltage is applied. When applied, a spark is generated between the metal substrate and the built-in component, causing dielectric breakdown. If there is no foreign material, DC lkV withstand voltage can be obtained even if the insulation coating layer thickness is about 3 μm. Most foreign materials are mixed in a clean box or other clean box when forming the insulating coating layer.
[0023] 電気電子部品には直流または交流で通常 500V以上の絶縁耐圧性が求められ、 一方、小型薄型低背化のためには絶縁コーティング層の厚みは 60 m以下が好ま しぐ特に 30 m以下が好ましい。  [0023] Electrical and electronic parts are usually required to have a dielectric breakdown voltage of 500V or higher for direct current or alternating current. On the other hand, the thickness of the insulating coating layer is preferably 60 m or less, especially 30 m for a small, thin and low profile. The following is preferred.
[0024] 本発明の金属材料は、金属基材の絶縁を要する箇所に絶縁コーティング層を多層 に設けて絶縁性を高めたもので、好ましくは、例えば、多層絶縁コーティング層の全 厚みが 25 μ mで 500V以上の絶縁耐圧性が得られるものである。従ってこの金属基 材を用いることにより電気電子部品の小型薄型低背化が可能である。  [0024] The metal material of the present invention has a multi-layered insulation coating layer provided at a location requiring insulation of the metal base material to enhance insulation. Preferably, for example, the total thickness of the multi-layer insulation coating layer is 25 μm. A dielectric strength of 500V or more can be obtained at m. Therefore, by using this metal substrate, it is possible to reduce the size, thickness, and height of electrical and electronic parts.
[0025] 本発明において、多層絶縁コーティング層の 1層目の厚みと 2層目以降の厚みの関 係、多層絶縁コーティング層全体の厚みと各層の厚みの関係、各層相互の厚みの相 対的な関係などは製造条件などを配慮して適宜決めれば良い。但し、 1層あたりの厚 みは薄すぎるとピンホールが発生し易くなるので 2 μ m以上が好ましぐ特に 3 μ m以 上が好ましい。  [0025] In the present invention, the relationship between the thickness of the first layer of the multilayer insulating coating layer and the thickness of the second and subsequent layers, the relationship between the thickness of the entire multilayer insulating coating layer and the thickness of each layer, and the relative thickness of each layer. The appropriate relationship may be determined as appropriate in consideration of manufacturing conditions. However, if the thickness per layer is too thin, pinholes are likely to be generated, so 2 μm or more is preferable, and 3 μm or more is particularly preferable.
[0026] 本発明にお 、て、流動状塗布物にはポリエステル系榭脂など任意の榭脂のワニス が使用でき、榭脂としては、後に、半田接合、リフロー半田実装などの加熱工程を経 る場合はポリイミド系、ポリアミドイミド系、ポリアミド系、エポキシ系などの耐熱性榭脂 が好ましい。特にポリイミド系榭脂、ポリアミドイミド系榭脂が好ましい。また、多層絶縁 コーティング層の各層を形成する流動状塗布物の榭脂は同じであっても異なっても 良い。また、榭脂以外ではアルミナ等のセラミックや層状ケィ酸塩をグリーンシート状 に塗布形成し、加熱焼き付けしたものも使用できる。多層絶縁コーティング層の体積 固有抵抗は ΙΟ^ Ω 'cm以上が好ましぐ特に 1014 Ω 'cm以上が好ましい。 [0026] In the present invention, an arbitrary resin varnish such as polyester-based resin can be used for the fluid coating, and the resin is later subjected to a heating process such as solder bonding or reflow solder mounting. In this case, a heat-resistant resin such as polyimide, polyamideimide, polyamide or epoxy is preferred. In particular, polyimide resin and polyamideimide resin are preferable. In addition, the resin in the fluidized coating forming each layer of the multilayer insulating coating layer may be the same or different. In addition to resin, it is also possible to use a ceramic such as alumina or a layered silicate coated and formed in a green sheet and then baked by heating. The volume resistivity of the multilayer insulating coating layer is preferably ΙΟ ^ Ω 'cm or more, particularly 10 14 Ω' cm or more.
[0027] 絶縁コーティング層となる塗布物を紫外線 (UV)や電子線 (EP)を照射して硬化さ せる場合は、溶剤などの揮発成分を含まな 、塗料或いは塗布物を用いるので塗布 厚みがそのままコーティング厚みになる。  [0027] In the case where the coating material to be the insulating coating layer is cured by irradiating with ultraviolet rays (UV) or electron beams (EP), the coating thickness does not include a volatile component such as a solvent. It becomes the coating thickness as it is.
