WO2007049244A1 - Separateur gravitationnel et procede de separation d'un melange contenant de l'eau, de l'huile et du gaz - Google Patents

Separateur gravitationnel et procede de separation d'un melange contenant de l'eau, de l'huile et du gaz Download PDF

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Publication number
WO2007049244A1
WO2007049244A1 PCT/IB2006/053978 IB2006053978W WO2007049244A1 WO 2007049244 A1 WO2007049244 A1 WO 2007049244A1 IB 2006053978 W IB2006053978 W IB 2006053978W WO 2007049244 A1 WO2007049244 A1 WO 2007049244A1
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WO
WIPO (PCT)
Prior art keywords
gas
mixture
vessel
oil
gaseous medium
Prior art date
Application number
PCT/IB2006/053978
Other languages
English (en)
Inventor
Jørn Folkvang
Original Assignee
M-I Epcon As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by M-I Epcon As filed Critical M-I Epcon As
Priority to BRPI0617822-7A priority Critical patent/BRPI0617822A2/pt
Priority to EA200801205A priority patent/EA013256B1/ru
Priority to US12/084,144 priority patent/US8088286B2/en
Priority to AU2006307504A priority patent/AU2006307504B2/en
Priority to CA2626748A priority patent/CA2626748C/fr
Priority to CN2006800474834A priority patent/CN101330954B/zh
Publication of WO2007049244A1 publication Critical patent/WO2007049244A1/fr
Priority to NO20082427A priority patent/NO20082427L/no

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/0005Degasification of liquids with one or more auxiliary substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0205Separation of non-miscible liquids by gas bubbles or moving solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0208Separation of non-miscible liquids by sedimentation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/1412Flotation machines with baffles, e.g. at the wall for redirecting settling solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/24Pneumatic
    • B03D1/242Nozzles for injecting gas into the flotation tank
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/24Pneumatic
    • B03D1/247Mixing gas and slurry in a device separate from the flotation tank, i.e. reactor-separator type
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil

Definitions

  • a gravity separator and a method for separating a mixture containing water, oil, and gas.
  • the present invention relates to a gravity separator, primarily of the kind in which a mixture flowing from an oil well, containing water, oil, and gas is separated into discrete, vertically spaced water, oil, and gas layers in a separator vessel for subsequent extraction from the vessel by way of a water outlet, oil outlet, and gas outlet, respectively.
  • Gravity separators have been known for many decades and have been used within the oil industry in various embodiments of which some are quite complex, including a number of static mixers and cyclones. Examples of known types of gravity separators can be found in e.g. GB 1327991 and WO 99/25454.
  • US patent No. 5,080,802 discloses an air flotation separator having an eductor for drawing gas into the in- coming fluid. The eductor re-circulates gas collected in the uppermost section of the vessel to the incoming fluid.
  • the separator is provided with a coalescer riser tube positioned substantially in axial alignment with the axis of the vessel, and in order to obtain optimum coalescing high masses of gas, such as a gas to water ratio of about 30% is used.
  • gas flotation separator is known from US patent No. 5,516,434, and this separator is also provided with with a coalescer riser tube with filter medium.
  • a further separator for removing dispersed oil from an oil in water emulsion is disclosed in EP 0 793 987 where gas is dissolved in the inflowing water to form an aerated solution. This solution is intro- quiz quiz to the separator vessel in an assembly of closely spaced matrix plates formed of oleophilic material.
  • An object of the present invention is to provide a gravity separator that performs effectively and with a relatively simple construction and suitable low gas consumption.
  • the invention relates to a gravity separator comprising a vessel within which a mixture containing water, oil, and gas can separate under gravity to form vertically discrete oil and water layers and a gas phase, the vessel having an inlet duct communicating with a vessel entrance for the mixture containing water, oil, and gas; an outlet for wa- ter; an outlet for oil; and an outlet for gas, wherein the inlet duct of the gravity separator comprises injector means injecting a gaseous medium in a volume in the range of 0.01-1.9 Sm 3 gaseous medium per 1 m 3 mixture into the mixture containing water, oil, and gas.
  • a conduit supplying gaseous medium to the injector means re-circulates gas from the gravity separator to the injector means.
  • the re-circulation of gas reduces any consumption of gaseous medium from an external source.
  • the conduit for recirculation can collect gas from a gas processing device downstream of the outlet for gaseous medium from the separator.
  • the conduit supplying gaseous medium to the injector means is connected with the interior of the gravity separator at the upper part thereof.
  • conduit supplying re-circulated gas to the injector means is the sole supply of injection gas to the injector means.
  • the injector means in the inlet duct is spaced apart from the vessel entrance with a spacing in the range of 0.05 to 2.00 m. This separation of the injector means and the entrance makes it possible to obtain a very good mix of the gaseous medium with the mixture containing water, oil and gas.
  • the gravity separator may be provided with a mixer, preferably a static mixer, in the inlet duct between the injector means and the vessel entrance.
  • the inlet duct extends from above down through the vessel to the vessel entrance where the mixture flows out into the vessel.
  • the mixer may be located in a section of the inlet duct extending within the vessel so that a very compact design is obtained.
  • the present invention also relates to a method for separating a mixture containing water, oil, and gas, which method comprises the steps of: conducting the mixture to be separated via an inlet duct and a vessel entrance into a vessel, allowing the mixture in the vessel to separate under gravity into a water phase, an oil phase, and a gas phase; taking out the water phase via an outlet for water, taking out the oil phase via an outlet for oil, and taking out the gas phase via an outlet for gas; wherein a volume of gaseous medium in the range of 0.01-1.9 Sm 3 gaseous medium per 1 m 3 mixture is injected into the mixture flowing through the inlet duct to the vessel entrance.
  • This limited volume of injected gaseous medium has proven to sustain the separation process under gravity in the vessel and reduce costs for gas supplies without impairing the capacity of the separator.
  • the water taken out of the vessel may optionally be further cleaned be- fore it is returned to the reservoir.
  • the oil and gas may optionally be further processed before it is shipped off.
  • the dimension Sm 3 is used as the volumetric unit of gaseous medium injected in relation to the volume of mixture.
  • Sm 3 is standard cubic meters of the gaseous medium.
  • Sm 3 is standardised within the offshore field (volume of dry gas at 15.6 0 C and a pressure of 101.325 kPa).
  • the volume of gaseous medium injected into the mixture in the inlet duct is limited to a volume in the range of 0.05-0.40 Sm 3 gaseous medium per 1 m 3 mixture.
  • This volume can be withdrawn from the separator and be re- circulated to injection in the mixture in the inlet duct without any exter- nal supply of gaseous medium.
  • the mixture flowing to the separator on the upstream side of the injector means has a sufficient content of gas to provide the separator with the necessary volume of gaseous medium.
  • the mixture flow between the injector means and the entrance to the vessel of course has an increased amount of gas phase.
  • a volume of 0.05-0.15 Sm 3 gaseous medium per 1 m 3 mixture is injected into the mixture in the inlet duct, and in the most preferred method 0.08-1.2 Sm 3 gaseous medium per 1 m 3 mixture is injected into the mixture in the inlet duct.
  • the pressure in the vessel may vary and be within a wide range during operation from about 0.1 atm and upwards, it is normally preferred that the pressure in the vessel is in the range of 0.5 to 200 atm, conveniently in the range 1.0-100 atm. Adjustment of the pressure to an optimal value may improve formation of the gas phase and separation of the gas from the water and the oil.
  • the mixture containing water, oil, and gas is, in one embodiment, subjected to injection with one or more separation aids.
  • separation aids are normally in liquid form and include flocculants, emulsifiers etc.
