WO2006079273A1 - Procede et equipement pour le traitement d'eau potable - Google Patents

Procede et equipement pour le traitement d'eau potable Download PDF

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Publication number
WO2006079273A1
WO2006079273A1 PCT/CN2005/002193 CN2005002193W WO2006079273A1 WO 2006079273 A1 WO2006079273 A1 WO 2006079273A1 CN 2005002193 W CN2005002193 W CN 2005002193W WO 2006079273 A1 WO2006079273 A1 WO 2006079273A1
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Prior art keywords
active oxygen
photochemical oxidation
water
drinking water
ceramic
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PCT/CN2005/002193
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English (en)
French (fr)
Inventor
Kang Chen Sieh
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Kang Chen Sieh
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Application filed by Kang Chen Sieh filed Critical Kang Chen Sieh
Priority to US11/814,145 priority Critical patent/US20080128356A1/en
Publication of WO2006079273A1 publication Critical patent/WO2006079273A1/zh

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • C02F9/20Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/727Treatment of water, waste water, or sewage by oxidation using pure oxygen or oxygen rich gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

Definitions

  • the invention relates to a drinking water treatment process and a device thereof, in particular to a three-in-one treatment process and a device for drinking water. Background technique
  • human water purification and sterilization methods are nothing more than boiled boiling water, distilled water, purified water filtered by reverse osmosis, purified water produced by ion exchange or electrodialysis or pure water.
  • the above methods are not ideal.
  • the boiled boiled water is completely eliminated due to inorganic pollution and organic pollution. Long-term use is harmful to human health; while distilled water causes minerals in the water to disappear, but carcinogenic chlorides are still in it, and its cost is high. It is filtered by reverse osmosis.
  • the purpose of the present invention is to solve the above-mentioned drawbacks of the prior art and provide a combination of the ultraviolet light in the sunlight, the active oxygen in the air and the ceramic magnetic soil to achieve the most effective and natural natural drinking water.
  • a three-in-one treatment process for drinking water which includes a pretreatment process, and further includes a mixing process of active oxygen and water, a photochemical oxidation and reduction process, a ceramic membrane ultrafiltration process, and a backflushing process.
  • a three-in-one treatment device for drinking water which comprises a raw water storage tank, a coarse filter tank, a carbon filter tank, a fine filter tank, a water pipe, a valve, and further includes an active oxygen generator, an active oxygen mixer, and ultraviolet light.
  • the active oxygen generator passes through the pipeline and the active oxygen mixer chamber; one end of the active oxygen mixer is connected to the fine filter tank through the pipeline, and the other end is connected to the photochemical oxidation and reduction tube; the photochemical oxidation and reduction tube is disposed in the light source emitted by the ultraviolet light generator Within the area; photochemical oxidation and reduction tubes and ceramic magnetic ultrafilters ⁇ !
  • the above-mentioned three-in-one treatment process for drinking water wherein the mixed oxygen and water mixing process is set after the pretreatment process, and the active oxygen is added per liter of raw water before the photochemical oxidation and reduction process. 4mg/l, the temperature of raw water is 15°C-30°C, and the pressure of raw water is 1- 3kgf/cm 2 0
  • the aforementioned three-in-one treatment device for drinking water wherein the 3 ⁇ 4 active oxygen mixer is a mixing pump.
  • the above-mentioned three-in-one treatment device for drinking water wherein the photochemical oxidation and reduction tube is outside the tube wall
  • the side is coated with a polymer ceramic layer.
  • the above-mentioned three-in-one treatment apparatus for drinking water wherein the polymer ceramic layer is coated on the outer surface of the side of the photochemical oxidation and reduction tube remote from the light source.
  • polymer polyester, PET
  • PE polyethylene
  • tourmaline or medical stone with an average particle diameter of less than 100 nm, wherein the polymer resin has a weight content of 50 - 70%, tourmaline or The weight of the medical stone is 30-50%.
  • the invention has the advantages of effectively utilizing the combination of natural substances such as active oxygen, ultraviolet light and ceramic soil which are commonly found in nature, and the X-inch raw water is treated with pure water to make the treated water reach the texture of natural t ⁇ ffl water.
  • Figure 1 is a schematic view of the process of the present invention