[0028] 本発明において、多層絶縁コーティング層は、従来用いられる装置等を利用して安 価に、生産性良く設けることができる。但し、絶縁コーティング層を多層に設けるため には、流動性塗布物は高精度に塗布する必要がある。特に、塗布の際、金属基材幅 方向の位置は高精度に設定する必要がある。そのために金属基材の両側端をガイド[0028] In the present invention, the multi-layer insulating coating layer is made safe by using a conventionally used apparatus or the like. Can be provided with good productivity. However, in order to provide an insulating coating layer in multiple layers, the fluid coating must be applied with high accuracy. In particular, when applying, the position in the width direction of the metal substrate needs to be set with high accuracy. For that purpose, guide both sides of the metal base
(溝を入れたロール状や板状タイプ)で案内するのが好ま ヽ。 It is preferable to guide in the form of rolls or plates with grooves.
[0029] 本発明において、流動状塗布物を高精度に塗布するには、流動状塗布物を塗装 装置の吐出口から供給する方法が推奨される。この方法では吐出口を金属基材表 面の幅方向に対する所定位置に対面させて固定し、前記吐出口から吐出する流動 状塗布物を走行する金属基材上に連続的に供給し、続いて加熱炉に通して溶媒を 揮発させ、同時に、榭脂を反応させ硬化させて絶縁コーティング層を焼付ける。塗布 条件は絶縁コ一ティング層の形状や使用する流動状塗布物の種類により選定する。 通常、吐出圧力 3〜50kgZcm2、吐出口と金属基材との間隔 10〜200 mである。 [0029] In the present invention, in order to apply the fluid coating material with high accuracy, a method of supplying the fluid coating material from the discharge port of the coating apparatus is recommended. In this method, the discharge port is fixed at a predetermined position with respect to the width direction of the metal substrate surface, and the fluid coating material discharged from the discharge port is continuously supplied onto the traveling metal substrate. The insulating coating layer is baked by passing through a heating furnace to volatilize the solvent and simultaneously reacting and curing the resin. The coating conditions are selected according to the shape of the insulating coating layer and the type of fluidized coating used. Usually, the discharge pressure is 3 to 50 kgZcm 2 , and the distance between the discharge port and the metal substrate is 10 to 200 m.
[0030] 本発明において、絶縁コーティング層の横断面形状は、矩形、台形、逆台形など任 意であり、その多くは幅が金属基材幅より狭い。前記断面形状は両端部に斜めに垂 れていたり、両端上部が角状に部分突出している場合もある。吐出口の形状は、絶 縁コーティング層の横断面形状に近似させるのが好ましい。 In the present invention, the cross-sectional shape of the insulating coating layer is arbitrary such as a rectangle, a trapezoid, and an inverted trapezoid, and many of them are narrower than the width of the metal substrate. In some cases, the cross-sectional shape is slanted at both ends, or the upper ends of both ends are partially protruding in a square shape. The shape of the discharge port is preferably approximated to the cross-sectional shape of the insulating coating layer.
[0031] コーティング層に存在して絶縁性を害するピンホールなどの表面の絶縁欠陥は、多 層絶縁コ一ティング層を着色することで検出され易くなる。この傾向はイメージセンサ 一を利用した画像認識装置による自動検査の場合も、目視検査の場合も同じ傾向で ある。この着色は、前記流動状塗布物に、着色剤を添加することで容易に行える。本 発明においては、多層絶縁コーティング層の少なくとも 1層を着色することによりピン ホールなどの欠陥を的確に自動検知でき、多層絶縁コーティング層の絶縁欠陥の自 動検知率を向上させることができる。  [0031] Surface insulation defects such as pinholes that are present in the coating layer and impair insulation properties are easily detected by coloring the multilayer insulating coating layer. This tendency is the same for both the automatic inspection by the image recognition device using an image sensor and the visual inspection. This coloring can be easily performed by adding a coloring agent to the fluidized coating. In the present invention, by coloring at least one of the multilayer insulation coating layers, defects such as pinholes can be automatically detected accurately, and the automatic detection rate of insulation defects in the multilayer insulation coating layer can be improved.
[0032] 本発明において、着色の色は特に限定されるものではなぐ全ての色において欠 陥部分と無欠陥部分との間の色調差が明瞭に顕れる。  In the present invention, the color of coloring is not particularly limited, and the color tone difference between the defect portion and the defect-free portion clearly appears in all colors.
