WO2007014492A1 - Formulation émulsifiante mélangée et aqueuse pour essence, sa préparation et procédé de fabrication d’essence émulsifiée et aqueuse à partir de la formulation et de son produit - Google Patents

Formulation émulsifiante mélangée et aqueuse pour essence, sa préparation et procédé de fabrication d’essence émulsifiée et aqueuse à partir de la formulation et de son produit Download PDF

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Publication number
WO2007014492A1
WO2007014492A1 PCT/CN2005/001187 CN2005001187W WO2007014492A1 WO 2007014492 A1 WO2007014492 A1 WO 2007014492A1 CN 2005001187 W CN2005001187 W CN 2005001187W WO 2007014492 A1 WO2007014492 A1 WO 2007014492A1
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WO
WIPO (PCT)
Prior art keywords
gasoline
water
emulsified
watered
formulation
Prior art date
Application number
PCT/CN2005/001187
Other languages
English (en)
Chinese (zh)
Inventor
Liefan Luo
Original Assignee
Wang, Longzhen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wang, Longzhen filed Critical Wang, Longzhen
Priority to PCT/CN2005/001187 priority Critical patent/WO2007014492A1/fr
Publication of WO2007014492A1 publication Critical patent/WO2007014492A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328—Oil emulsions containing water or any other hydrophilic phase
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/191—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/226—Organic compounds containing nitrogen containing at least one nitrogen-to-nitrogen bond, e.g. azo compounds, azides, hydrazines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2368—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing heterocyclic compounds containing nitrogen in the ring

Definitions

  • the invention relates to an emulsifier, in particular to a formula of a gasoline water-incorporated compound emulsifier; the invention also relates to a method and a product thereof for preparing a gasoline hydrating compound emulsifier by using the formula, and a compound emulsifier using a gasoline water-mixing agent A method of producing emulsified gasoline and a product thereof.
  • the technical problem to be solved by the present invention is to provide a gasoline-water compound emulsifier formulation, which can mix gasoline and water into an emulsified form, save energy and protect the environment.
  • the present invention also provides a method for preparing a gasoline water-incorporated compound emulsifier and a product thereof, and a method for producing an emulsified gasoline using a gasoline-water compound emulsifier and a product thereof.
  • gasoline-water compound emulsifier formulation of the present invention is composed of the following weight ratio components:
  • the method for preparing a gasoline-water compound emulsifier comprises the steps of: placing each component in a container according to the above ratio, and then heating in a water bath to 60 ° C to 80 ° C for 5 to 10 minutes, Stir well and cool.
  • a gasoline-water compound emulsifier (brown paste viscous body) can be obtained by the above preparation method.
  • the method for producing water-containing emulsified gasoline by using the gasoline-water compound emulsifier comprises the following steps: According to the weight ratio, add 1 ⁇ 2% and 10 ⁇ 15% water of gasoline-water compound emulsifier to ordinary gasoline (base oil), and then stir it for 5 ⁇ 10 minutes with a general mechanical stirring device.
  • Emulsified gasoline having a stability of 30 days or more can be obtained by the above production method.
  • the gasoline-water compound emulsifier of the invention has the following main features:
  • the main component of the compound emulsifier is a water-depleted sorbitan monotetradecanoate, which is used as a main raw material by medicine and chemical plant waste. Therefore, not only the raw materials are wide, but also the cost is very low.
  • Emulsified gasoline made from gasoline-water compound emulsion can greatly reduce the emission concentration of exhaust gas during use, and is an environmentally friendly product.
  • the prepared emulsified gasoline has the same value as the base oil and is better than ordinary gasoline (base oil).
  • gasoline-water-incorporated compound emulsifier of the present invention and the emulsified gasoline produced using the emulsifier will be further described in detail in conjunction with specific examples.
  • Examples 1 to 2 The components of the formulation shown in Table 1 were placed in a beaker or other similarly functional container by weight ratio, and then placed in a 60-80 ° C water-soluble tank for heating, 5 to 10 minutes, and slightly After stirring, the gasoline-injected compound emulsifier of the present invention is obtained, and the emulsifier is a brown paste-like viscous body.
  • Table 1 The components of the formulation shown in Table 1 were placed in a beaker or other similarly functional container by weight ratio, and then placed in a 60-80 ° C water-soluble tank for heating, 5 to 10 minutes, and slightly After stirring, the gasoline-injected compound emulsifier of the present invention is obtained, and the emulsifier is a brown paste-like viscous body. Table 1
  • the gasoline-water compound emulsifier obtained in the above-mentioned Examples 1 to 2 was added to the conventional gasoline (base oil, the base oil of the present embodiment was 90 # unleaded gasoline).
  • the water is 13.5% to 15%, and then the water-in-oil type emulsified gasoline for transportation or industrial use can be obtained by stirring for 5 to 10 minutes using a general mechanical stirring device.
  • the obtained emulsified gasoline is tested according to the test method stipulated by the Chinese GB mandatory national standard, and the comparison results of various technical indexes and base oil are shown in Table 2.
  • the emulsified oil of the present invention has higher combustion efficiency than the base gasoline and is therefore more complete and more complete than the base gasoline combustion. Its emission concentration is lower than that of EU 4 (EU 0BD standard, NO. 4), which means that the environmental performance is very good. At the same time, since the combustion efficiency is higher than that of the base gasoline, the emulsified gasoline of the present invention has two fuel-saving effects, and the average fuel economy is 15 to 20% or more.
  • the main component of the gasoline-water-incorporated compound emulsifier of the present invention is a water-depleted sorbitan monotetradecanoate, which is used as a main raw material in medicine and a chemical plant, so that the raw material is wide and the cost is very low.
  • the emulsified gasoline of the invention adopts an engine bench test, a vehicle road test and a practical driving application test.
  • the test results show that the combustion efficiency, antiknock performance and dynamic performance of the emulsified gasoline of the present invention are significantly superior to those of the base oil. '
  • the gasoline mixed water emulsifier of the invention has good dynamic performance and has a secondary fuel saving effect, and the average fuel saving rate is 15% ⁇ 20% or more, and the economic benefit is particularly excellent.
  • Embodiment 1 Embodiment 2
  • Residual amount, % (V/V) is not greater than 2 2 2
  • GB mandatory benzene content, % ⁇ /) is not more than 2.5 2.5 2.5 Petroleum standard aromatic content, %(V/V) is not more than 40 40 GB/T11132 olefin content, %CV/V) is not greater than • 35 35 35 GB/ TH 132