  • Figure 2 is a schematic view of the apparatus of the present invention.
  • Figure 3 is a schematic view showing the surface structure of a photochemical oxidation and reduction tube. detailed description
  • the three-in-one treatment device for drinking water of the present invention comprises a raw water storage tank 1, a coarse filter tank 2, a carbon filter tank 3, a fine filter tank 4, a water pipe 5, and a valve 6, which Also included is an active oxygen generator 7, an active oxygen mixer 8, an ultraviolet light generator 9, a photochemical oxidation and reduction tube 10, a ceramic ultrafilter 11, and an active oxygen generator 7 through a pipe and an active oxygen mixer 8; Oxygen mixer 8 - end through the pipeline and fine filter tank 4, another The end is in communication with the photochemical oxidation and reduction tube 10; the photochemical oxidation and reduction tube 10 is disposed in the light source region emitted by the ultraviolet light generator 9; the photochemical oxidation and reduction tube 10 is in communication with the ceramic magnetic ultrafilter 11, and the active oxygen mixer 8 is mixed.
  • the raw water is pumped into the raw water storage tank 1 through the pump, and then through the water pipe 5 through the coarse filter tank 2, the carbon filter tank 3, the fine filter tank 4 to complete the water pretreatment process; the pretreated water is further ⁇ ⁇ oxygen mixer 8 At this time, the active oxygen (0 3 ) generated by the active oxygen generator 7 is also mixed into the active oxygen mixer 8 and mixed with water.
  • the active oxygen is added in an amount of l_4 mg/l per liter of raw water, and the temperature of the raw water is 15°.
  • the pressure of the raw water is 1-3 kgf / cm 2 ; complete the mixing process of active oxygen and water; the mixed water enters the photochemical oxidation and reduction tube 10, under the action of the ultraviolet light generator 9, its light energy
  • the excitation energy is 90-140kc a l/mol or 376-585k j/mol.
  • the active oxygen added in the previous process is subjected to anaerobic reaction in water to remove anaerobic bacteria in the water, while ultraviolet light ( UV) further sterilizes water and strengthens the oxidation and reduction functions of active oxygen to make photochemical oxidation and reduction reactions more complete.
  • the water that completes the photochemical oxidation and reduction process passes through the water pipe and enters the ceramic ultrafiltration device 11, the magnetic membrane ultrafiltration
  • the process is set in photochemical oxidation and reduction
  • the inner diameter of the ceramic magnetic filter 12 is 0. 0bu 0. 5 ⁇ , due to the use of the ceramic magnetic ultrafiltration membrane, the bacterial corpses left behind after UV sterilization in the photochemical oxidation and reduction process are filtered, so that the effluent of the water is discharged. Ok, and reduce the chance of secondary pollution.
  • the ceramic ultrafiltration membrane removes the organic and inorganic contaminants from the reduction of 0 3 by the reduced solid form, which also makes the water outlet feel better and reduces the damage of the pollutants to the human body; the ceramic ultrafiltration membrane 12 will be UV and 0. 3 bacteria and viruses that cannot be completely killed are completely filtered out.
  • the polymer ceramic layer 13 may be coated on the outside of the tube wall of the photochemical oxidation and reduction tube 10 remote from the light source.
  • the photochemical oxidation and reduction tube 10 is used in a multi-layered manner, it is only necessary to coat the polymer ceramic layer 13 on the outer side of the outermost tube wall; if the photochemical oxidation and reduction tube 10 is used in a single layer, the polymer ceramic Layer 13 should be applied outside of the tube wall that is remote from the source radiation.
  • the polymer ceramic layer 13 may be made of a polyester (PET) resin or a polyethylene (PE) resin mixed with tourmaline or medical stone having an average particle diameter of less than 100 nm, wherein the weight of the polymer resin Content is 50-70%, tourmaline or The weight of the medical stone is 30-50%; the ideal weight ratio is 2/3 of the polymer resin, 1/3 of the tourmaline or medical stone.
  • PET polyester
  • PE polyethylene
  • the backwashing system can be used to backwash the ceramic ultrafilter with a recoil pressure of 2 - 4 kgf / cra 2 . Due to the combined use of the foregoing processes, more than 96% of the organic pollutants in the water become carbon, water, oxygen, carbon dioxide and 0H, and the organic pollutants that are blocked on the ceramic membrane are solid, thus changing the water. The organic pollutants cause the adhesion and agglomeration to be lost. Therefore, when the ceramic ultrafiltration membrane is backwashed, the reduced solid matter can be easily discharged out of the ceramic ultrafilter, and the high-density ceramic membrane is easily clogged. And the problem of not being able to apply commercially.