着色の色が無彩色(白、灰、黒など)の場合、黒色は N値 3以下が好ましぐ白色は N値 8以上が好ましい。有彩色 (赤、黄、緑など)の場合、赤色は色相 10R〜10RP、 明度 3〜5、彩度 10〜14が好ましい。黄色は色相 10Y〜: LOYR、明度 6〜8、彩度 1 0〜 14が好ましい。緑色は色相 10G〜: LOGY、明度 5〜7、彩度 5〜 10が好ましい。 青色は色相 5PB〜: L0BG、明度 3〜5、彩度 10〜14が好ましい。紫色は色相 10P〜 10PB、明度 4〜6、彩度 10〜14が好ましい。 When the coloring color is an achromatic color (white, gray, black, etc.), black is preferred to have an N value of 3 or less. White has an N value of 8 or more. In the case of chromatic colors (red, yellow, green, etc.), red preferably has a hue of 10R to 10RP, a brightness of 3 to 5, and a saturation of 10 to 14. Yellow is preferably hue 10Y ~: LOYR, lightness 6-8, saturation 10-14. Green is preferably hue 10G ~: LOGY, lightness 5-7, saturation 5-10. Blue has a hue of 5PB-: L0BG, lightness of 3-5, and saturation of 10-14. Purple is preferred to have a hue of 10P to 10PB, lightness of 4 to 6, and saturation of 10 to 14.
[0033] 本発明において、着色剤には、好ましくは、無機顔料、有機顔料、前記顔料の前駆 体物質、染料、或いはこれらの混合物が用いられる。黒色着色の無機顔料としては カーボンブラックが用いることができる。その他には Cu— Cr— Mn系、 Mn— Fe— C u系、 Co— Fe— Cr系、 Ni— Cu系、 Cr— Fe系、 Fe— Cu系、 Ti— Mn— Cu系、 Cu — Cr—Fe系などの複合金属酸ィ匕物が使用できる。その他の色の無機顔料としては 酸ィ匕チタンなどを用いることができる。有機顔料としては、例えば、銅フタロシアニン などがある。また水または溶媒に可溶なァ-リンブラックなどの染料を使用してもよ 、 。また、これら顔料および染料を榭脂などでコーティングした加工物でもよい。 In the present invention, an inorganic pigment, an organic pigment, a precursor material of the pigment, a dye, or a mixture thereof is preferably used as the colorant. Carbon black can be used as the black pigmented inorganic pigment. Others include Cu-Cr-Mn, Mn-Fe-Cu, Co-Fe-Cr, Ni-Cu, Cr-Fe, Fe-Cu, Ti-Mn-Cu, Cu-Cr -Complex metal oxides such as Fe can be used. As other inorganic pigments, titanium oxide or the like can be used. Examples of the organic pigment include copper phthalocyanine. Alternatively, a dye such as alin black that is soluble in water or a solvent may be used. Moreover, the processed material which coated these pigments and dyes with rosin etc. may be sufficient.
着色の色の中では、外観の高級感ゃ、金属基材条材との色調の差、光を反射しな いなどの理由から、黒色または艷消し着色が好ましぐ特に艷消し黒色が好ましい。 黒色コーティング層を形成する場合、塗装ワニスへの黒色顔料の添加量は、好まし くは 0. 5〜60質量0 /0、より好ましくは 3〜30質量%である。 Of the colored colors, black or matte coloring is preferred, particularly matte black, because of the high-quality appearance, color tone difference from the metal substrate strip, and the fact that it does not reflect light. . When forming a black coating layer, the amount of black pigment into paint varnish, rather preferably is from 0.5 to 60 weight 0/0, more preferably from 3 to 30 mass%.
[0034] 本発明においては、前記流動状塗布物に、上記の着色剤に加え、さらに艷消剤を 添加することも好ましい。本発明に用いることができる艷消剤としては、シリカ(SiO ) In the present invention, it is also preferable to add a decoloring agent to the fluid coating material in addition to the colorant. As a disinfectant that can be used in the present invention, silica (SiO 2)
2 が好ましい。シリカの製造法には湿式法と乾式法があり、湿式法にはさらに沈降法と ゲル法があり、どの方法で製造したシリカも使用できる。この他、コロイダルシリカ、フ ユームドシリカ、榭脂などをコーティングして分散性を改善したシリカなども使用可能 である。どのシリカを用いるかは榭脂コーティング層の強度などに合わせて選択する 艷消剤、例えばシリカは、平均粒径が好ましくは 1〜5 /ζ πι、より好ましくは 2〜4 /ζ πι であり、添力卩量は好ましくは 0. 2〜20質量%、より好ましくは 1〜10質量%とする。  2 is preferred. There are wet and dry methods for producing silica, and wet methods include precipitation method and gel method, and silica produced by any method can be used. In addition, colloidal silica, fumed silica, silica with improved dispersibility by coating with rosin and the like can also be used. The silica to be used is selected according to the strength of the resin coating layer, etc. The quenching agent such as silica has an average particle size of preferably 1 to 5 / ζ πι, more preferably 2 to 4 / ζ πι. The amount of added force is preferably 0.2 to 20% by mass, more preferably 1 to 10% by mass.