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L’invention concerne une formulation émulsifiante mélangée et aqueuse pour essence, sa préparation, ainsi qu’un procédé de fabrication d’essence émulsifiée et aqueuse à partir de la formulation et de son produit. Ladite formulation consiste en 60 à 75 % de monomyristate de sorbitan, 7 à 10 % de Peregal O, 5 à 8 % d’agent dispersant IW, 2 à 4 % de 12-hydroxyl-lithium-stéarate, 4 à 8 % de graisse de laine, 4 à 7 % d’aziminobenzène et 1 à 4 % d’isopentanol (en pourcentages massiques). L’essence émulsifiée préparée à partir dudit émulsifiant a un rendement de combustion plus élevé, permet d’économiser du pétrole et a un impact moindre en termes de pollution environnementale.
PCT/CN2005/001187 2005-08-03 2005-08-03 Formulation émulsifiante mélangée et aqueuse pour essence, sa préparation et procédé de fabrication d’essence émulsifiée et aqueuse à partir de la formulation et de son produit WO2007014492A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2005/001187 WO2007014492A1 (fr) 2005-08-03 2005-08-03 Formulation émulsifiante mélangée et aqueuse pour essence, sa préparation et procédé de fabrication d’essence émulsifiée et aqueuse à partir de la formulation et de son produit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2005/001187 WO2007014492A1 (fr) 2005-08-03 2005-08-03 Formulation émulsifiante mélangée et aqueuse pour essence, sa préparation et procédé de fabrication d’essence émulsifiée et aqueuse à partir de la formulation et de son produit

Publications (1)

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WO2007014492A1 true WO2007014492A1 (fr) 2007-02-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110105991A (zh) * 2019-06-18 2019-08-09 河南晶品新材料科技有限公司 一种用于汽油车辆减排节油的太赫兹水基燃油添加剂及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5837088A (ja) * 1981-08-11 1983-03-04 グリントステツド・プロドウクツ・アクチエゼルスカベツト デイ−ゼル油中水の安定なエマルジヨンの製造方法
US4477258A (en) * 1980-10-30 1984-10-16 Labofina, S.A. Diesel fuel compositions and process for their production
CN1095752A (zh) * 1993-05-26 1994-11-30 赵文祥 汽油水基燃料及其制备方法
CN1126751A (zh) * 1995-08-22 1996-07-17 才伟 高效节能汽油、轻柴油化合剂及其合成油方法
CN1539924A (zh) * 2003-10-31 2004-10-27 罗列凡 柴油掺水复方乳化剂

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477258A (en) * 1980-10-30 1984-10-16 Labofina, S.A. Diesel fuel compositions and process for their production
JPS5837088A (ja) * 1981-08-11 1983-03-04 グリントステツド・プロドウクツ・アクチエゼルスカベツト デイ−ゼル油中水の安定なエマルジヨンの製造方法
CN1095752A (zh) * 1993-05-26 1994-11-30 赵文祥 汽油水基燃料及其制备方法
CN1126751A (zh) * 1995-08-22 1996-07-17 才伟 高效节能汽油、轻柴油化合剂及其合成油方法
CN1539924A (zh) * 2003-10-31 2004-10-27 罗列凡 柴油掺水复方乳化剂

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110105991A (zh) * 2019-06-18 2019-08-09 河南晶品新材料科技有限公司 一种用于汽油车辆减排节油的太赫兹水基燃油添加剂及其制备方法
CN110105991B (zh) * 2019-06-18 2021-07-30 天津中安信业集团有限公司 一种用于汽油车辆减排节油的太赫兹水基燃油添加剂及其制备方法

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