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  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Clinical Laboratory Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physical Water Treatments (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Description

TO水的三合一处理工艺及其装置 技术领域
本发明涉及一种饮用水处理工艺及其装置, 特别为一种饮用水的三合一处理工艺 及其装置。 背景技术
目前, 人类洁水、 除菌的方法不外乎煮沸的开水、 蒸馏水, 以反渗透法滤出的纯 净水, 以离子交换法或电渗透析法生产出来的净水或纯水。 以上方法均不理想。 煮沸 的开水由于无机污染和有机污染完全没有清除, 长期使用有害人体健康; 而蒸馏水会 导致水中矿物质消失, 但致癌的氯化物仍在其中, 同时, 其成本高; 以反渗透法滤出 的纯净水, 口感不佳, 矿物质稀有元素全无, 制作时浪费 75%的水资源; 以离子交换 法所生产出来的水含钠太高, 口感不佳, 不能保证完全灭菌; 电渗透析法生产出来的 纯水, 生产出来的水成本太高, 浪费水资源, 且口感不佳。 亿万年来, 以大自然中的 空气、 阳光和沙石所净化的地表水才是人类最健康的饮用水, 这种水是全世界科学家 仍在追求、企图达到的目标。 大自然空气中所含有的活性氧 (03)俗名臭氧, 由于具 有强腐蚀性, 极易^ 1军, 水质、 水量变化时, 投加量调节困难, 一般都用于工业废水 处理,在 水业多半仅用于防止二次污染的灭菌手段。太阳光中的紫外光线 UV具有 杀菌能力, 但不能去除有机污染和无机污染。 虽然在 90年代人们发现 UV和 03的配合 使用, 它的协同效应非常良好, 但是由于仍然不能保证完全灭菌, 又不能和有机纤维 (超滤)和有机膜(R0反渗透)配合使用。 因此, 只大量应用于工业废水的处理, 而 不能应用在要求严格的饮用水处理上。传统方法中以陶磁膜过滤, 在使用中, 滤芯容 易堵塞, 特别是过滤时如存在有机污染物瞬时即堵塞, 无法实现反冲洗, 陶磁超滤膜 滤芯的生产和使用成本昂贵, 它不能像有机滤芯、 有机膜那样可以频频更换, 这也是 陶磁膜无法在觀水产鍾行商业运用的主要障碍。 发明内容
本发明的目的就是为了解决现有技术的上述缺陷而提供一种利用太阳光中具有的 紫外光、 空气中具有的活性氧与陶磁土三者联合作用, 达到目前对饮用水最有效、最 大自然方式的一种 水的三合一处理工艺及其装置。
本发明的目的通过以下技术解决方案来实现:
一种饮用水的三合一处理工艺, 它包括有前处理工序, 其它还包括有活性氧与水 混合工序、 光化学氧化与还原工序、 陶磁膜超滤工序、 反冲工序。
—种饮用水的三合一处理装置,它包括有原水贮水桶、粗滤罐、碳滤罐、精滤罐、 水管、 阀, 其中还包括有活性氧发生器、 活性氧混合器、 紫外光发生器、 光化学氧化 与还原管、 陶磁超滤器。 活性氧发生器通过管道与活性氧混合器廳; 活性氧混合器 一端通过管道与精滤罐连通, 另一端与光化学氧化与还原管连通; 光化学氧化与还原 管设在紫外光发生器发出的光源区域内; 光化学氧化与还原管与陶磁超滤器 ίϋ!。
本发明目的还可通过以下技术解决措施来进一步实现:
前述的一种饮用水的三合一处理工艺, 其中所述的有活性氧与水混合工序设在前 处理工序后, 光化学氧化与还原工序前, 其活性氧的加入量为每升原水 1- 4mg/l, 原 水的温度为 15°C- 30°C, 原水的压力为 1- 3kgf/cm2 0
前述的一种饮用水的三合一处理工艺, 其中所述的光化学氧化与还原工序设在陶 磁膜超滤工序前, 其光能的激发能量为 90- 140kcal/mol或 376_585k j/mol。
前述的一种饮用水的三合一处理工艺, 其中所述的反冲工序设在陶磁膜超滤工序 后, 其反冲压力为 2- 4kgf/cm2
前述的一种饮用水的三合一处理装置, 其中)¾的活性氧混合器为混合泵。
前述的一种饮用水的三合一处理装置, 其中所述的光化学氧化与还原管的管壁外 侧涂有高分子陶瓷层。
前述的一种饮用水的三合一处理装置, 其中所述的高分子陶瓷层涂在光化学氧化 与还原管的远离光源辐射的一侧的外表面。
前述的一种饮用水的三合一处理装置, 其中所述的高分子陶瓷层是由聚酯