[0035] シリカ以外の榭脂系の艷消剤も使用可能である。艷消剤は要求される榭脂皮膜の 光沢度に合わせてその量を調整して塗装ワニスに添加する。艷消剤も着色剤と同様 に塗装ワニスに分散させ、好適な光沢度 (ダロス)を得ることができる。  [0035] A non-silica defatting agent other than silica can also be used. Detergent is added to the paint varnish after adjusting the amount according to the required gloss of the resin film. As with the colorant, the matting agent can be dispersed in the paint varnish to obtain a suitable gloss (dalos).
[0036] 多層絶縁コーティング層の少なくとも 1層を着色することにより、絶縁榭脂コ一ティン グ層の欠陥を極めて高感度に検出して、不良品を除去できる。そのエラー率は、最 大でも 25%以下、着色剤及び艷消剤の添加量を好適に調整した場合にお!ヽては 0 . 5%以下を実現できる。 [0036] By coloring at least one of the multilayer insulating coating layers, defects in the insulating resin coating layer can be detected with extremely high sensitivity, and defective products can be removed. The error rate is the highest At most 25% or less, and 0.5% or less can be realized when the addition amount of the coloring agent and the decoloring agent is suitably adjusted.
[0037] 本発明にお 、て、金属基材上に Niや Snなどの金属層を設けて、金属基材の耐食 性、はんだ付け性、絶縁コーティング層との密着性を向上させることができる。前記金 属層は前記金属基材上全面に設けても、金属基材の露出部分にのみ設けても良い [0037] In the present invention, a metal layer such as Ni or Sn can be provided on a metal substrate, and the corrosion resistance, solderability, and adhesion to the insulating coating layer of the metal substrate can be improved. . The metal layer may be provided on the entire surface of the metal substrate or only on the exposed portion of the metal substrate.
[0038] 本発明にお 、て、金属基材または金属層にシランカップリング処理やチタネート系 カップリング処理などの有機、無機結合の下地処理を施して絶縁コーティング層の密 着性を向上させることができる。 [0038] In the present invention, the adhesion of the insulating coating layer is improved by subjecting the metal substrate or metal layer to an organic or inorganic bond base treatment such as silane coupling treatment or titanate coupling treatment. Can do.
[0039] 本発明の金属材料を用いて電気電子部品の筐体を構成する場合、前記金属材料 の絶縁コーティング層を絶縁を要する箇所に設け、内蔵部品と筐体とを絶縁できる。 前記絶縁コ一ティング層は絶縁を要する部品との位置関係に応じて筐体の内側に設 けても外側に設けても良い。素子内蔵用低背化筐体やコネクタシールド筐体におい てその効果が大きく発現される。  [0039] When a metal material of the present invention is used to form a casing of an electrical / electronic component, an insulating coating layer of the metal material can be provided at a location requiring insulation to insulate the built-in component from the casing. The insulating coating layer may be provided inside or outside the housing depending on the positional relationship with a component that requires insulation. The effect is greatly manifested in low-profile housings for built-in elements and connector shield housings.
[0040] 本発明の電気電子部品が電磁シールドする対象は、携帯機器 (携帯電話、携帯情 報端末、ノ ソコン、デジタルカメラ、デジタルビデオ、ゲーム機など)のプリント基板な どに実装されるセラミック発振子、水晶発振器、電圧制御発振器、 SAWフィルター、 ダイプレクサ、力プラ、バラン、 LPF、 BPF、誘電体デュプレクサなどの個別部品、前 記個別部品を複数内蔵させたアンテナスィッチモジュール、フロントエンドモジュール 、 RF—体型モジュール、ブルートゥース(Bluetooth)モジュール、イメージセンサー モジュール、チューナーモジュール、無線 LANモジュールなどの各種モジュール、 或いは液晶ドライバ (LCD)やキーボード、マザ一ボードなどのプリント基板側の端子 接続コネクタと FPCケーブル側などの接続コネクタ、基板対基板コネクタ、さら〖こは検 出スィッチや小型メモリ'カード用コネクタ、リムーバブルタイプまたは半組み込みタイ プのコネクタなどである。  [0040] The electromagnetic shield of the electrical and electronic component of the present invention is a ceramic mounted on a printed circuit board of a portable device (mobile phone, portable information terminal, notebook computer, digital camera, digital video, game machine, etc.). Individual components such as resonators, crystal oscillators, voltage controlled oscillators, SAW filters, diplexers, force plastics, baluns, LPFs, BPFs, dielectric duplexers, antenna switch modules with multiple built-in individual components, front end modules, RF —Body module, Bluetooth module, image sensor module, tuner module, wireless LAN module, and other modules, or terminals on the printed circuit board side such as LCD driver, LCD, keyboard, motherboard etc. Connector and FPC cable side Connector, board to board, etc. Connector, further 〖This detection switch or a small-sized memory 'connector for the card, and the like removable type or semi-built-in type connector.