  • the gaseous medium is re-circulated, optionally after re- extraction from the gas phase. If natural gas from the oil well is used as gaseous medium, it will normally not be necessary to re-extract it, as a part of the collected natural gas may be taken out and used as gaseous medium to be injected into the mixture containing water, oil and gas.
  • the embodiment provides for a cost-effective method with minimum waste of resources. Examples of embodiments of the present invention are described in further detail in the following with reference to the highly schematic drawings, in which :
  • Fig. 1 illustrates a first embodiment of a gravity separator according to the present invention
  • Fig. 2 illustrates a nozzle system suitable for use in the gravity separator in Fig. 1.
  • Fig. 3 illustrates an alternative embodiment of a separator according to the present invention.
  • a gravity separator 1 is shown with a vessel 2 with an inlet duct 3 having a vessel entrance 4 located within vessel 2.
  • the inflow of fluid mixture through entrance 4 spread itself freely into the vessel where gravity acts on the constituents in the mixture.
  • the vessel 2 is further equipped with an outlet for water 5, an outlet for oil 6, and an outlet for gas 7.
  • a weir plate 8 is provided that serves to separate water phase 9 from oil phase 10.
  • Gas phase 11 is collected at the location in the space above the water phase 9 and the oil phase 10.
  • an injector means In the inlet duct 3 of the vessel 2 is mounted an injector means
  • nozzle device 12 in form of a nozzle device for gas injection.
  • the nozzle device is feed with a gaseous medium via line 13.
  • the gaseous medium is injected into the mixture containing water, oil and gas in the inlet duct 3 before the mixture enters the vessel 2 via vessel entrance 4.
  • the vessel is preferably a horizontal, substantially cylindrical vessel 2 closed at both ends, preferably with curved or convex closings.
  • Vessel 2 and attached equipment can be made from suitable metallic al- loys, preferably stainless alloys. Vessel 2 is preferably assembled by welding.
  • the mixture containing water, oil and gas has a liquid appearance, which may be more or less viscous depending on the ratio between water and oil.
  • the gas normally disperses in the mixture as tiny bobbles.
  • the mixture containing water, oil and gas may contain further constituents, e.g. impurities from an oil well.
  • the mixture may also contain solids. Possible solids in the mixture will normally leave the separator with the water phase.
  • the injector means is one or more nozzles.
  • the nozzle may be any nozzle suitable to inject a gaseous medium into the mixture comprising water, oil and gas.
  • the nozzle is capable of operating at pressures in the range of 5 to 250 atm.
  • the vessel preferably has an internal volume in the range of 1 to 200 m 3 , such as 3 to 100 m 3 in order to optimise the input/output ratio.
  • the gravity separator comprises means to separate the water phase from the oil phase.
  • the means are mainly physical means like weir plates and the like, which may be located at the bottom part of the vessel preventing access of the water phase to a cer- tain zone in the vessel, but allowing oil to flow into that zone, and optionally, the outlet for oil is placed in this zone.
  • the internal portion of vessel 2 may also be equipped with one or more baffles and/or guide vanes to obtain a desired flow or stream in the vessel, which may improve the separation capacity of the gravity separator.
  • the gravity separator may comprise further means for injection of separation aids.
  • the separation aids are mainly in liquid form, e.g. flocculants, emulsifiers, etc. Injection of such separation aids may fur- ther improve the separation under gravity.
  • the separation aids may be injected in the inlet duct or in the vessel or in both.
  • the gaseous medium may be any gas suitable to facilitate the separation of water, oil and gas in the mixture.
  • the gaseous medium is selected from nitrogen, hydrogen, natural gas, carbon dioxide and mixtures thereof.
  • Natural gas is normally the gas that may be extracted from an oil well. When natural gas is chosen as the most preferable gaseous medium part, the extracted natural gas from the oil well may be recycled as the gaseous medium. In this manner, the gaseous medium may be obtained in a simple and cost-effective manner.
  • the injector means for gas can be installed in the inlet ducts of existing gravity separation tanks, thereby modifying and improving the capacity of the existing separation tanks.
  • the benefit of the present invention can be applied on gravity separator already installed and in use, e.g. on an oil producing plant which may be located onshore or offshore.
  • the injector means may be one or more suitable nozzles, which may conveniently be arranged in an annular shaped device.
  • Figs. 2a and 2b show a nozzle device 20 suitable for use in the invention.
  • the nozzle device consists substantially of an annular flange 21.
  • the inner peripheral surface 22 of the flange 21 is equipped with a number of holes 23 (in this depicted embodiment eight holes 23).
  • the holes 23 communicate with a channel 24 within the flange 21 (the channel 24 is shown with dotted lines in figure 2 b).
  • the channel 24 further communicates with a supply line 25 for the gaseous medium, which is fastened to the outer peripheral surface 26 of the flange 21.
  • the nozzle device 20 is capable of providing a god mix of the mixture and the gaseous medium in the inlet duct 3 (Fig. 1).
  • FIG. 3 depicts an alternative embodiment of the gravity sepa- rator according to the invention.
  • the alternative gravity separator 31 comprises a vessel 32.
  • the separator 31 is also equipped with an inlet duct 33 communicating with the interior of the vessel 32 via vessel entrance 34, an outlet for water 35, an outlet for oil 36 and an outlet for gas 37.
  • a nozzle device 38 is located in the inlet duct 33 and fed with gas via a pipeline 39 from the interior of the vessel 32.
  • a static mixer is arranged to ensure good mixing of the mixture entering the vessel 32 via vessel entrance 34.
  • the gaseous medium is taken directly from the gas separated in the vessel 32 and extra supply of the gaseous medium can be avoided.
  • the injector means in the inlet can be combined with a pump in the conduit for withdrawing gas from upper portion of the vessel.
  • a pump in the conduit for withdrawing gas from upper portion of the vessel Such an embodiments is however less favourable because it is more complicated and not an automatic, self- regulating system which is independent from outside supplies and has no moving parts.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Cyclones (AREA)
  • Physical Water Treatments (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Removal Of Floating Material (AREA)