(polyester, PET)树脂或者聚乙烯 (polyethylene, PE)树脂与平均粒径在 lOOnm 以下的电气石或者麦饭石混合而成的, 其中聚合物树脂的重量含量为 50 - 70%, 电气 石或者麦饭石的重量含量为 30-50% 。
前述的一种饮用水的三合一处理装置, 其中所述的陶磁超滤器内陶瓷滤膜的空径 为 0. 01-0. 5μπι。
本发明的优点在于有效利用大自然中普遍具有的活性氧、 紫外光线和陶磁土等自 然物质的组合, X寸原水进 纯水处理, 使处理过的水达到天然 t^ffl水的质感。
本发明的目的、 优点和特点, 将通过下面优先实施例的非限制性说明进行图示和 解释, 这些实施例是参照附图仅作为例子给出的。 附图说明
图 1为本发明工艺示意图;
图 2为本发明装置示意图;
图 3为光化学氧化与还原管的表面结构示意图。 具体实施方式
如图 1、 图 2所示, 本发明饮用水的三合一处理装置, 它包括有原水贮水桶 1、粗 滤罐 2、碳滤罐 3、精滤罐 4、水管 5、 阀 6, 它还包括有活性氧发生器 7、活性氧混合 器 8、 紫外光发生器 9、 光化学氧化与还原管 10、 陶磁超滤器 11, 活性氧发生器 7通 过管道与活性氧混合器 8麵; 活性氧混合器 8—端通过管道与精滤罐 4舰, 另一 端与光化学氧化与还原管 10连通; 光化学氧化与还原管 10设在紫外光发生器 9发出 的光源区域内; 光化学氧化与还原管 10与陶磁超滤器 11连通, 活性氧混合器 8为混 合泵(型号 USESE 20 QY2. 5)。 原水经过泵泵入原水贮水桶 1, 再通过水管 5依序经过 粗滤罐 2、碳滤罐 3、精滤罐 4完成水的前处理工序; 经过前处理的水再 ¾Λ 性氧混 合器 8, 此时活性氧发生器 7发生出的活性氧 (03)也进入活性氧混合器 8与水一起进 行混合, 其活性氧的加入量为每升原水 l_4mg/l, 原水的温度为 15°C- 30°C, 原水的压 力为 1- 3kgf/cm2 ; 完成活性氧与水混合工序; 经过混合的水进入光化学氧化与还原管 10 , 在紫外光发生器 9 的作用下, 其光能的激发能量为 90-140kcal/mol 或 376- 585k j/mol, 在此工序中, 上道工序中加入的活性氧在水中进行厌氧反应, 清除水 中的厌氧菌, 同时紫外光 (UV)对水进一步杀菌, 并加强了活性氧的氧化与还原功能, 使光化学氧化与还原反应更为彻底; 完成光化学氧化与还原工序的水经过水管进入陶 磁超滤器 11中, 陶磁膜超滤工序设在光化学氧化与还原工序前, 其内陶磁滤膜 12的 空径为 0. 0卜 0. 5μηι, 由于使用了本陶磁超滤膜, 光化学氧化与还原工序中 UV杀菌后 遗留的细菌尸体被过滤, 使流出的水口感好, 并减少了二次污染的机会。 陶磁超滤膜 将 03还原后的有机和无机污染物以还原后的固体形式滤除, 也使出水口感较好, 并减 少了污染物对人体的伤害; 陶磁超滤膜 12将 UV及 03不能完全杀灭的细菌与病毒完全 滤出。
为了起到更好的应用效果、 产生更多的负离子, 本发明饮用水的三合一处理装置 当中, 可以在光化学氧化与还原管 10 的远离光源辐射的管壁外侧涂覆高分子陶瓷层 13, 如图 3所示。 当光化学氧化与还原管 10是多层绕在一起使用时, 只需在最外层的 管壁外侧涂覆高分子陶瓷层 13; 若光化学氧化与还原管 10是单层使用, 则高分子陶 瓷层 13应当涂覆在远离光源辐射的管壁外侧。 这里, 高分子陶瓷层 13可以由聚酯 (polyester, PET)树脂或者聚乙烯(polyethylene, PE)树脂与平均粒径低于 lOOnm 的电气石或者麦饭石混合而成, 其中聚合物树脂的重量含量为 50-70%, 电气石或者 麦饭石的重量含量为 30-50% ;较为理想的重量配比是聚合物树脂占 2/3、电气石或者 麦饭石占 1/3。
在本装置使用一段时间后, 可以利用反冲洗系统对陶磁超滤器进行反冲洗, 其反 冲压力为 2- 4kgf/cra2。 由于前述工序的联合使用, 使 96%以上的水中有机污染物变成 了碳、水、氧、二氧化碳和 0H―,附着在陶磁膜上被阻隔的有机污染物还原物成为固体, 因而改变了水中的有机污染物使其丧失粘着力与团聚力, 因而在对陶磁超滤膜进行反 冲洗时, 可轻易地将该被还原固体物排出陶磁超滤器外, 解决了高密度陶磁膜极易堵 塞而无法商业应用的难题。
除上述实施例外, 本发明还可以有其它实施方式。 凡采用等同替换或等效变换形 成的技术方案, 均落在本发明要求保护的范围之内。