[0041] 前記(1)項記載発明の電気電子部品用金属材料は、金属基材 1上の少なくとも絶 縁を要する箇所に 2層以上の多層絶縁コーティング層 2が設けられているので、例え ば、多層絶縁コーティング層を 2層にして設ける場合、 1層目の絶縁コーティング層に 異物が混入しても、その上には 2層目の健全な絶縁コーティング層が形成されるので 異物の影響が低減され、良好な絶縁耐圧性を有する。また 1層あたりの厚さを薄くで きるため気泡も抜け易い。従って絶縁コーティング層を厚くすることなく絶縁性を向上 させることができる。また絶縁コーティング層を、絶縁を要する箇所にのみ設けること により、電気電子部品の小型薄型低背化、流動状塗布物の節減、放熱性の高度維 持が図れる。 [0041] In the metal material for electrical and electronic parts of the invention described in (1), two or more multilayer insulating coating layers 2 are provided at least on the metal base 1 where insulation is required. When the multilayer insulation coating layer is provided in two layers, the first insulation coating layer Even if foreign matter is mixed in, the second layer of healthy insulating coating layer is formed on it, so the influence of the foreign matter is reduced and it has good dielectric strength. In addition, since the thickness per layer can be reduced, bubbles can easily escape. Therefore, the insulating property can be improved without increasing the thickness of the insulating coating layer. In addition, by providing an insulating coating layer only where insulation is required, it is possible to reduce the size and thickness of electrical and electronic parts, save fluidized coatings, and maintain high heat dissipation.
[0042] 前記(2)項記載発明の電気電子部品用金属材料は、前記多層絶縁コーティング 層の少なくとも 1層を着色し、前記着色によって該多層絶縁コ一ティング層の絶縁欠 陥の自動検知率を向上させたものなので、絶縁コーティング層の外観検査が的確に 行え、前記金属材料の信頼性が高まる。  [0042] In the metal material for electrical and electronic parts of the invention described in (2), at least one of the multilayer insulating coating layers is colored, and the automatic detection rate of the insulation defect of the multilayer insulating coating layer by the coloring. Therefore, the appearance inspection of the insulating coating layer can be performed accurately, and the reliability of the metal material is increased.
[0043] 前記(3)項記載発明は金属基材上の少なくとも絶縁を要する箇所に、流動状塗布 物を塗布し乾燥させる塗装工程を多数回(2回以上)施す電気電子部品用金属材料 の製造方法であり、前記 (4)項記載発明は前記(3)項記載発明における塗装工程の 少なくとも 1回の工程で塗布する流動状塗布物に着色剤を添加する製造方法であり 、いずれも従来用いられている装置を使用して製造することが可能であり、製造コスト が安い。  [0043] The invention described in the above item (3) is a metal material for electrical and electronic parts which is subjected to a coating process of applying a fluid coating material and drying it at least at a place where insulation is required on the metal base material a plurality of times (twice or more). The invention described in the above item (4) is a manufacturing method in which a colorant is added to a fluid coating applied in at least one step of the coating step in the invention described in the above (3), both of which are conventional It can be manufactured using the equipment used, and the manufacturing cost is low.
[0044] 前記(5)項記載の電気電子部品は、前記(1)または(2)項記載の電気電子部品用 金属材料が用いられているので、絶縁コーティング層を厚くせずに内蔵部品との間 の絶縁性を十分確保でき、小型薄型低背化に有利である。また絶縁コーティング層 の少なくとも 1層を着色したものは絶縁コーティング層の外観検査が的確に行えるた め信頼性に優れる。さらに絶縁コーティング層を、絶縁を要する箇所にのみ設けると 、流動状塗布物の節減、電気電子部品の小型薄型低背化、放熱性の高度維持が図 れる。  [0044] Since the electrical / electronic component described in (5) above uses the metal material for electrical / electronic component described in (1) or (2) above, the built-in component and the insulating coating layer are not thickened. Insulation between the two can be secured sufficiently, and it is advantageous for a small, thin and low profile. In addition, when at least one insulating coating layer is colored, the appearance of the insulating coating layer can be accurately inspected, resulting in excellent reliability. In addition, if an insulating coating layer is provided only in locations where insulation is required, fluidized coatings can be saved, electrical and electronic parts can be reduced in size, thickness and height, and high heat dissipation can be maintained.