Abstract

L'invention concerne un séparateur gravitationnel comportant une cuve dans laquelle un mélange contenant de l'eau, de l'huile et du gaz peut être fractionné sous l'effet de la gravité de manière à former des couches d'huile et d'eau verticalement discrètes, et une phase gazeuse. Un conduit d'entrée communique avec une entrée de la cuve destinée au mélange contenant de l'eau, de l'huile et du gaz. Le conduit d'entrée du séparateur gravitationnel comporte des éléments injecteurs injectant un fluide gazeux dans un volume de l'ordre de 0,01-1,9 Sm3 de fluide gazeux pour 1 m3 de mélange pour le mélange contenant de l'eau, de l'huile et du gaz.
PCT/IB2006/053978 2005-10-28 2006-10-27 Separateur gravitationnel et procede de separation d'un melange contenant de l'eau, de l'huile et du gaz WO2007049244A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BRPI0617822-7A BRPI0617822A2 (pt) 2005-10-28 2006-10-27 separador por gravidade, e um método para separação de um mistura contendo água, óleo e gás
EA200801205A EA013256B1 (ru) 2005-10-28 2006-10-27 Гравитационный сепаратор и способ разделения смеси, содержащей воду, нефть и газ
US12/084,144 US8088286B2 (en) 2005-10-28 2006-10-27 Gravity separator, and a method for separating a mixture containing water, oil, and gas
AU2006307504A AU2006307504B2 (en) 2005-10-28 2006-10-27 A gravity separator, and a method for separating a mixture containing water, oil, and gas
CA2626748A CA2626748C (fr) 2005-10-28 2006-10-27 Separateur gravitationnel et procede de separation d'un melange contenant de l'eau, de l'huile et du gaz
CN2006800474834A CN101330954B (zh) 2005-10-28 2006-10-27 重力分离器和用于分离含有水、油以及气体的混合物的方法
NO20082427A NO20082427L (no) 2005-10-28 2008-05-27 En gravitasjonsseparator og en fremgangsmåte for å separere en blanding inneholdende vann, olje og gass

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05388091.0 2005-10-28
EP05388091A EP1782869A1 (fr) 2005-10-28 2005-10-28 Un Séparateur par gravité.

Publications (1)

Publication Number Publication Date
WO2007049244A1 true WO2007049244A1 (fr) 2007-05-03

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PCT/IB2006/053978 WO2007049244A1 (fr) 2005-10-28 2006-10-27 Separateur gravitationnel et procede de separation d'un melange contenant de l'eau, de l'huile et du gaz

Country Status (10)

Country Link
US (1) US8088286B2 (fr)
EP (1) EP1782869A1 (fr)
CN (1) CN101330954B (fr)
AU (1) AU2006307504B2 (fr)
BR (1) BRPI0617822A2 (fr)
CA (2) CA2816148A1 (fr)
EA (1) EA013256B1 (fr)
MY (1) MY145371A (fr)
NO (1) NO20082427L (fr)
WO (1) WO2007049244A1 (fr)