Claims

权 利 要 求
1. 一种饮用水的三合一处理工艺, 它包括有前处理工序, 其特征在于: 它还包括 有活性氧与水混合工序、 光化学氧化与还原工序、 陶磁膜超滤工序、 反冲工序。
2. 根据权利要求 1所述的一种饮用水的三合一处理工艺,其特征在于: 所述的活 性氧与水混合工序设在前处理工序后, 光化学氧化与还原工序前, 其活性氧的加入量 为每升原水 1- 4mg/l, 原水的温度为 15°C- 30°C, 原水的压力为 1- 3kgf/cm2
3. 根据权利要求 1所述的一种饮用水的三合一处理工艺,其特征在于: 所述的光 化学氧化与还原工序设在陶磁膜超滤工序前,其光能的激发能量为 90-140kcal/mol或 376-585kj/mol o
4. 根据权利要求 1所述的一种饮用水的三合一处理工艺,其特征在于: 所述的反 冲工序设在陶磁膜超滤工序后, 其反冲压力为 2- 3kgf/cm2
5. 一种 水的三合一处理装置, 它包括有原水贮水桶、粗滤罐、 碳滤罐、 精滤 罐、 7 管、 阀, 反冲洗系统, 其特征在于: 它还包括有活性氧发生器、 活性氧混合器、 紫外光发生器、 光化学氧化与还原管、 陶磁超滤器, 活性氧发生器通过管道与活性氧 混合器连通; 活性氧混合器一端通过管道与精滤罐连通, 另一端与光化学氧化与还原 管连通; 光化学氧化与还原管设在紫外光发生器发出的光源区域内; 光化学氧化与还 原管与陶磁超滤器¾¾。
6. 根据权利要求 5所述的一种饮用水的三合一处理装置, 其特征在于: 所述的活 性氧混合器为混合泵。
7. 根据权利要求 5所述的一种饮用水的三合一处理装置,其特征在于: 所述的光 化学氧化与还原管的管壁外侧涂有高分子陶瓷层。
8. 根据权利要求 7所述的一种饮用水的三合一处理装置,其特征在于: 所述的高 陶瓷层涂在光化学氧化与还原管的远离光源辐射的一侧的夕卜表面。
9.根据权利要求 7或 8所述的一种饮用水的三合一处理装置,其特征在于: 所述 的高^ 陶瓷层是由聚酯树脂或者聚乙烯树脂与平均粒径在 100 以下的电气石或者 麦饭石混合而成的, 其中聚合物树脂的重量含量为 50-70% , 电气石或者麦饭石的重 量含量为 30- 50%
10. 根据权利要求 5所述的一种 TO水的三合一处理装置, 其特征在于: 所述的 陶磁超滤器内陶瓷滤膜的空径为 0. 01-0. 5μπι
PCT/CN2005/002193 2005-01-28 2005-12-15 Procede et equipement pour le traitement d'eau potable WO2006079273A1 (fr)

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