実施例  Example
[0045] 次に本発明を実施例に基づきさらに詳細に説明するが、本発明はこれに限定され るものではない。  [0045] Next, the present invention will be described in more detail based on examples, but the present invention is not limited thereto.
[0046] 実施例 1 [0046] Example 1
厚み 0. lmm,幅 10mmの金属条 (金属基材)に電解脱脂、水洗、酸洗、水洗、乾 燥 (加熱)の各工程をこの順に施し、次 、で各条の絶縁を要する箇所に多層絶縁コ 一ティング層を設けて電気電子部品用金属材料を製造した。金属条に «JIS合金 C5 210R (リン青銅、古河電気工業株式会社製)、 C7701R (洋白、三菱電機メテックス 社製)または SUS304— CPS (ステンレス、 日新製鋼社製)を用いた。 Electrolytic degreasing, water washing, pickling, water washing, and drying on a metal strip (metal substrate) with a thickness of 0.1 mm and a width of 10 mm Each step of drying (heating) was performed in this order, and then a metal material for electric and electronic parts was manufactured by providing a multilayer insulating coating layer at a location where insulation of each strip was required. JIS alloy C5 210R (phosphor bronze, manufactured by Furukawa Electric Co., Ltd.), C7701R (Yohaku, manufactured by Mitsubishi Electric Metex Co., Ltd.) or SUS304—CPS (stainless steel, manufactured by Nisshin Steel Co., Ltd.) was used for the metal strip.
[0047] 前記多層絶縁コーティング層は、ワニス (流動状塗布物)を、塗装装置の矩形状吐 出口から、走行する金属基材表面の幅方向中央部分に垂直に吐出し、次いで 300 °Cで 30秒間加熱して一層目の絶縁コーティング層をストライプ状に形成し、この上に 二層目、三層目を同様にして設けた。前記金属基材は幅方向を固定して走行させた [0047] The multilayer insulating coating layer discharges varnish (fluid coating) from the rectangular outlet of the coating apparatus perpendicularly to the central portion in the width direction of the traveling metal substrate surface, and then at 300 ° C. The first insulating coating layer was formed in a stripe shape by heating for 30 seconds, and the second and third layers were provided in the same manner. The metal substrate was run with the width direction fixed.
[0048] 前記ワニスには n—メチル 2—ピロリドンを溶媒とするポリイミド (PI)溶液 (荒川化学 社製)とポリアミドイミド (PAI)溶液 (東特塗料社製)の 2種類を用いた。前記ワニスの 吐出圧力は 10〜15kgZcm2、吐出口と金属基材との間隔は 20〜50 /ζ πιとした。絶 縁コーティング層の横断面形状は略矩形 (厚み 5 μ m以上、幅 7mm)であった。 [0048] Two types of varnish were used: a polyimide (PI) solution (made by Arakawa Chemical Co., Ltd.) using n-methyl 2-pyrrolidone as a solvent and a polyamideimide (PAI) solution (made by Tohoku Paint Co., Ltd.). The discharge pressure of the varnish was 10 to 15 kgZcm 2 , and the distance between the discharge port and the metal substrate was 20 to 50 / ζ πι. The cross-sectional shape of the insulating coating layer was almost rectangular (thickness 5 μm or more, width 7 mm).
[0049] 得られた電気電子部品用金属材料について、絶縁耐圧性を下記方法により調べた 即ち、前記金属材料を、その絶縁コーティング層がステンレスロール表面に接触す るように通過させ、このステンレスロールと金属材料間に 0. 5kVの直流電圧をスパー クテスタ (クリントン社製)を用いて印加し、絶縁耐圧性の劣る箇所で発生するスパー クの発生回数を計測した。前記金属材料の試験長さは各 100mとした。  [0049] With respect to the obtained metal material for electric and electronic parts, the withstand voltage resistance was examined by the following method. That is, the metal material was passed so that the insulating coating layer was in contact with the surface of the stainless steel roll. A 0.5 kV DC voltage was applied between the metal and the metal material using a spark tester (manufactured by Clinton), and the number of occurrences of sparks at locations with poor dielectric strength was measured. The test length of the metal material was 100 m each.