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US20110174741A1 (en) * 2008-07-14 2011-07-21 Mir Mahmood Sarshar Cyclonic separation system comprising gas injection means and method for separating a fluid mixture

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US8424784B1 (en) 2012-07-27 2013-04-23 MBJ Water Partners Fracture water treatment method and system
US9896918B2 (en) 2012-07-27 2018-02-20 Mbl Water Partners, Llc Use of ionized water in hydraulic fracturing
GB2510184A (en) * 2013-01-29 2014-07-30 Airbus Operations Ltd Aircraft fuel system with reservoir in pressure sensor line
CN105476512B (zh) * 2016-02-22 2017-10-10 贾惠涵 一种无油汤勺
US10456714B2 (en) * 2016-02-24 2019-10-29 William Jacob Management, Inc. Multi-purpose gas separator unit
CN107376425A (zh) * 2017-08-22 2017-11-24 浙江美纳环保科技有限公司 一种浮油收集分离机
BR102017023118B1 (pt) * 2017-10-26 2021-11-30 Petróleo Brasileiro S.A. - Petrobras Separador multifásico de primeiro estágio, e método de separação de um fluido multifásico
EP3539638B1 (fr) * 2018-03-14 2021-02-24 Tata Consultancy Services Limited Appareil intégré de mélange et de séparation de phases de fluide et procédé associé
DE102018216494A1 (de) * 2018-09-26 2020-03-26 Bayerische Motoren Werke Aktiengesellschaft Betriebsmittelversorgungsanlage mit einem Luftabscheider, Kraftfahrzeug und Verfahren zum Betrieb einer Betriebsmittelversorgungsanlage
US11794893B2 (en) 2020-09-08 2023-10-24 Frederick William MacDougall Transportation system for transporting organic payloads
US11414962B2 (en) 2020-09-08 2022-08-16 Frederick William MacDougall Coalification and carbon sequestration using deep ocean hydrothermal borehole vents

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DE3325969A1 (de) * 1983-07-19 1985-01-31 Klöckner-Humboldt-Deutz AG, 5000 Köln Vorrichtung zur begasung von fluessigkeiten, insbesondere einer mit flotationsreagenzien versetzten fluessigkeits-feststoff-suspension
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US5516434A (en) * 1995-05-26 1996-05-14 Unicel, Inc. Single cell gas flotation separator with filter media
EP0793987A2 (fr) * 1996-03-05 1997-09-10 National Tank Company Procédé de deshuilage d'une émulsion huile-eau utilisant des solutions aérées dans un milieu coalescent
WO2002066137A1 (fr) * 2001-02-23 2002-08-29 Statoil Asa Procede destine a separer l'huile, l'eau et le gaz dans un separateur par rupture d'emulsions eau dans l'huile
EP1388370A1 (fr) * 2002-08-07 2004-02-11 Voith Paper Patent GmbH Procédé d' élimination des impuretés d'une suspension de pâte à papier aqueuse

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US20110174741A1 (en) * 2008-07-14 2011-07-21 Mir Mahmood Sarshar Cyclonic separation system comprising gas injection means and method for separating a fluid mixture
US9073064B2 (en) * 2008-07-14 2015-07-07 Caltec Limited Cyclonic separation system comprising gas injection means and method for separating a fluid mixture

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BRPI0617822A2 (pt) 2011-08-09
EA013256B1 (ru) 2010-04-30
MY145371A (en) 2012-01-31
EP1782869A1 (fr) 2007-05-09
CN101330954B (zh) 2012-07-25
CA2626748A1 (fr) 2007-05-03
NO20082427L (no) 2008-05-27
CN101330954A (zh) 2008-12-24
EA200801205A1 (ru) 2009-02-27
AU2006307504A1 (en) 2007-05-03
CA2816148A1 (fr) 2007-05-03
US20100006517A1 (en) 2010-01-14
CA2626748C (fr) 2015-12-08
AU2006307504B2 (en) 2010-08-19
US8088286B2 (en) 2012-01-03

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