[0050] 前記金属材料につ!、て、絶縁コーティング層のピンホール個数を自動外観検査と 目視検査により調べ、自動外観検査で検知したピンホール個数 iと目視検査で検知し た個数 jと力も、自動外観検査の認識エラー率 [(j— i)Zj] x ioo%を求めた。自動 外観検査には一般的な 2値ィ匕による白黒画像処理手段を備えた画像認識装置を使 用し、目視検查には CCDを用 、たマイクロスコープ(キーエンス社製 VH - 8000)を 使用した。倍率は 200倍とした。前記金属材料の試験長さは各 5mとし、試験個数 (n )は各 10とした。認識エラー率の平均値が 5%未満を、自動外観検査性が極めて良 好 (◎)、 5〜15%を良好(〇)、 15%を超える場合を不良(X )と評価した。 [0050] Regarding the metal material, the number of pinholes in the insulating coating layer is checked by automatic visual inspection and visual inspection, and the number of pinholes detected by automatic visual inspection i, the number detected by visual inspection j, and the force are also calculated. The recognition error rate [(j—i) Zj] x ioo% for automatic visual inspection was obtained. Automatic visual inspection uses an image recognition device equipped with a general binary image processing means using binary values, and visual inspection uses a CCD and a microscope (Keyence VH-8000). did. The magnification was 200 times. The test length of the metal material was 5 m each, and the number of tests (n) was 10 each. When the average recognition error rate was less than 5%, the automatic appearance inspection was evaluated as very good (◎), 5-15% as good (◯), and more than 15% as bad (X).
[0051] 実施例 2 少なくとも 1層を、着色顔料と艷消剤を添加したワニスを用いてコーティングした他 は実施例 1と同じ方法により電気電子部品用金属材料を製造し、実施例 1と同じ方法 により絶縁耐圧性を調べた。また着色した層をコーティングする毎に実施例 1と同じ 方法により自動外観検査性を評価した。 [0051] Example 2 A metal material for electric and electronic parts was produced by the same method as in Example 1 except that at least one layer was coated with a varnish to which a color pigment and a decoloring agent were added. Examined. In addition, automatic appearance inspection was evaluated by the same method as in Example 1 every time the colored layer was coated.
[0052] 比較例 1  [0052] Comparative Example 1
絶縁コーティング層を 1層設けた他は、実施例 1と同じ方法により電気電子部品用 金属材料を製造し、実施例 1と同じ方法により絶縁耐圧性を調べた。  A metal material for electrical and electronic parts was produced by the same method as in Example 1 except that one insulating coating layer was provided, and the withstand voltage was examined by the same method as in Example 1.
[0053] 実施例 1、 2と比較例 1の結果を表 1に示す。表 1には絶縁コーティング層の厚みを 併記した。コーティング層の厚みは、 1層をコーティングする毎にマイクロメータを用い て測定した。また着色顔料と艷消剤の種類と添加量を表 2に示す。  [0053] Table 1 shows the results of Examples 1 and 2 and Comparative Example 1. Table 1 also shows the thickness of the insulating coating layer. The thickness of the coating layer was measured using a micrometer every time one layer was coated. In addition, Table 2 shows the types and amounts of color pigments and disinfectants.
[0054] [表 1] [0054] [Table 1]
表 1 table 1
Figure imgf000014_0001
Figure imgf000014_0001
(註)①複合酸化物、②鋇フタロシアニン (表 2参照)。  (Ii) ① Complex oxide, ② 鋇 phthalocyanine (see Table 2).
③自動外観検査の認識エラー率で評価、 ©極めて優れる、〇優れる。  ③Evaluated by recognition error rate of automatic visual inspection. © Excellent, 〇Excellent.
[0055] [表 2]  [0055] [Table 2]
表 2  Table 2
Figure imgf000014_0002
Figure imgf000014_0002
[0056] なお用いた着色剤、艷消剤の平均粒径は次のとおりである, カーボンブラック(CB) : 0. 04 μ ηί [0056] The average particle diameters of the colorant and the decoloring agent used are as follows: Carbon black (CB): 0.04 μ ηί
Cu— Cr系複合酸化物: 0. 26  Cu-Cr complex oxide: 0.26
酸化チタン (TiO ) : 0. 23 μ ηι  Titanium oxide (TiO): 0.23 μ ηι
2  2
銅フタロシアニン:0. 02  Copper phthalocyanine: 0.02
シリカ(SiO ) : 2. O ^ m  Silica (SiO 2): 2. O ^ m
2  2
[0057] 表 1から明らかなように、本発明例(実施例 1 2 : No. 1 16)の金属材料はいずれ もスパーク発生回数が 0で絶縁耐圧性が優れた。これは絶縁コーティング層が多層 に形成されているため異物や気泡の影響が軽減されたためである。また少なくとも 1 層を着色したもの(No. 1 1 16)は表面欠陥(ピンホール)の自動検査が的確に行 ο  As is clear from Table 1, all of the metal materials of the inventive examples (Example 12: No. 116) had zero spark occurrence and excellent dielectric strength. This is because the influence of foreign matter and air bubbles is reduced because the insulating coating layer is formed in multiple layers. In addition, for those with at least one layer colored (No. 1 1 16), automatic inspection of surface defects (pinholes) is performed accurately.
これに対し、比較例 1 (No. 17 23)の金属材料は絶縁コーティング層が単層のた めいずれもスパークが多数回発生し絶縁耐圧性が著しく劣った。  On the other hand, since the metal material of Comparative Example 1 (No. 17 23) had a single insulating coating layer, sparks were generated many times and the dielectric strength resistance was remarkably inferior.
産業上の利用の可能性  Industrial applicability
[0058] 本発明の金属材料は、電気電子機器、特に小型薄型の携帯式電気電子機器に搭 載される低背化電気電子部品、或いは、シールドコネクタ、カードコネクタ、薄型スィ ツチなどを電磁シールドするための電気電子部品(ケース、カバー、筐体、キャップな ど)用の金属材料として好適なものである。  [0058] The metal material of the present invention is an electromagnetic shield for electrical and electronic devices, particularly low-profile electrical and electronic components mounted on small and thin portable electrical and electronic devices, or shield connectors, card connectors, and thin switches. Therefore, it is suitable as a metal material for electrical and electronic parts (cases, covers, housings, caps, etc.).
[0059] 本発明をその実施態様とともに説明したが、我々は特に指定しない限り我々の発明 を説明のどの細部においても限定しょうとするものではなぐ添付の請求の範囲に示 した発明の精神と範囲に反することなく幅広く解釈されるべきであると考える。  [0059] While this invention has been described in conjunction with its embodiments, we do not intend to limit our invention in any detail of the description unless otherwise specified. The spirit and scope of the invention as set forth in the appended claims I think that it should be interpreted widely without contradicting.
[0060] 本願は、 2005年 1 1月 25日に日本国で特許出願された特願 2005— 340515、及 び 2006年 9月 6日に日本国で特許出願された特願 2006— 241909に基づく優先 権を主張するものであり、これらはいずれもここに参照してその内容を本明細書の記 載の一部として取り込む。  [0060] This application is based on Japanese Patent Application 2005-340515 filed in Japan on January 25, 2005, and Japanese Patent Application 2006-241909 filed in Japan on September 6, 2006. All of which are hereby incorporated herein by reference in their entirety.

Claims

請求の範囲 The scope of the claims
[1] 金属基材上の少なくとも絶縁を要する箇所に 2層以上の多層絶縁コーティング層が 設けられ、絶縁耐圧性を有することを特徴とする電気電子部品用金属材料。  [1] A metal material for electrical and electronic parts, which is provided with two or more multilayer insulation coating layers on at least a place where insulation is required on a metal base material, and has a withstand voltage resistance.
[2] 前記多層絶縁コーティング層の少なくとも 1層が着色され、前記着色によって該多 層絶縁コーティング層の絶縁欠陥の自動検知率を向上させたことを特徴とする請求 項 1記載の電気電子部品用金属材料。 [2] The electric / electronic component according to claim 1, wherein at least one of the multilayer insulation coating layers is colored, and the automatic detection rate of insulation defects of the multilayer insulation coating layer is improved by the coloring. Metal material.
[3] 金属基材上の少なくとも絶縁を要する箇所に、流動状塗布物を塗布し乾燥させる 塗装工程を複数回施すことを特徴とする請求項 1記載の電気電子部品用金属材料 の製造方法。 [3] The method for producing a metal material for electrical and electronic parts according to [1], wherein a coating step of applying and drying the fluidized coating is performed a plurality of times on at least a place requiring insulation on the metal substrate.
[4] 金属基材上の少なくとも絶縁を要する箇所に、流動状塗布物を塗布し乾燥させる 塗装工程を複数回施す電気電子部品用金属材料の製造方法であって、前記塗装 工程の少なくとも 1回の工程で塗布する流動状塗布物に着色剤が添加されているこ とを特徴とする請求項 2記載の電気電子部品用金属材料の製造方法。  [4] A method for producing a metal material for electrical and electronic parts, in which a fluidized coating is applied and dried at least on a place where insulation is required on a metal substrate, and the coating process is performed a plurality of times. 3. The method for producing a metal material for electrical and electronic parts according to claim 2, wherein a colorant is added to the fluidized coating applied in the step.
[5] 請求項 1または 2記載の電気電子部品用金属材料が用いられて 、ることを特徴とす る電気電子部品。  [5] An electrical / electronic component characterized in that the metal material for electrical / electronic component according to claim 1 or 2 is used.
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